JPS60161474A - Production of solidified waste oil - Google Patents
Production of solidified waste oilInfo
- Publication number
- JPS60161474A JPS60161474A JP1426384A JP1426384A JPS60161474A JP S60161474 A JPS60161474 A JP S60161474A JP 1426384 A JP1426384 A JP 1426384A JP 1426384 A JP1426384 A JP 1426384A JP S60161474 A JPS60161474 A JP S60161474A
- Authority
- JP
- Japan
- Prior art keywords
- waste oil
- plasticizer
- mixture
- polyvinyl chloride
- solidifying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【発明の詳細な説明】
本発明は%廃油とくに自動車、オートバイ等の車輌用廃
油の有効利用を図った廃油固形物の製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing solid waste oil, which aims to effectively utilize waste oil, particularly waste oil for vehicles such as automobiles and motorcycles.
近時、自動車、オートバイ等の利用が大巾に増加し、こ
れに供ない使用済みのエンジンオイル、ミッションオイ
ルなどの廃油が多′11kIC排出されている。しかし
これらの廃油は、再利用の道があまりなく、はとんどJ
jIi東焼却されているのが現状である。In recent years, the use of automobiles, motorcycles, etc. has increased dramatically, and a large amount of waste oil such as used engine oil and transmission oil is being discharged. However, there are not many ways to reuse these waste oils, and most of them are
The current situation is that the jIi East is being incinerated.
そこで本発明者は、廃油の再利用方法につき鋭意研究を
行った結果、可塑剤にポリビニルクロ2イド(pvc)
とともに廃油を加えて加熱混合することにより、特徴あ
る性質を有する組成物が得られることがわかった。Therefore, as a result of intensive research on methods for reusing waste oil, the present inventor found that polyvinyl chloride (PVC) was used as a plasticizer.
It has been found that by adding waste oil and heating and mixing, a composition with distinctive properties can be obtained.
本発明は、上記知見にもとづいてなされたものでその目
的とするところは、廃油を固形化して別の用途への再活
用t−可能とする廃油固形物の製造方法t−得んとする
ものである。The present invention has been made based on the above-mentioned knowledge, and its purpose is to solidify waste oil and reuse it for other purposes. It is.
すなわち本発明は、ポリビニルクロ2イド100重量部
に対し廃油10−1000重量部と可塑剤lO〜100
0重量部と全加熱混合して一体化した後冷却固化するこ
とt−%徴とする。That is, in the present invention, 10 to 1000 parts by weight of waste oil and lO to 100 parts by weight of plasticizer are added to 100 parts by weight of polyvinyl chloride.
It is defined as t-% by completely heating and mixing with 0 parts by weight, integrating, cooling and solidifying.
以下本発8A’を詳細に説明する。The present invention 8A' will be explained in detail below.
まずポリビニルクロ2イド(PVC)100重蓋部に対
し、廃油10〜1000重量部と可塑剤lO〜1000
重量部とを加熱混合する。First, 10 to 1000 parts by weight of waste oil and 10 to 1000 parts of plasticizer are added to 100 parts by weight of polyvinyl chloride (PVC).
Parts by weight are heated and mixed.
PVCに加える町重剤は、得られる廃油固形物のモジュ
ラスを低くシ、材質を軟かくしてゼリ一様とするもので
ある。この可塑剤として。The additive added to PVC lowers the modulus of the obtained solid waste oil, softens the material, and makes it uniform in jelly. As this plasticizer.
従来からPVCの成形に用いられている町巌剤を使用で
き1例えばジオクチルンクレート(DOP)、ジンチル
フタレー)(DBP)%ジインテVA/7 fi レー
) (DIDP) 4%の7タル酸エステル系可塑剤、
トリオクチルホスフェート(TOP)等のF[エステル
系可塑剤、メタクリル酸エステル系可塑剤などを用いる
。またこれにトリクレジルホスフェ−) (TCP)等
の難燃性町IHIJ會入れれば、製品を難燃化させるこ
ともできる。Machining agents conventionally used in PVC molding can be used, such as dioctyl lactate (DOP), dintyl phthalate (DBP), 4% 7-talic acid ester plasticizer (DIDP), etc. agent,
Use F[ester plasticizers, methacrylate ester plasticizers, etc. such as trioctyl phosphate (TOP). Furthermore, by adding flame retardant materials such as tricresyl phosphate (TCP) to this product, it is possible to make the product flame retardant.
PVCに加える廃油は、得られる廃油固形物のモジュラ
スを更に低くシ、材質を軟かくしてゼリ一様とする性質
がある。この廃油として可塑剤と相溶性のあるもの、例
えは二/ジンオイル、ミッションオイルなどを使用でき
る。The waste oil added to PVC has the property of further lowering the modulus of the resulting waste oil solid and softening the material to make it more uniform. As this waste oil, one that is compatible with the plasticizer can be used, such as 2/gin oil, transmission oil, etc.
ここで可塑剤の添加割合を上記範囲に限定した理由は、
lO重蓋部未満では廃油固形物がゼリー状とならず、ま
fc1000重量部を越えるとコストが高くなるととも
にブリードしやすくなるためである。また廃油の添加割
合を上記範囲に限定した理由は、lO重蓋部未満ではそ
の添加量が少なすぎて有効利用fニーるのが難かしく、
また1000重賃部を越えるとブリードしやすくなるた
めである。この場合廃油の添加蓋は、可塑剤の添加il
t越えないようにするのが好ましい。The reason for limiting the addition ratio of plasticizer to the above range is as follows:
This is because if the amount is less than 10 parts by weight, the waste oil solids will not become jelly-like, and if it exceeds 1,000 parts by weight, the cost will be high and bleeding will occur easily. The reason for limiting the addition ratio of waste oil to the above range is that if the amount is less than 1O, the amount added is too small and it is difficult to use it effectively.
This is also because if the weight exceeds 1000, bleed tends to occur. In this case, the waste oil addition lid is the plasticizer addition lid.
It is preferable not to exceed t.
本発明では、上述した添加物に加えて更にステアリン酸
亜鉛等の安定剤、着色剤あるいは充填剤等の各慎添加剤
を混合してもよい。油の臭いがある時は香料等を混合し
てもよい。In the present invention, in addition to the above-mentioned additives, various additives such as a stabilizer such as zinc stearate, a coloring agent, or a filler may be mixed. If there is an odor from the oil, you may add fragrance or the like.
これらPVC,可塑剤、廃油等の混合物を加熱混合する
際、その加熱温度をPVCが溶融しうる150〜220
℃でおこなう。この後これt−型などに入れて冷却固化
することにより廃油固形物を得る。When heating and mixing the mixture of PVC, plasticizer, waste oil, etc., the heating temperature is set to 150 to 220, which is the temperature at which the PVC melts.
Perform at ℃. Thereafter, this is put into a T-type or the like and cooled and solidified to obtain solid waste oil.
このようにして得られたゼリ一様オイル組成物は、寒天
ゼリーと同じようなゼリ一様の弾性および感触を有して
いる。これは、廃油固形物t−膜製造る過程でPVC分
子が可塑剤及び廃油を取り込んでグル化し、これによっ
てPVCのゼリーが形成されたことを推定させ得るもの
である。但し、このゼリ一様PVC組成物は、寒天ゼリ
ー等のようなシネレシスを生じず、極めて安定である。The jelly-like oil composition thus obtained has a jelly-like elasticity and feel similar to agar jelly. This suggests that during the process of manufacturing the waste oil solid T-film, PVC molecules took in the plasticizer and waste oil to form a glue, thereby forming a PVC jelly. However, this jelly-like PVC composition does not cause syneresis like agar jelly and is extremely stable.
また、かなりの伸び特性および引張強度を有し、寒天ゲ
ルのように容易にちぎれたりすることがない0また。変
形性に富み魁形状追随性に優れているといった特徴があ
る。It also has considerable elongation properties and tensile strength, and does not tear easily like agar gel. It has the characteristics of being highly deformable and having excellent shape-following properties.
しかも低温での物性低下や硬度の上昇がみられずb−a
o℃〜−40℃での長時間の使用においても常温と変ら
ない挙動を示す。Moreover, there is no decrease in physical properties or increase in hardness at low temperatures, and b-a
Even when used for a long time at 0°C to -40°C, it shows the same behavior as at room temperature.
とくに従来廃棄焼却していた廃油を添加しているので、
製造コストをきわめて安くすることができる。しかも廃
油の添加量を調節することにより、廃油固形物の硬さを
広範囲に変えることができる。In particular, since it contains waste oil that was previously incinerated,
Manufacturing costs can be extremely reduced. Furthermore, by adjusting the amount of waste oil added, the hardness of the waste oil solids can be varied over a wide range.
また本発明によって得られる廃油固形物は。Moreover, the waste oil solids obtained by the present invention are as follows.
弾力性及び形状追随性に優れて−する。このためこの性
質を利用して、電線、コイル等の被覆充填材、シール材
、産業資材、道路材料などに有効に使用できる。Excellent elasticity and shape-following properties. Therefore, by utilizing this property, it can be effectively used for covering fillers for electric wires, coils, etc., sealing materials, industrial materials, road materials, etc.
以下本発明の実施例につき説明する。Examples of the present invention will be described below.
下記m1表に示す製造条件で本発明に係る廃油固形物を
得た。A waste oil solid according to the present invention was obtained under the production conditions shown in Table m1 below.
ただし、町厩剤としてDOP、廃油としてエンジンオイ
ル廃油を用いた。However, DOP was used as a household agent and waste engine oil was used as waste oil.
次にこのようにして得た廃油固形物の硬さを針入度試験
で調べたその結果t−$2表に示す。Next, the hardness of the solid waste oil thus obtained was examined by a penetration test, and the results are shown in the t-$2 table.
以上説明したように本発明によれば、従来廃棄、焼却し
ていた廃油を有効KPIr利用でき、しかもその製造方
法もきわめて簡単であり、また得られた廃油固形物が特
徴ある性質を有し種々の用途に使用できるなど顕著な効
果を奏する。As explained above, according to the present invention, waste oil that was conventionally discarded or incinerated can be effectively used as KPIr, and the manufacturing method thereof is extremely simple, and the waste oil solids obtained have distinctive properties and can be used in various ways. It has remarkable effects, such as being able to be used for many purposes.
Claims (1)
o00!m部と町朦剤lO〜1000重賞部とを加熱混
合して一体化した後冷却固化することを特徴−とする廃
油固形物の製造方法。Waste oil lO~z for polyvinyl chloride 100 heavy lid part
o00! 1. A method for producing solid waste oil, which comprises heating and mixing 10 to 1000 parts of a town detergent, integrating them, and then cooling and solidifying them.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1426384A JPS60161474A (en) | 1984-01-31 | 1984-01-31 | Production of solidified waste oil |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1426384A JPS60161474A (en) | 1984-01-31 | 1984-01-31 | Production of solidified waste oil |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS60161474A true JPS60161474A (en) | 1985-08-23 |
Family
ID=11856201
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1426384A Pending JPS60161474A (en) | 1984-01-31 | 1984-01-31 | Production of solidified waste oil |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60161474A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103193933A (en) * | 2013-03-29 | 2013-07-10 | 宁波市江北成达色母粒有限公司 | Preparation method of macromolecule plasticizer based on recycled cooking oil |
-
1984
- 1984-01-31 JP JP1426384A patent/JPS60161474A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103193933A (en) * | 2013-03-29 | 2013-07-10 | 宁波市江北成达色母粒有限公司 | Preparation method of macromolecule plasticizer based on recycled cooking oil |
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