JPS605534B2 - Method for manufacturing inorganic vitreous foam - Google Patents

Method for manufacturing inorganic vitreous foam

Info

Publication number
JPS605534B2
JPS605534B2 JP16191480A JP16191480A JPS605534B2 JP S605534 B2 JPS605534 B2 JP S605534B2 JP 16191480 A JP16191480 A JP 16191480A JP 16191480 A JP16191480 A JP 16191480A JP S605534 B2 JPS605534 B2 JP S605534B2
Authority
JP
Japan
Prior art keywords
foam
foaming
weight
parts
inorganic vitreous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP16191480A
Other languages
Japanese (ja)
Other versions
JPS5788042A (en
Inventor
栄一 半田
雄平 曽我部
芳太郎 村田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Chemical Industrial Co Ltd
Original Assignee
Nippon Chemical Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Chemical Industrial Co Ltd filed Critical Nippon Chemical Industrial Co Ltd
Priority to JP16191480A priority Critical patent/JPS605534B2/en
Publication of JPS5788042A publication Critical patent/JPS5788042A/en
Publication of JPS605534B2 publication Critical patent/JPS605534B2/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C11/00Multi-cellular glass ; Porous or hollow glass or glass particles
    • C03C11/007Foam glass, e.g. obtained by incorporating a blowing agent and heating

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Description

【発明の詳細な説明】 本発明は、無機ガラス質発泡体、詳しくは粒状の無機ガ
ラス質発泡体の製造法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing inorganic vitreous foams, particularly granular inorganic vitreous foams.

無機ガラス質発泡体は一般に多泡ガラスとも呼ばれ、断
熱材、吸音材として優れた性質を有している。近時、建
造物の高層化や人命保護の強い要請からこの種の発泡材
料は建築材として極めて好ましい性質を有しているので
その開発が望まれている。従来、この種の発泡体は「ガ
ラス粉末に発泡剤として炭素物質や炭酸カルシウムなど
の炭酸塩を用いて発泡させたものが一般的に知られてい
る。しかしながら、従来の多泡ガラス発泡方法は800
〜900つ○の範囲で型枠内で発泡させるために、徐冷
前に型枠を外す必要があり、しかも徐冷に長時間を要す
るので建材に使用するような大型の発泡体を経済的に製
造することは難しかった。特に、均質性のある泡を有す
る発泡体を得ることは原料組成と加熱方法とのかねあい
で微妙であり、非常に難しい。一方、珪酸アルカリはそ
れ自体加熱発泡することは周知である。しかしながら、
この発泡体は耐水性が殆んどなく、強度および耐熱性も
弱いもので建材としての実用性に欠ける。従って、この
発泡体の改質のため非常に数多くの提案がなされている
が、いずれも一長一短であって決定的なものはないのが
現状である。他方、有機質や無機質のマトリクスで成型
するか有機質や無機質のバインダーを用いて成型し、軽
量建材を製造するための軽量骨材としては、真珠岩や黒
曜石の発泡体や発泡ひる石、発泡シラスおよび天然軽石
などが知られている。
Inorganic vitreous foam is generally called cellular glass and has excellent properties as a heat insulating material and a sound absorbing material. In recent years, as buildings have become taller and there has been a strong need to protect human lives, this type of foam material has extremely favorable properties as a building material, and the development thereof has been desired. Conventionally, this type of foam is generally known as one made by foaming glass powder using a carbon material or carbonate such as calcium carbonate as a foaming agent.However, the conventional multi-cell glass foaming method is 800
In order to foam within the formwork within the range of ~900 ○, it is necessary to remove the formwork before slow cooling, and since slow cooling takes a long time, it is not economical to use large foams such as those used for building materials. was difficult to manufacture. In particular, it is very difficult to obtain a foam with homogeneous foam due to the delicate balance between raw material composition and heating method. On the other hand, it is well known that alkali silicate itself foams when heated. however,
This foam has almost no water resistance, low strength and low heat resistance, and lacks practicality as a building material. Therefore, a large number of proposals have been made to modify this foam, but at present they all have advantages and disadvantages, and there is no definitive solution. On the other hand, lightweight aggregates for manufacturing lightweight building materials by molding in organic or inorganic matrices or using organic or inorganic binders include perlite and obsidian foams, foamed vermiculite, foamed shirasu, and Natural pumice is also known.

しかしながら真珠岩や黒曜石の発泡体や発泡ひる石は強
度が弱く混合時につぶれてしまい成型物の見掛比重が軽
くならず、天然の軽石も見類比重0.5〜0.9と重い
ので軽い建材が出来ないという欠点があった。
However, pearlite, obsidian foam, and foamed vermiculite have weak strength and collapse during mixing, making it difficult to reduce the apparent specific gravity of the molded product. Natural pumice is also heavy with an apparent specific gravity of 0.5 to 0.9, so it is light. The drawback was that it could not be used as a building material.

本発明者らは上記の欠点に鑑み、建材用のガラス質発泡
体の製造について鋭意検討してきたが、従来と異なり、
ガラス粉末、発泡剤、珪酸アルカリおよびゼオラィト類
を主原料として、従来よりも低温で均質な泡を有する発
泡体が得られることを知見し本発明の完成を見た。
In view of the above-mentioned drawbacks, the present inventors have been intensively studying the production of glassy foam for building materials, but unlike conventional methods,
The present invention was completed by discovering that a foam having homogeneous foam can be obtained at a lower temperature than before by using glass powder, a blowing agent, an alkali silicate, and zeolites as main raw materials.

ガラス粉末100重量部に対し、発泡剤1〜10重量部
、珪酸アルカリが固形分として1〜4の重量部およびゼ
オラィト1〜5の重量部の割合で配合した混合物を加熱
発泡させることを特徴とする無機ガラス質発泡体の製造
法にかかる。
It is characterized by heating and foaming a mixture of 1 to 10 parts by weight of a blowing agent, 1 to 4 parts by weight of alkali silicate as a solid content, and 1 to 5 parts by weight of zeolite to 100 parts by weight of glass powder. The present invention relates to a method for producing an inorganic vitreous foam.

まず使用する原料のうち、ガラス粉末は特に限定の必要
はなく、いずれも使用可能であり、例えば通常のソーダ
石灰ガラス、ほう珪酸ガラスなどの粉末が代表的である
First, among the raw materials used, there is no need to limit the glass powder in particular, and any can be used, for example, typical powders such as ordinary soda lime glass and borosilicate glass.

従って、用途的にいえば、板ガラス粉末や各種瓶ガラス
粉末などの肩ガラス粉末で安価にかつ大量に入手できる
ものであればよい。なおこの粉末は粒度が大きくとも1
49仏肌(100メッシュ)以下とすることが均質発泡
体を得ることが必要である。発泡剤は公知のものが殆ん
ど適用できるが、比較的低温で気体を発生するようなも
のが適当であり、例えば、炭酸ソーダ、炭酸カルシウム
、炭酸マグネシウム又は炭酸バリウムなどの炭酸塩、そ
れらの含有物であるドロマィト、燐鉱石、二酸化マンガ
ン等があげられ、それらは1種又は2種以上併用しても
差支えない。
Therefore, in terms of usage, any glass powder that can be obtained inexpensively and in large quantities may be used, such as plate glass powder or various bottle glass powders. The particle size of this powder is at most 1
It is necessary to obtain a homogeneous foam having a mesh size of 49 mm (100 mesh) or less. Most known blowing agents can be used, but those that generate gas at relatively low temperatures are suitable.For example, carbonates such as soda carbonate, calcium carbonate, magnesium carbonate, or barium carbonate, and their Examples include dolomite, phosphate rock, manganese dioxide, etc., which are included, and these may be used alone or in combination of two or more.

なお、この場合発泡助剤として、尿素、チオ尿素、シュ
ウ酸その他常温で固体の有機物を必要に応じて使用する
こともよい。前記の如きガラス粉末と発泡剤との混合物
を加熱処理すると発泡するが、均質な細胞状のガラス発
泡体を再現性よく工業的に大量生産することは仲々困難
であるが、本発明には、更に珪酸アルカリおよびゼオラ
ィトを添加した混合物を加熱発泡させることによって効
果的にガラス発泡体を調製しうる。
In this case, as a foaming aid, urea, thiourea, oxalic acid, and other organic substances that are solid at room temperature may be used as necessary. When a mixture of glass powder and a blowing agent as described above is heated, it foams, but it is difficult to industrially mass-produce homogeneous cellular glass foam with good reproducibility. Further, a glass foam can be effectively prepared by heating and foaming a mixture to which an alkali silicate and zeolite are added.

その作用機構の詳細については明らかでないが、恐らく
珪酸アルカリは融一則降下態と共に発泡剤でもあり、又
、ゼオラィトは混合物中にあって、加熱するとガラス化
すると共に発泡する泡の安定化能を有するためではない
かと推定される。本発明において、珪酸アルカリは一般
に水ガラスと称している溶液はもちろん含水又は無水の
固形珪酸アルカリであっても差支えない。
Although the details of its mechanism of action are not clear, it is likely that the alkali silicate is a foaming agent as well as a melting law descending agent, and the zeolite is present in the mixture and has the ability to vitrify and foam when heated. It is presumed that this is because of this. In the present invention, the alkali silicate may be a solution generally referred to as water glass, or may be a hydrous or anhydrous solid alkali silicate.

又珪酸アルカリは多くの場合、珪酸ソーダであるが、カ
リ塩であってもよい。その組成は、モル比Si02/地
○(ただしMはNa又はKを表わす)で1〜4の範囲に
あるもので充分である。次に、ゼオライトは三次元的骨
格構造を有し、かつ結晶水を有する結晶性アルミノ珪酸
塩の総称でありSi02/AI203のモル比によって
種々のゼオライトが知られており本発明においてはゼオ
ラィトであれば特に限定はない。
The alkali silicate is often sodium silicate, but may also be a potassium salt. It is sufficient that the composition has a molar ratio of Si02/G2 (where M represents Na or K) in the range of 1 to 4. Next, zeolite is a general term for crystalline aluminosilicate having a three-dimensional skeleton structure and water of crystallization, and various zeolites are known depending on the molar ratio of Si02/AI203. There are no particular limitations.

例えば、A型、X型、Y型又はP型ゼオラィト、モルデ
十ナイト「 アナルサイト、ソーダライト族アルミノ珪
酸塩、クリノプチロラィト、ヱリオラィト又はチャバサ
ィト等があげられ、これらは合成物又は天然物のいずれ
であってもよく、また使用に当り1種又は2種以上であ
っても差支えない。
Examples include A-type, Any of them may be used, and one type or two or more types may be used.

発泡体の用途にもよるが、本発明において、かかるゼオ
ラィトのうち、珪酸アルカリガラスを水熱処理して水ガ
ラスを製造する際に副生するゼオライトが有利に適用で
きる。
Although it depends on the use of the foam, in the present invention, among such zeolites, zeolite that is produced as a by-product when hydrothermally treating alkali silicate glass to produce water glass can be advantageously applied.

かかる原料からなる混合物の組成は加熱発泡条件および
発泡体の所望する特性によって比較的許容される割合が
とられるけれども、少なくともガラス粉末に対して重量
で発泡剤1〜10%、珪酸アルカリが固形分として1〜
40%およびゼオラィトが1〜50%の範囲、即ち重量
部で表わすと、ガラス粉末10の重量部に対し、発泡剤
1〜10重量部、珪酸アルカリが固形分として1〜4の
重量部およびゼオラィト1〜5の重量部の範囲にあり、
特に発泡剤が3〜7%、珪酸アルカリ2〜10%および
ゼオラィト2〜20%の割合が好ましい。
Although the composition of the mixture consisting of such raw materials is set in a relatively permissible proportion depending on the heating and foaming conditions and the desired properties of the foam, at least 1 to 10% of the blowing agent and alkali silicate by weight based on the glass powder and the solid content of the alkali silicate should be determined. As 1~
40% and zeolite in the range of 1 to 50%, that is, expressed in parts by weight, based on 10 parts by weight of glass powder, 1 to 10 parts by weight of blowing agent, 1 to 4 parts by weight of alkali silicate as solid content, and zeolite. in the range of 1 to 5 parts by weight;
Particularly preferred proportions are 3 to 7% blowing agent, 2 to 10% alkali silicate, and 2 to 20% zeolite.

この理由は、前記組成範囲をはずれると発泡温度が高く
なるか又は逆に低くなりすぎて加熱条件や操作の制御の
みでは品質良好なガラス発泡体が得られなくなるからで
ある。
The reason for this is that when the composition is outside the above range, the foaming temperature becomes too high or too low, making it impossible to obtain a glass foam of good quality only by controlling heating conditions and operations.

かかる混合物を所望の形に造粒又は成型に加熱焼成する
がその所望の大きさの造粒又は成型にあたり、必要に応
じて水又は有機もしくは無機質結合剤を用いる。
The mixture is granulated or molded into a desired shape by heating and baking, and water or an organic or inorganic binder is used as necessary to granulate or mold the mixture into the desired size.

有機質結合剤としてはポリビニルアルコール、CMC、
ポリアクリルアミド、ポリアクリル酸ソーダ又はゴムラ
テックスの如き水溶性高分子などが適当であり、無機質
結合剤としては、蓮酸アルカリ、ベントナィトなどがあ
げられる。更に、前記造粒又は成型に際し、加熱発泡の
操作如何によっては発泡体が互に融着等によって結合す
る場合が生じることがあるので、これを防ぐため、少な
くとも加熱発泡温度以下では溶融又は嘘結しない不活性
な粉末で造粒物等を被着することが好ましい。
As the organic binder, polyvinyl alcohol, CMC,
Water-soluble polymers such as polyacrylamide, sodium polyacrylate or rubber latex are suitable, and examples of inorganic binders include alkali lotus acid and bentonite. Furthermore, during the above-mentioned granulation or molding, depending on the heating and foaming operation, foams may be bonded to each other by fusion, etc., so in order to prevent this, melting or false condensation is required at least below the heating and foaming temperature. It is preferable to coat the granules, etc. with an inert powder that does not contain any carbon dioxide.

このような粉末は例えばアルミナマグネシア、酸化鉄等
の金属酸化物、珪酸カルシウム、鉄鋼又は非鉄製錬スラ
グ、粘土類、シャモツト、セメント類、フライアツシュ
等の1種又は2種以上があげられるがこれらに特に限定
される必要はない。なお、必要に応じて各種着色無機顔
料、無機ファイバー等を添加することもできる。かくて
、造粒又は成型された混合物は、必要に応じて乾燥処理
を行った後、適当な加熱炉により加熱発泡される。発泡
条件としては、雰囲気温度720〜8500Cが発泡温
度城であり、この温度で少なくとも5分以上保持される
ように設定することを要する。この温度以上では焼結あ
るいは軟化が生じる傾向にあって良好な発泡体は得られ
ない。また、加熱方法は静的又は動的操作のいずれでも
よく、従って炉としては静贋式加熱炉、トンネルキルン
又はロータリーキルン等が適当である。しかし、本発明
においては、特にロータリーキルンを用いた粒状発泡体
の製造が最も好ましい方法としてあげられる。本発明に
かかる無機ガラス質発泡体は、条件にもよるが多くの場
合、見掛け比重0.15〜0.0運適気泡率30〜80
%、泡径0.1〜2側、粒状物の場合の一点強度は2k
9以上、および熱伝導率0.04〜0.07Kcal′
の・hr・qCの特性を有し、各種分野の断熱材、吸音
材にすぐれものとして提供することができる。
Examples of such powders include one or more of alumina magnesia, metal oxides such as iron oxide, calcium silicate, iron and steel or non-ferrous smelting slag, clays, chamots, cements, fly ash, etc. There is no need to be particularly limited. Note that various colored inorganic pigments, inorganic fibers, etc. may be added as necessary. The granulated or molded mixture is subjected to a drying treatment if necessary, and then heated and foamed in a suitable heating furnace. As for the foaming conditions, the ambient temperature is 720 to 8500C, which is the temperature limit for foaming, and it is necessary to set the temperature so that it is maintained at this temperature for at least 5 minutes. Above this temperature, sintering or softening tends to occur, making it impossible to obtain a good foam. Further, the heating method may be either static or dynamic operation, and therefore, a static heating furnace, a tunnel kiln, a rotary kiln, etc. are suitable as the furnace. However, in the present invention, the most preferable method is to produce a granular foam using a rotary kiln. The inorganic vitreous foam according to the present invention has an apparent specific gravity of 0.15 to 0.0 and a cell ratio of 30 to 80 in most cases, depending on the conditions.
%, bubble diameter 0.1 to 2 side, single point strength in case of granular material is 2k
9 or more, and thermal conductivity 0.04 to 0.07 Kcal'
It has the characteristics of .hr.qC, and can be provided as an excellent heat insulating material and sound absorbing material in various fields.

以下実施例をあげて更に具体的に説明する。実施例 1
各種の廃棄ガラスを200メッシュ全通に粉砕し、表1
に示す所定の割合で発泡剤を添加した混合物、さらに珪
酸アルカリ又は/およびゼオラィトを添加した混合物を
それぞれ平均粒径5肌に造粒した後、ポリビニルアルコ
ール溶液(3重量%)をバインダーとしてアルミナ粉末
をコーティングした。次いでロータリーキルンを用いて
、熱と混合物とを向流で供給し、排ガス温度500oo
、入口ガス温度850ooに、平均滞留時間は20分間
に設定して、加熱処理したところ、ガラス質発泡体が得
られた。その条件と結果は表1の通りである。得られた
発泡体は互に結合したものは実質的になく、平均粒径8
〜1仇舷であり、その特性をみたところ、表1の結果が
得られた。表1 在天1)ゼオラィトは、無水珪酸アルカリガラスを水熱
処理して水力ラスを製造する際に副生した結晶性アルミ
ノ珪酸ソ一ダ粉末である。
The present invention will be described in more detail below with reference to Examples. Example 1
Various types of waste glass were crushed into 200 mesh pieces, and Table 1
After granulating a mixture to which a blowing agent was added in the prescribed proportions shown in Figure 1 and a mixture to which alkali silicate and/or zeolite were added to an average particle size of 5, alumina powder was added using a polyvinyl alcohol solution (3% by weight) as a binder. coated. Then, using a rotary kiln, heat and mixture are supplied in countercurrent, and the exhaust gas temperature is 500 oo
A glassy foam was obtained by heat treatment at an inlet gas temperature of 850 oo and an average residence time of 20 minutes. The conditions and results are shown in Table 1. The resulting foam was substantially free of interconnections and had an average particle size of 8.
-1 ship length, and when we looked at its characteristics, the results shown in Table 1 were obtained. Table 1: 1) Zeolite is a crystalline aluminosilicate soda powder that is produced as a by-product when hydrothermally treating anhydrous silicate alkali glass to produce hydraulic lath.

妾2)泡の外観の評価は下記のように5段階評価とした
。・非常に安定している 1 1安定している 2
1普 通 3・泡径にばらつきあり 4 ・泡径が
非常にバラッィている。実施例 2褐色びんガラス粉末
(200メッシュ全通)10礎部に、発泡剤、JIS3
号珪酸ソーダおよび天然ゼオラィトの各所定量を配合し
て混合した後、平均粒径5柳に造粒し乾燥して造粒物を
得た。
2) The appearance of bubbles was evaluated on a 5-level scale as shown below.・Very stable 1 1 Stable 2
1. Normal 3. Bubble diameter varies. 4. Bubble diameter varies greatly. Example 2 Brown bottle glass powder (200 mesh all through) 10 In the base part, foaming agent, JIS 3
After blending and mixing predetermined amounts of sodium silicate and natural zeolite, the mixture was granulated to an average particle size of 5 Yanagi and dried to obtain a granulated product.

次いでこの造粒物を温度790±1000において20
分間加熱したところ、平均粒径8〜1仇奴の均一なガラ
ス発泡体を得た。この発泡体の特性をみたところ、表2
の結果が得られた。表2 実施例 3 褐色びんガラス粉末(100メッシュ全通)10礎部に
炭酸カルシウム4部およびJIS3号珪酸ソーダと合成
ゼオラィトの所定量を配合して原料混合物を調製し実施
例1と同様に造粒した。
Next, this granulated material was heated at a temperature of 790±1000 for 20
After heating for a minute, a uniform glass foam with an average particle size of 8 to 1 mm was obtained. Looking at the properties of this foam, Table 2
The results were obtained. Table 2 Example 3 A raw material mixture was prepared by blending 4 parts of calcium carbonate, JIS No. 3 sodium silicate, and a predetermined amount of synthetic zeolite with 10 bases of brown bottle glass powder (100 mesh all through), and the same procedure as in Example 1 was carried out. It was grainy.

次いで、この造粒物にアルミナとボルトランドセメント
の1;1の混合物をアラビアゴムをバインダーとして添
加してその表面を被覆した。この被覆混合物を温度75
0±500「 800土500、850±5℃の各温度
でそれぞれ20分間加熱したところガラス発泡体が得ら
れた。その特性をみたところ、表3の結果が得られた。
一方、上記の結果に基づいて、前記混合物(珪酸ソーダ
7.6%、ゼオラィト10%)を実施例1と同様の条件
でロータリーキルンにて加熱したところ、平均粒径8〜
9肌、見掛比重0.34強度4〜12k9/個、熱伝導
率0.06Kcal′の・hr・℃、蓮通気泡率63%
、および吸音率36%(1000日2)の均一性のある
ガラス発泡体が得られた。
Next, a 1:1 mixture of alumina and Bortland cement was added to the granulated material using gum arabic as a binder to coat the surface thereof. This coating mixture was heated to 75°C.
A glass foam was obtained by heating at temperatures of 0±500°C and 850°C±5°C for 20 minutes. When the properties were examined, the results shown in Table 3 were obtained.
On the other hand, based on the above results, when the mixture (sodium silicate 7.6%, zeolite 10%) was heated in a rotary kiln under the same conditions as in Example 1, the average particle size was 8.
9 skin, apparent specific gravity 0.34 strength 4-12k9/piece, thermal conductivity 0.06 Kcal'・hr・℃, lotus ventilation foam rate 63%
A homogeneous glass foam with a sound absorption coefficient of 36% (1000 days 2) was obtained.

・鞘熱伝導率および吸音率は発泡体を珪酸ソーダと蓮フ
ッ化ソーダを用いて成型板にし測定した。
- Sheath thermal conductivity and sound absorption coefficient were measured by molding the foam into a plate using sodium silicate and sodium fluoride.

表3 実施例 4 各種の廃棄ガラス粉末(200メッシュ全通)100部
にフロリダ産りん鉱石1碇部‘こJIS3号珪酸ソーダ
および水ガラスからの副生ゼオラィトを所定量配合して
15仇松×10仇吻×3仇吻のスラブをモールドーごて
成型した。
Table 3 Example 4 100 parts of various waste glass powders (all 200 mesh) were mixed with 1 part of Florida phosphate rock, JIS No. 3 sodium silicate, and a predetermined amount of by-product zeolite from water glass to produce 15 pieces of waste glass powder. A slab of 10 lengths x 3 lengths was formed using a mold trowel.

次いでこれを790±10℃の加熱雰園気で3船ご間加
熱処理したところガラス質発泡体が得られた。その特性
をみたところ表4の結果が得られた。4 なお見掛比重、強度「熱伝導率、運通気泡率および吸青
率は次の方法による。
Next, this was heat-treated in a heating atmosphere of 790±10° C. in three ships, and a vitreous foam was obtained. When we looked at its characteristics, the results shown in Table 4 were obtained. 4 Apparent specific gravity, strength, thermal conductivity, bubble transport rate, and blue absorption rate are determined by the following methods.

見掛比重:重量測定し計算で求めた体積を用いて計算す
る。
Apparent specific gravity: Calculated using the volume determined by weight measurement.

強 度:木星式硬度計による点強度Strength: Point strength measured by Jupiter hardness tester

Claims (1)

【特許請求の範囲】 1 ガラス粉末100重量部に対し、発泡剤1〜10重
量部、珪酸アルカリが固形分として1〜40重量部およ
びゼオライト1〜50重量部の割合で配合した混合物を
加熱発泡させることを特徴とする無機ガラス質発泡体の
製造法。 2 発泡剤が炭酸ソーダ、炭酸カルシウム、炭酸マグネ
シウム、炭酸バリウム、ドロマイト、燐鉱石又は二酸化
マンガンから選ばれた1種又は2種以上の粉末である特
許請求の範囲第1項記載の無機ガラス質発泡体の製造法
。 3 加熱発泡は温度720〜850℃の範囲で行わせる
ことを特徴とする特許請求の範囲第1項記載の無機ガラ
ス質発泡体の製造法。 4 加熱発泡は粒状化した混合物をロータリーキルンで
行わせることを特徴とする特許請求の範囲第1項又は第
3項記載の無機ガラス質発泡体の製造法。 5 粒状化した混合物は発泡温度以下では溶融又は焼結
等しない不活性な粉末で被覆されていることを特徴とす
る特許請求の範囲第1項から第4項までの各項の何れか
に記載の無機ガラス質発泡体の製造法。
[Claims] 1 A mixture of 100 parts by weight of glass powder, 1 to 10 parts by weight of a blowing agent, 1 to 40 parts by weight of alkali silicate as a solid content, and 1 to 50 parts by weight of zeolite is heated and foamed. A method for producing an inorganic vitreous foam characterized by: 2. The inorganic vitreous foam according to claim 1, wherein the foaming agent is one or more powders selected from soda carbonate, calcium carbonate, magnesium carbonate, barium carbonate, dolomite, phosphate rock, or manganese dioxide. How the body is manufactured. 3. The method for producing an inorganic vitreous foam according to claim 1, wherein the heating and foaming is carried out at a temperature in the range of 720 to 850°C. 4. The method for producing an inorganic vitreous foam according to claim 1 or 3, characterized in that the heating and foaming is carried out using a rotary kiln for the granulated mixture. 5. The granulated mixture is coated with an inert powder that does not melt or sinter at temperatures below the foaming temperature, as described in any one of claims 1 to 4. A method for producing an inorganic vitreous foam.
JP16191480A 1980-11-19 1980-11-19 Method for manufacturing inorganic vitreous foam Expired JPS605534B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16191480A JPS605534B2 (en) 1980-11-19 1980-11-19 Method for manufacturing inorganic vitreous foam

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16191480A JPS605534B2 (en) 1980-11-19 1980-11-19 Method for manufacturing inorganic vitreous foam

Publications (2)

Publication Number Publication Date
JPS5788042A JPS5788042A (en) 1982-06-01
JPS605534B2 true JPS605534B2 (en) 1985-02-12

Family

ID=15744417

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16191480A Expired JPS605534B2 (en) 1980-11-19 1980-11-19 Method for manufacturing inorganic vitreous foam

Country Status (1)

Country Link
JP (1) JPS605534B2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59501824A (en) * 1982-09-30 1984-11-01 アトランテイツク リツチフイ−ルド カンパニ− Alkali-resistant glass bodies and fibers
JPS63252932A (en) * 1987-04-06 1988-10-20 Nippon Funen Kk Production of foamed glass board
JP6350661B2 (en) * 2014-07-11 2018-07-04 株式会社村田製作所 Porous body and heat storage device
CN107417073B (en) * 2017-09-26 2020-12-11 重庆巨鼎玻璃有限公司 Preparation method of building sound-insulation high-porosity foam glass
RU2726091C1 (en) * 2019-07-23 2020-07-09 Федеральное государственное бюджетное образовательное учреждение высшего образования Иркутский государственный университет путей сообщения (ФГБОУ ВО ИрГУПС) Charge for environmentally safe production of foamed glass
RU2723886C1 (en) * 2019-09-25 2020-06-18 Акционерное общество "Якутский государственный проектный, научно-исследовательский институт строительства" Method of producing granular foamed glass-ceramic filler

Also Published As

Publication number Publication date
JPS5788042A (en) 1982-06-01

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