JPS5635793A - Electrolytic formation of verdigris on surface of copper or copper alloy - Google Patents

Electrolytic formation of verdigris on surface of copper or copper alloy

Info

Publication number
JPS5635793A
JPS5635793A JP11217179A JP11217179A JPS5635793A JP S5635793 A JPS5635793 A JP S5635793A JP 11217179 A JP11217179 A JP 11217179A JP 11217179 A JP11217179 A JP 11217179A JP S5635793 A JPS5635793 A JP S5635793A
Authority
JP
Japan
Prior art keywords
copper
verdigris
copper alloy
electrolyte
concn
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11217179A
Other languages
Japanese (ja)
Inventor
Tsutomu Takahashi
Kazuo Toda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Metal Corp
Original Assignee
Mitsubishi Metal Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Metal Corp filed Critical Mitsubishi Metal Corp
Priority to JP11217179A priority Critical patent/JPS5635793A/en
Publication of JPS5635793A publication Critical patent/JPS5635793A/en
Pending legal-status Critical Current

Links

Landscapes

  • Electrochemical Coating By Surface Reaction (AREA)

Abstract

PURPOSE: To form beautiful verdigris artificially, by contacting the surface of a cathode with the surface of copper or copper alloy, which serves as an anode, with interposition of holding material of electrolyte for generating verdigris.
CONSTITUTION: Beautiful verdigris having good adhesive property is formed on the surface of copper or copper alloy in a shorttime. The surface of a cathode is contacted with the surface of the copper or copper alloy with interposition of a holdig material which is impregnated with electrolyte for generating verdigris, and electrolysis is conducted with the copper or copper alloy used as an anode. For the electrolyte is used sodium carbonate about 10W80g/l in concn., sodium hydrogencarbonate about 10W120g/l in concn., or ammonium sulfate about 5W40g/l in concn. When carbonate is used, about 9W11pH is preferable. Cotton cloth, or sponge is used as the holding material. The electrolysis is carried out at 10W45°C electrolyte temp., 1W100A/dm2 current density, 0.5W5min electrolysis time. The verdigris formed by this method turns clearer bluish-green when heated to about 100W200°C.
COPYRIGHT: (C)1981,JPO&Japio
JP11217179A 1979-08-31 1979-08-31 Electrolytic formation of verdigris on surface of copper or copper alloy Pending JPS5635793A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11217179A JPS5635793A (en) 1979-08-31 1979-08-31 Electrolytic formation of verdigris on surface of copper or copper alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11217179A JPS5635793A (en) 1979-08-31 1979-08-31 Electrolytic formation of verdigris on surface of copper or copper alloy

Publications (1)

Publication Number Publication Date
JPS5635793A true JPS5635793A (en) 1981-04-08

Family

ID=14580016

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11217179A Pending JPS5635793A (en) 1979-08-31 1979-08-31 Electrolytic formation of verdigris on surface of copper or copper alloy

Country Status (1)

Country Link
JP (1) JPS5635793A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5967393A (en) * 1982-10-12 1984-04-17 Furukawa Electric Co Ltd:The Method for coloring copper
US7948158B2 (en) 2007-07-17 2011-05-24 Denso Corporation Plasma ignition system with recess porton in the center electrode
US8267075B2 (en) 2007-07-24 2012-09-18 Toyota Jidosha Kabushiki Kaisha Ignition device for internal combustion engine

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5967393A (en) * 1982-10-12 1984-04-17 Furukawa Electric Co Ltd:The Method for coloring copper
US7948158B2 (en) 2007-07-17 2011-05-24 Denso Corporation Plasma ignition system with recess porton in the center electrode
US8267075B2 (en) 2007-07-24 2012-09-18 Toyota Jidosha Kabushiki Kaisha Ignition device for internal combustion engine

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