JPS5821690B2 - Foaming liquid for gas leak inspection - Google Patents
Foaming liquid for gas leak inspectionInfo
- Publication number
- JPS5821690B2 JPS5821690B2 JP52021329A JP2132977A JPS5821690B2 JP S5821690 B2 JPS5821690 B2 JP S5821690B2 JP 52021329 A JP52021329 A JP 52021329A JP 2132977 A JP2132977 A JP 2132977A JP S5821690 B2 JPS5821690 B2 JP S5821690B2
- Authority
- JP
- Japan
- Prior art keywords
- foaming liquid
- foaming
- water
- fatty acid
- gas leak
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Examining Or Testing Airtightness (AREA)
Description
【発明の詳細な説明】
本発明は、例えば都市ガス・加圧ガス等の弁・パイプ接
続部などに起泡液を塗布してその発泡の有無によりガス
の漏洩を検査する方法に於て使用する気体漏洩検査用起
泡液に係り、被検体を腐蝕。[Detailed Description of the Invention] The present invention is used in a method of applying a foaming liquid to valves, pipe connections, etc. of city gas, pressurized gas, etc. and inspecting for gas leakage by checking the presence or absence of foaming. The foaming liquid for gas leak testing corrodes the test object.
させ、ることかな、く、且つ泡の発泡性・安定性のよい
安価な起泡液を得ることを目的とする。To obtain an inexpensive foaming liquid that has good foaming properties and stability.
従来は市販の適宜の石鹸或は合成洗剤を水に溶解して適
当濃度の石鹸水を作り、これを起泡液として用いるもの
である。Conventionally, commercially available soaps or synthetic detergents are dissolved in water to prepare soapy water of an appropriate concentration, and this is used as a foaming liquid.
然しなから石鹸水中には芒硝等の無機塩が含まれている
から検査後乾燥によりその無機塩が弁等の被検体表面に
白く付着残存して被検体の外観を損うと共に被検体に腐
蝕を生じさせ、甚しい場合には検査の度毎に遂次堆積し
た無機塩、及び腐蝕の進行により弁の開閉機能をも困難
にする。However, since soapy water contains inorganic salts such as mirabilite, when dried after the test, the inorganic salts remain as white adherents on the surface of the test object such as valves, damaging the appearance of the test object and corroding the test object. In severe cases, the opening and closing functions of the valve become difficult due to the inorganic salts that accumulate with each inspection and the progress of corrosion.
又石鹸水はガス漏洩検査用起泡液として十分な泡の発泡
性・安定性を具備しているとは云えない。In addition, soap water cannot be said to have sufficient foaming properties and stability as a foaming liquid for gas leakage inspection.
本発明は上記に鑑みて被検体を腐蝕させることなく、且
つ泡の発泡性・安定性に優れた特殊成分及び組成のガス
漏洩検査用起泡液を開発したもので、直鎖アルキルベン
ゼンスルホン酸ソーダ(5)と、脂肪酸ジェタノールア
ミド囚とをW:(B)−(2〜3):(0,5〜2)重
量部の割合で水に溶解させて成るガス漏洩検査用起泡液
を要旨とする。In view of the above, the present invention has developed a foaming liquid for gas leakage inspection with special ingredients and composition that does not corrode the test object and has excellent foaming properties and stability. (5) and fatty acid jetanolamide prisoner are dissolved in water at a ratio of W:(B)-(2-3):(0.5-2) parts by weight. This is the summary.
父上配回及び(B)の成分の他に更に脂肪酸モノエタノ
ールアミド1モルに5〜10モルのエチレンオキサイド
を付加したものC(脂肪酸モノエタノールアミド1分子
に5〜10分子のエチレンオキサイドが直鎖に化学結合
したもの)を(A) ::B) :(C’)= (2〜
3):(0,5〜2):(0,1〜1)重量部の割合で
水に溶解させて成るガス漏洩検査用起泡液を要旨とする
。In addition to the parent structure and component (B), 5 to 10 moles of ethylene oxide are added to 1 mole of fatty acid monoethanolamide C (5 to 10 molecules of ethylene oxide are linearly chained to 1 molecule of fatty acid monoethanolamide) (chemically bonded to) (A) ::B) :(C')= (2~
3):(0,5-2):(0,1-1) parts by weight of a foaming liquid for gas leakage inspection, which is dissolved in water.
起泡液の調整は上記特定割合の囚及び(B)、或は(5
)、(B)及びCを適当少量の水に一旦溶解して原液と
し、使用に際して該原液を100〜200倍に希釈して
用いる。The foaming liquid can be adjusted using the above specified ratio and (B) or (5).
), (B) and C are once dissolved in an appropriate small amount of water to make a stock solution, and the stock solution is diluted 100 to 200 times before use.
囚、 (B) 、 (C)の各成分の起泡性は個々には
高いものではないが、(5)、(B)或は(A) 、
(B) 、 (0と組合せて且つそれ等の相互配合割合
を上記特定の割合にして水に溶解させたときは各成分の
相乗的効果によりガス漏洩検査用として十分な起泡性と
安定性を有する起泡液となることが実験により確められ
九即ち、Aの2〜3重量部に対してBを0.5〜2重量
部以上の割合にしても液全体の起泡性・安定性のそれ以
上の向上はなく、又Bは高価なものであるので不経済で
ある。Although the foaming properties of each component (B) and (C) individually are not high, (5), (B) or (A),
(B) (When combined with 0 and dissolved in water at the above specified ratio, the synergistic effect of each component results in sufficient foaming properties and stability for gas leak testing. It has been confirmed through experiments that a foaming liquid with There is no further improvement in performance, and since B is expensive, it is uneconomical.
又Bの割合を上記以下にすると泡立・安定性が低下し、
Bの添加効果がない。Also, if the proportion of B is lower than the above, foaming and stability will decrease,
There is no effect of adding B.
又Aに対しCを0.1〜1重量部以上にすると液全体の
粘度が低下し逆効果となる。Furthermore, if C is added to A in an amount of 0.1 to 1 part by weight or more, the viscosity of the entire liquid decreases, resulting in an adverse effect.
父上記以下ではCの添加効果がない。Below the above, there is no effect of adding C.
又(0の成分についてエチレンオキサイドの付加量を5
モル以下にすると水溶解度が低下し、10モル以上にす
ると粘度が低下してそれ自体の起泡性が低下すると共に
成分(5)、(B)と組合せた場合に於ても相乗的効果
を十分には得ることが出来ない。In addition, (for the component 0, the amount of ethylene oxide added is 5
When the amount is less than 1 mol, the water solubility decreases, and when it is 10 mol or more, the viscosity decreases and the foaming property itself decreases, and when combined with components (5) and (B), there is no synergistic effect. I can't get enough.
以上本発明の特定成分・特定配合割合から成る起泡液は
以下の実施例及び比較例から明らかなように従来の石鹸
水と異なり、被検体に対する無機塩の付着残存、腐蝕性
がなく、又ガス漏洩検査用の起泡液として十分な起泡性
と泡安定性を有する。As mentioned above, the foaming liquid composed of the specific ingredients and specific blending ratio of the present invention is different from conventional soapy water, as is clear from the following Examples and Comparative Examples, and has no residual inorganic salt adhesion or corrosivity to the test object. It has sufficient foaming properties and foam stability as a foaming liquid for gas leak inspection.
又100〜200倍に希釈した低濃度で十分に使用出来
るから極めて経済的である。Furthermore, it is extremely economical because it can be used at a low concentration diluted 100 to 200 times.
更に皮膚に対。する刺激性もほとんどなく安全なもので
、ガス漏洩検査用の起泡液として有効適切である。Furthermore, against the skin. It is safe with almost no irritation, and is effective and suitable as a foaming liquid for gas leak inspection.
実施例 1 +成分囚
直鎖アルキルベンゼンスル
ホン酸ソーダ(LAS−Na)
の50%水溶液 36重量%
(無機塩1%以下)
成分(B)° やし油脂肪酸ジェタノールアミド(脂
肪酸とジエタノ 6 〃
−ルアミドのモル比1:1)
水 58 〃をよく
混合して原液とした(AとBの重量比3:1)。Example 1 + Component 50% aqueous solution of linear sodium alkylbenzenesulfonate (LAS-Na) 36% by weight (inorganic salt 1% or less) Component (B) ° Coconut oil fatty acid jetanolamide (fatty acid and dietano 6 - (molar ratio of A and B: 1:1) and water were thoroughly mixed to obtain a stock solution (weight ratio of A and B: 3:1).
使用に際してはこれを200倍に希釈した実施例 2
実施例1に於て成分(2)、1刊の他に更に成分(C)
としてやし油脂肪酸モノエタノールアミド1モルにエチ
レンオキサイドを5モル付加したものを3重量%加えて
原液としくA:B:Cの重量比3:1:0.5)、使用
に際して該原液を200倍に希釈した。Example 2 In addition to the component (2) in Example 1 and the first issue, component (C) was diluted 200 times before use.
Add 3% by weight of 5 moles of ethylene oxide to 1 mole of coconut oil fatty acid monoethanolamide to make a stock solution. It was diluted 200 times.
比較例
市販の液体合成洗剤(アニオン界面活性剤・トリポIJ
IJン酸ソーダ等を成分とするもの)を水で10倍に
希釈して検査液とした。Comparative example: Commercially available liquid synthetic detergent (anionic surfactant/Tripo IJ)
A test solution was prepared by diluting IJ (containing sodium chloride, etc. as a component) ten times with water.
以上の実施例1,2、及び比較例の検査液についての各
種試験結果は下表の通りであった。The various test results for the test solutions of Examples 1 and 2 and Comparative Example above are as shown in the table below.
尚、泡立及び安定度試験はJISK3362のロス・マ
イルス(Ross & Milss)法による。Note that the foaming and stability tests were conducted according to the Ross & Milss method of JIS K3362.
腐蝕試験は起泡液中にテストピースとして鉋金片を6ケ
月間浸漬放置して腐蝕の発生の有無を見た。In the corrosion test, a piece of planer metal was immersed as a test piece in a foaming solution for 6 months to see if corrosion occurred.
成分の付着残存は、鉋金片に起泡液を塗布し乾燥するサ
イクルを数回繰返して成分の付着残存具合を見た。To determine whether or not the components remained attached, the cycle of applying the foaming liquid to the planer piece and drying it was repeated several times to check the degree to which the components remained attached.
又実施1,2の原液及び比較例の液体合成洗剤について
それ等を10倍・50倍・100倍。Also, the undiluted solution of Examples 1 and 2 and the liquid synthetic detergent of Comparative Example were multiplied by 10 times, 50 times, and 100 times.
200倍・300倍に希釈したものの各泡立ち及び安定
度試験結果を下表に示す。The table below shows the foaming and stability test results for 200-fold and 300-fold dilutions.
Claims (1)
酸ジエタノールアミド(B)とを(A):(B)−(2
〜3):(0,5〜2)重量部の割合で水に溶解させて
成る気体漏洩検査用起泡液。 2 直鎖アルキルベンゼンスルホン酸ソーダ(4)と、
脂肪酸ジェタノールアミド(Blと、脂肪酸モノエタ。 ノールアミド1モルに5〜10モルのエチレンオキサイ
ドを付加したもの(0とを、(A):(Bl:(C’1
=(2〜3):(0,5〜2):(o、1〜1)重量部
の割合で水に溶解させて成る気体漏洩検査用起泡液。[Claims] 1. Linear alkylbenzenesulfonic acid sodium hydroxide and 9-fatty acid diethanolamide (B) (A):(B)-(2
-3): A foaming liquid for gas leakage inspection, which is dissolved in water at a ratio of (0.5 to 2) parts by weight. 2 linear alkylbenzenesulfonate sodium (4),
Fatty acid jetanolamide (Bl and fatty acid monoeta. 5 to 10 moles of ethylene oxide added to 1 mole of nolamide (0), (A):(Bl:(C'1)
= (2-3): (0, 5-2): (o, 1-1) A foaming liquid for gas leakage inspection, which is dissolved in water in a proportion of parts by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP52021329A JPS5821690B2 (en) | 1977-02-28 | 1977-02-28 | Foaming liquid for gas leak inspection |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP52021329A JPS5821690B2 (en) | 1977-02-28 | 1977-02-28 | Foaming liquid for gas leak inspection |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS53106189A JPS53106189A (en) | 1978-09-14 |
JPS5821690B2 true JPS5821690B2 (en) | 1983-05-02 |
Family
ID=12052091
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP52021329A Expired JPS5821690B2 (en) | 1977-02-28 | 1977-02-28 | Foaming liquid for gas leak inspection |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5821690B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59157913U (en) * | 1983-04-08 | 1984-10-23 | マツダ株式会社 | Automotive door glass suction prevention structure |
JPS6034920U (en) * | 1983-08-17 | 1985-03-09 | マツダ株式会社 | Automobile door glass sealing device |
JPS60139516U (en) * | 1984-02-28 | 1985-09-14 | 富士重工業株式会社 | Vehicle door glass lifting prevention device |
JPS61105220U (en) * | 1984-12-17 | 1986-07-04 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107727323A (en) * | 2017-11-07 | 2018-02-23 | 中石油昆仑燃气有限公司 | A kind of gas leakage detects liquid |
-
1977
- 1977-02-28 JP JP52021329A patent/JPS5821690B2/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59157913U (en) * | 1983-04-08 | 1984-10-23 | マツダ株式会社 | Automotive door glass suction prevention structure |
JPS6034920U (en) * | 1983-08-17 | 1985-03-09 | マツダ株式会社 | Automobile door glass sealing device |
JPS60139516U (en) * | 1984-02-28 | 1985-09-14 | 富士重工業株式会社 | Vehicle door glass lifting prevention device |
JPS61105220U (en) * | 1984-12-17 | 1986-07-04 |
Also Published As
Publication number | Publication date |
---|---|
JPS53106189A (en) | 1978-09-14 |
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