JPS59224392A - Thermal transfer material - Google Patents
Thermal transfer materialInfo
- Publication number
- JPS59224392A JPS59224392A JP58098775A JP9877583A JPS59224392A JP S59224392 A JPS59224392 A JP S59224392A JP 58098775 A JP58098775 A JP 58098775A JP 9877583 A JP9877583 A JP 9877583A JP S59224392 A JPS59224392 A JP S59224392A
- Authority
- JP
- Japan
- Prior art keywords
- ink layer
- thermal transfer
- heat
- ink
- transfer material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/38228—Contact thermal transfer or sublimation processes characterised by the use of two or more ink layers
Abstract
Description
【発明の詳細な説明】
本発明は、熱転写性能と保存性とを兼ね備えた感熱転写
材に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a thermal transfer material that has both thermal transfer performance and storage stability.
近年、情報産業の急速な発展に伴ない１種々の情報処理
システムが開発され、また、それぞれの情報処理システ
ムに適した記録方法および装置も開発、採用されている
。このような記録方法の一つとして、感熱記録方法は、
使用する装置が軽量かつコンパクトで騒音がなく、操作
性、保守性にも優れており、最近広く使用されている。In recent years, with the rapid development of the information industry, various information processing systems have been developed, and recording methods and devices suitable for each information processing system have also been developed and adopted. One such recording method is the thermal recording method.
The equipment used is lightweight, compact, noiseless, and has excellent operability and maintainability, and has recently been widely used.
しかし感熱記録方法に用いられる記録紙のうち、通常の
感熱記録紙は、発色剤と顕色剤とを含有する発色型の加
工紙であるため高価であり、また記録の改ざんが可能で
、記録紙が熱や有機溶剤により容易に発色したり、比較
的短時間に記録像が退色するなど記録の保存性が悪い欠
点を有する。However, among the recording papers used in thermal recording methods, ordinary thermal recording paper is a color-forming processed paper containing a color former and a color developer, so it is expensive, and records can be tampered with. The paper has disadvantages in that it has poor storage stability, such as the paper easily developing color due to heat or organic solvents, and the recorded image fading in a relatively short period of time.
］二記した感熱記録方法の長所を維持し、感熱記録紙の
使用に伴なう欠点を補うものとして、最近特に注目され
ているのが、感熱転写記録方法である。] The thermal transfer recording method has recently been attracting particular attention as a method that maintains the advantages of the thermal recording method mentioned above and compensates for the drawbacks associated with the use of thermal recording paper.
この感熱転写記録方法は、一般に、シート状の支持体上
に、熱溶融性バインダー中に着色剤を分散させてなる熱
転写性インクを溶融塗布してなる感熱転写材を用い、こ
の感熱転写材をその熱転写性インク層が記録媒体に接す
るように記録媒体に重畳し、感熱転写材の支持体側から
熱ヘッドにより熱を供給して溶融したインク層を記録媒
体に転写することにより、記録媒体上に熱供給形状に応
した転写インク像を形成するものである。この方法によ
れば、感熱記録方法の上記した利点を維持し且つ汀通紙
を記録媒体として使用可能であり１．１記した感熱記録
方法の使用に伴なう欠点も除くことができる。This heat-sensitive transfer recording method generally uses a heat-sensitive transfer material made by melt-coating a heat-transferable ink made of a heat-melting binder with a colorant dispersed on a sheet-like support. The thermally transferable ink layer is superimposed on the recording medium so as to be in contact with the recording medium, and heat is supplied from the support side of the thermal transfer material by a thermal head to transfer the melted ink layer onto the recording medium. A transfer ink image is formed according to the heat supply shape. According to this method, while maintaining the above-mentioned advantages of the thermal recording method, it is possible to use paper passing through the paper as a recording medium, and the disadvantages associated with the use of the thermal recording method described in 1.1 can also be eliminated.
しかしながら、このような優れた特徴を有する感熱転写
記録方法においても、なおいくつかの改良を要すべき点
がある。その一つは、熱転写性能、特に少ないエネルギ
ーであるいは比較的短時間での加熱により鮮明な記Ｎ像
を与えるための記録感度の向−１ユである。この熱転写
性能の向上のためには、融点の低い熱溶融性バインダー
を使用することも考えられるが、この場合には、熱転写
性インク層が比較的低温においても粘着性をおび、感熱
転写材の保存性の低ド、感熱転写材と接触する記録媒体
の低温時における汚損あるいは非印字部での汚損嘗の不
都合を生ずる。However, even in a thermal transfer recording method having such excellent characteristics, there are still some points that require improvement. One of these is the improvement of thermal transfer performance, particularly recording sensitivity in order to provide clear recorded images by heating with little energy or in a relatively short time. In order to improve this thermal transfer performance, it is possible to use a heat-melting binder with a low melting point, but in this case, the heat-transferable ink layer becomes sticky even at relatively low temperatures, and the heat-sensitive transfer material becomes sticky. This results in problems such as poor storage stability, staining of the recording medium in contact with the thermal transfer material at low temperatures, or staining in non-printing areas.
本発明の主要な目的は、上記した従来の感熱転写材の欠
点を除き、熱転写性能と保存性とを兼ね備えた感熱転写
材を提供することにある。A main object of the present invention is to provide a thermal transfer material that has both thermal transfer performance and storage stability, while eliminating the drawbacks of the conventional thermal transfer materials described above.
本発明者の研究によれば相矛盾する要素を含む熱転写性
能と保存性の両者を満足させるためには、一層の熱転写
性インク層では不適当であり、熱転写性インク層自体を
複層化し、特に支持体側の一層を比較的低融点化するこ
とが有効であることが見出された。According to the research of the present inventor, in order to satisfy both the contradictory factors of thermal transfer performance and storage stability, a single thermal transfer ink layer is inadequate, and the thermal transfer ink layer itself is multilayered. It has been found that it is particularly effective to lower the melting point of one layer on the support side to a relatively low melting point.
本発明の感熱転写材は、上述の知見に基づくものであり
、より詳しくは、支持体上に熱転写性インク層を形成し
てなり、該熱転写性インク層が、支持体側から順に設け
た、比較的低融点の熱溶融性バインダーからなる第１イ
ンク層と比較的高融点の熱溶融性バインダーからなる第
２インク層とからなり、且つ前記第１インク層と第２イ
ンク層の少なくとも一層には着色剤が含まれていること
を特徴とするものである。The heat-sensitive transfer material of the present invention is based on the above-mentioned knowledge, and more specifically, the heat-transferable ink layer is formed on a support, and the heat-transferable ink layer is provided in order from the support side. a first ink layer made of a thermofusible binder with a relatively low melting point and a second ink layer made of a thermofusible binder with a relatively high melting point, and at least one of the first ink layer and the second ink layer contains It is characterized by containing a coloring agent.
以下、必要に応じて図面を参照しつつ、本発明を更に詳
細に説明する。以下の記載において猜比を表わす「％」
およびＥ部」は、特に断わらない限り重量基準とする。Hereinafter, the present invention will be described in further detail with reference to the drawings as necessary. “%” represents percentage in the following descriptions.
and "Part E" are based on weight unless otherwise specified.
第１図は、本発明の最も基本的な態様における感熱転写
材の厚さ方向栓式断面図である。すなわち感熱転写材ｌ
は、通常はシート（フィルムを包含する趣旨で用いる）
状の支持体？上に熱転写性インク層３を形成してなる。FIG. 1 is a plug-type sectional view in the thickness direction of a heat-sensitive transfer material in the most basic embodiment of the present invention. That is, thermal transfer material l
is usually a sheet (used to include film)
shaped support? A thermally transferable ink layer 3 is formed thereon.
また熱転写性インク層３は、それ自体複層拾遺を有し、
支持体側から順に３；ｔけた第１インク層３ａおよび第
２インク層３ｂの２層からなる。更に第１インク層と第
２インク層の少なくとも一層には１着色剤（特に図示せ
ず）が分散ないし相溶状態で含まれている。Further, the thermal transferable ink layer 3 itself has a multilayer feature,
It consists of two layers, a first ink layer 3a and a second ink layer 3b, spaced apart by 3;t from the support side. Further, at least one of the first ink layer and the second ink layer contains a colorant (not particularly shown) in a dispersed or compatible state.
支持体２としては、従来より公知のフィルムや紙をその
まま使用することができ、例えばポリエステル、ボゲカ
ーポネート、トリアセチルセルロース、ナイロン、ポリ
イミド等の比較的耐熱性の良いプラスチックのフィルム
、セロハシあるいは硫酸紙などが好適に使用できる。支
持体の厚さは、熱転写に際しての熱源として熱ヘッドを
考慮する場合には２〜１５ミクロン程度であることが望
ましいが、たとえばレーザー光等の熱転写性インク層を
選択的に加熱できる熱源を使用する場合には特に開眼は
ない、また熱ヘッドを使用する場合に、熱ヘッドと接触
する支持体の表面に、シリコーン樹脂、ふっ素樹脂、ポ
リイミド樹脂、エポキシ樹脂、フェノール樹脂、メラミ
ンｍ １ｌｔｉ、ニトロセルロース等からなる＃熱性保
ｉ：Ｉ Ｗｊを設けることにより支持体の耐熱性を向上
することができ、あるいは従来用いることのできなかっ
た支持体材料を用いることもできる。As the support 2, conventionally known films and papers can be used as they are, such as films of relatively heat-resistant plastics such as polyester, bogey carbonate, triacetyl cellulose, nylon, and polyimide, cellophane, or parchment paper. can be suitably used. The thickness of the support is preferably about 2 to 15 microns when considering a thermal head as a heat source during thermal transfer, but for example, a heat source such as a laser beam that can selectively heat the thermal transferable ink layer is used. In addition, when using a thermal head, the surface of the support that comes into contact with the thermal head may contain silicone resin, fluororesin, polyimide resin, epoxy resin, phenolic resin, melamine m1lti, nitrocellulose. The heat resistance of the support can be improved by providing #thermal resistance i:I Wj, etc., or it is also possible to use a support material that could not be used conventionally.
第１インク層および第２インク層を構成する熱溶融性バ
インダーは、それぞれ、カルナウバワックス、パラフィ
ンワックス、サゾールワックス。The heat-melting binders constituting the first ink layer and the second ink layer are carnauba wax, paraffin wax, and Sasol wax, respectively.
マイクロクリスタリンワックス、カスターワックス等の
ワックス類；ステアリン酸、パルミチン酸、ラウリン酸
、ステアリン酸アルミニウム、ステアリン醜鉛、ステア
リン酸バリウム、ステアリン醜亜鉛、パルミチン酸亜鉛
、メチルヒドロキシステアレート、グリセロールモノヒ
ドロキシステアレート等の高級脂肪酸あるいはその金属
１１！、エステル等の誘導体；ポリエチレン、ポリプロ
ピレン、ポリイソブチレン、ポリエチレンワックス、ｄ
化ポリエチレン、ポリ四ふっ化エチレン、エチレンーア
クリル酸共重合体、エチレン−アクリル酸エチル共重合
体、エチレン−酢酸ビニル共重合体等のオレフィンの？
ｌｉ独または共重合体あるいはこれらの誘導体等からな
る熟加塑性樹脂などから、その融点等を考慮して適宜選
択される。Waxes such as microcrystalline wax and castor wax; stearic acid, palmitic acid, lauric acid, aluminum stearate, lead stearate, barium stearate, zinc stearate, zinc palmitate, methyl hydroxystearate, glycerol monohydroxystearate Higher fatty acids such as or metals 11! , derivatives such as esters; polyethylene, polypropylene, polyisobutylene, polyethylene wax, d
of olefins such as polyethylene, polytetrafluoroethylene, ethylene-acrylic acid copolymer, ethylene-ethyl acrylate copolymer, ethylene-vinyl acetate copolymer, etc.
The material is appropriately selected from mature plastic resins made of li, copolymers, derivatives thereof, etc., taking into account its melting point and the like.
インク層３ａお木び３ｂを構成する熱溶融性バインダー
は、それぞれに記した熱溶融性バインダーの一種または
二種以上を混合することにより得られる。第１インクＲ
３ａを構成する熱溶融性バインダーは、５０〜６０°Ｃ
の範囲の融点を有することが好ましく、また第２インク
ｆｉ３ｂを構成する熱溶融性バインダーは、本発明にし
たがい、第１インク層３ｂを構成する熱溶融性バインダ
ーよりも１０〜２０ ’Ｃ高い融点を有することが好ま
しい。またインクＷｊ ３ ａ、インクｉ３ｂの厚さは
、それぞれｌ〜５ｐＬの範囲であり、熱転写性インク層
３の合計厚さは２〜ｌＯ＃１．であることが好ましい。The heat-melting binder constituting the ink layer 3a and the wood 3b can be obtained by mixing one or more of the heat-melting binders described respectively. 1st ink R
The thermofusible binder constituting 3a is 50 to 60°C
According to the present invention, the thermofusible binder constituting the second ink fi3b preferably has a melting point in the range of 10 to 20'C higher than that of the thermofusible binder constituting the first ink layer 3b. It is preferable to have. The thicknesses of the ink Wj 3 a and the ink i3b are each in the range of 1 to 5 pL, and the total thickness of the thermal transferable ink layer 3 is in the range of 2 to 1 O#1. It is preferable that
インクＢ４３ ａおよび３ｂの少なくとも一層には着色
剤が含まれる。いずれか一層に加える場合には、第２イ
ンク層３ｂに加えることが望ましい。At least one layer of inks B43a and 3b contains a colorant. When added to any one layer, it is desirable to add it to the second ink layer 3b.
これは、インク層が記録媒体に転写した後において、着
色剤含有層を未含有層がおおう形態となり、擦過等の外
力を受けても着色剤含有層への影響を防止できるためで
ある０着色剤としては、印刷、記録の分野で広く用いら
れている各種の染、顔料あるいはカーボンブラックなど
を使用できる。This is because after the ink layer is transferred to the recording medium, the colorant-containing layer is covered with a non-colorant-containing layer, which prevents the colorant-containing layer from being affected by external forces such as scratches. As the agent, various dyes, pigments, carbon black, etc. that are widely used in the fields of printing and recording can be used.
着色剤の含有量は、インク１７．３ ａおよび３ｂのそ
れぞれについて６０％以下、熱転写性インク層３全体と
して５〜５０％の範囲が適当である。The content of the colorant is suitably 60% or less for each of inks 17.3a and 3b, and 5 to 50% for the thermal transferable ink layer 3 as a whole.
本発明の感熱転写材を得るには、インク層３ａおよび３
ｂのそれぞれについて、上記した熱溶融性バインダー、
着色剤およびこの種のインク層に通常加えられる任意添
加剤を、アトライター等の分散装置を用いて溶融混練す
るか、あるいは適当な溶剤とともに混練して、熱溶融性
あるいは溶液ないし分散液状のインクを得、これらイン
クを支持体上に順次塗布し、必要に応じて乾燥すること
により、第１インク層３ａ、第２インクＷ３ｂの順で形
成すればよい。In order to obtain the thermal transfer material of the present invention, ink layers 3a and 3
For each of b, the above-mentioned hot-melt binder,
A colorant and optional additives normally added to this type of ink layer are melted and kneaded using a dispersion device such as an attritor, or kneaded with a suitable solvent to form a hot-melt, solution or dispersion ink. The first ink layer 3a and the second ink W3b may be formed in this order by sequentially applying these inks onto a support and drying as necessary.
未発ＩＪＩＪの感熱転写材の平面形状は、特に限定され
ないが、一般にタイプライタ−リボン状あるいはライン
プリンター等に用いられる広幅のテープ状などの形態で
使用される。またカラー記録のために何種類かの色調の
熱溶融性インクをストライプ状あるいはブロック状に塗
り分けた感熱転写材とすることもできる。The planar shape of the undeveloped IJIJ thermal transfer material is not particularly limited, but it is generally used in the form of a typewriter ribbon or a wide tape used in line printers. Further, for color recording, it is also possible to use a heat-sensitive transfer material in which heat-melting inks of several different tones are applied in stripes or blocks.
」−記感熱転写材を用いる感熱転写記録方法は、通常の
感熱転写記録方法と特に異なるものではないが、念のた
め熱源として最も典型的な熱ヘッドを用いる場合につい
て説明する。第２図は、その４！！を要を示す感熱転写
材の厚さ方向役人断面図である。すなわち感熱転写材ｌ
の熱溶融性インク層３に記録媒体４を密着させ、必要に
応じて更に記録媒体の背面からプラテン５によって熱パ
ルスを与えながら熱ヘッド６によって熱パルスを与えて
、インク層３を所望の印字ないし転写パターンに応じて
局部的に加熱する。インク層３の被加熱部は温度−Ｊ−
昇し、特にその第１インクＤ ３ ａから速やかに溶融
し、溶融ないし軟化した第２インク層３ｂとともに記録
媒体に転写され、感熱転写材の剥離後、記録媒体４上に
インク転写像３Ｃを残す。A thermal transfer recording method using a thermal transfer material is not particularly different from a normal thermal transfer recording method, but just to be sure, the case where the most typical thermal head is used as a heat source will be described. Figure 2 is part 4! ! FIG. 3 is a cross-sectional view in the thickness direction of the heat-sensitive transfer material showing the main points. That is, thermal transfer material l
The recording medium 4 is brought into close contact with the heat-melting ink layer 3 of the recording medium, and if necessary, heat pulses are applied from the back side of the recording medium by the platen 5 and the thermal head 6 to apply the heat pulses to the ink layer 3 for desired printing. Or locally heated according to the transfer pattern. The heated part of the ink layer 3 has a temperature of -J-
In particular, the first ink D 3 a quickly melts and is transferred to the recording medium together with the melted or softened second ink layer 3b, and after the thermal transfer material is peeled off, an ink transfer image 3C is formed on the recording medium 4. leave.
上記においては熱転写記録の熱源として熱ヘッドを用い
る例を説明したが、レーザー光等の他の熱源を用いる場
合にも同様に実施できることは容易に理解できよう。Although an example in which a thermal head is used as a heat source for thermal transfer recording has been described above, it is easy to understand that the present invention can be implemented similarly when using other heat sources such as laser light.
以上、詳細に説明したように、本発明によれば支持体上
の熱転写性インク層を複層化し熱転写性インク層と隣接
するインク層に比較的低融点の熱溶融性バインダーを用
いることにより、熱転写性能、特に記録感一度と保存性
を兼ね備えた感熱転写材が提供される。As explained above in detail, according to the present invention, by forming the thermally transferable ink layer on the support into multiple layers and using a relatively low melting point heat-melting binder in the ink layer adjacent to the thermally transferable ink layer, Provided is a thermal transfer material that has thermal transfer performance, especially a good recording feel and good storage stability.
以ド、実施例により本発明を更に具体的に説明する。Hereinafter, the present invention will be explained in more detail with reference to Examples.
実施例
パラフィン（腸、ｐ、５０〜５５℃） ５０部カ
ルナウバワックス ２５部エチレン−酢
酸ビニル共重合体 ２５部（エチレン／酢酸ビニル
＝ １３０／１０ ）Ｌ記各成分を容器に入れ、１５０
℃に加熱し、ホモミキサーにより均一分散させた。この
溶融物を厚さ６川のポリエチレンテレフタレートフィル
ムＪ−にワイヤーバーを用いて塗布し、厚さ５ＪＬの第
１インク層（融点約６０℃）を設けた。別に、ド記各成
分を７トライターを用いて、３００部のＩ・ルエン中に
加温分散させ、徐々に室温まで冷却してミクロ分散液状
の着色インクを得た。Example Paraffin (intestinal, p, 50-55°C) 50 parts Carnauba wax 25 parts Ethylene-vinyl acetate copolymer 25 parts (ethylene/vinyl acetate = 130/10) Place each component in a container and add 150 parts
℃ and uniformly dispersed using a homomixer. This melt was applied to a polyethylene terephthalate film J- with a thickness of 6 mm using a wire bar to provide a first ink layer (melting point: about 60°C) with a thickness of 5 JL. Separately, each of the above components was dispersed under heating in 300 parts of I.luene using 7 triliters, and the mixture was gradually cooled to room temperature to obtain a colored ink in the form of a microdispersed liquid.
カーボンブラック ２５部パラフィン
（ｎ＋、ｐ、８０〜７０℃） ３５５部カルナラ
へンクス ２０部エチレン−酢酸ビニル
共重合体 ２０部（エチレン／酢酸ビニル＝ ９０
／１０ ）このインクを、−１−記で得た第１インク層
上に。Carbon black 25 parts Paraffin (n+, p, 80-70°C) 355 parts Karnara Henx 20 parts Ethylene-vinyl acetate copolymer 20 parts (ethylene/vinyl acetate = 90
/10) This ink was placed on the first ink layer obtained in -1-.
ワイヤーバーを用いて塗布し、乾燥して厚さ３１１゜の
第２インク層（融点約７５℃）を形成して本発明による
感熱転写材を得た。A second ink layer (melting point: about 75° C.) having a thickness of 311° was formed by coating using a wire bar and drying to obtain a thermal transfer material according to the present invention.
次いで、このようにして得られた感熱転写材を用い、木
質的に第２図により説明したような態様で、印字圧力１
．６Ｋｇ／ゴ、印加パルスＩｔｌ ５ ｍ、ｓｅｅで感
熱転写記録を行なったところ、記録紙上に、ぼやけやに
じみのない鮮明な印字が得られた。また、上記感熱転写
材の熱転写性インク層は常温においては全く粘着性がな
く保存性も良好であった。Next, using the heat-sensitive transfer material thus obtained, a printing pressure of 1
．． When thermal transfer recording was performed at 6 kg/g and an applied pulse of 5 m, see, clear print without blurring or bleeding was obtained on the recording paper. Furthermore, the thermal transferable ink layer of the thermal transfer material had no tackiness at room temperature and had good storage stability.
第１図は本発明の感熱転写材の一実施例の厚さ方向模式
断面図、第２図は第１図の感熱転写材を用いる感熱転写
記録方法の実施態様を説明するための感熱転写材の厚さ
方向で見た校式断面図である。
ｌ−拳・感熱転写材
２・・・支持体
３・・φ熱転写性インク層
３ａ１１＠拳第１インク層
３ｂＩＩＩ１１１第２インク層
３ｃ・・・転写記録像
４・・・記録媒体
５０１プラテンFIG. 1 is a schematic cross-sectional view in the thickness direction of an embodiment of the thermal transfer material of the present invention, and FIG. 2 is a thermal transfer material for explaining an embodiment of a thermal transfer recording method using the thermal transfer material of FIG. 1. FIG. 3 is a sectional view of the calibration type viewed in the thickness direction. l-fist/thermal transfer material 2... support 3... φ thermal transferable ink layer 3a11@fist first ink layer 3bIII111 second ink layer 3c... transfer recorded image 4... recording medium 501 platen
Claims (1)
性インク層が、支持体側から順に設けた、比較的低融点
の熱溶融性バインダーからなる第１インク層と比較的高
融点の熱溶融性バインダーからなる第２インク層とから
なり、且つ前記第１インク層と第２インク屑の少なくと
も一層には着色剤が含まれていることを特徴とする感熱
転写材。A heat-transferable ink layer is formed on a support, and the heat-transferable ink layer includes a first ink layer made of a heat-melting binder having a relatively low melting point and a heat-transferable ink layer having a relatively high melting point, which is provided in order from the support side. 1. A heat-sensitive transfer material comprising a second ink layer made of a meltable binder, and at least one of the first ink layer and second ink waste contains a colorant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58098775A JPS59224392A (en) | 1983-06-04 | 1983-06-04 | Thermal transfer material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58098775A JPS59224392A (en) | 1983-06-04 | 1983-06-04 | Thermal transfer material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59224392A true JPS59224392A (en) | 1984-12-17 |
| JPH0466717B2 JPH0466717B2 (en) | 1992-10-26 |
Family
ID=14228746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58098775A Granted JPS59224392A (en) | 1983-06-04 | 1983-06-04 | Thermal transfer material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59224392A (en) |
Cited By (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60115488A (en) * | 1983-11-29 | 1985-06-21 | Ricoh Co Ltd | Thermal transfer recording medium |
| JPS60176798A (en) * | 1984-02-22 | 1985-09-10 | Toppan Printing Co Ltd | Thermal transfer film |
| JPS60239285A (en) * | 1984-05-15 | 1985-11-28 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
| JPS60240493A (en) * | 1984-05-16 | 1985-11-29 | Toppan Printing Co Ltd | Multilayered thermal transfer sheet |
| JPS6151388A (en) * | 1984-08-20 | 1986-03-13 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS6178692A (en) * | 1984-09-26 | 1986-04-22 | Mitsubishi Paper Mills Ltd | Thermal transfer material |
| JPS61114889A (en) * | 1984-11-08 | 1986-06-02 | Alps Electric Co Ltd | Thermal transfer medium |
| JPS61116592A (en) * | 1984-11-13 | 1986-06-04 | Carbon Paper Kk | Thermal transfer type recording medium |
| JPS61258789A (en) * | 1985-05-10 | 1986-11-17 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS61201859U (en) * | 1985-06-06 | 1986-12-18 | ||
| JPS6221592A (en) * | 1985-07-22 | 1987-01-29 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS6221591A (en) * | 1985-07-22 | 1987-01-29 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS6221586A (en) * | 1985-07-23 | 1987-01-29 | Canon Inc | Thermal transfer material and production thereof |
| JPS6248590A (en) * | 1985-08-28 | 1987-03-03 | Sony Corp | Ink ribbon for thermal fusion transfer |
| JPS6280093A (en) * | 1985-10-04 | 1987-04-13 | Alps Electric Co Ltd | Thermal printer and printing method thereof |
| JPS62183384A (en) * | 1986-02-07 | 1987-08-11 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
| JPS62231789A (en) * | 1986-03-31 | 1987-10-12 | Konika Corp | Production of thermal transfer recording medium |
| JPS62231790A (en) * | 1986-04-01 | 1987-10-12 | Konika Corp | Thermal transfer recording method |
| JPS62292487A (en) * | 1986-06-11 | 1987-12-19 | Sugai Kagaku Kogyo Kk | Thermal transfer recording ink ribbon |
| JPS63162287A (en) * | 1986-12-26 | 1988-07-05 | Kao Corp | Thermal transfer recording medium |
| JPS63296984A (en) * | 1987-05-29 | 1988-12-05 | Ricoh Co Ltd | Transfer-type thermal recording medium |
| JPS6427992A (en) * | 1987-07-24 | 1989-01-30 | Ricoh Kk | Transfer-type thermal recording medium |
| JPS6463191A (en) * | 1987-09-03 | 1989-03-09 | Konishiroku Photo Ind | Thermal transfer recording medium |
| JPH01113286A (en) * | 1987-10-28 | 1989-05-01 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| US4840837A (en) * | 1987-07-02 | 1989-06-20 | Pilot Man-Nen-Hitsu Kabushiki Kaisha | Heat transfer medium |
| JPH01174487A (en) * | 1987-12-29 | 1989-07-11 | Mitsubishi Paper Mills Ltd | Thermal transfer recording sheet |
| JPH01186385A (en) * | 1988-01-21 | 1989-07-25 | Brother Ind Ltd | Production of thermal transfer ink ribbon for dry transfer material |
| JPH01263083A (en) * | 1988-04-15 | 1989-10-19 | Mitsubishi Paper Mills Ltd | Thermal transfer recording sheet |
| US4880324A (en) * | 1985-06-24 | 1989-11-14 | Canon Kabushiki Kaisha | Transfer method for heat-sensitive transfer recording |
| US4880686A (en) * | 1986-10-17 | 1989-11-14 | Canon Kabushiki Kaisha | Thermal transfer material |
| JPH02153792A (en) * | 1988-12-05 | 1990-06-13 | Konica Corp | Thermal transfer recording medium |
| JPH0334893A (en) * | 1989-06-30 | 1991-02-14 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| US5106694A (en) * | 1984-08-20 | 1992-04-21 | Dai Nippon Insatsu Kabushiki Kaisha | Heat transfer sheet |
| JPH07164772A (en) * | 1994-11-18 | 1995-06-27 | Dainippon Printing Co Ltd | Heat-sensitive transfer sheet |
| JPH07164768A (en) * | 1994-10-03 | 1995-06-27 | Dainippon Printing Co Ltd | Recording sheet |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5146954A (en) * | 1974-10-21 | 1976-04-22 | Nippon Telegraph & Telephone | |
| JPS56148591A (en) * | 1980-04-21 | 1981-11-18 | Nippon Telegr & Teleph Corp <Ntt> | Two-color type heat-sensitive transfer recording element |
| JPS57199472U (en) * | 1981-06-15 | 1982-12-18 | ||
| JPS5816865A (en) * | 1981-07-21 | 1983-01-31 | Canon Inc | Color recording device |
| JPS5884777A (en) * | 1981-11-13 | 1983-05-20 | Canon Inc | Multicolor printer |
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1983
- 1983-06-04 JP JP58098775A patent/JPS59224392A/en active Granted
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5146954A (en) * | 1974-10-21 | 1976-04-22 | Nippon Telegraph & Telephone | |
| JPS56148591A (en) * | 1980-04-21 | 1981-11-18 | Nippon Telegr & Teleph Corp <Ntt> | Two-color type heat-sensitive transfer recording element |
| JPS57199472U (en) * | 1981-06-15 | 1982-12-18 | ||
| JPS5816865A (en) * | 1981-07-21 | 1983-01-31 | Canon Inc | Color recording device |
| JPS5884777A (en) * | 1981-11-13 | 1983-05-20 | Canon Inc | Multicolor printer |
Cited By (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60115488A (en) * | 1983-11-29 | 1985-06-21 | Ricoh Co Ltd | Thermal transfer recording medium |
| JPH0333118B2 (en) * | 1984-02-22 | 1991-05-15 | Toppan Printing Co Ltd | |
| JPS60176798A (en) * | 1984-02-22 | 1985-09-10 | Toppan Printing Co Ltd | Thermal transfer film |
| JPS60239285A (en) * | 1984-05-15 | 1985-11-28 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
| JPS60240493A (en) * | 1984-05-16 | 1985-11-29 | Toppan Printing Co Ltd | Multilayered thermal transfer sheet |
| JPS6151388A (en) * | 1984-08-20 | 1986-03-13 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| US5106694A (en) * | 1984-08-20 | 1992-04-21 | Dai Nippon Insatsu Kabushiki Kaisha | Heat transfer sheet |
| JPS6178692A (en) * | 1984-09-26 | 1986-04-22 | Mitsubishi Paper Mills Ltd | Thermal transfer material |
| JPH0473390B2 (en) * | 1984-09-26 | 1992-11-20 | Mitsubishi Paper Mills Ltd | |
| JPS61114889A (en) * | 1984-11-08 | 1986-06-02 | Alps Electric Co Ltd | Thermal transfer medium |
| JPS61116592A (en) * | 1984-11-13 | 1986-06-04 | Carbon Paper Kk | Thermal transfer type recording medium |
| JPS61258789A (en) * | 1985-05-10 | 1986-11-17 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS61201859U (en) * | 1985-06-06 | 1986-12-18 | ||
| US4880324A (en) * | 1985-06-24 | 1989-11-14 | Canon Kabushiki Kaisha | Transfer method for heat-sensitive transfer recording |
| JPS6221592A (en) * | 1985-07-22 | 1987-01-29 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS6221591A (en) * | 1985-07-22 | 1987-01-29 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPH0465797B2 (en) * | 1985-07-23 | 1992-10-21 | Canon Kk | |
| JPS6221586A (en) * | 1985-07-23 | 1987-01-29 | Canon Inc | Thermal transfer material and production thereof |
| JPS6248590A (en) * | 1985-08-28 | 1987-03-03 | Sony Corp | Ink ribbon for thermal fusion transfer |
| JPS6280093A (en) * | 1985-10-04 | 1987-04-13 | Alps Electric Co Ltd | Thermal printer and printing method thereof |
| JPS62183384A (en) * | 1986-02-07 | 1987-08-11 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
| JPS62231789A (en) * | 1986-03-31 | 1987-10-12 | Konika Corp | Production of thermal transfer recording medium |
| JPS62231790A (en) * | 1986-04-01 | 1987-10-12 | Konika Corp | Thermal transfer recording method |
| JPS62292487A (en) * | 1986-06-11 | 1987-12-19 | Sugai Kagaku Kogyo Kk | Thermal transfer recording ink ribbon |
| US4880686A (en) * | 1986-10-17 | 1989-11-14 | Canon Kabushiki Kaisha | Thermal transfer material |
| JPS63162287A (en) * | 1986-12-26 | 1988-07-05 | Kao Corp | Thermal transfer recording medium |
| JPS63296984A (en) * | 1987-05-29 | 1988-12-05 | Ricoh Co Ltd | Transfer-type thermal recording medium |
| US4840837A (en) * | 1987-07-02 | 1989-06-20 | Pilot Man-Nen-Hitsu Kabushiki Kaisha | Heat transfer medium |
| JPS6427992A (en) * | 1987-07-24 | 1989-01-30 | Ricoh Kk | Transfer-type thermal recording medium |
| JPS6463191A (en) * | 1987-09-03 | 1989-03-09 | Konishiroku Photo Ind | Thermal transfer recording medium |
| JPH01113286A (en) * | 1987-10-28 | 1989-05-01 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPH01174487A (en) * | 1987-12-29 | 1989-07-11 | Mitsubishi Paper Mills Ltd | Thermal transfer recording sheet |
| JPH01186385A (en) * | 1988-01-21 | 1989-07-25 | Brother Ind Ltd | Production of thermal transfer ink ribbon for dry transfer material |
| JPH0566876B2 (en) * | 1988-01-21 | 1993-09-22 | Brother Ind Ltd | |
| JPH01263083A (en) * | 1988-04-15 | 1989-10-19 | Mitsubishi Paper Mills Ltd | Thermal transfer recording sheet |
| JPH02153792A (en) * | 1988-12-05 | 1990-06-13 | Konica Corp | Thermal transfer recording medium |
| JPH0334893A (en) * | 1989-06-30 | 1991-02-14 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| JPH07164768A (en) * | 1994-10-03 | 1995-06-27 | Dainippon Printing Co Ltd | Recording sheet |
| JPH07164772A (en) * | 1994-11-18 | 1995-06-27 | Dainippon Printing Co Ltd | Heat-sensitive transfer sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0466717B2 (en) | 1992-10-26 |
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