JPH11342578A - Decorative material and manufacture thereof - Google Patents
Decorative material and manufacture thereofInfo
- Publication number
- JPH11342578A JPH11342578A JP15016598A JP15016598A JPH11342578A JP H11342578 A JPH11342578 A JP H11342578A JP 15016598 A JP15016598 A JP 15016598A JP 15016598 A JP15016598 A JP 15016598A JP H11342578 A JPH11342578 A JP H11342578A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- decorative
- transfer
- sheet
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、家具、住宅機器、
内外装材等に用いられる絵付けのための化粧材およびそ
の製造方法に関するものである。The present invention relates to furniture, housing equipment,
The present invention relates to a decorative material for painting used for interior and exterior materials and the like, and a method for producing the same.
【０００２】[0002]
【従来の技術】従来、化粧板への絵付け方法としては、
化粧シートラミネート法や転写法があったが、化粧板と
同面積のプラスチックフィルム等の基材シートが必要で
あった。とくに転写法では、転写後剥離された基材シー
トは廃棄物となるので、資源保護や環境保護の観点から
も問題があった。2. Description of the Related Art Conventionally, as a method of painting a decorative plate,
Although there were a decorative sheet laminating method and a transfer method, a substrate sheet such as a plastic film having the same area as the decorative plate was required. In particular, in the transfer method, since the substrate sheet peeled off after the transfer becomes a waste, there is a problem from the viewpoint of resource protection and environmental protection.
【０００３】基材シートを使用しない絵付け方法として
は、例えば砂、木粉などの粉粒体を散布する方法や、イ
ンキジェット方式やグラビアオフセット方式などで基材
上に直接印刷する方法などがあるが、いずれも精密な絵
柄の付与には不向きであり、生産性や品質安定性等の問
題があって、必ずしも十分満足すべきものではなかっ
た。[0003] As a painting method without using a base sheet, for example, a method of spraying particles such as sand and wood powder, a method of directly printing on a base material by an ink jet method, a gravure offset method, and the like are exemplified. However, none of them are suitable for providing a precise picture, and there are problems such as productivity and quality stability, and they have not always been satisfactory.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、以上のよう
な問題点に着目してなされたもので、特に化粧材の転写
層を被転写基材上に転写後、転写層から剥離して残存し
た非転写層の装飾層を有する基材シートを化粧シートと
して有効利用できる化粧材およびその製造方法を提供す
ることを目的とする。SUMMARY OF THE INVENTION The present invention has been made in view of the above problems. In particular, the present invention is intended to remove the transfer layer of a decorative material from a transfer layer after transferring the transfer layer onto a substrate to be transferred. An object of the present invention is to provide a decorative material that can effectively use a base sheet having a remaining non-transfer layer decorative layer as a decorative sheet and a method for producing the same.
【０００５】[0005]
【課題を解決するための手段】請求項１記載の発明は、
基材シートの少なくとも片面に設けた非転写性の装飾層
と、基材シートの片面に転写層とを設けたことを特徴と
する化粧材である。According to the first aspect of the present invention,
A decorative material comprising: a non-transferable decorative layer provided on at least one side of a base sheet; and a transfer layer provided on one side of the base sheet.
【０００６】請求項２記載の発明は、請求項１記載の化
粧材の転写層を被転写基材上に転写してなる化粧材であ
る。According to a second aspect of the present invention, there is provided a decorative material obtained by transferring a transfer layer of the decorative material according to the first aspect onto a substrate to be transferred.
【０００７】請求項３記載の発明は、化粧材の転写層を
被転写基材上に転写後、転写層から剥離して残存した非
転写性の装飾層を有する基材シートを基板上に積層して
なる化粧材である。According to a third aspect of the present invention, after a transfer layer of a decorative material is transferred onto a substrate to be transferred, a substrate sheet having a non-transferable decorative layer which is peeled off from the transfer layer and remains is laminated on the substrate. It is a cosmetic material made of.
【０００８】請求項４記載の発明は、請求項２または３
記載の化粧材において、表面に透明保護層を有すること
を特徴とする。The invention according to claim 4 is the invention according to claim 2 or 3.
The decorative material according to any one of the preceding claims, further comprising a transparent protective layer on the surface.
【０００９】請求項５記載の発明は、請求項１記載の化
粧材を使用して、その転写層を被転写基材上に転写して
第１の化粧材を製造した後、転写層から剥離して残存し
た非転写性の装飾層を有する基材シートを基板上に積層
して第２の化粧材を製造することを特徴とする化粧材の
製造方法である。According to a fifth aspect of the present invention, a first decorative material is manufactured by transferring the transfer layer onto a substrate to be transferred using the decorative material according to the first aspect, and then peeling off the transfer layer. A second decorative material is produced by laminating a base sheet having a non-transferable decorative layer remaining on the substrate, and producing a second decorative material.
【００１０】[0010]
【発明の実施の形態】以下、本発明の実施の形態につき
図に基づいて詳細に説明する。図１は、本発明の化粧材
の構成の一例である。転写層３および非転写性の装飾層
４を、互いに基材シート２の反対面側に設けた化粧材１
である。DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the present invention will be described below in detail with reference to the drawings. FIG. 1 is an example of the configuration of the decorative material of the present invention. Cosmetic material 1 in which transfer layer 3 and non-transferable decorative layer 4 are provided on opposite sides of base sheet 2
It is.
【００１１】基材シートとしては、とくに限定されるも
のはない。熱転写の場合には、転写温度で融解しない材
質の基材シートを使用する必要がある。汎用上、ポリエ
ステル系シート、ポリオレフィン系シート、ポリ塩化ビ
ニル系シート、また剥離層を有した紙などが挙げられ
る。シートの厚さは特に限定されるものではなく、透明
および不透明い何れでもよい。また、剥離後残存した非
転写性の装飾層を有する基材シートは化粧シートとして
用いられるため、耐候性を向上させる意味で、紫外線に
よる劣化を低減するための紫外線吸収剤もしくは光安定
剤を添加してもよい。それぞれ量的に限定されるもので
はない。The base sheet is not particularly limited. In the case of thermal transfer, it is necessary to use a base sheet made of a material that does not melt at the transfer temperature. For general purposes, polyester-based sheets, polyolefin-based sheets, polyvinyl chloride-based sheets, and papers having a release layer can be used. The thickness of the sheet is not particularly limited, and may be transparent or opaque. In addition, since the base sheet having a non-transferable decorative layer remaining after peeling is used as a decorative sheet, an ultraviolet absorber or a light stabilizer for reducing deterioration due to ultraviolet rays is added in order to improve weather resistance. May be. Each is not limited in quantity.
【００１２】基材シートを特に透明なものを用いた場合
には、転写層と基材シートとの間にフッ素系樹脂層もし
くはシリコン系樹脂層といった層を設ければ、転写層を
転写する場合、被転写基材への転移性を向上させること
ができる。こうして第１の化粧板を得た後に、残りの非
転写性の装飾層を有する基材シートを接着基材へ貼り合
わせ第２の化粧板を作製すれば、第２の化粧板は表面が
フッ素系樹脂層もしくはシリコン系樹脂層となり耐汚染
性に優れたものになる。後述でも示すが、転写層が転写
ができるのであれば、前述のフッ素系樹脂、シリコン系
樹脂に限らず、例えば熱硬化型樹脂、紫外線硬化型樹
脂、電離放射線硬化型樹脂等からなる層を設ければ、第
２の化粧板は耐汚染性、耐磨耗性に優れたものになる。When a particularly transparent base material sheet is used, if a layer such as a fluorine-based resin layer or a silicon-based resin layer is provided between the transfer layer and the base sheet, the transfer layer can be transferred. In addition, transferability to the transfer substrate can be improved. After the first decorative board is thus obtained, the base sheet having the remaining non-transferable decorative layer is adhered to the adhesive base material to produce the second decorative board. It becomes a system-based resin layer or a silicon-based resin layer, and has excellent contamination resistance. As will be described later, provided that the transfer layer can transfer, a layer made of, for example, a thermosetting resin, an ultraviolet-curing resin, an ionizing radiation-curing resin, or the like is not limited to the above-described fluorine-based resin and silicon-based resin. Then, the second decorative board becomes excellent in stain resistance and abrasion resistance.
【００１３】また、基材シートが透明、不透明にかかわ
らず、非転写性の装飾層の表面にさらに透明性の熱硬化
型樹脂、フッ素系樹脂もしくはシリコン系樹脂、紫外線
硬化型樹脂、電離放射線硬化型樹脂等からなる層を設け
れば、転写層を転写させ第１の化粧板を得た後、残りの
非転写性の装飾層を有する基材シートの基材側を被接着
基材に接着させて得られる第２の化粧板は、表面が透明
性の熱硬化型樹脂、フッ素系樹脂もしくはシリコン系樹
脂、紫外線硬化型樹脂、電離放射線硬化型樹脂等からな
る層となり耐汚染性、耐磨耗性等に優れたものになる。Regardless of whether the base material sheet is transparent or opaque, the surface of the non-transferable decorative layer is further provided with a transparent thermosetting resin, fluorine resin or silicone resin, ultraviolet curing resin, ionizing radiation curing. If a layer made of a mold resin or the like is provided, the transfer layer is transferred to obtain a first decorative plate, and then the base material side of the base sheet having the remaining non-transferable decorative layer is bonded to the base material to be bonded. The second decorative plate obtained by the above-mentioned process becomes a layer made of a thermosetting resin, a fluororesin or a silicon resin, an ultraviolet curing resin, an ionizing radiation curing resin, etc., whose surface is transparent, and has a stain resistance, abrasion resistance. It becomes excellent in abrasion and the like.
【００１４】転写層を形成するには、方式は特に限定さ
れない。単色や単純な絵柄層である場合には、コータ
ー、例えばグラビアコーター、ナイフコーター、コンマ
コーター、ブレードコーターなどで行ってもよい。ま
た、砂や木粉といった粉粒体の散布、インクジェット
法、グラビアオフセット法、蒸着による方法や噴霧によ
る方法などで行ってもよい。さらには、高意匠で複雑な
絵柄を施すには、グラビア印刷、スクリーン印刷、オフ
セット印刷が好適である。The method for forming the transfer layer is not particularly limited. In the case of a single color or simple pattern layer, the coating may be performed with a coater, for example, a gravure coater, a knife coater, a comma coater, a blade coater, or the like. Further, it may be carried out by spraying powders such as sand or wood powder, an inkjet method, a gravure offset method, a method by vapor deposition, a method by spraying, or the like. Further, gravure printing, screen printing, and offset printing are suitable for applying a complicated design with a high design.
【００１５】転写層として用いられるインキおよび樹脂
は、特に限定されるものではない。基材シートとの相性
から剥離しやすいものを選定する、あるいは剥離層をシ
ートと絵柄層との間に設けた転写層を形成するなどの方
法が考えられる。さらには、転写層として、剥離層、化
粧板となったときのための表面保護層、絵柄層、接着剤
層といったように複合させた転写層を形成することも可
能である。The ink and resin used as the transfer layer are not particularly limited. A method is conceivable in which a material which is easily peeled off from the compatibility with the base sheet is selected, or a transfer layer in which a release layer is provided between the sheet and the picture layer is formed. Further, as the transfer layer, it is also possible to form a composite transfer layer such as a release layer, a surface protective layer for a decorative plate, a picture layer, an adhesive layer, and the like.
【００１６】剥離層は必要に応じて設けられるものであ
って、その材質は特に限定されるものではなく、基材シ
ートから容易に剥離可能な皮膜層を形成できる材質であ
ればよい。例えば、後述の非転写性の装飾層に用いられ
るバインダーや、易剥離性のシリコン系樹脂、フッ素系
樹脂、オレフィン系樹脂、アクリル系樹脂、ビニル系樹
脂、メラミン系樹脂、繊維素誘導体、塩化ゴム、環化ゴ
ム等からなる基材シートとの相性に応じ適当なものを選
んで使用すればよい。The release layer is provided as needed, and the material is not particularly limited as long as it can form a coating layer that can be easily peeled from the base sheet. For example, a binder used for a non-transferable decorative layer described later, an easily peelable silicone resin, a fluorine resin, an olefin resin, an acrylic resin, a vinyl resin, a melamine resin, a cellulose derivative, and a chlorinated rubber Any suitable material may be selected and used according to the compatibility with the base sheet made of cyclized rubber or the like.
【００１７】表面保護層も必要に応じて設けられるもの
であって、例えばウレタン系樹脂、アクリル系樹脂、メ
ラミン系樹脂、エポキシ系樹脂、ポリエステル系樹脂、
繊維素誘導体、紫外線硬化型樹脂、電離放射線硬化型樹
脂等を塗工する、もしくはオレフィン系樹脂、ポリエス
テル系樹脂、アクリル系樹脂、ビニル系樹脂、フッ素系
樹脂、シリコン系樹脂からなるフィルムを貼り合わせる
等の方法で設けることができる。The surface protective layer is also provided as needed, and may be, for example, a urethane resin, an acrylic resin, a melamine resin, an epoxy resin, a polyester resin,
Apply cellulose derivative, ultraviolet curable resin, ionizing radiation curable resin, etc., or attach a film made of olefin resin, polyester resin, acrylic resin, vinyl resin, fluorine resin, or silicon resin. And the like.
【００１８】非転写性の装飾層としては、用いられるイ
ンキおよびバインダー樹脂は特に限定されるものではな
く、基材シートとインキまたはバインダー樹脂とを考慮
して適宜選定すればよい。ただし、剥離層と異なり、基
材と接着するため密着は十分でなければならない。もし
くは、基材をコロナ処理、プライマー処理といった表面
処理を行うことで密着性を向上させる方法をとってもよ
い。樹脂としては、例えばフッ素系樹脂、アクリル系樹
脂、ポリ塩化ビニル系樹脂、アルキッド系樹脂、ポリア
ミド系樹脂、ポリエステル系樹脂、ポリ塩化ビニル系樹
脂、ポリ酢酸ビニル系樹脂、繊維素系樹脂などやそれぞ
れの混合系の樹脂、あるいは共重合物などがあげられ
る。また、その凝集力からポリエステルポリオールをバ
インダーとしたインキがよく、イソシアネートで架橋さ
せることでさらに凝集力を向上させることが可能であ
る。さらに、非転写性の装飾層は接着剤を介して基材に
接着される場合があり、接着剤層は、転写基材へ接着剤
を塗布する工程を省く意味で設けても良い。特に限定さ
れるものではなく、ウレタン系ホットメルト型接着剤な
ど必要に応じて用いればよい。接着剤によっては、所定
の密着性が発現しない場合があるので選定には注意を要
する。転写層の転写後に、非転写性の装飾層を有する基
材シートの基材側側を被接着基材に接着する場合には、
非転写性の装飾層上にあらかじめ透明保護層を設けてお
くこともできる。The ink and binder resin used as the non-transferable decorative layer are not particularly limited, and may be appropriately selected in consideration of the base sheet and the ink or binder resin. However, unlike the release layer, the adhesion must be sufficient to adhere to the substrate. Alternatively, a method of improving the adhesion by performing a surface treatment such as a corona treatment and a primer treatment on the base material may be adopted. Examples of the resin include a fluorine resin, an acrylic resin, a polyvinyl chloride resin, an alkyd resin, a polyamide resin, a polyester resin, a polyvinyl chloride resin, a polyvinyl acetate resin, a cellulose resin, and the like. And a resin or a copolymer thereof. In addition, an ink using a polyester polyol as a binder is preferable based on its cohesion, and the cohesion can be further improved by crosslinking with an isocyanate. Further, the non-transferable decorative layer may be adhered to the base material via an adhesive, and the adhesive layer may be provided in a way that the step of applying the adhesive to the transfer base material is omitted. There is no particular limitation, and a urethane-based hot-melt adhesive or the like may be used as needed. Care must be taken in selection, as certain adhesives may not exhibit the desired adhesion. After the transfer of the transfer layer, when bonding the substrate side of the substrate sheet having a non-transfer decoration layer to the substrate to be adhered,
A transparent protective layer may be provided in advance on the non-transferable decorative layer.
【００１９】転写の方法は、公知のロール転写法もしく
はプレス板での圧着法で可能である。ロール転写の場合
では、転写された後のシートはいったん巻き取っても良
いし、インラインで別の基材に貼りあわせても良い。剥
離後のシートは転写性が十分であればよいが、一部転写
せずにシートに残る場合がある。この場合、溶剤を塗工
してふき取る必要がある。The transfer can be performed by a known roll transfer method or a pressure bonding method using a press plate. In the case of roll transfer, the sheet after the transfer may be wound once, or may be bonded inline to another substrate. It is sufficient that the sheet after peeling has sufficient transferability, but the sheet may remain on the sheet without being partially transferred. In this case, it is necessary to apply a solvent and wipe off.
【００２０】本発明の化粧材は枚葉で使用する場合は問
題ないが、紙管に巻き取る場合にはシートの自重および
巻き取り後の積みおきのために、転写層と非転写性の装
飾層がブロッキングする場合がある。そのためには、メ
ラミン系やアミノアルキド系等の速乾性インキや、紫外
線または電離放射線硬化型インキを使用する、何れかの
インキもしくは両方のインキ、または樹脂層にブロッキ
ング防止となるシリカなどの粉体を添加する、あるい
は、耐ブロッキング性のためのシートまたは紙を同時に
巻く、といった方策が挙げられる。The decorative material of the present invention is not problematic when used as a single sheet, but when wound up on a paper tube, the transfer layer and the non-transferable decoration are used due to the weight of the sheet and stacking after winding. Layers may block. To do so, use a quick-drying ink such as a melamine-based or aminoalkyd-based ink, or an ultraviolet or ionizing radiation-curable ink, either ink or both inks, or a powder such as silica that prevents blocking in the resin layer. Or simultaneously winding a sheet or paper for blocking resistance.
【００２１】図２は、本発明の化粧材の他の例である。
基材シート１１の片面に、非転写性の装飾層１３と転写
層１２とをこの順に積層して設けた例の化粧材１０を示
した断面図である。 ロール圧着または平板プレスによ
って、被転写基材に転写層１２が転写され、非転写性の
装飾層１３が残るような構成であればとくに限定されな
い。非転写性の装飾層１３と転写層１２との層間の密着
強度は、転写後の転写層と被転写基材との密着性に比べ
小さければよい。必要に応じて、剥離層を非転写性の装
飾層１３と転写層１２との間に設けてもよい。さらに
は、非転写性の装飾層１３と転写層１２との層間に表面
保護層を設けることによって、離型層または板貼り後の
表面保護層となり得る。FIG. 2 shows another example of the decorative material of the present invention.
FIG. 3 is a cross-sectional view showing a decorative material 10 of an example in which a non-transferable decorative layer 13 and a transfer layer 12 are laminated on one surface of a base sheet 11 in this order. The configuration is not particularly limited as long as the transfer layer 12 is transferred to the transfer target substrate by the roll press bonding or the flat plate press, and the non-transferable decorative layer 13 remains. The adhesive strength between the non-transferable decorative layer 13 and the transfer layer 12 may be smaller than the adhesive strength between the transfer layer after transfer and the substrate to be transferred. If necessary, a release layer may be provided between the non-transferable decorative layer 13 and the transfer layer 12. Further, by providing a surface protective layer between the non-transferable decorative layer 13 and the transfer layer 12, the surface protective layer can be a release layer or a surface protective layer after sticking on a plate.
【００２２】さらに、本発明の化粧材の構成は、片面だ
けでなく両面に非転写性の装飾層を設けたり、上記以外
の構成が可能であり、特に限定されるものではない。Further, the configuration of the decorative material of the present invention is not particularly limited, and a non-transferable decorative layer may be provided on both sides as well as on one side, and a configuration other than those described above is possible.
【００２３】[0023]
【実施例】以下実施例によって本発明を詳細に説明す
る。 ＜実施例１＞厚さ12μm の２軸延伸ポリエチレンテレフ
タレートシート（東洋紡績（株）製：Ｅ５１０２）にコ
ロナ処理を施し、２液硬化型ウレタン系樹脂をバインダ
ーとしたインキで絵柄印刷を行った後に、１００℃で２
４ｈ乾燥し、裏面に無処理のままポリビニルブチラール
系インキ（大日精化工業（株）製）を転写インキ層とし
て塗工した。一方、珪酸カルシウム板に接着剤を塗布乾
燥後、この化粧材の転写インキ層をロール転写によっ
て、珪酸カルシウム板に転写させて、シートを剥がした
ところ、転写が十分であった。この意匠面を保護する意
味で、紫外線硬化型樹脂（セイカビームＷＴ−ＹＩ：大
日精化工業（株）製）をコートし紫外線で硬化させ第１
の化粧板を得た。さらに、別に中質繊維板（以後「ＭＤ
Ｆ」と呼ぶ）へエマルジョン系接着剤（ＢＡ−５３：中
央理化工業（株）製）を塗工し、インキ面が接着剤側に
なるように圧締したところ、透明シートがインキ保護層
となる高意匠性の第２の化粧板を得た。このようにして
得られたそれぞれの化粧板は、高意匠を有したものであ
り実用上も優れたものであった。The present invention will be described in detail with reference to the following examples. <Example 1> A biaxially stretched polyethylene terephthalate sheet (E5102 manufactured by Toyobo Co., Ltd .: E5102) having a thickness of 12 µm was subjected to corona treatment, followed by pattern printing with an ink using a two-component curable urethane resin as a binder. 2 at 100 ° C
After drying for 4 h, a polyvinyl butyral-based ink (manufactured by Dainichi Seika Kogyo Co., Ltd.) was applied as a transfer ink layer on the back surface without any treatment. On the other hand, after applying and drying the adhesive on the calcium silicate plate, the transfer ink layer of this decorative material was transferred to the calcium silicate plate by roll transfer, and the sheet was peeled off. The transfer was sufficient. In order to protect the design surface, an ultraviolet curable resin (Seika Beam WT-YI: manufactured by Dainichi Seika Kogyo Co., Ltd.) is coated and cured with ultraviolet light to form a first resin.
Was obtained. In addition, a medium fiberboard (hereinafter referred to as "MD
F) was coated with an emulsion-based adhesive (BA-53: manufactured by Chuo Rika Kogyo Co., Ltd.) and pressed so that the ink surface was on the adhesive side. A highly decorative second decorative plate was obtained. Each decorative plate obtained in this manner had a high design and was practically excellent.
【００２４】＜実施例２＞厚さ７５μm のポリプロピレ
ン系シートにコロナ処理を施し、２液硬化型ウレタン系
樹脂をバインダーとしたインキで絵柄印刷をグラビアで
行い、剥離層としてシリコン系樹脂を噴霧塗布した後、
７０℃で７２ｈ乾燥し、そのシリコン系樹脂上にポリウ
レタン系樹脂をバインダーとしたインキを塗工した。一
方、ＭＤＦに目止め剤、接着剤の順にそれぞれ塗工後８
０℃１ｍｉｎの乾燥後、ロール転写によって、この化粧
材の転写インキ層をＭＤＦに転写させて、シートを剥が
したところ、転写が十分でありかつ非転写性の装飾層で
ある絵柄インキは残存シートに残った。転写によって得
られた化粧板の意匠面を保護する意味で、アクリルポリ
オール（ＵＲＶ２８３：東洋インキ製造（株）製）をＴ
ＤＩ系イソシアネート（ＨＡＲＤＮＥＲＴ−７５：日本
ポリウレタン（株）製）で架橋させた樹脂をコートし、
第１の化粧板を得た。残存したシートの柄のない方の面
に接着性を向上させるためにコロナ処理を施し、濡れ指
数を40dyne/cm 以上となるようにした。さらに、ＭＤＦ
へエマルジョン系接着剤（BA-53 ：中央理化工業（株）
製）を塗工し、転写後得られたシートの柄層が表となる
ように接着を行い、第２の化粧板を得た。以上のように
して得られた２種類の化粧板はともに高意匠のものであ
り、実用上も問題のないものであった。Example 2 A polypropylene sheet having a thickness of 75 μm is subjected to a corona treatment, a pattern is printed by gravure with an ink using a two-component curable urethane resin as a binder, and a silicone resin is spray-coated as a release layer. After doing
After drying at 70 ° C. for 72 hours, an ink using a polyurethane-based resin as a binder was applied onto the silicon-based resin. On the other hand, after application to MDF in order of filler and adhesive, 8
After drying at 0 ° C. for 1 min, the transfer ink layer of this cosmetic material was transferred to MDF by roll transfer, and the sheet was peeled off. The pattern ink, which was a sufficient transfer and non-transferable decorative layer, was a residual sheet. Remained. Acrylic polyol (URV283: manufactured by Toyo Ink Mfg. Co., Ltd.) was used to protect the decorative surface of the decorative plate obtained by transfer.
Coating a resin cross-linked with DI-based isocyanate (HARDNERT-75: manufactured by Nippon Polyurethane Co., Ltd.)
A first decorative panel was obtained. Corona treatment was applied to the surface of the remaining sheet having no handle to improve the adhesiveness, so that the wetting index was 40 dyne / cm or more. Furthermore, MDF
He-emulsion adhesive (BA-53: Chuo Rika Kogyo Co., Ltd.)
Was applied so that the pattern layer of the sheet obtained after the transfer became the front surface, and a second decorative plate was obtained. The two types of decorative boards obtained as described above were both of high design and had no practical problems.
【００２５】＜実施例３＞厚さ５０μm のポリプロピレ
ンシート（二村化学工業（株）製）にコロナ処理を施
し、２液硬化型ウレタン系樹脂をバインダーとしたイン
キ（ラミスター：東洋インキ製造（株）製）で絵柄印刷
を行った後に、１００℃で２４ｈ乾燥し、裏面に無処理
のまま１液ウレタン系インキ（ラミスター：東洋インキ
製造（株）製）を転写インキ層として塗工した。一方、
鋼板に接着剤を塗布乾燥後、ロール転写によってこの化
粧材の転写インキ層を鋼板に転写させてシートを剥がし
たところ、転写が十分であった。この意匠面を保護する
意味で、１２μm ポリエチレンテレフタレートシートを
積層し、第１の化粧板を得た。さらに、転写後のシート
を鋼板へウレタン系接着剤（Ａ−３２１０：武田薬品工
業（株）製）を塗工し、インキ面が接着剤側になるよう
に圧締したところ、透明シートがインキ保護層となる高
意匠性の第２の化粧板を得た。以上のようにして得られ
た２種類の化粧板はともに高意匠のものであり、実用上
も問題のないものであった。<Example 3> An ink (Lamister: Toyo Ink Mfg. Co., Ltd.) using a 50-μm-thick polypropylene sheet (manufactured by Nimura Chemical Industry Co., Ltd.) subjected to corona treatment and using a two-component curable urethane resin as a binder Was printed at 100 ° C. for 24 hours, and a one-liquid urethane-based ink (Lamister: manufactured by Toyo Ink Mfg. Co., Ltd.) was applied as a transfer ink layer on the back surface without any treatment. on the other hand,
After applying and drying the adhesive on the steel sheet, the transfer ink layer of the decorative material was transferred to the steel sheet by roll transfer, and the sheet was peeled off. The transfer was sufficient. In order to protect the design surface, a 12 μm polyethylene terephthalate sheet was laminated to obtain a first decorative panel. Further, the sheet after transfer was coated with a urethane-based adhesive (A-3210: manufactured by Takeda Pharmaceutical Co., Ltd.) on a steel plate, and was pressed so that the ink surface was on the adhesive side. A highly decorative second decorative plate serving as a protective layer was obtained. The two types of decorative boards obtained as described above were both of high design and had no practical problems.
【００２６】＜実施例４＞厚さ９０μm の透明ポリ塩化
ビニルシート（理研ビニル工業（株）製）の片面に、塩
化ビニル酢酸ビニル共重合系インキ（ＶＣＧＴＫ：東洋
インキ製造（株）製）で絵柄印刷を行った後に、もう一
方の面に剥離層としてポリビニルブチラール系樹脂を塗
工し、さらに転写インキ層としてポリビニルブチラール
系インキで重ねてグラビア塗工した。一方、セメント板
に目止め剤および接着剤を塗布乾燥後、ロール転写によ
っての化粧材の転写インキ層を転写させてシートを剥が
したところ、転写が十分であった。この意匠面を保護す
る意味で、紫外線硬化型樹脂でコートを行い、第１の化
粧板を得た。さらに、転写後のシートをＭＤＦへエマル
ジョン系接着剤（ＣＶＣ−３６：コニシ（株）製）を塗
工し、インキ面が接着剤側になるように圧締したとこ
ろ、透明シートがインキ保護層となる高意匠性の第２の
化粧板を得た。以上のようにして得られた２種類の化粧
板はともに高意匠のものであり、実用上も問題のないも
のであった。Example 4 One side of a transparent polyvinyl chloride sheet (manufactured by Riken Vinyl Industry Co., Ltd.) having a thickness of 90 μm was coated with a vinyl chloride-vinyl acetate copolymer ink (VCGTK: manufactured by Toyo Ink Mfg. Co., Ltd.). After pattern printing, a polyvinyl butyral-based resin was applied to the other surface as a release layer, and the transfer ink layer was overlaid with a polyvinyl butyral-based ink, followed by gravure coating. On the other hand, after filling and drying the filler and the adhesive on the cement board, the transfer ink layer of the decorative material was transferred by roll transfer and the sheet was peeled off. As a result, transfer was sufficient. In order to protect this design surface, coating was performed with an ultraviolet curable resin to obtain a first decorative plate. Further, the sheet after the transfer was coated on the MDF with an emulsion adhesive (CVC-36: manufactured by Konishi Co., Ltd.) and pressed so that the ink surface was on the adhesive side. Thus, a highly decorative second decorative board was obtained. The two types of decorative boards obtained as described above were both of high design and had no practical problems.
【００２７】＜実施例５＞厚さ９０μm の透明ポリエチ
レンテレフタレートシート（パナック（株）製）の片面
に、ウレタン系インキ（ラミスター：東洋インキ製造
（株）製）でグラビア絵柄印刷を行った後に、もう一方
の面に剥離層としてポリビニルブチラール系樹脂を塗工
し、さらに転写インキ層としてポリビニルブチラール系
インキで重ねてグラビア塗工した。一方、セメント板に
目止め剤および接着剤を塗布乾燥後、プレス機にて圧締
を行いこの化粧材の転写インキ層をセメント板に転写さ
せてシートを剥がしたところ、転写が十分であった。こ
の意匠面を保護する意味で、紫外線硬化型樹脂でコート
を行い、第１の化粧板を得た。さらに、転写後のシート
を合板へエマルジョン系接着剤（ＣＶＣ−３６：コニシ
（株）製）を塗工し、インキ面が接着剤側になるように
圧締したところ、透明シートがインキ保護層となる高意
匠性の第２の化粧板を得た。以上のようにして得られた
２種類の化粧板はともに高意匠のものであり、実用上も
問題のないものであった。Example 5 A gravure pattern was printed on one surface of a transparent polyethylene terephthalate sheet (manufactured by Panac Co., Ltd.) having a thickness of 90 μm with a urethane-based ink (Lamister: manufactured by Toyo Ink Mfg. Co., Ltd.). On the other side, a polyvinyl butyral-based resin was applied as a release layer, and a transfer ink layer was further overlaid with polyvinyl butyral-based ink and gravure coated. On the other hand, after filling and drying the cement filler and the adhesive on the cement board, pressing was performed with a press machine, and the transfer ink layer of this decorative material was transferred to the cement board, and the sheet was peeled off. . In order to protect this design surface, coating was performed with an ultraviolet curable resin to obtain a first decorative plate. Further, the sheet after the transfer was coated on the plywood with an emulsion adhesive (CVC-36: manufactured by Konishi Co., Ltd.) and pressed so that the ink surface was on the adhesive side. Thus, a highly decorative second decorative board was obtained. The two types of decorative boards obtained as described above were both of high design and had no practical problems.
【００２８】＜実施例６＞厚さ９０μm の透明ポリエチ
レンテレフタレートシート（東洋紡績（株）製）の片面
に、転写層としてウレタン系インキ（ラミスター：東洋
インキ製造（株）製）でグラビア絵柄印刷を行った後、
巻き取った。その後、非印刷面にラミスターインキを印
刷しつつシリコン系樹脂をコートした紙を挟みながら、
巻き取った。この転写兼化粧シートの巻きに対して、鋼
板に接着剤を塗布乾燥後、ロール転写機にて圧延を行い
転写インキ層を転写させてシートを剥がしつつ第１の化
粧板を作製し、さらに剥がされたシートを接着剤を塗布
されたパーティクルボードへインキ面と貼りあわせ第２
の化粧板を得た。以上のようにして、連続で２枚の化粧
板を作製することができた。以上のようにして得られた
２種類の化粧板は高意匠性をもち、後コーティング等を
行うにも十分に足るものであった。またブロッキング防
止のために用いたシリコン系樹脂コート紙の効果で、巻
き自体がブロッキングすることもなかった。Example 6 A gravure picture print was made on one side of a transparent polyethylene terephthalate sheet (manufactured by Toyobo Co., Ltd.) having a thickness of 90 μm with a urethane-based ink (Lamister: manufactured by Toyo Ink Mfg. Co., Ltd.) as a transfer layer. After going,
Wound up. After that, while printing the ramister ink on the non-printing surface and sandwiching the paper coated with silicone resin,
Wound up. After applying and drying the adhesive on the steel sheet, the roll of the transfer / decorative sheet is rolled by a roll transfer machine to transfer the transfer ink layer, and the first decorative sheet is produced while peeling off the sheet. The bonded sheet is attached to the adhesive-coated particle board and the ink surface.
Was obtained. As described above, two decorative plates were continuously produced. The two types of decorative boards obtained as described above had high design properties and were sufficient for post-coating and the like. Further, the winding itself did not block due to the effect of the silicon-based resin-coated paper used for preventing blocking.
【００２９】＜実施例７＞着色ポリプロピレンフィルム
の片面に、絵柄印刷を行った後に表面保護の役割を果た
すアクリル系樹脂を塗工した。もう一方の面に転写層と
して、まず表面保護層として紫外線硬化型樹脂、アンカ
ー剤を塗工した後に塩化ビニル酢酸ビニル共重合体をバ
インダーとしたインキで転写絵柄層をグラビア方式で印
刷した。一方、ＭＤＦへ目止め剤および接着剤を順次噴
霧塗工し、このようにして得られた化粧材の転写面をＭ
ＤＦに転写させ第１の化粧板を得た。さらに、転写後の
シートを転写した面をＭＤＦとウレタン系接着剤で接着
し第２の化粧板を得た。以上のようにして得られた２種
類の化粧板は高意匠を有し、かつ表面保護層が化粧材に
設けられていたので、あらためて化粧板に表面保護層ま
たはトップコート層を設ける必要もなかった。Example 7 One side of a colored polypropylene film was coated with an acrylic resin which plays a role of protecting the surface after pattern printing. On the other side, as a transfer layer, first, a UV-curable resin and an anchor agent were applied as a surface protective layer, and then a transfer pattern layer was printed by a gravure method using an ink using a vinyl chloride-vinyl acetate copolymer as a binder. On the other hand, a filler and an adhesive are sequentially spray-coated on the MDF, and the transfer surface of the thus obtained decorative material is M
This was transferred to DF to obtain a first decorative board. Further, the surface on which the sheet after the transfer was transferred was bonded to MDF with a urethane-based adhesive to obtain a second decorative plate. Since the two types of decorative boards obtained as described above have a high design and the surface protective layer is provided on the decorative material, it is not necessary to provide a surface protective layer or a top coat layer on the decorative board again. Was.
【００３０】[0030]
【発明の効果】本発明の化粧材は、基材シートの片面ま
たは両面に非転写性の装飾層を有し、さらに該非転写性
の装飾層を有する基材シートの片面または両面に転写層
を有する構成であるため、転写および化粧シートの２種
類の機能を併せ持ったものであり、コスト的にも資源的
にも有効利用できる。転写による第１の化粧板が得ら
れ、かつ転写後の非転写性の装飾層を有する基材シート
が廃棄されることなく化粧シートとしての機能を持ち、
各種基材へ貼りあわせて、第２の化粧板が得られる。特
に、基材シートが透明であり、転写層と非転写性の装飾
層とが互いに基材シートの反対面側に設けられてなる本
発明の化粧材の場合には、転写により第１の化粧板を作
製した後、転写後のシートで透明基材シートが表面保護
層としての機能をもった第２の化粧板を作製することが
できる。The decorative material of the present invention has a non-transferable decorative layer on one or both sides of a base sheet, and a transfer layer on one or both sides of the base sheet having the non-transferable decorative layer. With this configuration, it has both functions of transfer and decorative sheet, and can be effectively used in terms of cost and resources. A first decorative board is obtained by transfer, and the base sheet having the non-transferable decorative layer after transfer has a function as a decorative sheet without being discarded,
A second decorative board is obtained by attaching the laminate to various substrates. In particular, in the case of the decorative material of the present invention in which the base material sheet is transparent, and the transfer layer and the non-transferable decorative layer are provided on opposite sides of the base material sheet, the first cosmetic material is transferred. After preparing the board, a second decorative board having the function of the transparent base sheet as a surface protective layer can be prepared from the transferred sheet.
【００３１】これらの構成をもった化粧材は、さらに、
非転写性の装飾層と転写層とをインラインで印刷するこ
とで、複数種類の化粧板への絵付けのための絵柄を１工
程で印刷することもできる。さらにまた、本発明の化粧
材を用いて化粧板を作製したものにおいては、コーティ
ングをはじめとした様々な加工が可能であり、優れた実
用上の効果を発揮する。本発明により、化粧材の転写層
を被転写基材上に転写後、転写層から剥離して残存した
非転写層の装飾層を有する基材シートを化粧シートとし
て有効利用でき、かつ装飾性に優れた化粧材およびその
製造方法を提供することができる。[0031] The decorative material having these constitutions further comprises
By printing the non-transferable decorative layer and the transfer layer in-line, it is possible to print a pattern for painting a plurality of types of decorative boards in one step. Furthermore, in the case where a decorative board is produced using the decorative material of the present invention, various processes including coating can be performed, and an excellent practical effect is exhibited. According to the present invention, a base sheet having a decorative layer of a non-transfer layer which has been peeled off from the transfer layer after the transfer layer of the decorative material is transferred onto the base material to be transferred can be effectively used as a decorative sheet, and the decorative property is improved. An excellent decorative material and a method for producing the same can be provided.
【図１】本発明の一実施例の化粧材の構成を示す断面
図。FIG. 1 is a sectional view showing the configuration of a decorative material according to one embodiment of the present invention.
【図２】本発明の他の実施例の化粧材の構成を示す断面
図。FIG. 2 is a sectional view showing the configuration of a decorative material according to another embodiment of the present invention.
１、１０………化粧材 ２、１１………基材シート ３、１２………転写層 ４、１３………非転写性の装飾層 1, 10 ... decorative material 2, 11 ... base sheet 3, 12 ... transfer layer 4, 13 ... non-transferable decorative layer
───────────────────────────────────────────────────── フロントページの続き (72)発明者 新名 勝之 東京都台東区台東１丁目５番１号 凸版印 刷株式会社内 ──────────────────────────────────────────────────続 き Continuing the front page (72) Inventor Katsuyuki Niname 1-5-1, Taito, Taito-ku, Tokyo Letterpress Printing Co., Ltd.
Claims (5)
写性の装飾層と、基材シートの片面に転写層とを設けた
ことを特徴とする化粧材。1. A decorative material comprising a non-transferable decorative layer provided on at least one side of a base sheet and a transfer layer provided on one side of the base sheet.
材上に転写してなる化粧材。2. A decorative material obtained by transferring the transfer layer of the decorative material according to claim 1 onto a substrate to be transferred.
転写層から剥離して残存した非転写性の装飾層を有する
基材シートを基板上に積層してなる化粧材。3. After transferring the transfer layer of the decorative material onto the substrate to be transferred,
A decorative material obtained by laminating a base sheet having a non-transferable decorative layer that has been peeled off from a transfer layer and remains on a substrate.
る請求項２または３記載の化粧材。4. The decorative material according to claim 2, wherein the cosmetic material has a transparent protective layer on the surface.
写層を被転写基材上に転写して第１の化粧材を製造した
後、転写層から剥離して残存した非転写性の装飾層を有
する基材シートを基板上に積層して第２の化粧材を製造
することを特徴とする化粧材の製造方法。5. A non-transfer material which has been peeled off from the transfer layer after the transfer layer has been transferred onto a substrate to be transferred using the decorative material according to claim 1 to produce a first decorative material. A method for manufacturing a decorative material, comprising: laminating a base sheet having a decorative layer on a substrate on a substrate to manufacture a second decorative material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15016598A JP4110616B2 (en) | 1998-05-29 | 1998-05-29 | Cosmetic material and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15016598A JP4110616B2 (en) | 1998-05-29 | 1998-05-29 | Cosmetic material and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11342578A true JPH11342578A (en) | 1999-12-14 |
| JP4110616B2 JP4110616B2 (en) | 2008-07-02 |
Family
ID=15490937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15016598A Expired - Fee Related JP4110616B2 (en) | 1998-05-29 | 1998-05-29 | Cosmetic material and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4110616B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20220017821A (en) * | 2020-08-05 | 2022-02-14 | (주)엘엑스하우시스 | Decorating Material |
| US12017475B2 (en) | 2020-08-05 | 2024-06-25 | Lx Hausys, Ltd. | Decoration material |
-
1998
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20220017821A (en) * | 2020-08-05 | 2022-02-14 | (주)엘엑스하우시스 | Decorating Material |
| KR20220017822A (en) * | 2020-08-05 | 2022-02-14 | (주)엘엑스하우시스 | Decorating Material |
| US12017475B2 (en) | 2020-08-05 | 2024-06-25 | Lx Hausys, Ltd. | Decoration material |
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| Publication number | Publication date |
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| JP4110616B2 (en) | 2008-07-02 |
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