JPS60194179A - Anti-bacterial processing of fiber material - Google Patents
Anti-bacterial processing of fiber materialInfo
- Publication number
- JPS60194179A JPS60194179A JP4562084A JP4562084A JPS60194179A JP S60194179 A JPS60194179 A JP S60194179A JP 4562084 A JP4562084 A JP 4562084A JP 4562084 A JP4562084 A JP 4562084A JP S60194179 A JPS60194179 A JP S60194179A
- Authority
- JP
- Japan
- Prior art keywords
- polymer containing
- fiber material
- anionic
- polyoxyalkyl
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
技術分野
本発明は、繊維材料に抗菌効果を付与する加工方法に関
し、特に繊維材料に吸水制電防汚性と同時に耐久性ある
抗菌性能を付与せしめることのできる加工方法に関する
。[Detailed Description of the Invention] Technical Field The present invention relates to a processing method for imparting antibacterial effects to textile materials, and in particular to a processing method capable of imparting durable antibacterial properties to textile materials as well as water absorption, antistatic and antifouling properties. Regarding.
従来技術
最近になって、シャツや肌着、ブラック、ファンデーシ
ョン類に合成繊維や合繊混紡繊維が多く使われるように
な9、衣類に対する抗菌・防カビ処理の必要性が増大し
た。天然繊維や混紡品は、保水性か大きく、発汗時には
乾燥までに時間が長くかかシ、微生物作用の結果臭気を
生ずる場合かある。−力、合成繊維では、吸水、吸汗性
は無いが、乾燥性は良好である。また、機械的性質に優
れ、耐洗濯性にも強い。従って、天然繊維と合成繊維の
両者の長所を併せ持つ繊維が理想である。2. Prior Art Recently, synthetic fibers and synthetic fiber blends have come into widespread use in shirts, underwear, black coats, and foundations9, increasing the need for antibacterial and antifungal treatments for clothing. Natural fibers and blended fabrics have a high water retention capacity, take a long time to dry when sweating, and may produce odors as a result of microbial action. - Synthetic fibers have no water or sweat absorption properties, but have good drying properties. It also has excellent mechanical properties and is resistant to washing. Therefore, fibers that combine the advantages of both natural fibers and synthetic fibers are ideal.
我々の周囲には、様々な細菌やカビが存在している。高
温多湿な環境下では、それらの繁殖が特に活発になバ水
虫に侵されたシ、腐敗発酵現象を起こしたシ、不快な臭
気を発生したシする。汗くさい臭いが生ずるのも、細菌
の作用による。汗そのものには臭気は無いのに、皮膚表
面の汗や下着、靴下などに吸収された汗に細菌類が繁殖
して、臭いの原因となる。微生物による弊害は悪臭だけ
でなく、人体および被服類に対して、脆化変色、伝染性
疾患、皮膚炎、水虫等の悪影響を与える。Various bacteria and molds exist around us. In a hot and humid environment, their reproduction becomes particularly active, resulting in infections caused by athlete's foot, rotting and fermentation, and unpleasant odors. The sweaty smell is also caused by the action of bacteria. Sweat itself has no odor, but bacteria breeds in the sweat on the surface of the skin and in sweat absorbed by underwear, socks, etc., causing odor. The harmful effects of microorganisms include not only bad odors, but also adverse effects on the human body and clothing, such as brittleness and discoloration, infectious diseases, dermatitis, and athlete's foot.
これらの微生物による弊害を防ぐ抗菌加工として要求さ
れる事項は、
1)抗菌効果が大きいこと、
2)耐久性のあること、
3)人体生理機能に影響を及はさないこと、4)処理材
料を損傷せず、外観を損なわないこと、5)処理方法が
簡単で加工賃の安価なこと、などである。The requirements for antibacterial processing to prevent the harmful effects of these microorganisms are: 1) high antibacterial effects, 2) durability, 3) no impact on human physiological functions, and 4) treated materials. 5) The processing method is simple and the processing fee is low.
このような抗菌加工製品の普及はいまだに不十分であシ
、このような単一機能では商品価値は小さく、複合化し
た機能を持つものが消費者の要求を満たすものと考えら
れる。また抗菌加工は、ポリエステル、ナイロン、アク
リル等の合成繊維に対する適用例が少なく、加工効果に
耐久性が出ないことに加えて、これらの疎水性繊維特有
の吸水性が低い、汚れが脱落し離い、n電気が起き易い
等の欠点があシ、これらを容易に機能改質出来ないとと
も商品化を妨げる原因である。The spread of such antibacterial processed products is still insufficient, and products with such a single function have little commercial value, and it is thought that products with multiple functions will satisfy consumer demands. In addition, antibacterial processing is rarely applied to synthetic fibers such as polyester, nylon, and acrylic, and in addition to the lack of durability in the processing effect, these hydrophobic fibers have low water absorption and stains can easily fall off and become detached. There are drawbacks such as the tendency to generate electricity, and the fact that these cannot be easily modified in function is a cause of hindering commercialization.
繊維材料に抗菌性能を付与する加工方法&;j 1特に
木綿等天然繊維への応用例が多い。例えば、特開昭57
−51874には、下記の如きオルガノシリコン等の4
級アンモニウム塩を吸着させたカーペットの製造方法が
開示されている。特に、下記のシランカッシリング剤、
?H31■
(CH,O)、5t(CH2)3−N−CnH2n+1
cx。Processing method for imparting antibacterial properties to textile materials &;j 1 There are many applications, especially to natural fibers such as cotton. For example, JP-A-57
-51874 contains 4 types of organosilicon as shown below.
A method of manufacturing a carpet having adsorbed grade ammonium salts is disclosed. In particular, the following silane cassilling agents? H31■ (CH,O), 5t(CH2)3-N-CnH2n+1
cx.
CH5
は水の存在下における脱メチルアルコール反応によシ架
橋して、耐久性ある高分子物質を形成する。CH5 crosslinks by demethylalcohol reaction in the presence of water to form a durable polymeric material.
力でオン性化合物が細菌、カビ類の生育を抑制すること
は、古くから知られているが、これらを単に繊維に付着
させただけでは洗潅によシ脱落し、その効果は失われる
。シリコン化合物の応用は、その架橋性を利用した耐久
性向上に意義がある。It has been known for a long time that onic compounds can suppress the growth of bacteria and mold by applying force, but if these are simply attached to fibers, they will fall off during washing and their effectiveness will be lost. The application of silicon compounds is significant in improving durability by utilizing their crosslinking properties.
また、5−クロロ−2−(2,4−ジクロロフェノキシ
)フェノールを繊維製品の仕上加工の段階に用い、繊維
原糸の内部まで浸透させ、恒久的殺菌、防カビ、防臭機
能を与えることができる。また金楓イオンの殺菌性を利
用するものとして、アクリロニトリル系繊維に銅キレー
トを形成させ、銅イオンの効果によシ、防菌、防カビ効
果を付与する方法が知られている。In addition, 5-chloro-2-(2,4-dichlorophenoxy)phenol can be used in the finishing process of textile products to penetrate deep into the fiber filaments and provide permanent sterilization, anti-mold, and deodorizing functions. can. Furthermore, as a method of utilizing the bactericidal properties of Kaede ions, a method is known in which a copper chelate is formed in acrylonitrile-based fibers to impart antibacterial, antibacterial, and antifungal effects to the copper ions.
発明の目的
本発明の目的は、合成繊維材料もしくはその混紡、混繊
品に耐久性のある抗菌性を付与し、しかも同時に耐久性
のある制電、吸水、防汚性を付与するという複合化した
機能改質繊維製品を与えることのできる加工方法を提供
することである。Purpose of the Invention The purpose of the present invention is to provide a synthetic fiber material, a blend thereof, or a blended fiber product with durable antibacterial properties, and at the same time with durable antistatic, water absorption, and antifouling properties. It is an object of the present invention to provide a processing method that can provide functionally modified fiber products.
発明の構成
本発明は、アニオン基を含む高分子重合体を繊維材料上
に固着し、ついでこの繊維材料を下記(X)もしくは〔
Y〕の構造式を有する化合物、以下余白
(式中nは正の整数を表わす)
の水溶液で処理することを特徴とする繊維材料の抗菌加
工方法を提供する。Structure of the Invention The present invention involves fixing a high molecular weight polymer containing anionic groups onto a fiber material, and then applying the following (X) or [
Provided is an antibacterial processing method for textile materials, which comprises treating with an aqueous solution of a compound having the structural formula Y], hereinafter (in the formula, n represents a positive integer).
発明の構成の具体的説明
アニオン基を含む高分子重合体を繊維材料に固着するた
めの方法としては、つぎの方法がある。Detailed Description of the Structure of the Invention The following method is available as a method for fixing a high molecular weight polymer containing an anionic group to a fiber material.
即ち、
A:ポリオキシアルキル基を含有するポリエステル重合
体とポリオキシアルキル基とアニオン基を含有するポリ
エステル重合体とによシ同浴で処理する方法、
B:アニオン基を含有する水溶性反応型ウレタン樹脂に
よシパッドキュア一方法を用いて処理する方法、
C:上記Aの方法によシ加工処理後、ついで上記Bの方
法により加工処理する方法、
である。これら、A−Cの方法でアニオン基を含む高分
子重合体を繊維上に固着した後、構造式〔X〕もしくは
〔Y〕で示される化合物の水溶液で処理する。That is, A: A method in which a polyester polymer containing a polyoxyalkyl group and a polyester polymer containing a polyoxyalkyl group and an anionic group are treated in the same bath; B: A water-soluble reactive type containing an anionic group. A method in which the urethane resin is treated using a pad curing method; C: A method in which the resin is processed by the above method A and then processed by the above method B. After the high molecular weight polymer containing anionic groups is fixed onto the fibers by the method A to C, the fibers are treated with an aqueous solution of a compound represented by the structural formula [X] or [Y].
Aの加工方法は通常の染色条件下に行うことができ、重
合体の使用量はそれぞれ0.50Wf〜5%owfであ
る。Processing method A can be carried out under normal dyeing conditions, and the amount of polymer used is 0.50 Wf to 5% OWF, respectively.
Bの加工方法は繊維材料をアニオン基を含有する水溶性
反応型ウレタン樹脂の3〜15チ水溶液に浸し、マング
ルで絞った後、120〜180℃で50秒〜200秒間
の処理を行なうものである。Processing method B involves soaking the fiber material in a 3-15% aqueous solution of a water-soluble reactive urethane resin containing anionic groups, squeezing it with a mangle, and then treating it at 120-180°C for 50-200 seconds. be.
化合物[Xlもしくは〔Y〕の加工方法は、上記A、B
又はC処理後、繊維材料を〔X〕もしくは〔Y〕の0.
5〜20チ水溶液に浸漬し、室温乃至100℃の温度で
5分〜1時間処理を行なう。The processing method of the compound [Xl or [Y] is the above-mentioned A and B.
Or after C treatment, the fiber material is treated with [X] or [Y] of 0.
The sample is immersed in an aqueous solution for 5 to 20 hours and treated at a temperature of room temperature to 100°C for 5 minutes to 1 hour.
前述したポリオキシアルキル基とアニオン基を含むポリ
エステル重合体は、吸水、防汚性能を付与する目的のみ
ならず、塩基性化合物〔X〕もしくは(Y)とのイオン
結合を形成させ、耐久性ある抗菌性能を発揮させる為の
ものである。一方、アニオン基を含捷ないポリエステル
重合体を併用することについては、吸水、防汚性向上の
意味を持つだけで、なんら抗菌性向上の意味は無い。使
用する2種類のポリエステル1合体の割合やその使用量
に制限は無いが、ただアニオン基を含むポリエステル重
合体の使用量は〔X〕もしくは〔Y〕の結合量に影響す
る為、この重合体をあまシに少量で用いるのは好ましく
ない。The polyester polymer containing the above-mentioned polyoxyalkyl group and anionic group not only has the purpose of imparting water absorption and antifouling properties, but also forms an ionic bond with the basic compound [X] or (Y) and has durability. This is to demonstrate antibacterial performance. On the other hand, the concomitant use of a polyester polymer that does not contain anionic groups is only meant to improve water absorption and antifouling properties, but does not mean any improvement in antibacterial properties. There are no restrictions on the ratio of the two types of polyester 1 polymer to be used or the amount used, but the amount of polyester polymer containing anionic groups will affect the bond amount of [X] or [Y], so this polymer It is not recommended to use it in small amounts for sweetness.
アニオン基を含有する水溶性反応型ウレタン樹脂は、帯
電防止性能を付与する目的のみならず、塩基性化合物〔
X〕もしくは〔Y〕とのイオン結合を形成させ、耐久性
ある抗菌性能を発揮させる為のものである。使用するウ
レタン分子の量に制限は無いが、その使用量は〔X〕も
しくは〔Y〕の結合量に影響する為、これをあまシに少
量で用いることは好ましくない。Water-soluble reactive urethane resins containing anionic groups are used not only for the purpose of imparting antistatic properties, but also for basic compounds [
This is to form an ionic bond with [X] or [Y] and exhibit durable antibacterial performance. Although there is no limit to the amount of urethane molecules used, it is not preferable to use a small amount to compensate, since the amount affects the bonding amount of [X] or [Y].
Aの処理移さらにBの処理をした繊維材料は、使用した
重合体及び樹脂の性能をそれぞれ合わせもち、秀れた制
電、吸水8汚性を示す。ついで〔X〕もしくは〔Y〕と
の化学結合がなされることによシ上述した制電、吸水、
防汚性に加えて耐久性のある抗菌性を示すようになる。The fiber material subjected to the treatment A and the treatment B has the properties of the polymer and resin used, and exhibits excellent antistatic properties, water absorption, and stain resistance. Then, by forming a chemical bond with [X] or [Y], the above-mentioned antistatic, water absorption,
In addition to being antifouling, it also exhibits durable antibacterial properties.
本発明の対象とする繊維材料は、ポリエステル、ナイロ
ン、アクリル等の合成繊維およびその混紡もしくは交織
品が主体であるが、本発明の方法を木綿、羊毛、麻等の
天然繊維に適用することも可能である。また、これらの
繊維材料の形態は織物、編物、その他いかなる形態であ
っても良い。The fiber materials targeted by the present invention are mainly synthetic fibers such as polyester, nylon, and acrylic, and their blended or interwoven products, but the method of the present invention can also be applied to natural fibers such as cotton, wool, and hemp. It is possible. Moreover, the form of these fiber materials may be woven fabric, knitted fabric, or any other form.
以下、実施例によシ、本発明を具体的に説明する。尚、
例中の処理品の性能評価は以下の方法を用いた。Hereinafter, the present invention will be specifically explained with reference to Examples. still,
The following method was used to evaluate the performance of the treated products in the example.
(1)抗菌性
■ 黄色ブドウ球菌1×108個/dの濃度のものをト
リシトソーヤ寒天100+mに0.1 mlの比で混合
したものを用意する。(1) Antibacterial properties ■ Prepare a mixture of Staphylococcus aureus at a concentration of 1 x 108 cells/d in 0.1 ml of Tricytosawya agar 100+m.
■ シャーレに上記の菌10ml (10mlの菌数1
×106個)を入れて薄層培地を作シ、その上に試験繊
維材料(3cm X 3 cm )を置き、冷蔵庫に2
時間保存したのち、37℃で24時間培養し、抗菌性の
有無を調べる。■ Put 10ml of the above bacteria in a petri dish (number of bacteria in 10ml is 1)
A thin layer culture medium was prepared by adding 106 x 106 pieces), and a test fiber material (3 cm x 3 cm) was placed on top of it, and it was placed in the refrigerator for two
After preserving for a while, culture at 37°C for 24 hours and check for antibacterial properties.
■ 抗菌性を次のように位置づけ評価する。■ Antibacterial properties are evaluated as follows.
5級:布下に透明な阻止帯が形成され、菌の生育が見ら
れない。Grade 5: A transparent inhibition zone is formed under the cloth, and no bacterial growth is observed.
4級:布下に阻止帯があるが、少し透明性に欠けわずか
の菌が生育している。Grade 4: There is an inhibition zone under the cloth, but it lacks transparency and a few bacteria grow.
3級:布下に阻止帯があるが、手下透明で菌が刺子生育
している。Grade 3: There is an inhibition zone under the cloth, but the underside is transparent and bacteria are growing on it.
2級:布下に半透明な阻止帯があるが、がなシにごって
おシ、菌の生育を示す。Grade 2: There is a translucent inhibition zone under the cloth, but the stain is cloudy, indicating the growth of bacteria.
1級:布下に阻止帯が無く、菌は生育している。Grade 1: There is no inhibition zone under the cloth, and bacteria are growing.
(2)摩擦帯電圧
京大化研式ロータリースタティックテスターを用い、2
0℃、40%R,H,にて綿布と摩擦し、帯[圧全測定
した( JIS 1094−1980 B法)。(2) Frictional charging voltage Using a Kyoto University Kaken type rotary static tester, 2
It was rubbed against a cotton cloth at 0° C. and 40% R and H, and the total pressure was measured (JIS 1094-1980 B method).
(3)吸水性
試料を水平に張シ、5ctnの高さからビユレットより
1滴の蒸留水を滴下し、水分が完全に吸収され、独特の
反射光を示さなくなるまでの時間を測定した。(3) A water-absorbing sample was stretched horizontally, one drop of distilled water was dropped from a billet from a height of 5 ctn, and the time until the water was completely absorbed and the sample no longer exhibited a unique reflected light was measured.
(4)防汚性
約15cm×15crnの試料の中心部にB重油を1部
落し、完全に吸収させた後、2時間放置する。(4) Antifouling property One drop of B heavy oil is placed in the center of a sample of approximately 15 cm x 15 crn, and after it is completely absorbed, it is left for 2 hours.
ついでJIS−LO217−103による家庭洗濯を3
回くシ返し、自然乾燥し、汚染用グレースケールにて未
加工布と比較判定した。Next, do 3 home laundry according to JIS-LO217-103.
It was turned over, air-dried, and compared with the untreated cloth using a gray scale for staining.
(5)洗濯耐久性
JIS−LO217−103法により20回洗濯し、耐
久性を評価した。(5) Washing durability The product was washed 20 times according to the JIS-LO217-103 method, and its durability was evaluated.
実施例1
ポリxステルポンデー織物4Iを用意し、ポリオキシア
ルキル基を含有するポリエステル重合体1%ovtfと
ポリオキシアルキル基とアニオン基を含有するポリエス
テル重合体1.5 % owlとをそれぞれ精秤し、混
合液を130CX30分処理した。Example 1 A poly x sterpond fabric 4I was prepared, and 1% ovtf of a polyester polymer containing polyoxyalkyl groups and 1.5% owl of a polyester polymer containing polyoxyalkyl groups and anionic groups were each accurately weighed. , the mixed solution was treated at 130C for 30 minutes.
ついで、化合物〔X〕の1%ows水溶液に浸漬し、1
50℃で30秒間処理した。このものの性能を未処理布
と比較し、評価した。結果を第1表に示す。Then, it was immersed in a 1% ows aqueous solution of compound [X], and
It was treated at 50°C for 30 seconds. The performance of this product was compared and evaluated with untreated fabric. The results are shown in Table 1.
以下全白
実施例2
ポリエステルニット編物を用意し、アニオン基を含有す
る反応型水溶性ウレタン樹脂5%OWBイソシアヌール
系酸化防止剤0.25%owa 、重ao、oos%o
wsおよび有機スズ触媒0.3%owsを添加し、よく
混合した水溶液に浸し、マングルで絞、!t、x50℃
で100秒間処理した。ついで、化合物(Y ) (P
roxel IB 11CI社)の0.8%ows水溶
液に浸漬し、150℃で45秒間処理した。The following all-white Example 2 A polyester knitted fabric was prepared, and a reactive water-soluble urethane resin containing anionic groups was prepared using 5% OWB isocyanuric antioxidant 0.25% owa, heavy ao, and oos% o.
Add ws and organotin catalyst 0.3% ows, soak in a well-mixed aqueous solution, squeeze with a mangle,! t, x50℃
was processed for 100 seconds. Then, the compound (Y) (P
Roxel IB 11CI) was immersed in a 0.8% OWS aqueous solution and treated at 150° C. for 45 seconds.
このものの性能を未処理布と比較し、評価した。The performance of this product was compared and evaluated with untreated fabric.
結果を第2表に示す。The results are shown in Table 2.
実施例3
s9 リエステル100%からなる織物を用意し、精秤
する。つぎに、ポリオキシアルキル基を含有するポリエ
ステル重合体1%owfとポリオキシアルキル基とアニ
オン基を含有するポリエステル重合体1%owfとをそ
れぞれ精秤し、CI 、DisperseBlue 7
90.5%owf1酢酸0.3 cc/ l 5KS−
100,2CC/A’を添加した染料液に加える。混合
液を130℃で30分間処理する。ついで、処理した繊
維材料をアニオン基を含有する反応型水溶性ウレタン樹
脂5 % ows、インシアヌール系酸化防止剤0.2
5%owe、垂力o、 o o s%0w11および有
機スズ融媒0.3%owaを添加し、よく攪拌した水溶
液に浸し、マングルで絞、!7.150℃で1o O秒
間処理する。つぎに、処理した繊維材料を化合物〔X〕
の1%ows水溶液に浸漬し、150℃で30秒間処理
した。このものの性能を未処理布と比較し評価した。結
果を第3表に示す。Example 3 s9 A fabric made of 100% realester is prepared and accurately weighed. Next, 1% owf of a polyester polymer containing a polyoxyalkyl group and 1% owf of a polyester polymer containing a polyoxyalkyl group and an anionic group were each accurately weighed, and CI, DisperseBlue 7
90.5%owfl Acetic acid 0.3 cc/l 5KS-
Add 100.2 CC/A' to the dye solution. The mixture is treated at 130° C. for 30 minutes. Next, the treated fiber material was treated with 5% ows of a reactive water-soluble urethane resin containing anionic groups and 0.2% of an incyanur antioxidant.
Add 5% owe, sulfur o, o o s%0w11 and organotin melting agent 0.3% owa, immerse in a well-stirred aqueous solution, squeeze with a mangle,! 7. Treat at 150°C for 100 seconds. Next, the treated fiber material is converted into a compound [X]
It was immersed in a 1% OWS aqueous solution of and treated at 150° C. for 30 seconds. The performance of this product was evaluated in comparison with untreated fabric. The results are shown in Table 3.
以下余e
実施例4
ポリエステル/綿(65/35)からなる織物6gを用
意し、ポリオキシアルキル基を含有するポリエステル重
合体0.8%owfとポリオキシアルキル基とアニオン
基を含有するポリエステル重合体1.2%owfとをそ
れぞれ精秤し、混合液を130℃で30分間処理した。Example 4 6 g of a fabric made of polyester/cotton (65/35) was prepared, and 0.8% owf of a polyester polymer containing a polyoxyalkyl group and a polyester polymer containing a polyoxyalkyl group and an anionic group were prepared. The combined 1.2% owf was accurately weighed, and the mixed solution was treated at 130° C. for 30 minutes.
ついで化合物〔X、lの2チowf[Hを同浴に加え、
室温下20分間浸漬処理した。つぎに、液を捨て、水洗
を5分間行なった。Then, the compound
The sample was immersed at room temperature for 20 minutes. Next, the liquid was discarded and washed with water for 5 minutes.
自然乾燥後、このものの性能を未処理布と比較し評価し
た。結果を第4表に示す。After air drying, the performance of this material was evaluated in comparison with untreated fabric. The results are shown in Table 4.
−4゜ 2−-4° 2-
Claims (1)
着し、ついでこの繊維材料を下記〔X〕もしくは[Y)
の構造式を有する化合物、以下余白 (式中、nは正の整数を表わす) の水溶液で処理することを特徴とする繊維材料の抗菌加
工方法。 2、 アニオン基を含む高分子重合体を繊維材料上に固
着するに際して、ポリオキシアルキル基を含有するポリ
エステル重合体とポリオキシアルキル基とアニオン基を
含有するポリエステル重合体とによシ同浴で処理するこ
とを特徴とする特許請求の範囲第1項記載の繊維材料の
抗菌加工方法。 3、アニオン基を含む高分子重合体を繊維材料上に固着
するに際して、アニオン基を含有する水溶性反応型ウレ
タン樹脂によシパッドキュアー法を用いて処理すること
を特徴とする特許請求の範囲第1項記載の繊維利料の抗
菌加工方法。 4、 アニオン基を含む高分子重合体を繊維制斜上に固
着するに際して、ポリオキシアルキル基を含有するポリ
エステル重合体とポリオキシアルキル基とアニオン基を
含有するポリエステル重合体とによシ同浴で処理し、つ
いでアニオン基を含有する水溶性反応型ウレタン樹脂に
よシパッドキーアー法を用いて処理することを特徴とす
る特許請求の範囲第1項記載の繊維材料の抗菌加工方法
。[Claims] 1. A high molecular weight polymer containing an anionic group is fixed onto a fiber material, and then this fiber material is applied to the following [X] or [Y].
1. A method for antibacterial processing of textile materials, which comprises treating with an aqueous solution of a compound having the structural formula: (in the formula, n represents a positive integer). 2. When fixing a high molecular weight polymer containing an anionic group onto a fiber material, a polyester polymer containing a polyoxyalkyl group and a polyester polymer containing a polyoxyalkyl group and an anionic group are mixed together in the same bath. 2. A method for antibacterial processing of textile materials according to claim 1, which comprises: treating fiber materials. 3. Claims characterized in that when fixing a high molecular weight polymer containing anionic groups onto a fiber material, a water-soluble reactive urethane resin containing anionic groups is treated using a pad curing method. The method for antibacterial processing of a fiber material according to item 1. 4. When fixing the high molecular weight polymer containing anionic groups onto the textile slope, a polyester polymer containing polyoxyalkyl groups and a polyester polymer containing polyoxyalkyl groups and anionic groups are mixed in a bath. 2. A method for antibacterial processing of fiber materials according to claim 1, characterized in that the method comprises treating with a water-soluble reactive urethane resin containing an anionic group using the Pad-Kier method.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4562084A JPS60194179A (en) | 1984-03-12 | 1984-03-12 | Anti-bacterial processing of fiber material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4562084A JPS60194179A (en) | 1984-03-12 | 1984-03-12 | Anti-bacterial processing of fiber material |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60194179A true JPS60194179A (en) | 1985-10-02 |
JPS6260509B2 JPS6260509B2 (en) | 1987-12-16 |
Family
ID=12724417
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4562084A Granted JPS60194179A (en) | 1984-03-12 | 1984-03-12 | Anti-bacterial processing of fiber material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60194179A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61245378A (en) * | 1985-04-23 | 1986-10-31 | 東レ株式会社 | Antibacterial polyester fiber |
-
1984
- 1984-03-12 JP JP4562084A patent/JPS60194179A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61245378A (en) * | 1985-04-23 | 1986-10-31 | 東レ株式会社 | Antibacterial polyester fiber |
Also Published As
Publication number | Publication date |
---|---|
JPS6260509B2 (en) | 1987-12-16 |
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