JPS6094678A - Treatment of fiber structure - Google Patents
Treatment of fiber structureInfo
- Publication number
- JPS6094678A JPS6094678A JP58199221A JP19922183A JPS6094678A JP S6094678 A JPS6094678 A JP S6094678A JP 58199221 A JP58199221 A JP 58199221A JP 19922183 A JP19922183 A JP 19922183A JP S6094678 A JPS6094678 A JP S6094678A
- Authority
- JP
- Japan
- Prior art keywords
- monomer
- solution
- unsaturated double
- treating
- double bond
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
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- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は、ポリエステル又はポリアミド繊維構造体に、
耐久性のある帯電防止能、吸湿性、吸水性を付与すると
共に、染色布の深色性を向上させる方法に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION The present invention provides a polyester or polyamide fiber structure with
The present invention relates to a method for imparting durable antistatic ability, hygroscopicity, and water absorbency, as well as improving the bathochromic properties of dyed fabrics.
具体的には、本発明は、ポリエステル又はポリアミド繊
維構造体に、下記一般式に表わされる親水/親油構造物
(Aは一〇−1−NH−l−CH,−1−s O,−1
−s O,−1(m及びnは、0〜50の整数、m)n
%m −1−n = 4〜50)である〕と、分子の両
端に重合可能な一官能性不飽和二重結合M換基を有12
、−目つ両者の間に、アマイド結合穿結合(−Nn8−
Nn−)<こわらは複数個を有してもよい)を有する単
量体を含有する水溶液、有機溶剤溶液又はエマルジョン
液(該水溶液、有機溶剤溶液又はエマルジョン液け、更
に陶機性と有榛杓の比が0.55〜40であるー官能性
、もしくは多官能性不飽和二重結合を有する単量体を少
なくとも一種含有していてもよい)を施与し、次で熱処
理するととにより、耐久性のある帯電防止能、吸湿性、
吸水性を付与すると共に染色布の深色性を向上させるポ
リエステル又dポリアミドIIk維搗造体の処理方法に
関するものである。Specifically, the present invention provides a polyester or polyamide fiber structure with a hydrophilic/oleophilic structure represented by the following general formula (A is 10-1-NH-1-CH, -1-s O, - 1
-s O, -1 (m and n are integers from 0 to 50, m) n
%m −1−n = 4 to 50)] and has a polymerizable monofunctional unsaturated double bond M substituent at both ends of the molecule 12
, - between the two, there is an amide bond penetrating bond (-Nn8-
An aqueous solution, an organic solvent solution or an emulsion containing a monomer having Nn- When applying a monomer having a diluent ratio of 0.55 to 40 (which may contain at least one monomer having a functional or polyfunctional unsaturated double bond) and then heat-treating, Due to its durable antistatic ability, moisture absorption,
The present invention relates to a method for treating a polyester or d-polyamide IIk fiber structure that imparts water absorbency and improves the bathochromic properties of dyed fabrics.
従来より、ポリエステル又はポリアミド繊維構造体の共
通の欠点として、帯電しやすく、Mffl性や吸水性が
小さいことが知られておシ、これらの欠点を補うため、
いわゆる帯電防止剤や吸瀞剤を染色もしくは仕上加工段
階において、繊維表面に付着処理させる方法、すなわち
抜加工による帯電防止、晒湿、吸水加工法が施こされて
きたが、その効果は、耐久性に欠けるものであった。Conventionally, it has been known that common drawbacks of polyester or polyamide fiber structures are that they are easily charged and have low Mffl properties and water absorption.In order to compensate for these drawbacks,
Methods have been used in which so-called antistatic agents and absorbent agents are attached to the fiber surface during the dyeing or finishing stages, i.e., antistatic through punching, moisture bleaching, and water absorption processing methods, but their effects are limited by durability. It lacked sex.
ところが最近、これら繊維に対し、紡糸段階にて耐久性
帯電防止、吸湿、吸水性を付与する改質繊維が考えられ
たが、製糸性低下、糸特性の低下等の欠点があシ、いま
だ完全なものには至っていない。Recently, however, modified fibers have been considered that impart durable antistatic properties, moisture absorption, and water absorption properties to these fibers during the spinning stage, but they have drawbacks such as reduced spinnability and reduced yarn properties, and are still completely unrefined. It hasn't reached anything yet.
また、一方これら繊維に対し、各種のラジカル重合可能
表官能基を分子内に持つ油水性単量体を施与して重合せ
しめる、いわゆるグラフト重合による耐久性帯電防止、
吸湿、吸水性を付与する方法が脚光をあびるようになっ
てきた。On the other hand, durable antistatic properties are achieved through so-called graft polymerization, in which oil-water monomers having various radically polymerizable surface functional groups in their molecules are applied to these fibers and polymerized.
Methods of imparting moisture absorption and water absorption properties have been attracting attention.
しかしながら、これらに使用する単量体によっては、性
能の良し悪しの他、風合の変化、着色及び染色性の低下
、又は耐感性及び堅牢度の低下、更には単1体溶液をつ
くる5−
場合の溶jiff作業及びI#紐衷面への均一付与が困
鄭である等、品質上及び作業性−Fe々の問題点を有す
る。However, depending on the monomer used for these, in addition to good or bad performance, there may be a change in texture, a decrease in coloring and dyeability, a decrease in sensitivity and fastness, and even the difficulty of creating a monomer solution. There are problems in terms of quality and workability, such as difficulty in melting jiff work and applying Fe uniformly to the I# string surface.
次に、ポリエステル及びポリアミド繊維におけるもう一
つの欠点として繊維の屈折率が大きいため、光が散乱さ
れやすいことがあけられる。Another disadvantage of polyester and polyamide fibers is that light is easily scattered due to the high refractive index of the fibers.
つまり、これらの級雑に鮮明性の乏しい分散染料を使用
した場合、特にポリエステル繊維においては、分散染料
のみしか使用できないため重要視されるが、染色物の色
が淡く見える、すなわち深色化に欠けるという現象がお
こる。In other words, when these coarse and poorly defined disperse dyes are used, which is important because only disperse dyes can be used, especially for polyester fibers, the color of the dyed product appears pale, that is, it tends to become deep-colored. A phenomenon of missing occurs.
これらを改善すべく、如上[率の低い化合物、す力わち
フッ素化合物、シリコン化合物、ウレタン化合物等を用
い繊維表面に付与する方法が提案され試みられている。In order to improve these problems, methods have been proposed and attempted in which compounds with low oxidation rates, such as fluorine compounds, silicon compounds, urethane compounds, etc., are applied to the fiber surface.
しかし、この方法では、十分力効朱なあける迄には至っ
ていないのが現状である。However, the current situation is that this method has not reached the point where it is sufficiently effective.
本発明者は、これらの問題点を解決すべく、系統的に追
6−
求し、すでにいくつかの方法を提案したが、更に欽意研
究を重ねた結果、効果の顕著々本発明に到達した。In order to solve these problems, the present inventor has systematically pursued 6- methods and has already proposed several methods, but as a result of further research, he has arrived at the present invention, which is highly effective. did.
すなわち、本発明は、特定の分子構造を有する単量体を
必須成分とし、所望によシ仙の単l゛体をも含有する水
溶液、有機溶剤溶液又はエマルジョン液を、ポリエステ
ル又はポリアミド粉細構造体に付与し、更に熱処理を施
こすことで、風合の変化、着色及び染色性の低下、又は
1皺性及び堅牢度の低下等を起こすことなく、納入性の
ある帯電防止性、吸湿性、吸水性を付与17、更に深色
化を向−ヒさせた。That is, the present invention converts an aqueous solution, an organic solvent solution, or an emulsion solution, which contains a monomer having a specific molecular structure as an essential component and optionally also contains a monomer, into a polyester or polyamide powder structure. By applying it to the body and further heat-treating it, it has antistatic and moisture absorption properties that are easily delivered without causing changes in texture, decreases in coloring and dyeability, or decreases in wrinkle resistance and fastness. , imparted water absorbency17, and further improved deep coloring.
本発明では、一般式 +Y汁咲Rh(Y+ [但し、R
は親油禍造部を表わし、−〇nHn−1−CnH2n−
1おしをつなぐ部なる結合手である)を滴味し、tは1
又は〜50の勢数、m)n、m+n=4〜50)である
〕で表又は尿素結合(−NIIC−NH−)を介して重
合可能カー官能性不飽和二重結合奮換基を有する単量体
(A)を含有する水溶液、有機溶剤溶液又はエマルジョ
ン液をポリエステル又はポリアミド繊維構造体に施与す
ることを本質とする 広帥囲でしかも容易、且つ経済的
に処理しうる方法を見出し、本発明に至った。In the present invention, the general formula +Y Shirusaki Rh (Y+ [However, R
represents a lipophilic region, -〇nHn-1-CnH2n-
1) is the bond that connects the buttocks), and t is 1
or ~50, m) n, m+n = 4 to 50)] and has a car-functional unsaturated double bond stimulating group that is polymerizable via a urea bond (-NIIC-NH-) Discovered a method that can be easily and economically processed over a wide range of areas, which essentially involves applying an aqueous solution, organic solvent solution, or emulsion containing monomer (A) to a polyester or polyamide fiber structure. , led to the present invention.
次に、本発明についてさらに詳細に欽明する。Next, the present invention will be explained in more detail.
上記単量体(A)ね適宜の方法で製造される。The above monomer (A) is produced by an appropriate method.
たとえば、上記した親木/親油部を有し、両末端がイソ
シアネート基である化合物と、イソシアネート基と反応
して尿素結合、ウレタン結合、アマイド結合をっくりう
るアクリル銹導体とを反応させることができる。また逆
の反応を利用することもできる。For example, a compound having the parent wood/oleophilic moiety described above and having isocyanate groups at both ends is reacted with an acrylic rust conductor that reacts with the isocyanate group to form urea bonds, urethane bonds, and amide bonds. I can do it. It is also possible to use the opposite reaction.
親水/親油構造部と両端に位置する一官能性不飽和二重
結合を有する構造部とを結ぶ例としては次のよう寿もの
がある。Examples of connecting a hydrophilic/oleophilic structure and a structure having monofunctional unsaturated double bonds located at both ends include the following.
(1)尿素結合
末端にイソシアネート基を有する化合物と、末端にアマ
イド基を有する化合物間の反応
〜NCO+〜C0NH,→〜NHCNH〜(2) ウレ
タン結合
末端にイソシアネート基を有する化合物と、末端にヒド
ロキシ基を有する化合物間の反応
〜NCO+〜OH→〜NHCO〜
9−
(3)アマイド結合
末端にイソシアネート基を有する化合物と、末端にカル
ボン酸基を有する化合物間の反応
〜NCO+〜C0OH→ 〜NHC〜
また、ラジカル重合可t−a不飽和二重結合を有する化
合物内に、イソシアネート遅やアミド結合、尿素結合、
ウレタン結合を包含するもの、例えに、
^
結合が構成可能になり、これらも本発明に包含される。(1) Reaction between a compound having an isocyanate group at the end of the urethane bond and a compound having an amide group at the end ~NCO+~C0NH,→~NHCNH~ (2) A reaction between a compound having an isocyanate group at the end of the urethane bond and a compound having an amide group at the end Reaction between compounds having a group ~NCO+ ~OH→ ~NHCO~ 9- (3) Reaction between a compound having an isocyanate group at the amide bond end and a compound having a carboxylic acid group at the end ~NCO+ ~C0OH→ ~NHC~ In addition, in the compound having a radically polymerizable t-a unsaturated double bond, an isocyanate bond, an amide bond, a urea bond,
Those that include urethane bonds, such as ^ bonds, can be constructed and are encompassed by the present invention.
末端にイソシアネート基を有する化合物は、たとえに、
先の一般式−+Y HR辷+y+において、Y構造部を
しめる両末端に、水酸基を有するポリアルキレングリコ
ールの水酸基を酸化した後、アルキルアミンと反応させ
て酸10−
アミドな作り、次に次亜ハロゲン酸アルカリを使用し、
ホフマン転位により作ることができるが、本発明は、勿
論これらの方法に限定されるものではない。Compounds having an isocyanate group at the end are, for example,
In the above general formula -+YHR+y+, after oxidizing the hydroxyl groups of polyalkylene glycol having hydroxyl groups at both ends concluding the Y structure, it is reacted with an alkylamine to form an acid 10-amide, and then hypochlorite is added. Using alkali halogen acid,
Although it can be produced by Hofmann rearrangement, the present invention is of course not limited to these methods.
次に、一般式で表わされる親水/親沖構造部(Y )−
(R)−(Y )−中のR構造部分は、クラフト重合時
、ポリエステル又はポリアミド経維構造体の初期吸着段
階で重要ガ役割を果すものであシ、例えば、−CnHn
−1末端にアマイド基を有する化合物としては、アクリ
ルアマイド、メタクリルアマイド、N、N’−メチレン
ビスアクリルアマイド、NN’−メチレンメタアクリル
アマイド、NN’Nノーレンビスエチルアマイド等があ
げられる。Next, the hydrophilic/offshore structure (Y) expressed by the general formula
The R structural moiety in (R)-(Y)- plays an important role in the initial adsorption stage of the polyester or polyamide fiber structure during kraft polymerization, for example, -CnHn
Examples of the compound having an amide group at the -1 terminal include acrylamide, methacrylamide, N,N'-methylenebisacrylamide, NN'-methylenemethacrylamide, NN'Nnorenbisethylamide, and the like.
末端にヒドロキシ基を有する化合物としては、2−ヒド
ロキシエチルアクリレート、2−ヒドロキシエチルメタ
クリレート、2−ヒドロキシプロピルメタクリレ−)、
N−メチロールアクリルアミド、N−メチロールメタア
クリルアミド、アルキレンオキサイド系化合物のアクリ
レート又はメタクリレート等があけられ、更に、末端に
カルボン酸基を有する化合物としては、アクリル酸、メ
タクリル酸等があけられる。Compounds having a hydroxy group at the terminal include 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate),
N-methylol acrylamide, N-methylol methacrylamide, acrylates or methacrylates of alkylene oxide compounds, and the like, and compounds having a terminal carboxylic acid group include acrylic acid, methacrylic acid, and the like.
本発明で用いる単量体(A)は上記に例示した方法で製
造されうるが、かくして製造された単量体(A)の具体
例としては次のようかものがある:
本発明では上記単量体(A)と共に、所望によシ、無機
性と有機性の比の値が0.55〜4.0である一官能性
もしくね多官能性不飽和二重結合を有する単量体CB)
の一種又は二種以上が併用される。The monomer (A) used in the present invention can be produced by the method exemplified above, and specific examples of the monomer (A) produced in this way include the following: Along with the mer (A), if desired, a monomer having a monofunctional or polyfunctional unsaturated double bond having an inorganic to organic ratio of 0.55 to 4.0. CB)
One or two or more of these are used in combination.
ここで−官能性不飽和二重結合単量有とは、単量体中に
1個のラジカル重合可能力不飽和二重結合基を有するも
のであり、多官能性不飽和二l結合単1とは、単量体中
に2個以上のラジカル重合可111−力不飽和二重結合
基を有するものである。Here, the monomer containing a functional unsaturated double bond refers to a monomer having one radically polymerizable force unsaturated double bond group, and a monomer containing a polyfunctional unsaturated double bond monomer. means a monomer having two or more radically polymerizable 111-unsaturated double bond groups.
本発明における無機性と有機性との比の値け、膝用(化
学の領域11.179.1957)によって提唱された
“有機概念”に基すくものである。The value of the ratio between inorganic and organic properties in the present invention is based on the "organic concept" proposed by Niyo (Chemistry no. 11.179.1957).
すなわち、その数値が“0”に近づくにつれて有機性が
強く、つまシ親油性になることを示す概念であり、無機
性と有機性の比の数値を具体例をもって示せは、アクリ
ル酸(2,53)、メタクリル酸(1,90)等の不飽
和酸、2−ヒドロキシエチルメタクリレ−)(1,35
)、グリシジルメタクリレート(0,59)、エチレン
グリコールジメタアクリレ−)(!L94)等の不飽和
酸エステル類、マレインff(3,8)、イタコン#(
3,0)等の不飽和酸煙水物類、N−メチロールアクリ
ルアミド(五8)、ジメチルエチルメタアクリレ−)(
0,8!l)等の不飽和アミン類がある。In other words, it is a concept that indicates that as the value approaches "0", the organicity becomes stronger and the property becomes more lipophilic. 53), unsaturated acids such as methacrylic acid (1,90), 2-hydroxyethyl methacrylate) (1,35
), unsaturated acid esters such as glycidyl methacrylate (0,59), ethylene glycol dimethacrylate (!L94), malein ff (3,8), itacon # (
Unsaturated acid fumes such as 3,0), N-methylol acrylamide (58), dimethylethyl methacrylate) (
0,8! There are unsaturated amines such as l).
次に本発明による加工方法は上記単1体を含む水溶液、
有様溶剤溶液、或いはエマルジョン液をポリエステル又
はポリアミド繊維構造体に施与し、熱処理を施こすもの
である。Next, the processing method according to the present invention includes an aqueous solution containing the above-mentioned monomer,
A specific solvent solution or emulsion liquid is applied to a polyester or polyamide fiber structure, and heat treatment is performed.
本発明に使用する単量体濃度は、水溶液、有機溶剤溶液
、或いはエマルジョン液として、5f/l〜200 t
/lの範囲が好ましく、耐久性帯電防止、吸水性及び吸
湿性を顕著に得るには、これら重合物の繊維構造物上の
固着または附着量が0.5〜15市“蒙パーセントの範
囲、特に2.0〜80重I”パーセントの節回が好まし
い。The monomer concentration used in the present invention is 5 f/l to 200 t as an aqueous solution, organic solvent solution, or emulsion solution.
/l is preferable, and in order to obtain remarkable durable antistatic properties, water absorption and hygroscopicity, the amount of adhesion or adhesion of these polymers on the fiber structure should be in the range of 0.5 to 15%. Particularly preferred is a knot of 2.0 to 80 weight I'' percent.
単量体溶液を施与する手段は、浸漬法、パッディング法
、L7ごき法、スプレー法等公知の方法を用いることが
でき、また熱処理としては、浸漬加熱法、常圧〜高圧ス
チーム加熱法、高周波加熱法、紫外線光加熱法、乾熱加
熱法、電子線加熱法等又はこれらの糾合せ法を、細紐構
造物の違いに応じて使用することができる。As a means for applying the monomer solution, known methods such as an immersion method, a padding method, an L7 rubbing method, and a spray method can be used.As for the heat treatment, an immersion heating method, normal pressure to high pressure steam heating can be used. method, high frequency heating method, ultraviolet light heating method, dry heat heating method, electron beam heating method, etc., or a combination of these methods can be used depending on the difference in the thin string structure.
処理条件は、温度が30℃〜200℃の範囲、処理時間
が0.05分〜60分の範囲であるが、好ましくは温度
を50℃〜180℃の範囲、処理時間0.5分〜20分
の範囲が最適条件である。The processing conditions include a temperature range of 30°C to 200°C and a processing time range of 0.05 to 60 minutes, but preferably a temperature range of 50°C to 180°C and a processing time of 0.5 to 20 minutes. The range of minutes is the optimum condition.
また、熱処理の効率を高めるためには、触媒の使用が好
ましく、有機及び無機の過酸化物類、過−酸塩類等を用
いることが望ましい。Further, in order to increase the efficiency of heat treatment, it is preferable to use a catalyst, and it is desirable to use organic and inorganic peroxides, peracid salts, and the like.
16− 次に実施例をあげ、本発明を詳しく砦、明する。16- Next, the present invention will be explained in detail with reference to Examples.
伺、実施例に示した耐久性、摩擦帯電圧、吸水性、吸湿
性、耐量性、深色性は各々次の測定法を採用した。The following measurement methods were used for each of the durability, frictional charging voltage, water absorption, hygroscopicity, durability, and bathochromic properties shown in the Examples.
耐久性二合成洗剤”ザブ″(化工石鹸)1 f/lを含
む40℃の温湯を用い、家庭用洗濯機にて浴比1:50
で10分間洗濯を行った稜、5分間すすぎ洗いを行う。Using 40℃ warm water containing 1 f/l of durable dual synthetic detergent "ZABU" (chemical soap), wash the bath at a bath ratio of 1:50 in a household washing machine.
After washing for 10 minutes, rinse for 5 minutes.
摩擦帯電圧:20℃、50チRHの雰囲気下において、
京大化研式ロータリースタチックテスター(興亜商会製
〕を用い、綿布(余有1号)を摩擦布として測定する。Frictional charging voltage: In an atmosphere of 20°C and 50cmRH,
Using a Kyoto University Kaken type rotary static tester (manufactured by Koa Shokai), cotton cloth (Yuyu No. 1) was used as the friction cloth for measurement.
吸水性:20℃、65チRHの雰囲気下において、水平
に張った試料に、これより5α上方に設置したビューレ
ットの先端から一滴の水を落下せしめ、水滴が拡がり消
滅する迄の時間を測定する。Water absorption: In an atmosphere of 20℃ and 65cmRH, a drop of water is dropped from the tip of a buret placed 5α above the sample stretched horizontally, and the time taken for the water droplet to spread and disappear is measured. do.
17−
吸湿性二P乾状態にした試料を、20℃、65q6RH
の雰囲り下に4時間放置し、その雰囲気下で重量測定す
る。この重量増分を、重量パーセントとして算出する。17- Hygroscopic 2P dry sample at 20°C, 65q6RH
The sample was left for 4 hours under an atmosphere of This weight increment is calculated as a weight percentage.
1皺性:20℃、65%RHの雰囲気下で、モンサット
法にて測定する。1 Wrinkle property: Measured by the Monsat method in an atmosphere of 20° C. and 65% RH.
染色性:コルモーゲン社分光光度組を用い、L値を測定
する。Stainability: Measure the L value using a Kollmorgen spectrophotometer.
実施例 1
使用するポリエステル加工糸織物(150j)は通常の
方法で精練、染色を施こし、黒染品を得た。Example 1 The polyester processed yarn fabric (150j) used was scoured and dyed in a conventional manner to obtain a black-dyed product.
鞠られた布帛は、重量測定後、組成溶液(1)を用い、
浴比1:30で密閉容器中に浸漬させ、50℃より1分
間に1℃の割合で160℃迄列温させ、そのまま20分
間処理した。After measuring the weight of the rolled fabric, using the composition solution (1),
It was immersed in a closed container at a bath ratio of 1:30, heated from 50°C to 160°C at a rate of 1°C per minute, and treated for 20 minutes.
次に冷却後、]f7!を出した処理布はソーピング液(
1)を用い80℃で20分間処理した後、重量測定を行
った。Next, after cooling,] f7! The treated cloth that has been removed should be soaked in soaping liquid (
After treatment at 80° C. for 20 minutes using 1), the weight was measured.
本発明の効果を検討するため、洗濯30回の耐久性試験
を実施した。In order to examine the effects of the present invention, a durability test of 30 washes was conducted.
ソーピング液(1) 実施例 2 実施例(1)と同様の黒染品を使用した。Soaping liquid (1) Example 2 The same black-dyed product as in Example (1) was used.
布帛は、重量測定後、組成溶液(2)を用い、実施例(
1)と同条件で浸漬し、50℃より1分間に1℃の割合
いで100℃迄昇潟させ、そのまま60分間処理した0
。After measuring the weight of the fabric, using the composition solution (2), the fabric was prepared in Example (
It was immersed under the same conditions as in 1), raised from 50°C to 100°C at a rate of 1°C per minute, and then treated for 60 minutes.
.
次に冷却後、4vり出した処理布け、実施例(1)と同
条件でソーピング処理を施こし、重l°測定を行った。Next, after cooling, the treated cloth taken out by 4V was subjected to a soaping treatment under the same conditions as in Example (1), and the weight was measured in l°.
本発明の効果を検討するため、実施例(1)と同様に耐
久性試験を行った。In order to examine the effects of the present invention, a durability test was conducted in the same manner as in Example (1).
組成溶液(2) 20一 実施例 3 実施例(1)と同様の黒染品を使用した。Composition solution (2) 201 Example 3 The same black-dyed product as in Example (1) was used.
布帛は、重量測定後、組成溶液(3)に浸漬し、ピック
アップ80%の条件で、マングルにて均一に絞った。After measuring the weight, the fabric was immersed in the composition solution (3) and squeezed uniformly with a mangle under the condition of 80% pick-up.
次に処理布は100℃の飽和蒸気中で20分間熱処理を
行った後、実施例(1)と同条件でソーピンク処理を施
こし、重量測定を行った。Next, the treated fabric was heat treated in saturated steam at 100° C. for 20 minutes, and then subjected to saw pink treatment under the same conditions as in Example (1), and its weight was measured.
本発明の効果を検討するため、実施例(1)と同様に耐
久性試験を行った。In order to examine the effects of the present invention, a durability test was conducted in the same manner as in Example (1).
21− 実施例 4 実施例(1)と同様の黒染品を使用した。21- Example 4 The same black-dyed product as in Example (1) was used.
布帛ね重量測定祐、組成溶液(4)に浸漬し、実施fK
3)と同条件で、マングルにて絞った稜、ガラス棒に巻
き取った。Measure the weight of the fabric by soaking it in the composition solution (4) and carrying out
Under the same conditions as in 3), the edges were squeezed with a mangle and wound around a glass rod.
次に、処理布は出カフkwの高周波発生器に入れ、回転
させながら10分間加熱処理を行い、実施例(1)と同
条件でソーピンク処理を施こし、重量測定を行った。Next, the treated fabric was placed in a high-frequency generator with a cuff output of kW, heated for 10 minutes while rotating, and subjected to saw pink treatment under the same conditions as in Example (1), and its weight was measured.
本発明の効果を棟割するため、実施例(1)と同様に耐
久性試験を行った。In order to determine the effects of the present invention, a durability test was conducted in the same manner as in Example (1).
組成溶液(4)
比較例 1
本発明の効果を比較するため、実施例(1)と同様の黒
染品を使用し、処理することなく、そのまま実施例1と
同様に耐久性試しを行った。Composition Solution (4) Comparative Example 1 In order to compare the effects of the present invention, the same black-dyed product as in Example (1) was used and a durability test was conducted in the same manner as in Example 1 without any treatment. .
22−
以上、和らiまた織物の件部測定値を、表1にまとめた
。22- The measured values of the fabrics are summarized in Table 1.
その結果はいずれも高性能の布帛が得られ、その効果が
認められた。As a result, high-performance fabrics were obtained in all cases, and their effects were recognized.
24−
23−
実施例 5
ポリアミド締紐からなる30dトリコット編物を用い、
通常の方法にて精練を行った。24-23- Example 5 Using a 30d tricot knitted fabric made of polyamide cord,
Scouring was carried out in the usual manner.
布帛は、重量測定後、組成溶液(5)を用い、浴比1:
42の条件で密閉式染色機中に浸漬し、50℃より1分
間に1℃の割合いで100℃迄昇温させ、そのまま30
分間処理した抜、水洗を行った。After measuring the weight of the fabric, use composition solution (5) at a bath ratio of 1:
Immerse it in a closed dyeing machine under the conditions of 42, raise the temperature from 50℃ to 100℃ at a rate of 1℃ per minute, and leave it for 30 minutes.
It was treated for a minute, then drained and washed with water.
本発明の効果を検討するため、実施例(1)と同榮件で
耐久性試験を行った。In order to examine the effects of the present invention, a durability test was conducted under the same conditions as in Example (1).
組成溶液(5)
25−
環上間られた繊物の性能測定値を表2にまとめた。その
1沫は比較例に比べいずれも向上していることが虻めら
れた0
表 2
特許出願人 セーレン株式会社
代理人 弁理士 用彬良治
〃 〃 斉麗武彦
27−Composition Solution (5) 25- Table 2 summarizes the measured performance values of the woven fibers. It was noted that each drop was improved compared to the comparative example0.
Claims (1)
般式に表わされる親水/親油構造部4Y M R)T4
Y )−〔但し、Rは、親油構造部を表わし、−Cn
Hn−1−CHHgn−1おしをつなぐ単なる結合手で
ある)を意味し、tは1又は50の整数、rn>n、m
+n=4〜50)である〕と、分子の両端に重合可能な
一官能性不飽和二重結合置換基を有有する単量体を含有
する水溶液、有機溶剤液又はエマルジョン液を施与し、
次で熱処理することを特徴とする耐久性のある帯電防止
能、吸湿性、吸水性及び深色性を付与する繊維構造体の
処理方法。 Z 該水溶液、有機溶剤液又はエマルジョン液が、更に
無機性と有機性の比の値が0.55〜4.0である一官
能性もしくは多官能性不飽和二重結合を有する単量体を
少なくとも一稙含有することを特徴とする特許請求の範
囲第1項に記載の繊維構造体の処理方法。[Claims] 1. Hydrophilic/oleophilic structure portion 4Y M R) T4 represented by the following general formula in the polyester or polyamide fiber structure
Y)-[However, R represents a lipophilic structure, -Cn
t is an integer of 1 or 50, rn>n, m
+ n = 4 to 50)] and an aqueous solution, organic solvent solution or emulsion solution containing a monomer having a polymerizable monofunctional unsaturated double bond substituent at both ends of the molecule,
A method for treating a fibrous structure that imparts durable antistatic ability, hygroscopicity, water absorption and bathochromic properties, the method comprising heat-treating it by: Z The aqueous solution, organic solvent solution or emulsion solution further contains a monomer having a monofunctional or polyfunctional unsaturated double bond with an inorganic to organic ratio of 0.55 to 4.0. The method for treating a fibrous structure according to claim 1, characterized in that the fibrous structure contains at least one grain.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58199221A JPS6094678A (en) | 1983-10-26 | 1983-10-26 | Treatment of fiber structure |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58199221A JPS6094678A (en) | 1983-10-26 | 1983-10-26 | Treatment of fiber structure |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6094678A true JPS6094678A (en) | 1985-05-27 |
JPH045789B2 JPH045789B2 (en) | 1992-02-03 |
Family
ID=16404153
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58199221A Granted JPS6094678A (en) | 1983-10-26 | 1983-10-26 | Treatment of fiber structure |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6094678A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3360930A1 (en) | 2014-07-04 | 2018-08-15 | FUJIFILM Corporation | Novel compound, coloring composition for dyeing or textile, ink jet ink, method of printing on fabric, and dyed or printed fabric |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS584871A (en) * | 1981-06-26 | 1983-01-12 | 東レ株式会社 | Treatment of synthetic fiber |
JPS58220876A (en) * | 1982-06-10 | 1983-12-22 | 東レ株式会社 | Hydrophilicity imparting treatment of polyester fiber |
-
1983
- 1983-10-26 JP JP58199221A patent/JPS6094678A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS584871A (en) * | 1981-06-26 | 1983-01-12 | 東レ株式会社 | Treatment of synthetic fiber |
JPS58220876A (en) * | 1982-06-10 | 1983-12-22 | 東レ株式会社 | Hydrophilicity imparting treatment of polyester fiber |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3360930A1 (en) | 2014-07-04 | 2018-08-15 | FUJIFILM Corporation | Novel compound, coloring composition for dyeing or textile, ink jet ink, method of printing on fabric, and dyed or printed fabric |
Also Published As
Publication number | Publication date |
---|---|
JPH045789B2 (en) | 1992-02-03 |
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