JPH09253618A - Treatment of animal-and plant-derived organic solid matter and apparatus therefor - Google Patents

Treatment of animal-and plant-derived organic solid matter and apparatus therefor

Info

Publication number
JPH09253618A
JPH09253618A JP8101814A JP10181496A JPH09253618A JP H09253618 A JPH09253618 A JP H09253618A JP 8101814 A JP8101814 A JP 8101814A JP 10181496 A JP10181496 A JP 10181496A JP H09253618 A JPH09253618 A JP H09253618A
Authority
JP
Japan
Prior art keywords
treatment tank
liquid
aerobic
anaerobic
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8101814A
Other languages
Japanese (ja)
Inventor
Shiro Okamoto
士郎 岡本
Yoshiaki Horigome
良明 堀米
Akira Hayashi
昶 林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KANKYO PROJECT KK
Original Assignee
KANKYO PROJECT KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KANKYO PROJECT KK filed Critical KANKYO PROJECT KK
Priority to JP8101814A priority Critical patent/JPH09253618A/en
Publication of JPH09253618A publication Critical patent/JPH09253618A/en
Pending legal-status Critical Current

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  • Processing Of Solid Wastes (AREA)
  • Treatment Of Sludge (AREA)

Abstract

PROBLEM TO BE SOLVED: To solve a problem of evolution of unpleasant malodor by supplying primarily treated liquid in a constant concentration and at a constant flow fate to an aerobic treatment tank while diluting the primarily treated liquid produced by decomposing methane gas into inorganic substances with a part of treated liquid which is secondarily treated liquid by aerobic treatment or with cleaning liquid such as clean water. SOLUTION: Animal- and plant-derived organic solid matters 3, e.g. animals and plants and fishes and shellfishes are liquefied by the function of anaerobic microbe in an anaerobic treatment tank 1 and further decomposed into methane gas, carbonic acid gas, hydrogen sulfide gas, etc., and converted into inorganic substances by methane bacteria to produce a primarily treated liquid. The primarily treated liquid is sent toward an aerobic treatment tank 18 in the next stage, and while being so diluted with a part of the treated liquid which is a liquid treated by aerobic secondary treatment or with a cleaning liquid such as clean water as to keep the organic substance load at a prescribed value in the aerobic treatment tank 18, the primarily treated liquid is supplied and returned as a final treatment water in a constant concentration and at a constant flow rate to the aerobic treatment tank 18. Consequently, a problem of evolution of unpleasant malodor can be solved.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、動物・植物・魚介
類等の動植物性有機固形物の処理方法、ならびにその装
置、さらに詳細には、発電所、製鉄所、化学プラント、
あるいは養殖場等の海水を用いる工場、事業所等の取水
設備等の海水に直接触れる部分に発生するムラサキイ
貝、牡蠣、フジツボ等の貝肉と貝殻との分離、処理、あ
るいは水産加工業、ならびに畜産加工業等から排出され
る魚介類、ならびに動物等の残骸の腐敗性有機物質と
骨、角質部分、繊維質部分、ならびにそれらに混入する
石、砂等との分離、さらには厨房等からの生ゴミ等の腐
敗性有機質部分と動植物の骨、角質部分、繊維質部分、
ならびにそれらに混入する石、砂、プラスチック等の生
物による分解が不可能なものとの分離処理を行う方法、
ならびにその装置に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for treating animal and plant organic solids such as animals, plants and seafood, and an apparatus therefor, more specifically a power plant, a steel plant, a chemical plant,
Alternatively, separation and treatment of shellfish and shellfish such as mussels, oysters, barnacles, etc. that occur in parts that come into direct contact with seawater such as factories using seawater such as farms, water intake facilities at business establishments, or the seafood processing industry, and Separation of septic organic matter from fish and seafood discharged from the livestock processing industry, etc., and debris of animals, etc. from bones, horny parts, fibrous parts, and stones, sand, etc. mixed with them, and further from kitchens, etc. Perishable organic parts such as garbage and bones of animals and plants, horny parts, fibrous parts,
And a method of separating stones, sand, plastics, and other substances that cannot be decomposed by living organisms,
And the device.

【0002】[0002]

【従来の技術】従来、事故死、病死した動物の死骸、家
畜、魚肉等を精肉にしたあとの残骸、ほたて貝の貝柱を
採取したあとの臓物や残滓、厨房ゴミや貝類、ヒトデ、
ホヤ等は、主として焼却処分、あるいは埋立て処分され
されている。しかしながら、埋立て処分する場合は、埋
立てする敷地に限界があることと、極めて不快な悪臭を
放つといった問題があり、他方、焼却処分する場合は、
その処理量が非常に多く、腐敗する前の短期間で処理し
なければならない制約があり、焼却炉が大型のものとな
ってイニシャルコスト、ランニングコストともに高くな
り、周期的に大量に排出される被処理物を時間をかけて
焼却することにより、炉の小型化を計ろうとすると大規
模な貯留ピットが必要となり、その建設および処理対象
物の搬送システムの建設に多額の費用を要し、そこから
発生する悪臭対策にも多額の費用が発生する。また、骨
や貝殻固形物、石、砂、残滓が混っているため焼却炉の
寿命が短くなり、さらに多量の焼却灰が発生する等の欠
点がある。
2. Description of the Related Art Conventionally, carcasses of carcasses of dead animals, dead animals, dead animals, livestock, fish meat, etc., offal and residues after collecting scallop scallops, kitchen garbage and shellfish, starfish,
Ascidians are mainly incinerated or landfilled. However, in the case of landfill disposal, there are problems that there is a limit to the landfill site and that it emits an extremely unpleasant foul odor.
The amount of treatment is very large and there is a constraint that it must be treated in a short period of time before it decomposes, the incinerator becomes large and both initial cost and running cost increase, and a large amount is periodically discharged. A large-scale storage pit is required when attempting to downsize the furnace by incinerating the object to be processed over time, which requires a large amount of cost for its construction and the construction of the system for transferring the object to be processed. A large amount of cost is also incurred for the control of the bad smell generated from the. In addition, since bone and shell solid matter, stones, sand, and residues are mixed, the life of the incinerator is shortened, and there is a drawback that a large amount of incinerated ash is generated.

【0003】[0003]

【発明が解決しようとする課題】本発明が解決しようと
する課題は、動植物・魚介類等の動植物性有機固形物を
嫌気性微生物の働きにより液化し、メタンガス、炭酸ガ
ス、硫化水素等のガスに分解し、無機化することによ
り、肉部分と骨、貝肉と貝殻や角質部分、あるいは貝類
のひも、臓物と石、砂、残滓、さらには厨房ゴミの腐敗
性有機質と骨や貝殻等とを分離、処理する方法、ならび
にその装置を提供することにある。
The problem to be solved by the present invention is to liquefy animal and plant organic solids such as animals and plants and seafood by the action of anaerobic microorganisms, and to gas such as methane gas, carbon dioxide gas and hydrogen sulfide. By decomposing into minerals and mineralizing it, meat and bones, shellfish and shells and horny parts, or strings of shellfish, offal and stones, sand, residue, and perishable organic substances of kitchen garbage and bones and shells, etc. To provide a method for separating and processing the same, and an apparatus therefor.

【0004】[0004]

【課題を解決するための手段】前記課題を解決するため
に、本発明の動植物性有機固形物の処理方法、ならびに
その装置は、少なくとも嫌気性微生物群を含む水溶液
に、動植物性有機固形物を浸漬し、外気と遮断した雰囲
気中で該有機固形物を嫌気性微生物の働きにより低分子
有機物とすることにより液化させ、さらにこれをメタン
発酵菌の働きによってメタンガス、炭酸ガス、硫化水素
等のガスに分解し無機化させて一次処理液を得るととも
に、前記一次処理液を、後段の好気性処理槽内の有機物
負荷が所定値に保たれるよう好気性二次処理した処理液
の一部、もしくは清水のような洗浄液で希釈しながら一
定濃度、一定流量で好気性処理槽内へ供給し好気性二次
処理するようにしたものである。
In order to solve the above-mentioned problems, a method for treating an animal and plant organic solid according to the present invention, and an apparatus therefor are provided with an animal and plant organic solid in an aqueous solution containing at least an anaerobic microorganism group. By immersing and liquefying the organic solid matter by converting it into a low-molecular organic matter by the action of anaerobic microorganisms in an atmosphere isolated from the outside air, and further liquefying it by the action of methane-fermenting bacteria, gas such as methane gas, carbon dioxide gas, hydrogen sulfide, etc. While obtaining a primary treatment liquid by decomposing into a mineral, the primary treatment liquid, a part of the treatment liquid subjected to aerobic secondary treatment so that the organic load in the subsequent aerobic treatment tank is maintained at a predetermined value, Alternatively, it is diluted with a cleaning solution such as fresh water and supplied to the aerobic treatment tank at a constant concentration and a constant flow rate for aerobic secondary treatment.

【0005】そして、前記一次処理液を後続する好気性
処理槽内の有機物負荷が所定値に保たれるよう一定濃度
に希釈する構成は、一次処理液を、好気性処理槽内の処
理液生物相が維持されるよう好気性二次処理した処理液
の一部、もしくは清水のような洗浄液で希釈しながら制
御して、一定濃度、一定流量で好気性処理槽内へ供給す
るようにした態様が含まれる。
The structure in which the primary treatment liquid is diluted to a constant concentration so that the organic load in the subsequent aerobic treatment tank is maintained at a predetermined value is obtained by treating the primary treatment liquid with the treatment liquid organisms in the aerobic treatment tank. A mode in which control is performed while diluting with a part of the treatment liquid that has been subjected to the aerobic secondary treatment so that the phase is maintained, or with a cleaning liquid such as fresh water, and is supplied into the aerobic treatment tank at a constant concentration and a constant flow rate Is included.

【0006】[0006]

【発明の実施の形態】この発明に係る動植物性有機固形
物の処理方法、ならびにその装置は、少なくとも嫌気性
微生物群を含む水溶液に、動植物性有機固形物を浸漬
し、外気と遮断した雰囲気中で該有機固形物を嫌気性微
生物の働きにより低分子有機物とすることにより液化さ
せ、さらにこれをメタン発酵菌の働きによってメタンガ
ス、炭酸ガス、硫化水素等のガスに分解し無機化させて
一次処理液を得るとともに、前記一次処理液を、後段の
好気性処理槽内の有機物負荷が所定値に保たれるよう好
気性二次処理した処理液の一部、もしくは清水で希釈し
ながら一定濃度、一定流量で好気性処理槽内へ供給する
ようにしたものである。以下、実施例を説明しながら実
施形態の具体的詳細を述べる。
BEST MODE FOR CARRYING OUT THE INVENTION A method for treating animal and plant organic solids according to the present invention, and an apparatus therefor are used in an atmosphere in which the animal and vegetable organic solids are immersed in an aqueous solution containing at least an anaerobic microorganism group and isolated from the outside air. The organic solid matter is liquefied by converting it into a low molecular weight organic matter by the action of anaerobic microorganisms, and is further decomposed into gas such as methane gas, carbon dioxide gas, hydrogen sulfide and the like by the action of methane-fermenting bacteria to be a primary treatment. Along with obtaining the liquid, the primary treatment liquid, a portion of the treatment liquid aerobically secondary treatment so that the organic load in the aerobic treatment tank of the latter stage is maintained at a predetermined value, or a constant concentration while diluted with fresh water, The gas is supplied into the aerobic treatment tank at a constant flow rate. Hereinafter, specific details of the embodiment will be described while describing examples.

【0007】[0007]

【実施例】本発明の詳細な特長について、添付図面に記
載された実施例により説明する。図1には、本発明の動
植物・魚介類等の動植物性有機固形物を嫌気性微生物の
働きにより液化させ、さらにこれをメタン発酵菌の働き
によってメタンガス、炭酸ガス、硫化水素等のガスに分
解し無機化するようにした分離、処理装置の基本構成が
示されており、図中、符号1は動植物性有機固形物3を
外気と遮断した雰囲気で少なくとも嫌気性微生物群を含
む水溶液中に浸漬する嫌気性処理槽を示す。嫌気性処理
槽1は、液化、発酵と洗浄の工程を兼用して行うもの
で、その頂部には、処理槽内部を外気と遮断した雰囲気
にする蓋5が、また、その底部または処理槽内壁面に
は、該嫌気性微生物群を含む水溶液と動植物性有機固形
物を液化およびガス化するのに最適な温度に加温する加
温管10、および動植物性有機固形物と嫌気性微生物群
を含む水溶液との接触をこの処理槽内で良好に嫌気性消
化が促進されるようにする攪拌手段9とが備えられてい
る。また、この底部近傍には、動植物性有機固形物を入
れた籠、網、または布袋、もしくはそれらから成る篭箱
2、ならびに動植物性有機固形物自体等を受けるスノコ
状の受台4が設けられている。処理槽底部の形状は、漏
斗状になっており、その最下部にスラリー抜取りノズル
が設けられている。処理槽1の内部は単一空間でもよい
が、好ましくは、図示したように隔壁により複数の処理
区画に画成し、該処理区画内に嵌装されるよう用意され
た篭箱2により、貝類等投入、分離処理、ならびに分離
後の骨、貝殻、残滓等の洗浄、搬出が各々の処理区画毎
に行われるようにする方がその機能を向上せしめる。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Detailed features of the present invention will be described with reference to embodiments shown in the accompanying drawings. In FIG. 1, animal and plant organic solids such as animals and plants of the present invention are liquefied by the action of anaerobic microorganisms, which are further decomposed into gases such as methane gas, carbon dioxide gas and hydrogen sulfide by the action of methane-fermenting bacteria. The basic structure of the separation and treatment device which is adapted to be mineralized is shown. In the figure, reference numeral 1 is an atmosphere in which animal and plant organic solids 3 are shielded from the outside air, and immersed in an aqueous solution containing at least anaerobic microorganisms. An anaerobic treatment tank is shown. The anaerobic treatment tank 1 combines the processes of liquefaction, fermentation and washing, and has a lid 5 at the top thereof for making the inside of the treatment tank an atmosphere isolated from the outside air, and at the bottom thereof or in the treatment tank. On the wall surface, a heating tube 10 for heating the aqueous solution containing the anaerobic microorganisms and the animal and vegetable organic solids to an optimum temperature for liquefying and gasifying the animal and vegetable organic solids, and the animal and plant organic solids and the anaerobic microorganisms are provided. An agitating means 9 is provided so as to favorably promote the anaerobic digestion in the treatment tank in contact with the aqueous solution containing. In the vicinity of the bottom, a basket, a net, or a cloth bag containing animal or plant organic solids, or a cage 2 made of them, and a slat-shaped receiving stand 4 for receiving the animal or plant organic solids themselves are provided. ing. The shape of the bottom of the processing tank is funnel-shaped, and the slurry withdrawing nozzle is provided at the bottom of the funnel. The inside of the treatment tank 1 may be a single space, but preferably, as shown in the figure, a plurality of treatment compartments are defined by partition walls, and shells are prepared by a cage box 2 prepared to be fitted into the treatment compartments. The function is improved by performing equal injection, separation treatment, and washing and unloading of bones, shells, and debris after separation for each treatment section.

【0008】符号6は嫌気性処理槽1の頂部から抽出さ
れるガスから硫黄分を除去する脱硫器、7は脱硫後のガ
ス(主としてメタンガス)を貯留するガス貯槽、8は嫌
気性処理槽1の頂部ガスを、攪拌手段9に向けて風入し
槽内をガス攪拌する送風機、11は動植物性有機固形物
を入れた篭箱を処理槽に投入、搬出するクレーン、12
は篭箱に振動を加えて篭箱内の分離後の骨、貝殻、残滓
等の固形物の洗浄を良好に促進するための加振器、13
は貝肉を液化およびガス化するのに最適な温度を加える
温水ボイラー、14は嫌気性微生物群を含む水溶液の液
温を測定する温度計、15は嫌気性微生物群を含む水溶
液の水素イオン濃度を測定するPH計、16は水溶液の
酸化還元電位を測定するORP計、17は水溶液の有機
物濃度を測定する濃度計、18は好気性処理槽、19は
曝気槽用送風機、20は曝気槽用散気口、21は沈殿
槽、22は余剰汚泥槽、23は余剰汚泥を脱水処理しケ
ーキ状にして廃棄するための脱水機である。
Reference numeral 6 is a desulfurizer for removing sulfur from the gas extracted from the top of the anaerobic treatment tank 1, 7 is a gas storage tank for storing the gas (mainly methane gas) after desulfurization, and 8 is the anaerobic treatment tank 1. An air blower that blows the top gas into the stirring means 9 to stir the inside of the tank, 11 is a crane that puts in and out a basket box containing animal and plant organic solids in the processing tank, 12
Is a shaker for vibrating the cage to favorably promote the washing of solids such as bones, shells, and debris after separation in the cage, 13
Is a hot water boiler that applies the optimum temperature for liquefying and gasifying shellfish, 14 is a thermometer for measuring the liquid temperature of an aqueous solution containing anaerobic microorganisms, and 15 is the hydrogen ion concentration of an aqueous solution containing anaerobic microorganisms. A PH meter for measuring, an ORP meter for measuring an oxidation-reduction potential of an aqueous solution, a densitometer for measuring an organic matter concentration of the aqueous solution, a aerobic treatment tank, a blower for an aeration tank, and a blower for an aeration tank. An air diffuser, 21 is a sedimentation tank, 22 is an excess sludge tank, and 23 is a dehydrator for dehydrating excess sludge to form a cake and discarding it.

【0009】図2に一次処理液を好気性処理槽内に導い
て好気性二次処理するフローチャートを示す。本発明の
好気性二次処理は、処理槽内に処理後の骨、貝殻、残滓
等の無機固形物を洗浄するための洗浄液を供給する供給
路と、前記処理槽から一次処理液を好気性処理槽に向け
て排出する排出路と、前記供給路と排出路とを短絡する
バイパスとを設け、さらに前記供給路91中には供給制
御弁CV−2、排出路92中には排出制御弁CV−3、
およびバイパス93中には返送水制御弁CV−1をそれ
ぞれ設け、それらの各制御弁の開閉、開度調節を好気性
処理槽内への一次処理液濃度が一定濃度、かつ一定流量
となるよう調整できるようにしている。P−1は排出補
助ポンプ、P−2は供給ポンプ、DC−1、DC−2、
DC−3は濃度計である。.
FIG. 2 shows a flow chart for introducing the primary treatment liquid into the aerobic treatment tank to perform the aerobic secondary treatment. The aerobic secondary treatment of the present invention is a supply path for supplying a cleaning liquid for washing inorganic solids such as bones, shells, and residues after the treatment in the treatment tank, and aerobically treating the primary treatment liquid from the treatment tank. A discharge passage for discharging to the processing tank and a bypass for short-circuiting the supply passage and the discharge passage are provided, and further, a supply control valve CV-2 is provided in the supply passage 91, and a discharge control valve is provided in the discharge passage 92. CV-3,
A return water control valve CV-1 is provided in the bypass 93 and the control valve is opened / closed and the opening thereof is adjusted so that the concentration of the primary treatment liquid in the aerobic treatment tank becomes a constant concentration and a constant flow rate. I am able to adjust it. P-1 is an auxiliary discharge pump, P-2 is a supply pump, DC-1, DC-2,
DC-3 is a densitometer. .

【0010】次に動植物性有機固形物と骨、貝殻、残滓
等の無機固形物とを分離、処理するプロセスについて説
明する。被処理物である動植物性有機固形物、例えば貝
類を、貝殻がついたまま、篭箱2に入れ嫌気性処理槽1
に投入し、パッキンを介して処理槽上部を蓋5により密
閉したのち、少なくとも嫌気性微生物群を含む水溶液を
貝類が完全に浸漬するよう注入する。これにより嫌気性
発酵が開始される。
Next, the process for separating and treating the animal and plant organic solid matter and the inorganic solid matter such as bones, shells and residues will be described. An anaerobic treatment tank 1 containing an animal and plant organic solid substance, such as shellfish, which is an object to be treated, is put in a basket box 2 with the shell attached.
Then, the upper part of the treatment tank is sealed with a lid 5 through a packing, and then an aqueous solution containing at least an anaerobic microorganism group is injected so that the shellfish are completely immersed. This starts anaerobic fermentation.

【0011】動植物性有機固形物は、初期の段階で嫌気
性微生物群を含む水溶液中に含まれる酸生成菌群の作用
により、単糖類、アミノ酸等の分子量の小さい物質を経
て、酢酸、プロピオン酸、酪酸、バレリアン酸等の低級
脂肪酸に変換し液化される。次いで、ガス生成過程に入
り、前過程で生じた有機酸類は、基質特異性の強いメタ
ン細菌群により分解され、CH、COなどのガスに
分解される。このようにして動植物性有機固形物を構成
する有機物は、有機酸に変換されたのち、メタンガスと
炭酸ガスに分解され、一部菌体として増殖するが、基質
の減少により一部は死滅し、他のメタン菌によりメタン
ガスと炭酸ガスに分解され、全体として減少の方向に進
み、無機化が進む。このようにして、動植物性有機固形
物は減容化および無機化が行われ、不快な悪臭問題等を
解消した一次処理液が得られる。
The animal and plant organic solid matter is converted to acetic acid or propionic acid through substances having a small molecular weight such as monosaccharides and amino acids by the action of acid-producing bacteria contained in an aqueous solution containing anaerobic microorganisms at an early stage. , Butyric acid, valeric acid, etc. are converted to lower fatty acids and liquefied. Next, in the gas generation process, the organic acids generated in the previous process are decomposed by a group of methane bacteria having a strong substrate specificity, and decomposed into gas such as CH 4 and CO 2 . In this way, the organic matter constituting the animal and plant organic solid matter is converted into organic acid, decomposed into methane gas and carbon dioxide gas, and proliferates as a part of mycelium, but partly dies due to the decrease of the substrate, It is decomposed into methane gas and carbon dioxide gas by other methane bacteria, and as a whole, it progresses in the direction of decrease and mineralization progresses. In this way, the animal and plant organic solid matter is reduced in volume and mineralized, and a primary treatment liquid that solves the problem of unpleasant malodor can be obtained.

【0012】貝類等の動植物性有機固形物は、必ずしも
篭箱2に入れなくても嫌気性発酵は行なわれるが、ハン
ドリングの面、分離、処理の調整の面から篭箱に入れ、
かつ、複数の処理区画をもたせて重複処理が行なえるよ
うにすることが飛躍的に有利である。また、嫌気性発酵
は、加温管10を作動させ、嫌気性微生物群を含む水溶
液と貝類等の動植物性有機固形物を液化、およびガス化
するのに最適な温度に加温し、また攪拌手段9を作動さ
せて両者の接触を大きくしてやることにより、この処理
槽内で良好な嫌気性消化が行なわれる。温水ボイラー1
3の熱源はガス、重油、電気等どのようなものでもよい
が、嫌気性発酵に伴って発生するメタンガスをこれに当
てるのが経済的である。攪拌手段9は前述のガス攪拌以
外に、図2に略示したような機械的攪拌機で行なうか、
あるいは両者を併用する方式でも同様の成果が得られ
る。
Although anaerobic fermentation is carried out even if animal and plant organic solids such as shellfish are not necessarily put in the basket box 2, they are put in the basket box from the viewpoint of handling, separation and adjustment of treatment.
At the same time, it is dramatically advantageous to provide a plurality of processing sections so that duplicate processing can be performed. In the anaerobic fermentation, the heating tube 10 is operated to heat the aqueous solution containing the anaerobic microorganisms and animal and plant organic solids such as shellfish to an optimum temperature for gasifying and stirring the mixture. By activating the means 9 to increase the contact between the two, good anaerobic digestion is performed in this treatment tank. Hot water boiler 1
The heat source of 3 may be any of gas, heavy oil, electricity, etc., but it is economical to apply methane gas generated by anaerobic fermentation. The stirring means 9 may be a mechanical stirrer as schematically shown in FIG. 2 in addition to the above gas stirring.
Alternatively, the same result can be obtained by using both methods together.

【0013】次に好気性二次処理について説明する。好
気性処理槽18に送られた嫌気性発酵・消化が終了した
嫌気性微生物群を含む一次処理液は、COD、およびB
ODは数百ppmまでしか処理されていないため、その
濃度は放流規制値をはるかに上回り、さらに有機物を分
解処理する工程を組み合わせる必要がある。この有機物
分解方法には、標準活性汚泥法、接触酸化法、散水濾床
法、回転円板法等があり、そのいずれでもよいが、標準
活性汚泥法を例にとれば、曝気槽用送風機19により曝
気槽用散気口20から好気性処理槽18内へ空気を送っ
て好気性活性汚泥中の微生物群にその空気中の酸素を吸
収させ、有機物を酸化分解させる。これによれば、最終
処理水を洗浄水として嫌気性処理槽1にリターンさせ、
前述のように骨、貝殻、残滓等の無機固形物の洗浄に使
ったり、好気性二次処理を行うための希釈水として使う
など水の有効利用を計ることができる。曝気槽液は連続
的に沈殿槽21に導かれ、活性汚泥を沈降、分離させ
る。そして、上澄水は前述のように当該処理システム用
の洗浄水、希釈水としてリサイクルを計るか、海洋に放
流される。同時に、沈降した活性汚泥の大部分は返送汚
泥として好気性処理槽18に返送され、他は余剰汚泥と
して余剰汚泥槽22に貯留する。過剰な汚泥が発生した
場合は、脱水機23により汚泥を脱水し、固形状(ケー
キ)にして処分される。
Next, the aerobic secondary processing will be described. The primary treatment liquid containing the anaerobic microorganism group that has been subjected to the anaerobic fermentation and digestion sent to the aerobic treatment tank 18 is COD and B.
Since OD is treated only up to several hundreds ppm, its concentration is far higher than the emission control value, and it is necessary to combine a step of decomposing organic matter. This organic matter decomposition method includes a standard activated sludge method, a catalytic oxidation method, a sprinkling filter method, a rotating disk method and the like, and any of them may be used, but in the case of the standard activated sludge method, an aerator tank blower 19 Thus, air is sent from the aeration tank air diffuser 20 into the aerobic treatment tank 18 so that the microorganisms in the aerobic activated sludge absorb oxygen in the air to oxidize and decompose the organic matter. According to this, the final treated water is returned to the anaerobic treatment tank 1 as washing water,
As described above, the water can be effectively used by washing it with inorganic solids such as bones, shells, and debris, or by using it as dilution water for aerobic secondary treatment. The aeration tank liquid is continuously guided to the settling tank 21 to settle and separate the activated sludge. Then, the supernatant water is recycled as washing water or dilution water for the treatment system as described above, or is discharged to the ocean. At the same time, most of the settled activated sludge is returned to the aerobic treatment tank 18 as return sludge, and the rest is stored in the excess sludge tank 22 as excess sludge. When excessive sludge is generated, the sludge is dehydrated by the dehydrator 23 to be solid (cake) and disposed.

【0014】次にバイパス制御弁CV−1、供給制御弁
CV−2を操作して、二次処理設備である好気性処理槽
へ供給する一次処理水を、水質および水量が一定になる
よう最終処理水、または清水を用いて、希釈して制御す
る方法について説明する。好気性二次処理は、嫌気性一
次処理により、メタン、硫化水素、アンモニア、炭酸ガ
ス等に分解されずに残留している低級脂肪酸等の分解中
間生成物等を好気性微生物群を用いて分解し、無機化す
ることにより、BOD、CODの値を放流可能な値まで
下げるための装置であり、安定した処理水水質を得るた
めには、好気性微生物槽に対し、一定のBOD負荷[k
g/m・日]また最終沈殿池に対しては一定の水面積
負荷[m/m・日]で運転することが望ましい。こ
のため一次処理液は直接二次処理設備に導かないで一次
処理液と希釈水の比率を刻々変化させ、一定濃度、一定
水量になるよう希釈しつつ二次処理設備に導入する。希
釈水としては、清水、あるいは二次処理した処理水が用
いられる。
Next, the bypass control valve CV-1 and the supply control valve CV-2 are operated to finalize the primary treated water to be supplied to the aerobic treatment tank, which is the secondary treatment facility, so that the quality and quantity of water are constant. A method of diluting and controlling treated water or fresh water will be described. The aerobic secondary treatment is a anaerobic primary treatment that decomposes residual intermediate decomposition products such as lower fatty acids without decomposition into methane, hydrogen sulfide, ammonia, carbon dioxide, etc. using aerobic microorganisms. However, it is a device for lowering the BOD and COD values to a dischargeable value by making them inorganic. In order to obtain stable treated water quality, a certain BOD load [k
g / m 3 · day] It is desirable to operate the final settling tank with a constant water surface load [m 3 / m 2 · day]. Therefore, the primary treatment liquid is introduced directly into the secondary treatment equipment while being directly introduced into the secondary treatment equipment by diluting the ratio of the primary treatment liquid and the diluting water to a constant concentration and a constant amount of water. As the diluting water, fresh water or treated water subjected to secondary treatment is used.

【0015】この希釈を含む好気性処理槽内の有機物負
荷が所定値に保たれるのに適した一定濃度、かつ一定流
量とするための調節は、返送水制御弁CV−1、供給制
御弁CV−2の各々を以下のように開閉、もしくは開度
を調節して行う。これら一連の調節は好気性処理槽18
の入口における供給液の濃度を濃度計DC−1により刻
々測定し、この入口を通過する供給液の流量Qを一定に
保ちながら、供給制御弁CV−2の開度を調節して、こ
の部分の濃度Cを一定に維持する。濃度Cの維持は、一
次処理液の濃度が高い運転初期においては、供給制御弁
CV−2の開度が極端に絞られ、また、一次処理液の濃
度が低い運転停止間近かにおいては、供給制御弁CV−
2の開度が解放状態となるように開かれ、バイパスから
送給されてくる洗浄液と一次処理液との混合割合をバリ
アブルに変化させて行っている。
Adjustments to maintain a constant concentration and a constant flow rate suitable for keeping the organic matter load in the aerobic treatment tank including the dilution at a predetermined value are performed by the return water control valve CV-1 and the supply control valve. Each CV-2 is opened / closed or the opening is adjusted as follows. These series of adjustments are performed in the aerobic treatment tank 18
The concentration of the supply liquid at the inlet of the inlet is constantly measured by a densitometer DC-1, and the opening of the supply control valve CV-2 is adjusted while maintaining a constant flow rate Q of the supply passing through the inlet. The concentration C of is kept constant. To maintain the concentration C, the opening of the supply control valve CV-2 is extremely narrowed at the beginning of the operation when the concentration of the primary treatment liquid is high, and the supply of the concentration C is near when the operation is stopped when the concentration of the primary treatment liquid is low. Control valve CV-
The opening of No. 2 is opened so as to be in an open state, and the mixing ratio of the cleaning liquid and the primary treatment liquid sent from the bypass is changed in a variable manner.

【0016】この調節は、これらシーケンスを順次処理
実行するマイコンにより、全自動で運転操作するように
してもよい。シーケンスの概要を説明すると、まず、返
送水制御弁CV−1をFC−2の指令により開き、好気
性二次処理した処理液の一部、もしくは清水のような洗
浄液を供給ポンプP−2により、流量Q[m/mi
n]で処理槽1、バイパスに向けて送給する。このあ
と、洗浄液の一部はバイパスを通り、他の一部は洗浄水
および希釈水として嫌気性処理槽1へ送られる。嫌気性
処理槽1に導かれた洗浄液は、攪拌手段により攪拌され
流入量と同量の混合流がオーバーフローし流出する。こ
の流出液はバイパスを通過してきた希釈水と合流し希釈
され、好気性処理槽に流入する。この時の流入液濃度が
濃度計DC−1により、検出され、その値が設定値のC
c[ppm]より大であれば、CV−2によりqが減
じ、Qは一定であるからqは増加し、小になればq
が増加しqは減少する。このようにして、QおよびC
は一定に保たれる。
This adjustment may be carried out fully automatically by a microcomputer that sequentially executes these sequences. To explain the outline of the sequence, first, the return water control valve CV-1 is opened by the command of FC-2, and a part of the aerobic secondary treatment liquid or a cleaning liquid such as fresh water is supplied by the supply pump P-2. , Flow rate Q [m 3 / mi
n] to feed the treatment tank 1 to the bypass. Then, a part of the cleaning liquid passes through the bypass, and the other part is sent to the anaerobic treatment tank 1 as cleaning water and dilution water. The cleaning liquid introduced into the anaerobic treatment tank 1 is agitated by the agitating means and a mixed flow of the same amount as the inflow is overflowed and flows out. This effluent joins the dilution water that has passed through the bypass, is diluted, and flows into the aerobic treatment tank. The concentration of the influent at this time was detected by the densitometer DC-1, and the value was set as C.
If it is larger than c [ppm], q 1 will be decreased by CV-2, and since Q is constant, q 2 will increase, and if it becomes small, q 1
Increases and q 2 decreases. Thus, Q and C
Is kept constant.

【0017】次に運転停止間近かの操作について述べ
る。運転の経過とともに嫌気性処理槽1の出口濃度Ce
は暫時減少し予めDC−2に設定した洗浄の終点濃度に
達すると、DC−2の信号によりSV−2,SV−6は
閉となり、SV−1,SV−7は開となる。同時にQ
[m/min]に設定されたFC−1、およびCV−
3が作動し、好気性処理槽18への流入液量を制御す
る。またこの時点からCV−1は、FC−2の支配から
解放され、FC−3の支配を受ける。CV−1により制
御される流量はQ[m/min]からCeが終点濃度
に達したときの流量qmax [m/min]を差
引いた流量に制御される。この循環系に対してqma
xだけ余剰となるため好気性処理槽18からオーバーフ
ローし放流される。このことにより嫌気性処理槽1の水
位が低下し、下限に達したときLCの発信により供給補
助ポンプP−1は停止し、全運転過程を終了する。終了
と同時にSV−3は閉、SV−4は開となり、好気性処
理槽18内の生物相が維持される。これら一連の調整は
当該供給液の濃度を濃度計DC−1により感知し、その
信号を供給制御弁CV−2にフィードバックして全自動
運転する。
Next, a description will be given of an operation that is about to be stopped. Outlet concentration Ce of anaerobic treatment tank 1 with the progress of operation
Decreases for a while and reaches the cleaning end point concentration set in DC-2 in advance, SV-2 and SV-6 are closed and SV-1 and SV-7 are opened by the signal of DC-2. Q at the same time
FC-1 set to [m 3 / min], and CV-
3 operates to control the amount of liquid flowing into the aerobic treatment tank 18. From this point on, CV-1 is released from the control of FC-2 and is controlled by FC-3. The flow rate controlled by CV-1 is controlled to a flow rate obtained by subtracting the flow rate q 1 max [m 3 / min] when Q reaches the end point concentration from Q [m 3 / min]. Q 1 ma for this circulatory system
Since there is a surplus of x, it overflows from the aerobic treatment tank 18 and is discharged. As a result, the water level in the anaerobic treatment tank 1 is lowered, and when it reaches the lower limit, the supply auxiliary pump P-1 is stopped by the transmission of LC, and the entire operation process is terminated. Simultaneously with the end, SV-3 is closed and SV-4 is opened, and the biota in the aerobic treatment tank 18 is maintained. In the series of adjustments, the concentration of the supply liquid is sensed by the densitometer DC-1, and the signal is fed back to the supply control valve CV-2 to operate fully automatically.

【0018】処理槽1内にはPH計15、およびORP
計16の電極部を装着し、嫌気性微生物群を含む水溶液
におけるPH値、酸化還元電位を測定して発酵の進捗状
況を確認する。そして、動植物性有機固形物が液化し
て、嫌気性発酵・消化が終了したかどうかは、濃度計1
7により確認する。嫌気性発酵・消化が終了した嫌気性
微生物群を含む水溶液は、処理槽1上部から好気性処理
の二次処理設備に向けて抜取られ、それら処理設備によ
り、放流規制値以下に浄化され、当該処理システム用の
洗浄水、希釈水としてリサイクルを計るか、海洋に放流
される。
A PH meter 15 and an ORP are provided in the processing tank 1.
A total of 16 electrode parts are attached, and a PH value and an oxidation-reduction potential in an aqueous solution containing an anaerobic microorganism group are measured to confirm the progress status of fermentation. Then, it is determined whether the anaerobic fermentation / digestion is completed by liquefying the organic solids of animals and plants and the concentration meter 1
Confirm by 7. The aqueous solution containing the anaerobic microorganisms group that has undergone anaerobic fermentation / digestion is withdrawn from the upper part of the treatment tank 1 toward the secondary treatment equipment for aerobic treatment, and purified by these treatment equipment to below the discharge regulation value, Recycle as wash water or dilution water for treatment system or discharge to the ocean.

【0019】嫌気性処理槽1内に残された分離後の骨、
貝殻、残滓等の固形物は、それら表面に嫌気性発酵・消
化済みの水溶液が付着したままとなっているので、前記
最終処理水、もしくは清水により洗浄を行う。洗浄は、
嫌気性処理槽1をそのまま洗浄槽として用い、槽内に最
終処理水、もしくは清水を流入させ、前記攪拌手段9を
作動させて空気攪拌を行う。この攪拌は、篭箱2をクレ
ーン11により若干吊上げ、加振器12を駆動して篭箱
に振動を加え、洗浄の促進を計るようにしてもよい。洗
浄された貝殻は、クレーン11により篭箱2とともに吊
上げ、水分を切ったのち、嫌気性処理槽1外に取出す。
The separated bone left in the anaerobic treatment tank 1,
Since solid substances such as shells and residues have the anaerobic fermentation and digested aqueous solution still attached to their surfaces, they are washed with the final treated water or fresh water. Washing is
The anaerobic treatment tank 1 is used as it is as a washing tank, the final treated water or fresh water is introduced into the tank, and the stirring means 9 is operated to perform air stirring. For this agitation, the basket box 2 may be slightly lifted by the crane 11 and the vibrator 12 may be driven to apply vibration to the basket box to accelerate cleaning. The washed shell is lifted together with the cage 2 by the crane 11 to remove water, and then taken out of the anaerobic treatment tank 1.

【0020】[0020]

【発明の効果】本発明は、次のような効果を奏する。The present invention has the following effects.

【0021】A.前記のように構成された動植物性有機
固形物の処理方法、ならびにその装置によれば、少なく
とも嫌気性微生物群を含む水溶液に、の動植物性有機固
形物を投入浸漬し、外気と遮断した雰囲気中でそれらを
加温し、該の動植物性有機固形物を嫌気性微生物の働き
により液化し、メタンガス、炭酸ガス、硫化水素等のガ
スに分解し減容化、無機化するようにしたものであるか
ら、埋立てする敷地の制約を受けることもなく、不快な
悪臭を放つ問題も解消される。B.従来の焼却処分との
比較において、イニシャルコスト、ランニングコストと
もに飛躍的に小さくなって、多量の焼却灰が発生すると
いうこともなく、分離された貝殻固形物は、非常にきれ
いな状態にあって、飼料、肥料等のカルシュウム源とし
て活用することもできる。C.一次処理液を、後段の好
気性処理槽内の有機物負荷が所定値に保たれるよう好気
性二次処理した処理液の一部、もしくは清水のような洗
浄液で希釈しながら一定濃度、一定流量で好気性処理槽
内へ供給し好気性二次処理するようにしたので、処理後
の骨、貝殻、残滓等の無機固形物を洗浄するとができ、
なおかつ処理液は放流規制値以下に浄化され、当該処理
システム用の洗浄水、希釈水としてリサイクルを計る
か、海洋に放流することができる。
A. According to the method for treating animal and plant organic solids configured as described above, and according to the apparatus, an aqueous solution containing at least an anaerobic microbial group, is immersed by immersing the animal and plant organic solids in an atmosphere isolated from the outside air. By heating them, and liquefying the animal and plant organic solids by the action of anaerobic microorganisms, decomposing them into gases such as methane gas, carbon dioxide gas, hydrogen sulfide, etc. to reduce the volume and mineralize them. Therefore, the problem of giving off an unpleasant odor is solved without being restricted by the landfill site. B. Compared with conventional incineration disposal, both initial cost and running cost are dramatically reduced, and a large amount of incinerated ash is not generated, the separated shell solid is in a very clean state, It can also be used as a source of calcium for feed, fertilizer, etc. C. A certain concentration and a constant flow rate while diluting the primary treatment liquid with a portion of the treatment liquid that has undergone aerobic secondary treatment so that the organic load in the subsequent aerobic treatment tank is maintained at a specified value, or with a cleaning liquid such as fresh water. Since it was supplied to the aerobic treatment tank for secondary aerobic treatment, it is possible to wash the inorganic solids such as bones, shells, and residues after the treatment.
Moreover, the treatment liquid is purified to below the discharge regulation value, and can be recycled as wash water or dilution water for the treatment system or discharged to the ocean.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の動植物性有機固形物と骨、貝殻、残滓
等の無機固形物とを分離、処理する装置の説明図。
FIG. 1 is an explanatory view of an apparatus for separating and treating an animal and plant organic solid matter of the present invention and an inorganic solid matter such as bones, shells and residues.

【図2】一次処理液を好気性処理槽内に導いて好気性二
次処理するフローチャート。
FIG. 2 is a flowchart for introducing the primary treatment liquid into the aerobic treatment tank to perform the aerobic secondary treatment.

【符号の説明】[Explanation of symbols]

1…嫌気性処理槽 18…好気性処
理槽 2…篭箱 19…曝気槽用
送風機 3…動植物性有機固形物 20…曝気槽用
散気口 4…受台 21…沈殿槽 5…蓋 22…余剰汚泥
槽 6…脱硫器 23…脱水機 7…ガス貯槽 91…供給路 8…送風機 92…排出路 9…攪拌手段 93…バイパス 10…加温管 P−1…供給
補助ポンプ 11…クレーン P−2…供給
ポンプ 12…加振器 CV−1…バ
イパス制御弁 13…温水ボイラー CV−2…供
給制御弁 14…温度計 CV−3…排
出制御弁 15…PH計 DC−1…濃
度計 16…ORP計 17…濃度計
1 ... Anaerobic treatment tank 18 ... Aerobic treatment tank 2 ... Basket box 19 ... Aerator air blower 3 ... Animal and plant organic solids 20 ... Aeration tank air diffuser 4 ... Receptacle 21 ... Settling tank 5 ... Lid 22 ... Excess sludge tank 6 ... Desulfurizer 23 ... Dehydrator 7 ... Gas storage tank 91 ... Supply path 8 ... Blower 92 ... Discharge path 9 ... Stirring means 93 ... Bypass 10 ... Heating pipe P-1 ... Supply auxiliary pump 11 ... Crane P- 2 ... Supply pump 12 ... Vibrator CV-1 ... Bypass control valve 13 ... Hot water boiler CV-2 ... Supply control valve 14 ... Thermometer CV-3 ... Discharge control valve 15 ... PH meter DC-1 ... Concentration meter 16 ... ORP meter 17 ... Densitometer

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 少なくとも嫌気性微生物群を含む水溶液
に、動植物性有機固形物を浸漬し、外気と遮断した雰囲
気中で該有機固形物を嫌気性微生物の働きにより低分子
有機物とすることにより液化させ、さらにこれをメタン
発酵菌の働きによってメタンガス、炭酸ガス、硫化水素
等のガスに分解し無機化させて一次処理液を得るととも
に、前記一次処理液を、後段の好気性処理槽内の有機物
負荷が所定値に保たれるよう好気性二次処理した処理液
の一部、もしくは清水のような洗浄液で希釈しながら一
定濃度、一定流量で好気性処理槽内へ供給するようにし
たことを特長とする動植物性有機固形物の処理方法。
1. A liquefaction by immersing an animal or plant organic solid in an aqueous solution containing at least an anaerobic microorganism group and converting the organic solid into a low-molecular organic substance by the action of the anaerobic microorganism in an atmosphere shielded from the outside air. Further, by the action of methane-fermenting bacteria, it is decomposed into gas such as methane gas, carbon dioxide gas, hydrogen sulfide and the like to be mineralized to obtain a primary treatment liquid, and the primary treatment liquid is used as an organic substance in an aerobic treatment tank in the subsequent stage. To ensure that the load is maintained at a predetermined value, a portion of the aerobic secondary treatment liquid or a cleaning liquid such as fresh water is diluted and supplied at a constant concentration and flow rate into the aerobic treatment tank. A characteristic method for treating organic solids of plants and animals.
【請求項2】 洗浄液を嫌気性処理槽内に導き、処理後
の骨、貝殻、残滓等の無機固形物を洗浄するようにした
請求項1記載の動植物性有機固形物の処理方法。
2. The method for treating animal and plant organic solids according to claim 1, wherein the cleaning liquid is introduced into an anaerobic treatment tank to wash the treated inorganic solids such as bones, shells and debris.
【請求項3】 少なくとも嫌気性微生物群を含む水溶液
に、動植物性有機固形物を浸漬し、外気と遮断した雰囲
気中で該有機固形物を嫌気性微生物の働きにより低分子
有機物とすることにより液化させ、さらにこれをメタン
発酵菌の働きによってメタンガス、炭酸ガス、硫化水素
等のガスに分解することにより無機化して一次処理する
ための嫌気性処理槽と、前記一次処理液を好気性二次処
理する好気性処理槽と、前記嫌気性処理槽内に処理後の
骨、貝殻、残滓等の無機固形物を洗浄するための洗浄液
を供給する供給路と、前記嫌気性処理槽から一次処理液
を好気性処理槽に向けて排出する排出路と、前記供給路
と排出路とを短絡するバイパスとからなり、洗浄液で処
理後の無機固形物を洗浄するとともに、バイパスにより
供給路から分岐される当該洗浄液で、一次処理液を後続
する好気性処理槽内の有機物負荷が所定値に保たれるよ
う一定濃度に希釈するようにしたことを特長とする動植
物性有機固形物の処理装置。
3. A liquefaction by immersing an animal and plant organic solid in an aqueous solution containing at least an anaerobic microbial group, and converting the organic solid into a low-molecular organic substance by the action of the anaerobic microorganism in an atmosphere shielded from the outside air. Further, by the action of methane-fermenting bacteria, it is decomposed into gas such as methane gas, carbon dioxide gas, hydrogen sulfide, etc. by anaerobic treatment tank for mineralization and primary treatment, and the aerobic secondary treatment of the primary treatment liquid. An aerobic treatment tank, a supply path for supplying a cleaning liquid for washing inorganic solids such as bones, shells, and residues after the treatment in the anaerobic treatment tank, and a primary treatment liquid from the anaerobic treatment tank. It consists of a discharge path for discharging toward the aerobic treatment tank, and a bypass that short-circuits the supply path and the discharge path. The inorganic solid matter after processing is washed with a cleaning liquid, and is branched from the supply path by the bypass. An apparatus for treating animal and plant organic solids, characterized in that the cleaning liquid is used to dilute the primary treatment liquid to a constant concentration so that the organic substance load in the subsequent aerobic treatment tank is maintained at a predetermined value.
【請求項4】 前記供給路に供給制御弁、排出路に排出
制御弁、およびバイパスに返送水制御弁をそれぞれ設
け、それらの各制御弁の開度を好気性処理槽内への供給
液濃度が一定濃度、かつ一定流量となるよう当該供給液
の濃度を濃度計により感知し、その信号を前記供給制御
弁にフィードバックして自動制御することを特長とする
請求項3記載の動植物性有機固形物の処理装置。
4. A supply control valve is provided in the supply passage, a discharge control valve is provided in the discharge passage, and a return water control valve is provided in the bypass, and the opening of each control valve is set to the concentration of the supply liquid into the aerobic treatment tank. 4. The animal and plant organic solid according to claim 3, wherein the concentration of the feed liquid is sensed by a densitometer so as to have a constant concentration and a constant flow rate, and the signal is fed back to the feed control valve for automatic control. Object processing equipment.
JP8101814A 1996-03-19 1996-03-19 Treatment of animal-and plant-derived organic solid matter and apparatus therefor Pending JPH09253618A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8101814A JPH09253618A (en) 1996-03-19 1996-03-19 Treatment of animal-and plant-derived organic solid matter and apparatus therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8101814A JPH09253618A (en) 1996-03-19 1996-03-19 Treatment of animal-and plant-derived organic solid matter and apparatus therefor

Publications (1)

Publication Number Publication Date
JPH09253618A true JPH09253618A (en) 1997-09-30

Family

ID=14310604

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8101814A Pending JPH09253618A (en) 1996-03-19 1996-03-19 Treatment of animal-and plant-derived organic solid matter and apparatus therefor

Country Status (1)

Country Link
JP (1) JPH09253618A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002501481A (en) * 1997-01-20 2002-01-15 ロレアル Cosmetic composition containing a film-forming mixture comprising film-forming polymer particles and non-film-forming particles as a keratin fiber coating agent
JP2003190913A (en) * 2001-12-27 2003-07-08 Marine Chemical Kenkyusho:Kk Method for treating marine organic waste
JP2007000821A (en) * 2005-06-27 2007-01-11 Kajima Corp Treatment system of calcium mass-containing organic waste
JP2008049274A (en) * 2006-08-25 2008-03-06 Tama Tlo Kk Treatment apparatus and treatment method of shellfish
KR101450752B1 (en) * 2014-02-06 2014-10-17 이형철 Processing apparatus for fermentation of Animal carcasses

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002501481A (en) * 1997-01-20 2002-01-15 ロレアル Cosmetic composition containing a film-forming mixture comprising film-forming polymer particles and non-film-forming particles as a keratin fiber coating agent
JP2003190913A (en) * 2001-12-27 2003-07-08 Marine Chemical Kenkyusho:Kk Method for treating marine organic waste
JP2007000821A (en) * 2005-06-27 2007-01-11 Kajima Corp Treatment system of calcium mass-containing organic waste
JP2008049274A (en) * 2006-08-25 2008-03-06 Tama Tlo Kk Treatment apparatus and treatment method of shellfish
KR101450752B1 (en) * 2014-02-06 2014-10-17 이형철 Processing apparatus for fermentation of Animal carcasses

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