JPH10510308A - ジアシルペルオキシドの粒子を含む自動食器洗浄組成物 - Google Patents
ジアシルペルオキシドの粒子を含む自動食器洗浄組成物Info
- Publication number
- JPH10510308A JPH10510308A JP8517726A JP51772696A JPH10510308A JP H10510308 A JPH10510308 A JP H10510308A JP 8517726 A JP8517726 A JP 8517726A JP 51772696 A JP51772696 A JP 51772696A JP H10510308 A JPH10510308 A JP H10510308A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- weight
- sodium
- diacyl peroxide
- peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3951—Bleaching agents combined with specific additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Biochemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 顆粒または粉末状の自動食器洗浄用洗剤組成物であって、前記組成物の 重量で約0.01%〜約20%の水不溶性のジアシルペルオキシドを含んでなり 、前記ジアシルペルオキシドをジアシルペルオキシド粒子として組成物に添加し 、前記粒子が、前記粒子の重量で、一般式 RC(O)OO(O)CR1 (式中、RおよびR1は、同一でもまたは異なっていてもよく、好ましくは一方 だけが10個の炭素原子より長いヒドロカルビル鎖であり、更に好ましくは少な くとも一方が芳香族核を有する)を有する約1%〜約80%の水不溶性ジアシル ペルオキシドと、約0.01%〜約95%の前記ジアシルペルオキシドが溶解し ない安定化添加剤とを含んでなり、前記安定化添加剤が無機塩、遷移金属キレー ト化剤、酸化防止剤、結合剤、コーティング剤、およびそれらの混合物からなる 群から選択され、好ましくは無機塩、結合剤、コーティング剤、およびそれらの 混合物からなる群から選択され、前記組成物の洗浄溶液pHが8〜13であり、 好ましくは9〜12であり、前記組成物がプラスチック容器からカロチノイドの 染みを除去することを特徴とする、組成物。 2. 前記組成物が0.1%〜10%の水不溶性のジアシルペルオキシドを含 む、請求の範囲第1項に記載の組成物。 3. 組成物の重量で、低起泡性のノニオン界面活性剤0.1%〜10%を含 み、好ましくは前記の低起泡性のノニオン性界面活性剤が100°Fを下回る温 度下で固体である、請求の範囲第1項または第2項に記載の組成物。 4. (i) 炭酸またはセスキ炭酸ナトリウム/カリウム、 (ii) クエン酸ナトリウム/カリウム、 (iii) クエン酸、 (iv) 重炭酸ナトリウム/カリウム、 (v) ホウ酸ナトリウム/カリウム、好ましくはホウ砂、 (vi) 水酸化ナトリウム/カリウム、 (vii) ケイ酸ナトリウム/カリウム、および (viii)それらの混合物 からなる群から選択されるpH調整成分も含む、請求の範囲第1〜3項のいずれ か1項に記載の組成物。 5. 組成物の重量で、塩素漂白剤または過酸素漂白剤、好ましくは過炭酸塩 、過硫酸塩、過ホウ酸塩、およびそれらの混合物からなる群から選択されるもの 、およびMnIV 2(u−O)3(1,4,7−トリメチル−1,4,7−トリアシ クロノナン)2−(PF6)2、MnIII 2(u−O)1(u−OAc)2(1,4, 7−トリメチル−1,4,7−トリアシクロノナン)2−(ClO4)2、MnIV 4 (u−O)6(1,4,7−トリアシクロノナン)4−(ClO4)2、MnIIIM nIV 4(u−O)1(u−OAc)2(1,4,7−トリメチル−1,4,7−ト リアザシクロノナン)2−(ClO4)3、Mn(1,4,7−トリメチル−1, 4,7−トリアシクロノナン(OCH3)3−(PF6)、Co(2,2′−ビス ピリジル−アミン)Cl2、ジ−(イソチオシアナト)ビスピリジルアミン−コ バルト(II)、トリスジピリジルアミン−コバルト(II)ペルクロレート、Co(2 ,2−ビスピリジルアミン)2−O2ClO4、ビス(2,2′−ビスピリジルア ミン)銅(II)ペルクロレート、トリス(ジ−2−ピリジルアミン)鉄(II)ペルク ロレート、Mnグルコネート、Mn(CF3SO3)2、Co(NH3)5Cl、テ トラ−N−デンテートおよびビ−N−デンテート配位子と錯体形成した二核性M n、例えばN4MnIII(u−O)2MnIVN4)+および[ビpy2MnIII(u− O)2MnIVビpy2]−(ClO4)3、およびそれらの混合物からなる群から選 択される漂白剤触媒をも含む、請求の範囲第 1〜4項のいずれか1項に記載の組成物。 6. 組成物の重量で、好ましくはプロテアーゼ、アミラーゼ、リパーゼおよ びそれらの混合物からなる群から選択される洗剤酵素0.001%〜5%、更に 好ましくはプロテアーゼまたはアミラーゼ0.005%〜3%をも含む、請求の 範囲第1〜5項のいずれか1項に記載の組成物。 7. 前記組成物の重量で、3%〜10%のSiO2も含み、前記組成物重量 でポリアクリレートおよびポリアクリレートコポリマーからなる群から選択され る分散剤0.5%〜20%を含む、請求の範囲第1〜6項のいずれか1項に記載 の組成物。 8. 前記のジアシルペルオキシドがジベンゾイルペルオキシドであり、平均 粒度が150μm未満である、請求の範囲第1〜7項のいずれか1項に記載の組 成物。 9. 顆粒状または粉末状の自動食器洗浄用洗剤組成物であって、 (a) 平均粒度が600μm〜800μmのジアシルペルオキシド粒状物質1重 量%〜15重量%であって、前記ジアシルペルオキシド粒状物質が5重量%〜4 0重量%のジアシルペルオキシドおよび0.01重量%〜95重量%の安定化添 加剤であって、前記ジアシルペルオキシドが溶解しないものを含み、前記安定化 添加剤は、無機塩、酸化防止剤、結合剤、コーティング剤、遷移金属キレート化 剤およびそれらの混合物からなる群から選択されるもの、 (b) 過酸素漂白剤の利用可能な酸素として0.01重量%〜8重量%、 (c) 炭酸ナトリウム、セスキ炭酸ナトリウム、クエン酸ナトリウム、クエン酸 、重炭酸ナトリウム、水酸化ナトリウム、およびそれらの混合物から選択される 水溶性塩または塩/ビルダー混合物からなるpH調整成分0.1重量%〜50重 量%、 (d) SiO2としてのケイ酸塩3重量%〜10重量%、 (e) アミンオキシド以外の低起泡性のノニオン性界面活性剤0〜10重量%、 (f) シリコーン気泡抑制剤0〜10重量%、 (g) 活性な洗剤用酵素0.01重量%〜5重量%、および (h) 分散剤ポリマー0〜25重量% を含んでなり、 洗浄溶液pHが9.5〜11.5であることを特徴とする、組成物。 10. 食器を、少なくともpH8であって、少なくとも0.1重量%の水不 溶性のジアシルペルオキシドを含んでなる洗浄水性媒体と接触させることを特徴 とする、汚れた食器のクリーニング法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US35246894A | 1994-12-09 | 1994-12-09 | |
US08/352,468 | 1994-12-09 | ||
PCT/US1995/015815 WO1996017921A1 (en) | 1994-12-09 | 1995-12-01 | Automatic dishwashing composition containing particles of diacyl peroxides |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH10510308A true JPH10510308A (ja) | 1998-10-06 |
Family
ID=23385251
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8517726A Pending JPH10510308A (ja) | 1994-12-09 | 1995-12-01 | ジアシルペルオキシドの粒子を含む自動食器洗浄組成物 |
Country Status (12)
Country | Link |
---|---|
US (1) | US5710115A (ja) |
EP (1) | EP0796317B1 (ja) |
JP (1) | JPH10510308A (ja) |
AT (1) | ATE190090T1 (ja) |
CA (1) | CA2206992C (ja) |
DE (1) | DE69515331T2 (ja) |
DK (1) | DK0796317T3 (ja) |
ES (1) | ES2145315T3 (ja) |
GR (1) | GR3032909T3 (ja) |
HK (1) | HK1003389A1 (ja) |
PT (1) | PT796317E (ja) |
WO (1) | WO1996017921A1 (ja) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004526826A (ja) * | 2001-02-14 | 2004-09-02 | ザ プロクター アンド ギャンブル カンパニー | ジアシルペルオキシド漂白剤及びブルーミング香料を含んでなる自動食器洗浄用組成物 |
JP2006342256A (ja) * | 2005-06-09 | 2006-12-21 | Adeka Corp | 飲料ディスペンサ用洗浄剤組成物 |
JP2008540743A (ja) * | 2005-05-13 | 2008-11-20 | ザ プロクター アンド ギャンブル カンパニー | 漂白製品 |
JP6035447B1 (ja) * | 2016-05-30 | 2016-11-30 | 株式会社ニイタカ | 自動洗浄機用洗浄剤組成物 |
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- 1995-12-01 DE DE69515331T patent/DE69515331T2/de not_active Expired - Lifetime
- 1995-12-01 AT AT95941520T patent/ATE190090T1/de not_active IP Right Cessation
- 1995-12-01 DK DK95941520T patent/DK0796317T3/da active
- 1995-12-01 JP JP8517726A patent/JPH10510308A/ja active Pending
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Cited By (5)
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JP2004526826A (ja) * | 2001-02-14 | 2004-09-02 | ザ プロクター アンド ギャンブル カンパニー | ジアシルペルオキシド漂白剤及びブルーミング香料を含んでなる自動食器洗浄用組成物 |
JP2008540743A (ja) * | 2005-05-13 | 2008-11-20 | ザ プロクター アンド ギャンブル カンパニー | 漂白製品 |
JP2006342256A (ja) * | 2005-06-09 | 2006-12-21 | Adeka Corp | 飲料ディスペンサ用洗浄剤組成物 |
JP6035447B1 (ja) * | 2016-05-30 | 2016-11-30 | 株式会社ニイタカ | 自動洗浄機用洗浄剤組成物 |
JP2017214447A (ja) * | 2016-05-30 | 2017-12-07 | 株式会社ニイタカ | 自動洗浄機用洗浄剤組成物 |
Also Published As
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DK0796317T3 (da) | 2000-06-05 |
GR3032909T3 (en) | 2000-07-31 |
EP0796317B1 (en) | 2000-03-01 |
HK1003389A1 (en) | 1998-10-30 |
DE69515331T2 (de) | 2000-10-19 |
US5710115A (en) | 1998-01-20 |
ES2145315T3 (es) | 2000-07-01 |
CA2206992A1 (en) | 1996-06-13 |
DE69515331D1 (de) | 2000-04-06 |
WO1996017921A1 (en) | 1996-06-13 |
EP0796317A1 (en) | 1997-09-24 |
CA2206992C (en) | 2001-04-10 |
PT796317E (pt) | 2000-08-31 |
ATE190090T1 (de) | 2000-03-15 |
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