JPH101646A - Pressure-sensitive adhesive bactericidal sheet - Google Patents
Pressure-sensitive adhesive bactericidal sheetInfo
- Publication number
- JPH101646A JPH101646A JP8155318A JP15531896A JPH101646A JP H101646 A JPH101646 A JP H101646A JP 8155318 A JP8155318 A JP 8155318A JP 15531896 A JP15531896 A JP 15531896A JP H101646 A JPH101646 A JP H101646A
- Authority
- JP
- Japan
- Prior art keywords
- pressure
- sensitive adhesive
- sheet
- agent layer
- adhesive layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Apparatus For Disinfection Or Sterilisation (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、粘着シートに関
し、特に殺菌性に優れ、病院内において使用するのに好
適な粘着殺菌シートに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pressure-sensitive adhesive sheet, and more particularly to a pressure-sensitive adhesive sheet having excellent sterilization properties and suitable for use in hospitals.
【0002】[0002]
【従来の技術】従来から、表面が粘着性を有するシート
またはマットは、病院やクリーンルームの入り口などに
配置され、人がその上を歩くと表面の粘着剤に靴の裏側
に付いている様々な汚れ物質が付着し、汚染物質を落と
すものとして良く知られている。また空気中の汚染物質
が落下して粘着剤に付着する場合もある。2. Description of the Related Art Conventionally, sheets or mats having a sticky surface have been placed at entrances of hospitals and clean rooms, etc., and when a person walks on it, various adhesives on the surface are attached to the back of shoes. It is well known that dirt adheres and drops off contaminants. Also, pollutants in the air may fall and adhere to the adhesive.
【0003】近年、病院内で耐メシチリン性黄色ブドウ
球菌(MRSA)等の細菌に対する抵抗力の低下した病
人の院内感染が大きな問題となっている。そこで、抗菌
を目的とし、合成樹脂に無機抗菌剤を練り込んだマット
や粘着層に抗菌剤を含有させた粘着マット(特開平7−
289498号公報)等の製品が提案されているが、乾
燥状態では効果が不十分であるばかりでなく、殺菌速度
も不十分なため、殺菌の増殖を抑えることができず、充
分な感染防止対策までには至っていない。[0003] In recent years, hospital infections of sick people with reduced resistance to bacteria such as mesitillin-resistant Staphylococcus aureus (MRSA) in hospitals have become a major problem. Therefore, for the purpose of antibacterial, a mat in which an inorganic antibacterial agent is kneaded in a synthetic resin or an adhesive mat in which an antibacterial agent is contained in an adhesive layer (Japanese Patent Application Laid-Open No.
289498) have been proposed, but in the dry state, not only the effect is insufficient, but also because the sterilization speed is insufficient, it is not possible to suppress the proliferation of sterilization, and sufficient infection prevention measures are taken. Not yet.
【0004】[0004]
【発明が解決しようとする課題】前記したように、特開
平7−289498号公報等で提案されている従来の方
法は、殺菌速度が不十分なため、殺菌の増殖を抑えるこ
とができず、充分な感染防止対策までには至っていない
という問題があった。As described above, the conventional method proposed in Japanese Patent Application Laid-Open No. 7-289498 or the like cannot suppress the proliferation of sterilization because the sterilization speed is insufficient. There was a problem that sufficient infection control measures had not been reached.
【0005】本発明は、前記従来の問題を解決するた
め、病院内における殺菌の感染を防止するに適し、安全
性が高く、殺菌効果に優れる粘着シートを提供すること
を目的とする。[0005] In order to solve the above-mentioned conventional problems, an object of the present invention is to provide a pressure-sensitive adhesive sheet which is suitable for preventing sterilization infection in hospitals, has high safety, and is excellent in sterilization effect.
【0006】[0006]
【課題を解決するための手段】前目的を達成するため、
本発明の粘着殺菌シートは、プラスチックシートの表面
に粘着剤層を備えたシート状物であって、前記粘着剤層
の粘着力が失われない程度に前記粘着剤層の表面に繊維
が存在し、前記繊維は少なくとも表面に光触媒酸化チタ
ン微粒子を含むことを特徴とする。この構成によれば、
粘着剤層の粘着性を良好に保ちつつ、光触媒酸化チタン
微粒子を含む繊維がシートの表面に存在しているので、
細菌が粘着剤層に補足されやすく、かつ補足された後は
光触媒酸化チタン微粒子触媒によって速やかに殺菌され
る。この結果、病院内における殺菌の感染を防止するの
に適し、安全性が高く、殺菌効果に優れる粘着シートを
実現できる。Means for Solving the Problems In order to achieve the foregoing object,
The pressure-sensitive adhesive sterilizing sheet of the present invention is a sheet-like material having a pressure-sensitive adhesive layer on the surface of a plastic sheet, and fibers are present on the surface of the pressure-sensitive adhesive layer to such an extent that the pressure-sensitive adhesive force of the pressure-sensitive adhesive layer is not lost. The fiber is characterized in that it contains photocatalytic titanium oxide fine particles on at least the surface. According to this configuration,
Since the fiber containing the photocatalytic titanium oxide fine particles is present on the surface of the sheet while maintaining good adhesiveness of the adhesive layer,
Bacteria are easily trapped in the pressure-sensitive adhesive layer, and after being trapped, are quickly killed by the photocatalytic titanium oxide fine particle catalyst. As a result, it is possible to realize a pressure-sensitive adhesive sheet which is suitable for preventing infection by sterilization in a hospital, has high safety, and has an excellent sterilizing effect.
【0007】前記粘着殺菌シートにおいては、光触媒酸
化チタン微粒子を担持した繊維が、粘着剤層表面に露出
していることが好ましい。粘着剤層表面に付着する細菌
を効率良く殺菌するためである。[0007] In the pressure-sensitive adhesive sterilizing sheet, it is preferable that the fibers carrying the photocatalytic titanium oxide fine particles are exposed on the surface of the pressure-sensitive adhesive layer. This is to efficiently sterilize bacteria adhering to the surface of the pressure-sensitive adhesive layer.
【0008】また前記粘着殺菌シートにおいては、粘着
殺菌シートが、複数層積層されていることが好ましい。
表面の1層の粘着剤層の粘着性が低下した場合、その粘
着剤層を基材のプラスチックシートごと剥がし、次の粘
着剤層を用いることにより、常に高い粘着剤層を表面に
配置することができる。実用的に好ましい積層数は6〜
7層である。[0008] Further, in the pressure-sensitive adhesive sterilizing sheet, it is preferable that a plurality of layers of the pressure-sensitive adhesive sterilizing sheet are laminated.
When the adhesiveness of one pressure-sensitive adhesive layer on the surface is reduced, peel off the pressure-sensitive adhesive layer together with the base plastic sheet, and use the next pressure-sensitive adhesive layer to arrange a high pressure-sensitive adhesive layer on the surface at all times. Can be. The practically preferred number of laminations is 6 to
There are seven layers.
【0009】また前記粘着殺菌シートにおいては、光触
媒酸化チタン微粒子がアナターゼ型であり、その粒子直
径が0.007〜0.2μmの範囲で、かつ配合量が
0.5〜30重量%の範囲であることが好ましい。これ
により、粘着剤層に補足した細菌を効率良く殺菌するこ
とができる。[0009] In the pressure-sensitive adhesive sterilizing sheet, the photocatalytic titanium oxide fine particles are anatase type, the particle diameter is in the range of 0.007 to 0.2 µm, and the compounding amount is in the range of 0.5 to 30% by weight. Preferably, there is. Thereby, the bacteria supplemented to the adhesive layer can be efficiently sterilized.
【0010】また前記粘着殺菌シートにおいては、繊維
層を構成する繊維が合成繊維であり、かつ光触媒酸化チ
タン微粒子が露出している構造であることが好ましい。
これにより、合成繊維はコストが低く、かつ酸化チタン
を配合しても強力等の物性の低下が少ない。また、光触
媒酸化チタン微粒子が露出していると、殺菌作用が高
い。In the pressure-sensitive adhesive sterilizing sheet, it is preferable that the fiber constituting the fiber layer is a synthetic fiber and the photocatalytic titanium oxide fine particles are exposed.
Thereby, the cost of the synthetic fiber is low, and even if titanium oxide is blended, the decrease in physical properties such as strength is small. Moreover, when the photocatalytic titanium oxide fine particles are exposed, the bactericidal action is high.
【0011】また前記粘着殺菌シートにおいては、粘着
剤層の表面に存在する繊維の目付が5〜30g/m2 の
範囲であることが好ましい。これにより、粘着剤層の粘
着力の低下を防止できる。In the pressure-sensitive adhesive sterilizing sheet, the basis weight of the fibers present on the surface of the pressure-sensitive adhesive layer is preferably in the range of 5 to 30 g / m 2 . Thereby, it is possible to prevent a decrease in the adhesive strength of the adhesive layer.
【0012】[0012]
【発明の実施の形態】本発明は酸化チタンの光触媒反応
に着目し、殺菌速度が速く、かつ乾燥状態においても殺
菌を分解することが可能な酸化チタンを表面に担持した
粘着マットの発明に至った。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention focuses on the photocatalytic reaction of titanium oxide, and has led to the invention of an adhesive mat having a titanium oxide capable of disinfecting sterilization even at a high sterilization rate even in a dry state. Was.
【0013】すなわち、酸化チタンに光が当たると、強
い酸化力をもつ正孔と強い還元力を持った電子が生成
し、空気中の酸素や水分を活性酸素に変化させる。この
活性酸素は、塩素やオゾンに比べ非常に強い酸化力を持
っており、細菌が接触したときには、細胞膜を損傷し短
時間で死滅させる。この作用は、蛍光灯などの微弱な室
内光下で充分発揮され、酸化チタン自身は変化しないの
で、継続して働く。That is, when light is applied to the titanium oxide, holes having a strong oxidizing power and electrons having a strong reducing power are generated to change oxygen and moisture in the air into active oxygen. This active oxygen has a much stronger oxidizing power than chlorine and ozone, and when bacteria come in contact with it, it damages the cell membrane and kills it in a short time. This effect is sufficiently exhibited under weak indoor light such as a fluorescent lamp, and the titanium oxide itself does not change, so that it works continuously.
【0014】本発明では、前記機能有する酸化チタンを
粘着剤上に粘着性を損なわずかつ脱落しないように表面
に担持されなければならないため、酸化チタン粒子を担
持した繊維を表面に吹き付ける方法が適しいる。In the present invention, since the titanium oxide having the above function must be supported on the surface of the pressure-sensitive adhesive in such a manner that the adhesive does not slightly lose its adhesiveness, a method of spraying fibers carrying titanium oxide particles onto the surface is suitable. I have.
【0015】繊維の製造方法としては、一般的な不織布
の製造方法を採用することができる。たとえばシート状
物を解繊する方法、メルトブロー法等があるが、粘着剤
表面に連続的に担持させることのできるメルトブロー法
が適している。As a method for producing a fiber, a general method for producing a nonwoven fabric can be employed. For example, there are a method of defibrating a sheet-like material, a melt blow method, and the like, and a melt blow method that can be continuously carried on the surface of the pressure-sensitive adhesive is suitable.
【0016】メルトブローが用いられるポリマーとして
は、ポリエチレン、ポリプロピレン等のポリオレフィン
系樹脂、アクリル樹脂、酢酸ビニル樹脂、塩化ビニル樹
脂、ウレタン樹脂、ポリエステル樹脂等が挙げられ、ポ
リオレフィン系樹脂、アクリル樹脂、ポリエステル樹脂
等が好適に用いられる。また、光触媒酸化チタンは光活
性の点からアナターゼ型が好ましく、その粒径は通常
0.007〜0.2μmで、配合量としては、0.5〜
30重量%、好ましくは5〜15重量%である。Examples of the polymer to be used for melt blowing include polyolefin resins such as polyethylene and polypropylene, acrylic resins, vinyl acetate resins, vinyl chloride resins, urethane resins and polyester resins. Polyolefin resins, acrylic resins and polyester resins Etc. are preferably used. The photocatalytic titanium oxide is preferably an anatase type from the viewpoint of photoactivity, and the particle size is usually 0.007 to 0.2 μm, and the compounding amount is 0.5 to 0.5 μm.
It is 30% by weight, preferably 5 to 15% by weight.
【0017】この混合物をメルトブローにより、粘着シ
ートの粘着剤表面に吹き付ける。粘着シートの支持体と
しては、ポリエチレンフィルムなどからなる厚さが40
〜100μm程度のプラスチックシートが用いられ、粘
着剤層としては特に限定されるものではないが、アクリ
ル酸アルキルエステル及びメタアクリル酸アルキルエス
テルを主成分とし、共重合させたアクリル系粘着剤等の
粘着剤を使用することができる。その厚さは通常5〜4
0μm程度である。This mixture is sprayed onto the surface of the pressure-sensitive adhesive of the pressure-sensitive adhesive sheet by melt blowing. The support of the pressure-sensitive adhesive sheet has a thickness of 40 formed of a polyethylene film or the like.
A plastic sheet having a thickness of about 100 μm is used, and the pressure-sensitive adhesive layer is not particularly limited. However, the pressure-sensitive adhesive such as an acrylic pressure-sensitive adhesive which is mainly composed of alkyl acrylate and alkyl methacrylate and is copolymerized is used. Agents can be used. Its thickness is usually 5-4
It is about 0 μm.
【0018】粘着剤表面と光触媒含有繊維の比率は、繊
維の径や酸化チタンの含有量によってわかるが、通常目
付け量で5〜30g/m2、好ましくは10〜20g/
cm2であり、粘着力がステンレスか鋼板に対する常温
下での180℃剥離接着力が50〜800g/20mm
幅程度となるように調整されているのがよい。The ratio between the pressure-sensitive adhesive surface and the photocatalyst-containing fiber can be determined by the diameter of the fiber and the content of titanium oxide, but is usually 5 to 30 g / m 2 , preferably 10 to 20 g / m 2 in basis weight.
cm 2 , and 180 ° C. peel adhesion at room temperature to stainless steel or steel plate at room temperature of 50 to 800 g / 20 mm
It is preferable that the width is adjusted to be about the width.
【0019】もちろん、光触媒含有繊維で予め不織布を
作成し、ラミネートする方法を採用してもよい。これら
粘着シートは2枚以上積層して用いられ、積層後のマッ
トとしての全体の厚さは、通常30〜600μmであ
る。Of course, a method in which a nonwoven fabric is prepared in advance from photocatalyst-containing fibers and then laminated may be employed. These pressure-sensitive adhesive sheets are used by laminating two or more sheets, and the total thickness of the mat after lamination is usually 30 to 600 μm.
【0020】次に図面を用いて説明する。図1は本発明
に係る殺菌粘着シートの一実施例の断面図である。図1
において、1は光触媒微粒子含有繊維であり、その下に
は粘着剤層2が配置され、その下にはプラスチックシー
ト3が配置されている。4は粘着殺菌シートユニット層
であり、このユニット層が6〜7層で積層シート5を形
成している。これにより、表面の1層の粘着剤層の粘着
性が低下した場合、その粘着剤層をプラスチックシート
ごと剥がし、次の粘着剤層を用いることにより、常に高
い粘着剤層を表面に配置することができる。Next, description will be made with reference to the drawings. FIG. 1 is a sectional view of one embodiment of the sterilizing pressure-sensitive adhesive sheet according to the present invention. FIG.
In the figure, reference numeral 1 denotes a photocatalyst fine particle-containing fiber, under which an adhesive layer 2 is disposed, and under that, a plastic sheet 3 is disposed. Reference numeral 4 denotes an adhesive sterilizing sheet unit layer, and this unit layer forms a laminated sheet 5 with 6 to 7 layers. As a result, when the adhesiveness of one pressure-sensitive adhesive layer on the surface is reduced, the pressure-sensitive adhesive layer is peeled off together with the plastic sheet, and by using the next pressure-sensitive adhesive layer, a high pressure-sensitive adhesive layer is always disposed on the surface. Can be.
【0021】[0021]
【実施例】以下実施例を用いて、本発明をさらに具体的
に説明する。メタクリル酸メチル濃度50重量%の水性
ディスパージョン100重量部に、粒子径0.007〜
0.5μmの光触媒酸化チタン30重量%水分散液1
2.5重量部を配合し、均一に混合した。その混合ディ
スパージョンを、重合した後パウダー化し、常法により
混練り押出してペレットを作成した。このペレットを2
30℃の温度で、別途用意した粘着力500g/20m
m幅の粘着テープの粘着面に目付け量が15g/m2 に
なるようにメルトブローして、目的の光触媒を担持した
粘着シートを得た。この粘着シートの粘着力は400g
/20mm幅で粘着性を維持しており、かつ繊維の脱落
もない良好なものであった。次に、この粘着シートの粘
着面の殺菌性を大腸菌を用いて下記の方法により行っ
た。The present invention will be described more specifically with reference to the following examples. A particle size of 0.007 to 100 parts by weight of the aqueous dispersion having a methyl methacrylate concentration of 50% by weight is added.
0.5 μm photocatalytic titanium oxide 30% by weight aqueous dispersion 1
2.5 parts by weight were blended and uniformly mixed. The mixed dispersion was polymerized, powdered, kneaded and extruded by a conventional method to form pellets. Put these pellets in 2
At a temperature of 30 ° C, an adhesive force of 500g / 20m prepared separately
The pressure-sensitive adhesive surface of the pressure-sensitive adhesive tape having a width of m was melt blown so that the basis weight was 15 g / m 2 to obtain a pressure-sensitive adhesive sheet carrying a desired photocatalyst. The adhesive strength of this adhesive sheet is 400g
The adhesiveness was maintained at a width of / 20 mm, and the fibers did not fall off. Next, the bactericidal property of the adhesive surface of the adhesive sheet was evaluated using Escherichia coli by the following method.
【0022】(殺菌性試験)大腸菌濃度3×105個/
mlの菌液0.5mlを25mm2の試験上に滴下し、
ブラックライト(0.3mW/cm2)を照射、一定時
間後に液を採取し、寒天培養した後、大腸菌コロニー数
を測定した。その結果を表1に示す。(Bactericidal test) E. coli concentration 3 × 105 cells /
0.5 ml of the bacterial solution was dropped on a 25 mm 2 test,
After irradiation with black light (0.3 mW / cm 2 ), the solution was collected after a certain period of time, and after agar culture, the number of E. coli colonies was measured. Table 1 shows the results.
【0023】[0023]
【表1】 [Table 1]
【0024】以上説明した通り、本実施例によれば、合
成繊維中に光触媒粒子を含有させ、粘着テープの粘着剤
表面に担持させた構造を持つため、病院内で使用するマ
ット等に用いると、靴に付着した細菌及び空気中より落
下してくる細菌を有効的に捕捉し、しかも捕捉した細菌
類を殺菌することができる。よって、もし水分が存在す
るような状況においても、二度と細菌が活動することな
く感染を防止できる。As described above, according to the present embodiment, the photocatalyst particles are contained in the synthetic fiber and are supported on the surface of the pressure-sensitive adhesive of the pressure-sensitive adhesive tape. In addition, bacteria adhering to shoes and bacteria falling from the air can be effectively captured, and the captured bacteria can be sterilized. Therefore, even in a situation where water is present, infection can be prevented without activating bacteria again.
【0025】[0025]
【発明の効果】以上説明した通り、本発明の粘着殺菌シ
ートによれば、プラスチックシートの表面に粘着剤層を
備えたシート状物であって、前記粘着剤層の粘着力が失
われない程度に前記粘着剤層の表面に繊維が存在し、前
記繊維は少なくとも表面に光触媒酸化チタン微粒子を含
むことにより、粘着剤層の粘着性を良好に保ちつつ、光
触媒酸化チタン微粒子を含む繊維がシートの表面に存在
しているので、細菌が粘着剤層に補足されやすく、かつ
補足された後は光触媒酸化チタン微粒子触媒によって速
やかに殺菌される。この結果、病院内における殺菌の感
染を防止するのに適し、安全性が高く、殺菌効果に優れ
る粘着シートを実現できる。As described above, according to the pressure-sensitive adhesive sterilizing sheet of the present invention, the pressure-sensitive adhesive sheet is a sheet-like material having a pressure-sensitive adhesive layer on the surface of a plastic sheet. Fibers are present on the surface of the pressure-sensitive adhesive layer, and the fibers contain photocatalytic titanium oxide fine particles at least on the surface, while maintaining good adhesion of the pressure-sensitive adhesive layer, the fibers containing the photocatalytic titanium oxide fine particles are used in the sheet. Since the bacteria are present on the surface, bacteria are easily trapped in the adhesive layer, and after being trapped, the bacteria are quickly sterilized by the photocatalytic titanium oxide fine particle catalyst. As a result, it is possible to realize a pressure-sensitive adhesive sheet which is suitable for preventing infection by sterilization in a hospital, has high safety, and has an excellent sterilizing effect.
【図1】 本発明に係る殺菌粘着シートの一実施例を示
す断面図である。FIG. 1 is a cross-sectional view showing one embodiment of a sterilizing pressure-sensitive adhesive sheet according to the present invention.
1 光触媒微粒子含有繊維 2 粘着剤層 3 プラスチックシート 4 粘着殺菌シートユニット層 5 積層シート DESCRIPTION OF SYMBOLS 1 Fiber containing photocatalyst fine particles 2 Adhesive layer 3 Plastic sheet 4 Adhesive sterilizing sheet unit layer 5 Laminated sheet
Claims (6)
備えたシート状物であって、前記粘着剤層の粘着力が失
われない程度に前記粘着剤層の表面に繊維が存在し、前
記繊維は少なくとも表面に光触媒酸化チタン微粒子を含
むことを特徴とする粘着殺菌シート。1. A sheet-like article having a pressure-sensitive adhesive layer on the surface of a plastic sheet, wherein fibers are present on the surface of the pressure-sensitive adhesive layer to such an extent that the adhesive force of the pressure-sensitive adhesive layer is not lost. Is a pressure-sensitive adhesive sterilizing sheet comprising at least a surface thereof containing photocatalytic titanium oxide fine particles.
が、粘着剤層表面に露出している請求項1に記載の粘着
殺菌シート。2. The pressure-sensitive adhesive sterilizing sheet according to claim 1, wherein the fibers carrying the photocatalytic titanium oxide fine particles are exposed on the surface of the pressure-sensitive adhesive layer.
る請求項1に記載の粘着殺菌シート。3. The pressure-sensitive adhesive sterilizing sheet according to claim 1, wherein a plurality of pressure-sensitive adhesive sterilizing sheets are laminated.
であり、その粒子直径が0.007〜0.2μmの範囲
で、かつ配合量が0.5〜30重量%の範囲である請求
項1に記載の粘着殺菌シート。4. The photocatalytic titanium oxide fine particles are of anatase type, the particle diameter is in the range of 0.007 to 0.2 μm, and the blending amount is in the range of 0.5 to 30% by weight. Adhesive sterilizing sheet.
り、かつ光触媒酸化チタン微粒子が露出している構造で
ある請求項1に記載の粘着殺菌シート。5. The pressure-sensitive adhesive sterilizing sheet according to claim 1, wherein the fibers constituting the fibrous layer are synthetic fibers, and the photocatalytic titanium oxide fine particles are exposed.
5〜30g/m2 の範囲である請求項1に記載の粘着殺
菌シート。6. The pressure-sensitive adhesive sterilizing sheet according to claim 1, wherein the basis weight of the fibers present on the surface of the pressure-sensitive adhesive layer is in the range of 5 to 30 g / m 2 .
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8155318A JPH101646A (en) | 1996-06-17 | 1996-06-17 | Pressure-sensitive adhesive bactericidal sheet |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8155318A JPH101646A (en) | 1996-06-17 | 1996-06-17 | Pressure-sensitive adhesive bactericidal sheet |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH101646A true JPH101646A (en) | 1998-01-06 |
Family
ID=15603273
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8155318A Pending JPH101646A (en) | 1996-06-17 | 1996-06-17 | Pressure-sensitive adhesive bactericidal sheet |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH101646A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002017768A3 (en) * | 2000-08-25 | 2002-09-06 | Tech Mats Llc | Advanced floor mat |
EP1798317A1 (en) * | 2005-12-19 | 2007-06-20 | Kang Na Hsiung Enterprise Co., Ltd. | Composite fibre |
CN113583589A (en) * | 2021-07-23 | 2021-11-02 | 临沂天勤塑业有限公司 | Sterilization sticky mat for pets and preparation method thereof |
-
1996
- 1996-06-17 JP JP8155318A patent/JPH101646A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002017768A3 (en) * | 2000-08-25 | 2002-09-06 | Tech Mats Llc | Advanced floor mat |
EP1798317A1 (en) * | 2005-12-19 | 2007-06-20 | Kang Na Hsiung Enterprise Co., Ltd. | Composite fibre |
CN113583589A (en) * | 2021-07-23 | 2021-11-02 | 临沂天勤塑业有限公司 | Sterilization sticky mat for pets and preparation method thereof |
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