JPS59228740A - Heat resistant insulating plate - Google Patents

Heat resistant insulating plate

Info

Publication number
JPS59228740A
JPS59228740A JP10276083A JP10276083A JPS59228740A JP S59228740 A JPS59228740 A JP S59228740A JP 10276083 A JP10276083 A JP 10276083A JP 10276083 A JP10276083 A JP 10276083A JP S59228740 A JPS59228740 A JP S59228740A
Authority
JP
Japan
Prior art keywords
insulating layer
layer
insulating
substrate
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10276083A
Other languages
Japanese (ja)
Inventor
Tatsuro Sawano
沢野 達郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP10276083A priority Critical patent/JPS59228740A/en
Publication of JPS59228740A publication Critical patent/JPS59228740A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/34Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
    • H01L23/36Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
    • H01L23/373Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
    • H01L23/3735Laminates or multilayers, e.g. direct bond copper ceramic substrates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/26Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
    • H01L2224/31Structure, shape, material or disposition of the layer connectors after the connecting process
    • H01L2224/32Structure, shape, material or disposition of the layer connectors after the connecting process of an individual layer connector
    • H01L2224/321Disposition
    • H01L2224/32151Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/32221Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/32225Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Insulating Bodies (AREA)

Abstract

PURPOSE:To obtain heat sink and preferable withstand voltage heat resistant insulating plate by forming the first layer by binding ceramics with phosphate on an aluminum plate, and superposing Si resin or polyamideimide resin. CONSTITUTION:A binder of phosphate is added to one or more types of aggregate of ceramice (having 1-30mum of grain size) such as Al2O3, the mixture is kneaded, a coated film is dried, baked, and an insulating layer 10 of 0.1-0.15mm. thick is formed on an aluminum plate 5. Powder of Al2O3 is added to Si resin or polyamideimide resin, the film is dried and baked, an insulating layer 11 of 0.05-0.1mm. thick is superposed to form 2-layers (having totally 0.15-0.2mm. thick), A conductive layer 2 is formed thereon, and a circuit element 3 is soldered. According to this structure, a preferable heat sink heat insulating substrate can be provided inexpensively.

Description

【発明の詳細な説明】 〔発明の技術分野〕 この発明はたとえば大容量半導体素子などによる発熱の
多い電気回路に使用される耐熱性絶縁板に関する。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to a heat-resistant insulating plate used in electric circuits that generate a lot of heat, such as those caused by large-capacity semiconductor elements.

〔発明の技術的背景〕[Technical background of the invention]

たとえばエレクトロニクスの分野では、絶縁基板または
絶縁層を形成した金属基板上に導電層を形成し、この導
電層上に半導体素子などの回路素子を取付けた電子部品
がしばしば用いられる。このような電子部品の基板は、
機械的強度は勿論規定以上の耐電圧を有し、かつ、発熱
の大きい回路素子おるいは高温雰囲気中で使用するとき
には放熱良好な耐熱絶縁基板としなければならない。
For example, in the field of electronics, electronic components are often used in which a conductive layer is formed on an insulating substrate or a metal substrate on which an insulating layer is formed, and circuit elements such as semiconductor elements are mounted on the conductive layer. The substrate for such electronic components is
The heat-resistant insulating substrate must have not only mechanical strength but also a withstand voltage higher than the specified value, and good heat dissipation when used as a circuit element that generates a large amount of heat or in a high-temperature atmosphere.

従来、かかる電子部品として、前者については、第1図
に示すようにアルミナセラミック基板(1)を用い、そ
の上にたとえばAf−Pdペーストの如き導電ペースト
からなる導電層(2)を印刷し、回路素子(3)をはん
だ付けしたものが知られている。(4)はそのはんだで
ある。また、後者については、第2図に示すように鉄板
(5)にほうろうかけしたほうろう基板(6)が知られ
ている。この後者の例としては、そのほかに、熱良導体
であるアルミニウム板に熱伝導良好なアルミナをプラズ
マ溶射したもの、アルミニウム板にシん酸塩まだは珪酸
塩をバインダとする無機絶縁層を形成したものが知られ
ている。
Conventionally, for the former electronic component, as shown in FIG. 1, an alumina ceramic substrate (1) is used, on which a conductive layer (2) made of a conductive paste such as Af-Pd paste is printed, One in which the circuit element (3) is soldered is known. (4) is the solder. Regarding the latter, as shown in FIG. 2, an enameled substrate (6) made by enameling an iron plate (5) is known. Other examples of the latter include plasma-sprayed alumina, which is a good thermal conductor, on an aluminum plate, which is a good thermal conductor, and aluminum plates with an inorganic insulating layer made of phosphate or silicate as a binder. It has been known.

〔背景技術の問題点〕[Problems with background technology]

(1)アルミナセラミック基板(1)を用いたものは機
械強度が弱く破損しやすい。また、コスト高になる欠点
がある。
(1) Those using an alumina ceramic substrate (1) have low mechanical strength and are easily damaged. Furthermore, there is a drawback that the cost is high.

(2)はうろう基板(6)は650〜800℃の高温で
焼成するため、一般に鉄板(5)が使用され、熱伝導良
好なアルミニウム板を使用できない欠点がある。
(2) Since the floating substrate (6) is fired at a high temperature of 650 to 800°C, an iron plate (5) is generally used, which has the disadvantage that an aluminum plate with good heat conductivity cannot be used.

(3)アルミナをプラズマ溶射した絶縁基板は溶射膜の
密着が弱く剥離しやすい。また、プラズマ溶射がコスト
高となる。
(3) Insulating substrates coated with alumina by plasma spraying have weak adhesion and are easily peeled off. Furthermore, plasma spraying is expensive.

(4)シん酸塩、珪酸塩などをバインダとする無機絶縁
層を形成した絶縁基板は耐電圧、絶縁抵抗などの電気特
性が劣る。
(4) An insulating substrate formed with an inorganic insulating layer using a binder such as sicrate or silicate has poor electrical properties such as withstand voltage and insulation resistance.

〔発明の目的〕[Purpose of the invention]

この発明は放熱良好な耐熱絶縁基板を安価に提供するこ
とを目的とする。
An object of the present invention is to provide a heat-resistant insulating substrate with good heat dissipation at a low cost.

〔発明の概璧〕[Synopsis of the invention]

アルミニウム板上にセラミックスを羽村とし、シん酸塩
をバインダとする第1絶KMを形成し、この第1絶縁層
上にシリコーン樹脂またはポリアミドイミドからなる第
2絶縁層を形成して、熱放散および耐電圧良好な耐熱絶
縁板とした。
A first insulating layer made of ceramics and sinate as a binder is formed on an aluminum plate, and a second insulating layer made of silicone resin or polyamide-imide is formed on this first insulating layer to dissipate heat. and a heat-resistant insulating board with good voltage resistance.

実施例 第3図はアルミニウム板(5)上に順次第1絶縁層(1
0,第2絶縁層(li)を形成し、この第2絶縁MaD
上に導電層(2)を形成したのち、回路素子(3)をは
んだ付けしたもので、前記第1図および第2図に示した
電子部品に対応した構造のものであるが、アルミニウム
板(5)に第1.第2絶縁層(10)(11)が形成さ
れた絶縁基板(121を用いている点が異なる。
Embodiment FIG. 3 shows one insulating layer (1
0, a second insulating layer (li) is formed, and this second insulating layer (MaD)
After forming a conductive layer (2) thereon, a circuit element (3) is soldered to it, and the structure corresponds to the electronic component shown in FIGS. 1 and 2. However, an aluminum plate ( 5) First. The difference is that an insulating substrate (121) on which a second insulating layer (10) (11) is formed is used.

上記絶縁基板a2)の第1絶縁層00)はアルミナ、シ
リカ、マグネシャ、ベリリア、ジルコニアなどのセラミ
ックス材料を骨材とし、その一種または複数種に9ん酸
塩系バインダを加えて混練した無機塗料を塗布したのち
乾燥、焼成して形成される。
The first insulating layer 00) of the insulating substrate a2) is an inorganic paint made of a ceramic material such as alumina, silica, magnesia, beryllia, or zirconia as an aggregate, and one or more of them mixed with a nonaphosphate binder. It is formed by coating, drying, and firing.

この場合、バインダに混練する骨材の粒度としては1〜
30μmが適切である。
In this case, the particle size of the aggregate mixed into the binder is 1 to 1.
30 μm is suitable.

第2絶縁層(11)は上記第1絶縁)f4 GO)形成
後に形成される。この第2絶縁層αυはシリコーン樹脂
捷たはポリアミドイミド樹脂、好ましくはこれら樹脂に
アルミナ、マイカなど無機絶縁物粉末を添加した塗料を
塗布、乾燥、焼成して形成される。
A second insulating layer (11) is formed after forming the first insulating layer (f4 GO). The second insulating layer αυ is formed by coating a silicone resin or a polyamide-imide resin, preferably a paint prepared by adding inorganic insulating powder such as alumina or mica to these resins, drying, and baking.

この絶縁基板(1艶の絶縁層の膜厚は第1杷縁層00)
を0.1〜0.15 mm 、第2絶縁層圓を0−05
〜0.1 mm程度に形成し、2層の合計の厚さを0.
15〜0.2mm程度にすることにより十分な電気的特
性をもたすことができる。第1表にアルミニウム板(5
)にスミセラムS −208D (住友化学製)を用い
て第1絶縁層00)を形成し、ダイモマッハS −20
02,K ()ピーエ業製)を用いて第2絶縁層αυを
形成し、それら膜厚の変化したときの電気特性を第1.
第2絶縁層utn、■単独の場合、および絶縁層をアル
ミナ溶射で形成した従来例と比較して示した。
This insulating substrate (the thickness of the insulating layer of 1 gloss is 000 for the first lozenge layer)
0.1~0.15 mm, second insulating layer radius 0-05 mm
~0.1 mm, and the total thickness of the two layers is 0.1 mm.
By setting the thickness to about 15 to 0.2 mm, sufficient electrical characteristics can be obtained. Table 1 shows the aluminum plate (5
), a first insulating layer 00) was formed using Sumiceram S-208D (manufactured by Sumitomo Chemical), and Dymo Mach S-20
02,K (manufactured by PV Industry Co., Ltd.) to form the second insulating layer αυ, and the electrical characteristics when the film thickness was changed were as follows.
A case where the second insulating layer utn, (2) is used alone, and a comparison with a conventional example in which the insulating layer is formed by spraying alumina are shown.

以下、この第1.第2絶縁層α0)、(11)の形成を
具体例について示す。
Below, this first part. A specific example of the formation of the second insulating layers α0) and (11) will be described.

(具体例1) 厚さ0.15mmのアルミニウム板にシリカ粉末、シん
酸アルミニウムからなるスミ上ラムS−20Jt−スプ
レーガンにて塗布し、300℃で30分焼成し、厚さQ
、lttrmの第1絶縁層を形成したのち、合成マイカ
粉末、シリコーン樹脂スからなるダイモマソハS−20
02Kをスプレー塗布し、200°C160分焼付乾燥
して、厚さO,1mの第2絶縁層を形成し、耐電圧30
00V、 150°C熱板上ツメカー値2000MΩノ
絶縁基板を形成した。また、この絶縁基板に半導体装置
を実装して連続通電した場合の素子湿度上昇はアルミナ
溶射基板と同程度であった。また、絶縁基板をioaで
90°折曲げた場合の絶縁層の密着性はアルミナ溶射基
板および第1絶縁層を単独に形成した基板に比べてすぐ
れていた。これら特性は無機質の第1絶縁層と有機質の
第2絶縁層を薄層状態で重ねることにより単純に得られ
たもので、第1絶縁層または第2絶縁層の単独では得が
たいものである。
(Specific Example 1) Silica powder and aluminum sulfate were coated on an aluminum plate with a thickness of 0.15 mm using a Sumikaram S-20Jt spray gun, and baked at 300°C for 30 minutes to give a thickness of Q.
After forming the first insulating layer of , lttrm, Dymoma Soha S-20 made of synthetic mica powder and silicone resin
02K was spray-coated and baked at 200°C for 160 minutes to form a second insulating layer with a thickness of 0.1 m, and the withstand voltage was 30.
An insulating substrate having a force value of 2000 MΩ was formed on a hot plate at 00V and 150°C. Further, when a semiconductor device was mounted on this insulating substrate and continuously energized, the increase in element humidity was comparable to that of an alumina sprayed substrate. Furthermore, the adhesion of the insulating layer when the insulating substrate was bent at 90° at IOA was superior to that of the alumina sprayed substrate and the substrate on which the first insulating layer was formed alone. These characteristics are obtained simply by laminating the inorganic first insulating layer and the organic second insulating layer in a thin layer state, and are difficult to obtain by using the first insulating layer or the second insulating layer alone.

(具体例2) 厚さ0.15mmのアルミニウム板にスミセラムS−2
osMをスプレーガンで塗布し、300℃で30分焼成
し厚さ0.1FMmの第1絶縁層を形成したのち、固形
分3Qwt%含むポリアミドイミド樹脂フェスに3μm
粒径のアルミナ粉末を55wt%混練したペーストをス
クリーン印刷し、220℃で15分焼付乾燥して厚さ0
.1關の第2絶縁層を形成し、具体例1とほぼ同様の結
果を得た。
(Specific example 2) Sumiceram S-2 on an aluminum plate with a thickness of 0.15 mm
After applying osM with a spray gun and baking it at 300°C for 30 minutes to form a first insulating layer with a thickness of 0.1FMm, a 3μm thick layer was applied to a polyamide-imide resin face containing 3Qwt% solids.
A paste made by kneading 55 wt% of alumina powder with a particle size was screen printed, baked at 220°C for 15 minutes, and dried to a thickness of 0.
.. One second insulating layer was formed, and almost the same results as in Example 1 were obtained.

〔発明の効果〕〔Effect of the invention〕

(1)無機質または有機質の単独では厚い絶縁層を形成
しないと、所要の電気特性を得ることができないが、無
機質の第1絶縁層と有機質の第2絶縁層とを重ねると、
比較的薄い絶縁層で所要の電気特性を得ることができる
(1) If an inorganic or organic material is used alone, the required electrical properties cannot be obtained unless a thick insulating layer is formed, but when an inorganic first insulating layer and an organic second insulating layer are stacked,
Required electrical properties can be obtained with a relatively thin insulating layer.

(2)絶縁層が薄いために放熱性、基板に対する脣着性
が良好である。
(2) Since the insulating layer is thin, heat dissipation and adhesion to the substrate are good.

【図面の簡単な説明】[Brief explanation of drawings]

第1図および第2図はそれぞれ絶縁基板に回路素子を取
付けた従来の電子部品の図、第3図はこの発明の絶縁基
板に回路素子を取付けた電子部品の図である。 (5)ニアルミニウム板   (2):導電層(3)二
重路素子    (10) :第1絶縁層(11) :
第2絶縁層 代理人 弁理士  則 近 憲 佑 (ほか1名) γ 二f 電 2 目 一回て γ 3 区 ≦工 3 〜4 ] 3 4 ヨヨヨ 3 ど−2 會
1 and 2 are diagrams of a conventional electronic component in which a circuit element is mounted on an insulating substrate, and FIG. 3 is a diagram of an electronic component in which a circuit element is mounted on an insulating substrate according to the present invention. (5) Nialuminum plate (2): Conductive layer (3) Double path element (10): First insulating layer (11):
2nd Insulating Layer Agent Patent Attorney Nori Kensuke Chika (and 1 other person) γ 2f Den 2 Once in a while γ 3 Ward ≦ Engineering 3 ~ 4] 3 4 Yoyoyo 3 Do-2 Meeting

Claims (1)

【特許請求の範囲】[Claims] 金属基板と、熱伝導良好な耐熱絶縁性のセラミックスを
骨材とし、pん酸塩を結合剤として上記金属基板に密着
形成された第1層と、シリコーン樹脂またはポリアミド
イミド樹脂のいづれかからなる上記第1層上に密着形成
された第2層とを具備することを特徴とする耐熱性絶縁
板。
A metal substrate, a first layer formed in close contact with the metal substrate using a heat-resistant insulating ceramic with good heat conduction as an aggregate and a phosphate as a binder, and the above-mentioned layer consisting of either a silicone resin or a polyamide-imide resin. A heat-resistant insulating board comprising a second layer closely formed on the first layer.
JP10276083A 1983-06-10 1983-06-10 Heat resistant insulating plate Pending JPS59228740A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10276083A JPS59228740A (en) 1983-06-10 1983-06-10 Heat resistant insulating plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10276083A JPS59228740A (en) 1983-06-10 1983-06-10 Heat resistant insulating plate

Publications (1)

Publication Number Publication Date
JPS59228740A true JPS59228740A (en) 1984-12-22

Family

ID=14336147

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10276083A Pending JPS59228740A (en) 1983-06-10 1983-06-10 Heat resistant insulating plate

Country Status (1)

Country Link
JP (1) JPS59228740A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2646018A1 (en) * 1989-04-12 1990-10-19 Mitsubishi Electric Corp SEMICONDUCTOR DEVICE AND MANUFACTURING METHOD THEREOF
EP1020914A2 (en) * 1989-10-09 2000-07-19 Mitsubishi Materials Corporation Ceramic substrate used for fabricating electric or electronic circuit

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2646018A1 (en) * 1989-04-12 1990-10-19 Mitsubishi Electric Corp SEMICONDUCTOR DEVICE AND MANUFACTURING METHOD THEREOF
EP1020914A2 (en) * 1989-10-09 2000-07-19 Mitsubishi Materials Corporation Ceramic substrate used for fabricating electric or electronic circuit
EP1020914A3 (en) * 1989-10-09 2000-08-02 Mitsubishi Materials Corporation Ceramic substrate used for fabricating electric or electronic circuit

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