JPH11176438A - Lead-acid battery, and manufacture of material lead powder for lead-acid battery - Google Patents
Lead-acid battery, and manufacture of material lead powder for lead-acid batteryInfo
- Publication number
- JPH11176438A JPH11176438A JP9337020A JP33702097A JPH11176438A JP H11176438 A JPH11176438 A JP H11176438A JP 9337020 A JP9337020 A JP 9337020A JP 33702097 A JP33702097 A JP 33702097A JP H11176438 A JPH11176438 A JP H11176438A
- Authority
- JP
- Japan
- Prior art keywords
- lead
- powder
- alloy
- acid battery
- active material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Battery Electrode And Active Subsutance (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、鉛蓄電池用正極活
物質に使用する、鉛を主成分とする原料鉛粉の製造方法
とその原料鉛粉を用いた鉛蓄電池に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a lead powder containing lead as a main component, and a lead storage battery using the lead powder.
【０００２】[0002]
【従来の技術】鉛蓄電池は安価で信頼性が高いという特
徴を有するため、無停電電源装置用の電源として広く使
用されている。そして、最近ではこれらの装置に用いら
れる鉛蓄電池として、高率放電特性の向上が強く要求さ
れてきている。高率放電特性を向上させる手段として、
正極用活物質の利用率を向上させることが重要である。
なお、正極用活物質の利用率を向上させる手段として、
正極板の導電性を高くしたり電解液の拡散を良くするこ
とを目的として、酸化スズや硫酸カルシウムなどを鉛粉
に添加する方法が特開平８−１８０８７６号公報や特開
平９−２８９０２０号公報において開示されている。こ
れらの方法は、鉛粉と希硫酸との混合物であるペースト
状活物質に酸化スズや硫酸カルシウムの粉末を添加し、
それを鉛合金からなる格子体に塗着して作製するもので
ある。2. Description of the Related Art Lead storage batteries are widely used as power supplies for uninterruptible power supplies because of their low cost and high reliability. Recently, high-rate discharge characteristics have been strongly required to be improved as lead storage batteries used in these devices. As a means to improve high rate discharge characteristics,
It is important to improve the utilization rate of the positive electrode active material.
As a means for improving the utilization rate of the positive electrode active material,
JP-A-8-180876 and JP-A-9-289020 disclose a method of adding tin oxide, calcium sulfate, and the like to lead powder for the purpose of increasing the conductivity of the positive electrode plate and improving the diffusion of the electrolyte. Are disclosed. These methods add tin oxide or calcium sulfate powder to a paste active material that is a mixture of lead powder and dilute sulfuric acid,
It is produced by coating it on a grid made of a lead alloy.
【０００３】しかしながら、上述した方法による鉛蓄電
池は以下に示すような問題点がある。すなわち、酸化ス
ズや硫酸カルシウムの粉末を活物質に添加した場合に
は、０．３ＣＡ程度の低率放電において正極用活物質利
用率の向上が認められる。しかし、３ＣＡ程度の高率放
電では、正極用活物質利用率の向上がほとんど効果が認
められないことが明らかになっている。さらに、鉛粉と
酸化スズや硫酸カルシウムとは比重が大きく異なるた
め、混合に時間がかかり、製造コストが増加するという
問題点もある。However, the lead storage battery according to the above-described method has the following problems. That is, when tin oxide or calcium sulfate powder is added to the active material, an improvement in the utilization rate of the positive electrode active material is observed at a low rate discharge of about 0.3 CA. However, it has been clarified that in a high-rate discharge of about 3 CA, the effect of improving the utilization rate of the positive electrode active material is hardly recognized. Furthermore, since the specific gravity of the lead powder is greatly different from that of tin oxide or calcium sulfate, it takes a long time to mix the powder and the production cost increases.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、前記問題点
に鑑みてなされたものであって、高率放電特性の優れた
鉛蓄電池を製造することである。SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned problems, and an object of the present invention is to produce a lead storage battery having excellent high-rate discharge characteristics.
【０００５】[0005]
【課題を解決するための手段】上記の課題を解決するた
めに本発明では、鉛にカルシウムまたはスズの少なくと
も一方を添加した合金を用いる。そして、その合金から
ボールミル式またはバートンポット式のいずれかの鉛粉
製造機を用いて鉛粉を製造し、その鉛粉を鉛蓄電池の電
極に用いることを特徴としている。In order to solve the above problems, the present invention uses an alloy in which at least one of calcium and tin is added to lead. Then, lead powder is produced from the alloy using a ball mill type or barton pot type lead powder production machine, and the lead powder is used for an electrode of a lead storage battery.
【０００６】[0006]
【発明の実施の形態】Ｐｂ−０．１ｗｔ．％Ｃａ、Ｐｂ
−１ｗｔ．％Ｓｎ又はＰｂ−０．１ｗｔ．％Ｃａ−１ｗ
ｔ．％Ｓｎの３種類の鉛を主成分とする合金を用いて粉
末を作製した。これらの鉛合金を通常の鉛粉を作るボー
ルミルに投入して一酸化鉛を主成分とする粉末を作成し
た。これら３種類の粉末を希硫酸で混練してペースト状
活物質を作製した。そして、このペースト状活物質をＰ
ｂ−Ｃａ−Ｓｎ合金製の格子体に充填して正極板とし
た。以下に、本発明の一実施例を示す。DESCRIPTION OF THE PREFERRED EMBODIMENTS Pb-0.1 wt. % Ca, Pb
-1 wt. % Sn or Pb-0.1 wt. % Ca-1w
t. % Sn was used to prepare a powder. These lead alloys were charged into a ball mill for producing ordinary lead powder to prepare a powder mainly composed of lead monoxide. These three kinds of powders were kneaded with dilute sulfuric acid to prepare a paste-like active material. Then, this paste-like active material is
The positive electrode plate was filled in a lattice made of a b-Ca-Sn alloy. An embodiment of the present invention will be described below.
【０００７】[0007]
【実施例】（実施例１）前記した組成がＰｂ−０．１ｗ
ｔ．％Ｃａの鉛粉１００重量部と、濃度３５ｗｔ．％の
硫酸１５重量部とを混練し、正極用のペースト状活物質
を作製した。一方、従来から使用していた純度９９．９
９％の鉛塊をボールミルに投入して一酸化鉛を主成分と
する粉末を作成した。この粉末１００重量部、リグニン
０．２重量部、硫酸バリウム０．５重量部と、濃度３５
ｗｔ．％の硫酸１５重量部を混練して負極用のペースト
状活物質を作製した。作製したこれらのペースト状活物
質を、Ｐｂ−０．０８ｗｔ．％Ｃａ−１．５ｗｔ．％Ｓ
ｎ合金製で寸法がw ４０ｍｍ × l ７０ｍｍ × t
３ｍｍの格子体に充填し、大気中、６０℃、相対湿度９
０％、２４時間放置して未化成の鉛蓄電池用極板を作製
した。この正極板と負極板とをガラス繊維セパレータを
介して組み合わせてＡＢＳ製電槽に組み込んだ後、濃度
３０ｗｔ．％の希硫酸電解液を注入した。その後、正極
活物質の理論容量の２倍の電気量で充電して電槽化成
し、公称容量７Ａｈ（ただし２０時間率容量）の鉛蓄電
池を作製した。作製した電池は、２１Ａ（３ＣＡ）の電
流で終止電圧１．３Ｖ／セルまで放電して放電時間を測
定した。(Example 1) The composition described above was Pb-0.1w
t. % Lead powder of 100% Ca and a concentration of 35 wt. And 15 parts by weight of sulfuric acid to obtain a paste-like active material for a positive electrode. On the other hand, a purity of 99.9 which has been conventionally used.
A 9% lead lump was charged into a ball mill to prepare a powder mainly composed of lead monoxide. 100 parts by weight of this powder, 0.2 parts by weight of lignin, 0.5 parts by weight of barium sulfate and a concentration of 35 parts
wt. % Of sulfuric acid was kneaded to prepare a paste-like active material for a negative electrode. These paste-like active materials thus prepared were mixed with Pb-0.08 wt. % Ca-1.5 wt. % S
Made of n alloy with dimensions w 40 mm x l 70 mm x t
Filled into a 3mm grid, in air, 60 ° C, relative humidity 9
It was left at 0% for 24 hours to produce an unformed lead-acid battery electrode plate. After combining the positive electrode plate and the negative electrode plate via a glass fiber separator and assembling them in an ABS battery case, the concentration was 30 wt. % Dilute sulfuric acid electrolyte was injected. Thereafter, the battery was charged with an amount of electricity twice the theoretical capacity of the positive electrode active material to form a battery case, thereby producing a lead-acid battery having a nominal capacity of 7 Ah (20 hour rate capacity). The prepared battery was discharged at a current of 21 A (3 CA) to a cutoff voltage of 1.3 V / cell, and the discharge time was measured.
【０００８】（実施例２）組成がＰｂ−１ｗｔ．％Ｓｎ
の鉛粉１００重量部と、濃度３５ｗｔ．％の硫酸１５重
量部とを混練し、正極用のペースト状活物質を作製し
た。それを、実施例１で用いた鉛合金製の格子体に充填
した。この後、（実施例１）に示した条件で正極板・負
極板及び電池を作製して試験した。Example 2 When the composition is Pb-1 wt. % Sn
100 parts by weight of lead powder and a concentration of 35 wt. And 15 parts by weight of sulfuric acid to obtain a paste-like active material for a positive electrode. It was filled into the lead alloy lattice used in Example 1. Thereafter, a positive electrode plate / negative electrode plate and a battery were prepared and tested under the conditions shown in (Example 1).
【０００９】（実施例３）組成がＰｂ−０．１ｗｔ．％
Ｃａ−１ｗｔ．％Ｓｎの鉛粉１００重量部と、濃度３５
ｗｔ．％の硫酸１５重量部とを混練し、正極用のペース
ト状活物質を作製した。それを、実施例１で用いた鉛合
金製の格子体に充填した。この後、（実施例１）に示し
た条件で正極板・負極板及び電池を作製して試験した。Example 3 The composition was Pb-0.1 wt. %
Ca-1 wt. % Sn lead powder 100 parts by weight and concentration 35
wt. And 15 parts by weight of sulfuric acid to obtain a paste-like active material for a positive electrode. It was filled into the lead alloy lattice used in Example 1. Thereafter, a positive electrode plate / negative electrode plate and a battery were prepared and tested under the conditions shown in (Example 1).
【００１０】（比較例１）純度９９．９９％の鉛塊を用
いて作成した鉛粉１００重量部と、濃度３５ｗｔ．％の
硫酸１５重量部とを混練し、正極用のペースト状活物質
を作製した。それを、実施例１で用いた鉛合金製の格子
体に充填した。この後、（実施例１）に示した条件で正
極板・負極板及び電池を作製して試験した。(Comparative Example 1) 100 parts by weight of a lead powder prepared using a lead lump having a purity of 99.99%, and a concentration of 35 wt. And 15 parts by weight of sulfuric acid to obtain a paste-like active material for a positive electrode. It was filled into the lead alloy lattice used in Example 1. Thereafter, a positive electrode plate / negative electrode plate and a battery were prepared and tested under the conditions shown in (Example 1).
【００１１】（比較例２）純度９９．９９％の鉛塊を用
いて作成した鉛粉１００重量部と、酸化カルシウム粉末
０．２重量部、濃度３５ｗｔ．％の硫酸１５重量部とを
混練し、正極用のペースト状活物質を作製した。それ
を、実施例１で用いた鉛合金製の格子体に充填した。こ
の後、（実施例１）に示した条件で正極板・負極板及び
電池を作製して試験した。Comparative Example 2 100 parts by weight of a lead powder prepared using a lead lump having a purity of 99.99%, 0.2 parts by weight of a calcium oxide powder, and a concentration of 35 wt. And 15 parts by weight of sulfuric acid to obtain a paste-like active material for a positive electrode. It was filled into the lead alloy lattice used in Example 1. Thereafter, a positive electrode plate / negative electrode plate and a battery were prepared and tested under the conditions shown in (Example 1).
【００１２】（比較例３）純度９９．９９％の鉛塊を用
いて作成した鉛粉１００重量部と、酸化カルシウム粉末
０．２重量部、酸化スズ粉末２重量部、濃度３５ｗｔ．
％の硫酸１５重量部とを混練し、正極用のペースト状活
物質を作製した。それを、実施例１で用いた鉛合金製の
格子体に充填した。この後、（実施例１）に示した条件
で正極板・負極板及び電池を作製して試験した。Comparative Example 3 100 parts by weight of a lead powder prepared using a lead lump having a purity of 99.99%, 0.2 parts by weight of a calcium oxide powder, 2 parts by weight of a tin oxide powder, and a concentration of 35 wt.
And 15 parts by weight of sulfuric acid to obtain a paste-like active material for a positive electrode. It was filled into the lead alloy lattice used in Example 1. Thereafter, a positive electrode plate / negative electrode plate and a battery were prepared and tested under the conditions shown in (Example 1).
【００１３】以上、作製した６種類の電池の３ＣＡ放電
時間を測定した結果を表１に示す。実施例１〜３は、比
較例１〜３に比べて、３ＣＡ放電特性が良好である。こ
の理由として、粉末中にカルシウムやスズが均一に分散
しているため、高率放電持続時間が大幅に向上したもの
と考えられる。Table 1 shows the results of measuring the 3CA discharge time of the six types of batteries manufactured as described above. Examples 1 to 3 have better 3CA discharge characteristics than Comparative Examples 1 to 3. It is considered that the reason is that calcium and tin are uniformly dispersed in the powder, so that the high-rate discharge duration is greatly improved.
【００１４】[0014]
【表１】 [Table 1]
【００１５】実施例ではボールミル式鉛粉製造機によっ
て製造した粉末を使用した場合について述べたが、バー
トンポット式鉛粉製造機によって製造した粉末を使用し
た場合についても同様の効果を示した。In the embodiment, the case where the powder produced by the ball mill type lead powder producing machine is used has been described. However, the same effect is obtained when the powder produced by the barton pot type lead powder producing machine is used.
【００１６】[0016]
【発明の効果】上述したように本発明は、鉛を主成分と
する粉末を活物質として使用する鉛蓄電池において、高
率放電特性に優れた電池を製造できる。さらに製造設備
を変更することが無いため、コストの増加はほとんどな
く、工業的価値は非常に高いものである。As described above, according to the present invention, in a lead storage battery using a powder containing lead as a main component as an active material, a battery excellent in high rate discharge characteristics can be manufactured. Further, since there is no change in manufacturing equipment, there is almost no increase in cost, and the industrial value is very high.
Claims (3)
する鉛蓄電池において、前記鉛を主成分とする粉末は鉛
にカルシウムまたはスズの少なくとも一方を添加した合
金から粉末化したものであることを特徴とする鉛蓄電
池。1. A lead-acid battery using a lead-based powder as an active material, wherein the lead-based powder is powdered from an alloy in which at least one of calcium and tin is added to lead. A lead-acid battery characterized by the above-mentioned.
に鉛合金を投入し、酸化と粉砕とを同時に行うボールミ
ル式の鉛粉製造機を用い、前記鉛合金にカルシウムまた
はスズの少なくとも一方を含むものを用いることを特徴
とする鉛蓄電池用原料鉛粉の製造方法。2. A lead mill of a ball mill type, in which a lead alloy is charged into a rotating drum while supplying air, and oxidization and pulverization are performed simultaneously, wherein at least one of calcium and tin is used as the lead alloy. A method for producing a raw material lead powder for a lead-acid battery, comprising:
速で回転する翼に吹き付けて酸化させることによって製
造するバートンポット式の鉛粉製造機を用い、前記鉛合
金にカルシウムまたはスズの少なくとも一方を含むもの
を用いることを特徴とする鉛蓄電池用原料鉛粉の製造方
法。3. A barton pot type lead powder production machine for producing a molten lead alloy by blowing it onto a rotating blade at a high speed while supplying air to oxidize the lead alloy, wherein the lead alloy contains at least calcium or tin. A method for producing a raw material lead powder for a lead-acid battery, characterized by using one of them.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9337020A JPH11176438A (en) | 1997-12-08 | 1997-12-08 | Lead-acid battery, and manufacture of material lead powder for lead-acid battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9337020A JPH11176438A (en) | 1997-12-08 | 1997-12-08 | Lead-acid battery, and manufacture of material lead powder for lead-acid battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11176438A true JPH11176438A (en) | 1999-07-02 |
Family
ID=18304713
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9337020A Pending JPH11176438A (en) | 1997-12-08 | 1997-12-08 | Lead-acid battery, and manufacture of material lead powder for lead-acid battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11176438A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001004976A1 (en) * | 1999-07-09 | 2001-01-18 | Japan Storage Battery Co., Ltd. | Positive plate current collector for lead storage battery and lead storage battery comprising the same |
| EP1801902A2 (en) * | 2005-12-21 | 2007-06-27 | Shin-Kobe Electric Machinery Co., Ltd. | Lead acid battery |
| CN102303119A (en) * | 2011-05-16 | 2012-01-04 | 安徽奥力机械科技有限公司 | Full-automatic lead ingot granulating machine |
| CN106077680A (en) * | 2016-08-25 | 2016-11-09 | 四川荣联电子科技有限公司 | Prevent the powder manufacturing apparatus that constant temperature raises |
| CN106077681A (en) * | 2016-08-25 | 2016-11-09 | 四川荣联电子科技有限公司 | Improve the lead-power machine of milling efficiency |
| CN115889786A (en) * | 2022-09-23 | 2023-04-04 | 湖州德旭科技有限公司 | Preparation process of lead powder for long-life lead-acid storage battery |
-
1997
- 1997-12-08 JP JP9337020A patent/JPH11176438A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001004976A1 (en) * | 1999-07-09 | 2001-01-18 | Japan Storage Battery Co., Ltd. | Positive plate current collector for lead storage battery and lead storage battery comprising the same |
| US6620551B1 (en) | 1999-07-09 | 2003-09-16 | Japan Storage Battery Co., Ltd. | Positive plate current collector for lead storage battery and lead storage battery comprising the same |
| EP1801902A2 (en) * | 2005-12-21 | 2007-06-27 | Shin-Kobe Electric Machinery Co., Ltd. | Lead acid battery |
| EP1801902A3 (en) * | 2005-12-21 | 2007-07-18 | Shin-Kobe Electric Machinery Co., Ltd. | Lead acid battery |
| CN102303119A (en) * | 2011-05-16 | 2012-01-04 | 安徽奥力机械科技有限公司 | Full-automatic lead ingot granulating machine |
| CN106077680A (en) * | 2016-08-25 | 2016-11-09 | 四川荣联电子科技有限公司 | Prevent the powder manufacturing apparatus that constant temperature raises |
| CN106077681A (en) * | 2016-08-25 | 2016-11-09 | 四川荣联电子科技有限公司 | Improve the lead-power machine of milling efficiency |
| CN115889786A (en) * | 2022-09-23 | 2023-04-04 | 湖州德旭科技有限公司 | Preparation process of lead powder for long-life lead-acid storage battery |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5302476A (en) | High performance positive electrode for a lead-acid battery | |
| JPH11176438A (en) | Lead-acid battery, and manufacture of material lead powder for lead-acid battery | |
| JP2000251896A (en) | Lead-acid battery and its manufacture | |
| JPH11213993A (en) | Manufacture of sealed lead-acid battery | |
| US4329408A (en) | Lead oxide composition for use in lead-acid batteries | |
| JP4293130B2 (en) | Positive electrode plate for lead acid battery and lead acid battery | |
| JPS6060A (en) | Positive electrode active substance for lead storage battery and battery utilizing said active substance | |
| JP3835093B2 (en) | Sealed lead acid battery | |
| JP3511949B2 (en) | Sealed lead-acid battery | |
| JP3575145B2 (en) | Negative electrode plate for lead storage battery and method for producing the same | |
| JPH11162456A (en) | Lead-acid battery | |
| JP2003142147A (en) | Lead-acid battery | |
| KR100342198B1 (en) | Method for producing the positive plate of a lead battery | |
| JP2000200598A (en) | Sealed lead-acid battery | |
| US5352549A (en) | Lead oxide composition for use in lead-acid batteries | |
| JP2004055309A (en) | Manufacturing method of pasty active material for positive electrodes, and lead storage battery using it | |
| JP4501246B2 (en) | Control valve type stationary lead acid battery manufacturing method | |
| JPH11162455A (en) | Lead-acid battery | |
| JP3013623B2 (en) | Sealed lead-acid battery | |
| JPH11135117A (en) | Lead-acid battery | |
| JP2002198041A (en) | Manufacturing method of positive pole plate for lead acid battery | |
| JP2000182615A (en) | Lead-acid battery | |
| JP3040718B2 (en) | Lead storage battery | |
| JPS588558B2 (en) | Positive electrode grid for lead-acid batteries | |
| JP2004111226A (en) | Positive electrode plate for lead-acid battery, and its manufacturing method |