JPS5814810B2 - Electron beam exhaust gas desulfurization and denitrification method and equipment - Google Patents
Electron beam exhaust gas desulfurization and denitrification method and equipmentInfo
- Publication number
- JPS5814810B2 JPS5814810B2 JP53006058A JP605878A JPS5814810B2 JP S5814810 B2 JPS5814810 B2 JP S5814810B2 JP 53006058 A JP53006058 A JP 53006058A JP 605878 A JP605878 A JP 605878A JP S5814810 B2 JPS5814810 B2 JP S5814810B2
- Authority
- JP
- Japan
- Prior art keywords
- electron beam
- electric field
- desulfurization
- exhaust gas
- denitrification
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Treating Waste Gases (AREA)
- Electrostatic Separation (AREA)
Description
【発明の詳細な説明】
本発明は燃焼排ガス中に含まれるＳＯ２およびＮＯを電
子ビームと電界の組合せ効果により迅速有効に除去する
所の排ガス脱硫脱硝方法および装置に関するものである
。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an exhaust gas desulfurization and denitrification method and apparatus for rapidly and effectively removing SO2 and NO contained in combustion exhaust gas by the combined effect of an electron beam and an electric field.
Ｓ０２およびＮＯを含有する排ガス中に高エネルギーの
電子ビームを金属箔を通して照射することにより、ＳＯ
２およびＮＯを固体ないし液体の微粒子に転化せしめ、
これを照吋室外の下流領域に設けた適当な後置集塵装置
（例えは電気集塵装置）により該排ガス中より除去する
所の、いわゆる電子ビーム排ガス脱硫脱硝方式はそれ自
体公知である。By irradiating the exhaust gas containing S02 and NO with a high-energy electron beam through a metal foil, SO2 is removed.
2 and NO into solid or liquid fine particles,
The so-called electron beam exhaust gas desulfurization and denitration method, in which this is removed from the exhaust gas by a suitable downstream dust collector (for example, an electrostatic precipitator) provided in the downstream area outside the irradiation room, is known per se.
また上記方式において電子ビーム照射室の内部に直接適
当な正負の電極を対向配置し、その間に高電圧を印加す
ることにより、ＳＯ２ないしＮＯより転化せる微粒子を
直接該電極表面上に電気的に除去堆積せしめ得ることも
、それ自体公知である。In addition, in the above method, suitable positive and negative electrodes are placed opposite each other directly inside the electron beam irradiation chamber, and by applying a high voltage between them, fine particles that can be converted from SO2 or NO are directly electrically removed on the surface of the electrodes. It is also known per se that it can be deposited.
すなわち本願発明者はこの方法によって極めて有効に転
化微粒子を排ガスより電気的に除去することか出来、こ
れによって上記の後置集塵装置を省略できることを実験
的に見出した（例えば本願発明者の発表論文［電子ビー
ムを利用した電気集塵の実験（その１）−１昭和５１年
電気学会全国大会論文集４６４、「同（その２）」同４
６５参照）。In other words, the inventor of the present invention has experimentally discovered that by this method, the converted particles can be electrically removed from the exhaust gas, and that the above-mentioned post-collection device can be omitted (for example, as described in the inventor's announcement). Paper [Experiment on electrostatic precipitation using electron beam (Part 1)-1 Proceedings of the 1976 National Conference of the Institute of Electrical Engineers of Japan 464, "Same (Part 2)" Same 4
65).
この場合、電子ビームのガス分子への衝突電離により電
極間に生成する正負イオンの濃度は電界の作用で大きく
変歪し、正電極近傍では負イオン濃度が増大、負電極近
傍では正イオン濃度が増大して、正電極近傍の転化微粒
子はイオン射突により負に荷電されて正電極に吸引附着
し、負電極近傍の転化微粒子は同様にして負電極に附着
除去されるのであって、その電気的微粒子除去効果は上
記電界、すなわち挿入電極の印加電圧と共にほぼ比例的
に上昇する。In this case, the concentration of positive and negative ions generated between the electrodes due to the impact ionization of the electron beam on gas molecules is greatly distorted by the action of the electric field, with the negative ion concentration increasing near the positive electrode and the positive ion concentration decreasing near the negative electrode. The converted particles near the positive electrode are negatively charged by ion bombardment and are attracted to the positive electrode, and the converted particles near the negative electrode are similarly attached to the negative electrode and removed. The particle removal effect increases almost proportionally with the electric field, that is, with the applied voltage of the inserted electrode.
本願発明者は更にこの様な電子ビーム照射空間への電界
の重畳が電子ビームによる放射線化学的脱硫脱硝反応自
体におよぼす作用を詳細に探究した結果、電極間に形成
される電界の値がある特定の閾値、すなわち３〔Ｋ■／
ＣｒｒＬ〕を越えると、該脱硫脱硝反応の反応速度が第
３図に示した如く、突然急激に上昇し、電界の上昇によ
って容易に電子ビームの照射のみの場合の数倍の反応速
度上昇効果を達成しうろことを見出した。The inventor of the present application has further investigated in detail the effect that the superimposition of an electric field on the electron beam irradiation space has on the radiochemical desulfurization and denitrification reaction itself by the electron beam, and has found that the value of the electric field formed between the electrodes has a certain value. threshold, that is, 3 [K■/
CrrL], the reaction rate of the desulfurization and denitrification reaction suddenly increases rapidly as shown in Figure 3, and the increase in the electric field easily increases the reaction rate several times that of electron beam irradiation alone. I discovered what I could achieve.
その機構の詳細は未だ明らかではないが、一応脱硫脱硝
反応に寄与しえないエネルギーレベル迄下った電子を電
界によって加速し、そのエネルギーを再び再生するため
ではないかと予想される。The details of the mechanism are not yet clear, but it is assumed that the electric field accelerates electrons whose energy level has dropped to a level where they cannot contribute to the desulfurization and denitrification reaction, and regenerates that energy again.
いずれにせよ上述の微粒子除去効果が印加電界の増加と
共にほぼ連続的な増加を見せるのに対し、本反応促進効
果は電界を上記閾値以上にした時にはじめてあらわれる
特異な作用効果であって、この時の反応速度の増分は、
電界の上記閾値からの増分の約５乗に比例するという著
るしいものである。In any case, while the above-mentioned particulate removal effect shows an almost continuous increase as the applied electric field increases, this reaction promotion effect is a unique effect that appears only when the electric field is increased above the above threshold. The increment of reaction rate is
This is remarkable as it is proportional to about the fifth power of the increase in electric field from the above threshold value.
本発明はこの特異な作用効果を利用することにより、従
来公知の電子ビーム脱硫脱硝方式に固有の重大な欠点、
すなわち電子ビーム発生装置の設備費および運転費が著
るしく高価となるという問題を克服し、電子ビーム発生
装置の設備容量ならびに運転費を大巾に低減することを
可能ならしめた安価で経済的な新規の電子ビーム排ガス
脱硫脱硝方法および装置を提供することを目的とする。By utilizing this unique effect, the present invention solves the serious drawbacks inherent in the conventionally known electron beam desulfurization and denitrification methods.
In other words, it is an inexpensive and economical method that overcomes the problem of extremely high equipment costs and operating costs for electron beam generators, and makes it possible to significantly reduce the equipment capacity and operating costs of electron beam generators. The purpose of the present invention is to provide a novel electron beam exhaust gas desulfurization and denitrification method and device.
すなわち、本発明は、ＳＯ２およびＮｏを含有する排ガ
ス中に、少くとも電界による脱硫脱硝反応促進効果のあ
らわれる閾値たる３ｒＫＶ／ｃ／ｒＬ）以上の補助電界
を形成する如く高電王を印加し、該３〔Ｋ■／ｃＴＬ〕
以七の補助電界の作用下に電子ビームを金属箔を通して
照射し、該電子ビームと該補助電界の協同作用によって
該Ｓ０２，ＮＯを迅速有効に微粒子に転化の上、これを
電子ビーム照射室の内部に絶縁の上対向配置した電極群
の表面上に電気的に附着せしめ、これを電極表面より剥
離してホツパー内に落下せしめたのち微粒子排出口より
外部に排出し、脱硫脱硝後の清浄ガスをガス出口よりス
タックへ排出することを特徴とし、およびＳＯ２および
ＮＯを含有する排ガスを導入するためのガス入口と、脱
硫脱硝後の清浄ガスを排出するためのガス出口と、Ｓ０
２，ＮＯより転化された微粒子を落下送入するためのホ
ッパ一部と、該ホッパ一部より該微粒子を外部に排出す
るための微粒子排出口と、電子ビームを導入するための
金属箔を持った照射窓とを備えた所の函体より成る照射
室を有し、かつ該照射窓を通して該照射室内に電子ビー
ムを照射するための電子ビーム発生装置を有し、かつ該
照射室内に互に絶縁の上対向配置せる反応促進用電極群
を有し、かつ該電極群の間に少くとも３ＣＫＶ／ｃｒｆ
Ｌ）以上の補助電界を形成する如く高電圧を印加するた
めの高圧電源を有することを特徴とする。That is, the present invention applies a high electric field to the exhaust gas containing SO2 and No so as to form an auxiliary electric field of at least 3rKV/c/rL, which is the threshold value at which the desulfurization and denitrification reaction promotion effect by the electric field appears, and 3 [K■/cTL]
An electron beam is irradiated through the metal foil under the action of the following auxiliary electric field, and the S02, NO is quickly and effectively converted into fine particles by the cooperative action of the electron beam and the auxiliary electric field, and then transferred to the electron beam irradiation chamber. It is electrically attached to the surface of a group of electrodes arranged facing each other with internal insulation, and after being peeled off from the electrode surface and falling into the hopper, it is discharged to the outside from the particulate discharge port, and the clean gas after desulfurization and denitrification is generated. is discharged from the gas outlet to the stack, and includes a gas inlet for introducing exhaust gas containing SO2 and NO, a gas outlet for discharging clean gas after desulfurization and denitrification, and a gas outlet for discharging clean gas after desulfurization and denitration.
2. It has a part of the hopper for dropping the fine particles converted from NO, a particulate discharge port for discharging the fine particles to the outside from the hopper, and a metal foil for introducing the electron beam. It has an irradiation chamber made of a box with an irradiation window, and an electron beam generator for irradiating an electron beam into the irradiation chamber through the irradiation window. It has a group of reaction promoting electrodes disposed facing each other on top of the insulator, and at least 3CKV/crf is provided between the electrode group.
L) It is characterized by having a high voltage power supply for applying a high voltage to form an auxiliary electric field of or above.
この場合本発明の補助電界の作用によって、上述の脱硫
脱硝反応速度が著るしく上昇する結果、それに見合った
分だけ電子ビーム発生装置の設備容量と、その運転電力
費を大きく低減することができ、まったく同一の脱硫脱
硝効率が得られるという著るしい作用効果が達成される
のである。In this case, as a result of the action of the auxiliary electric field of the present invention, the above-mentioned desulfurization and denitrification reaction rate increases significantly, and the installed capacity of the electron beam generator and its operating power cost can be reduced by a commensurate amount. , a remarkable effect is achieved in that exactly the same desulfurization and denitrification efficiency can be obtained.
その上転化微粒子は後置集塵装置がなくても、照射室内
でここに設置された該反応促進用電極上に効率よく捕集
されるという、粒子除去効果が副次的作用効果として達
成されることとなる。As a side effect, the particle removal effect is achieved in that the superconverted fine particles are efficiently collected on the reaction promoting electrode installed in the irradiation chamber even without a post-filtering device. The Rukoto.
以下に本発明による新規の電子ビーム排ガス脱硫脱硝方
法および装置の特徴を実施例ならびに図面によって、よ
り詳細に説明する。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The features of the novel electron beam exhaust gas desulfurization and denitration method and apparatus according to the present invention will be explained in more detail below with reference to examples and drawings.
第１図は本発明の一実施例の縦断面図、第２図はその水
平断面図で、各図における破線Ａ−Ａ，Ｂ−Ｂは当該断
面ならびに視線方向を示す。FIG. 1 is a longitudinal cross-sectional view of an embodiment of the present invention, and FIG. 2 is a horizontal cross-sectional view thereof. Broken lines AA and B-B in each figure indicate the cross-section and the viewing direction.
第３図は電界の値と脱硫脱硝反応速度との関係を示す実
験結果であり、電界の値が３ＣＫＶ／ｃｍ）を超えると
脱硫脱硝反応速度が急激に上昇することがわかる。FIG. 3 shows the experimental results showing the relationship between the electric field value and the desulfurization and denitrification reaction rate, and it can be seen that when the electric field value exceeds 3CKV/cm, the desulfurization and denitrification reaction rate increases rapidly.
第１図および第２図において１は本発明装置の本体をな
す函体で、ガス人口２、ガス出口３、ホッパ一部４、微
粒子排出口５、チタン金属箔６，６′で密閉された照射
窓γ，γ′を有し、その内部空間８が照射室９を構成し
ている。In FIGS. 1 and 2, 1 is a box that forms the main body of the device of the present invention, and is sealed with a gas port 2, a gas outlet 3, a part of the hopper 4, a particulate discharge port 5, and titanium metal foils 6 and 6'. It has irradiation windows γ and γ', and its interior space 8 constitutes an irradiation chamber 9.
１０．１０’は電子ビーム発生装置でそれぞれ照射窓７
，７′の金属箔６，６′を通して照射室９内にガス流と
平行に高エネルギーの電子ビーム１１，１１’を照射す
る。10 and 10' are electron beam generators, each with irradiation window 7.
, 7', high-energy electron beams 11, 11' are irradiated into the irradiation chamber 9 in parallel with the gas flow through the metal foils 6, 6'.
１２，１２’，１２“，・・・は照射室９の内部にガス
流ならびに電子ビーム１１，１１’と平行に等間隔に配
設され、函体と共に接地された接地平板電極群で、その
両端部１２，１２“は本例では函体１の側壁を兼ねてい
る。12, 12', 12", . . . are a group of grounded flat plate electrodes arranged at equal intervals inside the irradiation chamber 9 parallel to the gas flow and the electron beams 11, 11' and grounded together with the box. Both end portions 12, 12'' also serve as side walls of the box 1 in this example.
１３，１３’，・・・は該接地平板電極群１２，１２’
，１２“の中間にこれらと平行に配設された高圧平板電
極群で、横腕１４，１４’，１５，１５’，１６，１６
’，１７，１７’，・・・ならびに鉛直支柱１８，１９
，２０，２１を介して碍管２２，２３，・・・に絶縁支
持されている。13, 13', . . . are the ground plate electrode groups 12, 12'
, 12", and are arranged parallel to the horizontal arms 14, 14', 15, 15', 16, 16.
', 17, 17', ... and vertical supports 18, 19
, 20, 21, and are insulated and supported by insulator tubes 22, 23, . . . .
２４は直流高圧電源でその一つの出力端子は函体１と共
に接地され、他の出力端子２５は導線２６を介して支柱
１８，２０，・・・に接続され、上記高圧平板電極群１
３，１３’，・・・に本例では負の直流高電圧を印加す
る。24 is a DC high voltage power supply, one output terminal of which is grounded together with the box 1, and the other output terminal 25 is connected to the pillars 18, 20, .
3, 13', . . . in this example, a negative DC high voltage is applied.
かくして照射室９の内部には電子ビーム１１，１１’と
平行に正負の平行平板電極群１２，１３，１２′，１３
’，１２“，・・・が存在し、又上述の反応促進用電極
群を構成し、両電極間の電子ビームの照射を直接受ける
照射空間内に上記補助電界たる平等な直流高電界が形成
されている。Thus, inside the irradiation chamber 9, positive and negative parallel plate electrode groups 12, 13, 12', 13 are arranged parallel to the electron beams 11, 11'.
', 12'', . . . are present, and constitute the above-mentioned reaction promoting electrode group, and an equal DC high electric field, which is the above-mentioned auxiliary electric field, is formed in the irradiation space that directly receives the electron beam irradiation between the two electrodes. has been done.
但しその電界値は少くともすでに述べた脱硫脱硝反応の
電界による促進効果のあらわれる閾値たる３〔Ｋ■／Ｃ
ｒｒＬ〕以上の値に保たれ、多くの場合火花放電発生寸
前の高い値になる如く電源２４の出力電圧が定められて
いる。However, the electric field value is at least 3 [K
The output voltage of the power supply 24 is determined so as to be maintained at a value equal to or higher than [rrL] and, in many cases, to a high value on the verge of spark discharge.
いまガス入口２より照射室９内に導入された排ガス中に
含有されるＳＯ２およびＮＯは電子ビーム１１，１１’
の照射効果と電極１２，１３，１２′，１３′，１２“
，・・・間に形成された上記補助電界の協同効果により
迅速かつ有効に固体又は液体の微粒子に転化され、直ち
に該電極表面上に電気的に除去される。SO2 and NO contained in the exhaust gas now introduced into the irradiation chamber 9 from the gas inlet 2 are absorbed by the electron beams 11, 11'.
irradiation effect and electrodes 12, 13, 12', 13', 12''
, . . . due to the cooperative effect of the auxiliary electric field formed between them, they are quickly and effectively converted into solid or liquid fine particles, which are immediately electrically removed onto the electrode surface.
この際例えはボンベ２７からパイプ２８を介して被照射
排ガス中に適当な添加ガス、例えばＮＨ３を少量添加す
ると、脱硫・脱硝率が大巾に向上できるのみならず、転
化微粒子として安定な固体の硫硝安微粒子を生ずる。In this case, for example, if a small amount of an appropriate additive gas, such as NH3, is added to the irradiated exhaust gas from the cylinder 27 through the pipe 28, not only can the desulfurization and denitrification rates be greatly improved, but also the solid solids are stable as converted fine particles. Produces fine particles of ammonium sulfate.
２９，３０は支柱２０，２１を槌打することによって高
圧平板電極群１３，１３’，・・・に機械的衝撃を与え
るための槌打装置、３１は函体１の天井に取りつけられ
た振動器で該天井に上端を固定された接地平板電極群１
２，１２’，１２“，・・・に機械的衝撃を与える。Reference numerals 29 and 30 refer to a hammering device for applying a mechanical shock to the high-voltage flat plate electrode groups 13, 13', . . . by hammering the pillars 20 and 21; Ground plate electrode group 1 whose upper end is fixed to the ceiling with a container
2, 12', 12", . . .
これらの機械的衝撃によって上記各電極群上に堆積した
微粒子層は剥離し、下部ホッパ−４へと落下し、微粒子
排出口５より外部に排出される。Due to these mechanical impacts, the particulate layer deposited on each of the electrode groups is peeled off, falls into the lower hopper 4, and is discharged to the outside from the particulate discharge port 5.
清浄となった脱硫脱硝終了後の排ガスはガス出口よりス
タックへと排出される。The clean exhaust gas after desulfurization and denitrification is discharged from the gas outlet to the stack.
第１図および第２図の実施例は本発明の原理的構成態様
の一つの例に過ぎず、本発明の実施に当っては、目標と
条件に応じてこれと異なる様々の実施形態を自由に採用
することができることは云うまでもない。The embodiments shown in FIGS. 1 and 2 are merely examples of the principle configuration of the present invention, and in carrying out the present invention, various embodiments different from these may be used depending on the goals and conditions. Needless to say, it can be employed in
また照射室９内に配設する反応促進用電極群１２，１３
，１２’，１３’，１２“，１３”，・・・は平行平板
の他、平行円筒、平行金網等任意の形状に構成してもよ
い。In addition, reaction promoting electrode groups 12 and 13 arranged in the irradiation chamber 9
, 12', 13', 12", 13", . . . may be configured in any shape, such as a parallel cylinder, parallel wire mesh, etc., in addition to parallel flat plates.
更にその設置部位は電子ビーム１１，１１’の直接照射
域から遠ざかった位置または外れた位置に選んでも良く
、これによってこの領域に残存するエネルギーレベルの
下った２次電子の脱硫脱硝作用を賦活して脱硫脱硝効率
を向上することができる。Furthermore, the installation location may be selected to be far away from or away from the direct irradiation area of the electron beams 11, 11', thereby activating the desulfurization and denitrification effect of the secondary electrons remaining in this area and having a lower energy level. desulfurization and denitrification efficiency can be improved.
また高圧直流電源２４の代わりに高圧交流電源を用い、
照射室９内の反応促進用電極群間に形成する上記補助電
界として直流電界の代わりに交流電界を使用することも
出来る。Also, a high voltage AC power source is used instead of the high voltage DC power source 24,
As the auxiliary electric field formed between the reaction promoting electrode groups in the irradiation chamber 9, an alternating current electric field can be used instead of the direct current electric field.
この場合には若干反応促進効果が低下するが、電源２４
のコストは大巾に低下できるという経済効果が得られる
。In this case, the reaction promotion effect is slightly reduced, but the power supply 24
An economic effect can be obtained in that the cost can be significantly reduced.
また照射室９の内部において適当な手段がガスを攪拌し
てもよく、これによってガスを一様に電子ビームに照射
される様にして脱硫脱硝効果を更に向上することができ
る。Further, the gas may be stirred by a suitable means inside the irradiation chamber 9, thereby making it possible to uniformly irradiate the gas with the electron beam, thereby further improving the desulfurization and denitration effect.
第１図は本発明の一実施例の縦断図面、第２図はその水
平断面図、第３図は電界の値と脱硫脱硝反応速度との相
関図である。
図において、１・・・・・・函体、２・・・・・・ガス
入口、３・・・・・・ガス出口、４・・・・・・ホッパ
一部、５・・・・・・微粒子排出口、６，６′・・・・
・・金属箔、７，７′・・・・・・照射窓、９・・・・
・・照射室、１０，１０’・・・・・・電子ビーム発生
装置、１１，１１’・・・・・・電子ビーム、１２，１
２’，１２“・・・・・・接地平板電極、１３，１３’
，・・・・・・高圧平板電極、２２，２３・・・・・・
碍管、２４・・・・・・直流高圧電源、２６・・・・・
・導線、２７・・・・・・アンモニアボンベ、２８・・
・・・・パイプ。FIG. 1 is a longitudinal sectional view of an embodiment of the present invention, FIG. 2 is a horizontal sectional view thereof, and FIG. 3 is a correlation diagram between the electric field value and the desulfurization and denitration reaction rate. In the figure, 1...Box, 2...Gas inlet, 3...Gas outlet, 4...Part of hopper, 5...・Particle outlet, 6, 6'...
...Metal foil, 7,7'...Irradiation window, 9...
...Irradiation chamber, 10,10'...Electron beam generator, 11,11'...Electron beam, 12,1
2', 12"... Ground plate electrode, 13, 13'
,...High voltage flat plate electrode, 22,23...
Insulator pipe, 24...DC high voltage power supply, 26...
・Conductor wire, 27...Ammonia cylinder, 28...
····pipe.
Claims (1)
電界による脱硫脱硝反応促進効果のあらわれる閾値たる
３ＣＫＶ／ｃｒ７Ｌ）以上の補助電界を形成する如く高
電王を印加し、該３〔ＫＶ／ｃｍ）以上の補助電界の作
用下に電子ビームを金属箔を通して照射し、該電子ビー
ムと該補助電界の協同作用によって該Ｓ０２，ＮＯを迅
速有効に微粒子に転化の上、これを電子ビーム照射室の
内部に絶縁の上対向配置した電極群の表面上に電気的に
附着せしめ、これを電極表面より剥離してホツパー内に
落下せしめたのち微粒子排出口より外部に排出し、脱硫
脱硝後の清浄ガスをガス出口よりスタックへ排出するこ
とを特徴とする電子ビーム排ガス脱硫脱蛸方法。 ２ Ｓ０２およびＮＯを含有する排ガスを導入するため
のガス入口と、脱硫脱硝後の清浄ガスを排出するための
ガス出口と、ＳＯ２ＮＯより転化された微粒子を落下送
入ずるだめのホッパ一部と、該ホツパ一部より該微粒子
を外部に排出するための微粒子排出口と、電子ビームを
導入するための金属箔を持った照射窓とを備えた所の函
体より成る照射室を有し、かつ該照射窓を通して該照射
室内に電子ビームを照財するための電子ビーム発生装置
を有し、かつ該照射室内に互に絶縁の上対向配置せる反
応促進用電極群を有し、かつ該電極群の間に少くとも３
〔Ｋ■／ｃｒｒＬ〕以上の補助電界を形成する如く高電
圧を印加するための高圧電源を有することを特徴とする
電子ビーム排ガス脱硫脱硝装置。[Scope of Claims] 1. A high electric field is applied to the exhaust gas containing SO2 and NO so as to form an auxiliary electric field of at least 3CKV/cr7L) which is the threshold value at which the desulfurization and denitration reaction promotion effect by the electric field appears, An electron beam is irradiated through the metal foil under the action of an auxiliary electric field of [KV/cm] or more, and the S02, NO is quickly and effectively converted into fine particles by the cooperative action of the electron beam and the auxiliary electric field, and then converted into electrons. The particles are electrically attached to the surface of a group of electrodes arranged facing each other on an insulated surface inside the beam irradiation chamber, and after being peeled off from the electrode surface and falling into the hopper, they are discharged from the particulate outlet to the outside for desulfurization and denitrification. An electron beam exhaust gas desulfurization method characterized by discharging the cleaned gas from a gas outlet into a stack. 2. A gas inlet for introducing exhaust gas containing S02 and NO, a gas outlet for discharging clean gas after desulfurization and denitrification, and a part of a hopper into which fine particles converted from SO2NO are dropped, It has an irradiation chamber made of a box equipped with a particulate discharge port for discharging the particulates to the outside from a part of the hopper, and an irradiation window having a metal foil for introducing the electron beam, and an electron beam generator for directing an electron beam into the irradiation chamber through the irradiation window, and a reaction promoting electrode group disposed insulated and facing each other in the irradiation chamber, and the electrode group at least 3 between
An electron beam exhaust gas desulfurization and denitrification device characterized by having a high voltage power supply for applying a high voltage to form an auxiliary electric field of [K■/crrL] or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP53006058A JPS5814810B2 (en) | 1978-01-23 | 1978-01-23 | Electron beam exhaust gas desulfurization and denitrification method and equipment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP53006058A JPS5814810B2 (en) | 1978-01-23 | 1978-01-23 | Electron beam exhaust gas desulfurization and denitrification method and equipment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5499272A JPS5499272A (en) | 1979-08-04 |
| JPS5814810B2 true JPS5814810B2 (en) | 1983-03-22 |
Family
ID=11627990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP53006058A Expired JPS5814810B2 (en) | 1978-01-23 | 1978-01-23 | Electron beam exhaust gas desulfurization and denitrification method and equipment |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5814810B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07155255A (en) * | 1993-12-06 | 1995-06-20 | Rinnai Corp | Rice cooker |
-
1978
- 1978-01-23 JP JP53006058A patent/JPS5814810B2/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07155255A (en) * | 1993-12-06 | 1995-06-20 | Rinnai Corp | Rice cooker |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5499272A (en) | 1979-08-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4695358A (en) | Method of removing SO2, NOX and particles from gas mixtures using streamer corona | |
| US3653185A (en) | Airborne contaminant removal by electro-photoionization | |
| CA1056901A (en) | Method and apparatus for separating dispersed matter from a fluid medium | |
| JPH10174899A (en) | Dedusting device | |
| JP2008023412A (en) | Electric dust collector | |
| CN109127136B (en) | Ultra-high-efficiency low-temperature electric dust removal device based on multi-field agglomeration | |
| US3633337A (en) | Gas-handling method and apparatus | |
| US5380355A (en) | Airstream decontamination unit | |
| EP0713562B1 (en) | Electronic purification of exhaust gases | |
| CN107029644A (en) | A kind of mesh shape surface discharge plasma produces the device of oxygen active substance | |
| JP3115326B2 (en) | Method and apparatus for treating gas carrier particles and use of the apparatus | |
| CN108114814A (en) | A kind of electrostatic precipitator | |
| US2682313A (en) | Alternating current ion-filter for electrical precipitators | |
| EP3943195A1 (en) | Low specific resistance substance treatment method and treatment device | |
| JPS5814810B2 (en) | Electron beam exhaust gas desulfurization and denitrification method and equipment | |
| CN110369133A (en) | A kind of acoustic-electric combined dust-eliminating device for belt-conveying | |
| CN111760450A (en) | Line plate type dielectric barrier discharge cooperative catalysis denitration device | |
| RU2144433C1 (en) | Two-zone electric filter | |
| KR101377977B1 (en) | Electrical precipitator | |
| JP2001038138A (en) | Method and device for treating material | |
| US3568404A (en) | Low pressure electrostatic precipitator | |
| RU2095150C1 (en) | Method of cleaning gases | |
| RU2192927C2 (en) | Double-zone electric filter | |
| SU977842A1 (en) | Method and apparatus for neutralizing i.c. engine waste gases | |
| JPH08168696A (en) | Small-sized high velocity electric dust collector by high current density operation |