JPS5951486A - Enclosed lead storage battery - Google Patents

Enclosed lead storage battery

Info

Publication number
JPS5951486A
JPS5951486A JP57162489A JP16248982A JPS5951486A JP S5951486 A JPS5951486 A JP S5951486A JP 57162489 A JP57162489 A JP 57162489A JP 16248982 A JP16248982 A JP 16248982A JP S5951486 A JPS5951486 A JP S5951486A
Authority
JP
Japan
Prior art keywords
liquid holder
electrical resistance
porous material
battery
electrodes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP57162489A
Other languages
Japanese (ja)
Other versions
JPH0352190B2 (en
Inventor
Kunio Yonezu
米津 邦雄
Masashi Iwata
政司 岩田
Eiji Okamoto
英治 岡本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Storage Battery Co Ltd
Nihon Denchi KK
Original Assignee
Japan Storage Battery Co Ltd
Nihon Denchi KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Storage Battery Co Ltd, Nihon Denchi KK filed Critical Japan Storage Battery Co Ltd
Priority to JP57162489A priority Critical patent/JPS5951486A/en
Publication of JPS5951486A publication Critical patent/JPS5951486A/en
Publication of JPH0352190B2 publication Critical patent/JPH0352190B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H01M10/484Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte for measuring electrolyte level, electrolyte density or electrolyte conductivity
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)

Abstract

PURPOSE:To control the degree of deterioration of battery characteristic through optional measurement of dry-wet condition of a liquid holder by providing the electrodes to the porous material being coupled to a liquid holder which is impregnated with the electrolyte for holding it and by measuring an electrical resistance of the porous material. CONSTITUTION:A liquid holder 4, which is located between the positive pole plate 2 and the negative pole plate 3 of an enclosed lead storage battery, and composed of a mat of such as silicic acid gel or glass fiber and is holding rare sulfuric acid, is coupled with a porous material 5 made of glass fiber or plastic fiber and the electrodes 6, 7 are disposed on both sides thereof. An AC voltage is supplied across the electrodes 6, 7 from a power supply 8 and an electrical resistance is measured with a circuit 9. Thereby change of dry and wet condition of liquid holder 6 is detected. Since an electrical resistance remarkably increases when the liquid holder 5 dries up, the degree of deterioration of battery characteristic can be controlled anytime without discharging the battery by detecting the change of resistance.

Description

【発明の詳細な説明】 本発明は電池の劣化状態を指示する機能を持った密閉形
鉛蓄電池に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a sealed lead-acid battery having a function of indicating the state of deterioration of the battery.

密閉形鉛蓄電池はゲルまたは多孔体などの保液体を用い
て電1lIl液を非流動化し、酸素サイクルの密閉反応
によって電解液の水の□減少を防いでいる。
Sealed lead-acid batteries use a retaining liquid such as gel or porous material to make the electrolyte non-fluid and prevent the water in the electrolyte from decreasing due to the sealing reaction of the oxygen cycle.

しかし放置、フロート充電あるいは充放電などで若干の
水素ガス発生があれ、水は徐々に失われて 1− 保液体は乾燥してゆく。これがある限度を越えると、内
部抵抗は著しく高くなって、放電性能は低下する。しf
二がって緊急時に充分な放電性能を期待するためには、
保液体の乾湿状態を随時測定して電池性能の劣化程度を
管理する必要がある。
However, even if a small amount of hydrogen gas is generated due to neglect, float charging, charging/discharging, etc., the water will gradually be lost and the retained liquid will dry out. When this exceeds a certain limit, the internal resistance becomes significantly high and the discharge performance deteriorates. Shif
Second, in order to expect sufficient discharge performance in an emergency,
It is necessary to monitor the degree of deterioration of battery performance by constantly measuring the dry and wet state of the liquid retaining liquid.

不発明は上記の必要性を満足させることを目的とし、そ
の要旨は正・負−仮と接融して電解液を含浸・保持して
いる保液体と連っている多孔性体−に交流を流し、環1
間の電流tfこはtFEを測定。
The purpose of the invention is to satisfy the above-mentioned needs, and its gist is to create an alternating current in a porous body connected to a liquid retaining liquid impregnated with and retaining an electrolyte by welding positive and negative electrodes. flow, ring 1
The current between tf and tFE is measured.

指示する回路を設ける仁とにある。There is a need to provide a circuit for instructions.

本発明の実施例を□第1図によって説明すると、(11
は電槽および蓋、(セ)は正1仮、(3)は負Fh仮、
(4)は保液体で、珪酸ゲルやガラス繊維などからなる
やプラスチック繊維からなるマットあるいは多孔体より
構成されている。(6)および(7)は多孔性体(5)
をへだでて配置した二つの電画で、多孔性体(5)と2
− それぞれ接触している。(8)は電m +61および(
7)に電流を流す1こめの電源、(9)はその電流まT
こは電1iM +61および(71の間の電圧を測定、
指示する回路、  (10)は排気部である。なお、ス
トラップ、ポールおよの乾湿に応じて湿潤状態が変化す
る。この湿潤状態の変化と電気抵抗との関係は第2図に
ホすように、多孔性体の空隙容積に占める希硫酸の容積
比が07を境にしてそれよりも乾燥すると著しく増加す
る。なお第2図には多孔性体として平均直径0.5μの
ガラス繊維マットの場合と、ポリエチレンとシリカ微粉
末からなる多孔シートの場合とについて示しである。
An embodiment of the present invention will be explained with reference to □Figure 1. (11
is the battery case and lid, (C) is positive 1 provisional, (3) is negative Fh provisional,
(4) is a liquid retaining material, which is made of silicic acid gel, glass fiber, etc., or a mat or porous material made of plastic fiber. (6) and (7) are porous bodies (5)
Porous body (5) and 2
- are in contact with each other. (8) is electric m +61 and (
7) is a power source that passes current, (9) is the current or T
Measure the voltage between 1iM +61 and (71,
In the instructing circuit, (10) is the exhaust section. Note that the wet state changes depending on the dryness and humidity of the strap and pole. As shown in FIG. 2, the relationship between the change in the wet state and the electrical resistance increases significantly when the volume ratio of dilute sulfuric acid to the pore volume of the porous body reaches 0.07 and dries further. Note that FIG. 2 shows the case of a glass fiber mat having an average diameter of 0.5 μm as the porous body, and the case of a porous sheet made of polyethylene and fine silica powder.

多孔性体(5:の電気抵抗の測定には交流を用いるとよ
い。直流では2つの電1! +61.(7+のうち片方
が陽陽酸化、他万が陰陽還元されてそれぞれ異なる電位
を示すTこめ、多孔性体(5)を通して流れる電流やそ
の両端の電圧測定に誤差が入りやすい。交流であれば2
つの電−の電位が同じになるfこめ、とくてもよい。ま
TこN h (61,+71に流れろ電流を測定するに
は所定のt[fEを!6間に印加し、電王を測定するに
は所定の電流を流せばよい。
It is best to use alternating current to measure the electrical resistance of a porous material (5: Errors are likely to occur in the measurement of the current flowing through the porous body (5) and the voltage across it.For alternating current, 2
It is fine if the two electric potentials are the same. To measure the current flowing through MaTkoNh (61, +71), apply a predetermined t[fE between !6, and to measure the electric current, apply a predetermined current.

本発明は以−ヒのように、保液体の乾湿を測定すること
iこよりit池を放電することなく、その劣化程度を知
ることを可能にしTこものである。
The present invention, as described below, makes it possible to determine the degree of deterioration of an IT battery without discharging it by measuring the wetness and dryness of the retained liquid.

【図面の簡単な説明】[Brief explanation of the drawing]

第1Nは本発明の一実鵬例を示す要部縦断面模式内、第
2図は多孔性体の湿潤状態すなわち空隙容積に占める希
硫酸の容積比と電気抵抗との関係を示す特性図である。 4・・・・・・保液体、 5・・・・・・多孔性体、6
,7・・・・・・電1、8・・・・・・電源、 9・・
・・・・電流・電圧測定回路。 汀 11!] −y′r 7  囚 ρ    /、2  、  1.4     σ、6 
   タ8    tρづすpl咋卜め堂隋に阿1に6
め合4嘔鰹敞のzJ1ヰ。
1N is a schematic vertical cross-sectional view of the main part showing an example of the present invention, and FIG. 2 is a characteristic diagram showing the relationship between the wet state of the porous body, that is, the volume ratio of dilute sulfuric acid to the pore volume, and the electrical resistance. be. 4...Liquid retention, 5...Porous body, 6
,7...Power 1,8...Power, 9...
...Current/voltage measurement circuit. 11! ] −y′r 7 prisoner ρ /, 2, 1.4 σ, 6
ta 8 tρzu pl Kui Baku Medo Sui ni A1 ni 6
The zJ1 of the match 4 and the bonito.

Claims (1)

【特許請求の範囲】 足、指示する回路を設けたことを特徴とする密閉形鉛蓄
電池。 (2)  多孔性体をへだでて配置した二つの電動に交
流を流し、t−間の電流または電圧を測定、指示する回
路を設け1こことを特徴とする特許請求の範囲第(1)
項に記載の密閉形鉛蓄電池。
[Claims] A sealed lead-acid battery characterized by being provided with an indicating circuit. (2) A circuit is provided for measuring and indicating the current or voltage between t and t by supplying an alternating current to two electric motors disposed outside the porous body. )
Sealed lead-acid batteries as described in .
JP57162489A 1982-09-18 1982-09-18 Enclosed lead storage battery Granted JPS5951486A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57162489A JPS5951486A (en) 1982-09-18 1982-09-18 Enclosed lead storage battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57162489A JPS5951486A (en) 1982-09-18 1982-09-18 Enclosed lead storage battery

Publications (2)

Publication Number Publication Date
JPS5951486A true JPS5951486A (en) 1984-03-24
JPH0352190B2 JPH0352190B2 (en) 1991-08-09

Family

ID=15755582

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57162489A Granted JPS5951486A (en) 1982-09-18 1982-09-18 Enclosed lead storage battery

Country Status (1)

Country Link
JP (1) JPS5951486A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100477720B1 (en) * 1997-08-05 2005-05-16 삼성에스디아이 주식회사 Battery for testing resistance of active material layer and testing method of resistance using the same
KR100477719B1 (en) * 1997-08-04 2005-05-16 삼성에스디아이 주식회사 Battery for testing interfacial resistance and testing method of resistance using the same
KR100865401B1 (en) 2007-05-25 2008-10-24 삼성에스디아이 주식회사 Method of measuring wettability for non aqueous electrolyte battery and apparatus for the same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5624068U (en) * 1979-08-01 1981-03-04

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5445921A (en) * 1977-09-17 1979-04-11 Sumitomo Metal Mining Co Method of executing floor plate of alc panel

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5624068U (en) * 1979-08-01 1981-03-04

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100477719B1 (en) * 1997-08-04 2005-05-16 삼성에스디아이 주식회사 Battery for testing interfacial resistance and testing method of resistance using the same
KR100477720B1 (en) * 1997-08-05 2005-05-16 삼성에스디아이 주식회사 Battery for testing resistance of active material layer and testing method of resistance using the same
KR100865401B1 (en) 2007-05-25 2008-10-24 삼성에스디아이 주식회사 Method of measuring wettability for non aqueous electrolyte battery and apparatus for the same

Also Published As

Publication number Publication date
JPH0352190B2 (en) 1991-08-09

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