JPS6081012A - Fine globular colored silica gel and its manufacture - Google Patents
Fine globular colored silica gel and its manufactureInfo
- Publication number
- JPS6081012A JPS6081012A JP18776983A JP18776983A JPS6081012A JP S6081012 A JPS6081012 A JP S6081012A JP 18776983 A JP18776983 A JP 18776983A JP 18776983 A JP18776983 A JP 18776983A JP S6081012 A JPS6081012 A JP S6081012A
- Authority
- JP
- Japan
- Prior art keywords
- pigment
- sodium silicate
- silica gel
- acid
- type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【発明の詳細な説明】
本発明は新規なメークアップ化粧、品用顔料に関するも
ので、更に詳しくは、光沢があり滑らかで伸が良く、感
触の優れた顔料を提供するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a novel pigment for makeup and cosmetics, and more specifically, to provide a pigment that is glossy, smooth, spreadable, and has an excellent feel.
従来よりメークアップ化粧品（ファンデーション、アイ
シャドウ等）は着色材として無機質顔料、有機質顔料お
よび染料を配合している。Traditionally, makeup cosmetics (foundation, eye shadow, etc.) have included inorganic pigments, organic pigments, and dyes as colorants.
その代表的なものとして無機質顔料では、酸化チタン、
弁柄、黄酸化鉄、群青、鉄黒など、有機質顔料ではへリ
ントンピンクＯＮ、リソールルピンＢ、ブリリアントブ
ルー、フタロシャニンブルーなどが挙げられる。しかし
これらの着色材は不定形の微粒子で凝集し易いためメー
クアップ化粧品に配合した際にはその感触を悪くする大
きな要因となっている。Typical examples of inorganic pigments include titanium oxide,
Examples of organic pigments include Bengara, yellow iron oxide, ultramarine, and iron black, as well as Herrington Pink ON, Lysole Lupine B, Brilliant Blue, and Phthaloshanine Blue. However, these colorants are amorphous fine particles that tend to aggregate, which is a major factor in deteriorating the feel of makeup cosmetics when they are incorporated into them.
本発明者らはメークアップ化粧品用顔料として非常に優
れた感触のものを得るため鋭意研究の結果、本発明に至
った。The present inventors have conducted intensive research to obtain pigments for makeup cosmetics that have an extremely excellent feel, and have finally arrived at the present invention.
すなわち、１〜６０ミクロンの微細球状シリカゲルに於
て、その内部に少なくとも一種類の着色材を含むことを
特徴とする着色された微細球状シリカゲルを得ることに
よりその目的が達成される。That is, the object is achieved by obtaining a colored fine spherical silica gel having a size of 1 to 60 microns and containing at least one kind of coloring material therein.
この様にして本来感触の悪い顔料なシリカでコーティン
グし、かつその粉体を１〜６０ミクロンの球体となす事
により非常に感触が良く、光沢があり、滑らかで仲が良
い特徴を有し、化粧品用顔料として理想的なものが得ら
れる。In this way, by coating with silica, a pigment that originally has a bad texture, and forming the powder into spheres of 1 to 60 microns, it has a very pleasant texture, gloss, smoothness, and good appearance, making it suitable for cosmetics. An ideal pigment for commercial use can be obtained.
本発明の感触の優れた顔料の製造方法は、Ｎａ２Ｏ・ｎ
８１０２・ＸＨ２Ｏで示される珪酸ソーダを主成分と
する水溶液中に、撹拌機、ホモジナイザー、ボールミル
等を用いて着色材を均一に分散あるいは溶解させる。The method for producing pigments with excellent texture according to the present invention includes Na2O・n
A coloring material is uniformly dispersed or dissolved in an aqueous solution containing sodium silicate represented by 8102.XH2O as a main component using a stirrer, a homogenizer, a ball mill, or the like.
この様にして得られた液体を、スプレードライヤーを用
いて噴霧乾燥することにより、内部に着色料を含んだ微
細球状珪酸ソーダを製造する。次に得られた粒子を、硫
酸、塩酸などの強酸で中和、水洗によりソーダ分を除去
し、乾燥することにより目的とする感触の優れた顔料が
得られる。By spray-drying the liquid thus obtained using a spray dryer, fine spherical sodium silicate containing a coloring agent is produced. Next, the obtained particles are neutralized with a strong acid such as sulfuric acid or hydrochloric acid, washed with water to remove the soda content, and dried to obtain the desired pigment with an excellent texture.
本発明で言う珪酸ソーダ水溶液としては、オルソ、メタ
珪酸ソーダ水溶液、ＪＩＳＩ号、２号、３号、４号珪酸
ソーダ水溶液、粉末珪酸ソーダを水に溶解したものが用
いられる。As the sodium silicate aqueous solution referred to in the present invention, an ortho- or meta-sodium silicate aqueous solution, a JISI No. 2, No. 3, or No. 4 sodium silicate aqueous solution, or a solution obtained by dissolving powdered sodium silicate in water is used.
これらは単独でもあるいは混合して用いても良く、ソー
ダ分の多いもの程、出来−Ｅっだシリカゲルは多孔質と
なる。These may be used alone or in combination, and the higher the soda content, the more porous the resulting silica gel will be.
またこれらの珪酸ソーダを主成分とする水溶液の中には
、得られる粒子の改質を目的として、アルミニウム、カ
ルシウム、マグネシウムなどを混入することも出来る。In addition, aluminum, calcium, magnesium, etc. can be mixed into these aqueous solutions containing sodium silicate as a main component for the purpose of modifying the obtained particles.
本発明で言う無機質顔料とは、酸化チタン、弁柄、黄酸
化鉄、群青、紺青、鉄黒、カーボンブラック、カオリン
、タルク、炭酸カルシウム、炭酸マグネシウム、硫酸バ
リウム、マイカ、マイカチタン、セリサイトなどが挙げ
られる。The inorganic pigments referred to in the present invention include titanium oxide, Bengara, yellow iron oxide, ultramarine, navy blue, iron black, carbon black, kaolin, talc, calcium carbonate, magnesium carbonate, barium sulfate, mica, mica titanium, sericite, etc. can be mentioned.
本発明で言う有機質顔料とは、リソールルビン系、レー
キレッド系、リソールレッド系、ブリリアントレーキレ
ッドＲ，ディープマルーン、トルイジンレッド、パーマ
ネントオレンジ、インジゴ、カルパンスレンブルー、ベ
ンジジンエローＧその他タール色素などが挙げられる。The organic pigments referred to in the present invention include Lysol Rubin series, Lake Red series, Lysol Red series, Brilliant Lake Red R, Deep Maroon, Toluidine Red, Permanent Orange, Indigo, Calpanthrene Blue, Benzidine Yellow G, and other tar pigments. It will be done.
本発明で言う有機染料とは、アマランス、エリスロシン
、ニラ−１りシン、エオシン系、フロキシン系、「１−
ズベンガル系、アシッドレッド、タートラジン、サンセ
ットエローＦＯＦ、ギネアグリーンＢ１ライトグリーン
８Ｆ、ファストグリーンＦＯＦ、ブリリアントブルーＦ
ＯＦ。The organic dyes referred to in the present invention include amaranth, erythrosine, chive-1-lysine, eosin-based, phloxine-based, "1-
Zvengali, Acid Red, Tartrazine, Sunset Yellow FOF, Guinea Green B1 Light Green 8F, Fast Green FOF, Brilliant Blue F
OF.
インジゴカルミン、アシッドバイオレット６Ｂ。Indigo carmine, acid violet 6B.
ファストアシッドマゼンタ、ジブロムフルオレセイン系
、オレンジ■、エリスロシン黄ＮＡ、ウラニン系、キノ
リンエローＷＳ１アリザリンシャニングリンＦ１ピラニ
ンコンク、アルファズリンＦＯ，レゾルシンブラウンそ
の他食用色素などが挙げられる。Examples include fast acid magenta, dibrome fluorescein type, orange ■, erythrosin yellow NA, uranine type, quinoline yellow WS1 alizarin shinning green F1 pyranine conc, alphazurin FO, resorcin brown and other food colorings.
なお上記の他化粧品用着色材としての基準に従うものは
使用できる。また化粧品以外の用途であれば他の顔料、
染料も広く用いる事ができる。これらの着色材は通常５
１０２に対して染料、有機質顔料で０．１〜５０％、無
機顔料で５〜１００％の範囲で添加することが出来る。In addition to the above, materials that comply with the standards for colorants for cosmetics can be used. In addition, for purposes other than cosmetics, other pigments,
Dyes can also be widely used. These colorants are usually 5
102, dyes and organic pigments can be added in an amount of 0.1 to 50%, and inorganic pigments can be added in an amount of 5 to 100%.
本発明で用いる珪酸ソーダを主成分とする水溶液の粘度
は通常１００ｃｐ以下が好ましく、これ以上になると粒
子が大きくなったり、粒子同士が付着するなどの不都合
が起る。The viscosity of the aqueous solution containing sodium silicate as a main component used in the present invention is usually preferably 100 cp or less; if it exceeds this value, problems such as particles becoming large or particles adhering to each other occur.
本発明の噴霧乾燥は通常よく知られているスプレードラ
イヤーが用りられる。スプレードライヤーは回転ディス
クによる高速遠心噴霧方式および二液体ノズル方式が好
ましく、加圧ノズル方式は粒径が大きくなりすぎ好まし
くない。In the spray drying of the present invention, a well-known spray dryer is usually used. The spray dryer is preferably a high-speed centrifugal spray method using a rotating disk or a two-liquid nozzle method; a pressurized nozzle method is not preferred because the particle size becomes too large.
回転ディスク方式の場合においては、回転ディスクの大
きさと回転数により得られる粒子の大きさが変動するが
、回転ディスクより珪酸ソーダを主成分とする水溶液が
とび出す位置の速！
度、すなわちディスクの周速が毎分７０００ｍ以上であ
ることが必要である。これ以下の速度の場合は粒子が大
きく、全体に不揃となり所望のものが得られない。In the case of the rotating disk method, the size of the particles obtained varies depending on the size and rotation speed of the rotating disk, but the speed at which the aqueous solution containing sodium silicate as the main component is ejected from the rotating disk! It is necessary that the circumferential speed of the disk is 7000 m/min or more. If the speed is lower than this, the particles will be large and irregular, making it impossible to obtain the desired particles.
また二流体ノズル方式の場合は、ノズルの中心より珪酸
ソーダを主成分とする水溶液を供給し、その周囲より圧
搾空気を噴射して霧状の珪酸ソーダとして噴霧する。こ
の時の圧力は３ｈ／ｃｌ〜７Ｋｐ／ｃｌの範囲が好まし
い。３ＫＰ／ｄ未満の圧力では粒子が太きく 、 ７Ｋ
ｐ／ｃＪ２Ｌ上では細かくなりすぎ所望のものが得られ
ない。In the case of a two-fluid nozzle system, an aqueous solution containing sodium silicate as a main component is supplied from the center of the nozzle, and compressed air is injected from around the nozzle to atomize it as a mist of sodium silicate. The pressure at this time is preferably in the range of 3 h/cl to 7 Kp/cl. If the pressure is less than 3KP/d, the particles will be thick and 7K.
On p/cJ2L, it becomes too fine and the desired product cannot be obtained.
この様にして噴霧された珪酸ソーダを主成分とする水溶
液は、内部に着色材を包含した状態で空気中で自らの表
面張力により真球状となり、乾燥される。The aqueous solution mainly composed of sodium silicate sprayed in this manner becomes a perfect sphere in the air due to its own surface tension while containing the colorant therein, and is dried.
次にこの粉体を酸によって中和する。用いられる酸とし
ては、硫酸、塩酸、硝酸などでナトリウムと反応して水
可溶性の塩を作り、水洗により除去できるものであれば
何でも良い。This powder is then neutralized with acid. Any acid can be used, such as sulfuric acid, hydrochloric acid, or nitric acid, as long as it reacts with sodium to form a water-soluble salt and can be removed by washing with water.
通常５〜１０％濃度の強酸を激しく撹拌し、その中に除
々に粉体を入れることにより中和され、同時にナトリウ
ムは水可溶性の塩となって粉体粒子外に出る。その後、
脱水、水洗、乾燥の操作を経て目的とする内部に少なく
とも一種類の着色材を含む微細球状シリカゲルが得られ
る。この様にして得られた着色材を含む微細球状シリカ
ゲルは、従来の顔料の様にベタツキ、仲が悪くメークア
ップ化粧品にした際に非常に感触を悪くすると言う欠点
を完全に解消し、顔料自体が非常（−滑らかで感触が良
く、しかも光沢があり、透明感もある優れたものとなっ
た。A strong acid, usually at a concentration of 5 to 10%, is vigorously stirred and the powder is gradually introduced into the acid to neutralize it, and at the same time, sodium becomes a water-soluble salt and exits from the powder particles. after that,
After dehydration, washing, and drying operations, the desired fine spherical silica gel containing at least one type of coloring material is obtained. The fine spherical silica gel containing the colorant obtained in this way completely eliminates the disadvantages of conventional pigments, such as stickiness and poor texture, which causes a very bad feel when used in make-up cosmetics, and the pigment itself It was very (-) smooth, had a good feel, was glossy, and had excellent transparency.
このためこの顔料をメータアンプ用化粧料（例えばファ
ンデーション、アイシャドウ、頬紅等）に５〜４０％配
合することにより従来にない軽妙滑らかな伸びの良いも
のとなる。これらの顔料は必要に応じシリコン処理、金
属セッケン処理等により表面の親水性を改良すること７
ができる。Therefore, by blending 5 to 40% of this pigment into meter amplifier cosmetics (for example, foundations, eye shadows, blushers, etc.), it becomes light, smooth, and spreads well, which is unprecedented. The surface hydrophilicity of these pigments may be improved by silicon treatment, metal soap treatment, etc. as necessary7.
Can be done.
本発明は主としてメークアップ化粧料を目的として開発
されたものであるが、もちろんこの用途に限定されるも
のではなく、プラスチックの着色充填材、各種滑材、塗
料用顔料など着色された微細球状シリカゲルを必要とす
る所にはすべて利用できる。Although the present invention was developed primarily for use in make-up cosmetics, it is of course not limited to this use, and can be used for colored fine spherical silica gel, such as colored fillers for plastics, various lubricants, and pigments for paints. It can be used wherever you need it.
以下実施例（二より更に詳細に説明する。Example 2 will be described in more detail below.
実施例Ｉ
ＪＩ８に１４０８に定める３号珪酸ソーダ８ Ｋｐに酸
化チタンをＩ Ｋｆ加えボールミルで３時間混合した。Example I I Kf of titanium oxide was added to 8 Kp of No. 3 sodium silicate specified in JI8/1408 and mixed in a ball mill for 3 hours.
次いで水２ Ｋｆを加えて均一に溶解し原液を作成した
。原液の粘度は３５Ｃ！Ｐであった。Next, 2 Kf of water was added to uniformly dissolve the mixture to prepare a stock solution. The viscosity of the stock solution is 35C! It was P.
この原液を回転ディスク方式のスプレードライヤー（胴
部直径２．２ｍ、高さ３ｍ）の中に毎時２０７供給し、
回転ディスクの周速７５００ｍ／ｍｉｎで２００℃の空
気中に噴霧し、約３．５ Ｋｆの粉体な得た。得られた
粉体はスプレードライヤーの下部よりサイクロンに導き
集収した。This stock solution is fed into a rotating disk type spray dryer (body diameter 2.2 m, height 3 m) at 207 mph per hour.
It was sprayed into air at 200° C. at a peripheral speed of 7500 m/min of a rotating disk to obtain a powder of about 3.5 Kf. The obtained powder was introduced into a cyclone from the bottom of the spray dryer and collected.
次に激しく撹拌した１０％の硫酸水溶液３０１に除々に
加え１０分間撹拌を続けた。Next, it was gradually added to a vigorously stirred 10% aqueous sulfuric acid solution 301, and stirring was continued for 10 minutes.
その後還水脱水機にて脱水し、ろ液のＰＨ７１＝なるま
で４〜５回水洗して１２０℃で５時間加熱乾燥し、約２
．８ Ｋｐの白色球状粉体を得た。After that, it was dehydrated using a reflux dehydrator, washed with water 4 to 5 times until the pH of the filtrate became 71, and then heated and dried at 120°C for 5 hours.
．． A white spherical powder of 8 Kp was obtained.
得られた粉体は平均粒径２０ミクロン、最少５ミクロン
、最大５０ミクロンの真球状白色粉体で、酸化チタンそ
の物とはまったく異る滑らかな感触と、光沢を有し、非
常に好ましい顔料であった。（以下酸化チタンビーズと
称ス）実施例−２
実施例−１と同様な条件、方法で黄酸化鉄、弁柄、黒色
酸化鉄について着色微細球状シリカゲルを製造した。（
以下黄酸化鉄ビーズ、弁柄ビーズ黒色酸化鉄ビーズと称
す）
得られた黄酸化鉄ビーズは平均粒径１８ミクロン、最少
５ミクロン１．最大４５ミクロンで滑らかで、光沢を有
し、非常に好ましい顔料であった。The obtained powder is a true spherical white powder with an average particle size of 20 microns, a minimum of 5 microns, and a maximum of 50 microns, and has a smooth feel and gloss that is completely different from titanium oxide itself, making it a highly desirable pigment. Met. (Hereinafter referred to as titanium oxide beads) Example 2 Colored fine spherical silica gels were produced using yellow iron oxide, peta, and black iron oxide under the same conditions and method as in Example 1. (
(hereinafter referred to as yellow iron oxide beads and Bengara beads as black iron oxide beads) The obtained yellow iron oxide beads had an average particle size of 18 microns and a minimum of 5 microns. It was smooth, glossy, with a maximum of 45 microns, and was a very desirable pigment.
また弁柄ビーズは、平均粒径２３ミクロン、最少５ミク
ロン、最大５７ミクロン、黒色酸化鉄は平均粒径２５ミ
クロン、最少５ミクロン、最大５５ミクロンで共に滑ら
かで光沢のある顔料が得られた。Furthermore, the Bengara beads had an average particle diameter of 23 microns, a minimum of 5 microns, and a maximum of 57 microns, and the black iron oxide had an average particle diameter of 25 microns, a minimum of 5 microns, and a maximum of 55 microns, and smooth and glossy pigments were obtained.
実施例−３
実施例−１および実施例−２で得た各色のビーズを用い
パウダーファンデーションを作った。Example-3 Powder foundation was made using beads of each color obtained in Example-1 and Example-2.
成分１ セリサイト ４４．９（重量部）タルク ８．
２
マイカ粉 ３．０
雲母チタン ３．０
酸化チタンビーズ ２０．Ｏ
黄酸化鉄ビーズ ６．０
弁柄ビーズ ２．０
黒色酸化鉄ビーズ ０．４
成分２ スクワラン ５．０（重量部）メチルポリシロ
キサン ３０
ミリスチン酸イソプロピル ２．０
パラフイン １０
界面活性剤 １．０
香料 ０．５
まず成分１のセリサイト、タルク、マイカ粉、雲母チタ
ンをヘンシルミキサーで混合し、アトマイザ−で粉砕し
た。次いで酸化チタンビーズ、黄酸化鉄ビーズ、弁柄ビ
ーズ、黒色酸化鉄ビーズを加えてヘンシルミキサーで十
分混合した後、成分２の加熱混合物を加えてヘンシルミ
キサーで混合し、再度アトマイザ−で粉砕した。Ingredient 1 Sericite 44.9 (parts by weight) Talc 8.
2 Mica powder 3.0 Titanium mica 3.0 Titanium oxide beads 20. O Yellow iron oxide beads 6.0 Bengara beads 2.0 Black iron oxide beads 0.4 Component 2 Squalane 5.0 (parts by weight) Methylpolysiloxane 30 Isopropyl myristate 2.0 Paraffin 10 Surfactant 1.0 Fragrance 0.5 First, Component 1, sericite, talc, mica powder, and mica titanium, were mixed using a Henshil mixer and pulverized using an atomizer. Next, titanium oxide beads, yellow iron oxide beads, Bengara beads, and black iron oxide beads were added and thoroughly mixed with a Henshil mixer, then the heated mixture of component 2 was added and mixed with a Henshil mixer, and then ground again with an atomizer. did.
これを中皿に充填成型して製品とした８この様にして得
られたパウダーファンデーションは従来のものと比較し
、伸び、滑らかさ、光沢の点で非常に優れたものであっ
た。This powder foundation was filled and molded into a medium plate to produce a product.8 The powder foundation thus obtained was extremely superior in spreadability, smoothness, and gloss compared to conventional products.
また、ベタツキが少なくさっばりした仕上りとなった。Also, it has a light finish with less stickiness.
比較例−１
従来の顔料である酸化チタン、黄酸化鉄、弁柄、黒色酸
化鉄を用いてパウダーファンデタルク ８，３
マイカ粉 ３．０
雲母チタン ３．０
酸化チタン １０，０・
黄酸化鉄 ３．０
弁柄 １．０
黒色酸化鉄 ０．２
（重量部）
成分２ スクヮラン ５．０
メチルポリシロキサン ３．０
ミリスチン酸イソプロピル ２．０
パラフイン １．０
界面活性剤 １０
香料 ０．５
成分１をヘンシルミキサーで混合し、アイマイザーで粉
砕した。この中に成分２の加熱混合物を入れ、ヘンシル
ミキサーで混合後、再度アトマイザ−で粉砕した。これ
を中皿に充填成型して製品とした。Comparative Example-1 Powder van des Talc using conventional pigments such as titanium oxide, yellow iron oxide, Bengara, and black iron oxide 8,3 Mica powder 3.0 Mica titanium 3.0 Titanium oxide 10,0 Yellow iron oxide 3.0 Bengara 1.0 Black iron oxide 0.2 (parts by weight) Component 2 Squalane 5.0 Methylpolysiloxane 3.0 Isopropyl myristate 2.0 Paraffin 1.0 Surfactant 10 Fragrance 0.5 Component 1 were mixed with a Henshil mixer and pulverized with an eyemizer. The heated mixture of component 2 was put into this, mixed with a Henshil mixer, and then ground again with an atomizer. This was filled into a medium plate and molded to produce a product.
得られたファンデージワンは実施例−３のものと比較す
ると伸びが悪く、滑らかさ、光沢の点で劣っていた。The obtained Foundation One had poor spreadability and was inferior in smoothness and gloss compared to that of Example-3.
以上の記載から明らかな様に、本発明の感触の優れた顔
料およびその製造方法は、従来のものと比較し、伸びの
良さ、滑らかさ、感触に優れ、光沢を与えると言う、化
粧品用顔料として非常に優れた特徴を有するものである
。As is clear from the above description, the pigment with excellent texture and the method for producing the same of the present invention can be used to produce a pigment for cosmetics that has excellent spreadability, smoothness, texture, and gloss compared to conventional pigments. It has very excellent characteristics.
特許出願人有限会社三好化成Patent applicant Miyoshi Kasei Co., Ltd.
Claims (6)
ロンの微細球状シリカゲルの内部に、少なくとも一種類
の無機質顔料を含むことを特徴とする顔料。(1) A pigment characterized by containing at least one type of inorganic pigment inside a fine spherical silica gel of 1 to 60 microns represented by SiO2.XH2O.
ロンの微細球状シリカゲルの内部に、少なくとも一種類
の有機質顔料を含むことを特徴とする顔料。(2) A pigment characterized by containing at least one type of organic pigment inside microscopic spherical silica gel of 1 to 60 microns represented by SiO2.X H2O.
ンの微細球状シリカゲルの内部に、少なくとも一種類の
染料を含むことを特徴とする顔料。(3) A pigment characterized by containing at least one type of dye inside microscopic spherical silica gel of 1 to 60 microns represented by Si02.XH2.
も一種類の無機質顔料を分散し、噴霧乾燥により造粒し
た後、酸によりソーダ分を中和し、除去することを特徴
とする顔料の製造方法。(4) A pigment characterized by dispersing at least one type of inorganic pigment in an aqueous solution containing sodium silicate as a main component, granulating it by spray drying, and then neutralizing and removing the soda content with an acid. Production method.
も一種類の有機質顔料を分散し、噴霧乾燥により造粒し
た後、酸によりソーダ分を中和し除去することを特徴と
する顔料の製造方法。(5) Production of a pigment characterized by dispersing at least one type of organic pigment in an aqueous solution containing sodium silicate as a main component, granulating it by spray drying, and then neutralizing and removing the soda content with acid. Method.
も一種類の染料を溶解し、噴霧乾燥により造粒した後、
酸によりソーダ分を中和し、除去することを特徴とする
顔料の製造方法。(6) After dissolving at least one type of dye in an aqueous solution containing sodium silicate as a main component and granulating it by spray drying,
A method for producing pigments, characterized by neutralizing and removing soda content with acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18776983A JPS6081012A (en) | 1983-10-06 | 1983-10-06 | Fine globular colored silica gel and its manufacture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18776983A JPS6081012A (en) | 1983-10-06 | 1983-10-06 | Fine globular colored silica gel and its manufacture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6081012A true JPS6081012A (en) | 1985-05-09 |
Family
ID=16211885
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18776983A Pending JPS6081012A (en) | 1983-10-06 | 1983-10-06 | Fine globular colored silica gel and its manufacture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6081012A (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62216911A (en) * | 1986-03-17 | 1987-09-24 | Wako Pure Chem Ind Ltd | Activated carbon-containing silica gel, its production, and analytical method using said gel as packing material of cleanup column |
| JPH05201830A (en) * | 1992-01-30 | 1993-08-10 | Kose Corp | Porous spherular powder and cosmetic containing the same powder |
| EP0581651A2 (en) * | 1992-07-27 | 1994-02-02 | Suzuki Yushi Industries Co., Ltd. | Materials in the form of colored spherical fine particles, processes for producing the same and cosmetic compositions containing the particulate material |
| US6080232A (en) * | 1996-11-14 | 2000-06-27 | Degussa Aktiengesellschaft | Spherical color pigments, process for their production and use thereof |
| EP1397109A1 (en) * | 2001-06-18 | 2004-03-17 | The Procter & Gamble Company | Cosmetic compositions comprising discrete color domains |
| US6786965B2 (en) * | 1999-12-03 | 2004-09-07 | Sun Chemical Corporation | Organic pigment dispersion for coloring building materials |
| WO2005028568A1 (en) * | 2003-09-22 | 2005-03-31 | Nippon Sheet Glass Company, Limited | Black brigthening flake and cosmetic preparation, coating composition, resin composition, and ink composition each containing the same |
| WO2005028567A1 (en) * | 2003-09-22 | 2005-03-31 | Nippon Sheet Glass Company, Limited | Blue-colored flake, and cosmetic, coating composition, resin composition and ink composition comprising the same |
| JP2008184354A (en) * | 2007-01-30 | 2008-08-14 | New Industry Research Organization | Method of producing spherical silica gel particle |
| JP2010535929A (en) * | 2007-08-13 | 2010-11-25 | プロクター アンド ギャンブル インターナショナル オペレーションズ エス エー | Spray drying process for the production of dye-carrying particles |
| JP2010535928A (en) * | 2007-08-13 | 2010-11-25 | プロクター アンド ギャンブル インターナショナル オペレーションズ エス エー | Dye-carrying particles |
| JP2010535856A (en) * | 2007-08-13 | 2010-11-25 | プロクター アンド ギャンブル インターナショナル オペレーションズ エス エー | Composition comprising dye-carrying particles |
| DE102009026746A1 (en) * | 2009-06-04 | 2010-12-09 | Sensient Imaging Technologies Gmbh | Spray-dried dye composites, process for their preparation and their use |
| JP2011195803A (en) * | 2010-02-25 | 2011-10-06 | Mitsubishi Pencil Co Ltd | Liquid ink composition for writing utensil |
| JP2012017437A (en) * | 2010-07-09 | 2012-01-26 | Mitsubishi Pencil Co Ltd | Water-based ball-point pen |
| FR2973225A1 (en) * | 2011-03-31 | 2012-10-05 | Lvmh Rech | PIGMENT PARTICLES |
| JP2013095888A (en) * | 2011-11-04 | 2013-05-20 | Jgc Catalysts & Chemicals Ltd | Method for producing pigment-including silica particle, pigment-including silica particle, and cosmetic including the particle |
| JP2013095797A (en) * | 2011-10-28 | 2013-05-20 | Jgc Catalysts & Chemicals Ltd | Method for producing dye-including silica-based particle, dye-including silica-based particle, and use of the particle |
| JP2013133410A (en) * | 2011-12-27 | 2013-07-08 | Jgc Catalysts & Chemicals Ltd | Method for producing dyestuff and/or pigment-including metal oxide particle, the dyestuff and/or pigment-including metal oxide particle, and use of the particle |
-
1983
- 1983-10-06 JP JP18776983A patent/JPS6081012A/en active Pending
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62216911A (en) * | 1986-03-17 | 1987-09-24 | Wako Pure Chem Ind Ltd | Activated carbon-containing silica gel, its production, and analytical method using said gel as packing material of cleanup column |
| JPH05201830A (en) * | 1992-01-30 | 1993-08-10 | Kose Corp | Porous spherular powder and cosmetic containing the same powder |
| EP0581651A2 (en) * | 1992-07-27 | 1994-02-02 | Suzuki Yushi Industries Co., Ltd. | Materials in the form of colored spherical fine particles, processes for producing the same and cosmetic compositions containing the particulate material |
| EP0581651A3 (en) * | 1992-07-27 | 1994-09-28 | Suzuki Yushi Kogyo Kk | Materials in the form of colored spherical fine particles, processes for producing the same and cosmetic compositions containing the particulate material |
| US6080232A (en) * | 1996-11-14 | 2000-06-27 | Degussa Aktiengesellschaft | Spherical color pigments, process for their production and use thereof |
| US6786965B2 (en) * | 1999-12-03 | 2004-09-07 | Sun Chemical Corporation | Organic pigment dispersion for coloring building materials |
| EP1397109A1 (en) * | 2001-06-18 | 2004-03-17 | The Procter & Gamble Company | Cosmetic compositions comprising discrete color domains |
| WO2005028568A1 (en) * | 2003-09-22 | 2005-03-31 | Nippon Sheet Glass Company, Limited | Black brigthening flake and cosmetic preparation, coating composition, resin composition, and ink composition each containing the same |
| WO2005028567A1 (en) * | 2003-09-22 | 2005-03-31 | Nippon Sheet Glass Company, Limited | Blue-colored flake, and cosmetic, coating composition, resin composition and ink composition comprising the same |
| JPWO2005028568A1 (en) * | 2003-09-22 | 2007-11-15 | 日本板硝子株式会社 | Black glittering flakes and cosmetics, coating compositions, resin compositions and ink compositions containing the same |
| JPWO2005028567A1 (en) * | 2003-09-22 | 2007-11-15 | 日本板硝子株式会社 | Blue colored flakes and cosmetics, coating compositions, resin compositions and ink compositions containing the same |
| JP2008184354A (en) * | 2007-01-30 | 2008-08-14 | New Industry Research Organization | Method of producing spherical silica gel particle |
| JP2010535929A (en) * | 2007-08-13 | 2010-11-25 | プロクター アンド ギャンブル インターナショナル オペレーションズ エス エー | Spray drying process for the production of dye-carrying particles |
| JP2010535928A (en) * | 2007-08-13 | 2010-11-25 | プロクター アンド ギャンブル インターナショナル オペレーションズ エス エー | Dye-carrying particles |
| JP2010535856A (en) * | 2007-08-13 | 2010-11-25 | プロクター アンド ギャンブル インターナショナル オペレーションズ エス エー | Composition comprising dye-carrying particles |
| DE102009026746A1 (en) * | 2009-06-04 | 2010-12-09 | Sensient Imaging Technologies Gmbh | Spray-dried dye composites, process for their preparation and their use |
| JP2011195803A (en) * | 2010-02-25 | 2011-10-06 | Mitsubishi Pencil Co Ltd | Liquid ink composition for writing utensil |
| JP2012017437A (en) * | 2010-07-09 | 2012-01-26 | Mitsubishi Pencil Co Ltd | Water-based ball-point pen |
| FR2973225A1 (en) * | 2011-03-31 | 2012-10-05 | Lvmh Rech | PIGMENT PARTICLES |
| JP2012214471A (en) * | 2011-03-31 | 2012-11-08 | Lvmh Recherche | Makeup composition containing encapsulated carbon black |
| US8506976B2 (en) | 2011-03-31 | 2013-08-13 | Lvmh Recherche | Makeup composition comprising encapsulated carbon black |
| JP2013095797A (en) * | 2011-10-28 | 2013-05-20 | Jgc Catalysts & Chemicals Ltd | Method for producing dye-including silica-based particle, dye-including silica-based particle, and use of the particle |
| JP2013095888A (en) * | 2011-11-04 | 2013-05-20 | Jgc Catalysts & Chemicals Ltd | Method for producing pigment-including silica particle, pigment-including silica particle, and cosmetic including the particle |
| JP2013133410A (en) * | 2011-12-27 | 2013-07-08 | Jgc Catalysts & Chemicals Ltd | Method for producing dyestuff and/or pigment-including metal oxide particle, the dyestuff and/or pigment-including metal oxide particle, and use of the particle |
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