JPS54106436A - Preparation of ethylbenzene - Google Patents
Preparation of ethylbenzeneInfo
- Publication number
- JPS54106436A JPS54106436A JP1364478A JP1364478A JPS54106436A JP S54106436 A JPS54106436 A JP S54106436A JP 1364478 A JP1364478 A JP 1364478A JP 1364478 A JP1364478 A JP 1364478A JP S54106436 A JPS54106436 A JP S54106436A
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- catalyst
- metal
- ethylbenzene
- zeolite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To prepare ethylbenzene useful as a raw meterial of styrene monomer, in high conversion, by the low-temperature, liquid-phase reaction of benzene with ethylene in the presence of hydrogen and a long-life catalyst comprising a metal supported by zeolite.
CONSTITUTION: Ethylbenzene is prepared by the liquid phase alkylation reaction of benzene (1 mole) with ethylene in the presence of hydrogen (1W0.01 mole) using a catalyst comprising a metal (such as Cu, Ag, Au, etc.) supported by zeolite. The catalyst may contain 0.1W5wt% of F, or it may be prepared by supporting the metal on a solid acid by ion exchange process. Polyalkylbenzene produced as by-products, are recycled to the reaction zone to conduct the alkylation reaction and the transalkylation reaction.
EFFECT: Improved catalytic activity; long catalytic life; and suppressed side reactions.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1364478A JPS54106436A (en) | 1978-02-10 | 1978-02-10 | Preparation of ethylbenzene |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1364478A JPS54106436A (en) | 1978-02-10 | 1978-02-10 | Preparation of ethylbenzene |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS54106436A true JPS54106436A (en) | 1979-08-21 |
Family
ID=11838932
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1364478A Pending JPS54106436A (en) | 1978-02-10 | 1978-02-10 | Preparation of ethylbenzene |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS54106436A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58210030A (en) * | 1982-05-21 | 1983-12-07 | コスデン・テクノロジ−・インコ−ポレ−テツド | Manufacture of ethyl benzene |
JPS60174730A (en) * | 1984-02-22 | 1985-09-09 | Res Assoc Util Of Light Oil | Preparation of p-dialkylbenzene |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4875490A (en) * | 1971-11-10 | 1973-10-11 |
-
1978
- 1978-02-10 JP JP1364478A patent/JPS54106436A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4875490A (en) * | 1971-11-10 | 1973-10-11 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58210030A (en) * | 1982-05-21 | 1983-12-07 | コスデン・テクノロジ−・インコ−ポレ−テツド | Manufacture of ethyl benzene |
JPH0416447B2 (en) * | 1982-05-21 | 1992-03-24 | Cosden Technology | |
JPS60174730A (en) * | 1984-02-22 | 1985-09-09 | Res Assoc Util Of Light Oil | Preparation of p-dialkylbenzene |
JPH0513933B2 (en) * | 1984-02-22 | 1993-02-23 | Keishitsu Ryubun Shinyoto Kaihatsu Gijutsu Kenkyu Kumiai |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Cao et al. | Alkylation of benzene with dodecene. The activity and selectivity of zeolite type catalysts as a function of the porous structure | |
Chen et al. | Niobic acid as an efficient catalyst for vapor phase esterification of ethyl alcohol with acetic acid | |
ES471957A1 (en) | A process for isomerizing xylenes. | |
CA2264700A1 (en) | Alkylation process using zeolite beta | |
IN153717B (en) | ||
Pai et al. | Friedel-Crafts Benzylation of Arenes Using FeCl3 Impregnated Montmorillonite K10. | |
Smith et al. | Regioselective methanesulfonylation of toluene catalysed by cation-exchanged zeolite β | |
CA2008693A1 (en) | Process for the manufacture of 1,4-bis(4-phenoxybenzoyl) benzene with certain metal-containing catalysts | |
JPS54106436A (en) | Preparation of ethylbenzene | |
TAKEUCHI et al. | Isomer selectivity in isopropylation of biphenyl over solid acid catalysts | |
Tamagaki et al. | Hydroxylation of benzene by hydrogen peroxide catalyzed by an Fe3+-catechol catalyst supported on silica gel. | |
Ono et al. | LOW TEMPERATURE CONVERSION OF PENTANE WITH ALUMINUM CHLORIDE–METAL SULFATE MIXTURES | |
US3248443A (en) | Process for alkylating aromatic hydrocarbons | |
JPH03501975A (en) | Improved polyalkylbenzene transalkylation method | |
Ono et al. | Highly selective isomerization of pentane with AlBr3-Metal Sulfate Mixtures | |
EP0085718A4 (en) | Selectively calcined dehydrogenation catalyst. | |
CS277105B6 (en) | Process for preparing nitrobenzenes | |
KR930701368A (en) | Alkyl group transfer reaction in the presence of catalyst slurry | |
JPS5363318A (en) | Preparation of ethyl benzene | |
Hino et al. | t-BUTYLATION AND ISOPROPYLATION OF TOLUENE WITH t-BUTYL AND ISOPROPYL CHLORIDES CATALYZED BY CALCINED IRON SULFATE TREATED WITH HYDROGEN CHLORIDE | |
TAKEUCHI et al. | Isopropylation of p-terphenyl over solid acid catalysts | |
SU819094A1 (en) | Method of producing alkylaromatic hydrocarbon hydroperoxides | |
JPS63162632A (en) | Production of ethylbiphenyls | |
EP0165215B1 (en) | Method for the production of benzene and cumene | |
OFSTAD | Superacids as catalysts for selected hydrocarbon convers |