JPS6059187A - Application of metal pattern to cloth - Google Patents
Application of metal pattern to clothInfo
- Publication number
- JPS6059187A JPS6059187A JP16856083A JP16856083A JPS6059187A JP S6059187 A JPS6059187 A JP S6059187A JP 16856083 A JP16856083 A JP 16856083A JP 16856083 A JP16856083 A JP 16856083A JP S6059187 A JPS6059187 A JP S6059187A
- Authority
- JP
- Japan
- Prior art keywords
- fabric
- pattern
- application
- silver
- electroless plating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Chemically Coating (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Decoration Of Textiles (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、布帛に無電解メッキを適用して金属模様を付
与する方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a method of imparting a metallic pattern to a fabric by applying electroless plating.
従来技術
従来、金属模様を有する布帛の製造は、金銀糸を柄糸と
した布帛の織成や布帛へのスタンピングホイルなどによ
る金属箔の貼着に限られていた。前者は帯地などの衣料
に用いられているが、特殊な糸を用いるだめ、その織成
法には限度があり、適用される生地及び模様に限度があ
った。また、後者は布帛に全く異質の硬い金属箔を取付
けるため、布帛の風合や通気性などが損なわれ、一部舞
台衣装に用いられることがあるとはいえ、広く衣料用に
使用できるものではなかった。BACKGROUND ART Conventionally, the production of fabrics having metallic patterns has been limited to weaving fabrics using gold and silver threads as pattern threads and pasting metal foils onto fabrics using stamping foil or the like. The former is used for clothing such as obi fabrics, but because special threads are used, there are limits to the weaving method, and there are limits to the fabrics and patterns that can be applied. In addition, the latter involves attaching hard metal foil of a completely different nature to the fabric, which impairs the texture and breathability of the fabric. Although it is sometimes used for stage costumes, it cannot be widely used for clothing. There wasn't.
発明の目的
本発明は、このような従来法の欠点を解消し、布帛の風
合や通気性を著しく害することなく、どのような布帛に
も効果的に金属模様をイづ与する方法を提供することを
目的とする。Purpose of the Invention The present invention eliminates the drawbacks of such conventional methods and provides a method for effectively imparting a metallic pattern to any fabric without significantly impairing the texture or breathability of the fabric. The purpose is to
発明の構成
本発明の方法は、布帛表面に、化学的及び/又は物理的
処理をして、無電解メッキ速度に差のある部分を模様状
に形成し、その後無電解メッキすることを特徴とする。Structure of the Invention The method of the present invention is characterized in that the surface of the fabric is chemically and/or physically treated to form areas with different electroless plating speeds in a pattern, and then electroless plating is performed. do.
るいはハンマーによる打撃やエンボス加工による組織表
面の変形処理など、布帛表面の処理面と非処理面の無電
解帰ける加工がいずれも適用できる。特に、撥水剤処理
、親水性樹脂の塗布、エンボス加工又はこれらの組合わ
せかなるものが、効果的に利用できる。Electroless processing of the treated and non-treated surfaces of the fabric can be applied, such as deformation of the tissue surface by hammering or embossing. In particular, any treatment with a water repellent, coating with a hydrophilic resin, embossing or a combination thereof can be effectively utilized.
撥水剤としては、シリコン系、パラフィン系又はフッ素
系撥水剤がいずれも適用でき、撥水剤塗布部分は無電解
メッキ液を付着しないため、非メッキ部分として残る。Any silicone-based, paraffin-based or fluorine-based water repellent can be used as the water repellent, and since the electroless plating solution does not adhere to the water repellent applied area, it remains as a non-plated area.
次に、触媒毒となる金属化合物、例えば錫、ビスマス、
カドミウム、アンチモン、鉛、亜鉛などを含む化合物の
適用は、適用部分での無電解メッキ速度を落とし、完全
なメッキを不能とする効果がある。これら化合物は樹脂
等を併含する塗料として適用するのがよ−。Next, metal compounds that act as catalyst poisons, such as tin, bismuth,
Application of compounds containing cadmium, antimony, lead, zinc, etc. has the effect of slowing down the electroless plating rate in the applied area, making complete plating impossible. These compounds are best applied as paints containing resins and the like.
また、親水性すなわち撥水性のない塗料としては、ポリ
アミド樹脂、ニトロセルローズ系樹脂などの一般的な合
成樹脂塗料が利用できる。Furthermore, as the paint that is not hydrophilic, that is, water repellent, general synthetic resin paints such as polyamide resins and nitrocellulose resins can be used.
親水性塗料塗布部分は無電解メッキに対する触媒化工程
などが強く作用し、鮮明にして堅牢な金属模様が形成さ
れる。The catalytic process for electroless plating works strongly on the areas where the hydrophilic paint is applied, forming a clear and durable metal pattern.
更に、ハンマーによる打撃やエンボス加工では布帛表面
の組織が物理的にエツチングされ、かつまた扁平化され
て、上述の如きメッキ効果がより強大となり、該加工面
は無電解メッキによって、ソフトな広がシをもった金属
模様に形成サレル。また、撥水剤処理後にエンボス加工
をすると、エンボス加工部分の撥水剤塗膜が破壊される
ため、エンボス加工面にのみ鮮かな金属塗膜が形成され
る。Furthermore, when hitting with a hammer or embossing, the structure of the fabric surface is physically etched and flattened, making the plating effect as described above even stronger, and the processed surface has a soft spread due to electroless plating. Sarel formed into a metal pattern with a shank. Furthermore, when embossing is performed after water repellent treatment, the water repellent coating on the embossed area is destroyed, so a bright metal coating is formed only on the embossed surface.
なお、無電解メッキ法としては、一般的な方法がいずれ
も利用でき、無電解メッキ法と置換メッキ、あるいは電
解メッキ、電解腐蝕などを併用してもよい。Note that any general method can be used as the electroless plating method, and electroless plating and displacement plating, electrolytic plating, electrolytic corrosion, etc. may be used in combination.
更に、本発明では、変色し易い金属を利用する場合には
、金属模様上にIn、Niなどの金属又は合成樹脂など
の保護膜を形成してもよい。Furthermore, in the present invention, when a metal that easily discolors is used, a protective film of metal such as In or Ni or synthetic resin may be formed on the metal pattern.
しかし、本発明では布帛にメッキするだめ、金属膜は布
帛の表裏全体の組織に均一に結合した状態で形成される
ため、一般には保護膜を必要としない、非常に風合のよ
い製品を得ることができる。However, in the present invention, instead of plating the fabric, the metal film is formed uniformly bonded to the structure on the entire front and back of the fabric, so generally a protective film is not required and a product with a very good texture can be obtained. be able to.
実施例(1)
ポリエステル繊維50D/12 Fを経糸とし、75D
/24Fを緯糸として織布を形成し、これに赤色の撥水
性塗料を唐草模様にスクリーン捺染し、加熱乾燥後、銅
鏡反応による銀メッキをし、更に銀の変色防止の為、イ
ンジウムを電解メッキした。Example (1) The warp is made of polyester fiber 50D/12F, and 75D
/24F is used as the weft to form a woven fabric, which is screen-printed with a red water-repellent paint in an arabesque pattern. After heating and drying, it is plated with silver using a copper mirror reaction, and then electrolytically plated with indium to prevent the silver from discoloring. did.
製品は、銀色の地に赤色の唐草模様が浮き出1各 8情
すIr事恭ち庄軸hシ外つ奔−実施例(2)
ポリアミド繊維20D/IFを経糸及び緯糸に用いて製
織しだ紗織布の全面に、撥水剤を付着させ、その後幅5
肩肩の斜線縞の柄をエンボス加工し、更に銅鏡反応によ
る銅メッキをしだ。The product is made of silver with a red arabesque pattern embossed on it.Example (2) Polyamide fiber 20D/IF is woven using polyamide fiber 20D/IF for the warp and weft. A water repellent is applied to the entire surface of the gauze fabric, and then a width of 5
The diagonal striped pattern on the shoulders is embossed, and it is further plated with copper using copper mirror reaction.
その結果、エンボス加工した部分は加熱加圧によって、
経糸及び緯糸が幾分扁平となり、織組織が変化し、更に
撥水膜も破壊されるため、銅が付着し、美しい銅色の斜
縞模様の布帛が得られた。As a result, the embossed part is heated and pressurized.
The warp and weft became somewhat flattened, the weave structure changed, and the water-repellent film was also destroyed, resulting in copper adhesion and a beautiful copper-colored fabric with a diagonal striped pattern.
更に、この布帛をクロメート処理し、銅色模様を玉虫様
の色調に変え、合成樹脂塗膜の形成で変色防止して、玉
虫色の大胆な続柄の服地を得た。Furthermore, this fabric was treated with chromate to change the copper-colored pattern to an iridescent tone, and a synthetic resin coating was formed to prevent discoloration, resulting in a fabric with a bold iridescent pattern.
実施例(3)
ポリアミド繊維50D/15Fを経糸及び緯糸として得
た織布に、親水性の合成樹脂を鮫小紋(径0.2〜0.
31111の点状の柄)に印捺し、塩化第一錫4F!/
lと塩酸2 ocr−71を含む処理液で処理し、水洗
後、塩化パラジウム1 g/lとHC6lax/lを含
む液に浸漬して、水洗しその後無電解ニッケルメッキし
た。Example (3) A hydrophilic synthetic resin was applied to a woven fabric made of polyamide fibers 50D/15F as warp and weft yarns in a shark pattern (diameter 0.2 to 0.0 mm).
31111 dotted pattern) and stamped with stannous chloride 4F! /
After washing with water, it was immersed in a solution containing palladium chloride 1 g/l and HC6lax/l, washed with water, and then electroless nickel plated.
その結果、渋い銀色の地に、鮫小紋の点状の柄が銀色に
強く輝く、非常に洒落たプリント地が得られた。As a result, a very fashionable printed fabric was obtained, with the dotted pattern of the shark pattern shining strongly in silver on a dark silver background.
なお、上述の方法で塩化パラジウムによる触媒化処理後
の水洗を通常の約3倍と長くすると、合成樹脂印捺部分
以外の織物地はメッキされず白く残った。次にこれを分
散染料で黒色に染めだところ、黒色の地に銀色の鮫小紋
が美しく配置された非常に優雅なプリント地となった。In addition, when washing with water after the catalytic treatment with palladium chloride in the above-mentioned method was carried out for about three times as long as usual, the fabric other than the synthetic resin printed area remained white without being plated. Next, this was dyed black using disperse dye, resulting in a very elegant printed material with beautifully arranged silver shark patterns on a black background.
実施例(4)
実施例(2)と同様の撥水剤処理した織布に、20Mの
径の水玉模様をエンボス加工した後、銀反応液に30’
Cで60秒間浸漬し、水洗、乾燥した。Example (4) A woven fabric treated with a water repellent similar to Example (2) was embossed with a 20M diameter polka dot pattern, and then immersed in a silver reaction solution for 30 minutes.
C for 60 seconds, washed with water, and dried.
製品は灰色の地に輪郭のはつきりした銀色の水玉模様が
浮き出した、風合のよい服地となった。The product is a textured fabric with a sharp silver polka dot pattern that stands out on a gray background.
銀反応液の浸漬時間を180秒として前記同様の方法を
くり返すと、砂子状の銀色の地に、燦然たる銀色の水玉
模様が飛び散った美しい服地となった。When the same method as described above was repeated with the immersion time in the silver reaction solution being 180 seconds, a beautiful cloth with brilliant silver polka dots scattered on a grain-like silver background was obtained.
いずれの服地も、化成被膜の形成と、樹脂コーティング
によって変色防止加工した。Both fabrics were treated to prevent discoloration through the formation of a chemical conversion film and resin coating.
実施例(5)
実施例(2)と同様の撥水剤処理した織布に、親水性の
合成樹脂液を花柄に印捺し、乾燥後、350C1分間の
銀鏡反応処理した。その結果、未処理部分は全く反応せ
ず、花柄のプリント部分にのみ銀鏡反応が起った。水洗
、乾燥後、プリント柄に同調させて、プリント柄の表面
と裏面を、花弁部分にはピンク色に、枝の部分は茶色に
、そして葉の部分は緑色に着色した透明樹脂を用いてそ
れぞれ保護コーティングして、金属光沢ある美しい花柄
の風合のよいプリント地を得た。柄部分以外は生地がそ
のままの状態で残るため、非常に触感のよい扱い易い服
地となった。Example (5) A hydrophilic synthetic resin liquid was printed on a floral pattern on a woven fabric treated with a water repellent as in Example (2), and after drying, a silver mirror reaction treatment was performed at 350C for 1 minute. As a result, there was no reaction at all in the untreated area, and a silver mirror reaction occurred only in the floral print area. After washing and drying, the front and back sides of the printed pattern are colored pink for the petals, brown for the branches, and green for the leaves using transparent resin to match the printed pattern. By applying a protective coating, we obtained a printed fabric with a beautiful metallic luster and a nice texture. The fabric remains intact except for the pattern, making the fabric extremely tactile and easy to handle.
発明の効果
本発明では、布帛の風合や通気性などをほとんど害する
ことなく、美しい金属模様布帛を得ることかできる。ま
た、形成された金属模様の金属膜は基布の組織すなわち
フィラメントの周囲を均一に覆うため、堅牢度に強く、
本発明の製品は衣料用としても幅広く使用できるものと
なる。Effects of the Invention According to the present invention, a beautiful metal-patterned fabric can be obtained without substantially impairing the feel or air permeability of the fabric. In addition, the formed metallic film with a metallic pattern uniformly covers the structure of the base fabric, that is, the surroundings of the filaments, so it has strong fastness.
The product of the present invention can be widely used for clothing.
特許出願人 安 凋 八 部 代理人 新実健部 外1名Patent Applicant: Yasushi Yabu Agent Kenbe Niimi 1 other person
Claims (2)
、無電解メッキ速度に差のある部分を模様状に形成し、
その後無電解メッキすることを特徴とする布帛に金属模
様を付与する方法。(1) Applying chemical and/or physical treatment to the surface of the fabric to form areas with different electroless plating speeds in a pattern,
A method of imparting a metallic pattern to a fabric, which comprises then electroless plating.
物の適用、親水性樹脂の塗布、エンボス加工又はこれら
の組合わせからなることを特徴とする特許請求の範囲第
1項記載の方法。(2) Claim 1, characterized in that the above-mentioned treatment consists of a water repellent treatment, application of a metal compound that acts as a desolative poison, application of a hydrophilic resin, embossing, or a combination thereof. the method of.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16856083A JPS6059187A (en) | 1983-09-12 | 1983-09-12 | Application of metal pattern to cloth |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16856083A JPS6059187A (en) | 1983-09-12 | 1983-09-12 | Application of metal pattern to cloth |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6059187A true JPS6059187A (en) | 1985-04-05 |
Family
ID=15870289
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP16856083A Pending JPS6059187A (en) | 1983-09-12 | 1983-09-12 | Application of metal pattern to cloth |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6059187A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62257487A (en) * | 1986-05-01 | 1987-11-10 | 東レ株式会社 | Metal-containing cloth and its production |
WO2014065207A1 (en) * | 2012-10-26 | 2014-05-01 | 太陽化学工業株式会社 | Mesh structure and manufacturing method therefor |
WO2016126212A1 (en) * | 2015-02-04 | 2016-08-11 | Agency For Science, Technology And Research | A process for plating a metal on a textile fiber |
JP2017031441A (en) * | 2015-07-29 | 2017-02-09 | 日立マクセル株式会社 | Manufacturing method of plated part and plated part |
-
1983
- 1983-09-12 JP JP16856083A patent/JPS6059187A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62257487A (en) * | 1986-05-01 | 1987-11-10 | 東レ株式会社 | Metal-containing cloth and its production |
JPH0379479B2 (en) * | 1986-05-01 | 1991-12-18 | Toray Industries | |
WO2014065207A1 (en) * | 2012-10-26 | 2014-05-01 | 太陽化学工業株式会社 | Mesh structure and manufacturing method therefor |
WO2016126212A1 (en) * | 2015-02-04 | 2016-08-11 | Agency For Science, Technology And Research | A process for plating a metal on a textile fiber |
JP2017031441A (en) * | 2015-07-29 | 2017-02-09 | 日立マクセル株式会社 | Manufacturing method of plated part and plated part |
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