JPH10500723A - 硬化性エチレン共重合体ブレンド組成物 - Google Patents
硬化性エチレン共重合体ブレンド組成物Info
- Publication number
- JPH10500723A JPH10500723A JP7530363A JP53036395A JPH10500723A JP H10500723 A JPH10500723 A JP H10500723A JP 7530363 A JP7530363 A JP 7530363A JP 53036395 A JP53036395 A JP 53036395A JP H10500723 A JPH10500723 A JP H10500723A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- ethylene
- copolymer
- parts
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
- C08L23/0876—Neutralised polymers, i.e. ionomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.a)エチレンと、C1〜C8アルキルアクリレート類、C1〜C8アルキルメタ クリレート類およびC2〜C8カルボン酸のビニルエステル類より成る群から選ば れたモノマーとが共重合した単位を有するジポリマー; b)i)エチレンと、ii)C1〜C8アルキルアクリレート類、C1〜C8アル キルメタクリレート類およびC2〜C8カルボン酸のビニルエステル類より成る群 から選ばれたコモノマー、並びにiii)α,β−不飽和モノカルボン酸類、α, β−不飽和ジカルボン酸類、およびα,β−不飽和ジカルボン酸のモノエステル 類より成る群から選ばれた少なくとも1種の3〜12炭素原子カルボン酸が共重 合した単位を有するコポリマー、ここで該コポリマーは金属イオンで少なくとも 10%の程度まで中和されている;および c)成分a)および成分b)の総量100部当たり0.5〜6部の有機過酸 化物のブレンドを含んで成り、ここで成分a)の成分b)に対する比が99:1 〜70:30であり、そして前記ブレンドは実質的に発泡剤を含まないことを特 徴とする硬化性組成物。 2.前記有機過酸化物は成分a)および成分b)の総量100部当たり2〜4部 の量で存在することを特徴とする請求項1記載の組成物。 3.前記ジポリマーはエチレンとC1〜C8アルキルメタクリレートが共重合した 単位を含有することを特徴とする請求項1記載の組成物。 4.前記C1〜C8アルキルメタクリレートはメチルメタクリレートであることを 特徴とする請求項3記載の組成物。 5.前記ジポリマーはエチレンとC2〜C4カルボン酸のビニルエステルが共重 合した単位を含有することを特徴とする請求項1記載の組成物。 6.前記ビニルエステルはビニルアセテートであることを特徴とする請求項5記 載の組成物。 7.前記成分b)はエチレンとC1〜C8アルキルアクリレートのコポリマーであ ることを特徴とする請求項1記載の組成物。 8.前記コポリマーはエチレンとメチルアクリレートのコポリマーであることを 特徴とする請求項7記載の組成物。 9.前記コポリマーはエチレン、メチルアクリレートおよびα,β−不飽和ジカ ルボン酸のモノエステルのコポリマーであることを特徴とする請求項8記載の組 成物。 10.さらに助剤を含有することを特徴とする請求項1記載の組成物。 11.a)エチレンと、C1〜C8アルキルアクリレート類、C1〜C8アルキルメ タクリレート類およびC2〜C8カルボン酸のビニルエステル類より成る群から選 ばれたモノマーとが共重合した単位を有するジポリマー; b)i)エチレンと、ii)C1〜C8アルキルアクリレート類、C1〜C8ア ルキルメタクリレート類およびC2〜C8カルボン酸のビニルエステル類より成る 群から選ばれたコモノマーと、iii)α,β−不飽和モノカルボン酸類、α,β −不飽和ジカルボン酸類、およびα,β−不飽和ジカルボン酸のモノエステル類 より成る群から選ばれた少なくとも1種の3〜12炭素原子カルボン酸とが共重 合した単位を有するコポリマー;ここで該コポリマーは金属イオンで少なくとも 10%の程度まで中和されている; c)成分a)および成分b)の総量100部当たり0.5〜6部の有機過 酸化物;および d)成分a)および成分b)の総量100部当たり1〜50部の、カルボ ン酸基と反応してカルボン酸塩を形成することができる金属化合物 を混合することを含み、ここで成分a)の成分b)に対する比が99:1〜70 :30であり、そして前記ブレンドは実質的に発泡剤を含まないことを特徴とす る請求項1記載の硬化性組成物の調製方法。 12.請求項1記載の組成物を押出機またはカレンダーに導入し、該組成物を、 実質的な架橋が起きない条件下で押出しまたはカレンダー掛けし、そして押出ま たはカレンダー掛けされた組成物を外圧が適用されない条件下で100〜300 ℃の間の温度に加熱し、それにより非多孔質の架橋された組成物を製造すること を特徴とする請求項1記載の組成物の硬化方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/246,208 | 1994-05-19 | ||
US08/246,208 US5492971A (en) | 1994-05-19 | 1994-05-19 | Curable ethylene copolymer blend composition |
PCT/US1995/006088 WO1995032241A1 (en) | 1994-05-19 | 1995-05-15 | Curable ethylene copolymer blend composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH10500723A true JPH10500723A (ja) | 1998-01-20 |
JP3604392B2 JP3604392B2 (ja) | 2004-12-22 |
Family
ID=22929729
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP53036395A Expired - Fee Related JP3604392B2 (ja) | 1994-05-19 | 1995-05-15 | 硬化性エチレン共重合体ブレンド組成物 |
Country Status (5)
Country | Link |
---|---|
US (2) | US5492971A (ja) |
EP (1) | EP0759954B1 (ja) |
JP (1) | JP3604392B2 (ja) |
DE (1) | DE69502019T2 (ja) |
WO (1) | WO1995032241A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011521802A (ja) * | 2008-05-01 | 2011-07-28 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | エチレン酸コポリマーおよび官能性エチレンコポリマーを含む組成物 |
CN109679213A (zh) * | 2018-12-27 | 2019-04-26 | 宣城广能非织造有限公司 | 一种增加油过滤性能的功能母料及其制备方法 |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6743847B1 (en) * | 1994-12-20 | 2004-06-01 | Callaway Golf Company | Golf ball cover compositions |
US6217982B1 (en) | 1997-10-10 | 2001-04-17 | E. I. Du Pont De Nemours And Company | Thermoplastic polymer alloy composition |
DE60028214T2 (de) * | 1999-06-21 | 2007-05-03 | Daikin Industries, Ltd. | Verwendung einer vernetzten elastomerenzusammensetzung zur versiegelung einer halbleiterherstellungsvorrichtung |
US20050004298A1 (en) * | 1999-06-21 | 2005-01-06 | Daikin Industries, Ltd. | Crosslinkable elastomer composition and molded article produced from same |
CA2437913A1 (en) * | 2002-10-09 | 2004-04-09 | The Goodyear Tire & Rubber Company | Hose construction containing polymer composition |
US7521503B2 (en) * | 2003-07-24 | 2009-04-21 | E. I. Du Pont De Nemours And Company | Ethylene/alkyl acrylate copolymers, compounds and vulcanizates thereof |
US7153918B2 (en) * | 2003-07-24 | 2006-12-26 | E. I. Du Pont De Nemours And Company | Random ethylene/alkyl acrylate copolymers, compounds and elastomeric compositions thereof with improved low temperature properties |
US20060263556A1 (en) * | 2003-09-15 | 2006-11-23 | Dayco Products, Llc | Elastomer compositions for use in a hydrocarbon resistant hose |
US20060270783A1 (en) * | 2003-09-15 | 2006-11-30 | Dayco Products, Llc | Elastomer compositions for use in a hydrocarbon resistant hose |
US20050059763A1 (en) * | 2003-09-15 | 2005-03-17 | Beck Harold D. | Elastomer compositions for use in a hydrocarbon resistant hose |
US7021337B2 (en) * | 2004-02-27 | 2006-04-04 | Markham Allen R | Plumbing test plug and method |
US7175543B2 (en) * | 2005-01-26 | 2007-02-13 | Callaway Golf Company | Golf ball and thermoplastic material |
US7544757B2 (en) * | 2005-06-30 | 2009-06-09 | E. I. Du Pont De Nemours And Company | Ethylene/alkyl acrylate copolymers and compounds, vulcanizates and articles thereof |
CN101253204B (zh) * | 2005-06-30 | 2012-05-23 | 纳幕尔杜邦公司 | 乙烯/丙烯酸烷基酯共聚物和其胶料和硫化橡胶 |
US20070105984A1 (en) * | 2005-11-07 | 2007-05-10 | Griffin Elizabeth R | Composition comprising cellulose and polyvinyl chloride polymer |
US20100018600A1 (en) * | 2008-07-25 | 2010-01-28 | Crouse Michael L | High temperature-resistant hose |
US20100126558A1 (en) * | 2008-11-24 | 2010-05-27 | E. I. Du Pont De Nemours And Company | Solar cell modules comprising an encapsulant sheet of an ethylene copolymer |
US8779061B2 (en) | 2011-10-26 | 2014-07-15 | E I Du Pont De Nemours And Company | Curable elastomeric compositions |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3267083A (en) * | 1963-06-07 | 1966-08-16 | Union Carbide Corp | Reprocessable crosslinked polymeric compositions |
GB1603205A (en) * | 1977-04-12 | 1981-11-18 | Raychem Ltd | Polymer compositions |
US4304887A (en) * | 1978-03-16 | 1981-12-08 | E. I. Du Pont De Nemours And Company | Ethylene/carboxylic acid copolymers |
JPS55102641A (en) * | 1979-01-29 | 1980-08-06 | D J- K Internatl Kk | Thermoplastic composite polymer composition |
JPS58217533A (ja) * | 1982-06-11 | 1983-12-17 | Du Pont Mitsui Polychem Co Ltd | 射出成形用樹脂組成物 |
US4801649A (en) * | 1982-12-28 | 1989-01-31 | E. I. Du Pont De Nemours And Company | Ionomers having improved low temperature properties and blends thereof with thermoplastic resins |
DE3506685A1 (de) * | 1985-02-26 | 1986-08-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung eines ionisch vernetzten ethylencopolymerisates |
US4710544A (en) * | 1985-11-07 | 1987-12-01 | E. I. Du Pont De Nemours And Company | Thermoplastic composition of polyolefin and high ethylene content ethylene/alkyl acrylate elastomer |
JPS63183359A (ja) * | 1987-01-26 | 1988-07-28 | ダイキン工業株式会社 | 冷凍装置 |
DE3927719C2 (de) * | 1989-08-23 | 1995-01-05 | Alkor Gmbh | Kunststofformmasse und Verwendung derselben |
US5274035A (en) * | 1991-12-30 | 1993-12-28 | Ferro Corporation | Ethylene vinyl acetate compositions and tubing made therefrom |
US5214108A (en) * | 1992-07-10 | 1993-05-25 | E. I. Du Pont De Nemours And Company | Process for modifying the viscosity of copolymers of ethylene and unsaturated carboxylic acids |
-
1994
- 1994-05-19 US US08/246,208 patent/US5492971A/en not_active Expired - Lifetime
-
1995
- 1995-05-15 EP EP95919200A patent/EP0759954B1/en not_active Expired - Lifetime
- 1995-05-15 WO PCT/US1995/006088 patent/WO1995032241A1/en active IP Right Grant
- 1995-05-15 JP JP53036395A patent/JP3604392B2/ja not_active Expired - Fee Related
- 1995-05-15 DE DE69502019T patent/DE69502019T2/de not_active Expired - Lifetime
- 1995-06-06 US US08/465,302 patent/US5498669A/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011521802A (ja) * | 2008-05-01 | 2011-07-28 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | エチレン酸コポリマーおよび官能性エチレンコポリマーを含む組成物 |
CN109679213A (zh) * | 2018-12-27 | 2019-04-26 | 宣城广能非织造有限公司 | 一种增加油过滤性能的功能母料及其制备方法 |
CN109679213B (zh) * | 2018-12-27 | 2021-03-19 | 宣城广能非织造有限公司 | 一种增加油过滤性能的功能母料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
US5492971A (en) | 1996-02-20 |
EP0759954A1 (en) | 1997-03-05 |
US5498669A (en) | 1996-03-12 |
DE69502019D1 (de) | 1998-05-14 |
DE69502019T2 (de) | 1998-11-19 |
WO1995032241A1 (en) | 1995-11-30 |
JP3604392B2 (ja) | 2004-12-22 |
EP0759954B1 (en) | 1998-04-08 |
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