JPH1136189A - Japanese paper having far infrared radiation characteristic, antimicrobial, deodorizing, mildewproof and insect repellent property and further antistatic property and its production - Google Patents
Japanese paper having far infrared radiation characteristic, antimicrobial, deodorizing, mildewproof and insect repellent property and further antistatic property and its productionInfo
- Publication number
- JPH1136189A JPH1136189A JP20105197A JP20105197A JPH1136189A JP H1136189 A JPH1136189 A JP H1136189A JP 20105197 A JP20105197 A JP 20105197A JP 20105197 A JP20105197 A JP 20105197A JP H1136189 A JPH1136189 A JP H1136189A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- powder
- mixed
- properties
- base material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paper (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、遠赤外線放射特
性、抗菌性、脱臭性、防カビ性および防虫性を有すると
共に、静電気防止効果を有する和紙並びにその製造方法
に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to Japanese paper having far-infrared radiation properties, antibacterial properties, deodorizing properties, antifungal properties and insect repellent properties, and also having an antistatic effect and a method for producing the same.
【０００２】[0002]
【従来の技術】従来、遠赤外線放射特性、抗菌性、脱臭
性、防カビ性および防虫性を有すると共に、静電気防止
効果を有する和紙は存在していなかった。2. Description of the Related Art Hitherto, there has been no Japanese paper that has far-infrared radiation properties, antibacterial properties, deodorizing properties, fungicidal properties and insect repellent properties, and also has an antistatic effect.
【０００３】[0003]
【発明が解決しようとする課題】上記のように、従来は
遠赤外線放射特性、抗菌性、脱臭性、防カビ性および防
虫性を有すると共に、静電気防止効果を有する和紙は存
在していなかったため、従来の和紙を用いて作られた障
子紙または襖紙あるいは壁紙では、室内の汚臭や雑菌が
除去されず、極めて不衛生であり、更に防カビ性もな
く、またノミやダニ等の衛生害虫に対する防虫性もな
く、また更に和紙を被服やシーツに利用した場合遠赤外
線を放射しないので、皮膚表面温度を昇温させること
や、血流を促進させることができず、そして静電気が発
生して不快感を与えるという課題があった。As described above, Japanese paper which has far-infrared radiating properties, antibacterial properties, deodorizing properties, fungicidal properties and insect repellent properties, and has an antistatic effect has not existed. Sash paper or sliding paper or wallpaper made using conventional Japanese paper does not remove indoor odors and germs, is extremely unsanitary, has no fungicide resistance, and is a sanitary pest such as fleas and mites. It does not have insect repellency and does not emit far-infrared rays when using Japanese paper for clothing or sheets, so it cannot raise the temperature of the skin surface, promote blood flow, and generate static electricity. There was a problem of giving discomfort.
【０００４】本発明はかかる課題を解決すべくなしたも
ので、和紙に遠赤外線放射特性、抗菌性、脱臭性、防カ
ビ性、防虫性および静電気防止効果を付与することによ
り、例えば障子紙または襖紙あるいは壁紙に利用した場
合、冬期において暖かく、雑菌の発生を防止し、且つ部
屋の臭気を除去し、併せて防カビ作用およびノミやダニ
等の衛生害虫が寄り付かないという防虫効果を有し、更
に被服やシーツ等に利用した場合、皮膚表面温度を昇温
させて血流を促進させ、且つ帯電電圧が低く静電気防止
効果を有する和紙並びにその製造方法を提供しようとす
るものである。SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and provides Japanese paper with far-infrared radiating properties, antibacterial properties, deodorizing properties, fungicidal properties, insect-proofing properties and antistatic effects. When used for fusuma paper or wallpaper, it is warm in the winter, prevents the occurrence of various germs, removes odors in the room, and has a fungicidal action and an insect repellent effect that sanitary pests such as fleas and ticks do not approach. In addition, when used for clothing or sheets, it is an object of the present invention to provide a Japanese paper having a low charging voltage and an antistatic effect by raising the skin surface temperature to promote blood flow, and a method for producing the same.
【０００５】[0005]
【課題を解決するための手段】本発明は、角閃石、マグ
ネシア、炭素、蛇紋石、花崗斑石、石英閃緑石、シリカ
およびチタンの各セラミックス中、角閃石粉末、マグネ
シア粉末および炭素粉末を基材とし、該基材に対して混
合材として前記角閃石、マグネシアおよびシリカ以外の
１〜３種類のセラミックス粉末を添加混合して得られた
複合セラミックスを和紙に含有させるという手段、角閃
石粉末２０〜３０重量％、マグネシア粉末１５〜２５重
量％および炭素粉末５〜１５重量％を基材とすると共
に、蛇紋石粉末２０〜３０重量％およびシリカ粉末１５
〜２５重量％を混合材として前記基材に添加混合して、
混合機および粉砕機に順次複数回に亘って投入して、前
記基材および混合材を混合攪拌および粉砕して均一に混
合し、然る後２００〜５００℃の仮焼温度で焼成機によ
り焼成して得られた複合セラミックスを、和紙の製造工
程中の紙漉き工程において原材料中に添加混入するとい
う手段、角閃石粉末３〜７重量％、マグネシア粉末５〜
１５重量％および炭素粉末５〜１５重量％を基材とする
と共に、蛇紋石粉末４０〜６０重量％、シリカ粉末１０
〜２０重量％およびチタン粉末５〜１５重量％を混合材
として前記基材に添加混合して、混合機および粉砕機に
順次複数回に亘って投入して、前記基材および混合材を
混合攪拌および粉砕して均一に混合し、然る後２００〜
５００℃の仮焼温度で焼成機により焼成して得られた複
合セラミックスを、和紙の製造工程中の紙漉き工程にお
いて原材料中に添加混入するという手段、角閃石粉末３
〜７重量％、マグネシア粉末４０〜６０重量％および炭
素粉末５〜１５重量％を基材とすると共に、シリカ粉末
５〜１５重量％およびチタン粉末２０〜３０重量％を混
合材として前記基材に添加混合して、混合機および粉砕
機に順次複数回に亘って投入して、前記基材および混合
材を混合攪拌および粉砕して均一に混合し、然る後２０
０〜５００℃の仮焼温度で焼成機により焼成して得られ
た複合セラミックスを、和紙の製造工程中の紙漉き工程
において原材料中に添加混入するという手段、角閃石粉
末５〜１５重量％、マグネシア粉末２５〜３５重量％お
よび炭素粉末３〜７重量％を基材とすると共に、花崗斑
石粉末４０〜６０重量％およびチタン粉末３〜７重量％
を混合材として前記基材に添加混合して、混合機および
粉砕機に順次複数回に亘って投入して、前記基材および
混合材を混合攪拌および粉砕して均一に混合し、然る後
２００〜５００℃の仮焼温度で焼成機により焼成して得
られた複合セラミックスを、和紙の製造工程中の紙漉き
工程において原材料中に添加混入するという手段、角閃
石粉末３〜７重量％、マグネシア粉末２０〜３０重量％
および炭素粉末３〜７重量％を基材とすると共に、石英
閃緑石粉末４０〜６０重量％、シリカ粉末５〜１５重量
％およびチタン粉末３〜７重量％を混合材として前記基
材に添加混合して、混合機および粉砕機に順次複数回に
亘って投入して、前記基材および混合材を混合攪拌およ
び粉砕して均一に混合し、然る後２００〜５００℃の仮
焼温度で焼成機により焼成して得られた複合セラミック
スを、和紙の製造工程中の紙漉き工程において原材料中
に添加混入するという手段、角閃石粉末２０〜３０重量
％、マグネシア粉末４０〜６０重量％および炭素粉末３
〜７重量％を基材とすると共に、チタン粉末１５〜２５
重量％を混合材として前記基材に添加混合して、混合機
および粉砕機に順次複数回に亘って投入して、前記基材
および混合材を混合攪拌および粉砕して均一に混合し、
然る後２００〜５００℃の仮焼温度で焼成機により焼成
して得られた複合セラミックスを、和紙の製造工程中の
紙漉き工程において原材料中に添加混入するという手
段、のいずれかを採用することにより、上記課題を解決
した。SUMMARY OF THE INVENTION The present invention relates to an amphibole powder, a magnesia powder, a magnesia powder, a magnesia powder, a magnesia powder, a porphyry stone, a quartz diorite, silica and titanium ceramics. A means for making a Japanese paper a composite ceramic obtained by adding and mixing one to three types of ceramic powders other than the amphibole, magnesia and silica as a mixed material to the base material as a mixed material; 20 to 30% by weight, 15 to 25% by weight of magnesia powder and 5 to 15% by weight of carbon powder as a base material, and 20 to 30% by weight of serpentine powder and silica powder 15
-25% by weight as a mixed material,
It is put into a mixer and a pulverizer sequentially several times, and the base material and the mixed material are mixed, stirred and pulverized to be uniformly mixed, and then calcined at a calcining temperature of 200 to 500 ° C. by a calciner. Means to add and mix the composite ceramics obtained in the paper making process in the manufacturing process of Japanese paper, the amphibole powder 3-7% by weight, the magnesia powder 5-5
15 to 15% by weight of carbon powder and 5 to 15% by weight of carbon powder, 40 to 60% by weight of serpentine powder, 10% by weight of silica powder
To 20% by weight and 5 to 15% by weight of titanium powder as a mixed material are added to and mixed with the base material, and the mixture is put into a mixer and a pulverizer sequentially several times to mix and mix the base material and the mixed material. And pulverize and mix uniformly, then 200 ~
Means for adding and mixing the composite ceramics obtained by calcining with a calciner at a calcining temperature of 500 ° C. into raw materials in a paper making process in a Japanese paper manufacturing process;
To 7% by weight, magnesia powder 40 to 60% by weight and carbon powder 5 to 15% by weight as a base material, and silica powder 5 to 15% by weight and titanium powder 20 to 30% by weight as a mixed material to the base material The mixture and the mixture are charged into a mixer and a pulverizer in succession a plurality of times to mix and stir and pulverize the base material and the mixture, and then uniformly mix the mixture.
Means for adding and mixing the composite ceramics obtained by calcining at a calcining temperature of 0 to 500 ° C. with a calcining machine into raw materials in a paper making process in a manufacturing process of Japanese paper, 5-15% by weight of amphibole powder, magnesia 25-35% by weight of powder and 3-7% by weight of carbon powder, 40-60% by weight of granite powder and 3-7% by weight of titanium powder
Is added to the base material as a mixed material, and the mixture is put into a mixer and a pulverizer sequentially several times, and the base material and the mixed material are mixed, stirred, pulverized and uniformly mixed. Means for adding and mixing the composite ceramics obtained by calcining with a calciner at a calcining temperature of 200 to 500 ° C. into raw materials in a paper making process in a Japanese paper manufacturing process, amphibole powder 3 to 7% by weight, magnesia 20-30% by weight of powder
And 3 to 7% by weight of carbon powder as a base material, and 40 to 60% by weight of quartz diorite powder, 5 to 15% by weight of silica powder and 3 to 7% by weight of titanium powder as a mixed material and mixed with the base material. Then, the mixture is put into a mixer and a crusher several times sequentially, and the base material and the mixed material are mixed, stirred and crushed to be uniformly mixed, and then calcined at a calcination temperature of 200 to 500 ° C. Means for adding and mixing the composite ceramics obtained by firing with a machine into raw materials in a paper making process in a manufacturing process of Japanese paper, amphibole powder 20-30% by weight, magnesia powder 40-60% by weight and carbon powder 3
About 7% by weight as a base material and titanium powder 15 to 25
% By weight as a mixed material and mixed with the base material, and charged into a mixer and a pulverizer sequentially multiple times to mix and stir and pulverize the base material and the mixed material to mix uniformly.
Then, the composite ceramic obtained by calcining at a calcining temperature of 200 to 500 ° C. by a calcining machine is added to the raw material in a paper making process in a manufacturing process of Japanese paper, and the raw material is mixed. Has solved the above problem.
【０００６】[0006]
【発明の実施の形態】本発明者は、単一成分のセラミッ
クスにつき、夫々遠赤外線放射率、抗菌率、脱臭率、防
カビ性を示す防カビ抵抗、ノミやダニ等の衛生害虫に対
する防虫性を示す忌避率および帯電電圧につき、個々に
測定し、遠赤外線放射率、抗菌率、脱臭率、防カビ抵
抗、忌避率および帯電電圧のいずれかにおいて優れたも
のを抽出すると共に、前記各セラミックスを複数種類一
定比率で混合攪拌し、然る後仮焼して遠赤外線放射特
性、抗菌性および脱臭性を有すると共に、防カビ性、防
虫性および帯電電圧が低く静電気防止効果を有する複合
セラミックスを製造し、そして該複合セラミックスを和
紙の製造工程中の紙漉き工程において和紙の原材料中に
添加混入して含有させることにより、遠赤外線放射特
性、抗菌性、脱臭性、防カビ性、防虫性を有すると共
に、静電気防止効果を有する和紙を完成した。以下本発
明製造方法につき詳細に説明する。BEST MODE FOR CARRYING OUT THE INVENTION The inventor of the present invention has proposed that a single-component ceramic has a far-infrared ray emissivity, an antibacterial rate, a deodorizing rate, a fungicide resistance showing fungicide properties, and an insect repellent property against sanitary pests such as fleas and ticks. The repellent rate and the charging voltage indicating are measured individually, and the far-infrared emissivity, antibacterial rate, deodorizing rate, anti-mold resistance, repellent rate and charging voltage are extracted, and each of the ceramics is extracted. Mix and stir multiple types at a fixed ratio, and then calcine to produce composite ceramics with far-infrared radiation properties, antibacterial properties and deodorizing properties, as well as mildew-proof, insect-proof and low electrostatic voltage, and an antistatic effect. Then, the composite ceramic is added to and mixed with the raw material of the washi in the paper making process of the manufacturing process of the washi, so that the far-infrared radiation property, antibacterial property, deodorizing property, prevention Bi-resistant, and has a insecticidal, was completed the Japanese paper with an antistatic effect. Hereinafter, the production method of the present invention will be described in detail.
【０００７】本発明に使用される遠赤外線放射特性、抗
菌性および脱臭性を有すると共に、防カビ性、防虫性お
よび帯電電圧が低く静電気防止効果を有する複合セラミ
ックスを構成する単一成分のセラミックスの平均放射
率、抗菌率、脱臭率、防カビ抵抗、忌避率および帯電電
圧を測定したところ、表１に示す測定値を得た。なお、
前記防カビ抵抗はＪＩＳ Ｚ ２９１１によって測定し
た。The single-component ceramics constituting the composite ceramics having far-infrared radiation properties, antibacterial properties and deodorizing properties, and having a low antifungal property, insect repellency and low charging voltage and having an antistatic effect used in the present invention. When the average emissivity, antibacterial rate, deodorization rate, mold resistance, repellency and charging voltage were measured, the measured values shown in Table 1 were obtained. In addition,
The mold resistance was measured according to JIS Z 2911.
【０００８】[0008]
【表１】 [Table 1]
【０００９】表１の結果から、シリカと炭素が９７％の
極めて高い遠赤外線放射率を有し、そしてマグネシアが
９５％、蛇紋石が９４％、花崗斑石が９３．５％、角閃
石と石英閃緑石が９３％、最低のチタンでも９０％とい
う高い遠赤外線放射率を有することが判った。また、蛇
紋石はブドウ状球菌に対しては９８％の抗菌率を有する
が、大腸菌に対しては６５％と中程度の抗菌率しかな
く、硫化水素に対しては１００％の脱臭率を有するが、
アンモニアに対しては５０％と中程度の脱臭率しかな
く、角閃石はブドウ状球菌に対して８２％と高い抗菌率
を有するが、大腸菌に対しては５０％と中程度の抗菌率
しかなく、アンモニアに対して５０％、硫化水素に対し
て６５％と中程度の脱臭率しかなく、また、花崗斑石は
大腸菌に対して６５％、ブドウ状球菌に対して７０％と
中程度の抗菌率を有し、アンモニアに対して６０％、硫
化水素に対して７０％と中程度の脱臭率を有し、更に、
石英閃緑石は大腸菌に対して７５％、ブドウ状球菌に対
して６７％と中程度の抗菌率を有し、アンモニアに対し
て６５％、硫化水素に対して７０％と中程度の脱臭率を
有することが判った。From the results in Table 1, it can be seen that silica and carbon have an extremely high infrared emissivity of 97%, magnesia 95%, serpentine 94%, granite porphyry 93.5%, amphibolite. It was found that quartz diorite had a high far-infrared emissivity of 93%, and the lowest titanium, 90%. Serpentine has an antibacterial rate of 98% against staphylococci, has only a moderate antibacterial rate against Escherichia coli at 65%, and has a deodorizing rate of 100% against hydrogen sulfide. But,
Ammonia has only a moderate deodorization rate of 50% against ammonia, and amphibole has a high antibacterial rate of 82% against staphylococci, but has only a moderate antibacterial rate against Escherichia coli of 50%. It has a moderate deodorization rate of 50% for ammonia and 65% for hydrogen sulfide, and granite porphyry has a moderate deodorization rate of 65% for E. coli and 70% for staphylococci. It has an antibacterial rate, a moderate deodorization rate of 60% for ammonia and 70% for hydrogen sulfide, and
Quartz diorite has a moderate antibacterial rate of 75% against Escherichia coli and 67% against staphylococci, and a moderate deodorization rate of 65% against ammonia and 70% against hydrogen sulfide. It was found to have.
【００１０】マグネシアは大腸菌に対して９９．９％、
ブドウ状球菌に対して９８％と極めて高い抗菌率を有す
るが、アンモニアに対して２５％、硫化水素に対して４
５％と脱臭率は高くなく、シリカは大腸菌に対して１５
％、ブドウ状球菌に対して３５％と低い抗菌率しかない
が、硫化水素に対して１００％、アンモニアに対して９
４％と非常に高い脱臭率を有することが判った。[0010] Magnesia is 99.9% against E. coli,
It has an extremely high antibacterial rate of 98% against staphylococci, but 25% against ammonia and 4 against hydrogen sulfide.
The deodorization rate is not high at 5%, and silica is
%, Only 35% against staphylococci, but 100% against hydrogen sulfide, 9% against ammonia
It was found to have a very high deodorization rate of 4%.
【００１１】そして、蛇紋石およびマグネシアは防カビ
抵抗が３で最高値を示して高い防カビ抵抗性を有し、角
閃石、花崗斑石、石英閃緑石およびシリカは防カビ抵抗
が２で中程度の防カビ抵抗性を有し、またノミやダニ等
の衛生害虫に対する防虫性を示す忌避率は、マグネシア
が９７％、蛇紋石が９６％、角閃石が９２％、石英閃緑
石が９１％、シリカが９０％および花崗斑石８５％でい
ずれも高率であった。[0011] Serpentine and magnesia have a high mold resistance of 3 at the maximum and have high mold resistance, and amphibolite, granite, quartz diorite and silica have a mold resistance of 2 and have a high mold resistance. It has moderate mold resistance and repellency against sanitary pests such as fleas and ticks. The repellency is 97% for magnesia, 96% for serpentine, 92% for amphibolite, and 91% for quartz diorite. %, Silica at 90% and granite porphyry at 85%, all of which were high.
【００１２】一方、チタンは大腸菌に対して２０％、ブ
ドウ状球菌に対して２５％の低い抗菌率しかなく、アン
モニアに対して６０％の中程度の脱臭率を有するが、硫
化水素に対しては２０％と低い脱臭率しか有しておら
ず、また炭素は大腸菌、ブドウ状球菌に対していずれも
２０％と低い抗菌率しかなく、アンモニアに対して６５
％、硫化水素に対して５５％と中程度の脱臭率を有す
る。そして、防カビ抵抗はチタン、炭素とも１で低い防
カビ抵抗しかなく、忌避率もチタンが５０％、炭素が２
５％で低いことが判った。On the other hand, titanium has only a low antibacterial rate of 20% against Escherichia coli and 25% against staphylococci, and has a moderate deodorization rate of 60% against ammonia, but has a low deodorizing rate against hydrogen sulfide. Has a low deodorization rate of 20%, carbon has an antibacterial rate of as low as 20% against Escherichia coli and staphylococci, and has a carbon content of 65% against ammonia.
% And a moderate deodorization rate of 55% with respect to hydrogen sulfide. The antifungal resistance is 1 for both titanium and carbon, which is low, and the repellent rate is 50% for titanium and 2 for carbon.
It turned out to be low at 5%.
【００１３】更に、帯電電圧は、蛇紋石が７．６ＫＶ、
角閃石が７．５ＫＶ、花崗斑石が８．０ＫＶ、石英閃緑
石が７．０ＫＶ、マグネシアが６．５ＫＶ、シリカが
６．０ＫＶでそれぞれ低いのに対して、チタンが３．０
ＫＶ、炭素が２．９ＫＶで更に低く、いずれのセラミッ
クスもほとんど静電気を帯電しないことが判った。The charging voltage of the serpentine is 7.6 KV,
Amphibole is 7.5 KV, granite porphyry is 8.0 KV, quartz diorite is 7.0 KV, magnesia is 6.5 KV, and silica is 6.0 KV, respectively, while titanium is 3.0, respectively.
KV and carbon were lower at 2.9 KV, indicating that none of the ceramics was charged with static electricity.
【００１４】前記抗菌率、脱臭率、防カビ抵抗および忌
避率において劣っている炭素およびチタンを本発明に使
用される複合セラミックスの素材として採用するのは、
炭素およびチタンは帯電電圧が低いので、他のセラミッ
クスの帯電電圧を下げるためであり、更にチタンは光に
よって他のセラミックスを活性励起させるという作用を
有し、チタンを他のセラミックスと混合することによ
り、他のセラミックスに活性励起作用が発生し、他のセ
ラミックスの特性を更に向上させるためである。Carbon and titanium, which are inferior in antibacterial rate, deodorizing rate, mold resistance and repellent rate, are employed as the material of the composite ceramic used in the present invention.
Since carbon and titanium have low charging voltages, this is to reduce the charging voltage of other ceramics.In addition, titanium has the effect of actively exciting other ceramics by light, and by mixing titanium with other ceramics, This is because an active excitation action occurs in other ceramics to further improve the properties of the other ceramics.
【００１５】上記の結果より、本発明者は遠赤外線放射
率、抗菌率、脱臭率、防カビ抵抗および忌避率におい
て、中程度から高率の数値を示した角閃石およびマグネ
シアと帯電電圧が低い炭素とを本発明に使用する複合セ
ラミックスの基材として採用し、これら基材に混合材と
して１〜３種類のセラミックスを添加混合することによ
って、遠赤外線放射特性、抗菌性、脱臭性、防カビ性お
よび防虫性を有すると共に、帯電電圧が低く静電気をほ
とんど帯電せず静電気防止効果を有する複合セラミック
スが得られると考え、前記各セラミックスをその配合比
率を種々変えて複合セラミックスを製造した。From the above results, the inventor of the present invention has found that the charging voltage is lower than that of amphibolite and magnesia, which show moderate to high values in the far-infrared ray emissivity, antibacterial rate, deodorization rate, mold resistance and repellency. By adopting carbon as the base material of the composite ceramics used in the present invention and adding and mixing 1 to 3 types of ceramics as a mixture to these base materials, far-infrared radiation properties, antibacterial properties, deodorizing properties, and mold prevention In view of the fact that a composite ceramic having an antistatic effect with low charge voltage and little static charge and having an antistatic effect, in addition to having properties and insect repellency, was produced by changing the mixing ratio of each of the above ceramics variously.
【００１６】すなわち、基材となる角閃石２０〜３０重
量％、好ましくは２５重量％、マグネシア１５〜２５重
量％、好ましくは２０重量％、炭素５〜１５重量％、好
ましくは１０重量％に対して、混合材として蛇紋石２０
〜３０重量％、好ましくは２５重量％、シリカ１５〜２
５重量％、好ましくは２０重量％を添加混合して複合セ
ラミックスＡを製造し、または基材となる角閃石３〜７
重量％、好ましくは５重量％、マグネシア５〜１５重量
％、好ましくは１０重量％、炭素５〜１５重量％、好ま
しくは１０重量％に対して、混合材として蛇紋石４０〜
６０重量％、好ましくは５０重量％、シリカ１０〜２０
重量％、好ましくは１５重量％、チタン５〜１５重量
％、好ましくは１０重量％を添加混合して複合セラミッ
クスＢを製造し、そしてまたは基材となる角閃石３〜７
重量％、好ましくは５重量％、マグネシア４０〜６０重
量％、好ましくは５０重量％、炭素５〜１５重量％、好
ましくは１０重量％に対して、混合材としてシリカ５〜
１５重量％、好ましくは１０重量％、チタン２０〜３０
重量％、好ましくは２５重量％を添加混合して複合セラ
ミックスＣを製造し、更に基材となる角閃石５〜１５重
量％、好ましくは１０重量％、マグネシア２５〜３５重
量％、好ましくは３０重量％、炭素３〜７重量％、好ま
しくは５重量％に対して、混合材として花崗斑石４０〜
６０重量％、好ましくは５０重量％、チタン３〜７重量
％、好ましくは５重量％を添加混合して複合セラミック
スＤを製造し、また更に基材となる角閃石３〜７重量
％、好ましくは５重量％、マグネシア２０〜３０重量
％、好ましくは２５重量％、炭素３〜７重量％、好まし
くは５重量％に対して、混合材として石英閃緑石４０〜
６０重量％、好ましくは５０重量％、シリカ５〜１５重
量％、好ましくは１０重量％、チタン３〜７重量％、好
ましくは５重量％を添加混合して複合セラミックスＥを
製造し、そして更に基材となる角閃石２０〜３０重量
％、好ましくは２５重量％、マグネシア４０〜６０重量
％、好ましくは５０重量％、炭素３〜７重量％、好まし
くは５重量％に対して、混合材としてチタン１５〜２５
重量％、好ましくは２０重量％を添加混合して複合セラ
ミックスＦを製造した。That is, the amphibole as a base material is 20 to 30% by weight, preferably 25% by weight, magnesia 15 to 25% by weight, preferably 20% by weight, carbon 5 to 15% by weight, preferably 10% by weight. And serpentine 20 as a mixture
~ 30% by weight, preferably 25% by weight, silica 15 ~ 2
5% by weight, preferably 20% by weight is added and mixed to produce a composite ceramics A, or an amphibole 3 to 7 serving as a base material.
% By weight, preferably 5% by weight, magnesia 5 to 15% by weight, preferably 10% by weight, carbon 5 to 15% by weight, preferably 10% by weight.
60% by weight, preferably 50% by weight, silica 10-20
%, Preferably 15% by weight, 5 to 15% by weight, preferably 10% by weight of titanium to produce a composite ceramic B, and / or amphibole 3 to 7 as a base material.
% By weight, preferably 5% by weight, magnesia 40 to 60% by weight, preferably 50% by weight, carbon 5 to 15% by weight, preferably 10% by weight;
15% by weight, preferably 10% by weight, titanium 20-30
The composite ceramics C is manufactured by adding and mixing 25% by weight, preferably 25% by weight, and 5 to 15% by weight, preferably 10% by weight, and 25 to 35% by weight, preferably 30% by weight of magnesia as a base material. %, Carbon 3 to 7% by weight, preferably 5% by weight, and granite porphyry 40 to
60% by weight, preferably 50% by weight, 3 to 7% by weight, preferably 5% by weight of titanium are added and mixed to produce a composite ceramics D, and 3 to 7% by weight of amphibole as a base material, preferably 5% by weight, 20 to 30% by weight of magnesia, preferably 25% by weight, 3 to 7% by weight of carbon, preferably 5% by weight;
60% by weight, preferably 50% by weight, 5 to 15% by weight, preferably 10% by weight of silica, 3 to 7% by weight, preferably 5% by weight of titanium are added and mixed to produce a composite ceramic E. Amphibole 20-30% by weight, preferably 25% by weight, magnesia 40-60% by weight, preferably 50% by weight, carbon 3-7% by weight, preferably 5% by weight; 15-25
By weight, preferably 20% by weight was added and mixed to prepare a composite ceramic F.
【００１７】そして、本発明で採用する複合セラミック
スを構成する単一成分のセラミックスである角閃石、マ
グネシア、炭素、蛇紋石、花崗斑石、石英閃緑石、シリ
カおよびチタンを夫々表２に示す好ましい混合率により
混合して製造された複合セラミックスの遠赤外線放射
率、抗菌率、脱臭率、防カビ抵抗、忌避率および帯電電
圧を測定した結果を表３に示す。前記防カビ抵抗はＪＩ
Ｓ Ｚ２９１１によって測定した。なお、表３における
記号Ａ〜Ｆは表２の記号Ａ〜Ｆと対応している。Table 2 shows amphibolite, magnesia, carbon, serpentine, granite, quartz diorite, silica and titanium which are single component ceramics constituting the composite ceramics employed in the present invention. Table 3 shows the results of measuring the far-infrared emissivity, antibacterial rate, deodorizing rate, anti-mold resistance, repellent rate and charging voltage of the composite ceramics produced by mixing at a preferable mixing ratio. The mold resistance is JI
Measured by SZ2911. The symbols A to F in Table 3 correspond to the symbols A to F in Table 2.
【００１８】[0018]
【表２】 [Table 2]
【００１９】[0019]
【表３】 [Table 3]
【００２０】前記表３の結果から、いずれの複合セラミ
ックスも、その複合セラミックスを構成する各単一成分
の各セラミックスの相乗効果により遠赤外線放射率が９
１．５〜９５％、大腸菌に対する抗菌率が９１〜９４
％、ブドウ状球菌に対する抗菌率が９０〜９５％、アン
モニアに対する脱臭率が９２〜９５％、硫化水素に対す
る脱臭率が９２〜９５％で高い数値が出て、遠赤外線放
射特性、抗菌性および脱臭性において優れていると共
に、防カビ抵抗が３および忌避率が９１〜９４％で高
く、防カビ性および衛生害虫に対する防虫性を示す忌避
効果においても優れていることが判った。また、前記各
複合セラミックスには、帯電電圧の低い炭素が６種類全
部に、またチタンが５種類に含まれているため、それぞ
れ３．７〜４．５ＫＶの低い帯電電圧しかなく、ほとん
ど静電気を帯電せず静電気防止効果を有することが判っ
た。From the results shown in Table 3, all the composite ceramics have a far-infrared emissivity of 9 due to the synergistic effect of each ceramic of each single component constituting the composite ceramics.
1.5-95%, antibacterial rate against E. coli 91-94
%, The antibacterial rate against staphylococci is 90-95%, the deodorizing rate against ammonia is 92-95%, and the deodorizing rate against hydrogen sulfide is 92-95%. In addition to being excellent in resistance, the antifungal resistance was 3 and the repellent rate was high at 91 to 94%, and it was found that the antifungal effect and the repellent effect showing the insect repellency against sanitary insects were also excellent. Further, since each of the composite ceramics contains carbon having a low charging voltage in all six types and titanium in five types, each has only a low charging voltage of 3.7 to 4.5 KV, and almost no static electricity is generated. It was found that it was not charged and had an antistatic effect.
【００２１】以下本発明に採用する遠赤外線放射特性、
抗菌性、脱臭性を有すると共に、防カビ性、防虫性およ
び静電気防止効果を有する複合セラミックスの製造方法
について更に詳細に説明する。前記複合セラミックスを
構成する各単一成分の各セラミックスの粒径は、好まし
くは１００μｍ以下の粉末を使用するが、これら各セラ
ミックスを混合すると、各セラミックスの比重、水分、
湿度等の物理的特性が夫々異なるので、前記各セラミッ
クスを均一に混合することは極めて容易ではない。The far-infrared radiation characteristics employed in the present invention are as follows:
A method for producing a composite ceramic having antibacterial properties, deodorizing properties, and fungicidal properties, insect repellency and antistatic effects will be described in more detail. The particle size of each ceramic of each single component constituting the composite ceramic is preferably a powder of 100 μm or less. When these ceramics are mixed, the specific gravity of each ceramic, moisture,
Since the physical properties such as humidity are different from each other, it is not very easy to uniformly mix the ceramics.
【００２２】そこで本発明者は、表２に示すような好ま
しい混合率により前記基材と混合材を夫々所定比率で混
合機に投入して混合攪拌した後、その混合物を粉砕機に
投入して粉砕し、そして更に、前記粉砕したものを再び
混合機に投入して混合攪拌し、その後また粉砕機に投入
して粉砕するという工程を順次約３０分間繰返すという
手段を採用することにより、基材と混合材とが均一に混
合された複合セラミックスを製造することができた。The inventor of the present invention introduced the base material and the mixed material at predetermined ratios into a mixer at a predetermined mixing ratio as shown in Table 2, mixed and stirred the mixture, and then charged the mixture into a pulverizer. By crushing, and further, the above-mentioned crushed thing is again put into the mixer, mixed and stirred, and then, the step of again putting into the crusher and crushing is repeated for about 30 minutes, thereby adopting a means of repeating the base material. And a mixed material were uniformly mixed to produce a composite ceramic.
【００２３】そして、前記均一に混合された複合セラミ
ックスの化学特性の安定化を図るため、複合セラミック
スを２００〜５００℃の仮焼温度で焼成機により焼成し
て、遠赤外線放射特性、抗菌性、脱臭性、防カビ性、防
虫性および静電気防止効果を有する複合セラミックスと
するのである。In order to stabilize the chemical properties of the uniformly mixed composite ceramics, the composite ceramics is fired by a firing machine at a calcining temperature of 200 to 500 ° C. to obtain far-infrared radiation properties, antibacterial properties, The purpose is to provide a composite ceramic having deodorizing properties, antifungal properties, insect repellency and antistatic effects.
【００２４】前記表３から前記製造方法によって得られ
た複合セラミックスは、仮焼によって結晶化されて電界
エネルギー（陽イオン）を発生する機能を有する複合セ
ラミックスであり、１年以上という長時間に亘って経時
変化がなく安定していて、脱臭機構は分解作用であると
いう特性を有し、その結果前記製造方法によって得られ
た複合セラミックスは、遠赤外線放射特性を有すると共
に、抗菌性、脱臭性、防カビ性および防虫性を兼ね備え
る外、前記したように炭素およびチタンが含まれている
ため帯電電圧が低く静電気をほとんど帯電せず、静電気
防止効果を有することが判る。From Table 3 above, the composite ceramics obtained by the above-mentioned production method is a composite ceramics which has a function of generating electric field energy (cations) by being crystallized by calcination, and has a long period of one year or more. It is stable without change over time, and has a property that the deodorizing mechanism is a decomposing action, and as a result, the composite ceramics obtained by the manufacturing method has far-infrared radiation properties, as well as antibacterial properties, deodorizing properties, In addition to having both fungicidal and insect repellent properties, as described above, since carbon and titanium are contained, the charging voltage is low and the static electricity is hardly charged, so that it has an antistatic effect.
【００２５】一般的に生菌の表層（壁）は陰イオンであ
って、そのため中性領域（ｐＨ７．０〜７．５）でしか
生息が不可能であるが、前記製造方法によって得られた
複合化された複合セラミックスの最大の特性として陽イ
オンを発生するので、陰イオンである菌体の表層（壁）
が、前記複合セラミックスの陽イオンによって破壊され
ると同時に、菌体蛋白質が変成して、呼吸困難となり死
滅するのである。In general, the surface layer (wall) of living bacteria is an anion, and therefore can only live in the neutral region (pH 7.0 to 7.5). The biggest characteristic of the composite ceramics is that it generates cations as the greatest property, so the surface layer (wall) of bacterial cells that are anions
However, at the same time as being destroyed by the cations of the composite ceramics, the bacterial protein is denatured and becomes difficult to breathe.
【００２６】更に、硫化水素およびアンモニア等に対す
る脱臭作用は、物理的吸着または化学的吸着等の一般的
作用ではなく、分解作用のため飽和状態にならないの
で、抗菌力と同様に、脱臭力を半恒久的に有すると共
に、毒性をも有していないのである。Furthermore, the deodorizing effect on hydrogen sulfide and ammonia is not a general effect such as physical adsorption or chemical adsorption, but does not become saturated due to the decomposing effect. It is permanent and has no toxicity.
【００２７】本発明製造方法の素材となる複合セラミッ
クスの粒子の粒径は、特に限定する必要はないが和紙の
製造に支障のない程度の大きさでなければならない。粒
径１００μｍ程度のものの利用も可能であるが、通常は
１０μｍ程度のもの、特に５μｍ程度のものが好適であ
る。The particle size of the particles of the composite ceramics used as the raw material in the production method of the present invention is not particularly limited, but must be a size that does not hinder the production of Japanese paper. Although a particle having a particle size of about 100 μm can be used, a particle having a particle diameter of about 10 μm, particularly about 5 μm is preferable.
【００２８】本発明製造方法により得られる遠赤外線放
射特性、抗菌性、脱臭性、防カビ性、防虫性および静電
気防止効果を有する和紙は、現在一般に用いられている
和紙の製造方法によって製造できる。すなわち、前記製
造方法によって得られた複合セラミックスは、従来公知
の和紙の製造工程中の紙漉き工程において漉き槽に投入
されたコウゾ、ミツマタ等の原材料中に添加混入され
る。The Japanese paper having the far-infrared radiation property, antibacterial property, deodorizing property, antifungal property, insect repellent property and antistatic effect obtained by the manufacturing method of the present invention can be manufactured by a generally used manufacturing method of Japanese paper at present. That is, the composite ceramics obtained by the above-mentioned production method is added and mixed into raw materials such as mulberry, mitsumata, etc., which are put into a paper making tank in a paper making step in a conventionally known paper making step.
【００２９】前記紙漉き工程中における前記複合セラミ
ックスの添加混入量は特に限定する必要はないが、２〜
５重量％が好ましく、３重量％とするのが特に好まし
い。前記複合セラミックスの原材料中への添加混入後
は、分散性を考慮して攪拌する必要がある。漉き槽に投
入された原材料は、漉き水等によって原材料の繊維質が
膨潤し、そしてこの膨潤状態において攪拌作業が行われ
るので、前記複合セラミックスが効率よく原材料中に均
一に分散して含有される。The amount of the composite ceramics added and mixed during the papermaking step is not particularly limited,
It is preferably 5% by weight, particularly preferably 3% by weight. After the addition and mixing of the composite ceramics into the raw materials, it is necessary to stir in consideration of dispersibility. In the raw material charged into the making tank, the fibrous material of the raw material is swollen by the making water or the like, and the stirring operation is performed in this swollen state, so that the composite ceramics are efficiently dispersed uniformly in the raw material. .
【００３０】そして、前記複合セラミックスを均一に分
散して原材料に含浸せしめ、一枚一枚和紙を漉き、その
後従来公知の脱水および乾燥工程を経て和紙が製造され
る。Then, the composite ceramics are uniformly dispersed and impregnated into raw materials, and each piece of Japanese paper is made. Thereafter, a conventionally known dewatering and drying process is performed to produce Japanese paper.
【００３１】前記特に好ましい混合率によって得られた
表２の記号Ａ〜Ｆに示す複合セラミックスを添加混入し
て製造された和紙につき、遠赤外線放射率、抗菌率、脱
臭率、防カビ抵抗および忌避率について測定した平均値
を表４に示す。表中のＡ〜Ｆは原材料に含浸された複合
セラミックスで、表２の記号Ａ〜Ｆと対応している。With respect to Japanese paper manufactured by adding and mixing the composite ceramics indicated by the symbols A to F in Table 2 obtained at the above particularly preferable mixing ratio, far-infrared ray emissivity, antibacterial rate, deodorizing rate, fungicide resistance and repellent Table 4 shows the average values measured for the ratios. A to F in the table are composite ceramics impregnated in raw materials, and correspond to symbols A to F in Table 2.
【００３２】[0032]
【表４】 [Table 4]
【００３３】表４で示すように、本発明製造方法によっ
て得られた和紙は、９０．５〜９４％の遠赤外線放射率
を有すると共に、大腸菌に対して９０〜９３％、ブドウ
状球菌に対して８９〜９４％の抗菌率を有し、そしてア
ンモニアに対して９２〜９７％、硫化水素に対して９０
〜９３％の脱臭率を有し、更に防カビ抵抗も複合セラミ
ックスＢを用いた和紙が２で、その他の複合セラミック
スを用いた和紙が３で非常に高い防カビ性を有し、衛生
害虫に対する忌避率も９０〜９８％と極めて高く、汎用
の和紙にはない遠赤外線放射特性、抗菌性、脱臭性、防
カビ性および防虫性が付与されていることが判った。As shown in Table 4, the Japanese paper obtained by the method of the present invention has a far-infrared emissivity of 90.5 to 94%, 90 to 93% against Escherichia coli, and against Staphylococcus aureus. It has an antibacterial rate of 89-94% and 92-97% for ammonia and 90 for hydrogen sulfide.
It has a deodorization rate of ~ 93%, and also has a very high antifungal property, having a very high antifungal property, with Japanese paper 2 using composite ceramics B being 2 and Japanese paper using other composite ceramics being 3 with mildew resistance. The repellency was also extremely high at 90 to 98%, indicating that far-infrared radiation properties, antibacterial properties, deodorizing properties, fungicidal properties and insect repellency, which were not found in general-purpose Japanese paper, were imparted.
【００３４】また、汎用和紙と、前記特に好ましい混合
率によって得られた表２の記号Ａ〜Ｆに示す複合セラミ
ックスを用いて製造された和紙の帯電電圧について測定
した結果を表５に示す。表５の測定結果より、本発明に
よる和紙は汎用和紙に比してほぼ半分の帯電電圧しかな
く、その分静電気防止効果を有することが判った。これ
は、複合セラミックスに含まれている帯電電圧の低い炭
素とチタンの作用によるもので、本発明による和紙に帯
電した電荷はすぐに中和する方向に移動し、帯電電圧が
減少して、静電気をほとんど帯電しないからである。Table 5 shows the results of measuring the charging voltage of general-purpose Japanese paper and Japanese paper manufactured using the composite ceramics indicated by symbols A to F in Table 2 obtained at the above particularly preferable mixing ratio. From the measurement results in Table 5, it was found that the Japanese paper according to the present invention had only about half the charging voltage as that of the general-purpose Japanese paper, and had an antistatic effect correspondingly. This is due to the action of carbon and titanium, which have low charging voltage contained in the composite ceramic, and the charge on the Japanese paper according to the present invention immediately moves in a neutralizing direction, the charging voltage decreases, and the static electricity decreases. Is hardly charged.
【００３５】[0035]
【表５】 [Table 5]
【００３６】次に、本発明製造方法によって得られた和
紙を、靴の中敷として使用した場合の抗菌作用効果、臭
気（アンモニア）に対する作用効果およびカビに対する
作用効果を汎用の和紙より成る中敷（ブランク）と比較
した測定結果を表６〜表８に示す。なお、表６〜表８に
示す本発明和紙による中敷の測定値は、前記表２の記号
Ａ〜Ｆに示す複合セラミックスを用いて製造された各和
紙による中敷の平均値である。Next, the antibacterial effect, the effect on odor (ammonia), and the effect on mold when the Japanese paper obtained by the production method of the present invention is used as an insole for shoes are described. Tables 6 to 8 show the measurement results in comparison with (blank). In addition, the measured value of the insole with the present invention Japanese paper shown in Tables 6 to 8 is the average value of the insole with each Japanese paper manufactured using the composite ceramics indicated by the symbols A to F in Table 2 above.
【００３７】[0037]
【表６】 [Table 6]
【００３８】[0038]
【表７】 [Table 7]
【００３９】[0039]
【表８】 [Table 8]
【００４０】更に、本発明製造方法によって得られた和
紙を、スリッパとして使用した場合の抗菌作用効果、臭
気（アンモニア）に対する作用効果およびカビに対する
作用効果を汎用の和紙より成るスリッパ（ブランク）と
比較した測定結果を表９〜表１１に示す。なお、表９〜
表１１に示す本発明和紙によるスリッパの測定値は、前
記表２の記号Ａ〜Ｆに示す複合セラミックスを用いて製
造された各和紙によるスリッパの平均値である。Further, the antibacterial effect, the effect on odor (ammonia) and the effect on mold when the Japanese paper obtained by the production method of the present invention is used as a slipper are compared with the slipper (blank) made of general-purpose Japanese paper. Tables 9 to 11 show the measurement results. Table 9-
The measured values of the slippers of the Japanese paper of the present invention shown in Table 11 are the average values of the slippers of each Japanese paper manufactured using the composite ceramics indicated by the symbols A to F in Table 2.
【００４１】[0041]
【表９】 [Table 9]
【００４２】[0042]
【表１０】 [Table 10]
【００４３】[0043]
【表１１】 [Table 11]
【００４４】前記表６〜表１１の測定結果より、本発明
和紙は抗菌性、脱臭性および防カビ性を有することが立
証された。その他の遠赤外線放射特性、防ダニ性および
静電気防止効果については測定されていないが、表４の
特性から当然これら効果を有することは類推できる。From the measurement results in Tables 6 to 11, it was proved that the Japanese paper of the present invention had antibacterial properties, deodorizing properties, and antifungal properties. Other far-infrared radiation properties, anti-mite properties, and antistatic effects have not been measured, but it can be inferred from the properties in Table 4 that these effects are of course obtained.
【００４５】本発明によって得られた和紙の主なる用途
は、障子紙、襖紙、壁紙、被服、シーツ等である。前記
のように遠赤外線放射率が高い本発明製造方法に係る和
紙を、例えば障子紙または襖紙あるいは壁紙に利用した
場合、冬期において暖かく、雑菌の発生を防止し、且つ
部屋の臭気を除去し、併せて防カビ作用およびノミやダ
ニ等の衛生害虫が寄り付かないという防虫効果を有し、
更に被服やシーツ等に利用した場合、皮膚表面温度を昇
温させて血流を促進させ、且つ静電気が発生することも
ない。The main uses of the Japanese paper obtained according to the present invention are shoji paper, fusuma paper, wallpaper, clothing, sheets and the like. When the Japanese paper according to the production method of the present invention having a high far-infrared emissivity as described above is used, for example, for shoji paper or fusuma paper or wallpaper, it is warm in winter, preventing the occurrence of various germs and removing odor in the room. In addition, it has a fungicidal action and an insect repellent effect that sanitary pests such as fleas and mites do not approach,
Furthermore, when used for clothing, sheets, etc., the skin surface temperature is increased to promote blood flow, and no static electricity is generated.
【００４６】本発明製造方法による和紙をシーツにした
場合はカビの発生が阻止されると共に、ノミやダニ等の
衛生害虫が寄りつかず快適な睡眠を得ることができる。
そして、被服として着用すると静電気防止効果を有して
いるため、静電気発生による不快感がない。In the case where the sheet of the Japanese paper is produced by the production method of the present invention, the generation of mold is prevented, and a hygienic pest such as fleas and ticks does not approach, so that a comfortable sleep can be obtained.
When worn as clothing, it has an antistatic effect, so that there is no discomfort due to the generation of static electricity.
【００４７】[0047]
【発明の効果】本発明製造方法によって得られた和紙は
遠赤外線放射特性を有するので、シーツや被服として利
用することにより、皮膚表面温度を昇温させると共に、
血流を促進させるという効果がある。本発明製造方法の
素材となる抗菌性、脱臭性、防カビ性およびノミやダニ
等の衛生害虫に対する防虫性を有する複合セラミックス
が、陽イオンを発生して一般生菌を死滅させて抗菌性を
有すると共に、硫化水素およびアンモニアを分解して脱
臭性をも有し、その抗菌性と脱臭性は恒久的にその作用
を有するため、本発明製造方法によって得られた和紙は
前記複合セラミックスにより抗菌性と脱臭性を合わせ保
有し、障子紙、襖紙および壁紙等に使用され、その用途
は極めて広い。更に、本発明製造方法によって得られた
和紙は防カビ抵抗を有すると共に、ノミやダニ等の衛生
害虫に対する忌避率が高く、カビの発生が阻止され、ノ
ミやダニ等の衛生害虫が寄りつかず防虫性があるという
優れた効果を有する。また更に、本発明製造方法によっ
て得られた和紙は帯電電圧が低く静電気防止効果を有す
るため、本発明製造方法によって得られた和紙を用いた
被服を着用すると、静電気の発生が防止されるため、静
電気発生による不快感がない。The Japanese paper obtained by the production method of the present invention has far-infrared radiation characteristics, so that it can be used as sheets or clothing to raise the skin surface temperature,
It has the effect of promoting blood flow. The composite ceramics having antibacterial properties, deodorizing properties, fungicidal properties and insect repellent properties against sanitary pests such as fleas and ticks, which are materials of the production method of the present invention, generate cations to kill general viable bacteria and improve antibacterial properties. In addition, it has a deodorizing property by decomposing hydrogen sulfide and ammonia, and its antibacterial properties and deodorizing properties have permanent effects. It has both deodorizing properties and is used for shoji paper, fusuma paper, wallpaper, etc., and its use is extremely wide. Furthermore, the Japanese paper obtained by the production method of the present invention has fungicide resistance, has a high repellency against sanitary pests such as fleas and ticks, inhibits the occurrence of mold, and prevents insects such as fleas and ticks from approaching. It has an excellent effect of having a property. Still further, Japanese paper obtained by the production method of the present invention has a low charging voltage and has an antistatic effect, so that when wearing clothes using the Japanese paper obtained by the production method of the present invention, the generation of static electricity is prevented. No discomfort caused by static electricity.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ｄ２１Ｈ 3/78 ──────────────────────────────────────────────────の Continued on front page (51) Int.Cl. 6 Identification code FI D21H 3/78
Claims (7)
斑石、石英閃緑石、シリカおよびチタンの各セラミック
ス中、角閃石粉末、マグネシア粉末および炭素粉末を基
材とし、該基材に対して混合材として前記角閃石、マグ
ネシアおよびシリカ以外の１〜３種類のセラミックス粉
末を添加混合して得られた複合セラミックスを和紙に含
有させたことを特徴とする遠赤外線放射特性、抗菌性、
脱臭性、防カビ性および防虫性を有すると共に、静電気
防止効果を有する和紙。1. An amphibole, magnesia, carbon, serpentine, granite, quartz diorite, silica and titanium ceramic, each of which is made of amphibole powder, magnesia powder and carbon powder as a base material. On the other hand, far-infrared radiation characteristics, antibacterial properties, characterized in that the mixed ceramic obtained by adding and mixing 1-3 types of ceramic powders other than the amphibole, magnesia and silica as a mixed material was contained in Japanese paper,
Washi paper having deodorizing properties, fungicidal properties and insect repellency, and having an antistatic effect.
粉末１５〜２５重量％および炭素粉末５〜１５重量％を
基材とすると共に、蛇紋石粉末２０〜３０重量％および
シリカ粉末１５〜２５重量％を混合材として前記基材に
添加混合して、混合機および粉砕機に順次複数回に亘っ
て投入して、前記基材および混合材を混合攪拌および粉
砕して均一に混合し、然る後２００〜５００℃の仮焼温
度で焼成機により焼成して得られた複合セラミックス
を、和紙の製造工程中の紙漉き工程において原材料中に
添加混入することを特徴とする遠赤外線放射特性、抗菌
性、脱臭性、防カビ性および防虫性を有すると共に、静
電気防止効果を有する和紙の製造方法。2. A composition comprising, as base material, 20-30% by weight of amphibole powder, 15-25% by weight of magnesia powder and 5-15% by weight of carbon powder, 20-30% by weight of serpentine powder and 15-25% of silica powder. Wt% as a mixed material is added to and mixed with the base material, and the mixture is added to a mixer and a crusher several times sequentially to mix and stir and crush the base material and the mixed material to mix uniformly. The composite ceramics obtained by calcining at a calcining temperature of 200 to 500 ° C. is added to the raw materials in the paper making process of the manufacturing process of Japanese paper, far-infrared radiation characteristics, antibacterial A method for producing Japanese paper having antistatic properties, as well as having properties, deodorizing properties, fungicidal properties and insect repellency.
５〜１５重量％および炭素粉末５〜１５重量％を基材と
すると共に、蛇紋石粉末４０〜６０重量％、シリカ粉末
１０〜２０重量％およびチタン粉末５〜１５重量％を混
合材として前記基材に添加混合して、混合機および粉砕
機に順次複数回に亘って投入して、前記基材および混合
材を混合攪拌および粉砕して均一に混合し、然る後２０
０〜５００℃の仮焼温度で焼成機により焼成して得られ
た複合セラミックスを、和紙の製造工程中の紙漉き工程
において原材料中に添加混入することを特徴とする遠赤
外線放射特性、抗菌性、脱臭性、防カビ性および防虫性
を有すると共に、静電気防止効果を有する和紙の製造方
法。3. A method according to claim 2, wherein the base material is 3-7% by weight of amphibole powder, 5-15% by weight of magnesia powder and 5-15% by weight of carbon powder, 40-60% by weight of serpentine powder and 10-20% of silica powder. % And 5-15% by weight of titanium powder as a mixed material are added to and mixed with the base material, and charged into a mixer and a crusher several times sequentially to mix and stir and crush the base material and the mixed material. And mix evenly, then 20
Far infrared radiation characteristics, antibacterial properties, characterized in that the composite ceramics obtained by firing with a firing machine at a calcining temperature of 0 to 500 ° C is added and mixed into raw materials in a paper making process in a manufacturing process of Japanese paper. A method for producing Japanese paper having deodorizing properties, fungicidal properties and insect repellency, and having an antistatic effect.
４０〜６０重量％および炭素粉末５〜１５重量％を基材
とすると共に、シリカ粉末５〜１５重量％およびチタン
粉末２０〜３０重量％を混合材として前記基材に添加混
合して、混合機および粉砕機に順次複数回に亘って投入
して、前記基材および混合材を混合攪拌および粉砕して
均一に混合し、然る後２００〜５００℃の仮焼温度で焼
成機により焼成して得られた複合セラミックスを、和紙
の製造工程中の紙漉き工程において原材料中に添加混入
することを特徴とする遠赤外線放射特性、抗菌性、脱臭
性、防カビ性および防虫性を有すると共に、静電気防止
効果を有する和紙の製造方法。4. A base material comprising 3 to 7% by weight of amphibole powder, 40 to 60% by weight of magnesia powder and 5 to 15% by weight of carbon powder, 5 to 15% by weight of silica powder and 20 to 30% by weight of titanium powder. % As a mixed material, mixed and added to the base material sequentially, and charged into a mixer and a pulverizer several times sequentially, and the base material and the mixed material are mixed, agitated and pulverized, and uniformly mixed. Then, the composite ceramics obtained by calcining at a calcining temperature of 200 to 500 ° C. by a calcining machine is added and mixed into raw materials in a paper making process in a Japanese paper manufacturing process. A method for producing Japanese paper, which has deodorizing properties, fungicidal properties and insect repellency, and has an antistatic effect.
末２５〜３５重量％および炭素粉末３〜７重量％を基材
とすると共に、花崗斑石粉末４０〜６０重量％およびチ
タン粉末３〜７重量％を混合材として前記基材に添加混
合して、混合機および粉砕機に順次複数回に亘って投入
して、前記基材および混合材を混合攪拌および粉砕して
均一に混合し、然る後２００〜５００℃の仮焼温度で焼
成機により焼成して得られた複合セラミックスを、和紙
の製造工程中の紙漉き工程において原材料中に添加混入
することを特徴とする遠赤外線放射特性、抗菌性、脱臭
性、防カビ性および防虫性を有すると共に、静電気防止
効果を有する和紙の製造方法。5. A composition comprising 5 to 15% by weight of amphibole powder, 25 to 35% by weight of magnesia powder and 3 to 7% by weight of carbon powder, 40 to 60% by weight of granite stone powder and titanium powder 3 ７7% by weight as a mixed material is added to and mixed with the base material, and charged into a mixer and a pulverizer several times sequentially to mix and stir and pulverize the base material and the mixed material to mix uniformly. A far-infrared radiation characteristic characterized in that the composite ceramics obtained by calcining at a calcining temperature of 200 to 500 ° C. is added to raw materials in a paper making process in a manufacturing process of Japanese paper. A method for producing washi having antibacterial, deodorizing, antifungal and insect repellent properties and having an antistatic effect.
２０〜３０重量％および炭素粉末３〜７重量％を基材と
すると共に、石英閃緑石粉末４０〜６０重量％、シリカ
粉末５〜１５重量％およびチタン粉末３〜７重量％を混
合材として前記基材に添加混合して、混合機および粉砕
機に順次複数回に亘って投入して、前記基材および混合
材を混合攪拌および粉砕して均一に混合し、然る後２０
０〜５００℃の仮焼温度で焼成機により焼成して得られ
た複合セラミックスを、和紙の製造工程中の紙漉き工程
において原材料中に添加混入することを特徴とする遠赤
外線放射特性、抗菌性、脱臭性、防カビ性および防虫性
を有すると共に、静電気防止効果を有する和紙の製造方
法。6. A base material comprising 3 to 7% by weight of amphibole powder, 20 to 30% by weight of magnesia powder and 3 to 7% by weight of carbon powder, 40 to 60% by weight of quartz diorite powder and 5 to 5% of silica powder. 15% by weight and 3 to 7% by weight of titanium powder are added and mixed as a mixed material to the base material, and the mixture is put into a mixer and a crusher several times sequentially to mix and stir the base material and the mixed material. Crush and mix evenly, then 20
Far infrared radiation characteristics, antibacterial properties, characterized in that the composite ceramics obtained by firing with a firing machine at a calcining temperature of 0 to 500 ° C is added and mixed into raw materials in a paper making process in a manufacturing process of Japanese paper. A method for producing Japanese paper having deodorizing properties, fungicidal properties and insect repellency, and having an antistatic effect.
粉末４０〜６０重量％および炭素粉末３〜７重量％を基
材とすると共に、チタン粉末１５〜２５重量％を混合材
として前記基材に添加混合して、混合機および粉砕機に
順次複数回に亘って投入して、前記基材および混合材を
混合攪拌および粉砕して均一に混合し、然る後２００〜
５００℃の仮焼温度で焼成機により焼成して得られた複
合セラミックスを、和紙の製造工程中の紙漉き工程にお
いて原材料中に添加混入することを特徴とする遠赤外線
放射特性、抗菌性、脱臭性、防カビ性および防虫性を有
すると共に、静電気防止効果を有する和紙の製造方法。7. A base material comprising 20 to 30% by weight of amphibole powder, 40 to 60% by weight of magnesia powder and 3 to 7% by weight of carbon powder and 15 to 25% by weight of titanium powder as a mixed material. The mixture is added to a mixer and a crusher several times sequentially, and the base material and the mixed material are mixed and stirred and crushed to be uniformly mixed.
The far-infrared radiation property, antibacterial property and deodorizing property, characterized in that the composite ceramics obtained by calcining at a calcining temperature of 500 ° C by a calciner is added to and mixed with raw materials in the paper making process of the manufacturing process of Japanese paper. , A method for producing Japanese paper having antifungal properties and antifungal properties.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20105197A JPH1136189A (en) | 1997-07-11 | 1997-07-11 | Japanese paper having far infrared radiation characteristic, antimicrobial, deodorizing, mildewproof and insect repellent property and further antistatic property and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20105197A JPH1136189A (en) | 1997-07-11 | 1997-07-11 | Japanese paper having far infrared radiation characteristic, antimicrobial, deodorizing, mildewproof and insect repellent property and further antistatic property and its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH1136189A true JPH1136189A (en) | 1999-02-09 |
Family
ID=16434593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20105197A Pending JPH1136189A (en) | 1997-07-11 | 1997-07-11 | Japanese paper having far infrared radiation characteristic, antimicrobial, deodorizing, mildewproof and insect repellent property and further antistatic property and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH1136189A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100501743B1 (en) * | 2002-06-04 | 2005-07-18 | 관 모 이 | Yellow soil, mineral compound Korean paper and texture combined multi purpose functional sheet |
| KR20220080452A (en) * | 2020-12-07 | 2022-06-14 | 대덕산업(주) | A manufacturing method for food storage container maintaining freshness |
-
1997
- 1997-07-11 JP JP20105197A patent/JPH1136189A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100501743B1 (en) * | 2002-06-04 | 2005-07-18 | 관 모 이 | Yellow soil, mineral compound Korean paper and texture combined multi purpose functional sheet |
| KR20220080452A (en) * | 2020-12-07 | 2022-06-14 | 대덕산업(주) | A manufacturing method for food storage container maintaining freshness |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BRPI0610153A2 (en) | silver based inorganic antimicrobial agent, and antimicrobial product. | |
| KR102051622B1 (en) | Method For preparing Inorganic Antimicrobial And Inorganic Antimicrobial Prepared By The Same Method | |
| CN106189864B (en) | A kind of plant fiber wall clothing coating with antibacterial and antimildew function | |
| JPH09209225A (en) | Production of processed yarn spun by blending or twisting milk protein fiber with composite rayon fiber having antimicrobial, deodorizing and insecticidal properties and further having far infrared light radiation characteristic | |
| JPH1136189A (en) | Japanese paper having far infrared radiation characteristic, antimicrobial, deodorizing, mildewproof and insect repellent property and further antistatic property and its production | |
| JP2836020B2 (en) | Process for producing a processed yarn in which a composite rayon and silk fiber having anti-bacterial, deodorizing, mold-proof and insect-proof properties and far-infrared radiation properties are mixed or twisted and spun. | |
| JP2879024B2 (en) | A method for producing rayon having far-infrared radiation properties, antibacterial properties, deodorizing properties, fungicidal properties and insect repellency, and having an antistatic effect | |
| JPH1143896A (en) | Wastern style paper having antistatic effect as well as far-infrared radiation, antimicrobial, deodorant, fungicidal and insecticidal properties and its production | |
| JPH10167803A (en) | Composite ceramics having antibacterial, deodorizing, antimold and mothproof properties as well as far infrared ray radiating characteristic and its production | |
| JP2579600B2 (en) | Method for producing rayon having antibacterial properties and deodorizing properties and having far-infrared radiation characteristics | |
| JP2002308665A (en) | Composite material capable of generating negative ion, and fibrous product, sheetlike material and pottery using the same composite material | |
| JP2822321B2 (en) | Composite ceramics having anti-bacterial, deodorizing, mold-proofing and insect-proofing properties while having far-infrared radiation characteristics, and method for producing the same | |
| JP2920123B2 (en) | A method for producing a paint having far-infrared radiation properties, antibacterial properties, deodorizing properties, fungicidal properties and insect repellency, and having an antistatic effect | |
| KR20120089384A (en) | a cushion for pets comprising functional materials and manufacturing method thereof functional materials | |
| JPH09170110A (en) | Production of rayon having far-infrared-radiation characteristic as well as antimicrobial effect, deodorizing ability and insectproofness | |
| JPH0598564A (en) | Production of fiber structure having deodorizing and antibacterial property | |
| KR20070012284A (en) | Bio ceramic and bio ceramic adhesives | |
| KR930008252B1 (en) | Preparation of polypropylene filament non-woven fabric having superior antibacterial deodorant and infrared ray radial property | |
| JP2000080008A (en) | Inorganic antimicrobial and fungicidal agent, antimicrobial resin composition and antimicrobial resin product | |
| JP2794627B2 (en) | Bed pat | |
| JP2873196B2 (en) | Wood block having far-infrared radiation properties, antibacterial property, deodorizing property, fungicidal property and insect repellent property, and processing method thereof | |
| KR100416075B1 (en) | A manufacturing process of a architecture structural ocher mixture | |
| JP2002348776A (en) | Fabric material excellent in heat retaining property or the like | |
| JP2847633B2 (en) | Wood chips having far-infrared radiation properties and having antibacterial, deodorant, mold-proof and insect-proof properties, and a processing method therefor | |
| JPH0598506A (en) | Production of fiber having deodorizing and antimicrobial property |