JPS6083559A - Defoaming agent for bean curd - Google Patents
Defoaming agent for bean curdInfo
- Publication number
- JPS6083559A JPS6083559A JP58189539A JP18953983A JPS6083559A JP S6083559 A JPS6083559 A JP S6083559A JP 58189539 A JP58189539 A JP 58189539A JP 18953983 A JP18953983 A JP 18953983A JP S6083559 A JPS6083559 A JP S6083559A
- Authority
- JP
- Japan
- Prior art keywords
- bean curd
- tofu
- defoaming agent
- polyricinoleic acid
- animal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Beans For Foods Or Fodder (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は豆腐用消泡剤に関する。詳しくは大豆、脱脂大
豆その他の植物タンパク水溶液を加熱した時に生ずる泡
および豆乳落下時に生ずる泡を抑泡、消失させる豆腐用
消泡剤であって、（Ａ＞ポリリシノール酸グリセリンエ
ステル、ポリリシノール酸ポリグリセリンエステル、ポ
リリシノール酸ソルビタンエステル、ポリリシノール酸
プロピレングリコールエステル、ポリリシノール酸ショ
糖エステルの１一種よ、たは２種以上（以下ポリリシノ
ール酸エステル類と総称する。）と（Ｂ）大豆リン脂−
と（Ｃ）炭酸カルシウム、リン酸ノＪルシウム、ケイ酸
カルシウム、炭酸マグネシウム、リン酸マグネシウムお
よびケイ酸マグネシウム（以下無機塩類と総称する。）
の１種または２種以上および（Ｄ）動植物油脂とを必須
成分として配合してなる豆１腐用消泡剤に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an antifoaming agent for tofu. More specifically, it is an antifoaming agent for tofu that inhibits and eliminates foam that is generated when an aqueous solution of soybeans, defatted soybeans, and other vegetable proteins is heated, and that is generated when soymilk falls. One or more of polyglycerin ester, polyricinoleic acid sorbitan ester, polyricinoleic acid propylene glycol ester, polyricinoleic acid sucrose ester (hereinafter collectively referred to as polyricinoleic acid esters) and (B) soybean Phosphorus fat
and (C) calcium carbonate, lucium phosphate, calcium silicate, magnesium carbonate, magnesium phosphate, and magnesium silicate (hereinafter collectively referred to as inorganic salts).
The present invention relates to an antifoaming agent for tofu that contains one or more of the following and (D) animal and vegetable oils and fats as essential components.
今日、豆腐業界では油揚げの廃油などに石灰などを混合
した廃油系消泡剤、グリセリン脂肪酸エステルを主成分
としたグリセリン脂肪酸エステル系消泡剤、シリコン樹
脂を主成分としたシリ」ン系消泡剤が使用されている。Today, in the tofu industry, there are waste oil-based defoaming agents that are made by mixing waste oil from deep-frying with lime, etc., glycerin fatty acid ester-based defoaming agents that are mainly composed of glycerin fatty acid esters, and silicone-based defoaming agents that are mainly composed of silicone resin. agent is used.
このうち廃油系消泡剤は酸価、過酸化物価が高く食品で
ある豆腐の製造工程に使用することは食品衛生上好まし
くない。グリセリン脂肪酸エステル系消泡剤については
、グリセリン脂肪酸エステルのみでは消泡力が十分でな
く、消泡力を高めるためにシリコン樹脂などを配合した
製剤の形をとっている。Among these, waste oil-based antifoaming agents have high acid values and peroxide values, and are therefore undesirable from the viewpoint of food hygiene when used in the manufacturing process of tofu, which is a food product. Regarding glycerin fatty acid ester antifoaming agents, glycerin fatty acid esters alone do not have sufficient antifoaming power, so formulations containing silicone resin and the like are used to increase the antifoaming power.
しかし、シリコン樹脂添加により価格が高くなるなどの
問題点を含んでいる。However, there are problems such as an increase in price due to the addition of silicone resin.
本発明者は前記の問題点を解決すべく鋭意検討した結果
、ポリリシノール酸エステル類が良好な消泡性を示すこ
とを見出した。As a result of intensive studies to solve the above-mentioned problems, the inventors of the present invention found that polyricinoleic acid esters exhibit good antifoaming properties.
また、さらにポリリシノール酸エステル類に大豆リン脂
質、無機塩類、動植物油を配合覆ることにより、より優
れた消泡性を示す豆腐用消泡剤を見出し本発明を完成し
た。In addition, by further blending polyricinoleic acid esters with soybean phospholipids, inorganic salts, and animal and vegetable oils, they discovered an antifoaming agent for tofu that exhibits even better antifoaming properties, and completed the present invention.
本発明でいうポリリシノール酸エステル類とはリシノー
ル酸が２〜１０モル重合した（好ましくは３〜５モル重
合した）ポリリシノール酸とグリセリン、ポリグリセリ
ン（重合度２〜５モル）、ソルビトール、プロピレング
リコールあるいはショ糖とのエステルをいう。The polyricinoleic acid esters referred to in the present invention are polyricinoleic acid in which 2 to 10 moles of ricinoleic acid are polymerized (preferably 3 to 5 moles), glycerin, polyglycerin (degree of polymerization 2 to 5 moles), sorbitol, propylene. An ester with glycol or sucrose.
ポリリシノール酸の代りに重合ヒマシ油脂肪酸、重合硬
化ヒマシ油脂肪酸を用いて同様にエステル化してポリリ
シノール酸エステル類を得ることができる。Polyricinoleic acid esters can be obtained by esterification in the same manner using polymerized castor oil fatty acid or polymerized hardened castor oil fatty acid instead of polyricinoleic acid.
また無機塩類とは炭酸カルシウム、第一リン酸カルシウ
ム、第ニリン酸カルシウム、第三リン酸カルシウム、ケ
イ酸カルシウム、炭酸マグネシウム、第一リン酸マグネ
シウム、第ニリン酸マグネシウム、第三リン酸マグネシ
ウム、ケイ酸マグネシウムから選ばれる１種または２種
以上を使用できるが、特に炭酸カルシウム、第三リン酸
カルシウム、炭酸マグネシウムが好ましい。Inorganic salts are selected from calcium carbonate, monocalcium phosphate, dibasic calcium phosphate, tribasic calcium phosphate, calcium silicate, magnesium carbonate, monobasic magnesium phosphate, dibasic magnesium phosphate, tribasic magnesium phosphate, and magnesium silicate. Although one type or two or more types can be used, calcium carbonate, tribasic calcium phosphate, and magnesium carbonate are particularly preferred.
動植物油脂とは天然の油脂、例えばＡ７シ油、パーム核
油、パーム油、大豆油、綿実油、ナタネ油、牛脂、ラー
ド、魚油など、またはこれらの硬化油の１種または２種
以上の混合物でも良い。Animal and vegetable oils include natural fats and oils, such as A7 coconut oil, palm kernel oil, palm oil, soybean oil, cottonseed oil, rapeseed oil, beef tallow, lard, and fish oil, or a mixture of one or more of these hydrogenated oils. good.
本発明の豆腐用消泡剤は（Ａ）ポリリシノール酸エステ
ル類、（Ｂ）大豆リン脂質、（Ｃ）無機塩類、（Ｄ）動
植物油脂を加熱均一混合する。ｌｒＪられる豆腐用消泡
剤は動植物油脂の構成脂肪酸及び（Ａ＞、（Ｂ）、（Ｃ
）、（Ｄ）の組成比率により粉末状、ビーズ状、フレー
ク状、顆粒状、ペースト状、液状などの形態となる。The antifoaming agent for tofu of the present invention is prepared by uniformly mixing (A) polyricinoleic acid esters, (B) soybean phospholipids, (C) inorganic salts, and (D) animal and vegetable oils and fats by heating. The antifoaming agent for tofu produced by lrJ contains the constituent fatty acids of animal and vegetable oils and (A>, (B), (C
) and (D), the composition may be in the form of powder, beads, flakes, granules, paste, liquid, etc.
本発明の成分の配合比はポリリシノール酸エステル類、
２〜５０重量％、好ましくは５〜３０重量％、大豆リン
脂質、２〜５０重量％、好ましくは５〜３０重量％、無
機塩類、２〜５０重量％、好ましくは５〜３０重量％、
動植物油脂、５〜６０重（６）％、好ましくは１０〜４
０重量％の範囲である。The blending ratio of the components of the present invention is polyricinoleic acid ester,
2-50% by weight, preferably 5-30% by weight, soybean phospholipids, 2-50% by weight, preferably 5-30% by weight, inorganic salts, 2-50% by weight, preferably 5-30% by weight,
Animal and vegetable oils and fats, 5-60% by weight (6), preferably 10-4
It is in the range of 0% by weight.
本発明ではポリリシノール酸エステル類、大豆リン脂質
、無ｔａ塩類、動植物油脂の必須成分のほかにグリセリ
ン脂肪酸エステルなどの多価アルコール脂肪酸エステル
、シリコーン樹脂などを支障のない範囲で配合してもか
まわない。In the present invention, in addition to the essential components of polyricinoleic acid esters, soybean phospholipids, non-tatal salts, and animal and vegetable oils and fats, polyhydric alcohol fatty acid esters such as glycerin fatty acid esters, silicone resins, etc. may be blended within a range that does not cause any problem. do not have.
本発明でいう豆腐用消泡剤は木綿豆腐、絹ごし豆腐、ソ
フト豆腐、充填豆腐などの豆腐類、油揚げ、凍豆腐、豆
乳飲料などの豆腐類の製造の際に使用できる。The antifoaming agent for tofu according to the present invention can be used in the production of tofu such as firm tofu, silken tofu, soft tofu, and stuffed tofu, as well as tofu such as fried tofu, frozen tofu, and soy milk drinks.
本発明の豆腐用消泡剤の使用量は原料生大豆に対しｏ、
ｉ〜１．５重量％、好ましくは０．３〜１．０重量％の
割合で添加すれば豆腐類製造工程中の発泡を抑えること
ができる。The amount of the antifoaming agent for tofu of the present invention used is o,
Foaming during the tofu manufacturing process can be suppressed by adding i to 1.5% by weight, preferably 0.3 to 1.0% by weight.
以下実施例によって本発明を説明りる。The present invention will be explained below with reference to Examples.
実施例１
表−１に記載した各消泡剤の配合成分は８０℃〜９０℃
に加温溶融し、均一混合されたのち、２０℃以下の雰囲
気の中に噴霧して粉末（ビーズ）と゛づる。Example 1 The ingredients of each antifoaming agent listed in Table-1 were 80°C to 90°C.
After heating and melting and mixing uniformly, the mixture is sprayed into an atmosphere of 20°C or less to form powder (beads).
消泡試験１ 蒸煮時の消泡試験法
各試験当り、生大豆５ Ａｇを流水中に９時間浸漬して
得た浸漬大豆に水を加えなから磨砕（）、４０ ＫＨの
「ご」を得る。Anti-foaming test 1 Anti-foaming test method during steaming For each test, 5 Ag raw soybeans were soaked in running water for 9 hours. obtain.
これに対し表−１に示した消泡剤各々２５ｇ（生大豆に
対し０．５％）加え、開放釜中で加熱し、９０℃に達し
てから４分間加熱し、その間の釜中の泡の高さの最高値
を測定する。To this, 25g of each antifoaming agent (0.5% based on raw soybeans) shown in Table 1 was added, heated in an open pot, and heated for 4 minutes after reaching 90°C, during which time bubbles in the pot were added. Measure the highest value of the height.
消泡試験２ 豆乳落下時の消泡試験法
消泡試験１終了後の「ご」を絞り機で絞り、１！１られ
た豆乳Ｉ Ｊ（ｇを１ｍの高さＪ：リロー１〜を通して
２０００ＴＩ１． Ｊ２容メスシリンダー中に落下させ
、落下直後及び１分後の泡のｆｆｉ（ｍ、ｅ）を測定し
た。Defoaming test 2 Defoaming test method when falling soymilk After defoaming test 1, the "go" is squeezed with a squeezer, and the soymilk I The foam was dropped into a J2 volume measuring cylinder, and the ffi (m, e) of the foam was measured immediately after dropping and 1 minute later.
表−１に示した本発明消泡剤および比較例消泡剤の試験
結果は表−２に示した。The test results of the antifoaming agent of the present invention and the comparative antifoaming agent shown in Table 1 are shown in Table 2.
表−２の結果から明らかなように本発明消泡剤の消泡力
がすぐれていることがわかる。As is clear from the results in Table 2, it can be seen that the antifoaming agent of the present invention has excellent antifoaming power.
表 −２消泡試験結果
試験 消泡剤 消泡試験１ 消泡試験２ （ｍ、ｅ）Ｎ
ｏ、 ＜ｃｍ＞ 落下直後 １分後
１ 本発明１ ５ ５０ １０
２ 、．２ ５ ５０ ’１０
３ ｕ３４ ３０ ０
４ ＃４４ ３０ ’０
５〃５５ ５０ １０
６ 〃 ６ ４ ３０ ０
７ 比較例ｉ ２０ ２００ １５０
８ ＃２２０ ２００ １５０
９ ｎ３ １５ １５０ １００
１０ １１４ １５ １５０ １００
ｉｉ 、、５ ｉｏ １ｏｏ２０
１２ ＃６１０ １００ ２０
実施例２
実施例１と同様の方法で本発明品３と市販廃油系豆腐用
消泡剤との試験を行なった。Table-2 Defoaming test results Test Defoaming agent Defoaming test 1 Defoaming test 2 (m, e)N
o, <cm> Immediately after falling 1 minute later 1 Invention 1 5 50 10 2 ,. 2 5 50 '10 3 u34 30 0 4 #44 30 '0 5〃55 50 10 6 〃 6 4 30 0 7 Comparative example i 20 200 150 8 #220 200 150 9 n3 15 150 100 10 114 15 150 100 ii, , 5 io 1oo20 12 #610 100 20 Example 2 In the same manner as in Example 1, a test was conducted using the product 3 of the present invention and a commercially available waste oil-based defoaming agent for tofu.
これらの消泡剤の配合組成は表−３に示した。The composition of these antifoaming agents is shown in Table-3.
消泡試験および豆腐製造試験は実際の豆腐製造ラインを
用いた。An actual tofu production line was used for the defoaming test and tofu production test.
消泡剤の添加ｍは生大豆に対し０．６％豆乳濃度１０．
５％の絹ごし豆腐を製造した。Addition of antifoaming agent m is 0.6% soy milk concentration 10.
5% silken tofu was produced.
表 −３消泡剤の配合組成 ％
配 合 成 分 本発明３ 市販消泡剤テトラリシノー
ル酸トリグリセリンエステル ２０大豆リン脂質 ５
硬化パーム油 ４５
炭酸カルシウム １５６０
炭酸マグネシウム １５
植物油脂 ４０
試験結果は表−４に示した。Table 3 Compounding composition of antifoaming agent % Compounding ingredient Present invention 3 Commercially available antifoaming agent Tetralicinoleic acid triglycerin ester 20 Soybean phospholipid 5 Hardened palm oil 45 Calcium carbonate 1560 Magnesium carbonate 15 Vegetable oil 40 Test results are shown in Table - 4.
本発明消泡剤は蒸煮時および豆乳落下時の消泡力がすぐ
れ、品質良好な絹ごし豆腐が得られた。The antifoaming agent of the present invention had excellent antifoaming ability during steaming and when soybean milk was dropped, and silken tofu of good quality was obtained.
表 −４消泡効果および豆腐の品質
試験 消 泡 剤 蒸煮時の消泡性 豆乳落下時の 豆
腐の品質Ｎｏ、 消泡性
豆乳落下終了
１３ 本発明３ 沸騰後１分で 時、液面に 表面なめ
らか消泡 泡がない
豆乳落下終了
１４ 市販消泡剤 沸騰後２分で 時、液−面に 表面
に泡あり消泡 泡が残るTable 4 Defoaming effect and quality test of tofu Defoaming agent Defoaming property during steaming Quality No. of tofu when soymilk drops, defoaming property Soymilk finish falling 13 Invention 3 1 minute after boiling, the liquid level reaches the surface Smooth defoaming Soy milk falls without bubbles 14 Commercially available defoamer 2 minutes after boiling, on the liquid surface Foam on the surface Defoaming Foam remains
Claims (1)
ノール酸ポ□リグリセリンエステル、ポリリシノール酸
ソルビタンエステル、ポリリシノール酸プロピレングリ
コールエステル、ポリリシノール酸ショ糖エステルの１
種または２８以上および＜８）大豆リン脂質、（Ｃ）炭
酸カルシウム、リン酸カルシウム、ケイ酸カルシウム、
炭酸マグネシウム、リン酸マグネシウムおよびケイ酸マ
グネシウムの１種または２種以上および（Ｄ）動植物油
脂とを必須成分として配合してなる豆腐用消泡。 剤。[Scope of Claims] (A> 1 of polyricinoleic acid glycerol ester, polyricinoleic acid polyglycerol ester, polyricinoleic acid sorbitan ester, polyricinoleic acid propylene glycol ester, polyricinoleic acid sucrose ester)
seeds or 28 or more and <8) soybean phospholipids, (C) calcium carbonate, calcium phosphate, calcium silicate,
An antifoaming agent for tofu, which contains one or more of magnesium carbonate, magnesium phosphate, and magnesium silicate, and (D) animal and vegetable oils and fats as essential components. agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58189539A JPS6083559A (en) | 1983-10-11 | 1983-10-11 | Defoaming agent for bean curd |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58189539A JPS6083559A (en) | 1983-10-11 | 1983-10-11 | Defoaming agent for bean curd |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6083559A true JPS6083559A (en) | 1985-05-11 |
| JPS6214260B2 JPS6214260B2 (en) | 1987-04-01 |
Family
ID=16242998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58189539A Granted JPS6083559A (en) | 1983-10-11 | 1983-10-11 | Defoaming agent for bean curd |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6083559A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61227756A (en) * | 1985-04-03 | 1986-10-09 | Riken Vitamin Co Ltd | Defoaming agent for 'tofu' |
| JPH0420257A (en) * | 1990-05-15 | 1992-01-23 | Riken Vitamin Co Ltd | Anti-foaming agent for tofu (bean curd) |
| US5223294A (en) * | 1990-04-05 | 1993-06-29 | Fujisawa Pharmaceutical Co., Ltd. | Liquid defoaming agent for food and method of use thereof |
| US5326499A (en) * | 1991-08-22 | 1994-07-05 | Basf Aktiengesellschaft | Antifoams for the paper industry, based on oil-in-water emulsions |
| WO1994014337A1 (en) * | 1992-12-21 | 1994-07-07 | Fujisawa Pharmaceutical Co., Ltd. | Food defoamer and food material containing the same |
| WO2005079590A1 (en) * | 2004-02-20 | 2005-09-01 | Splintiz Investment Limited | Improvements in and relating to beverages |
| WO2007021205A1 (en) * | 2005-08-19 | 2007-02-22 | Splintiz Investments Limited | Formulation of milk-based beverages for carbonation |
| JP2008011852A (en) * | 2006-06-07 | 2008-01-24 | Riken Vitamin Co Ltd | Method for producing defoaming agent composition |
| WO2011042852A1 (en) * | 2009-10-05 | 2011-04-14 | Danisco A/S | Use |
| JP2014187972A (en) * | 2013-03-28 | 2014-10-06 | Riken Vitamin Co Ltd | Defoaming agent for soybean milk and soybean curd |
| JP2016042851A (en) * | 2014-08-26 | 2016-04-04 | 理研ビタミン株式会社 | Antifoaming agent for soybean milk and bean curd |
| US9982392B2 (en) | 2013-11-19 | 2018-05-29 | Basf Se | Antifoaming agents for the paper industry, based on oil in water emulsions |
-
1983
- 1983-10-11 JP JP58189539A patent/JPS6083559A/en active Granted
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0120849B2 (en) * | 1985-04-03 | 1989-04-18 | Riken Vitamin Co | |
| JPS61227756A (en) * | 1985-04-03 | 1986-10-09 | Riken Vitamin Co Ltd | Defoaming agent for 'tofu' |
| US5223294A (en) * | 1990-04-05 | 1993-06-29 | Fujisawa Pharmaceutical Co., Ltd. | Liquid defoaming agent for food and method of use thereof |
| JPH0420257A (en) * | 1990-05-15 | 1992-01-23 | Riken Vitamin Co Ltd | Anti-foaming agent for tofu (bean curd) |
| US5326499A (en) * | 1991-08-22 | 1994-07-05 | Basf Aktiengesellschaft | Antifoams for the paper industry, based on oil-in-water emulsions |
| WO1994014337A1 (en) * | 1992-12-21 | 1994-07-07 | Fujisawa Pharmaceutical Co., Ltd. | Food defoamer and food material containing the same |
| WO2005079590A1 (en) * | 2004-02-20 | 2005-09-01 | Splintiz Investment Limited | Improvements in and relating to beverages |
| AU2006280501B2 (en) * | 2005-08-19 | 2012-06-14 | Splintiz Investments Limited | Formulation of milk-based beverages for carbonation |
| WO2007021205A1 (en) * | 2005-08-19 | 2007-02-22 | Splintiz Investments Limited | Formulation of milk-based beverages for carbonation |
| US8337924B2 (en) | 2005-08-19 | 2012-12-25 | Splintiz Investments, Ltd | Formulation of milk-based beverages for carbonation |
| JP2008011852A (en) * | 2006-06-07 | 2008-01-24 | Riken Vitamin Co Ltd | Method for producing defoaming agent composition |
| WO2011042852A1 (en) * | 2009-10-05 | 2011-04-14 | Danisco A/S | Use |
| AU2010304709B2 (en) * | 2009-10-05 | 2013-08-29 | Dupont Nutrition Biosciences Aps | Use |
| JP2014187972A (en) * | 2013-03-28 | 2014-10-06 | Riken Vitamin Co Ltd | Defoaming agent for soybean milk and soybean curd |
| US9982392B2 (en) | 2013-11-19 | 2018-05-29 | Basf Se | Antifoaming agents for the paper industry, based on oil in water emulsions |
| JP2016042851A (en) * | 2014-08-26 | 2016-04-04 | 理研ビタミン株式会社 | Antifoaming agent for soybean milk and bean curd |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6214260B2 (en) | 1987-04-01 |
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