JPH0836791A - Manufacture of optical disk with lubricant film - Google Patents

Manufacture of optical disk with lubricant film

Info

Publication number
JPH0836791A
JPH0836791A JP6172665A JP17266594A JPH0836791A JP H0836791 A JPH0836791 A JP H0836791A JP 6172665 A JP6172665 A JP 6172665A JP 17266594 A JP17266594 A JP 17266594A JP H0836791 A JPH0836791 A JP H0836791A
Authority
JP
Japan
Prior art keywords
layer
lubricant
resin
film
optical disk
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6172665A
Other languages
Japanese (ja)
Inventor
Mitsugi Wakabayashi
貢 若林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Priority to JP6172665A priority Critical patent/JPH0836791A/en
Publication of JPH0836791A publication Critical patent/JPH0836791A/en
Pending legal-status Critical Current

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  • Optical Record Carriers And Manufacture Thereof (AREA)
  • Manufacturing Optical Record Carriers (AREA)

Abstract

PURPOSE:To prevent the generation of dusts due to the friction of the surface of the inner periphery of an optical disk with the rim of the inner periphery of a cartridge by applying positive charge to curable resin contained in lubricant and spraying it to the surface of the disk. CONSTITUTION:A thin film of a conductive layer 2 is formed a part in contact with a cartridge rim with ITO, Al film on the surface of an optical disk substrate 1 a vapor depositing method, a sputtering method, etc. Then, in order to add slipperiness to the layer 2, curable resin containing lubricant is sprayed. The lubricant mixing quantity is so set that a dynamic frictional coefficient between the lubricant film and the inner peripheral rib of the cartridge after the resin is cured, becomes 1.0 or less. Thus, the lubricant containing curable resin 4 is sprayed from a tank 7 via a filter 8 from a nozzle 5 to the surface of the board 1 rotating around a shaft 3 as the center. Immediately after the resin 4 is sprayed from the nozzle 5, positive charge is given by a positive charge generator 6. The resin 4 is selectively adhered with the layer 2 as ground, it is cured by ultraviolet rays or heat to be a lubricant film.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は滑性膜つき光ディスクの
製造方法に関する。詳しくはカートリッジと光ディスク
とが接触した部分から切削屑の発生することの少ない滑
性膜つき光ディスクの製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing an optical disk with a slipping film. More specifically, the present invention relates to a method for producing an optical disk with a slipping film, in which cutting chips are less likely to be generated from a portion where a cartridge and an optical disk are in contact with each other.

【0002】[0002]

【従来の技術】一般に光ディスクのうち、特にコンピュ
ータメモリとしての使用が期待される光磁気ディスク等
においては、その使用目的から記録・再生に高い信頼性
が要求される。このため、保管時においてディスク面に
ホコリ等が付着し又は傷等が生ずることを防止するため
に、又使用時にはディスク回転駆動装置に装着する際に
ディスク表面に指紋等が付着しないようにするためにプ
ラスチック製のケース(カートリッジ)内に収容されて
取り扱われている。
2. Description of the Related Art Generally, among optical disks, a magneto-optical disk, which is expected to be used as a computer memory, is required to have high reliability in recording and reproducing for its purpose of use. For this reason, in order to prevent dust and the like from being attached to the disc surface during storage, and to prevent scratches, etc., and to prevent fingerprints and the like from attaching to the disc surface when mounted on the disc rotation drive device during use. It is stored and handled in a plastic case (cartridge).

【0003】カートリッジケース内に収納された光ディ
スクは、使用時に駆動装置内に挿入され回転される。そ
して、使用後、駆動装置内より取り出される時は、回転
が完全に停止していない状態でカートリッジケースごと
持ち上げられる。この時、カートリッジケース内のディ
スク支持用のリムと回転している光ディスクがこすれ、
カートリッジケースのリム及び光ディスクの表面が削れ
てゴミが発生する。
The optical disk housed in the cartridge case is inserted into the drive unit and rotated during use. Then, after being used, when it is taken out from the drive device, it is lifted together with the cartridge case while the rotation is not completely stopped. At this time, the rim for supporting the disc in the cartridge case and the rotating optical disc are rubbed,
The rim of the cartridge case and the surface of the optical disc are scraped off to generate dust.

【0004】このゴミは、光ディスクの書込み、読みだ
しに支障となる場合がある。このため、このようなディ
スクカートリッジに収納される光ディスクは、通常、デ
ィスク支持部に対応する位置にPET(ポリエチレンテ
レフタレート)製フィルム等の滑性に優れた樹脂よりな
る滑性リングを配し、上記ディスク内周支持リブと光デ
ィスクとが擦れ合うのを防止するようになされているも
のもある。
This dust may interfere with writing and reading of the optical disc. For this reason, an optical disk housed in such a disk cartridge usually has a slip ring made of a resin such as a PET (polyethylene terephthalate) film having excellent slip characteristics at a position corresponding to the disk support, Some discs are designed to prevent the inner peripheral support ribs of the disc from rubbing against each other.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、PET
製フィルムよりなる滑性リングを光ディスクに貼り合わ
せるため用いている接着剤は、通常感圧接着剤等であり
高温時或いは経時的変化により劣化し、貼り合わせた滑
性リングが剥がれたりすることがある。またPETから
なるフィルムは非常に扱いにくく所定の位置に貼り合わ
せるのも難しい技術を要し生産性が低かった。
DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention
The adhesive used to attach the slippery ring made of a film to an optical disc is usually a pressure sensitive adhesive or the like, and may deteriorate at high temperature or with time, and the adhered slippery ring may peel off. is there. Further, the film made of PET is very difficult to handle and requires a technique that is difficult to bond to a predetermined position, resulting in low productivity.

【0006】[0006]

【課題を解決するための手段】そこで本発明はこのよう
な従来の問題点に鑑み鋭意検討を重ねた結果接着剤を使
用せず目的とする滑性膜を形成する方法を見いだし生産
性の優れた滑性膜つき光ディスクの製造方法を完成する
に至った。すなわち本発明の要旨は光ディスク基板のカ
ートリッジケースのリム部と接触する位置に導電層を形
成し、次いで、滑り剤を含有させた硬化性樹脂に正電荷
を加えた状態でディスク表面に噴霧することにより導電
層上に硬化性樹脂を付着させ、その後硬化性樹脂を硬化
することを特徴とする滑性膜つき光ディスクの製造方
法。
Therefore, the present invention has found out a method for forming a target slippery film without using an adhesive as a result of extensive studies in view of such conventional problems, and has excellent productivity. And, we have completed the manufacturing method of the optical disk with a slippery film. That is, the gist of the present invention is to form a conductive layer at a position in contact with the rim portion of the cartridge case of the optical disc substrate, and then spray the curable resin containing a slipping agent onto the disc surface with a positive charge. A method for producing an optical disk with a slipping film, comprising the steps of: attaching a curable resin onto the conductive layer by means of, and then curing the curable resin.

【0007】本発明において用いられる基板としては、
ポリカーボネート樹脂、アクリル樹脂、ポリオレフィン
樹脂等の樹脂基板が挙げられる。この基板の厚みは1〜
2mm程度が一般的である。このような樹脂基板上に形
成する光磁気記録層の層構成としては特に制限はなく、
公知の光磁気記録層の層構成を採用することができる。
As the substrate used in the present invention,
Examples of the resin substrate include polycarbonate resin, acrylic resin, and polyolefin resin. The thickness of this substrate is 1
It is generally about 2 mm. The layer structure of the magneto-optical recording layer formed on such a resin substrate is not particularly limited,
A known layer structure of the magneto-optical recording layer can be adopted.

【0008】例えばTbFe,TbFeCo,TbC
o,DyTbFeCo等の希土類と遷移金属との非晶質
磁性合金、MnBi,MnCuBi等の多結晶垂直磁化
膜等が用いられる。光磁気記録層としては単一の層を用
いても良いし、GdTbFe/TbFeのように2層以
上の記録層を重ねて用いても良い。
For example, TbFe, TbFeCo, TbC
Amorphous magnetic alloys of rare earths and transition metals such as o and DyTbFeCo, polycrystalline perpendicular magnetization films such as MnBi and MnCuBi, and the like are used. As the magneto-optical recording layer, a single layer may be used, or two or more recording layers such as GdTbFe / TbFe may be stacked and used.

【0009】上記基板と光磁気記録層との間には、干渉
層を設けることもできる。この層は、高屈折率の透明膜
による光の干渉効果により反射率を落とすことでノイズ
を低下させC/Nを向上させるためのものである。干渉
層は単層膜でも多層膜でも良い。干渉層の構成物質とし
ては、金属酸化物や金属窒化物が用いられる。
An interference layer may be provided between the substrate and the magneto-optical recording layer. This layer is for reducing noise by improving the C / N by lowering the reflectance due to the light interference effect of the transparent film having a high refractive index. The interference layer may be a single layer film or a multilayer film. A metal oxide or a metal nitride is used as a constituent material of the interference layer.

【0010】金属酸化物としてはAl2 3 ,Ta2
5 ,SiO2 ,SiO,TiO2 等の金属酸化物単独又
はこれらの混合物、或いはAl−Ta−Oの複合酸化物
等が挙げられる。更に、これらの酸化物に、他の元素、
例えば、Ti,Zr,W,Mo,Yb等が酸化物の形で
単独で、或いはAl,Taと複合して酸化物を形成して
いるものでも良い。
Al 2 O 3 and Ta 2 O are used as metal oxides.
Examples thereof include metal oxides such as 5 , SiO 2 , SiO, and TiO 2 alone or a mixture thereof, or a composite oxide of Al—Ta—O. In addition to these oxides, other elements,
For example, Ti, Zr, W, Mo, Yb or the like may be used alone in the form of an oxide, or may be combined with Al or Ta to form an oxide.

【0011】これらの金属化物よりなる干渉層は、緻密
で外部からの水分や酸素の浸入を防ぐことができ、ま
た、耐食性が高く後述の反射層との反応性も小さい。更
に、基板として樹脂基板を使用する場合、基板を構成す
る樹脂との密着性にも優れている。金属窒化物として
は、窒化シリコン、窒化アルミニウム等が挙げられる。
The interference layer made of these metal compounds is dense and can prevent invasion of moisture and oxygen from the outside, has high corrosion resistance, and has low reactivity with the reflection layer described later. Furthermore, when a resin substrate is used as the substrate, it has excellent adhesion to the resin that constitutes the substrate. Examples of the metal nitride include silicon nitride and aluminum nitride.

【0012】これらの金属窒化物のうち、特に緻密で外
部からの水分や酸素の浸入を防ぐ効果に優れることか
ら、窒化シリコンを用いるのが好ましい。このような金
属酸化物又は金属窒化物よりなる干渉層の膜厚は、その
屈折率により最適膜厚が異なるが、通常400〜150
0Å程度、特に500〜1000Å程度とするのが適当
である。
Among these metal nitrides, silicon nitride is preferably used because it is particularly dense and has an excellent effect of preventing intrusion of moisture and oxygen from the outside. The optimum thickness of the interference layer made of such a metal oxide or metal nitride varies depending on its refractive index, but is usually 400 to 150.
About 0Å, especially about 500 to 1000Å is suitable.

【0013】光磁気記録層の干渉層と反対の面には、干
渉層と同様の材質を持つ誘電体よりなる保護層、即ち誘
電体層を設けるのが望ましい。この誘電体層の膜厚は通
常の場合、500〜1500Å程度とするのが良い。反
射層を設ける構造の媒体では、記録層に接して、又は数
百Åの誘電体層を介して高反射率の金属(例えばAl,
Cu等)の単体又はその合金の層を反射層として設け
る。反射層の上に更に誘電体層をもうけることもでき
る。
On the surface of the magneto-optical recording layer opposite to the interference layer, it is desirable to provide a protective layer made of a dielectric material having the same material as that of the interference layer, that is, a dielectric layer. Normally, the thickness of this dielectric layer is preferably about 500 to 1500 Å. In a medium having a structure in which a reflective layer is provided, a metal having a high reflectance (for example, Al, etc.) is brought into contact with the recording layer or through a dielectric layer of several hundred liters.
A single layer of Cu or the like or a layer of its alloy is provided as the reflective layer. It is also possible to further provide a dielectric layer on the reflective layer.

【0014】なお、本発明において、基板上に干渉層、
記録層、誘電体層、反射層、誘電体層等の各層を形成す
る方法としては、スパッタリング等の物理蒸着法(PV
D)、プラズマCVDのような化学蒸着法(CVD)等
が適用される。また、イオンプレーティングを用いる方
法でも良い。PVD法にて干渉層、光磁気記録層、誘電
体層、反射層、誘電体層等を成膜形成するには、所定の
組成をもったターゲットを用いて電子ビーム蒸着又はス
パッタリングにより基板上に各層を堆積するのが通常の
方法である。
In the present invention, the interference layer on the substrate,
As a method for forming each layer such as a recording layer, a dielectric layer, a reflective layer, and a dielectric layer, a physical vapor deposition method such as sputtering (PV
D), a chemical vapor deposition method (CVD) such as plasma CVD, or the like is applied. Alternatively, a method using ion plating may be used. In order to form an interference layer, a magneto-optical recording layer, a dielectric layer, a reflection layer, a dielectric layer, etc. by PVD method, a target having a predetermined composition is used to perform electron beam evaporation or sputtering on a substrate. It is common practice to deposit each layer.

【0015】膜の堆積速度は速すぎると膜応力を増加さ
せ、遅すぎると生産性が低下するので、通常、0.1〜
100Å/sec程度の範囲で適宜決定される。以下、
干渉層、光磁気記録層、誘電体層及び反射層等を含めて
「記録層」と称する。以下本発明を詳細に説明する。
If the deposition rate of the film is too fast, the film stress will increase, and if it is too slow, the productivity will decrease.
It is appropriately determined within the range of about 100 Å / sec. Less than,
The interference layer, the magneto-optical recording layer, the dielectric layer, the reflective layer and the like are collectively referred to as a "recording layer". Hereinafter, the present invention will be described in detail.

【0016】図1は本発明の方法を説明するための説明
図である。図中1は光ディスク基板、2は導電層、3は
軸、4は硬化性樹脂、5はノズル、6は正電荷発生装
置、7はタンク、8はフィルターをそれぞれ示す。まず
光ディスク基板1として用いられるポリカーボネート樹
脂などからなる樹脂を射出成形法により厚さ1〜2mm
程度の円板状の光ディスク基板1を作成する。
FIG. 1 is an explanatory view for explaining the method of the present invention. In the figure, 1 is an optical disk substrate, 2 is a conductive layer, 3 is a shaft, 4 is a curable resin, 5 is a nozzle, 6 is a positive charge generator, 7 is a tank, and 8 is a filter. First, a resin such as a polycarbonate resin used as the optical disc substrate 1 is formed by injection molding to have a thickness of 1 to 2 mm.
A disk-shaped optical disk substrate 1 having a size of about 1 is prepared.

【0017】光ディスク基板1の表面に記録層等を形成
した後もしくは形成する前に、所定の部分に導電層2を
形成する。導電層2を形成する部分はカートリッジのリ
ムと接触する部分である。導電層を形成する手段として
は、ITO,Al等の膜を蒸着法やスパッタリング法、
などを用いて薄膜に形成すれば良い。他の方法としては
例えば、カーボン粒子や導電性フィラーを含有した硬化
性樹脂を塗布等により形成してもよい。次に、導電層部
分に滑り性を付加するため、滑り剤を含有させた硬化性
樹脂を吹きつけるが、滑り剤としては、流動パラフィ
ン、天然ワックス、マイクロワックス、ポリエチレンワ
ックス等の脂肪族炭化水素系、ステアリン酸、ラウリン
酸等の炭素数14〜32の高級脂肪酸系、セチルアルコ
ール、ステアリルアルコール等の炭素数14以上の脂肪
族アルコール系、ステアリン酸アミド、パルミチン酸ア
ミド、メチレンビスステアロアミド、エチレンビスステ
アロアミド、オレイン酸アミド、エルシン酸アミド等の
脂肪酸アミド系、ブチルステアレートなどの脂肪酸の低
級アルコールエステル、硬化ヒマシ油などの脂肪酸の多
価アルコールエステル及びエチレングリコールモノステ
アレートなどの脂肪酸のグリコールエステル等の脂肪酸
エステル系、ステアリン酸の金属塩などの炭素数12〜
30の脂肪酸から誘導される金属石けん系及びシリコー
ン系等があげられる。
After the recording layer or the like is formed on the surface of the optical disc substrate 1 or before the formation, the conductive layer 2 is formed on a predetermined portion. The portion forming the conductive layer 2 is the portion that contacts the rim of the cartridge. As a means for forming the conductive layer, a film of ITO, Al or the like is deposited or sputtered,
It may be formed into a thin film by using, for example. As another method, for example, a curable resin containing carbon particles or a conductive filler may be applied to form the resin. Next, in order to add slipperiness to the conductive layer portion, a curable resin containing a slipping agent is sprayed. Examples of the slipping agent include liquid hydrocarbons such as liquid paraffin, natural wax, microwax and polyethylene wax. System, higher fatty acids having 14 to 32 carbon atoms such as stearic acid and lauric acid, aliphatic alcohols having 14 or more carbon atoms such as cetyl alcohol and stearyl alcohol, stearic acid amide, palmitic acid amide, methylenebisstearamide, Fatty acid amides such as ethylene bis stearamide, oleic acid amide, and erucic acid amide; lower alcohol esters of fatty acids such as butyl stearate; polyhydric alcohol esters of fatty acids such as hydrogenated castor oil; and fatty acids such as ethylene glycol monostearate. Fatty acids such as glycol esters Le system, 12 carbon atoms, such as metal salts of stearic acid
Examples thereof include metal soaps and silicones derived from 30 fatty acids.

【0018】滑り剤の配合量は硬化性樹脂の硬化後の滑
性膜とカートリッジ内周リブとの動摩擦係数が1.0以
下となる量配合するのが望ましく、通常硬化性樹脂成分
100重量部当り(5〜100)重量部の範囲が適当で
ある。上記滑り剤を硬化性樹脂に配合するに際し、該樹
脂との相溶性を良くするために滑り剤を溶媒に溶解させ
てもよい。
The amount of the slip agent is preferably such that the coefficient of dynamic friction between the hardened resin and the inner peripheral rib of the cartridge is 1.0 or less, and usually 100 parts by weight of the curable resin component. A range of (5 to 100) parts by weight is suitable. When blending the above slip agent into the curable resin, the slip agent may be dissolved in a solvent in order to improve the compatibility with the resin.

【0019】硬化性樹脂としては、エネルギー線(例え
ば、紫外線)硬化型或いは熱硬化型の硬化性樹脂等が用
いられる。エネルギー線(例えば、紫外線(UV))硬
化型樹脂としてはアクリレート又はメタアクリレート基
を単一或いは複数有する化合物よりなるものが、好適に
用いられる。
As the curable resin, energy ray (for example, ultraviolet ray) curable or thermosetting curable resin or the like is used. As the energy ray (for example, ultraviolet (UV)) curable resin, a resin composed of a single or a plurality of acrylate or methacrylate groups is preferably used.

【0020】熱硬化性樹脂としてはシリコン系、エポキ
シ系、チタン系等が用いられる。このように滑り剤を含
有した硬化性樹脂4はタンク7からフィルター8等を
経、ノズル5から軸3を中心に回転している光ディスク
基板の表面に噴霧状にスプレイされる。硬化性樹脂はノ
ズルから出た直後に正電荷発生装置6により正電荷が加
えられる。
As the thermosetting resin, silicon type, epoxy type, titanium type and the like are used. In this way, the curable resin 4 containing the slip agent is sprayed from the tank 7 through the filter 8 and the like onto the surface of the optical disk substrate rotating from the nozzle 5 about the shaft 3 as a spray. Immediately after exiting from the nozzle, the curable resin is applied with a positive charge by the positive charge generator 6.

【0021】電荷をもったコート液の粒子は、導電層2
の部分をアースとし選択的に導電層2の部分に付着する
こととなる。付着し形成された膜は紫外線あるいは熱に
より硬化され滑性膜を有する光ディスクとなる。
The particles of the coating liquid having a charge are the conductive layer 2
Is used as ground and is selectively attached to the conductive layer 2. The film formed by adhesion is cured by ultraviolet rays or heat to form an optical disk having a slipping film.

【0022】[0022]

【発明の効果】本発明の光ディスクは生産性が良好で、
長期連続使用においても、光ディスクの内周部表面とカ
ートリッジケースの内周リム部とのこすれによるゴミの
発生を防ぐことができる。
The optical disk of the present invention has good productivity,
Even during long-term continuous use, it is possible to prevent the generation of dust due to the rubbing between the inner peripheral surface of the optical disc and the inner peripheral rim of the cartridge case.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の方法を説明する説明図。FIG. 1 is an explanatory diagram illustrating a method of the present invention.

【符号の説明】[Explanation of symbols]

1 光ディスク基板 2 導電層 3 軸 4 硬化性樹脂 6 正電荷発生装置 1 Optical Disc Substrate 2 Conductive Layer 3 Axis 4 Curable Resin 6 Positive Charge Generator

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 光ディスク基板のカートリッジケースの
リム部と接触する位置に導電層を形成し、次いで、滑り
剤を含有させた硬化性樹脂に正電荷を加えた状態でディ
スク表面に噴霧することにより導電層上に硬化性樹脂を
付着させ、その後硬化性樹脂を硬化することを特徴とす
る滑性膜つき光ディスクの製造方法。
1. A conductive layer is formed on the optical disk substrate at a position in contact with the rim portion of the cartridge case, and then a curable resin containing a slipping agent is sprayed onto the disk surface with a positive charge applied. A method for producing an optical disk with a slipping film, which comprises depositing a curable resin on a conductive layer and then curing the curable resin.
JP6172665A 1994-07-25 1994-07-25 Manufacture of optical disk with lubricant film Pending JPH0836791A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6172665A JPH0836791A (en) 1994-07-25 1994-07-25 Manufacture of optical disk with lubricant film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6172665A JPH0836791A (en) 1994-07-25 1994-07-25 Manufacture of optical disk with lubricant film

Publications (1)

Publication Number Publication Date
JPH0836791A true JPH0836791A (en) 1996-02-06

Family

ID=15946108

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6172665A Pending JPH0836791A (en) 1994-07-25 1994-07-25 Manufacture of optical disk with lubricant film

Country Status (1)

Country Link
JP (1) JPH0836791A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1152408A2 (en) * 2000-04-27 2001-11-07 Origin Electric Co. Ltd. Method and apparatus for bonding optical disc substrates together, and method for supplying liquid material
EP0999249A3 (en) * 1998-11-04 2003-02-26 Singulus Technologies AG Process for avoiding the inclusion of bubbles during the joining by adhesives of optical data carrier substrates

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0999249A3 (en) * 1998-11-04 2003-02-26 Singulus Technologies AG Process for avoiding the inclusion of bubbles during the joining by adhesives of optical data carrier substrates
EP1152408A2 (en) * 2000-04-27 2001-11-07 Origin Electric Co. Ltd. Method and apparatus for bonding optical disc substrates together, and method for supplying liquid material
EP1152408A3 (en) * 2000-04-27 2003-02-26 Origin Electric Co. Ltd. Method and apparatus for bonding optical disc substrates together, and method for supplying liquid material
US6685794B2 (en) 2000-04-27 2004-02-03 Origin Electric Co., Ltd. Method and apparatus for bonding optical disc substrates together, and method for supplying liquid material
EP1656999A1 (en) * 2000-04-27 2006-05-17 Origin Electric Co. Ltd. Method for supplying liquid material

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