JPH0931415A - Production of water-proof shoe cream - Google Patents
Production of water-proof shoe creamInfo
- Publication number
- JPH0931415A JPH0931415A JP18757495A JP18757495A JPH0931415A JP H0931415 A JPH0931415 A JP H0931415A JP 18757495 A JP18757495 A JP 18757495A JP 18757495 A JP18757495 A JP 18757495A JP H0931415 A JPH0931415 A JP H0931415A
- Authority
- JP
- Japan
- Prior art keywords
- mixture
- wax
- organic solvent
- shoe cream
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】この発明は、防水性靴クリー
ム製造法に関するものであり、更に、詳しくは撥水性、
防水性に富んだ油性ポリッシュ、乳化性ペーストクリー
ム及び乳化性リキッドの製造法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a waterproof shoe cream manufacturing method, more specifically, water repellency,
The present invention relates to a method for producing an oily polish having a high waterproof property, an emulsifying paste cream, and an emulsifying liquid.
【０００２】[0002]
【従来の技術】従来の乳化性靴クリーム製造法はアニオ
ン性界面活性剤又は非イオン性界面活性剤を用いてワッ
クスを乳化させることによって製造している。2. Description of the Related Art Conventional emulsifying shoe creams are manufactured by emulsifying a wax with an anionic surfactant or a nonionic surfactant.
【０００３】そこで、該靴クリームを靴に塗布して靴を
磨くとき、前記界面活性剤が靴の表面に残留する。而し
て、該界面活性剤は前記ワックスの乳化作用を有し、靴
に光沢、柔軟性を付与させることはできるが、磨かれた
靴に水が当ったとき、該水は界面活性剤にて吸収されて
撥水性がない。従って、防水性を付与させるために別途
フッ素樹脂を有機溶剤で溶解して生成した防水スプレー
にて前記磨かれた靴の表面にスプレーしている。而し
て、該防水スプレーは撥水性を付与させることはできる
が、艶出し及び柔軟効果を付与させることはできない。Therefore, when the shoe cream is applied to a shoe to polish the shoe, the surfactant remains on the surface of the shoe. Thus, the surfactant has the emulsifying action of the wax and can impart gloss and flexibility to shoes, but when water is struck on a polished shoe, the water becomes a surfactant. It is absorbed and is not water repellent. Therefore, in order to provide waterproofness, a fluororesin is separately sprayed on the surface of the polished shoe with a waterproof spray produced by dissolving it in an organic solvent. Thus, the waterproof spray can impart water repellency, but cannot impart gloss and softening effect.
【０００４】更に又、前記界面活性剤を用い、ワックス
を乳化させて製造した前記乳化性靴クリームに樹脂溶液
のバインダーを添加して防水性を付与することも想定さ
れるが、この場合は耐屈折性が劣る。又、油性靴クリー
ムで防水性を付与させることは可能であるが、之は革の
種類によっては色落ちし、或いはシミとなり易く、更
に、革を硬化させて柔軟性を損う等の欠陥がある。Further, it is also conceivable to add a binder of a resin solution to the emulsifying shoe cream produced by emulsifying a wax using the above-mentioned surfactant to impart waterproofness. Inferior in refraction. Although it is possible to impart waterproofness with oil-based shoe cream, some types of leather tend to be discolored or have stains. Furthermore, there are defects such as hardening of the leather and loss of flexibility. is there.
【０００５】[0005]
【発明が解決しようとする課題】そこで、上記欠陥に鑑
み、防水スプレーを用いることなく、靴クリームの塗布
によって防水効果が期待でき、且つ、艶出し及び柔軟効
果も同時に兼ね備えることのできる靴クリームを製造す
るために解決せらるべき技術的課題が生じてくるのであ
り、本発明は該課題を解決することを目的とする。In view of the above-mentioned drawbacks, therefore, there is provided a shoe cream which can be expected to have a waterproof effect by applying the shoe cream without using a waterproof spray, and at the same time have a glossing effect and a softening effect. A technical problem to be solved for manufacturing arises, and an object of the present invention is to solve the problem.
【０００６】[0006]
【課題を解決するための手段】本発明は上記目的を達成
するために提案されたものであり、ワックスとポリメチ
ル水素シロキサンのアルケン（Ｃ10〜Ｃ50）及びプロピ
レン付加物を加熱溶解し、該溶解液に有機溶剤を加えて
攪拌混合して後、該混合物を冷却して油性ポリッシュと
して生成される防水性靴クリーム製造法、及びワックス
と、ポリメチル水素シロキサンのアルケン（Ｃ10〜
Ｃ50）及びプロピレン付加物と、界面活性剤とを加熱溶
解させ、該溶解液に有機溶剤を加えた後、アルカリ水を
加えて乳化させ、更に防黴剤等の添加剤を加えて乳化性
ペーストクリームとして生成される防水性靴クリーム製
造法、及びワックスと、ポリメチル水素シロキサンのア
ルケン（Ｃ10〜Ｃ50）及びプロピレン付加物と、界面活
性剤とを加熱溶解させた後、熱湯を加えて乳化させ、該
乳化物を冷却して防黴剤等の添加剤を加えて乳化性リキ
ッドとして生成される防水性靴クリーム製造法を提供す
るものである。SUMMARY OF THE INVENTION The present invention has been proposed to achieve the above-mentioned object, wherein a wax, an alkene (C 10 to C 50 ) of polymethylhydrogensiloxane and a propylene adduct are dissolved by heating, An organic solvent is added to the solution, and the mixture is stirred and mixed, and then the mixture is cooled to produce a waterproof shoe cream produced as an oily polish, and a wax and an alkene of polymethylhydrogensiloxane (C 10- ).
C 50 ), a propylene adduct, and a surfactant are dissolved by heating, an organic solvent is added to the solution, and then alkaline water is added to emulsify the mixture. A method for producing a waterproof shoe cream produced as a paste cream, a wax, an alkene (C 10 to C 50 ) of polymethylhydrogensiloxane and a propylene adduct, and a surfactant are dissolved by heating, and then hot water is added. The present invention provides a method for producing a waterproof shoe cream, which is emulsified and cooled to obtain an emulsifying liquid by adding an antifungal agent and other additives to the emulsion.
【０００７】ここで、ポリメチル水素シロキサンのアル
ケン（Ｃ10〜Ｃ50）及びプロピレン付加物は、基本的に
は主鎖ポリメチル水素シロキサンのＨ基にα−オレフィ
ンを付加して、アルケン（Ｃ10〜Ｃ50）の鎖をグラフト
して成る櫛型グラフトコポリマーである。又、物性は、
融点が７４℃、表面張力が２５dyn ／cmと非常に撥水性
に富んでいる。溶解性は水、メタノールに対しては殆ど
溶解しないが、ワックスに対して１２０℃〜１３０℃に
加熱することにより容易に溶解する化合物である。[0007] Here, alkene (C 10 ~C 50) and propylene adducts of polymethylhydrogensiloxane is basically by adding α- olefin H groups in the main chain polymethylhydrogensiloxane, alkene (C 10 ~ It is a comb-type graft copolymer obtained by grafting C 50 ) chains. Also, the physical properties are
It has a very high water repellency with a melting point of 74 ° C and a surface tension of 25 dyn / cm. Solubility is a compound which hardly dissolves in water and methanol, but easily dissolves in wax by heating at 120 ° C to 130 ° C.
【０００８】又、有機溶剤は主としてミネラルスピリッ
トのような炭化水素系のものを使用した。之は沸点が１
５０℃〜２００℃と高いが引火性や毒性を考慮したもの
であるから、同沸点の有機溶剤であれば何れも使用可能
である。As the organic solvent, a hydrocarbon type such as mineral spirit was mainly used. The boiling point is 1
Although it is as high as 50 ° C. to 200 ° C., since flammability and toxicity are taken into consideration, any organic solvent having the same boiling point can be used.
【０００９】更に又、界面活性剤は主としてポリエチレ
ンオキシド化合物の脂肪酸エステル、ポリエチレンオキ
シド縮合物等、比較的に水に相容しない非イオン活性剤
が用いられる。Furthermore, as the surfactant, a nonionic surfactant which is relatively incompatible with water, such as a fatty acid ester of a polyethylene oxide compound or a polyethylene oxide condensate, is used.
【００１０】[0010]
【発明の実施の形態】以下、本発明の実施の形態を説明
する。先ず、請求項１記載の発明は、基剤としてワック
スを用いる。該ワックスとポリメチル水素シロキサンの
アルケン（Ｃ 10〜Ｃ50）及びプロピレン付加物（以下、
ＮＲ−Ｂと称す）とを混合し、之を１２０〜１３０℃で
加熱すればワックスは溶解し、そして、前記ＮＲ−Ｂも
該溶解ワックス中に溶融して混合液が生成される。この
とき、該ＮＲ−Ｂは２〜１５重量％配合量が最も効果的
である。即ち、靴に塗布したときに、不揮発分として靴
の表面に残るワックス塗膜自体の撥水性を向上させるた
めには、ＮＲ−Ｂの使用量が２重量％未満ではその効果
が発揮されず、又、１５重量％以上を加えても該効果が
上らないからである。斯くの如き重量％で配合された前
記混合液に既述の有機溶剤を加えた後冷却し、５５〜６
５℃の雰囲気中で容器へ充填して固化させることにより
油性ポリッシュとしての防水性靴クリームが製造され
る。ここで、前記ＮＲ−Ｂは撥水効果があり、且つ、ワ
ックスに相容することが実験の結果判明した。之はアル
ケン（Ｃ10〜Ｃ50）が二重結合をもつ炭化水素であるか
ら、同じ炭化水素化合物であるワックスとは相容性を有
し、双方はよく混り合うのである。更に、前記ＮＲ−Ｂ
は水に対しての接触角が大であり、且つ、前進接触角と
後退接触角との差が小であるため、該ＮＲ−Ｂは撥水性
を奏することができるのである。Embodiments of the present invention will be described below.
I do. First, the invention according to claim 1 uses a wack as a base.
Using Of the wax and polymethylhydrogen siloxane
Alken (C Ten~ C50) And propylene adduct (hereinafter,
NR-B) and mixed at 120-130 ℃
The wax dissolves when heated, and the NR-B also
A mixed liquid is produced by melting in the melted wax. this
At this time, 2-15% by weight of NR-B is most effective.
It is. That is, when applied to shoes, the shoes are non-volatile.
Improves the water repellency of the wax coating itself that remains on the surface of the
To achieve this, if the amount of NR-B used is less than 2% by weight, its effect
Is not exhibited, and even if 15% by weight or more is added, the effect is
Because it does not rise. Before blended in such a weight%
After adding the above-mentioned organic solvent to the mixture, the mixture is cooled to 55 to 6
By filling the container in an atmosphere of 5 ° C and solidifying
Waterproof shoe cream as an oily polish is manufactured
You. Here, the NR-B has a water-repellent effect and
It was found as a result of the experiment that it is compatible with X. I ’m Al
Ken (CTen~ C50) Is a hydrocarbon with a double bond
Have a compatibility with wax, which is the same hydrocarbon compound.
However, the two mix well. Further, the NR-B
Has a large contact angle with water, and
Since the difference from the receding contact angle is small, the NR-B is water repellent.
Can be played.
【００１１】又、前記有機溶剤は防水効果には寄与しな
いが、油性ポリッシュを靴へ塗布する際に、該油性ポリ
ッシュの進展を良くする。而も、該有機溶剤は既述せる
如く揮発性であるため、該油性ポリッシュを靴に塗布し
た後には直ちに揮発することが望しい。そこで、本発明
の実施例に於ては、炭化水素系有機溶剤を用いた。Although the organic solvent does not contribute to the waterproof effect, it improves the progress of the oily polish when it is applied to shoes. Moreover, since the organic solvent is volatile as described above, it is desirable that the organic solvent be volatilized immediately after the oily polish is applied to the shoe. Therefore, in the examples of the present invention, a hydrocarbon organic solvent was used.
【００１２】次に、請求項２記載の発明は、前記ワック
スとＮＲ−Ｂと非イオン性界面活性剤とを１２０〜１３
０℃で加熱溶解し、該溶解液に前記有機溶剤を加えた
後、アルカリ水を加えることにより乳化させ、更に、防
黴剤、着色剤等の添加剤を加え、之を常温下で所定の容
器に充填して乳化性ペーストクリームを製造する。Next, the invention according to claim 2 is characterized in that the wax, NR-B, and a nonionic surfactant are added in an amount of 120 to 13
It is dissolved by heating at 0 ° C., the above-mentioned organic solvent is added to the solution, and then alkaline water is added to emulsify the mixture. Fill a container to produce an emulsifying paste cream.
【００１３】ここで、乳化性ペーストクリームの場合、
防水効果を阻止する最大要因は親水性の界面活性剤であ
るから、この発明の実施の形態に於ては比較的に水に相
容しない親油性の非イオン界面活性剤を用い、そして、
前記ＮＲ−Ｂを加えることにより、該乳化性ペーストク
リームの防水効果を一層向上させた。In the case of emulsifying paste cream,
Since the largest factor preventing the waterproof effect is the hydrophilic surfactant, a lipophilic nonionic surfactant which is relatively incompatible with water is used in the embodiment of the present invention, and
By adding the NR-B, the waterproof effect of the emulsifiable paste cream was further improved.
【００１４】又、請求項３記載の発明は、前記ワックス
とＮＲ−Ｂと界面活性剤とを１２０〜１３０℃で加熱溶
解させた後、９０℃以上の温度を保ち乍ら熱湯を加えて
該溶解液を乳化させる。更に、規定量を所定容器に入
れ、之を直ちに急冷して常温まで冷却し、そして、防黴
剤等の添加剤を加えて乳化性リキッドを製造する。In the invention according to claim 3, the wax, NR-B and the surfactant are heated and melted at 120 to 130 ° C, and then hot water is added while keeping the temperature at 90 ° C or higher. Emulsify the solution. Further, a prescribed amount is put in a predetermined container, and immediately cooled to room temperature, and an additive such as an antifungal agent is added to produce an emulsified liquid.
【００１５】ここで、前記溶解液を９０℃以上に保つの
は、ワックスの融点以上に該溶解液を常に維持し、そし
て、該ワックスの折出を防ぎ、乳化を円滑に促進させる
ためであり、更に、前記溶解液の規定量を所定容器に入
れた後に直ちに急冷して常温まで冷却するのは乳化粒子
の凝集を防ぎ、そして、該乳化粒子を均一に保持させる
ためである。Here, the reason why the solution is kept at 90 ° C. or higher is to keep the solution above the melting point of the wax, prevent the wax from sticking out, and promote the emulsification smoothly. Further, the reason why a predetermined amount of the solution is put into a predetermined container and then immediately cooled and cooled to room temperature is to prevent aggregation of the emulsified particles and to keep the emulsified particles uniformly.
【００１６】又、ワックスの使用量はクリームの伸展性
と艶出し効果によって算出せらるべきであり、ワックス
の使用量が少なければクリームの伸展性は良好となるが
艶出し効果が少なく、反対に、ワックスの使用量が多け
れば艶出し効果は向上するがクリームの伸展性が悪化す
る。実験の結果、最も好適なワックスの使用量は全体の
約２０％であることが判明した。The amount of wax used should be calculated based on the extensibility of the cream and the glossing effect. If the amount of wax used is small, the extensibility of the cream will be good but the glossing effect will be small. If a large amount of wax is used, the polishing effect is improved but the spreadability of the cream is deteriorated. As a result of experiments, it was found that the most preferable amount of wax used is about 20% of the whole amount.
【００１７】[0017]
【実施例】本発明の実験に用いた素材の配合割合は下記
の通りである。 （ヘ）物性比較例 撥水効果：雨に合った場合を想定し、５×６cmの皮革に
１回につき０．０４ｇの靴クリームを塗布し、塗布後、
水１０００mlをシャワーし、その吸水量（mg）を測定。
シャワー方法はＪＩＳ規格繊維製品の防水試験法（Ｌ−
１０９２）を使用。EXAMPLES The mixing ratios of the materials used in the experiments of the present invention are as follows. (F) Comparative example of physical properties Water repellent effect: Assuming that it is suitable for rain, 0.04 g of shoe cream is applied to 5 × 6 cm leather at a time, and after application,
Shower 1000 ml of water and measure its water absorption (mg).
The shower method is a JIS standard textile product waterproof test method (L-
1092) is used.
【００１８】塗布後、屈折しない場合 塗布後、屈折１万回した場合After application, no refraction After application, refraction 10,000 times
【００１９】[0019]
【表１】 [Table 1]
【００２０】撥水度：表１のテストの時の撥水度。評価
方法はＪＩＳ規格繊維製品の防水試験法（Ｌ−１０９
２）を使用。Water repellency: Water repellency in the test of Table 1. The evaluation method is the waterproof test method for JIS standard textile products (L-109
Use 2).
【００２１】[0021]
【表２】 [Table 2]
【００２２】（ト）表１〜２は、いずれも無色クリーム
で比較した一例であるが、表１〜２より防水効果が従来
の各々のクリームよりかなり優れている事が判明した。(G) Tables 1 and 2 are all examples of comparison with colorless creams, and it was found from Tables 1 and 2 that the waterproofing effect was considerably superior to the conventional creams.
【００２３】[0023]
【発明の効果】本発明は上記発明の実施の形態の項及び
実施例の項に於て詳述せる如く、この発明の製造法によ
って製造された靴クリームを靴に使用すれば次の効果を
奏することが判明した。As described in detail in the above embodiments and examples of the present invention, the following effects can be obtained by using the shoe cream produced by the production method of the present invention in a shoe. It turned out to play.
【００２４】 艶出し効果と共に防水効果を付与させ
ることができる。 ＮＲ−Ｂの作用で磨き操作が円滑となり、使用感触
が向上した。 ＮＲ−Ｂの作用で柔軟な塗膜ができ、靴を履いてい
るときのワックスの脱落が減少し、従って、靴の光沢の
持続性が向上する。A waterproof effect as well as a glazing effect can be imparted. The action of NR-B made the polishing operation smoother and improved the feeling of use. The action of NR-B produces a flexible coating, which reduces wax loss when wearing shoes, and thus improves the luster persistence of the shoe.
【００２５】 塗膜の撥水性が向上したため、水に当
っても白ボケするようなことはない。 誰でも短時間で且つ、簡単に靴の手入れができ、一
般消費者から靴メーカーに到るまで広く利用することが
可能となる。Since the water repellency of the coating film is improved, white blur does not occur even if it is exposed to water. Anyone can take care of shoes easily in a short time, and can be widely used by general consumers to shoe makers.
Claims (3)
アルケン（Ｃ10〜Ｃ 50）及びプロピレン付加物を加熱溶
解し、該溶解液に有機溶剤を加えて攪拌混合して後、該
混合物を冷却して油性ポリッシュとして生成されること
を特徴とする防水性靴クリーム製造法。1. A wax and polymethylhydrogensiloxane
Alken (CTen~ C 50) And propylene adduct are melted by heating
Dissolve, add an organic solvent to the solution, stir and mix,
Cooling the mixture to produce an oily polish
A method for producing a waterproof shoe cream characterized by:
のアルケン（Ｃ10〜Ｃ50）及びプロピレン付加物と、界
面活性剤とを加熱溶解させ、該溶解液に有機溶剤を加え
た後、アルカリ水を加えて乳化させ、更に防黴剤等の添
加剤を加えて乳化性ペーストクリームとして生成される
ことを特徴とする防水性靴クリーム製造法。2. A wax, an alkene (C 10 -C 50 ) of polymethylhydrogensiloxane and a propylene adduct, and a surfactant are dissolved by heating, and an organic solvent is added to the solution, and then alkaline water is added. A method for producing a waterproof shoe cream, which comprises producing an emulsifying paste cream by adding an additive such as a mildew proofing agent to an emulsifying paste cream.
のアルケン（Ｃ10〜Ｃ50）及びプロピレン付加物と、界
面活性剤とを加熱溶解させた後、熱湯を加えて乳化さ
せ、該乳化物を冷却して防黴剤等の添加剤を加えて乳化
性リキッドとして生成されることを特徴とする防水性靴
クリーム製造法。3. A wax, an alkene (C 10 -C 50 ) of polymethylhydrogen siloxane and a propylene adduct, and a surfactant are dissolved by heating, and then hot water is added to emulsify the mixture and the emulsion is cooled. A method for producing a waterproof shoe cream, which is produced as an emulsifying liquid by adding an additive such as an antifungal agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18757495A JPH0931415A (en) | 1995-07-24 | 1995-07-24 | Production of water-proof shoe cream |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18757495A JPH0931415A (en) | 1995-07-24 | 1995-07-24 | Production of water-proof shoe cream |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0931415A true JPH0931415A (en) | 1997-02-04 |
Family
ID=16208489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18757495A Pending JPH0931415A (en) | 1995-07-24 | 1995-07-24 | Production of water-proof shoe cream |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0931415A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10237389A (en) * | 1997-02-26 | 1998-09-08 | Moon Star Co | Glazing agent of leather shoes |
| US6538255B1 (en) | 1999-02-22 | 2003-03-25 | Nikon Corporation | Electron gun and electron-beam optical systems and methods including detecting and adjusting transverse beam-intensity profile, and device manufacturing methods including same |
| JP2006523757A (en) * | 2003-04-17 | 2006-10-19 | サラ リー／デーイー エヌ．ヴェー | Care products for shoes and leather |
-
1995
- 1995-07-24 JP JP18757495A patent/JPH0931415A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10237389A (en) * | 1997-02-26 | 1998-09-08 | Moon Star Co | Glazing agent of leather shoes |
| US6538255B1 (en) | 1999-02-22 | 2003-03-25 | Nikon Corporation | Electron gun and electron-beam optical systems and methods including detecting and adjusting transverse beam-intensity profile, and device manufacturing methods including same |
| JP2006523757A (en) * | 2003-04-17 | 2006-10-19 | サラ リー／デーイー エヌ．ヴェー | Care products for shoes and leather |
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