JPH1187264A - Semiconductor device and manufacture thereof - Google Patents

Semiconductor device and manufacture thereof

Info

Publication number
JPH1187264A
JPH1187264A JP24684497A JP24684497A JPH1187264A JP H1187264 A JPH1187264 A JP H1187264A JP 24684497 A JP24684497 A JP 24684497A JP 24684497 A JP24684497 A JP 24684497A JP H1187264 A JPH1187264 A JP H1187264A
Authority
JP
Japan
Prior art keywords
film
tin
plug
via hole
semiconductor device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP24684497A
Other languages
Japanese (ja)
Inventor
Kenji Tani
憲治 谷
Yasutaka Ishibashi
保孝 石橋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Microsystems Co Ltd
Asahi Kasei Microdevices Corp
Original Assignee
Asahi Kasei Microsystems Co Ltd
Asahi Kasei Microdevices Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Microsystems Co Ltd, Asahi Kasei Microdevices Corp filed Critical Asahi Kasei Microsystems Co Ltd
Priority to JP24684497A priority Critical patent/JPH1187264A/en
Publication of JPH1187264A publication Critical patent/JPH1187264A/en
Withdrawn legal-status Critical Current

Links

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  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
  • Electrodes Of Semiconductors (AREA)

Abstract

PROBLEM TO BE SOLVED: To eliminate the generation of f peelings in the base TiN film of a W plug by a method wherein the plug is formed of a W film embedded in a via hole with a bottom and wall surface, which are successively covered with Ti, TiN, Al and TiN films, in the via hole, provided 13 an insulating film. SOLUTION: An SiO2 film 2, which is an insulating film, is provided on the surface of a semiconductor substrate 1, which is formed with an element structure, such as a transistor, and a via hole 3 is formed at a prescribed position on the insulating film. Then, after a Ti film 4 and a TiN film 5 are successively formed by sputtering, an Al film 11 with the square part formed into a gentle form is formed on the film 5. After that, a TiN film 12 is formed on the film 11 by sputtering for increasing an adhesion of the film 11 to a W film, and after that, the interior of the hole 3 is filled with the W film formed using a WF6 material as its raw material by a CVD method and at the same time, the W film is formed on the film 12. Moreover, the W film other than the W film in the via hole part is removed by etching to form a W plug 6 and thereafter, the plug is formed into the form of a prescribed wiring.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は半導体装置に関し、
特に層間配線のためのタングステン(W)プラグを有す
る半導体装置とその製造方法に関する。
The present invention relates to a semiconductor device,
In particular, the present invention relates to a semiconductor device having a tungsten (W) plug for interlayer wiring and a method of manufacturing the same.

【0002】[0002]

【従来の技術】集積回路などの半導体装置の層間配線の
ためにプラグが用いられる。図1にこれまで一般に用い
られている層間配線構造を示す。半導体基板または下層
配線1の上に、例えばSiO2 などの絶縁膜2を形成
し、絶縁膜2の所望の位置には層間配線を形成するため
のビアホール3が設けられている。ビアホールの内面お
よび絶縁膜の表面を覆って、Ti膜4およびTiN膜5
をスパッタリングによって成膜し、CVD法によってビ
アホールを埋め込んでWプラグ6を形成する。Ti膜4
は絶縁膜および下地の半導体または下層配線との密着性
を高めるため、TiN膜4はその上に形成されるWとの
密着性を高めるために用いられる。さらに、Wプラグ6
およびTiN膜5の上にAl配線7を施し、その上にT
iN保護膜8を形成する。
2. Description of the Related Art Plugs are used for interlayer wiring of semiconductor devices such as integrated circuits. FIG. 1 shows an interlayer wiring structure generally used so far. An insulating film 2 of, for example, SiO 2 is formed on the semiconductor substrate or the lower wiring 1, and a via hole 3 for forming an interlayer wiring is provided at a desired position of the insulating film 2. The Ti film 4 and the TiN film 5 cover the inner surface of the via hole and the surface of the insulating film.
Is formed by sputtering, and via holes are buried by CVD to form W plugs 6. Ti film 4
The TiN film 4 is used to increase the adhesion to the insulating film and the underlying semiconductor or the lower wiring, and the TiN film 4 is used to increase the adhesion to W formed thereon. Furthermore, W plug 6
Al wiring 7 is provided on the TiN film 5 and TiN film 5, and T
An iN protective film 8 is formed.

【0003】[0003]

【発明が解決しようとする課題】上述した従来のプラグ
形成法には次のような問題がある。図2および図3にそ
の問題を説明するための模式図を示す。Ti膜4は一般
的にはスパッタリングで形成されその厚さは300Å程
度であり、絶縁膜との密着性が良く、絶縁膜の角部を元
の形状を保ったままでよく被覆する。しかし、スパッタ
リングによるTiN膜5は平均的には1000Å程度の
厚さであるが、図2に示すように、ビアホールの底面の
角部では薄くなりやすく、ビアホール上部の角部では厚
くなりやすい。そのために、TiN膜5の特に上部の角
部にはビアホール下部へ向かう応力と絶縁膜の表面方向
に向かう応力とが働き、その結果、TiN膜5のビアホ
ール上部の角部に位置する部分は多孔質になる。WF6
を原料ガスとしてCVD法によってビアホール内をWで
埋め込んでプラグを形成するとき、この多孔質のTiN
はWF6 のアタッキングを受ける。すなわち、TiN膜
5の上部の角部は多孔質のためにWF6 ガスが浸透し
て、下層のTi膜4と反応し、その結果、次式に示すよ
うにTiF4が生成する。
The above-mentioned conventional plug forming method has the following problems. 2 and 3 are schematic diagrams for explaining the problem. The Ti film 4 is generally formed by sputtering, has a thickness of about 300 °, has good adhesion to the insulating film, and well covers the corners of the insulating film while maintaining the original shape. However, the TiN film 5 formed by sputtering has an average thickness of about 1000 °, but tends to be thinner at the bottom corner of the via hole and thicker at the upper corner of the via hole as shown in FIG. Therefore, a stress directed toward the lower portion of the via hole and a stress directed toward the surface of the insulating film act on the upper corner portion of the TiN film 5 in particular. Be quality. WF 6
When the plug is formed by filling the via hole with W by the CVD method using the TiN as a source gas, the porous TiN
Gets attacked by WF 6 . That is, the upper corner portion of the TiN film 5 is porous, so that the WF 6 gas permeates and reacts with the lower Ti film 4, and as a result, TiF4 is generated as shown in the following equation.

【0004】[0004]

【化1】 2WF6 +3Ti→3TiF4 +2W (1) TiNとTiF4 は密着性が良くないので、図3に示す
ように、ビアホールの上部角部においてTiN膜5の剥
離が生じる。従って、Wプラグの形成、Al配線層の形
成その他の工程に障害が生じ、良好な層間配線を施すこ
とが困難になる。
Embedded image 2WF 6 + 3Ti → 3TiF 4 + 2W (1) Since the adhesion between TiN and TiF 4 is not good, peeling of the TiN film 5 occurs at the upper corner of the via hole as shown in FIG. Therefore, an obstacle occurs in the formation of the W plug, the formation of the Al wiring layer, and other steps, and it becomes difficult to provide a good interlayer wiring.

【0005】この問題を解決するために、従来はTiN
膜を厚く成膜したり、あるいはTiN膜中の未反応のT
iを再窒化させて、WF6 との反応を防いだりしていた
が、充分な効果を上げることができなかった。
In order to solve this problem, conventionally, TiN
Thick film is formed, or unreacted T in TiN film
Although i was renitrided to prevent the reaction with WF 6 , a sufficient effect could not be obtained.

【0006】本発明は、このような問題を解決し、Wプ
ラグを含む良好な層間配線構造を有する半導体装置およ
びそのための製造方法を提供することを目的とする。
An object of the present invention is to provide a semiconductor device having an excellent interlayer wiring structure including a W plug and a manufacturing method therefor, which solves such a problem.

【0007】[0007]

【課題を解決するための手段】上記目的を達成するため
に、本発明による半導体装置は、絶縁膜に設けられたビ
アホール内にプラグが形成されている半導体装置におい
て、前記プラグが、底面および壁面がTi、TiN、A
lおよびTiNによって順次覆われたビアホールを埋め
込んだWからなることを特徴とする。
In order to achieve the above object, a semiconductor device according to the present invention has a structure in which a plug is formed in a via hole provided in an insulating film. Is Ti, TiN, A
It is characterized by comprising W in which via holes sequentially covered with 1 and TiN are buried.

【0008】本発明による半導体装置の製造方法は、絶
縁膜に設けられたビアホール内にプラグを形成する工程
を有する半導体装置の製造方法において、前記ビアホー
ルの底面および壁面にTi、TiN、AlおよびTiN
を順次成膜し、さらに前記ビアホールを埋め込んでWを
成膜してプラグを形成する工程を有することを特徴とす
る。
According to a method of manufacturing a semiconductor device according to the present invention, there is provided a method of manufacturing a semiconductor device having a step of forming a plug in a via hole provided in an insulating film.
Are sequentially formed, and the plug is formed by forming W by filling the via hole.

【0009】[0009]

【発明の実施の形態】本発明においては、ビアホール内
にWプラグを形成する際に、まず、Ti膜およびTiN
膜を形成し、さらにAl膜およびTiN膜を形成した
後、Wプラグを形成する。形成されたAl膜はビアホー
ルの上部の角部の形状を緩やかにするので、その上に形
成されたTiN膜の角部には応力がかかり難く、そのた
めにTiN膜は多孔質にはならない。その結果、WF6
ガスを用いたCVD法によってWプラグを形成するとき
にTiN膜がWF6 ガスによってアタッキングを受けて
剥離することがないので、良好な層間配線を実現するこ
とができる。
DESCRIPTION OF THE PREFERRED EMBODIMENTS In the present invention, when forming a W plug in a via hole, first, a Ti film and a TiN
After forming a film and further forming an Al film and a TiN film, a W plug is formed. Since the formed Al film moderates the shape of the upper corner of the via hole, stress is less likely to be applied to the corner of the TiN film formed thereon, so that the TiN film does not become porous. As a result, WF 6
When the W plug is formed by the CVD method using gas, the TiN film is not attacked by the WF 6 gas and does not peel off, so that good interlayer wiring can be realized.

【0010】[0010]

【実施例】図4を参照して本発明の実施例を説明する。
トランジスタ、ダイオードなどの素子構造が形成されて
いる半導体基板1の表面に、絶縁膜として厚さ1.0μ
mのSiO2 膜2を形成した。絶縁膜2の所定の位置に
一辺が0.6μmのビアホール3を形成した。次いで、
スパッタリングによって、厚さ300ÅのTi膜4、厚
さ1000ÅのTiN膜5を順次形成した。さらに、T
iN膜5の上に平均厚さ4000ÅのAl膜11を形成
した。Al膜11の形状は図4に示すように、角部にお
いて緩やかであった。ついで、Wとの密着性を高めるた
めに、Al膜11の上にスパッタリングによって厚さ3
00ÅのTiN膜12を成膜した。TiN膜12はAl
膜11の表面形状を忠実に再現した。次にWF6 を原料
ガスとして、CVD法によってビアホール内をWで埋め
込むとともに、TiN膜12上にもWを成膜した。次に
ビアホール部分以外のWをエッチング除去してWプラグ
6を作成した。最後に所定の配線形状にエッチングして
層間配線構造を作成した。TiN膜12には剥離を生じ
ることなく、良好な層間配線が得られた。
An embodiment of the present invention will be described with reference to FIG.
A 1.0 μm thick insulating film is formed on the surface of the semiconductor substrate 1 on which element structures such as transistors and diodes are formed.
m of SiO 2 film 2 was formed. Via holes 3 each having a side of 0.6 μm were formed at predetermined positions of the insulating film 2. Then
A 300 .mu.m thick Ti film 4 and a 1000 .mu.m thick TiN film 5 were sequentially formed by sputtering. Furthermore, T
An Al film 11 having an average thickness of 4000 ° was formed on the iN film 5. As shown in FIG. 4, the shape of the Al film 11 was gentle at the corners. Then, in order to enhance the adhesion to W, a thickness of 3 is formed on the Al film 11 by sputtering.
A TiN film 12 of 00 ° was formed. TiN film 12 is made of Al
The surface shape of the film 11 was faithfully reproduced. Next, using WF 6 as a source gas, the via holes were filled with W by CVD, and W was formed on the TiN film 12. Next, W other than the via hole was removed by etching to form a W plug 6. Finally, etching was performed into a predetermined wiring shape to form an interlayer wiring structure. A good interlayer wiring was obtained on the TiN film 12 without peeling.

【0011】下層配線、例えばAl配線と上層配線との
層間配線をWプラグを用いて行う場合も、同様の工程で
良好な層間配線構造を得ることができる。
When a lower wiring, for example, an interlayer wiring between an Al wiring and an upper wiring is formed by using a W plug, a good interlayer wiring structure can be obtained by the same process.

【0012】[0012]

【発明の効果】以上説明したように、本発明によれば、
Wプラグの下地のTiN膜に剥離を生じることがない。
従って、良好なWプラグおよび良好な層間配線構造を有
する半導体装置を実現することができる。
As described above, according to the present invention,
There is no separation of the TiN film underlying the W plug.
Therefore, a semiconductor device having a good W plug and a good interlayer wiring structure can be realized.

【図面の簡単な説明】[Brief description of the drawings]

【図1】従来の層間配線構造を示す断面図である。FIG. 1 is a cross-sectional view showing a conventional interlayer wiring structure.

【図2】従来の問題を説明するための模式図である。FIG. 2 is a schematic diagram for explaining a conventional problem.

【図3】従来の問題を説明するための模式図である。FIG. 3 is a schematic diagram for explaining a conventional problem.

【図4】本発明の層間配線構造を示す断面図である。FIG. 4 is a sectional view showing an interlayer wiring structure of the present invention.

【符号の説明】[Explanation of symbols]

1 半導体基板または下層配線 2 絶縁膜 3 ビアホール 4 Ti膜 5 TiN膜 6 Wプラグ 7 Al配線 8 TiN保護膜 11 Al膜 12 TiN膜 Reference Signs List 1 semiconductor substrate or lower wiring 2 insulating film 3 via hole 4 Ti film 5 TiN film 6 W plug 7 Al wiring 8 TiN protective film 11 Al film 12 TiN film

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 絶縁膜に設けられたビアホール内にプラ
グが形成されている半導体装置において、前記プラグ
が、底面および壁面がTi、TiN、AlおよびTiN
によって順次覆われたビアホールを埋め込んだWからな
ることを特徴とする半導体装置。
1. A semiconductor device in which a plug is formed in a via hole provided in an insulating film, wherein the plug has a bottom surface and a wall surface formed of Ti, TiN, Al and TiN.
A semiconductor device comprising W in which via holes sequentially covered by W are buried.
【請求項2】 絶縁膜に設けられたビアホール内にプラ
グを形成する工程を有する半導体装置の製造方法におい
て、前記ビアホールの底面および壁面にTi、TiN、
AlおよびTiNを順次成膜し、さらに前記ビアホール
を埋め込んでWを成膜してプラグを形成する工程を有す
ることを特徴とする半導体装置の製造方法。
2. A method of manufacturing a semiconductor device, comprising the step of forming a plug in a via hole provided in an insulating film, wherein Ti, TiN,
A method of manufacturing a semiconductor device, comprising the steps of sequentially forming Al and TiN, forming a W by filling the via hole, and forming a plug.
JP24684497A 1997-09-11 1997-09-11 Semiconductor device and manufacture thereof Withdrawn JPH1187264A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24684497A JPH1187264A (en) 1997-09-11 1997-09-11 Semiconductor device and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24684497A JPH1187264A (en) 1997-09-11 1997-09-11 Semiconductor device and manufacture thereof

Publications (1)

Publication Number Publication Date
JPH1187264A true JPH1187264A (en) 1999-03-30

Family

ID=17154556

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24684497A Withdrawn JPH1187264A (en) 1997-09-11 1997-09-11 Semiconductor device and manufacture thereof

Country Status (1)

Country Link
JP (1) JPH1187264A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001006547A1 (en) * 1999-07-14 2001-01-25 Lucent Technologies Inc. A thin film resistor device and a method of manufacture therefor
US6703666B1 (en) 1999-07-14 2004-03-09 Agere Systems Inc. Thin film resistor device and a method of manufacture therefor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001006547A1 (en) * 1999-07-14 2001-01-25 Lucent Technologies Inc. A thin film resistor device and a method of manufacture therefor
US6703666B1 (en) 1999-07-14 2004-03-09 Agere Systems Inc. Thin film resistor device and a method of manufacture therefor

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Legal Events

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Effective date: 20041207