JPS5781466A - Polymer of novel nitrogen-containing monoterpene derivative - Google Patents

Polymer of novel nitrogen-containing monoterpene derivative

Info

Publication number
JPS5781466A
JPS5781466A JP14537681A JP14537681A JPS5781466A JP S5781466 A JPS5781466 A JP S5781466A JP 14537681 A JP14537681 A JP 14537681A JP 14537681 A JP14537681 A JP 14537681A JP S5781466 A JPS5781466 A JP S5781466A
Authority
JP
Japan
Prior art keywords
formula
compound
nitrogen
methyl
aglycon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP14537681A
Other languages
Japanese (ja)
Other versions
JPS6312499B2 (en
Inventor
Ryosuke Toyama
Hiroyuki Inoue
Tetsuo Shinguu
Yoshio Takeda
Takeshi Ikumoto
Hidetoshi Okuyama
Osamu Yamamoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taito Co Ltd
Original Assignee
Taito Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taito Co Ltd filed Critical Taito Co Ltd
Priority to JP14537681A priority Critical patent/JPS5781466A/en
Publication of JPS5781466A publication Critical patent/JPS5781466A/en
Publication of JPS6312499B2 publication Critical patent/JPS6312499B2/ja
Granted legal-status Critical Current

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  • Other In-Based Heterocyclic Compounds (AREA)

Abstract

NEW MATERIAL:Dimer and trimer of a novel nitrogen-containing monoterpene derivatives of formula I W formula IV (R1 is methyl ethyl, CH2COOCH3, phenyl; R2 is COOCH3; R3 is H, methyl; R4 is H, methyl, hydroxymethyl).
EXAMPLE: The compound of formula VI.
USE: Synthetic intermediate of dyes, pigments of medicines, analysis of pharmaceutical activity of iridoid compounds, blue protein and other uses.
PREPARATION: The saccharide part is removed from an iridoid by hydrolysis to obtain the very reactive aglycon and a compound containing a primary amino group is made to act on the aglycon to replace the oxygen atom readily with a nitrogen atom of a primary nitrogen group to produce a nitrogen-containing six- membered ring. For example, a compound of formula III is heated under an oxygen-free condition to give the compound of formula I.
COPYRIGHT: (C)1982,JPO&Japio
JP14537681A 1981-09-14 1981-09-14 Polymer of novel nitrogen-containing monoterpene derivative Granted JPS5781466A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14537681A JPS5781466A (en) 1981-09-14 1981-09-14 Polymer of novel nitrogen-containing monoterpene derivative

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14537681A JPS5781466A (en) 1981-09-14 1981-09-14 Polymer of novel nitrogen-containing monoterpene derivative

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP4941877A Division JPS53134824A (en) 1977-04-28 1977-04-28 Novel nitrogenncontaining monoterpene derivative

Publications (2)

Publication Number Publication Date
JPS5781466A true JPS5781466A (en) 1982-05-21
JPS6312499B2 JPS6312499B2 (en) 1988-03-19

Family

ID=15383795

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14537681A Granted JPS5781466A (en) 1981-09-14 1981-09-14 Polymer of novel nitrogen-containing monoterpene derivative

Country Status (1)

Country Link
JP (1) JPS5781466A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4878921A (en) * 1986-06-21 1989-11-07 Suntory Limited Natural blue dye composition and colorant using the same: prepared by reacting taurine and genipin
WO1992006061A1 (en) * 1990-10-09 1992-04-16 Tsumura & Co. Iridoide derivative and its use as medicine
KR100450880B1 (en) * 1995-10-30 2006-01-12 주식회사 중외제약 New Iridoid Derivatives to Suppress Replication of Hepatitis B Virus and Methods for Making the Same
WO2014001910A1 (en) * 2012-06-25 2014-01-03 Ecoflora S.A.S. Colorant compound derived from genipa americana genipin and glycine
US9376569B2 (en) 2013-05-22 2016-06-28 Ecoflora S.A.S. Colorant compounds derived from genipin or genipin containing materials
WO2017156744A1 (en) * 2016-03-17 2017-09-21 Dsm Ip Assets B.V. New gardenia blue pigment, preparation and use thereof
CN110156685A (en) * 2019-06-20 2019-08-23 江西省科学院应用化学研究所 The cyclopenta pyridine and its synthetic method of fragrance and application

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4878921A (en) * 1986-06-21 1989-11-07 Suntory Limited Natural blue dye composition and colorant using the same: prepared by reacting taurine and genipin
WO1992006061A1 (en) * 1990-10-09 1992-04-16 Tsumura & Co. Iridoide derivative and its use as medicine
KR100450880B1 (en) * 1995-10-30 2006-01-12 주식회사 중외제약 New Iridoid Derivatives to Suppress Replication of Hepatitis B Virus and Methods for Making the Same
WO2014001910A1 (en) * 2012-06-25 2014-01-03 Ecoflora S.A.S. Colorant compound derived from genipa americana genipin and glycine
CN104685004A (en) * 2012-06-25 2015-06-03 伊蔻夫劳拉股份公司 Colorant compound derived from genipa americana genipin and glycine
JP2015528028A (en) * 2012-06-25 2015-09-24 エコフローラ エス．エー．エス・Ｅｃｏｆｌｏｒａ Ｓ．Ａ．Ｓ． Colored compounds derived from Genipaamericana genipin and glycine
US9376569B2 (en) 2013-05-22 2016-06-28 Ecoflora S.A.S. Colorant compounds derived from genipin or genipin containing materials
JP2016527331A (en) * 2013-05-22 2016-09-08 エコフローラ エス．エー．エス．Ｅｃｏｆｌｏｒａ Ｓ．Ａ．Ｓ． Colorant compounds derived from genipin or genipin-containing materials
US9890286B2 (en) 2013-05-22 2018-02-13 Ecoflora S.A.S. Colorant compounds derived from genipin or genipin containing materials
US10266698B2 (en) 2013-05-22 2019-04-23 Ecoflora S.A.S. Colorant compounds derived from genipin or genipin containing materials
WO2017156744A1 (en) * 2016-03-17 2017-09-21 Dsm Ip Assets B.V. New gardenia blue pigment, preparation and use thereof
CN110156685A (en) * 2019-06-20 2019-08-23 江西省科学院应用化学研究所 The cyclopenta pyridine and its synthetic method of fragrance and application
CN110156685B (en) * 2019-06-20 2020-07-17 江西省科学院应用化学研究所 Aromatic cyclopentenopyridine, and synthesis method and application thereof

Also Published As

Publication number Publication date
JPS6312499B2 (en) 1988-03-19

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