JPH11301190A - Decorative part and its manufacture - Google Patents
Decorative part and its manufactureInfo
- Publication number
- JPH11301190A JPH11301190A JP12687698A JP12687698A JPH11301190A JP H11301190 A JPH11301190 A JP H11301190A JP 12687698 A JP12687698 A JP 12687698A JP 12687698 A JP12687698 A JP 12687698A JP H11301190 A JPH11301190 A JP H11301190A
- Authority
- JP
- Japan
- Prior art keywords
- plating layer
- bright
- base material
- white
- appearance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Electroplating Methods And Accessories (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、口紅等の化粧品容
器その他の化粧品用の部品、ボールペンやシャープペン
等のチップ、クリップその他の筆記具用の部品に関し、
更に詳述すると、これら部品の基材上に光沢性を有し、
かつ、明るい有色透明外観、特に金色外観を与える装飾
性の高い装飾部品及びその製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cosmetic container such as a lipstick and other cosmetic parts, a chip such as a ballpoint pen and a mechanical pen, a clip and other parts for a writing instrument.
More specifically, it has a gloss on the substrate of these parts,
The present invention also relates to a decorative component having a high decorative property that gives a bright colored transparent appearance, particularly a golden appearance, and a method for producing the same.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】従来、
化粧品や筆記具の部品は、装飾性及び耐食性の観点か
ら、その基材上に光沢ニッケルめっき層を形成し、その
上に金めっき層を形成したものが多い。2. Description of the Related Art
Many cosmetics and writing instrument parts have a bright nickel plating layer formed on a base material and a gold plating layer formed thereon from the viewpoint of decorativeness and corrosion resistance.
【０００３】しかし、従来のこの種の金めっき部品は、
下地の光沢ニッケルめっき層が比較的黒っぽい金属色を
与え、その上に形成される金めっき層も薄いので、下地
のニッケルめっき層の影響で外観が暗い印象を与えるこ
とが否めない。このため、明るい、鮮やかな金色外観を
与え、装飾効果の高い部品が望まれている。また、金め
っきは高価であり、より低コストで優れた金色外観を与
えることも要望されている。この場合、金めっきの代替
として真鍮めっきを用いれば、コストの低減を計ること
はできるが、外観の点で改良はされない。However, conventional gold-plated parts of this kind are:
Since the underlying bright nickel plating layer gives a relatively dark metallic color and the gold plating layer formed thereon is also thin, it cannot be denied that the undercoat nickel plating layer gives an impression that the appearance is dark. For this reason, a component that gives a bright, bright golden appearance and has a high decorative effect is desired. Also, gold plating is expensive, and there is also a demand for lower cost and better gold appearance. In this case, if brass plating is used instead of gold plating, the cost can be reduced, but the appearance is not improved.
【０００４】本発明は上記要望に応えたもので、明るい
鮮やかな有色外観を有し、化粧品容器の外装や筆記具外
装として用いて、高い装飾効果を有し、興趣のある外観
を与える化粧品又は筆記具の装飾部品及びその製造方法
を提供することを目的とする。The present invention meets the above-mentioned demand, and has a bright and vivid color appearance, and is used as an exterior of a cosmetic container or an exterior of a writing implement, and has a high decorative effect and a cosmetic or writing implement having an interesting appearance. And a method for manufacturing the same.
【０００５】[0005]
【課題を解決するための手段及び発明の実施の形態】本
発明者は、上記目的を達成するため鋭意検討を行った結
果、化粧品又は筆記具用部品の基材上に対し、光沢ニッ
ケルめっき等の光輝性めっき層を形成し、その上に銀、
錫等の白色めっき層を形成し、更にその上に金色等の色
調を与える染料を添加したクリヤーラッカー等の塗料を
用いて有色透明塗膜を形成した場合、該塗膜の下地の白
色めっき層と有色透明塗膜との相乗的作用で、光沢のあ
る、明るいしかも透明感を有する有色色調の外観が得ら
れ、従来のやや暗い沈んだ有色色調の外観に比べて、華
やかで透明性を伴った興趣のある装飾部品が得られるこ
とを知見した。またこの場合、上記基材表面がショット
ブラストなどによって梨地状に形成されていると、得ら
れる部品の外観が明るい透明感のある乱反射状の着色外
観となり、より明るい金属色を与え、非常に美麗な乱反
射状着色ができることを見出した。更に、上記方法は、
有色外観は塗料に染料を配合することによって行われ、
金色外観を形成するのに金めっきを行うものではないの
で、コスト的に安価に装飾部品を製造できることを見出
し、本発明をなすに至ったものである。Means for Solving the Problems and Embodiments of the Invention The present inventors have conducted intensive studies to achieve the above object, and as a result, applied bright nickel plating or the like to the base material of cosmetics or writing instrument parts. A bright plating layer is formed, and silver,
When a colored transparent coating film is formed by forming a white plating layer of tin or the like and further using a coating material such as a clear lacquer to which a dye giving a color tone of gold or the like is added, a white plating layer underlying the coating film With the synergistic action of the colored transparent coating film and the colored transparent coating film, a glossy, bright and transparent color tone appearance can be obtained, and it is more gorgeous and transparent than the conventional slightly darker sinking color tone appearance. We found that interesting decorative parts can be obtained. Further, in this case, when the base material surface is formed in a satin shape by shot blasting or the like, the appearance of the obtained component becomes a bright and transparent irregularly-reflected colored appearance, giving a brighter metallic color and a very beautiful appearance. It has been found that it is possible to perform irregular reflection coloring. Further, the above method
The colored appearance is achieved by compounding the paint with a dye,
The present inventors have found that decorative parts can be produced at low cost because gold plating is not performed to form a golden appearance, and the present invention has been accomplished.
【０００６】従って、本発明は、化粧品又は筆記具用部
品の基材上に光輝性めっき層を形成し、該光輝性めっき
層上に白色めっき層を形成すると共に、該白色めっき層
上に有色透明塗膜を形成してなることを特徴とする装飾
部品、及び、化粧品又は筆記具用部品の基材上に光輝性
めっき層を形成し、該光輝性めっき層上に白色めっき層
を形成した後、該白色めっき層上に有色透明塗膜を形成
することを特徴とする装飾部品の製造方法を提供する。
また、上記装飾部品及びその製造方法において、上記基
材の表面が梨地加工された態様を含む。Accordingly, the present invention provides a glittering plating layer formed on a base material of a cosmetic or writing instrument component, a white plating layer formed on the glittering plating layer, and a colored transparent layer formed on the white plating layer. Decorative parts characterized by forming a coating film, and, forming a glittering plating layer on the base material of cosmetics or writing instrument parts, after forming a white plating layer on the glittering plating layer, A method for producing a decorative component, comprising forming a colored transparent coating film on the white plating layer.
Further, in the decorative component and the method of manufacturing the same, the aspect may include an aspect in which the surface of the base material has a satin finish.
【０００７】以下、本発明につき更に詳しく説明する。
本発明の装飾部品は、口紅等の化粧品容器や化粧具など
の化粧品用部品、及びボールペン、シャープペン等の先
端の金属チップ部やクリップ部等の筆記具用部品として
用いられる。Hereinafter, the present invention will be described in more detail.
INDUSTRIAL APPLICABILITY The decorative component of the present invention is used as a cosmetic component such as a cosmetic container such as a lipstick and a cosmetic tool, and a writing tool component such as a metal tip portion and a clip portion at the tip of a ballpoint pen and a mechanical pen.
【０００８】本発明においては、これら部品の基材上に
光輝性めっき層を有する。この場合、基材は、通常スチ
ール、真鍮等の金属にて形成されているが、プラスチッ
クでもよく、基材の材質に応じた適宜な公知の方法によ
って光輝性めっき層を形成することができる。In the present invention, these components have a bright plating layer on the substrate. In this case, the substrate is usually formed of a metal such as steel or brass, but may be plastic, and the glittering plating layer can be formed by an appropriate known method according to the material of the substrate.
【０００９】なお、基材表面は、羽布仕上げなどによっ
て表面が平滑であっても、ショットブラスト加工等によ
って表面が梨地状に形成されていてもよい。この場合、
表面を梨地状に形成すると、乱反射状の光沢を有する興
趣の高い装飾外観が得られる。[0009] The surface of the base material may be smooth, such as by a feather cloth finish, or may be formed in a satin shape by, for example, shot blasting. in this case,
When the surface is formed in a satin shape, a highly attractive decorative appearance having diffusely reflective gloss is obtained.
【００１０】上記基材表面は、光輝性めっき層形成前
に、脱脂、酸洗等の公知の前処理を施すことができる。[0010] The base material surface can be subjected to a known pretreatment such as degreasing or pickling before forming the glittering plating layer.
【００１１】上記基材に形成される光輝性めっき層とし
ては、光沢ニッケル又はニッケル合金めっき層が好まし
い。この光輝性めっき層は、光沢を有する限り電気めっ
き法によっても無電解めっき法によってもよいが、光沢
性、レベリング性の点から電気めっき法が好ましく、特
に光沢電気ニッケルめっき液からの光輝性めっき層が好
ましい。なお、光沢電気ニッケルめっき層を光輝性めっ
き層とする場合、この光沢電気ニッケルめっき層は金属
製基材上に直接形成しても、光沢銅めっき層、半光沢ニ
ッケルめっき層等の他のめっき層を介在してもよい。基
材がプラスチックの場合は、常法通り、基材上に無電解
銅又はニッケルめっき層や更に必要によりその上に光沢
銅めっき層などを形成した後に、光沢ニッケルめっき層
を形成することができる。The bright plating layer formed on the substrate is preferably a bright nickel or nickel alloy plating layer. The glittering plating layer may be formed by electroplating or electroless plating as long as it has luster, but electroplating is preferred in terms of glossiness and leveling properties. Layers are preferred. When the bright electro-nickel plating layer is a bright plating layer, the bright electro-nickel plating layer may be formed directly on a metal substrate, or may be formed by other plating such as a bright copper plating layer or a semi-bright nickel plating layer. Layers may be interposed. When the substrate is a plastic, as usual, after forming an electroless copper or nickel plating layer on the substrate and further forming a bright copper plating layer thereon if necessary, a bright nickel plating layer can be formed. .
【００１２】なお、上記光輝性めっき層の厚さは適宜選
定されるが、光沢性、レベリング性、耐食性等の点から
１〜１００μｍ、特に２〜５０μｍであることが好まし
い。The thickness of the glittering plating layer is appropriately selected, but is preferably from 1 to 100 μm, particularly preferably from 2 to 50 μm, in view of glossiness, leveling property, corrosion resistance and the like.
【００１３】本発明の装飾部品は、上記光輝性めっき層
上に白色めっき層を有する。ここで、白色めっき層とし
ては、銀、錫、錫−銅合金等の錫合金、銀合金などの白
色状の金属色を与えるめっき層が用いられる。即ち、光
沢ニッケルめっき層は、黒味を帯びたような金属色調を
有するが、銀めっきや錫めっき、これら金属の合金めっ
き皮膜は、白っぽい金属色調を有するものである。な
お、この白色めっき層は、膜厚にもよるが、下地の光輝
性めっき層の光沢を損なわない点から同様に光輝性を有
する白色めっき層、特に光沢銀めっき層、光沢錫めっき
層や、これらの光沢合金めっき層であることが好まし
い。また、このように光沢を与えるという点から市販の
光沢剤が添加された光沢電気めっき液から形成すること
ができる。The decorative component of the present invention has a white plating layer on the glittering plating layer. Here, as the white plating layer, a plating layer that gives a white metallic color such as a silver alloy, a tin alloy such as a tin-copper alloy, or a silver alloy is used. That is, the bright nickel plating layer has a blackish metallic color tone, but silver plating, tin plating, and alloy plating films of these metals have a whitish metallic color tone. In addition, this white plating layer, although depending on the film thickness, also has a similar brilliant white plating layer in terms of not impairing the luster of the underlying brilliant plating layer, particularly a bright silver plating layer, a bright tin plating layer, These bright alloy plating layers are preferred. In addition, from the viewpoint of imparting gloss as described above, it can be formed from a bright electroplating solution to which a commercially available brightener is added.
【００１４】上記白色めっき層の厚さも適宜選定される
が、通常０．０１〜１０μｍ、特に０．０５〜５μｍと
することが好ましい。The thickness of the above-mentioned white plating layer is also appropriately selected, but is preferably 0.01 to 10 μm, particularly preferably 0.05 to 5 μm.
【００１５】なお、上記光輝性めっき層、白色めっき層
の形成は、市販のめっき液或いは光沢剤等の添加剤を用
い、公知のめっき液組成で常法によって行うことがで
き、ラック法に限られず、バレル法等を採用してもよ
い。The bright plating layer and the white plating layer can be formed by a conventional method using a commercially available plating solution or an additive such as a brightener and a known plating solution composition. Instead, a barrel method or the like may be employed.
【００１６】本発明の装飾用部品は、更に上記白色めっ
き層上に有色透明塗膜を形成するもので、これにより白
色めっき層と該有色透明塗膜との相乗的作用で光沢性を
有すると共に透明感のある明るい有色の金属色外観を与
え、特に有色透明塗膜が金色の場合、従来にない明るい
華やかな透明感を持つ金色外観が得られる。この場合、
上記白色めっき層を形成せず、直接光沢ニッケルめっき
層にこの有色透明塗膜を形成した場合は、光沢ニッケル
めっき層上に金めっき皮膜を形成した以上に暗い色調と
なり、装飾効果が低下して、本発明の目的を達成し得な
い。The decorative part of the present invention further comprises forming a colored transparent coating film on the white plating layer, whereby the white plating layer and the colored transparent coating have a synergistic effect and have gloss. A bright colored metallic color appearance with a sense of transparency is provided. In particular, when the colored transparent coating film is golden, a golden appearance having a bright and gorgeous transparency that has never been seen before can be obtained. in this case,
When the colored transparent coating film is directly formed on the bright nickel plating layer without forming the white plating layer, the color tone becomes darker than when the gold plating film is formed on the bright nickel plating layer, and the decorative effect is reduced. However, the object of the present invention cannot be achieved.
【００１７】ここで、有色透明塗膜の形成には、クリヤ
ーラッカー等の透明樹脂（例えばアクリル樹脂、ウレタ
ン樹脂、エポキシ樹脂など）を含む塗料に所望の有色色
調、例えば金、黄、橙及び黄、赤、青の三原色を含む中
間色などを与える染料を添加したものを用い、吹き付け
塗装、静電塗装、電気泳動塗装などの適宜な塗装法によ
り塗布し、次いで常法に従って乾燥、必要により硬化す
ればよい。Here, to form a colored transparent coating film, a paint containing a transparent resin such as a clear lacquer (for example, an acrylic resin, a urethane resin, an epoxy resin, etc.) has a desired color tone, for example, gold, yellow, orange and yellow. , Using a dye to which an intermediate color including the three primary colors of red and blue is added, and applying by an appropriate coating method such as spray coating, electrostatic coating, electrophoretic coating, and then drying according to a conventional method, and curing if necessary. I just need.
【００１８】なお、上記有色透明塗膜の膜厚は１〜１０
０μｍ、特に３〜５０μｍとすることができるが、これ
に限定されるものではない。The colored transparent coating film has a thickness of 1-10.
The thickness may be 0 μm, particularly 3 to 50 μm, but is not limited thereto.
【００１９】[0019]
【実施例】以下、実施例により本発明を更に具体的に説
明するが、本発明は下記の実施例に制限されるものでは
ない。EXAMPLES The present invention will be described more specifically with reference to the following examples, but the present invention is not limited to the following examples.
【００２０】［実施例１］真鍮製のシャープペンチップ
基材の表面を羽布研摩して表面を平滑にした後、常法に
よって脱脂等の前処理を施し、光沢電気ニッケルめっき
を行い、上記基材上に厚さ５μｍの光沢ニッケルめっき
層を形成した。次いで、この光沢ニッケルめっき層上に
光沢電気銀めっきを施し、厚さ１μｍの光沢銀めっき層
を形成した。Example 1 After the surface of a brass mechanical pencil tip substrate was polished with a feather cloth to smooth the surface, pretreatment such as degreasing was performed by a conventional method, and bright electro-nickel plating was performed. A bright nickel plating layer having a thickness of 5 μm was formed on the substrate. Next, bright silver plating was performed on the bright nickel plating layer to form a bright silver plating layer having a thickness of 1 μm.
【００２１】なお、光沢電気ニッケルめっき液として
は、通常のワット浴に市販光沢剤（上村工業（株）製）
を添加したものを用い、光沢銀めっき液としては、Ａｇ
ＣＮ２５ｇ／ｌ，ＫＣＮ１１０ｇ／ｌの組成のものに市
販光沢剤を添加したものを用いた。As a bright electro-nickel plating solution, a commercial brightener (manufactured by Uemura Kogyo Co., Ltd.) is used in a normal watt bath.
And the bright silver plating solution is Ag
A composition having a composition of 25 g / l CN and 110 g / l KCN to which a commercially available brightener was added was used.
【００２２】更に、クリヤーラッカー（日本ペイント社
製）に黄色染料（オリエット化学工業（株）製、Ｙｅｌ
ｌｏｗ＃１０１）を添加したものを用い、上記光沢銀め
っき層上にスプレー塗装し、１８０℃で、３０分乾燥、
硬化して、厚さ１０μｍの黄色（金色）透明塗膜を形成
した。Further, a clear lacquer (manufactured by Nippon Paint Co., Ltd.) has a yellow dye (Yelt, manufactured by Oriet Chemical Industry Co., Ltd.)
low # 101), spray-coated on the bright silver plating layer, dried at 180 ° C. for 30 minutes,
It was cured to form a yellow (gold) transparent coating film having a thickness of 10 μm.
【００２３】得られた部品は、明るい透明感のある、華
麗な光沢黄金色外観を有し、装飾効果に優れているもの
であった。The obtained part had a bright and transparent appearance, a brilliant glossy golden appearance, and was excellent in a decorative effect.
【００２４】［比較例１］比較のため、上記光沢ニッケ
ルめっき層に直接上記と同じ黄色透明塗膜を形成したも
のは、その金色が暗い色調で華やかさがなく、装飾効果
が劣るものであった。[Comparative Example 1] For comparison, the same transparent yellow coating film as described above was directly formed on the above-mentioned bright nickel plating layer, the gold color was dark and did not show any gorgeousness, and the decorative effect was inferior. .
【００２５】［実施例２］真鍮製の口紅容器基材をショ
ットブラスト加工し、表面を梨地状に形成した。次い
で、実施例１と同様にして前処理を行った後、厚さ５μ
ｍの光沢ニッケルめっき層を形成した。Example 2 A brass lipstick container base material was shot blasted to form a matte surface. Next, after performing pretreatment in the same manner as in Example 1, the thickness was 5 μm.
m bright nickel plating layer was formed.
【００２６】次に、この光沢ニッケルめっき層上に光沢
電気錫めっきを行い、厚さ２μｍの光沢錫めっき層を形
成した。なお、光沢電気錫めっき液としては、 ホウフ
ッ化スズＳｎ（ＢＦ4）2２００ｇ／ｌ，ホウフッ化水素
酸ＨＢＦ4１５０ｇ／ｌ，ホウ酸ＨＢＯ3２５ｇ／ｌの組
成のものを用いた。Next, bright tin plating was performed on the bright nickel plating layer to form a bright tin plating layer having a thickness of 2 μm. The bright electrotin plating solution had a composition of tin borofluoride Sn (BF 4 ) 2 of 200 g / l, hydrofluoric acid of HBF 4 of 150 g / l, and boric acid of HBO 3 of 25 g / l.
【００２７】更に、実施例１と同様の黄色染料添加クリ
ヤーラッカーを用いて実施例１と同様の方法で厚さ１０
μｍの塗膜を形成した。Further, the same method as in Example 1 was applied to a layer having a thickness of 10 using the same yellow dye-added clear lacquer as in Example 1.
A μm coating film was formed.
【００２８】得られた部品は、明るい透明感のある、華
麗な黄金色を有していると共に、乱反射状の光沢を有
し、その明るさがより強調され、興趣の高い美麗な外観
を有していた。The obtained part has a bright golden color with a brilliant transparency, and also has a diffuse reflection-like luster, its brightness is emphasized more, and it has an attractive and beautiful appearance. Was.
【００２９】［比較例２］比較のため、上記光沢ニッケ
ルめっき層に直接上記と同じ黄色透明塗膜を形成したも
のは、華やかさに欠ける暗い金色外観を有するものであ
った。[Comparative Example 2] For comparison, the bright nickel plating layer directly having the same yellow transparent coating film as described above had a dark gold appearance lacking in gorgeousness.
【００３０】[0030]
【発明の効果】本発明の装飾部品は、明るい透明感を有
する有色の金属外観を与え、装飾効果に優れている上、
安価に製造し得、しかもその工程も簡単であるから、大
量加工に適したものである。The decorative part of the present invention gives a colored metallic appearance having a bright transparent feeling, and is excellent in decorative effect.
Since it can be manufactured at low cost and the process is simple, it is suitable for mass processing.
Claims (4)
性めっき層を形成し、該光輝性めっき層上に白色めっき
層を形成すると共に、該白色めっき層上に有色透明塗膜
を形成してなることを特徴とする装飾部品。1. A glittering plating layer is formed on a base material of a cosmetic or writing instrument part, a white plating layer is formed on the glittering plating layer, and a colored transparent coating is formed on the white plating layer. A decorative component characterized by being made.
求項１記載の装飾部品。2. The decorative component according to claim 1, wherein the surface of the base material is satin-finished.
ケル合金めっき層であり、白色めっき層が光沢銀めっき
層、光沢錫めっき層又は銀もしくは錫の合金めっき層で
ある請求項１又は２記載の装飾部品。3. The method according to claim 1, wherein the glittering plating layer is a bright nickel or nickel alloy plating layer, and the white plating layer is a bright silver plating layer, a bright tin plating layer, or a silver or tin alloy plating layer. Decoration parts.
性めっき層を形成し、該光輝性めっき層上に白色めっき
層を形成した後、該白色めっき層上に有色透明塗膜を形
成することを特徴とする装飾部品の製造方法。4. A brilliant plating layer is formed on a base material of a cosmetic or writing instrument component, a white plating layer is formed on the brilliant plating layer, and then a colored transparent coating is formed on the white plating layer. A method of manufacturing a decorative component.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12687698A JPH11301190A (en) | 1998-04-21 | 1998-04-21 | Decorative part and its manufacture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12687698A JPH11301190A (en) | 1998-04-21 | 1998-04-21 | Decorative part and its manufacture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11301190A true JPH11301190A (en) | 1999-11-02 |
Family
ID=14946042
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12687698A Pending JPH11301190A (en) | 1998-04-21 | 1998-04-21 | Decorative part and its manufacture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11301190A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001141844A (en) * | 1999-11-15 | 2001-05-25 | Kawaguchiko Seimitsu Co Ltd | Display plate |
| KR20020072141A (en) * | 2001-03-09 | 2002-09-14 | (주)유일금속 | Method of Two Tone over Printing for Metal |
| JP2008184669A (en) * | 2007-01-31 | 2008-08-14 | Pentel Corp | Clip, and manufacturing method therefor |
| JP2015155571A (en) * | 2014-02-21 | 2015-08-27 | 株式会社Ｋａｎｚａｃｃ | composite metal material |
-
1998
- 1998-04-21 JP JP12687698A patent/JPH11301190A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001141844A (en) * | 1999-11-15 | 2001-05-25 | Kawaguchiko Seimitsu Co Ltd | Display plate |
| KR20020072141A (en) * | 2001-03-09 | 2002-09-14 | (주)유일금속 | Method of Two Tone over Printing for Metal |
| JP2008184669A (en) * | 2007-01-31 | 2008-08-14 | Pentel Corp | Clip, and manufacturing method therefor |
| JP2015155571A (en) * | 2014-02-21 | 2015-08-27 | 株式会社Ｋａｎｚａｃｃ | composite metal material |
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