JPS5875705A - Composition for heating panel heater - Google Patents
Composition for heating panel heaterInfo
- Publication number
- JPS5875705A JPS5875705A JP17288581A JP17288581A JPS5875705A JP S5875705 A JPS5875705 A JP S5875705A JP 17288581 A JP17288581 A JP 17288581A JP 17288581 A JP17288581 A JP 17288581A JP S5875705 A JPS5875705 A JP S5875705A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- rubber
- metal
- heating panel
- panel heater
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発ａａ、面状発熱体に用いて有用な斃熱用組成−に関
するものである◇
従来、面状発熱体の尭熱用履成物としては、価格の閏な
どから有利であるゴム若しく社プッスチッタに導電性カ
ーボンを配合したものが用いられているが、かかる組成
物を使用し良１状尭熱体の場合、使用ｔｓｉ絖している
間に発熱量が著しく減少し、製品の長期安定性に欠ける
−があう九〇
そこて、本発明看等が、価格向で膚ｆ１なゴム、グラス
チック０４１性會生しつつ、長期安定性に優れ九発熱体
を一発すべく、鋭意研究し九結果、ゴム、プラスチνり
に導電性カーボンを配合する匍に１金属と配位結合し得
る化合物を配合したところ、最期的に安定した発熱体の
発熱用組成物を得ることができることを見い出した。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a heating composition useful for use in planar heating elements ◇ Conventionally, as heating footwear for planar heating elements, there have been a number of Rubber or steel sheets mixed with conductive carbon are used, but when such a composition is used to make a high-quality heating element, the amount of heat generated during use decreases. Therefore, the present invention has been developed to create a heat generating element with excellent long-term stability while having the properties of rubber and glasstic 041, which are cost effective and have excellent long-term stability. In order to make a breakthrough, we conducted extensive research and found that by blending a compound capable of coordinating with a metal into a compound that combines conductive carbon with rubber and plastic, we finally achieved a stable heating element composition. I discovered that I could get things done.
本発明は、このような点に着目してなされ良もので、そ
の目的とするところは、面状発熱体に用いｆＩ−場合、
長期に畝って発熱量の１低下のない発熱用組成物を提供
することにＴｏゐ。The present invention has been made with attention to these points, and its purpose is to
Our aim is to provide a heat-generating composition that does not deteriorate in calorific value over a long period of time.
かかる本角＠０＊黴社、上述のようにゴム若しくはプラ
スチックと導電性カーボンと金属と配位傭合し得る化合
物とよりなる発熱用組成物にある。As mentioned above, Honkaku@0*Kosha is a heat-generating composition comprising rubber or plastic, conductive carbon, and a compound capable of coordinating with metal.
本発明において便用されるゴム若しくはプラスチックと
しでは、大鏡ゴム中、シリコンゴム、ＩＦＩム、スチレ
ンブタジェンゴム（８ＢＲ）などの合成ゴム、ｔ＋はポ
リエチレン（アｌ）、アイオノマー、エチレン−酢ピコ
ポリｗ −（１マム）などのポリオレアイン彎脂、エポ
キシ樹層など、およびそれらの混合物が使用できる。Rubbers or plastics conveniently used in the present invention include silicone rubber, IFI rubber, synthetic rubber such as styrene-butadiene rubber (8BR), t+ is polyethylene (Al), ionomer, ethylene-acetate picopolymer, etc. Polyolein resins such as w-(1um), epoxy resin layers, and mixtures thereof can be used.
そして、導電性カーボン紘、これらゴム著しく社プラス
チツタ１００重量ｓＫ対し、ｌＯ〜１２０重量藝が望ま
しい。もし、１０重量部未満で杜十分な導電性が祷られ
ず、また１２０重量部を越えると、導電性より＆に錆性
が晶化して好ましくない。It is desirable that the conductive carbon material has a weight of 10 to 120 sK compared to 100 sK of these rubbers. If it is less than 10 parts by weight, sufficient electrical conductivity cannot be expected, and if it exceeds 120 parts by weight, it is undesirable because it becomes more rusty than it is electrically conductive.
また、金属と配位結合し得る化合物、４ＩＫ有機化合物
としては、エチレンシア電ン四酢ＩＩ（ｌＤテム）、ｉ
（ｍ−サリチロイル）ア建ノー１．２．４−）リアゾー
ル、ヒト２ジン誘導体、シラドラジン誘導体などを使用
することができる。この化合物の１ｌ−１１，い使用線
１ｌＦｉ、ゴム若しくはプラスチック１００重量部に対
し、α００１〜＆０重量部までがよい０ＱＯＯ１未満で
線満足な添加効果が得られず、オ危Ｓ重量ｌＩｔ越える
と、得られる効果よりｔ１経済性の点が晶化する九め好
筐しくない。In addition, as compounds capable of coordinating with metals, 4IK organic compounds, ethylenecyadenatetetraacetic acid II (ID tem), i
(m-salicyloyl)aryazole, human diazine derivatives, siladrazine derivatives, etc. can be used. 1l-11 of this compound, using 1lFi, 100 parts by weight of rubber or plastic, α001~&0 parts by weight is good.If it is less than 0QOO1, a satisfactory addition effect cannot be obtained, and it is dangerous.If the weight exceeds 1It, It is not a good case that the t1 economy is more important than the effect obtained.
この金属と配位結合し得る化合物を添加し危発熱用組成
物を用いることによシ、輪状発熱体の長期安定性が着し
く向上するのは次の層内によると、推論される。It is inferred that the long-term stability of the annular heating element is significantly improved by adding a compound capable of coordinating with this metal and using a composition for generating hazardous heat, based on the following layer.
一般にゴム、プラスチツタに導電性カーボンを配合し死
中導電性の発熱用組成−ｔＭいた通常の向状俺亀体にお
かて社、成形時の歪みや熱膨張率の違いなどから、継ｌ
１ＲＩ！用の後にありて低下は避けられなか′：ｈ九わ
けであるが、本発明のように金属と配位結合し得る有機
化合物を配合し九発熱用組成物の場合にありては、この
化合物の緒合力により、電他Ｏ導体金属との密着性がよ
いため、電気的接触が長期に渡って安定して保九れ、よ
って、発熱４Ｉ性の安定し大園状尭鵬体が得られるから
である。In general, conductive carbon is blended with rubber or plastic to create a heat-generating composition that is conductive during death.
1RI! However, in the case of a heat-generating composition containing an organic compound capable of coordinating with a metal as in the present invention, this compound Due to the combined force of the wires, the adhesion with the conductor metal is good, so the electrical contact is maintained stably for a long time, and a stable large-sized body with heat generation properties can be obtained. It is.
以下、本発明の実施例について述べる。Examples of the present invention will be described below.
本！ｉ＠の告実施ガに係る発熱用組成物の配合例とその
発熱量の経時変化を示すと、次表の如くであり九〇崗、
参ｊｌｔでに金属と配位結合し得る化合物を添加しなか
り九従米のものを比較例としかつその発熱量の経時変化
も示しである。Book! The following table shows a formulation example of the exothermic composition according to the i@ notification implementation and its calorific value over time.
As a comparative example, a sample made from Kujomai, in which no compound capable of coordinating with metal was added, is also shown, and the change in calorific value over time is also shown.
これら各実線１１ＩＩｌｓＰよび比較例に用いｆｔｌ状
発熱体の構造は（’ｌに限定されないが）、橋付ＩｇＩ
Ｉｉの如くで、長尺に押し出した発熱用組成物１０両＠
縁寄夛に一対の電極として１ ｍ ｌｉｌ Ｏ軟鋼線２
．２ｔ−設けると共に、組成物１上には絶縁体３を被覆
したものである０
表
ｍ＊４１４１俄のｍ厘は、周−温ｇｏｔ、発熱体の定常
ＩＩ用時ｏ＊＊ａｓｃで、１時間ＯＮ。The structure of the ftl-shaped heating element used in each of these solid lines 11IIlsP and the comparative example is (although not limited to 'l) a bridged IgI
10 exothermic compositions extruded into long lengths as shown in Ii @
1 ml O mild steel wire 2 as a pair of electrodes on the edge
．． 2t is provided, and the composition 1 is coated with the insulator 3. Table m*4141 shows the ambient temperature got, o**asc when the heating element is used in steady state II, and 1 Time is on.
１ 時１４ｏ ｙ ｙ ０１ｉｊ１ＭＬｔ １年間継続
して行なりた０
上記表から、金属と配位結合し得る化合−を添加し九本
尭＠ｖ＆廁例の場合、発熱量の経時変化轢殆んどなく、
長期安定性に優れているのに対し、上記化金物を會塘な
い従来の組成物の場合、発熱量の経時変化が着しく、使
用１年後には殆んどｉＩ！用不簡となることがわかる０
、崗、本発−の発電用組成物にあっては、ゴム、プラス
チツタに対し、導電性カーボン、金属と配位結合し得る
化金物の他に、必４１！なその他の充填剤などｔ適宜添
加することも可能であるＯ以上Ｏ貌明から明らかなよう
に本発明によれば、ゴム若しくは１ツスチツクに対し、
導電性カーボンと共に金属と配位結合し得る化合物を配
合しであるため、ｗＡ状発熱体に使用した場合、長期に
渡って安定した発熱量會鴎持する優れ穴発熱Ｍｉｌｌｉ
成物會得ることかで自る０４−一の簡単な鋺―
図は本発明に係る発熱用組成物を使用した面状発熱体の
一例を示す斜視図である。1 14o y y 01ij1MLt From the above table, in the case of adding a compound that can coordinate with a metal, the change in calorific value over time is almost the same. Without,
However, in the case of conventional compositions that do not contain the above-mentioned metal compounds, the calorific value changes rapidly over time, and after one year of use, almost iI! I know it will be inconvenient 0
In the power generation composition of the present invention, in addition to conductive carbon and a metal compound capable of coordinating with metal, 41! It is also possible to appropriately add other fillers such as
Because it contains conductive carbon and a compound that can coordinate with metals, it is an excellent hole heating product that maintains a stable calorific value over a long period of time when used in a wA-shaped heating element.
The figure is a perspective view showing an example of a planar heating element using the heating composition according to the present invention.
ｌ・・・発熱用組成物、２．２−電極、３−・絶縁体l... Heat generating composition, 2.2-electrode, 3-.insulator
Claims (1)
位結合し得る化合物とよりなることｔ４Ｉ黴とする面状
発熱体の発熱用組成物。A heat generating composition for a planar heating element, comprising rubber or plastic, conductive carbon, and a compound capable of coordinating with a metal.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17288581A JPS5875705A (en) | 1981-10-30 | 1981-10-30 | Composition for heating panel heater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17288581A JPS5875705A (en) | 1981-10-30 | 1981-10-30 | Composition for heating panel heater |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5875705A true JPS5875705A (en) | 1983-05-07 |
Family
ID=15950120
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17288581A Pending JPS5875705A (en) | 1981-10-30 | 1981-10-30 | Composition for heating panel heater |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5875705A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62215659A (en) * | 1986-01-30 | 1987-09-22 | サンビーム コーポレーシヨン | Electroconductive composite polymer material and manufacture |
| US4855091A (en) * | 1985-04-15 | 1989-08-08 | The Dow Chemical Company | Method for the preparation of carbon filaments |
| US5607996A (en) * | 1994-10-05 | 1997-03-04 | Ford Motor Company | Electrorheological elastomers useful as variable stiffness articles |
-
1981
- 1981-10-30 JP JP17288581A patent/JPS5875705A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4855091A (en) * | 1985-04-15 | 1989-08-08 | The Dow Chemical Company | Method for the preparation of carbon filaments |
| JPS62215659A (en) * | 1986-01-30 | 1987-09-22 | サンビーム コーポレーシヨン | Electroconductive composite polymer material and manufacture |
| US5607996A (en) * | 1994-10-05 | 1997-03-04 | Ford Motor Company | Electrorheological elastomers useful as variable stiffness articles |
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