JPH11313589A - Fishline and its production - Google Patents
Fishline and its productionInfo
- Publication number
- JPH11313589A JPH11313589A JP10121193A JP12119398A JPH11313589A JP H11313589 A JPH11313589 A JP H11313589A JP 10121193 A JP10121193 A JP 10121193A JP 12119398 A JP12119398 A JP 12119398A JP H11313589 A JPH11313589 A JP H11313589A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- fishing line
- molecular weight
- fluorine
- weight polyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/02—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics
- D07B1/025—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics comprising high modulus, or high tenacity, polymer filaments or fibres, e.g. liquid-crystal polymers
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/10—Rope or cable structures
- D07B2201/1096—Rope or cable structures braided
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/20—Organic high polymers
- D07B2205/201—Polyolefins
- D07B2205/2014—High performance polyolefins, e.g. Dyneema or Spectra
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/20—Organic high polymers
- D07B2205/2071—Fluor resins
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2401/00—Aspects related to the problem to be solved or advantage
- D07B2401/20—Aspects related to the problem to be solved or advantage related to ropes or cables
- D07B2401/2065—Reducing wear
- D07B2401/2075—Reducing wear externally
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2501/00—Application field
- D07B2501/20—Application field related to ropes or cables
- D07B2501/2038—Agriculture, forestry and fishery
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は超高分子量ポリエチ
レンフィラメント繊維を含む釣糸に関し、特に、超高分
子量ポリエチレンフィラメント繊維とフッ素繊維を組み
合わせてなる釣糸に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fishing line containing ultrahigh molecular weight polyethylene filament fibers, and more particularly to a fishing line combining ultrahigh molecular weight polyethylene filament fibers and fluorine fibers.
【０００２】[0002]
【従来の技術】従来、釣糸の材料としては、ポリアミ
ド、アラミド、ポリエステル、ポリアリレート、ポリフ
ッ化ビニリデンなどが主に使用されてきた。2. Description of the Related Art Conventionally, polyamide, aramid, polyester, polyarylate, polyvinylidene fluoride and the like have been mainly used as fishing line materials.
【０００３】しかしながら、最近になって、超高分子量
ポリエチレンフィラメント繊維の高強力が注目され、こ
の繊維が釣糸に多く使用されるようになってきている。
この繊維からなる釣糸は、比重が約０．９７と小さいこ
とから、上記の従来材料からなるものは水に沈むのに対
し、水に浮かぶ特徴を有する。このことは、浮きを使用
する釣りにおいては、竿先と浮きの間にある釣糸は水面
上を浮遊し、風、波などの影響を受け易く、釣り人の意
のままにコントロール出来ない欠点を有している。これ
を改善した釣糸の開発が、市場から強く要請されてい
た。[0003] Recently, however, attention has been paid to the high tenacity of ultrahigh molecular weight polyethylene filament fibers, and these fibers are increasingly used in fishing lines.
Since the fishing line made of this fiber has a small specific gravity of about 0.97, the fishing line made of the above-described conventional material sinks in water, whereas the fishing line made of the above-mentioned conventional material has a characteristic that it floats in water. This has the disadvantage that in fishing using floats, the fishing line between the pole tip and the float floats on the water surface, is easily affected by wind, waves, etc., and cannot be controlled at the will of the angler. Have. There has been a strong demand from the market for the development of fishing lines that improve this.
【０００４】これに対し、本発明者らは、特開平３−１
００９６０号公報などで高比重成分層などをコーティン
グする方法などを提案している。しかしながら、超高分
子量ポリエチレンフィラメント繊維は、表面が不活性で
ほとんどの接着剤と親和性が少ないことから、十分な耐
久性が得られていない。On the other hand, the present inventors have disclosed in Japanese Patent Laid-Open No.
No. 00960 discloses a method of coating a high specific gravity component layer and the like. However, the ultrahigh molecular weight polyethylene filament fiber has not been sufficiently durable because its surface is inactive and has little affinity with most adhesives.
【０００５】また、従来からの他の高比重な素材を複合
することも考えられる。特に、アラミド、ポリアリレー
ト繊維、金属繊維などの使用が有望である。It is also conceivable to combine another conventional material having a high specific gravity. In particular, the use of aramid, polyarylate fibers, metal fibers and the like is promising.
【０００６】[0006]
【発明が解決しようとする課題】しかしながら、上記釣
りにおいては、磯釣りなどが含まれるが、ここでは岩場
などの摺れ、摩擦などに対しても堅牢であることが要請
される。また、組み上げる製造段階でのマシンガイドの
摩擦により、毛羽発生、強力低下などの問題点がないこ
とが必要である。アラミド、ポリアリレートは、摩擦な
どに対しては特に弱く、上記特性には十分に発揮できな
いという問題がある。また、金属繊維は、キンクし易
く、高剛性のため釣糸からはみ出て、人間の皮膚を刺し
て好ましくないという問題がある。However, in the above-mentioned fishing, surf fishing and the like are included. Here, it is required that the fishing rod be robust against sliding and friction on rocks and the like. Further, it is necessary that there is no problem such as generation of fluff and reduction in strength due to friction of a machine guide in a manufacturing stage to be assembled. Aramid and polyarylate are particularly vulnerable to friction and the like, and have a problem that they cannot sufficiently exhibit the above properties. Further, there is a problem that the metal fiber is easily kinked and protrudes from the fishing line due to its high rigidity, and is not preferable because it pierces human skin.
【０００７】本発明は、前記従来の問題を解決するた
め、超高分子量ポリエチレンフィラメント繊維からなる
釣糸であって、特に浮きを使用する釣りを対象として、
水面下にわずかに沈んで、風や波間の影響を受けにく
く、岩場などへの摩擦にも強く、高強力で、キンク、毛
羽発生などのない優れた品質の釣糸を提供することを目
的とする。In order to solve the above-mentioned conventional problems, the present invention is directed to a fishing line made of ultra-high-molecular-weight polyethylene filament fiber, particularly for fishing using a float.
It aims to provide an excellent quality fishing line that sinks slightly below the water surface, is less susceptible to wind and waves, is resistant to friction with rocky areas, is strong, has no kink, and does not generate fluff. .
【０００８】また、上記の品質を有する製造法ととも
に、製造上の品質の欠点、ムラのない製造法も提供する
も目的とする。It is another object of the present invention to provide a production method having the above-mentioned quality as well as a production method free from defects in production quality and without unevenness.
【０００９】[0009]
【課題を解決するための手段】本発明者らは、上記の課
題を解決すべく種々検討し、超高分子量ポリエチレンフ
ィラメント繊維に単糸繊度が１０デニール以下のフッ素
繊維のマルチフィラメント繊維を組み合わせることによ
り、水面下に沈み、風などの影響を受け難く、しかも耐
摩擦性などに強い釣糸を提供すべく、本発明に到達し
た。Means for Solving the Problems The present inventors have studied variously to solve the above-mentioned problems, and have combined ultra-high molecular weight polyethylene filament fibers with multifilament fibers of a fluorine fiber having a single yarn fineness of 10 denier or less. As a result, the present invention has been made to provide a fishing line which sinks below the surface of the water, is less susceptible to the influence of wind and the like, and has a high resistance to friction and the like.
【００１０】前記の課題を解決するため、本発明は、超
高分子量ポリエチレンフィラメント繊維と少なくともフ
ッ素繊維が組み上げられた組物からなる釣糸であって、
前記フッ素繊維は、単糸繊度が１０デニール以下のマル
チフィラメント繊維であることを特徴とする。ここで、
超高分子量ポリエチレンとは、粘度平均分子量５０万以
上、または重量平均分子量が１００万以上のポリエチレ
ンをいう。[0010] In order to solve the above-mentioned problems, the present invention relates to a fishing line comprising a braided assembly of ultra-high molecular weight polyethylene filament fiber and at least fluorine fiber,
The fluorine fiber is a multifilament fiber having a single yarn fineness of 10 denier or less. here,
Ultra high molecular weight polyethylene refers to polyethylene having a viscosity average molecular weight of 500,000 or more or a weight average molecular weight of 1,000,000 or more.
【００１１】また前記構成においては、フッ素繊維がポ
リテトラフルオロエチレン（ＰＴＦＥ）繊維であること
が好ましい。また前記構成においては、フッ素繊維の複
合量が、超高分子量ポリエチレンフィラメント繊維に対
して１０重量％〜５０重量％であることが好ましい。In the above structure, the fluorine fiber is preferably a polytetrafluoroethylene (PTFE) fiber. Further, in the above configuration, it is preferable that the composite amount of the fluorine fiber is 10% by weight to 50% by weight based on the ultrahigh molecular weight polyethylene filament fiber.
【００１２】また釣糸全体として、見掛けの比重が１．
１０〜１．７０であることが好ましい。次に本発明の釣
糸の製造方法は、超高分子量ポリエチレンのフィラメン
ト繊維と、単糸繊度が１０デニール以下のマルチフィラ
メントのフッ素繊維から少なくとも組み上げられる組物
からなる釣糸を製造する方法であって、下記Ａ〜Ｃから
選ばれる少なくとも一つの工程により釣糸を組み上げる
ことを特徴とする。 Ａ．超高分子量ポリエチレンのフィラメント繊維と、フ
ッ素繊維を別々に供給して組み上げる工程 Ｂ．超高分子量ポリエチレンのフィラメント繊維と、フ
ッ素繊維を引き揃え、次いで組み上げる工程 Ｃ．フッ素繊維を芯糸とし、外周に超高分子量ポリエチ
レンのフィラメント繊維を配置して組み上げる工程The apparent specific gravity of the fishing line as a whole is 1.
It is preferably from 10 to 1.70. Next, the method for producing a fishing line of the present invention is a method for producing a fishing line consisting of a filament fiber of ultra high molecular weight polyethylene and a braid at least assembled from a multifilament fluorine fiber having a single yarn fineness of 10 denier or less, It is characterized in that a fishing line is assembled by at least one step selected from the following A to C. A. Step of separately supplying and assembling filament fibers of ultra-high molecular weight polyethylene and fluorine fibers B. Step of aligning filament fiber of ultra high molecular weight polyethylene with fluorine fiber and then assembling C. Assembling by arranging filament fibers of ultra-high molecular weight polyethylene on the outer circumference with fluorine fiber as the core yarn
【００１３】[0013]
【発明の実施の形態】前記した本発明においては、超高
分子量ポリエチレンフィラメント繊維とは、重量平均分
子量が１００万以上の超高分子量ポリエチレンからな
り、引張強力が２５ｇ／ｄ以上、引張弾性率が８００ｇ
／ｄ以上のフィラメント繊維である。DESCRIPTION OF THE PREFERRED EMBODIMENTS In the present invention, the ultrahigh molecular weight polyethylene filament fiber is made of ultrahigh molecular weight polyethylene having a weight average molecular weight of 1,000,000 or more, a tensile strength of 25 g / d or more, and a tensile modulus of elasticity. 800g
/ D or more filament fibers.
【００１４】本発明におけるフッ素繊維とは、分子中に
フッ素原子を含む樹脂から繊維化されたものを示し、樹
脂としては、ポリテトラフルオロエチレン（ＰＴＦ
Ｅ）、４フッ化エチレンとパーフルオロアルキルビニル
エーテルとの共重合体（ＰＦＡ）、テトラフルオロエチ
レンとヘキサフルオロプロピレンとの共重合体（ＦＥ
Ｐ）、エチレンとテトラフルオロエチレンとの共重合体
（ＥＴＦＥ）、ポリクロロトリフルオロエチレン（ＰＣ
ＴＦＥ）、３フッ化クロロエチレン（ＰＣＴＦＥ）、ポ
リビニルデンフルオライド（ＰＶＤＦ）、ポリフッ化ビ
ニル（ＰＶＦ）などがある。In the present invention, the term "fluorine fiber" refers to a fiber made from a resin containing a fluorine atom in the molecule, and the resin is polytetrafluoroethylene (PTF).
E) Copolymer of tetrafluoroethylene and perfluoroalkyl vinyl ether (PFA), copolymer of tetrafluoroethylene and hexafluoropropylene (FE
P), a copolymer of ethylene and tetrafluoroethylene (ETFE), polychlorotrifluoroethylene (PC
TFE), chloroethylene trifluoride (PCTFE), polyvinyl denfluoride (PVDF), polyvinyl fluoride (PVF), and the like.
【００１５】これらの中でも、特に高比重であること
と、低摩擦係数の面から、ポリテトラフルオロエチレン
（ＰＴＦＥ）繊維が特に好ましい。上記のフッ素繊維
は、マルチフィラメントであることが好ましい。モノフ
ィラメントでは、剛性が高く、超高分子量ポリエチレン
フィラメント繊維とは馴染みにくく、はみ出たり、風合
いが硬く好ましくない。Among these, polytetrafluoroethylene (PTFE) fiber is particularly preferred in terms of high specific gravity and low coefficient of friction. The above-mentioned fluorine fiber is preferably a multifilament. Monofilaments have high rigidity, are hardly compatible with ultra-high molecular weight polyethylene filament fibers, and protrude or have a hard texture, which is not preferable.
【００１６】マルチフィラメントでも、マルチフィラメ
ントを構成する単糸の繊度が１０デニール以下が、特に
風合い及び均斉性の面から好ましい。超高分子量ポリエ
チレンフィラメント繊維に対するフッ素繊維の存在量
は、１０重量％以上が好ましい。例えば、複合比率１０
重量％で、複合した釣糸の見掛けの比重を計算すると
１．１０となり、真水の比重１．００や海水の比重１．
０３を越えるからである。実際にこれらの複合率からな
る釣糸を水中につけると、水中に沈み、水中で浮遊す
る。フッ素繊維を５０重量％を越える量複合すると、釣
糸は、更に沈み易くなるが、一般に、フッ素繊維の引張
強度が小さく、これらを複合した釣糸の強度が小さくな
る。したがって、強度を一定以上に保持しようとすると
繊度を太くする必要があり、本発明の目的を達成する釣
糸は得がたい。In the case of the multifilament, the fineness of the single yarn constituting the multifilament is preferably 10 denier or less, particularly from the viewpoint of the feeling and uniformity. The content of the fluorine fiber with respect to the ultrahigh molecular weight polyethylene filament fiber is preferably 10% by weight or more. For example, a composite ratio of 10
The apparent specific gravity of the composite fishing line in terms of% by weight is calculated to be 1.10. The specific gravity of fresh water is 1.00 and the specific gravity of seawater is 1.
Because it exceeds 03. When a fishing line having these composite ratios is actually put in water, it sinks in water and floats in water. If the fluorine fiber is combined in an amount exceeding 50% by weight, the fishing line is more likely to sink, but in general, the tensile strength of the fluorine fiber is low, and the strength of the fishing line obtained by combining these is low. Therefore, in order to maintain the strength at a certain level or more, it is necessary to increase the fineness, and it is difficult to obtain a fishing line that achieves the object of the present invention.
【００１７】なお、見掛け比重は、各々の比重、超高分
子量ポリエチレンフィラメント繊維は０．９７、ＰＴＦ
Ｅは２．３を用い、複合率に掛け合わせて求めた。な
お、本発明の前記粘度平均分子量（Ｍｖ）は、１３５℃
デカリンにて毛細管粘度計法で測定した極限粘度から次
式（数１）を用いて便宜的に算出した。The apparent specific gravity was as follows: the specific gravity was 0.97 for ultra-high molecular weight polyethylene filament fiber, and PTF
E was obtained by multiplying the composite ratio by using 2.3. The viscosity average molecular weight (Mv) of the present invention is 135 ° C.
It was conveniently calculated from the intrinsic viscosity measured by a capillary viscometer with decalin using the following formula (Equation 1).
【００１８】[0018]
【数１】Ｍｖ＝５．３７×１０4 ［η］1.37 ## EQU1 ## Mv = 5.37 × 10 4 [η] 1.37
【００１９】[0019]
【実施例】以下実施例を用いて本発明を具体的に説明す
る。The present invention will be specifically described below with reference to examples.
【００２０】[0020]
【実施例１】ポリテトラフルオロエチレンからなるフッ
素繊維、「トヨフロン」（東レ（株）製）のトータル繊
度：１００デニール、フィラメント数：１５本（単糸デ
ニールは約６．７ｄ）を芯糸とし、その外周を、粘度平
均分子量が約１７０万の超高分子量ポリエチレンフィラ
メント繊維、「ダイニーマ」（東洋紡（株）製）、トー
タル繊度：１００デニール、単糸繊度：１．０４デニー
ル、４本を用いて組み上げた。フッ素繊維を芯糸とし、
外周に超高分子量ポリエチレンのフィラメント繊維を配
置して４本角打ち組織に組み上げた。これは前記製法の
Ｃ工程に該当する。Example 1 A core fiber of a fluorine fiber made of polytetrafluoroethylene, "Toyoflon" (manufactured by Toray Industries, Inc.) having a total fineness of 100 denier and a number of filaments of 15 (single yarn denier is about 6.7 d). Ultra-high molecular weight polyethylene filament fiber having a viscosity average molecular weight of about 1.7 million, "Dyneema" (manufactured by Toyobo Co., Ltd.), total fineness: 100 denier, single yarn fineness: 1.04 denier, and four outer circumferences Assembled. Fluorine fiber as core yarn,
Ultra-high molecular weight polyethylene filament fibers were arranged on the outer periphery and assembled into a four-square structure. This corresponds to step C of the above-mentioned manufacturing method.
【００２１】その結果、組み上げの製造段階でも、マシ
ンガイドでの滑りがよく、毛羽発生、糸切れなど問題点
も発生しなかった。得られた釣糸の太さは、ナイロン繊
維の号数に換算すると、約２号であった。また、引張強
力は１１ｋｇであった。また、超高分子量ポリエチレン
フィラメント繊維に対するフッ素繊維の複合率は、２０
重量％であり、見掛け比重は１．１０であった。As a result, even at the stage of assembling, slippage by the machine guide was good, and no problems such as fluffing and yarn breakage occurred. The thickness of the obtained fishing line was about 2 in terms of the number of nylon fibers. The tensile strength was 11 kg. The composite ratio of the fluorine fiber to the ultrahigh molecular weight polyethylene filament fiber is 20%.
% By weight and an apparent specific gravity of 1.10.
【００２２】この糸をミチ糸に用い、実際に磯釣りを行
った。竿先と浮きの間の釣糸は、海水中に少し沈むの
で、風、波への対応は容易であった。浮き止めを使用し
ないで、ミチ糸が自由に動ける状態で釣るスルスル釣り
においても、風、波の影響を受ける度合いが小さく、浮
きの操作が簡単で広範囲な棚が容易に探ることができ
た。Using this thread as a thread thread, surf fishing was actually performed. The fishing line between the pole and the float sinks a little in the seawater, so it was easy to respond to wind and waves. Even in the case of fishing through the sea where the thread is free to move without using the retaining pad, the degree of influence of wind and waves was small, the floating operation was simple, and a wide range of shelves could be easily searched.
【００２３】[0023]
【実施例２】ポリテトラフルオロエチレンからなるフッ
素繊維、「トヨフロン」（東レ（株）製）のトータル繊
度：１００デニール、フィラメント数：１５本を１本
と、粘度平均分子量が約１７０万の超高分子量ポリエチ
レンフィラメント繊維、「ダイニーマ」（東洋紡（株）
製）、トータル繊度：１００デニール、単糸繊度：１．
０４デニールを１本引き揃え、これを１つのスピンドル
へ装着（構成単位）し、他の３つのスピンドルへは前記
「ダイニーマ」１００デニール糸を装着し、組み上げ
た。組み上げ方法は、超高分子量ポリエチレンのフィラ
メント繊維と、フッ素繊維を引き揃え、４本角打ち組織
に組み上げた。これは前記製法のＢ工程に該当する。Example 2 Fluorine fiber made of polytetrafluoroethylene, "TOYOFLON" (manufactured by Toray Industries, Inc.), total fineness: 100 denier, number of filaments: 1, one filament, and viscosity average molecular weight of more than about 1.7 million High molecular weight polyethylene filament fiber, "Dyneema" (Toyobo Co., Ltd.)
Manufactured), total fineness: 100 denier, single yarn fineness: 1.
One piece of 04 denier was aligned and mounted on one spindle (constituent unit), and the other three spindles were mounted with the above-mentioned "Dyneema" 100 denier yarn and assembled. The assembling method was such that a filament fiber of ultra-high molecular weight polyethylene and a fluorine fiber were aligned and assembled into a quadrilateral structure. This corresponds to step B of the above-mentioned manufacturing method.
【００２４】その結果、組み上げの製造段階でも、マシ
ンガイドでの滑りがよく、毛羽発生、糸切れなど問題点
も発生しなかった。得られた釣糸の太さは、ナイロン繊
維の号数に換算すると、約２号であった。また、引張強
力は１１ｋｇであった。また、超高分子量ポリエチレン
フィラメント繊維に対するフッ素繊維の複合率は、２０
重量％であり、見掛け比重は１．１０であった。As a result, even in the assembling stage, slippage by the machine guide was good, and no problems such as fluffing and yarn breakage occurred. The thickness of the obtained fishing line was about 2 in terms of the number of nylon fibers. The tensile strength was 11 kg. The composite ratio of the fluorine fiber to the ultrahigh molecular weight polyethylene filament fiber is 20%.
% By weight and an apparent specific gravity of 1.10.
【００２５】この糸をミチ糸に用い、実際に磯釣りを行
った。竿先と浮きの間の釣糸は、海水中に少し沈むの
で、風、波への対応は容易であった。浮き止めを使用し
ないで、ミチ糸が自由に動ける状態で釣るスルスル釣り
においても、風、波の影響を受ける度合いが小さく、浮
きの操作が簡単で広範囲な棚が容易に探ることができ
た。Using this thread as a thread thread, surf fishing was actually performed. The fishing line between the pole and the float sinks a little in the seawater, so it was easy to respond to wind and waves. Even in the case of fishing through the sea where the thread is free to move without using the retaining pad, the degree of influence of wind and waves was small, the floating operation was simple, and a wide range of shelves could be easily searched.
【００２６】[0026]
【実施例３】ポリテトラフルオロエチレンからなるフッ
素繊維、「トヨフロン」（東レ（株）製）のトータル繊
度：１００デニール、フィラメント数：１５本を１つの
スピンドルへ装着（構成単位）し、他の３つのスピンド
ルへは粘度平均分子量が約１７０万の超高分子量ポリエ
チレンフィラメント繊維、「ダイニーマ」トータル繊
度：１００デニール、単糸繊度：１．０４デニール糸を
装着し、組み上げた。組み上げ方法は、超高分子量ポリ
エチレンのフィラメント繊維と、フッ素繊維を別々に供
給して、４本角打ち組織に組み上げた。これは前記製法
のＡ工程に該当する。Example 3 A fluorine fiber made of polytetrafluoroethylene, "Toyoflon" (manufactured by Toray Industries, Inc.), having a total fineness of 100 denier and a number of filaments: 15 was mounted on one spindle (constituent unit), and the other Ultra-high molecular weight polyethylene filament fibers having a viscosity average molecular weight of about 1.7 million, "Dyneema" total fineness: 100 denier, single yarn fineness: 1.04 denier yarn were mounted on three spindles, and assembled. The assembling method was such that a filament fiber of ultra-high molecular weight polyethylene and a fluorine fiber were separately supplied to assemble into a four-squared structure. This corresponds to step A of the above-mentioned manufacturing method.
【００２７】その結果、組み上げの製造段階でも、マシ
ンガイドでの滑りがよく、毛羽発生、糸切れなど問題点
も発生しなかった。得られた釣糸の太さは、ナイロン繊
維の号数に換算すると、約２号相当であった。また、引
張強力は８．３ｋｇであった。また、超高分子量ポリエ
チレンフィラメント繊維に対するフッ素繊維の複合率
は、２５重量％であり、見掛け比重は１．３０であっ
た。As a result, even in the assembling manufacturing stage, slippage by the machine guide was good, and no problems such as fluffing and yarn breakage occurred. The thickness of the obtained fishing line was equivalent to about 2 in terms of the number of nylon fibers. The tensile strength was 8.3 kg. The composite ratio of the fluorine fiber to the ultrahigh molecular weight polyethylene filament fiber was 25% by weight, and the apparent specific gravity was 1.30.
【００２８】この糸をミチ糸に用い、実際に磯釣りを行
った。竿先と浮きの間の釣糸は、海水中に少し沈むの
で、風、波への対応は容易であった。浮き止めを使用し
ないで、ミチ糸が自由に動ける状態で釣るスルスル釣り
においても、風、波の影響を受ける度合いが小さく、浮
きの操作が簡単で広範囲な棚が容易に探ることができ
た。また、岩場との摺れで、本実施例品は、実施例１及
び２ではほとんど認められなかった毛羽立ちがやや認め
られた。しかしながら、ポリテトラフルオロエチレンか
らなるフッ素繊維を含まない、４本がすべて超高分子量
ポリエチレンフィラメント繊維からなる釣糸に比べると
はるかに耐摩擦性は優れていた。Using this thread as a thread thread, surf fishing was actually performed. The fishing line between the pole and the float sinks a little in the seawater, so it was easy to respond to wind and waves. Even in the case of fishing through the sea where the thread is free to move without using the retaining pad, the degree of influence of wind and waves was small, the floating operation was simple, and a wide range of shelves could be easily searched. Further, due to the sliding with the rocky place, the product of the present example showed a little fuzz which was hardly observed in Examples 1 and 2. However, the friction resistance, which does not include the fluorine fiber made of polytetrafluoroethylene, was much superior to that of the fishing line in which all four fibers were made of ultrahigh molecular weight polyethylene filament fiber.
【００２９】[0029]
【発明の効果】以上説明したとおり本発明によれば、超
高分子量ポリエチレンフィラメント繊維にフッ素繊維を
複合し、組み上げた組物からなる釣糸にすることによ
り、水面下に沈み、風などの影響を受け難く、しかも耐
摩擦性などに強い釣糸を提供できた。また、種々の見掛
け比重を有する釣糸を容易に達成できる。特に、竿先と
浮きの間を水中に沈める磯釣りにおいて、水中にわずか
に沈める必要な釣りにおいて有用な釣糸とすることがで
きた。また、風合いもしなやかで、滑りのある釣糸が可
能となった。さらに、組み上げの製造段階でも、マシン
ガイドなどでの滑りが良く、毛羽立ちや糸切れなど品質
低下のない釣糸が容易に達成できた。As described above, according to the present invention, the ultrahigh molecular weight polyethylene filament fiber is combined with the fluorine fiber to form a fishing line composed of the assembled braid, so that the fishing line is settled below the surface of the water and affected by wind and the like. A fishing line that is hard to receive and has high friction resistance and the like was provided. Further, fishing lines having various apparent specific gravities can be easily achieved. In particular, it was possible to obtain a useful fishing line in surf fishing where the space between the pole tip and the float was submerged underwater, and in fishing where it was necessary to submerge slightly underwater. In addition, the texture is supple and a slippery fishing line is possible. Further, even in the assembling manufacturing stage, it was possible to easily achieve a fishing line with good slippage by a machine guide or the like and no quality deterioration such as fluffing or breakage.
─────────────────────────────────────────────────────
────────────────────────────────────────────────── ───
【手続補正書】[Procedure amendment]
【提出日】平成１１年６月８日[Submission date] June 8, 1999
【手続補正１】[Procedure amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】特許請求の範囲[Correction target item name] Claims
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【特許請求の範囲】[Claims]
【手続補正２】[Procedure amendment 2]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１０[Correction target item name] 0010
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【００１０】前記の課題を解決するため、本発明は、超
高分子量ポリエチレンフィラメント繊維と少なくともフ
ッ素繊維が組み上げられた組物からなる釣糸であって、
前記フッ素繊維は、単糸繊度が１０デニール以下のマル
チフィラメント繊維であり、かつ前記フッ素繊維の存在
量が前記超高分子量ポリエチレンのフィラメント繊維に
対して１０重量％以上５０重量％以下の範囲であること
を特徴とする。ここで、超高分子量ポリエチレンとは、
粘度平均分子量５０万以上、または重量平均分子量が１
００万以上のポリエチレンをいう。[0010] In order to solve the above-mentioned problems, the present invention relates to a fishing line comprising a braided assembly of ultra-high molecular weight polyethylene filament fiber and at least fluorine fiber,
The presence of the fluorine fibers, a single yarn fineness Ri following multifilament fiber der 10 denier, and the fluorine fibers
The amount is equivalent to the ultra high molecular weight polyethylene filament fiber.
Wherein the range der Rukoto of 10% by weight to 50% by weight against. Here, ultra-high molecular weight polyethylene is
Viscosity average molecular weight of 500,000 or more, or weight average molecular weight of 1
It means a polyethylene of 100,000 or more.
【手続補正３】[Procedure amendment 3]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１１[Correction target item name] 0011
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【００１１】また前記構成においては、フッ素繊維がポ
リテトラフルオロエチレン（ＰＴＦＥ）繊維であること
が好ましい。また前記構成においては、フッ素繊維を芯
糸に配置し、超高分子量ポリエチレンフィラメント繊維
を前記芯糸の外周に配置したことが好ましい。また釣糸
全体として、見掛けの比重が１．１０〜１．７０である
ことが好ましい。In the above structure, the fluorine fiber is preferably a polytetrafluoroethylene (PTFE) fiber. Further, in the above configuration, the core is made of a fluorine fiber.
Ultra high molecular weight polyethylene filament fibers placed on yarn
Is preferably arranged on the outer periphery of the core yarn . Further, the apparent specific gravity of the fishing line as a whole is preferably 1.10 to 1.70.
【手続補正４】[Procedure amendment 4]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１２[Correction target item name] 0012
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【００１２】次に本発明の釣糸の製造方法は、超高分子
量ポリエチレンのフィラメント繊維と、単糸繊度が１０
デニール以下のマルチフィラメントのフッ素繊維から少
なくとも組み上げられる組物からなり、かつ前記フッ素
繊維の存在量が前記超高分子量ポリエチレンのフィラメ
ント繊維に対して１０重量％以上５０重量％以下の範囲
である釣糸を製造する方法であって、下記Ａ〜Ｃから選
ばれる少なくとも一つの工程により釣糸を組み上げるこ
とを特徴とする。 Ａ．超高分子量ポリエチレンのフィラメント繊維と、フ
ッ素繊維を別々に供給して組み上げる工程 Ｂ．超高分子量ポリエチレンのフィラメント繊維と、フ
ッ素繊維を引き揃え、次いで組み上げる工程 Ｃ．フッ素繊維を芯糸とし、外周に超高分子量ポリエチ
レンのフィラメント繊維を配置して組み上げる工程Next, the method for producing a fishing line according to the present invention comprises the steps of:
Ri Do at least assembled is braided from denier of multifilament fluorocarbon fibers, and said fluorine
The fiber content of the ultra-high molecular weight polyethylene is
In the range of 10% by weight or more and 50% by weight or less based on
A method of manufacturing a Der Ru fishing line, characterized in that assembling the fishing line by at least one step selected from the following A through C. A. Step of separately supplying and assembling filament fibers of ultra-high molecular weight polyethylene and fluorine fibers B. Step of aligning filament fiber of ultra high molecular weight polyethylene with fluorine fiber and then assembling C. Assembling by arranging filament fibers of ultra-high molecular weight polyethylene on the outer circumference with fluorine fiber as the core yarn
Claims (5)
繊維と、少なくともフッ素繊維が組み上げられた組物か
らなる釣糸であって、前記フッ素繊維は、単糸繊度が１
０デニール以下のマルチフィラメント繊維であることを
特徴とする釣糸。1. A fishing line comprising a braid made of a filament fiber of ultra-high molecular weight polyethylene and at least a fluorine fiber, wherein the fluorine fiber has a single yarn fineness of 1
A fishing line characterized by being a multifilament fiber of 0 denier or less.
ン（ＰＴＦＥ）繊維である請求項１に記載の釣糸。2. The fishing line according to claim 1, wherein the fluorine fiber is a polytetrafluoroethylene (PTFE) fiber.
エチレンのフィラメント繊維に対して１０重量％以上５
０重量％以下の範囲である請求項１または２に記載の釣
糸。3. The method according to claim 1, wherein the amount of the fluorine fiber is at least 10% by weight based on the filament fiber of the ultrahigh molecular weight polyethylene.
3. The fishing line according to claim 1, wherein the amount of the fishing line is 0% by weight or less.
１０〜１．７０である請求項１〜３のいずれかに記載の
釣糸。4. The apparent specific gravity of the fishing line as a whole is 1.
The fishing line according to any one of claims 1 to 3, wherein the number is 10 to 1.70.
繊維と、単糸繊度が１０デニール以下のマルチフィラメ
ントのフッ素繊維から少なくとも組み上げられる組物か
らなる釣糸を製造する方法であって、下記Ａ〜Ｃから選
ばれる少なくとも一つの工程により釣糸を組み上げるこ
とを特徴とする釣糸の製造方法。 Ａ．超高分子量ポリエチレンのフィラメント繊維と、フ
ッ素繊維を別々に供給して組み上げる工程 Ｂ．超高分子量ポリエチレンのフィラメント繊維と、フ
ッ素繊維を引き揃え、次いで組み上げる工程 Ｃ．フッ素繊維を芯糸とし、外周に超高分子量ポリエチ
レンのフィラメント繊維を配置して組み上げる工程5. A method for producing a fishing line comprising a braid which is at least assembled from a filament fiber of ultra-high molecular weight polyethylene and a multifilament fluorine fiber having a single yarn fineness of 10 denier or less, selected from the following A to C: A method of manufacturing a fishing line, comprising assembling the fishing line in at least one step. A. Step of separately supplying and assembling filament fibers of ultra-high molecular weight polyethylene and fluorine fibers B. Step of aligning filament fiber of ultra high molecular weight polyethylene with fluorine fiber and then assembling C. Assembling by arranging filament fibers of ultra-high molecular weight polyethylene on the outer circumference with fluorine fiber as the core yarn
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10121193A JP2954925B1 (en) | 1998-04-30 | 1998-04-30 | Fishing line and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10121193A JP2954925B1 (en) | 1998-04-30 | 1998-04-30 | Fishing line and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2954925B1 JP2954925B1 (en) | 1999-09-27 |
| JPH11313589A true JPH11313589A (en) | 1999-11-16 |
Family
ID=14805177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10121193A Expired - Lifetime JP2954925B1 (en) | 1998-04-30 | 1998-04-30 | Fishing line and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2954925B1 (en) |
Cited By (6)
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|---|---|---|---|---|
| JP2008530385A (en) * | 2005-02-11 | 2008-08-07 | ゴア エンタープライズ ホールディングス，インコーポレイティド | Fluoropolymer fiber composite bundle |
| JP2009517557A (en) * | 2005-12-02 | 2009-04-30 | ディーエスエム アイピー アセッツ ビー．ブイ． | Rope containing high-performance polyethylene fiber |
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| JP2009254245A (en) * | 2008-04-14 | 2009-11-05 | Ygk:Kk | Yarn and spinning line comprising the yarns |
| JP2013521775A (en) * | 2010-03-09 | 2013-06-13 | ゴア エンタープライズ ホールディングス，インコーポレイティド | Fluoropolymer fiber composite bundle |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008530385A (en) * | 2005-02-11 | 2008-08-07 | ゴア エンタープライズ ホールディングス，インコーポレイティド | Fluoropolymer fiber composite bundle |
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| JP2009517557A (en) * | 2005-12-02 | 2009-04-30 | ディーエスエム アイピー アセッツ ビー．ブイ． | Rope containing high-performance polyethylene fiber |
| JP2009527661A (en) * | 2006-02-24 | 2009-07-30 | ハネウェル・インターナショナル・インコーポレーテッド | Rope with excellent pulley repeated bending performance |
| KR101390162B1 (en) * | 2006-02-24 | 2014-05-13 | 허니웰 인터내셔널 인코포레이티드 | Ropes having improved cyclic bend over sheave performance |
| JP2009235586A (en) * | 2008-03-26 | 2009-10-15 | Fukushima Prefecture | Fine particle coated organic material and method for coating organic material with fine particle |
| JP2009254245A (en) * | 2008-04-14 | 2009-11-05 | Ygk:Kk | Yarn and spinning line comprising the yarns |
| JP2013521775A (en) * | 2010-03-09 | 2013-06-13 | ゴア エンタープライズ ホールディングス，インコーポレイティド | Fluoropolymer fiber composite bundle |
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| Publication number | Publication date |
|---|---|
| JP2954925B1 (en) | 1999-09-27 |
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