JPS60216843A - Catalytic filter for oxidizing reducing gas - Google Patents
Catalytic filter for oxidizing reducing gasInfo
- Publication number
- JPS60216843A JPS60216843A JP59066524A JP6652484A JPS60216843A JP S60216843 A JPS60216843 A JP S60216843A JP 59066524 A JP59066524 A JP 59066524A JP 6652484 A JP6652484 A JP 6652484A JP S60216843 A JPS60216843 A JP S60216843A
- Authority
- JP
- Japan
- Prior art keywords
- film
- filter
- particles
- chloride
- reducing gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000003197 catalytic effect Effects 0.000 title description 3
- 230000001590 oxidative effect Effects 0.000 title description 2
- 239000002245 particle Substances 0.000 claims abstract description 17
- 239000000835 fiber Substances 0.000 claims abstract description 14
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000010419 fine particle Substances 0.000 claims abstract description 11
- 235000019504 cigarettes Nutrition 0.000 claims abstract description 9
- 230000003647 oxidation Effects 0.000 claims abstract description 9
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 9
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 9
- 239000000779 smoke Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000460 chlorine Substances 0.000 claims abstract description 3
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 3
- 239000008367 deionised water Substances 0.000 claims abstract description 3
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 22
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 8
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 8
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 239000007789 gas Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 3
- 230000000391 smoking effect Effects 0.000 description 3
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229960002715 nicotine Drugs 0.000 description 2
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 101000995861 Arabidopsis thaliana Regulatory protein NPR1 Proteins 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229910052705 radium Inorganic materials 0.000 description 1
- HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】
本発明は、アルミナ微粒子の表面に酸化触媒である白金
やパラジウムの皮膜を形成し、有機繊維などにこの皮膜
微粒子を１ふし、一定の形状にして気体流路中に配する
、タバコの煙や空気中の一酸化炭素などを酸化除去する
、還元性ガス酸化触媒フィルタに関する。Detailed Description of the Invention The present invention involves forming a film of platinum or palladium, which is an oxidation catalyst, on the surface of fine alumina particles, applying one film of this film to organic fibers, etc., and forming the film into a certain shape into a gas flow path. This invention relates to a reducing gas oxidation catalyst filter that oxidizes and removes cigarette smoke, carbon monoxide, etc. from the air.
酸化スズや酸化鉄は活性化すると還元性ガスを酸化吸着
するために、広くセンサとして使用されているが、酸化
除去のフィルタには技術的に難かしく、僅かに実願昭５
６−１９４３６７号（本願発明者）に散見されるだけで
ある。触媒として周知な白金やパラジウムでアルミナ微
粒子の表面に皮膜を形成し、有機繊維などにこの皮膜微
粒子をまぶす酸化触媒フィルタを以下図面に基づいて詳
しく説明する。When activated, tin oxide and iron oxide oxidize and adsorb reducing gases, so they are widely used as sensors.
No. 6-194367 (inventor). An oxidation catalyst filter in which a film is formed on the surface of fine alumina particles using platinum or palladium, which are well-known catalysts, and the film is coated on organic fibers will be described below in detail with reference to the drawings.
粒径が１ミクロン以下の酸化アルミニウム粉体を、白金
やパラジウム塩化物とともに、加熱撹拌している脱イオ
ン水内に入れて混和する。酸化アルミニウムが１００重
量に対して白金やパラジウムの塩化物は１〜５重量の割
合である。一定時間後にこれを取り出して観県すると、
アルミナ微粒子の表面は析出した白金やパラジウムの塩
化物からなる皮膜が形成されている。この皮膜微粒子を
５０１ＪＣ〜６００°Ｃで１時間程加熱すると、皮膜か
ら塩素が脱離して白金やパラジウムの原子だけの皮膜に
なる。白金やパラジウムだけの皮膜微粒子をフィルタを
構成する有機繊維などにまぶし、繊維表面に多数の皮膜
微粒子を付着する。微粒子の表面エネルギーは非常に大
きく、単に繊維にまぶすたけで微粒子は充分に繊維に付
着するが繊維と微粒子に互いに異なる静電荷を帯電させ
るか、或いは、皮膜微粒子の＃細氷浴液を繊維に塗布し
乾燥すれば一層微粒子の付着は強固になる○生産性は、
皮膜微粒子の濃縮水浴液内に繊維を漬けて乾燥するσ最
後の方式が優れる。いづれの方式にせよ、極めて多数の
皮膜微粒子を付着した繊維群を集合して適度の通気抵抗
を有するフィルタを形成する〇
第１図は喫煙具（１）のフィルタ（２）に採用したもの
で、煙草（３）に火を付けて差しこ与、吸気すれば一酸
化炭素を含む煙はこのフィルタ（２）を通過する。第２
図は煙草（３）本体にフィルタ（２）を装填したもので
あり、第５図は板状にフイ凸面を有するハニカム、スポ
ンジ等の気泡体などが用途に応じて選択される。Aluminum oxide powder with a particle size of 1 micron or less is mixed with platinum and palladium chloride in heated and stirred deionized water. The proportion of platinum or palladium chloride is 1 to 5 weight per 100 weight of aluminum oxide. If you take it out after a certain period of time and look at it,
A film made of precipitated platinum or palladium chloride is formed on the surface of the alumina fine particles. When the coated fine particles are heated at 501 JC to 600°C for about 1 hour, chlorine is removed from the coat, resulting in a coat consisting only of platinum and palladium atoms. Coating particles made only of platinum or palladium are sprinkled onto the organic fibers that make up the filter, and a large number of coating particles are attached to the fiber surface. The surface energy of fine particles is very large, and the fine particles will adhere to the fibers simply by sprinkling them on the fibers. If applied and dried, the adhesion of fine particles will become even stronger.Productivity is
The last method of σ, in which the fibers are soaked in a concentrated water bath containing film particles and dried, is superior. Regardless of the method, a group of fibers to which an extremely large number of film particles are attached is assembled to form a filter with appropriate ventilation resistance. 〇Figure 1 shows the filter adopted for filter (2) of smoking device (1). If you light a cigarette (3) and inhale, the smoke containing carbon monoxide will pass through the filter (2). Second
The figure shows a cigarette (3) in which the filter (2) is loaded, and in FIG. 5, a foam material such as a honeycomb or sponge having a plate-like convex surface is selected depending on the purpose.
次に作用について説明する。アルミナ微粒子の皮膜であ
る白金やパラジウムは触媒作用があり比表面積が大きい
ので、還元性ガスがこれに触れると直ちに酸化触媒作用
を生じ、このカスを酸化して無害化する。煙草（３）に
火を付けて鍋温の煙をフィルタ（２）に触れさせると、
煙に含まれる一酸化炭素は皮膜微粒子によって酸化され
、二酸化炭素になる。５％の一酸化炭素を含む気体をこ
のフィルタ（２）に通過させたところ、−酸化炭素は１
．５％と半減した。煙中の有害成分であるニコチンやタ
ールは繊維状粒子が多数付着しているために、単に一酸
化炭素の酸化だけでなく、ニコチンやタールをも効率良
く吸着し喫煙者の健康を大いに守る。第３図の空気清浄
器（４）は室内の空気を強制的にフィルタ（２）に送り
こむもので、空気中に増加した一酸化炭素やメタン、プ
ロパンなどの還元性カスを酸化除去する。Next, the effect will be explained. Platinum or palladium, which is a film of fine alumina particles, has a catalytic action and a large specific surface area, so when a reducing gas comes into contact with it, it immediately produces an oxidation catalytic action, oxidizing the residue and rendering it harmless. When you light a cigarette (3) and let the pot-temperature smoke touch the filter (2),
Carbon monoxide contained in smoke is oxidized by the film particles and becomes carbon dioxide. When a gas containing 5% carbon monoxide was passed through this filter (2), -carbon oxide was 1
．． It was halved to 5%. Nicotine and tar, which are harmful components in smoke, have many fibrous particles attached to them, so they not only oxidize carbon monoxide, but also efficiently adsorb nicotine and tar, greatly protecting the health of smokers. The air purifier (4) in FIG. 3 forcibly sends indoor air to the filter (2) to oxidize and remove reducing residues such as carbon monoxide, methane, and propane that have increased in the air.
費するに、本発明はアルミナ微粒子の表面に白金やノ（
ラジウムの皮膜を形成し、この皮膜微粒子を繊維などに
まぶしてフィルタを形成したため、煙草の煙中の一酸化
炭素などの還元性ガスを酸化触媒作用により酸化除去で
きる。In other words, the present invention provides platinum or metallization on the surface of fine alumina particles.
By forming a radium film and sprinkling fine particles of this film on fibers to form a filter, reducing gases such as carbon monoxide in cigarette smoke can be oxidized and removed by oxidation catalyst action.
図面は本発明実施の一例を示すもので、第１図は喫煙具
の縦断正面図、第２図は煙草自体のフィルタに採用した
時の一部切り欠き正面図、第５図は空気清浄器として使
用する場合の説明図である。
１・・喫煙具２・・フィルタ３・・煙草手続補正書
昭和９年を月〆２１」
昭和ｓ１年！ｌ）許願第４４′；２４号２、’ｎＲｑ％
’ｌＩ違ｒｔ４ｆｆｒ”ス勾筐イビＡｌｔ＄−フイ１Ｌ
９３、補正をする者
事件との関係朽１（七Ｉｃ後入
体冑ｉス峙１＋ｌ辱勅勢食へ餉１１３３％４、代理人
６補正により増加する発明の数丁Ｊ（
７、補正の対象
（９１１什）
（、ｅｆｌｔｍ＊９５ａ”ｔ’ｔｆｉＤ’−ｙｔ＋しり
ｘｉ＋ｔｌＪｓ、、ｓこｒＪソｍ；１３’ｂ。
）ｒｃ７）１’Ｊｙｖ３．ｒ７”Ｊ−１ｔｆ、ｘｔＬ＞
ｑ代１／１：１Ｉｔｃ’Ｌ＋Ｎ１ｚ６ｓ”ｉ−％７’ｔ
ａ’ｔｉｌｌｌＷ”２ｔ＆（、；ｃｒ１％ｊ≧、、ｌ−
Ｊ、７７ｔｃ９（１）ＱＸｌ：１イｌｉ’ｌＱＦ（し＋
ｘ−二（Ｉｌｑバー１１ｓ内乙ざ１１：ヒ１：イワＣ克
Ｌ〕
手続補正書
昭和少年ｒ月ｔｔｉ日
昭和Ｓ（１年′Ｐｌｔ！Ｔ−願第６信２４号２、４Ｃθ
ｌ’ｌ”Ｉ、＆ＶＦ５ｓｔ４−ｒ１’７／りせイｃｍｔ
フィ・し７３、補正をする者
事件との関係ｆｒ！￥出出血１
人１匙ネ′１宙とａ４−
４、代理人
６補正により増加する発明の数ｌ（
７、補正の対象
１ｎｌ＜４ｅｘ二ｙ＝＝、’ｉす＞ｌ正Ｖ３゜（１ン、
アルミ７仕シａ知−ｐζ４り）ご１む１１０ラシ゛うし
侵−１万１６１ルし、υ〜舎化ｑどｔ＜Ｓηよ緑倣十σ
浪詞、゛Ｌマ％ヱ、１ｔ・１・γが７〜會イヒ＾ｔＡＩ
Ｉフイ電しζ（９？、！１Ｌ−ｑｓ、＊＜４ｑ−ｔｔ”
ス所會ｔ’ＨＡ−ｙｔｔｂ７゜２、％３ｆｌＩＩＲｎｌ
＊才１’ｔ’ｉ’ｎ’５ｆｉＪ２１ｉ）−−−＋：ｉ’
ｌどＶＪ４ニア→り肇屑１１３゜
’Ｆｒ’ｋ＜匍Ｉπハ邦！し、贋ト・１ｄ旧１ｔ１録フ
ィルタヒ知り。
−名の１１シ徂：ｌ−１ｉ９不攻防中１・山Ｚイノ３、
ｅＲ＊１ｆ１１オ＋１’ＪＩ’７ｆ１’Ｑ’１３：Ｌｚ
−−−ｍ’ｌｊ＆３Ｎ；ｆＱ辿り卆薊１３゜
’”ｉｓ’：Ｌマフイ１しフｔ１η友１７ヤ゛、死・・
Ｉ距’ｉ＝＊”ｒｓ左の１）っ専Ｚ＠Ｌｌｒ（ｓへアＳ
ヒ私パ（十つ−姉イＣ。
ｔＬ’ｉＪ：／The drawings show an example of the implementation of the present invention. Fig. 1 is a longitudinal sectional front view of a smoking device, Fig. 2 is a partially cutaway front view when it is used as a filter for cigarettes, and Fig. 5 is an air purifier. FIG. 1.Smoking implements 2..Filter 3..Tobacco procedure amendment book 1939, end of month 21" Showa s1! l) Application No. 44'; 24 No. 2, 'nRq%
'lI difference rt4ffr' Sumagaku Ibi Alt$-Fi 1L
93. Relationship with the person making the amendment Target (911) (,efltm*95a"t'tfiD'-yt+shirixi+tlJs,,sorJsom;13'b.)rc7)1'Jyv3.r7"J-1tf, xtL>
q 1/1:1Itc'L+N1z6s"i-%7't
a'tillW"2t&(,;cr1%j≧,,l-
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x-2 (Ilq bar 11s in Otsuza 11: Hi 1: Iwa C K L) Procedural amendment Showa Shonen r Month tti Day Showa S (1 year' Plt! T-Gan No. 6 Signal No. 24 2, 4Cθ
l'l''I, &VF5st4-r1'7/Riseicmt
Fi・shi73, relationship with the person making the amendment fr! ￥ Bleeding 1 person 1 spoon '1 space and a4-4, Number of inventions increased by agent 6 amendment l (7, Target of correction 1nl<4ex2y==, 'isu>l positive V3゜( 1 n,
Aluminum 7 structure a knowledge - p ζ 4) Go 110 years ago - 10,161 years
Roni,゛Lma%ヱ, 1t・1・γ is 7～kaihi＾tAI
I feed ζ (9?, !1L-qs, *<4q-tt”
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ldo VJ4 Near → Ri 过屑 113゜'Fr'k＜匍Iπhakuni! I know of a fake/1d old 1t1 record filter. -Name's 11th side: l-1i9 non-attack/defense middle 1, Yama Z Ino 3,
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Claims (3)
を形成し、繊維などにこの皮膜微粒子をまぶしてなる、
還元性ガス酸化触媒フィルタ。(1) A film of platinum or palladium is formed on the surface of fine alumina particles, and fibers, etc. are coated with this film.
Reducing gas oxidation catalyst filter.
てアルミナ微粒子を混和し、表面に塩化皮膜が析出した
アルミナ微粒子を取りだして加熱し、この塩化皮膜から
塩素を脱離して活性化した白金やパラジウムの皮膜を形
成し繊維などにこの皮膜微粒子をまぶしてなる、還元性
ガス酸化触媒フィルタ。(2) Mix platinum chloride, palladium chloride, and alumina fine particles in deionized water, take out the alumina fine particles with a chloride film deposited on the surface, heat them, and remove chlorine from the chloride film to activate the platinum and alumina particles. A reducing gas oxidation catalyst filter that forms a palladium film and coats fibers with fine particles of this film.
徴する特許請求の範囲第２項記載の還元性ガス酸化触媒
フィルタ。(3) The reducing gas oxidation catalyst filter according to claim 2, which is used in a cigarette filter and is characterized by reducing carbon monoxide in smoke.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59066524A JPS60216843A (en) | 1984-04-03 | 1984-04-03 | Catalytic filter for oxidizing reducing gas |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59066524A JPS60216843A (en) | 1984-04-03 | 1984-04-03 | Catalytic filter for oxidizing reducing gas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS60216843A true JPS60216843A (en) | 1985-10-30 |
Family
ID=13318344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59066524A Pending JPS60216843A (en) | 1984-04-03 | 1984-04-03 | Catalytic filter for oxidizing reducing gas |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60216843A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0658320A2 (en) * | 1993-12-14 | 1995-06-21 | Rothmans International Services Limited | Smoking article and filter therefor |
| WO1998055211A1 (en) * | 1997-06-04 | 1998-12-10 | Wenyan Cui | A compound for removing harmful components from cigarette smoking and a method for preparing the compound |
| EP0913100A3 (en) * | 1997-10-30 | 2000-08-23 | British-American Tobacco (Germany) GmbH | Method for applying substances to a filter material |
| JP2007527782A (en) * | 2003-06-13 | 2007-10-04 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Catalysts for reducing carbon monoxide and nitric oxide from cigarette mainstream smoke. |
| WO2008018617A1 (en) * | 2006-08-10 | 2008-02-14 | Daicel Chemical Industries, Ltd. | Cigarette filter |
-
1984
- 1984-04-03 JP JP59066524A patent/JPS60216843A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0658320A2 (en) * | 1993-12-14 | 1995-06-21 | Rothmans International Services Limited | Smoking article and filter therefor |
| EP0658320A3 (en) * | 1993-12-14 | 1996-07-03 | Rothmans International Ltd | Smoking article and filter therefor. |
| WO1998055211A1 (en) * | 1997-06-04 | 1998-12-10 | Wenyan Cui | A compound for removing harmful components from cigarette smoking and a method for preparing the compound |
| EP0913100A3 (en) * | 1997-10-30 | 2000-08-23 | British-American Tobacco (Germany) GmbH | Method for applying substances to a filter material |
| JP2007527782A (en) * | 2003-06-13 | 2007-10-04 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Catalysts for reducing carbon monoxide and nitric oxide from cigarette mainstream smoke. |
| JP4773956B2 (en) * | 2003-06-13 | 2011-09-14 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Catalysts for reducing carbon monoxide and nitric oxide from cigarette mainstream smoke. |
| WO2008018617A1 (en) * | 2006-08-10 | 2008-02-14 | Daicel Chemical Industries, Ltd. | Cigarette filter |
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