JPS59204103A - Agent for reducing chemical injury and herbicide with chemical injury reduced - Google Patents
Agent for reducing chemical injury and herbicide with chemical injury reducedInfo
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- JPS59204103A JPS59204103A JP7828283A JP7828283A JPS59204103A JP S59204103 A JPS59204103 A JP S59204103A JP 7828283 A JP7828283 A JP 7828283A JP 7828283 A JP7828283 A JP 7828283A JP S59204103 A JPS59204103 A JP S59204103A
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- herbicide
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Abstract
Description
【発明の詳細な説明】
本発明は、一般式(II)
(式中、R1および馬、は低級アルキル基を示し、R3
は2個のメチル隻で置換されたエチレン鎖を示す)で表
わされるハロアセトアニリドの薬害軽減剤に関する。よ
り詳しくは、1,2−ベンゾイソチアゾール−3(21
()−オン−1,1−ジオキシドまたはその噂、あるい
は一般式(I)
Oi
(式中、1%は低級アルキル基または低級アルケニル基
を示す)で表わされる薬害1’4T ’It剤およびこ
れを含有する除草剤に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a compound of the general formula (II) (wherein R1 and R represent a lower alkyl group, and R3
is an ethylene chain substituted with two methyl groups). More specifically, 1,2-benziisothiazole-3 (21
()-one-1,1-dioxide or rumors thereof, or phytotoxic 1'4T'It agents represented by the general formula (I) Oi (in the formula, 1% represents a lower alkyl group or a lower alkenyl group), and this This relates to a herbicide containing.
除草剤は、そもそも選択性を利用して有用作物の栽培区
における有害な雑草を化学的手段によって防除するもの
であるが、作物と雑草間に本質的な選択性を著わすもの
は少なく、多くは作物と雑草の生育ステージの差、土壌
中における作物と雑草の種子の位置の差、葉面上のふ着
の差、などを利用して選択性を著わしている。そのため
、土壌の種類、温度、雨計などの天候、薬量などによっ
て、好ましくない副作用である薬害が生じる場合がしば
しばある。このことは、多くの除草剤、例えばトリアジ
ン系、尿素系、カーバメート系、フェノキシ系、フェノ
ール系、そしてアセトアニリド系等各除草剤にあてはま
ることである。Herbicides use selectivity to control harmful weeds in areas where useful crops are grown by chemical means, but there are few that show inherent selectivity between crops and weeds, and many Selectivity is achieved by utilizing differences in the growth stages of crops and weeds, differences in the position of seeds of crops and weeds in the soil, and differences in attachment on the leaf surface. Therefore, depending on the type of soil, temperature, weather conditions such as rain gauges, dosage, etc., chemical damage, which is an undesirable side effect, often occurs. This applies to many herbicides, such as triazine, urea, carbamate, phenoxy, phenol, and acetanilide herbicides.
そのためにこれら除草剤の薬害軽減剤の研究が過去多く
なされ、例えば、トウモロコシの除草剤であるEPTC
(S−エチル−N、N−ジ(n)−プロピルチオールカ
ーバメート)に対し薬害軽減作用を有するN、N−ジア
リル−2,2−ジクロロアセトアミドII、Weed
5cience 21(4) 、 292−295(1
973))やアラクロール(N−メトキンメチル−2,
6−ジエチル−α−クロロアセトアニリド)に対し薬害
軽減作用を有する1、8−ナフタリンファンハイドライ
ド(Weed 5cience 22(1) 、86−
90(1974) )などが知られている。For this reason, a lot of research has been done in the past on phytotoxicity reducers for these herbicides, such as EPTC, a corn herbicide.
N,N-diallyl-2,2-dichloroacetamide II, which has a phytotoxicity reducing effect on (S-ethyl-N,N-di(n)-propylthiol carbamate), Weed
5science 21(4), 292-295(1
973)) and alachlor (N-methine methyl-2,
1,8-naphthalene fan hydride (Weed 5science 22(1), 86-
90 (1974)) are known.
除草剤として有用な化合物であることが既に公知(特公
昭48−37820号、特開昭49−54527号)の
一般式(Ii)で表わされるハロアセトアニリドも、各
種の池の除草剤と同じように薬害を生じろことがある。Haloacetanilide represented by the general formula (Ii), which is already known to be a useful compound as a herbicide (Japanese Patent Publication No. 48-37820, Japanese Patent Publication No. 49-54527), is also useful as a herbicide for various ponds. may cause drug damage.
本発明者らは、一般式(1■)で表わされるノ・ロアセ
トアニリドの除草剤の薬害軽減剤を深策し、■、2−ベ
ンゾイノチアゾールー3(2H)−オン−1,1−ジオ
キシドまたはその塩、あるいは、一般式(I)で表わさ
れるイネいもち病防除剤として公知(特公昭45−38
080号)の化合物が、著しい、R減効果をあられずこ
とを見出した。この化合物の薬害11径減効果をあられ
ず作物は、水稲をはじめとし、一般式(II)で表わさ
れる除草剤が適用できる作物、つまりトウモロコシ、小
麦、大麦、ビール麦、陸稲、大豆、綿、ビーナツツ、テ
ンサイ等広範囲に及ぶものである。The present inventors have developed a herbicide phytotoxic agent of no-roacetanilide represented by the general formula (1), and have developed It is known as a rice blast control agent represented by the dioxide or its salt or the general formula (I)
It was found that the compound No. 080) did not have a significant R-reducing effect. Crops that do not suffer from the phytotoxicity 11 radius reduction effect of this compound include paddy rice and other crops to which the herbicide represented by formula (II) can be applied, such as corn, wheat, barley, beer barley, upland rice, soybeans, cotton, They range from a wide range of crops, including peanuts and sugar beets.
本発明で薬害軽減剤として使用する1、2−ベンゾイン
チアゾール−3(21()−オン−1,1−ジオキシド
、その塩、および一般式(I)であられされる化合物は
、イネいもち病防除効果について知られれていない。The 1,2-benzothiazole-3(21()-one-1,1-dioxide, its salt, and the compound represented by the general formula (I) used as a drug harm reducer in the present invention are effective for controlling rice blast disease. Not known about effectiveness.
本発明の薬害軽減剤として使用できる化合物として次表
のようなものがあげられる。Compounds that can be used as the drug-toxicity reducing agent of the present invention include those shown in the following table.
([二合物2 1,2−ベンゾイソチアゾール−3(2
H)−オン−1,1−ジオキシド ナトリウム化合物5
3−(11−ブトキシ)−1,2−ベンゾイソチアゾー
ル−1,1−ジオキシド 96
°C本発明の薬害軽減剤は、種々の方法で除草剤の薬害
を軽減することができる。([2 compound 2 1,2-benziisothiazole-3(2
H)-one-1,1-dioxide sodium compound 5
3-(11-butoxy)-1,2-benziisothiazole-1,1-dioxide 96
°C The phytotoxicity reducing agent of the present invention can reduce the phytotoxicity of herbicides in various ways.
即ち、大豆の栽培地では播種し、ハロアセトアニいは後
に薬害軽減剤を処理することができるし、また薬害軽減
剤を種子にコーティングすることができる。That is, soybeans can be sown in soybean cultivation areas, and the haloacetate can later be treated with a phytotoxicity reducing agent, or the seeds can be coated with a phytotoxicity reducing agent.
また薬害軽減剤を適当な担体と均一混合し、活性剤、分
Wi削および結合剤を添加した上で粒剤化して使用する
ことができる。Alternatively, the drug-toxicity reducing agent can be uniformly mixed with a suitable carrier, an activator, a binder and a binder added thereto, and the mixture can be made into granules for use.
本発明の薬害軽減剤は剤型をその他乳剤、水和剤、粉剤
、液剤、又はフロアブルの形として用℃・ることもでき
る。The drug safety agent of the present invention can also be used in the form of an emulsion, a wettable powder, a powder, a liquid, or a flowable formulation.
使用する薬害軽減剤の量は、・・ロアセトアニIJド1
重量部当り0.01〜5重電部であるが、最適な薬量に
ついては使用するノ・ロアセトアニリドの種類、対象作
物によってその都度検討の上決められろ。The amount of drug harm reducer to be used is... Roacetani IJ Do 1
The amount is 0.01 to 5 parts by weight, but the optimum amount should be determined on a case-by-case basis depending on the type of acetanilide used and the target crop.
ハロアセトアニリド除草剤の作用性はタンノくり質生合
成の阻害にあるとされているが、薬害症状については、
例えば水稲の場合、草丈抑制、新葉抽出の阻害、縮状便
、などの症状がみもれ、ひどい時には収量に大きく影響
をおよぼす。この場合本発明の薬害Ill城へ11を同
時に施用すれば、除草効果に何ら影響することなく、上
記薬害症状を著しく峰滅するか、あるいは全く薬害症状
が観察されず、水稲の収量に好結果をもたらす。The action of haloacetanilide herbicides is said to be due to the inhibition of tannin biosynthesis, but regarding drug-induced symptoms,
For example, in the case of paddy rice, symptoms such as reduced plant height, inhibition of new leaf extraction, and shrunken stools are observed, and in severe cases, the yield can be significantly affected. In this case, if 11 of the present invention is applied at the same time to the herbicidal disease, the above-mentioned symptoms of herbicidal damage will be significantly diminished, or no symptoms of herbivorous damage will be observed at all, without any effect on the herbicidal effect, resulting in good results on the yield of paddy rice. bring.
本発明の薬害q減除草剤は、前記一般式(fi)で゛表
わされるノ・ロアセトアニリドと本発明の前記薬害軽減
剤をともに含有してなるものである。The herbicide for reducing phytotoxicity q of the present invention contains both the acetanilide represented by the above general formula (fi) and the above-mentioned phytotoxicity reducing agent of the present invention.
一般式(TI)で表わされるノ・ロアセトアニリドとし
−C次表に示すようなものがあげられる。Examples of the acetanilide represented by the general formula (TI) include those shown in the following table.
化合物記号 化 学 名 釉
、哉(θド、屯)化合物J) 2−クロロ−N−(
2−工升し−6−メチ/レフェニル)−N−(2−メト
キシ−1−メチルエチル)7−1=)7ミ)”
(100°Ω’0 、OOlmml
(g )本発明の薬害軽減除草剤において、一般式(1
■)で表わされるノhロアセトアニリド1重量部に対し
、前記の薬害軽減剤を0.01〜5重量部の範囲で含有
させる。Compound symbol Chemical name Glaze, Ya (θdo, tun) Compound J) 2-chloro-N-(
2-works-6-methy/lephenyl)-N-(2-methoxy-1-methylethyl)7-1=)7mi)”
(100°Ω'0,OOlmml
(g) In the herbicide for reducing phytotoxicity of the present invention, the general formula (1
The above-mentioned phytotoxicity reducing agent is contained in the range of 0.01 to 5 parts by weight per 1 part by weight of noroacetanilide represented by (2).
また、剤型に応じて、担体、活性剤、分散剤、結合剤を
用い、粒剤、乳剤、水和剤、液剤とすることができる。Furthermore, depending on the dosage form, it can be made into granules, emulsions, wettable powders, and liquids by using carriers, active agents, dispersants, and binders.
一般には、このような剤型において、上記の範囲のハロ
アセトアニリドと・卑害軽城剤とを、例えば粒剤では0
.5〜5重量係、乳剤では1〜10重量%、水和剤ては
2〜20重量%、粉剤では0.1〜1重量重量性含有る
。Generally, in such a dosage form, the haloacetanilide and the mildly harmful agent in the above range are mixed, for example, in the form of granules, at a dosage of 0.
.. It contains 5 to 5% by weight, 1 to 10% by weight in emulsions, 2 to 20% by weight in wettable powders, and 0.1 to 1% by weight in powders.
以下、実施例および試験例によって本発明を説明する。The present invention will be explained below with reference to Examples and Test Examples.
実施例1 薬害軽減剤粒剤
化合物45部、ベントナイト 70部、タルク 21部
、ドデシルベンゼンスルホン酸ソーダ1部、ポリオキシ
エチレンアルキルアリルエーテル 1部、およびリグニ
ンスルホン酸ソーダ2部を混合した後、適数の水を加え
て混練し、造粒機を用いて11ハ常の方法で造粒し、粒
剤ioo部を得る実施例2 薬害軽減除草剤粒剤
化合物02部、化合物61部、ベントナイト 73部、
タルク 21部、リグニンスルホン酸ソーダ 2部、お
よびドデシルベンゼンスルホン酸ソーダ 1部を混合し
た後、適量の水を加えて混練し、造粒機を用いて通常の
方法で造粒し、粒剤ioo部を得る。Example 1 After mixing 45 parts of a chemical harm reducer granule compound, 70 parts of bentonite, 21 parts of talc, 1 part of sodium dodecylbenzenesulfonate, 1 part of polyoxyethylene alkyl allyl ether, and 2 parts of sodium ligninsulfonate, Example 2: 10 parts of granules are obtained by adding several parts of water, kneading, and granulating using a granulator in a conventional manner to obtain 10 parts of granules. 02 parts of compound, 61 parts of compound, 73 parts of bentonite Department,
After mixing 21 parts of talc, 2 parts of sodium ligninsulfonate, and 1 part of sodium dodecylbenzenesulfonate, an appropriate amount of water is added and kneaded, and the mixture is granulated using a granulator in the usual manner to form granules. get the part.
実1准例3 薬害軽減剤粉剤
化合物30.5部およびケイソウ土とクレー混合物99
.5部を混合粉砕し、粉剤100部を得る。Example 1 Sub-Example 3 30.5 parts of chemical harm reducer powder compound and 99 parts of diatomaceous earth and clay mixture
.. 5 parts were mixed and ground to obtain 100 parts of powder.
実施例4 薬害軽減除草剤水和剤
化合物D50部、化合物22部、ホワイトカーボン10
部、ケインウ±33部、リグニンスルホン酸ソーダ3部
およびドデシルベンゼンスルホン酸ソーダ2部を混合粉
砕して、水和剤100部を・111る。Example 4 Phytotoxicity-reducing herbicide wettable powder Compound D 50 parts, Compound 22 parts, White Carbon 10
100 parts of a wettable powder were prepared by mixing and pulverizing 100 parts of a wettable powder by mixing and pulverizing 100 parts of a wettable powder, 33 parts of acetic acid, 3 parts of sodium ligninsulfonate, and 2 parts of sodium dodecylbenzenesulfonate.
実施例5 薬害軽減除草剤乳剤
化合物A40部、化合物12部、オルソキシレン48部
および脂肪アルコールポリグリコールエーテル10部を
混合溶解して乳剤100部を得る。Example 5 Phytotoxicity Reducing Herbicide Emulsion 40 parts of Compound A, 12 parts of Compound, 48 parts of orthoxylene and 10 parts of fatty alcohol polyglycol ether were mixed and dissolved to obtain 100 parts of an emulsion.
試験例1 種子コーティングによる薬害軽減効果試験
温室内においてトウモロコシ(品種:ゴールテンクロス
パンタム)、小麦(品種:農林27号)大豆(品種:フ
クムスメ)の各種子に化合物3を5係含む粉剤を、種子
1009に対して10gの割合で粉衣し、砂質土壌を充
填したポットに唱種し、翌日に化合物Aまたは化合物り
を所定薬量処理し、処理後400日目抜取り調査をおこ
ない、薬害軽減剤無コーテイング種子を用いた場合と生
育量について比較した結果を第1表に示す。Test Example 1 Test on the effect of reducing chemical damage by seed coating In a greenhouse, each seed of corn (variety: Galten crosspantum), wheat (variety: Norin No. 27), and soybean (variety: Fukumusume) was coated with a powder containing 5 parts of Compound 3. The seeds were coated in powder at a ratio of 10 g to 1009 seeds, planted in a pot filled with sandy soil, treated with a prescribed amount of Compound A or Compound Ri on the next day, and conducted a sampling survey 400 days after the treatment. Table 1 shows the results of a comparison of the growth amount with seeds uncoated with a phytotoxicity reducer.
試、検測2 育苗箱処理による薬害軽減効果試験育苗箱
で生育させた水稲(品種:コシヒカリ)が2.5葉期に
到した時に、5係の粒剤に調製した化合物6を箱あたり
50りまたは100り施用し、2時間後にあらかじめ砂
質土壌を充填した%、000ワグネルボットに、土をつ
けたままの形で水稲を3本を1株として、ポット当り、
その2株を深さ3CrILにそう苗した。移植後5日目
に化合物I3または化合物Cの粒剤を所定薬量処理し、
温室内で生育させ、処理後100日目よび200日目観
察調査した結果を第2表に示す。Trial and measurement 2 Test for the effect of reducing chemical damage by seedling nursery box treatment When paddy rice (variety: Koshihikari) grown in a seedling nursery box reached the 2.5 leaf stage, Compound 6 prepared as a granule of Group 5 was added at 50% per box. After 2 hours, three paddy rice plants were placed in a %, 000 Wagnerbott filled with sandy soil in advance, with the soil still attached, per pot.
The two plants were sown at a depth of 3 CrIL. On the 5th day after transplantation, granules of Compound I3 or Compound C were treated at a prescribed dose,
Table 2 shows the results of observation and investigation conducted on the 100th and 200th day after the treatment after growing in a greenhouse.
水稲に対する薬害程度の表示区分は「甚害」 「犬舎」
「中吉」 「小書」 「微害」および[無害−1の6段
階とした。The classification of chemical damage to paddy rice is “severe damage” and “kennel”
There were six levels: ``Nakayoshi'', ``Small Hazard'', ``Minor Harm'', and [Harmless-1].
第2表
試験例3 薬害軽減剤入り除草剤の畑作曜場試験畑地雑
草が自然混在している畑地を通常の方法で耕起、施肥(
N、P、0.、K 、0各11v/a )、および整地
をおこない、1区10m(2,5mX4m)に区画し、
これにトウモロコシ、コムギ、イネ、ワタ、ビーナツツ
の種子を播種、覆土した後薬害軽減剤2%を含む50%
永和剤に調製した除草剤を所定薬量処理した。処理後2
55日目雑草に対する除草効果および作物に対する薬害
について調査し、これを下記に示す要領で指数に喚算し
、これを第3表に示す。Table 2 Test Example 3 Field cultivation field test of herbicide containing chemical damage reducer Field field in which weeds naturally coexist was plowed and fertilized in the usual manner (
N, P, 0. .
After sowing corn, wheat, rice, cotton, and peanut seeds and covering with soil, 50% contains 2% phytotoxicity reducer.
A prescribed amount of the herbicide prepared as a permanent agent was applied. After processing 2
On the 55th day, the herbicidal effect on weeds and the chemical damage to crops were investigated, and the results were calculated into an index as shown below, which is shown in Table 3.
8 4−8係
7 9−15% 00 慢
6 16−25% 1 1−5係
5 26−35% 2 6−10%4 36−4
5% 3 11−20%3 46−55% 4
21−30チ2 56−65% 531チ以上
1 66−75%
075チ以上
試i検測4薬害軽減剤入り除草剤の水田圃場試験水田雑
草が自然混在している水田を、通常の方法で耕起、施I
III!(N、 P2O3、K、O各1kg/a)、代
かきおよび整地をおこない、1区10 rn’ (2,
5mX 4 ni )に区画し、これに葉令2.5の水
稲稚苗3本を1株として、あぜ間隔30儂、株間隔15
CTLで移植した。移植後ばたん水深を3〜5に771
に保ちながら、雑草発芽始期(田植3日後)およびタイ
ヌビエの2葉期(田植10日後)に、薬害軽減剤1チを
含む5%粒剤に調製した除草剤を所定薬量処理した。処
理後20日目に雑草に対する除草効果および作物に対す
る薬害について調査し、これを前記に示した要領で指数
に喚算し第4表に示す。8 4-8 section 7 9-15% 00 Arrogant 6 16-25% 1 1-5 section 5 26-35% 2 6-10%4 36-4
5% 3 11-20%3 46-55% 4
21-30chi 2 56-65% 531chi or more 1 66-75% 075chi or more Test i Test 4 Paddy field test of herbicide with chemical harm reducer A rice field where paddy weeds are naturally mixed was tested using the normal method. Plowing, plowing
III! (N, P2O3, K, O each 1kg/a), plowing and leveling the land, 10 rn' (2,
5 m x 4 ni), each plant contains 3 young paddy rice seedlings of leaf age 2.5, with a ridge spacing of 30 yen and a plant spacing of 15 yen.
Transplanted with CTL. After transplanting, increase the water depth to 3 to 5 771
The herbicide prepared as a 5% granule containing 1 t of a chemical damage reducer was applied at a prescribed dose at the beginning of weed germination (3 days after rice planting) and at the 2-leaf stage of Japanese millet (10 days after rice planting) while maintaining the same conditions. On the 20th day after treatment, the herbicidal effect on weeds and phytotoxicity on crops were investigated, and the results were calculated into an index as described above, which is shown in Table 4.
Claims (1)
H)−オン−1,1−ンオキシドまたはその塩、あるい
は−(式中、Rは低級アルキル基または低級アルケニル
基を示す)で表わされる、一般式(II)(式中、l(
1およびI(は低級アルキル基を示し、R3はは2個の
メチル基で置換されたエチレン鎖を示す)で表わされる
ノ・ロアセトアニリドの薬害軽減剤。 (2) 1.2−ベンゾイソチアゾール−3(2H)
−オン−1,1−ジオキシドまたは塩、あるいは一般式
(I)SOλ (式中、Rは低級アルキル基または低級アルケニル基を
示す)で表わされる化合物と一般式(II)(式中、R
1および迅は低級アルキル基を示し、R。 くば2個のメチル基で;置換されたエチレン惨を示す)
で表わされるハロアセトアニリドとを含有する薬害軽減
除草剤。[Claims] (],) ]1.2-Benzisothiazole-3(2
H)-one-1,1-one oxide or a salt thereof, or - (wherein R represents a lower alkyl group or lower alkenyl group), represented by the general formula (II) (wherein l(
1 and I (represents a lower alkyl group, and R3 represents an ethylene chain substituted with two methyl groups). (2) 1,2-Benzisothiazole-3(2H)
-one-1,1-dioxide or salt, or a compound represented by general formula (I) SOλ (wherein R represents a lower alkyl group or lower alkenyl group) and general formula (II) (wherein R
1 and Xin represent a lower alkyl group, R. Two methyl groups (indicates substituted ethylene)
A herbicide with reduced phytotoxicity containing a haloacetanilide represented by:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7828283A JPS59204103A (en) | 1983-05-06 | 1983-05-06 | Agent for reducing chemical injury and herbicide with chemical injury reduced |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7828283A JPS59204103A (en) | 1983-05-06 | 1983-05-06 | Agent for reducing chemical injury and herbicide with chemical injury reduced |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59204103A true JPS59204103A (en) | 1984-11-19 |
JPH0450282B2 JPH0450282B2 (en) | 1992-08-13 |
Family
ID=13657602
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7828283A Granted JPS59204103A (en) | 1983-05-06 | 1983-05-06 | Agent for reducing chemical injury and herbicide with chemical injury reduced |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59204103A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61231284A (en) * | 1985-04-03 | 1986-10-15 | 東レ株式会社 | Ink jet or spray dyeing method |
JPS61231285A (en) * | 1985-04-03 | 1986-10-15 | 東レ株式会社 | Ink jet or spray dyeing method |
EP0218935A1 (en) * | 1985-09-26 | 1987-04-22 | Bayer Ag | Seed disinfectant on the basis of saccharin or a saccharin alkali metal salt |
WO1997024928A1 (en) * | 1996-01-11 | 1997-07-17 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Inhibiting induced phytotoxicity in herbicides on rice |
US5670450A (en) * | 1997-01-02 | 1997-09-23 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Composition and method of using fungicides for inhibiting induced phytotoxicity in rice from halogenated aromatic herbicides |
WO2000078142A3 (en) * | 1999-06-17 | 2001-04-26 | Basf Ag | Method for improving the resistance of cultivated plants to chemical stress |
WO2007023719A1 (en) * | 2005-08-22 | 2007-03-01 | Kumiai Chemical Industry Co., Ltd. | Agent for reducing chemical injury and herbicide composition with reduced chemical injury |
-
1983
- 1983-05-06 JP JP7828283A patent/JPS59204103A/en active Granted
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61231284A (en) * | 1985-04-03 | 1986-10-15 | 東レ株式会社 | Ink jet or spray dyeing method |
JPS61231285A (en) * | 1985-04-03 | 1986-10-15 | 東レ株式会社 | Ink jet or spray dyeing method |
JPH0444036B2 (en) * | 1985-04-03 | 1992-07-20 | Toray Industries | |
EP0218935A1 (en) * | 1985-09-26 | 1987-04-22 | Bayer Ag | Seed disinfectant on the basis of saccharin or a saccharin alkali metal salt |
WO1997024928A1 (en) * | 1996-01-11 | 1997-07-17 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Inhibiting induced phytotoxicity in herbicides on rice |
US5670450A (en) * | 1997-01-02 | 1997-09-23 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Composition and method of using fungicides for inhibiting induced phytotoxicity in rice from halogenated aromatic herbicides |
WO2000078142A3 (en) * | 1999-06-17 | 2001-04-26 | Basf Ag | Method for improving the resistance of cultivated plants to chemical stress |
WO2007023719A1 (en) * | 2005-08-22 | 2007-03-01 | Kumiai Chemical Industry Co., Ltd. | Agent for reducing chemical injury and herbicide composition with reduced chemical injury |
Also Published As
Publication number | Publication date |
---|---|
JPH0450282B2 (en) | 1992-08-13 |
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