JPS59137347A - Coating agent for concealing scratch on bottle - Google Patents

Coating agent for concealing scratch on bottle

Info

Publication number
JPS59137347A
JPS59137347A JP866483A JP866483A JPS59137347A JP S59137347 A JPS59137347 A JP S59137347A JP 866483 A JP866483 A JP 866483A JP 866483 A JP866483 A JP 866483A JP S59137347 A JPS59137347 A JP S59137347A
Authority
JP
Japan
Prior art keywords
component
coating agent
aqueous dispersion
bottle
bottles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP866483A
Other languages
Japanese (ja)
Other versions
JPH0420862B2 (en
Inventor
Naoto Tani
直人 谷
Seiichiro Ichikawa
市川 誠一郎
Kazuo Kawada
川田 和男
Takahide Konno
近野 孝英
Ichiro Nakamura
一郎 中村
Eizo Motohashi
本橋 栄蔵
Kenji Hikita
疋田 堅治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sapporo Breweries Ltd
Original Assignee
Sapporo Breweries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sapporo Breweries Ltd filed Critical Sapporo Breweries Ltd
Priority to JP866483A priority Critical patent/JPS59137347A/en
Publication of JPS59137347A publication Critical patent/JPS59137347A/en
Publication of JPH0420862B2 publication Critical patent/JPH0420862B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Paints Or Removers (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

PURPOSE:To provide superior dispersibility and work efficiency and to improve the dryability and water resistance after coating by adding liq. paraffin or carnauba wax, sodium polyacrylate and morpholine fatty acid ester. CONSTITUTION:This coating agent has a composition contg. liq. paraffin and/or carnauba wax (A), sodium polyacrylate (B) and morpholine fatty acid ester (C). The coating agent is used as an aqueous dispersion by adding water. The concn. of the component A in the aqueous dispersion is <=50%, that of the component B is <=5%, and that of the component C is <=15%. The component A is a base for hiding the scratched part of a bottle. The component B is a kind of paste for food, and when a bottle is coated with said aqueous dispersion, the component B forms a film and envelops liq. paraffin, so it improves the work efficiency of the coating agent as well as the touch to hands and the water resistance after coating.

Description

【発明の詳細な説明】 本発明はびん類の擦れ傷塗布剤に関する。[Detailed description of the invention] The present invention relates to a scuff coating agent for bottles.

従来よりビール、果汁等の容器としてガラスびんなどが
使用されており、これらびん類は使用後に回収され、洗
浄後再び使用されている。
BACKGROUND OF THE INVENTION Glass bottles and the like have conventionally been used as containers for beer, fruit juice, etc., and these bottles are collected after use and used again after being washed.

ところが、びん類を回収して繰返し使用していると、び
ん詰の際や流通過程等においてびん類の外表面、特に肩
部に擦れ傷が生じ、外観が損なわれて商品価値が低下し
てくる。
However, when bottles are collected and used repeatedly, scratches occur on the outer surface of the bottles, especially on the shoulders, during bottling and distribution processes, which impairs the appearance and reduces the product value. come.

したがって、回収したびん類を再使用場合、何らかの原
因で表面に擦れ傷が生じたびん類は適当な手段により該
擦れ傷を隠ぺいすることが必要である。
Therefore, when reusing collected bottles, it is necessary to cover up any scratches on the surface of the bottles by appropriate means if the bottles have scratches for some reason.

びん類の擦れ傷を隠ぺいするための塗布剤として、これ
までに種々の提案がなされている。しかし、従来の擦れ
傷塗布剤はびん類の擦れ偏部の隠ぺい効果にすぐれてい
ても、吸湿性のため乾燥性が悪くべとついたり、塵埃が
付N[〜やすい等の欠点があったり、びん類に対して強
固に接着するため、回収したびん類の洗浄工程を経ても
完全には剥落しない・等の問題点があった。さらに、従
来の塗布剤の中には高価であるため、実用性に欠けるも
のや衛生上や安全上の立場から好ましくないものもあっ
た。
Various proposals have been made so far as coating agents for concealing scratches on bottles. However, even though conventional scratch coating agents have an excellent effect of concealing uneven scratches on bottles, they have drawbacks such as poor drying properties due to their hygroscopic properties, making them sticky and easily attracting dust. However, because it adheres strongly to bottles, it does not come off completely even after the collected bottles are washed. Furthermore, some conventional coating agents are expensive and therefore impractical, and some are undesirable from a sanitary and safety standpoint.

以上の指摘から明らかなように、びん類の擦れ傷塗布剤
としては■擦れ偏部分の隠ぺい効果が良好であること、
■乳化性が良く塗布作業性にすぐれていること、■乾燥
性が良好でべとつかないこと、■耐水性にすぐれている
こと、■洗浄の際に完全に剥落すること、0食品衛生上
有害でないこと、■安価かつ安定的に入手できること等
の要件を満足することが必要である。
As is clear from the above points, as a coating agent for scratches on bottles, ■ it has a good effect of hiding unevenly rubbed areas;
■ Good emulsifying properties and excellent application workability, ■ Good drying properties and non-stickiness, ■ Excellent water resistance, ■ Completely peeling off during cleaning, 0 Not harmful in terms of food hygiene. It is necessary to satisfy the following requirements: 1. It must be inexpensive and stably available.

本発明者らは、これらの要件を満足する擦れ傷塗布剤を
開発すべく検討を重ね念結果、本発明に到達したのであ
る。
The present inventors have conducted repeated studies to develop a scratch coating agent that satisfies these requirements, and have finally arrived at the present invention.

本発明は、(4)流動パラフィンおよび/またはカルナ
ウバろう、(B)ポリアクリル酸ナトリウムおよび(0
モルホリン脂肪酸塩を含有せ1−めたびん類の擦れ傷塗
布剤である。
The present invention comprises (4) liquid paraffin and/or carnauba wax, (B) sodium polyacrylate and (0
This is a coating agent for abrasions on bottles containing morpholine fatty acid salt.

本発明のびん類の擦れ傷塗布剤は通常、水分散液として
使用されるが、水を除外した成分について説明すると、
(4)成分である流動パラフィンおよび/まタハカルナ
ウバろうはびん類の擦れ傷部分を隠ぺいするための基剤
であり、組成分(無水物、以下同じ)中3〜929係を
占める。流動パラフィンは食品添加物として許容されて
いる物質であり、またカルナウバろうは乾燥性が良好で
・べとつかないという特色を有j−ている。
The bottle scratch coating agent of the present invention is usually used as an aqueous dispersion, but the components excluding water are as follows:
(4) Components liquid paraffin and/or Taja carnauba wax are bases for hiding scratches on bottles, and account for 3 to 929 parts of the composition (anhydrous, hereinafter the same). Liquid paraffin is a substance that is permitted as a food additive, and carnauba wax has the characteristics of good drying properties and non-stickiness.

次に、(B)成分として用いるポリアクリル酸ナトリウ
ムは食品添加用糊料の1種であり、びん類に塗布(7た
とき被膜を形成して流動パラフィンを包み込むことによ
って作業性1手に対する感触、耐水性などを改善する作
用を有している。この(B)成分は組成物中0.001
〜83.2%の範囲となるように用いる。
Next, the sodium polyacrylate used as component (B) is a type of glue for food additives, and when applied to bottles (7), it forms a film and envelops the liquid paraffin, making it easier to work with. , has the effect of improving water resistance etc. This component (B) accounts for 0.001% of the composition.
It is used so that it is in the range of ~83.2%.

また、(C)成分として使用するモルホリン脂肪酸塩は
食品添加用被膜剤の1種であり、びん類に塗布したとき
、その表面に被膜を形成して前記(A)成分を包み込む
ことにより上記(B)成分とほぼ同様の作用を発揮する
。この(C)成分は組成物中[1,01〜93.8%の
範囲となるように添加する。
In addition, the morpholine fatty acid salt used as component (C) is a type of coating agent for food additives, and when applied to bottles, it forms a film on the surface and envelops the component (A). It exhibits almost the same effect as component B). Component (C) is added to the composition in an amount ranging from 1.01 to 93.8%.

さらに、本発明においては必要に応じてエチルアルコー
ル、プロピレングリコールなどの食品添加用溶剤を加え
ることが出来、その使用量は通常、10%以下(水分散
液中)であり、無水組成物中で1l−j、0〜9α9係
の範囲である。この溶剤を加えることによって乳化安定
性が一層改善される。
Furthermore, in the present invention, food additive solvents such as ethyl alcohol and propylene glycol can be added as necessary, and the amount used is usually 10% or less (in an aqueous dispersion), and in an anhydrous composition. 1l-j, in the range of 0 to 9α9. Emulsion stability is further improved by adding this solvent.

上記各成分を含むびん類の擦れ傷塗布剤は、前述の如く
、水を加えて水分散液として使用する。
As described above, the bottle scratch coating agent containing each of the above components is used as an aqueous dispersion by adding water.

水分散液とする場合、各成分の濃度は(4)成分50係
以下、好ましくは6〜30係であり、(B)成分5係以
下、好ましくはα005〜2%であり、(C)成分は1
5%以下、好ましくはQ、05〜5%である。
In the case of an aqueous dispersion, the concentration of each component is (4) component 50 parts or less, preferably 6 to 30 parts, (B) component 5 parts or less, preferably α005 to 2%, and (C) component is 1
5% or less, preferably Q, 05-5%.

本発明のびん類の擦れ傷塗布剤をびん類に塗布するには
、各種の方法を適用することができ、たとえば噴霧装置
を使用する方法、布、フェルト。
Various methods can be used to apply the bottle scuff coating agent of the present invention to bottles, such as using a spray device, cloth, or felt.

スポンジ等を用いて塗布する方法などがある。There is a method of applying using a sponge or the like.

本発明のびん類の擦れ傷塗布剤は分散性にすぐれており
、作業性が良好であると共に、塗布後の乾燥性や耐水性
も良好である。特に、回収分と(〜てカルナウバろうを
含むものを使用(−たと@は乾燥性にすぐれ、べとつき
がない。
The coating agent for coating scratches on bottles of the present invention has excellent dispersibility and good workability, as well as good drying properties and water resistance after application. In particular, those containing recovered carnauba wax are used (- and @) have excellent drying properties and are not sticky.

本発明のひん類の擦れ傷塗布剤を用いて擦れ傷部分を隠
ぺい[−たひん類は、常温で1ケ月程保存した場合に、
隠ぺい効果に変化がなく、また冷蔵渾、水冷ショーケー
スなどに保存した場合でも隠ぺい効果はほとんど低下し
ない。(〜かも、びん類に貼布したラベルにも濡れが生
じない。また、このびん類を回収して再使用する場合、
本発明の擦れ傷塗布剤は洗びん工程において完全に洗い
落とすことが出来る。さらに、本発明の擦れ傷塗布剤に
用いている各成分はいずれも安全性の面で心配がなく、
かつ安定的に入手可能である。
Hiding the abrasions using the coating agent for abrasions of the present invention.
There is no change in the concealing effect, and the concealing effect hardly decreases even when stored in a refrigerator, water-cooled showcase, etc. (It may be that the labels attached to the bottles do not get wet. Also, if you collect and reuse these bottles,
The scuff coating agent of the present invention can be completely washed off during the bottle washing process. Furthermore, each component used in the scratch coating agent of the present invention is safe from a safety standpoint.
and is stably available.

次に、本発明を実施例により説明する。Next, the present invention will be explained by examples.

実施例1 流動パラフィン(商品名ニラモールオイル、興丸化学製
)Z係、ポリアクリル酸ナトリウム(商品名ニアロンビ
ス、日本紬薬製)αD1%、およびモルホリン脂肪酸塩
(高松油脂製)0.2%となるように水と配合し、ホモ
ミキサーSL型(特殊機化工業製)を用いて700 r
pmで5分間攪拌(〜て均一に分散させたびん類の擦れ
傷塗布剤2.8を調製した。
Example 1 Liquid paraffin (trade name Niramor Oil, manufactured by Okimaru Chemical Co., Ltd.) Z, sodium polyacrylate (trade name Niaronbis, manufactured by Nippon Tsumugi Pharmaceutical Co., Ltd.) αD 1%, and morpholine fatty acid salt (Takamatsu Yushi Co., Ltd.) 0.2% Mix with water so that
pm for 5 minutes to prepare a uniformly dispersed bottle scuff coating 2.8.

上記擦れ傷塗布剤を調製して約3分後に該塗布剤を脱脂
綿にふく捷せてビールびんの擦れ偏部に塗布した。この
塗布剤の分散性は良好であり、作業性にすぐれていた。
Approximately 3 minutes after preparing the above-mentioned scratch coating agent, the coating agent was soaked in absorbent cotton and applied to the uneven scratched area of the beer bottle. This coating agent had good dispersibility and excellent workability.

さらに、触手による乾燥性、肉眼観察による擦れ傷の隠
ぺい効果、浸水による耐水性評価、塗布後のびん類の外
観、感触や安全性などについて評価し、総合的に良否の
判断を行なった。その結果、この塗布剤は非常に良好な
ものであるとの評価を得た。
Furthermore, we evaluated the drying properties by touch, the effect of hiding scratches by visual observation, the water resistance by water immersion, and the appearance, feel, and safety of the bottles after application, and made a comprehensive judgment of quality. As a result, this coating agent was evaluated as being very good.

実施例2 流動パラフィン(商品名:KP−10,出光興産製)1
0%、カルナウバろう(高松油脂製)0.5係、ポリア
クリル酸ナトリウム(実施例1と同じ)0.02%およ
びモルホリン脂肪酸塩(高松油脂製)0.15%を含む
水分散液を実施例1と同様にして調製した。
Example 2 Liquid paraffin (product name: KP-10, manufactured by Idemitsu Kosan) 1
An aqueous dispersion containing 0%, carnauba wax (manufactured by Takamatsu Yushi), 0.5%, sodium polyacrylate (same as in Example 1) 0.02%, and morpholine fatty acid salt (manufactured by Takamatsu Yushi) 0.15% was prepared. Prepared in the same manner as in Example 1.

得られた塗布剤についての総合評価は非常に良好であっ
た。
The overall evaluation of the obtained coating agent was very good.

実施例3 流動パラフィン(実施例2と同じ)1%、ポリアクリル
酸ナトリウム(実施例1と同じ)α001係およびモル
ホリン脂肪酸塩(高松油脂jJ5)0.01係を含む水
分散液を実施例1と同様にして調製1−たO 得られた塗布剤についての総合評価は良好であつた0 実施例4 流動パラフィン(実施例1と同じ)3%、ポリアクリル
酸ナトリウム(実施例1と同じ)1005%およびモル
ホリン脂肪酸塩(高松油脂製)cl、05係を含む水分
散液を実施例1と同様にして調製した。
Example 3 An aqueous dispersion containing 1% liquid paraffin (same as Example 2), α001 part of sodium polyacrylate (same as Example 1) and 0.01 part of morpholine fatty acid salt (Takamatsu Yushi jJ5) was prepared in Example 1. Example 4 Liquid paraffin (same as Example 1) 3%, sodium polyacrylate (same as Example 1) An aqueous dispersion containing 1005% and morpholine fatty acid salt (manufactured by Takamatsu Yushi) Cl, 05 was prepared in the same manner as Example 1.

得られた塗布剤についての総合評価はきわめて良好であ
った。
The overall evaluation of the obtained coating agent was extremely good.

実施例5 流動パラフィン(実施例1と同じ)15%、ポリアクリ
ル酸ナトリウム(実施例1と同じ)[15%2モルホリ
ン脂肪酸塩(高松油脂製)3.5%およびエチルアルコ
ール5.5%を含む水分散液を実施例1と同様にして調
製j〜た。
Example 5 Liquid paraffin (same as Example 1) 15%, sodium polyacrylate (same as Example 1) [15% 2 morpholine fatty acid salt (Takamatsu Yushi Co., Ltd.) 3.5% and ethyl alcohol 5.5%] An aqueous dispersion containing the following was prepared in the same manner as in Example 1.

得られた塗布剤についての総合、評価はきわめて良好で
あった。
The overall evaluation of the obtained coating agent was extremely good.

実施例6 流動パラフィン(実施例2と同じ)30%、ポリアクリ
ル酸ナトリウム(実施例1と同じ)t5係およびモルホ
リン脂肪酸塩(高松油脂製)5%を含む水分散液を実施
例1と同様にして調製]−た。
Example 6 An aqueous dispersion containing 30% liquid paraffin (same as in Example 2), t5 of sodium polyacrylate (same as in Example 1) and 5% of morpholine fatty acid salt (manufactured by Takamatsu Yushi Co., Ltd.) was prepared in the same manner as in Example 1. [prepared]

得られた塗布剤についての総合評価は良好であった0 実施例7 流動パラフィン(実施例2と同じ)50%、ポリアクリ
ル酸ナトリウム(実施例1と同じ)4.5%1モルホリ
ン脂肪酸塩(高松油脂製)13%およびプロピレングリ
コール10%を含む水分散液を実施例1と同様にして調
製I−た。
The overall evaluation of the obtained coating agent was good.0 Example 7 Liquid paraffin (same as Example 2) 50%, sodium polyacrylate (same as Example 1) 4.5% 1 Morpholine fatty acid salt ( An aqueous dispersion containing 13% (manufactured by Takamatsu Yushi) and 10% propylene glycol was prepared in the same manner as in Example 1.

得られた塗布剤についての総合評価は良好であった0The overall evaluation of the obtained coating agent was good.0

Claims (1)

【特許請求の範囲】 t (A)流動パラフィンおよび/またはカルナウバろ
う、(B)ポリアクリル酸ナトリウムおよび(C)モル
ホリン脂肪酸塩を含有せしめたびん類の擦れ傷塗布剤。 入水分散液中に(4)成分を50%以下、(B)成分を
5係以下および(C)成分を15%以下の割合で含有す
る特許請求の範囲第1項記載の組成物。
[Scope of Claims] A coating agent for abrasions on bottles containing (A) liquid paraffin and/or carnauba wax, (B) sodium polyacrylate, and (C) morpholine fatty acid salt. The composition according to claim 1, wherein the aqueous dispersion contains component (4) in a proportion of 50% or less, component (B) in a proportion of 5% or less, and component (C) in a proportion of 15% or less.
JP866483A 1983-01-24 1983-01-24 Coating agent for concealing scratch on bottle Granted JPS59137347A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP866483A JPS59137347A (en) 1983-01-24 1983-01-24 Coating agent for concealing scratch on bottle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP866483A JPS59137347A (en) 1983-01-24 1983-01-24 Coating agent for concealing scratch on bottle

Publications (2)

Publication Number Publication Date
JPS59137347A true JPS59137347A (en) 1984-08-07
JPH0420862B2 JPH0420862B2 (en) 1992-04-07

Family

ID=11699196

Family Applications (1)

Application Number Title Priority Date Filing Date
JP866483A Granted JPS59137347A (en) 1983-01-24 1983-01-24 Coating agent for concealing scratch on bottle

Country Status (1)

Country Link
JP (1) JPS59137347A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6828382B1 (en) * 1997-11-07 2004-12-07 Henkel Kommanditgesellschaft Auf Aktien Polyacrylate joint sealants

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6828382B1 (en) * 1997-11-07 2004-12-07 Henkel Kommanditgesellschaft Auf Aktien Polyacrylate joint sealants

Also Published As

Publication number Publication date
JPH0420862B2 (en) 1992-04-07

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