JPS594380B2 - 塩基性炭酸銅の結晶性粒子集塊の製法 - Google Patents

塩基性炭酸銅の結晶性粒子集塊の製法

Info

Publication number: JPS594380B2
Authority: JP; Japan
Prior art keywords: bismuth; catalyst; carbonate; copper carbonate; malachite
Prior art date: 1974-02-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP2250175A

Other languages

English (en)

Japanese (ja)

Other versions

JPS50119797A (xx

Inventor

メルビンフレモントジヨセフ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

EIDP Inc

Original Assignee

EI Du Pont de Nemours and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-02-25

Filing date

1975-02-25

Publication date

1984-01-30

1975-02-25 Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co

1975-09-19 Publication of JPS50119797A publication Critical patent/JPS50119797A/ja

1984-01-30 Publication of JPS594380B2 publication Critical patent/JPS594380B2/ja

Status Expired legal-status Critical Current

Links

239000002245 particle Substances 0.000 title claims description 37
229940116318 copper carbonate Drugs 0.000 title claims description 36
GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 title claims description 36
238000004519 manufacturing process Methods 0.000 title description 17
229910052797 bismuth Inorganic materials 0.000 claims description 50
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 50
238000000034 method Methods 0.000 claims description 29
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 18
239000010949 copper Substances 0.000 claims description 18
229910052802 copper Inorganic materials 0.000 claims description 17
238000010899 nucleation Methods 0.000 claims description 15
230000006911 nucleation Effects 0.000 claims description 15
239000011541 reaction mixture Substances 0.000 claims description 13
238000006243 chemical reaction Methods 0.000 claims description 12
239000013078 crystal Substances 0.000 claims description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
150000003839 salts Chemical class 0.000 claims description 7
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 6
150000001621 bismuth Chemical class 0.000 claims description 6
230000008569 process Effects 0.000 claims description 6
229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 5
150000008041 alkali metal carbonates Chemical class 0.000 claims description 5
230000001376 precipitating effect Effects 0.000 claims 1
239000003054 catalyst Substances 0.000 description 58
241000907663 Siproeta stelenes Species 0.000 description 35
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 21
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 20
239000000243 solution Substances 0.000 description 17
230000015572 biosynthetic process Effects 0.000 description 16
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 12
239000000047 product Substances 0.000 description 9
238000012360 testing method Methods 0.000 description 9
235000019256 formaldehyde Nutrition 0.000 description 7
238000001556 precipitation Methods 0.000 description 7
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
238000007792 addition Methods 0.000 description 5
XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 5
VWWMOACCGFHMEV-UHFFFAOYSA-N dicarbide(2-) Chemical compound [C-]#[C-] VWWMOACCGFHMEV-UHFFFAOYSA-N 0.000 description 5
239000002244 precipitate Substances 0.000 description 5
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
239000007789 gas Substances 0.000 description 4
239000011521 glass Substances 0.000 description 4
239000003112 inhibitor Substances 0.000 description 4
239000000376 reactant Substances 0.000 description 4
230000009466 transformation Effects 0.000 description 4
NPKGQBIUYHHPOT-UHFFFAOYSA-N [Cu+2].[C-]#[C-] Chemical compound [Cu+2].[C-]#[C-] NPKGQBIUYHHPOT-UHFFFAOYSA-N 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
KBZSNAZVDVIXKL-UHFFFAOYSA-L bismuth copper carbonate Chemical compound [Cu+2].[Bi+3].[O-]C([O-])=O KBZSNAZVDVIXKL-UHFFFAOYSA-L 0.000 description 3
-1 butyne diol Chemical class 0.000 description 3
238000002425 crystallisation Methods 0.000 description 3
230000008025 crystallization Effects 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
KDKYADYSIPSCCQ-UHFFFAOYSA-N ethyl acetylene Natural products CCC#C KDKYADYSIPSCCQ-UHFFFAOYSA-N 0.000 description 3
238000001914 filtration Methods 0.000 description 3
229910000029 sodium carbonate Inorganic materials 0.000 description 3
FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
229910002651 NO3 Inorganic materials 0.000 description 2
150000000476 acetylides Chemical class 0.000 description 2
230000009471 action Effects 0.000 description 2
239000012736 aqueous medium Substances 0.000 description 2
229910000416 bismuth oxide Inorganic materials 0.000 description 2
150000001721 carbon Chemical group 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
150000001879 copper Chemical class 0.000 description 2
TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 2
PPNKDDZCLDMRHS-UHFFFAOYSA-N dinitrooxybismuthanyl nitrate Chemical compound [Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PPNKDDZCLDMRHS-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000011156 evaluation Methods 0.000 description 2
239000008098 formaldehyde solution Substances 0.000 description 2
RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
230000007774 longterm Effects 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
239000000203 mixture Substances 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
239000002243 precursor Substances 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
239000002002 slurry Substances 0.000 description 2
229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
235000017557 sodium bicarbonate Nutrition 0.000 description 2
CBACFHTXHGHTMH-UHFFFAOYSA-N 2-piperidin-1-ylethyl 2-phenyl-2-piperidin-1-ylacetate;dihydrochloride Chemical compound Cl.Cl.C1CCCCN1C(C=1C=CC=CC=1)C(=O)OCCN1CCCCC1 CBACFHTXHGHTMH-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
238000012935 Averaging Methods 0.000 description 1
229910000014 Bismuth subcarbonate Inorganic materials 0.000 description 1
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
239000005751 Copper oxide Substances 0.000 description 1
239000012691 Cu precursor Substances 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
GACUIHAEKGVEIC-UHFFFAOYSA-L [Bi+2]=O.C([O-])([O-])=O Chemical compound [Bi+2]=O.C([O-])([O-])=O GACUIHAEKGVEIC-UHFFFAOYSA-L 0.000 description 1
238000013019 agitation Methods 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
MGLUJXPJRXTKJM-UHFFFAOYSA-L bismuth subcarbonate Chemical compound O=[Bi]OC(=O)O[Bi]=O MGLUJXPJRXTKJM-UHFFFAOYSA-L 0.000 description 1
229940036358 bismuth subcarbonate Drugs 0.000 description 1
DLDJFQGPPSQZKI-UHFFFAOYSA-N but-2-yne-1,4-diol Chemical compound OCC#CCO DLDJFQGPPSQZKI-UHFFFAOYSA-N 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000012018 catalyst precursor Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
229910000431 copper oxide Inorganic materials 0.000 description 1
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
DMRJVKOYZFHZJH-UHFFFAOYSA-L copper;hydrogen carbonate;hydroxide Chemical compound [OH-].[Cu+2].OC([O-])=O DMRJVKOYZFHZJH-UHFFFAOYSA-L 0.000 description 1
230000006378 damage Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
230000008034 disappearance Effects 0.000 description 1
239000000428 dust Substances 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
210000002837 heart atrium Anatomy 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
230000001788 irregular Effects 0.000 description 1
238000002386 leaching Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
239000002609 medium Substances 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
230000035699 permeability Effects 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
235000015497 potassium bicarbonate Nutrition 0.000 description 1
239000011736 potassium bicarbonate Substances 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
235000011181 potassium carbonates Nutrition 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
235000009518 sodium iodide Nutrition 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
238000012546 transfer Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/94—Bismuth compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2286—Alkynes, e.g. acetylides
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C33/04—Acyclic alcohols with carbon-to-carbon triple bonds
- C07C33/042—Acyclic alcohols with carbon-to-carbon triple bonds with only one triple bond
- C07C33/044—Alkynediols
- C07C33/046—Butynediols
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/08—Copper compounds

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Inorganic Compounds Of Heavy Metals (AREA)

JP2250175A 1974-02-25 1975-02-25 塩基性炭酸銅の結晶性粒子集塊の製法 Expired JPS594380B2 (ja)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US44547674A	1974-02-25	1974-02-25

Publications (2)

Publication Number	Publication Date
JPS50119797A JPS50119797A (xx)	1975-09-19
JPS594380B2 true JPS594380B2 (ja)	1984-01-30

Family

ID=23769056

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
JP2250175A Expired JPS594380B2 (ja)	1974-02-25	1975-02-25	塩基性炭酸銅の結晶性粒子集塊の製法
JP12805183A Granted JPS5931720A (ja)	1974-02-25	1983-07-15	１，４−ブチンジオ−ルの製造法

Family Applications After (1)

Application Number	Title	Priority Date	Filing Date
JP12805183A Granted JPS5931720A (ja)	1974-02-25	1983-07-15	１，４−ブチンジオ−ルの製造法

Country Status (7)

Country	Link
JP (2)	JPS594380B2 (xx)
BE (1)	BE825446A (xx)
DE (2)	DE2508084C2 (xx)
FR (2)	FR2264034B1 (xx)
GB (2)	GB1501459A (xx)
IT (1)	IT1033129B (xx)
NL (1)	NL183087C (xx)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee
JPH0311107Y2 (xx) *	1986-02-21	1991-03-18
JPH0413192B2 (xx) *	1984-05-30	1992-03-06	Mitsubishi Motors Corp
JPH0447026Y2 (xx) *	1986-03-10	1992-11-06

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1096134A (en) *	1976-08-05	1981-02-24	Joseph M. Fremont	Preparation of bismuth-modified spheroidal malachite
GB2039268B (en)	1978-12-15	1983-01-19	Exxon Research Engineering Co	Metal extraction by solid-liquid agglomerates
DE3417629C1 (de) *	1984-05-12	1985-01-24	Th. Goldschmidt Ag, 4300 Essen	Verfahren zur Herstellung von basischem Kupfercarbonat
DE102005042185A1 (de) *	2005-09-06	2007-03-08	Basf Ag	Verfahren zur Abtrennung von polymeren Nebenprodukten aus 1,4-Butindiol
JP5379149B2 (ja) *	2008-10-07	2013-12-25	日本曹達株式会社	テトラフルオロ化合物の製造方法
CN111589836B (zh) *	2019-09-16	2021-10-26	徐光耀	含乙炔化物的废料处理方法
CN111747439B (zh) *	2020-07-13	2023-08-29	泰兴冶炼厂有限公司	一种超高纯碱式碳酸铜制备工艺
CN115703647A (zh) *	2021-08-06	2023-02-17	阮氏化工（常熟）有限公司	利用酸性蚀刻废液连续化生产碱式碳酸铜的方法
CN114873653B (zh) *	2022-05-11	2023-10-13	金驰能源材料有限公司	碱式碳酸钴及其制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2300969A (en) *	1939-09-07	1942-11-03	Gen Aniline & Film Corp	Production of alkinols
US3650985A (en) *	1967-10-23	1972-03-21	Du Pont	Ethynylation catalyst catalyst preparation and process

1975
- 1975-02-12 BE BE153285A patent/BE825446A/xx not_active IP Right Cessation
- 1975-02-24 NL NL7502177A patent/NL183087C/xx not_active IP Right Cessation
- 1975-02-24 IT IT2058475A patent/IT1033129B/it active
- 1975-02-24 FR FR7505627A patent/FR2264034B1/fr not_active Expired
- 1975-02-25 DE DE19752508084 patent/DE2508084C2/de not_active Expired
- 1975-02-25 GB GB787775A patent/GB1501459A/en not_active Expired
- 1975-02-25 JP JP2250175A patent/JPS594380B2/ja not_active Expired
- 1975-02-25 DE DE19752560545 patent/DE2560545C2/de not_active Expired
- 1975-07-18 FR FR7522506A patent/FR2330647A1/fr active Granted
1978
- 1978-04-03 GB GB1296178A patent/GB1555297A/en not_active Expired
1983
- 1983-07-15 JP JP12805183A patent/JPS5931720A/ja active Granted

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee
JPH0413192B2 (xx) *	1984-05-30	1992-03-06	Mitsubishi Motors Corp
JPH0311107Y2 (xx) *	1986-02-21	1991-03-18
JPH0447026Y2 (xx) *	1986-03-10	1992-11-06

Also Published As

Publication number	Publication date
DE2508084A1 (de)	1975-08-28
FR2330647A1 (fr)	1977-06-03
IT1033129B (it)	1979-07-10
DE2560545C2 (de)	1986-05-07
NL183087C (nl)	1988-07-18
JPS5931720A (ja)	1984-02-20
NL183087B (nl)	1988-02-16
GB1555297A (en)	1979-11-07
FR2330647B1 (xx)	1981-06-26
FR2264034B1 (xx)	1981-06-26
JPS50119797A (xx)	1975-09-19
DE2508084C2 (de)	1984-06-07
JPS6113691B2 (xx)	1986-04-15
FR2264034A1 (xx)	1975-10-10
BE825446A (fr)	1975-08-12
GB1501459A (en)	1978-02-15
NL7502177A (nl)	1975-08-27

Publication	Publication Date	Title
JPS594380B2 (ja)	1984-01-30	塩基性炭酸銅の結晶性粒子集塊の製法
US4859432A (en)	1989-08-22	Novel ceric oxide particulates and process of making
US5243095A (en)	1993-09-07	Hydrogenation catalyst, process for preparing and process for using said catalyst
US4009124A (en)	1977-02-22	Basic mixed carbonate of copper and aluminum and process for manufacturing a copper-containing catalyst
US4305842A (en)	1981-12-15	Preparation of improved catalyst composition
US4107082A (en)	1978-08-15	Malachite preparation
JPH10510750A (ja)	1998-10-20	再構造化された酸化鉄
US5496528A (en)	1996-03-05	Rare earth oxides
JPS6183603A (ja)	1986-04-28	非晶質複合金属酸化物の製造方法
US3961037A (en)	1976-06-01	Process for forming hydrogen and carbon dioxide using a catalyst consisting essentially of oxides of copper, zinc and aluminum or magnesium
JP2000512261A (ja)	2000-09-19	メタノールの製造方法およびそのための触媒
JPS6110028A (ja)	1986-01-17	マラカイト結晶塊の凝集物及びその製造方法
US2274639A (en)	1942-03-03	Process for the production of hydrocarbons
US4143231A (en)	1979-03-06	Butinediol using catalyst prepared from synthetic malachite
CA1060876A (en)	1979-08-21	Malachite preparation
CN111686740A (zh)	2020-09-22	合成甲醇催化剂的制法
US4062899A (en)	1977-12-13	Butynediol manufacture
US3623837A (en)	1971-11-30	Process for producing fine particle size alumina hydrates
US3730886A (en)	1973-05-01	Method of purifying water
GB2128976A (en)	1984-05-10	Production of magnesium nitrate solution
WO1991004789A1 (de)	1991-04-18	Verfahren zur herstellung von säurefesten katalysatoren für die direkte hydrierung von carbonsäuren zu alkoholen
RU2100069C1 (ru)	1997-12-27	Способ приготовления катализатора
JPH0329004B2 (xx)	1991-04-22
JP2695663B2 (ja)	1998-01-14	メタノール合成用触媒の製造方法
JP3217854B2 (ja)	2001-10-15	有機金属の精製方法

JPS594380B2 - 塩基性炭酸銅の結晶性粒子集塊の製法 - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (1)

Publications (2)

Family

ID=23769056

Family Applications (2)

Family Applications After (1)

Country Status (7)

Cited By (3)

Families Citing this family (9)

Family Cites Families (2)

Cited By (3)

Also Published As

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