JPS59148007A - Glass fiber for optical transmission - Google Patents
Glass fiber for optical transmissionInfo
- Publication number
- JPS59148007A JPS59148007A JP58022564A JP2256483A JPS59148007A JP S59148007 A JPS59148007 A JP S59148007A JP 58022564 A JP58022564 A JP 58022564A JP 2256483 A JP2256483 A JP 2256483A JP S59148007 A JPS59148007 A JP S59148007A
- Authority
- JP
- Japan
- Prior art keywords
- glass fiber
- optical transmission
- fluoroelastomer
- compsn
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
Description
【発明の詳細な説明】
本発明はｋＪ熱、耐油、勾とう性に優れ、しがもガラス
ファイバとよく密着づる保護被覆を有づる光伝送用ガラ
スファイバに関りるものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a glass fiber for optical transmission, which has excellent kJ heat, oil resistance, and gradient properties, and has a protective coating that adheres well to the glass fiber.
一般に光伝送用ガラスファイバは補強用の保護被覆が施
されでいる。Glass fibers for optical transmission are generally coated with a protective coating for reinforcement.
今］〕、光伝送用ガラスファイバの適用分野は次第に広
がっており、特に１００’Ｃを越える高温雰囲気で、油
や薬品がかかるといった苛酷な環境でも使用できる光伝
送用ガラスファイバの要求がある。Currently, the field of application of glass fibers for optical transmission is gradually expanding, and there is a demand for glass fibers for optical transmission that can be used in harsh environments such as high-temperature atmospheres exceeding 100'C and exposure to oil and chemicals.
この場合の最大の問題は保護被覆Ｃあり、耐熱性、耐油
性、耐薬品性、強しｌυ性に優れでいるたりＣなく、ガ
ラスファイバとの畜稽性が必要Ｃある。これは高温にお
かれた場合、この密着性がな【プれば保護被覆がガラス
ファイバと遊離して熱膨張を起こし、特に」ネクタ部に
ｄ３いＣ伝送ノζ１失の増加あるいはガラスファイバの
断線を生ずるからである。The biggest problem in this case is the protective coating, which must have excellent heat resistance, oil resistance, chemical resistance, and strength, and must be compatible with glass fiber. This is because when exposed to high temperatures, if this adhesion is lost, the protective coating separates from the glass fiber and causes thermal expansion, resulting in an increase in loss of d3C transmission and loss of the glass fiber, especially at the connector. This is because it will cause a disconnection.
本発明者らは従来の知見をもとに、この要求に適合づる
保護被覆を種に倹約したが、その結果ナイロン系やポリ
上ヂレンなどのポリオレフィン系は耐熱性が不十分であ
り、この目的では使用できない。また、耐熱性から判断
′するとシリコーンゴムとフッ素樹脂が考えられるが、
シリコーンゴムは耐油性、耐薬品性が劣る上に強度が小
さい。Based on prior knowledge, the present inventors tried to find a protective coating that would meet this requirement, but as a result, polyolefins such as nylon and polyurethane have insufficient heat resistance, and for this purpose. cannot be used. Also, judging from heat resistance, silicone rubber and fluororesin are considered, but
Silicone rubber has poor oil resistance and chemical resistance, as well as low strength.
フッ素樹脂例えばフッ化ビーリデン樹脂、エチレンーテ
ｌ−ラフルア ＬＪエチレン共重合体、クロロ１〜リフ
ルオロエチレン樹脂、テトラフルオロエチレン−ベキ１
ノフルオロブロビレン共車合体は耐熱性、耐油性、＃４
薬品性が良く、強じんであるが、密着性が悪いの（−゛
やはりこのような目的には好ましくない。Fluororesins such as beylidene fluoride resin, ethylene-ther-l-LaFlua LJ ethylene copolymer, chloro-1-lyfluoroethylene resin, tetrafluoroethylene-1
Nofluorobrobylene co-merged is heat resistant, oil resistant, #4
It has good chemical properties and is strong, but its adhesion is poor (-) It is not suitable for such purposes.
本弁明は斯かる状況に鑑み、従来の技術において解消で
きなかった上記のような欠点を解消し、耐熱性、耐油性
、耐薬品性に優れ、しがもコネクタ部に（１５１〕る損
失増加が少ない光伝送用ガラスファイバを提供りること
を目的とする。In view of this situation, the present defense solves the above-mentioned drawbacks that could not be solved with the conventional technology, and has excellent heat resistance, oil resistance, and chemical resistance, but also increases loss (151) in the connector part. The purpose of the present invention is to provide a glass fiber for optical transmission with a small amount of light transmission.
づ゛なわら本発明の要旨は、光伝送用ガラスファイバの
保護被覆どして含フッ素エラストマーを採用したことに
ある。However, the gist of the present invention is to employ a fluorine-containing elastomer as a protective coating for a glass fiber for optical transmission.
本発明において含フッ素エラス１〜マーとしては、従来
より公知乃至周知のものなどが、特に限定されることな
く、広範囲にわたって種々例示され得る。例えば、テト
ラフルオロエヂレンープロピレン系共車合体、フッ化ど
ニリデンーへ４−１ノフルオロプロペン系共重合体、フ
ッ化ビニリデン−クロ１］１ヘリフルオロ■ヂレン系共
重合体、フッ化ビニリデン−ペンタフルオロプロペン系
共重合体、ポリフルオロアルキル基含有アクリレーう系
エラス］〜マー、ポリフルオロアルキル基含有ポリシロ
キサン系エラストマー、テトラフル７１１エチレン−フ
ッ化ビニリデンーブ１」ピレン系共重合体、テトラフル
オロエチレン−エチレン−イソブチレン系共重合体、■
ヂレンーへキリフルＡロー［チレン系共重合体、テトラ
フルオ口エチレン−ブテン−１系共重合体、テ］〜ラフ
ルオロ上チレンーエチルビニル上−チル系共重合体、含
フッ素フＡスフＡ二１−リル系エラス１〜？−、テトラ
フルオロ］−ブレンーフルオロビニルニーデル系共重合
体などが挙げられる。In the present invention, the fluorine-containing elastomer 1-mer may be exemplified by a wide variety of conventionally known or well-known ones without particular limitation. For example, tetrafluoroethylene-propylene copolymer, donylidene fluoride-4-1-nofluoropropene copolymer, vinylidene fluoride-chloro1]1 helifluoro-dylene copolymer, vinylidene fluoride-pentafluoride copolymer, etc. Fluoropropene copolymer, polyfluoroalkyl group-containing acrylic elastomer, polyfluoroalkyl group-containing polysiloxane elastomer, Tetraflu 711 ethylene-vinylidene fluoride pyrene copolymer, tetrafluoroethylene-ethylene -Isobutylene copolymer, ■
Dyrene-hekilyflu A rho [tyrene copolymer, tetrafluoro-ethylene-butene-1-based copolymer, te]-rafluoro-ethylene-ethylvinyl-based copolymer, fluorine-containing fluorine-containing fluorine-containing fluorine-containing fluorine-fluoride A-21- Lil type Elas 1~? -, tetrafluoro]-brene-fluorovinyl needle copolymer, and the like.
かかる含フツ素１ラス１〜マーとしては、加］二性の点
から、分子中に不飽和結合、−〇Ｆ２ Ｘあるいは／Ｃ
ＦＸ（ただしＸは１または１３ｒ）単位、−Ｃｔ−１３
単位等の硬化部位を有り−るちのが好ましく、テトフル
Ａロエヂレンーブし」ピレン系共重合体が好適である。Such a fluorine-containing 1-mer has an unsaturated bond, -〇F2
FX (X is 1 or 13r) unit, -Ct-13
It is preferable that the copolymer has a curing site such as a unit, and a pyrene-based copolymer such as tetoflu-A pyrene is preferable.
含フッ素■ラストマーとして好適なｉドラフルＡロエヂ
レンーブロビレン系共重合体としては、主成分のテトラ
フルオロエチレンとプロピレンに加えて、これらと共重
合可能な成分、例えば、１チレン、イソブチレン、アク
リル酸Ｊ３よびそのアル−１ル土スプル、メタクリン酸
およびそのアルキルＪ、スーフル、フッ化ビニル、フッ
化ビニリデン１、外キリノルＡ］゛１ブ１」ペン、クロ
ロエチルビニルエーテル、りＩＪ ｒ、］ ｌ〜リフル
オロエチレン、パーフルオ［Ｊアルキルビニルエーテル
等をｊＨ当に含有せしめたものであってもよい。かかる
共重合体において、ｊｌ−ラフルオロユチレン／プロピ
レンの含有モル比としては９５１５〜３０〜７０、特に
９０／１０−／１５１５５の範囲から選定１−ることが
、耐熱性：成形等の面からｌましく、また、適宜加えら
れる主成分以外の成分の含有ｍとしては通常５０−Ｅル
％以１・、特に３０モル％以下の範囲から選定りること
か好ましい。In addition to the main components of tetrafluoroethylene and propylene, the i-DRAFLU A roedylene-propylene copolymer suitable as a fluorine-containing lastomer contains components copolymerizable with these, such as 1-tylene, isobutylene, Acrylic acid J3 and its alkyl sprue, methacrylic acid and its alkyl J, sufur, vinyl fluoride, vinylidene fluoride 1, exokyrinol A]゛1but1'' pen, chloroethyl vinyl ether, RIJ r,] It is also possible to contain 1 to fluoroethylene, perfluoro[J alkyl vinyl ether, etc. per jH. In such a copolymer, the molar ratio of jl-lafluoroyutylene/propylene is selected from the range of 9515 to 30 to 70, particularly from 90/10 to 15155, in order to improve heat resistance, molding, etc. It is preferable that the content of components other than the main component, which may be added as appropriate, is usually selected from a range of 50-1% by mole or less, particularly 30% by mole or less.
本発明に使用される組成物は含フッ素エラストマー甲独
あるいは含フッ素工ラス１〜マーとフッ素樹脂との渥和
系で・も良い。このフッ素樹脂どじ−Ｃは含フツ素上ラ
ス］へマーとの分散性を考えれば、」デル−４フツ化］
−デル共重合体、ポリフッ化ビニリデンが最も良好であ
る。The composition used in the present invention may be a combination of a fluorine-containing elastomer or a fluorine-containing engineered glass and a fluororesin. Considering the dispersibility of this fluororesin Doji-C with the fluorine-containing lath and hemer,
-Del copolymer and polyvinylidene fluoride are the best.
この組成物は架橋しても良く、この場合、心機過酸化物
、アミンなどの化学架橋、または電子線４Ｔどの放射線
による架橋が可能（゛ある。The composition may be crosslinked, in which case chemical crosslinking using peroxides, amines, etc., or radiation such as electron beam 4T can be used.
配合剤とじて架橋助剤、充てん剤、安定剤、滑剤などを
適宜加えることもぐきる。It is also possible to add crosslinking aids, fillers, stabilizers, lubricants, etc. as appropriate.
本発明のさらに具体的な実施例について説明する。More specific embodiments of the present invention will be described.
直径１２５μｍφの石英ガ）スを主成分とりるクラッド
型多モード光伝送用ガラスファイバにシつ」ン樹脂組成
物（ＫＲ−２８２信越化学製）をガラスファイバの紡糸
直後に塗布、焼（’ＪＩ）を行ない、この上に第１表の
組成の材料を押出被覆し、被覆外径を１．０ｍｍとした
。架橋したものは電子線で行なっＣいる。Immediately after spinning the glass fiber, a resin composition (KR-282 manufactured by Shin-Etsu Chemical Co., Ltd.) was applied to a clad type multi-mode optical transmission glass fiber mainly composed of quartz gas with a diameter of 125 μmφ, and then baked (JI). ), and a material having the composition shown in Table 1 was extrusion coated thereon, and the outer diameter of the coating was set to 1.0 mm. Cross-linking was carried out using an electron beam.
この光伝送用ガラスファイバ１０ｍ、の両端にコネクタ
をつ【プ、温度幅−２０℃〜＋２００°Ｃ１１０υイク
ル／日でｉ ｏｏｏザイクルのピー１〜リーイクル試験
を行ない、伝送損失の変化を調べた。Connectors were connected to both ends of this optical transmission glass fiber (10 m), and an iooo cycle P1 to leak test was conducted at a temperature range of -20°C to +200°C at 110 cycles/day to examine changes in transmission loss.
この試験に用いた光伝送用ガラスファイバのピー１〜ザ
イクル前の伝送損失は両端の］ネクタを含み５．０〜５
．５ｄｆ３／Ｉ曽Ｃ′ある。The transmission loss of the optical transmission glass fiber used in this test was 5.0 to 5, including the connectors at both ends.
．． There is 5df3/IsoC'.
この第１表により明らかなように、本発明の実施例の場
合には、ヒー１〜（ノイクル試Ｍ後の伝送）０失の増加
率は２０％以Ｆであり、従来のフッ素樹脂による保護被
覆と比較しＣ顕＠な効果を奏す−る。As is clear from Table 1, in the case of the embodiment of the present invention, the increase rate of heat 1 to 0 loss (transmission after Noikl test M) is 20% or more, and the conventional protection by fluororesin It has a significant effect compared to coating.
第 ７ 表Table 7
Claims (1)
−マーを主成分とづる組成物を被覆づることににり補強
された光伝送用ガラスファイバ。 ２ 含フッ素上ラストマがデトラフルオＵエヂレンーゾ
Ｕピレン系共単合体であることを特徴どづる第１項記載
の光伝送用ガラスファイバ。[Claims] 1. Fluorine-containing glass on the outside of a glass fiber for optical transmission 1
- A glass fiber for optical transmission reinforced by coating with a composition based on mer. 2. The optical transmission glass fiber according to item 1, wherein the fluorine-containing epilastomer is a detrafluor-U-edylenzo-U-pyrene comonomer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58022564A JPS59148007A (en) | 1983-02-14 | 1983-02-14 | Glass fiber for optical transmission |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58022564A JPS59148007A (en) | 1983-02-14 | 1983-02-14 | Glass fiber for optical transmission |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS59148007A true JPS59148007A (en) | 1984-08-24 |
Family
ID=12086366
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58022564A Pending JPS59148007A (en) | 1983-02-14 | 1983-02-14 | Glass fiber for optical transmission |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59148007A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0239935A2 (en) * | 1986-04-03 | 1987-10-07 | Asahi Glass Company Ltd. | Plastic-clad light-transmitting fiber |
-
1983
- 1983-02-14 JP JP58022564A patent/JPS59148007A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0239935A2 (en) * | 1986-04-03 | 1987-10-07 | Asahi Glass Company Ltd. | Plastic-clad light-transmitting fiber |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS6142955B2 (en) | ||
| JP6881510B2 (en) | Optical fiber, optical fiber cable and communication equipment | |
| US4804246A (en) | Light-transmitting fiber of glass core and clad of cured copolymer of fluoroolefin and alkyl ether | |
| TWI797261B (en) | Plastic Optical Fiber and Plastic Optical Fiber Cable | |
| JPS59148007A (en) | Glass fiber for optical transmission | |
| JP3564128B2 (en) | Perfluoroelastomer binding | |
| JP5583456B2 (en) | Plastic optical fiber and cable | |
| JP3740861B2 (en) | Optical transmission | |
| JP2782880B2 (en) | Fluororesin composition | |
| US6238791B1 (en) | Coated glass fibers, composites and methods related thereto | |
| JP2014141599A (en) | Fluorine-containing elastomer composition, and insulated wire using the same | |
| JP4680715B2 (en) | Manufacturing method of plastic optical fiber cable | |
| US10969551B2 (en) | Sheathed optical ribbon cable assembly | |
| CN105940333B (en) | Optical cable and sensor | |
| JP4225547B2 (en) | Plastic optical fiber and plastic optical fiber cable | |
| CN104927290A (en) | Plastic hose | |
| JP4245513B2 (en) | Plastic optical fiber cable and plastic optical fiber cable with plug | |
| JPS62112104A (en) | Optical transmission fiber using plastic clad | |
| JPS63287908A (en) | Optical fiber clad with plastic material | |
| JP2004212871A (en) | Optical fiber and optical fiber cable | |
| JP2000028876A (en) | Plastic optical fiber cord | |
| JPH01128552A (en) | Semiconductor device | |
| JPH0451206A (en) | Plastic optical fiber | |
| JPS59105601A (en) | Optical fiber cord having high strength | |
| JPH0738884Y2 (en) | Single-core optical fiber code |