JPH0790096A - Prepreg and laminate - Google Patents
Prepreg and laminateInfo
- Publication number
- JPH0790096A JPH0790096A JP23627093A JP23627093A JPH0790096A JP H0790096 A JPH0790096 A JP H0790096A JP 23627093 A JP23627093 A JP 23627093A JP 23627093 A JP23627093 A JP 23627093A JP H0790096 A JPH0790096 A JP H0790096A
- Authority
- JP
- Japan
- Prior art keywords
- prepreg
- laminate
- glass cloth
- laminated
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
- H05K1/0366—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement reinforced, e.g. by fibres, fabrics
Landscapes
- Reinforced Plastic Materials (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、電子機器等に使用され
るプリント配線板の材料であるプリプレグ、及び積層板
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a prepreg, which is a material for printed wiring boards used in electronic equipment and the like, and a laminated board.
【0002】[0002]
【従来の技術】従来、平織のガラスクロスを基材として
使用したプリプレグ及びこのプリプレグを用いて積層一
体化された積層板がプリント配線板の材料として広く用
いられている。近年、電子機器の軽薄短小化の要求に対
応するために、寸法安定性の良好なプリント配線板が求
められている。この要求に対応するため、プリント配線
板の構成や製造方法について各種の研究がなされてお
り、本発明者等も特願平5−206161号において、
プリント配線板の低熱膨張率化を達成する方法として、
同時に浮沈させるヤーンの本数を2〜5本とするななこ
織りで織られているガラスクロスを基材とし、樹脂含有
率が20〜40重量%であるプリプレグ及びこのプリプ
レグを用いて積層一体化された積層板を提案している。
そして、プリント配線板の平面方向の寸法安定性の改善
という観点から、さらに研究を進めた結果、本発明に到
ったものである。2. Description of the Related Art Conventionally, a prepreg using a plain weave glass cloth as a base material and a laminated board laminated and integrated using the prepreg have been widely used as a material for a printed wiring board. In recent years, a printed wiring board having good dimensional stability has been demanded in order to meet the demand for lighter, thinner, shorter, and smaller electronic devices. In order to meet this demand, various studies have been conducted on the structure and manufacturing method of a printed wiring board, and the inventors of the present invention have disclosed in Japanese Patent Application No. 5-206161.
As a method of achieving a low coefficient of thermal expansion of a printed wiring board,
At the same time, a glass cloth woven from a satin weave having 2 to 5 yarns to be floated and settled at the same time was used as a base material, and a prepreg having a resin content of 20 to 40% by weight and a prepreg which was laminated and integrated using the prepreg. Proposed a laminated board.
The present invention has been achieved as a result of further research from the viewpoint of improving the dimensional stability of the printed wiring board in the planar direction.
【0003】[0003]
【発明が解決しようとする課題】本発明はプリント配線
板の寸法安定性、特に平面方向の寸法安定性を改善する
ことを課題とするものであり、プリント配線板の寸法安
定性を改善することのできるプリプレグ及び積層板を提
供することを目的としている。SUMMARY OF THE INVENTION It is an object of the present invention to improve the dimensional stability of a printed wiring board, particularly the dimensional stability in the plane direction, and to improve the dimensional stability of the printed wiring board. It is an object of the present invention to provide a prepreg and a laminated plate that can be manufactured.
【0004】[0004]
【課題を解決するための手段】本発明は、同時に浮沈さ
せるヤーンの本数を2〜5本とするななこ織りで織ら
れ、通気度が1〜10ccであるガラスクロスを基材と
し、樹脂含有率が20〜40重量%であるプリプレグ及
びこのプリプレグを用いて積層一体化された積層板であ
る。また、前記プリプレグを用いて積層一体化された内
層回路を有する積層板である。DISCLOSURE OF THE INVENTION The present invention is based on a glass cloth having a breathability of 1 to 10 cc and woven with a satin weave having 2 to 5 yarns simultaneously floated and sinked, and having a resin content of Is 20 to 40% by weight, and a laminated plate integrally laminated using this prepreg. Further, it is a laminated board having an inner layer circuit which is laminated and integrated by using the prepreg.
【0005】以下、本発明をより詳細に説明する。従来
この用途に使用されている平織のガラスクロスは、図3
に示すように、たて糸(1)及びよこ糸(2)の各ヤー
ンが交互に浮沈して織られている。それに対し、本発明
で使用するななこ織りのガラスクロスは、図1に示して
いるたて糸(1)及びよこ糸(2)が共に2本同時に浮
沈して織られているものや、図2に示しているたて糸
(1)及びよこ糸(2)が共に3本同時に浮沈して織ら
れているもの等、たて糸(1)及びよこ糸(2)の複数
のヤーン〔たて糸とよこ糸の本数は一致していない場合
もある。〕が同時に浮沈して織られているクロスであ
る。このななこ織りのガラスクロスは平織のガラスクロ
スに比べ糸のうねり(屈曲)が小さいので、寸法安定性
の改善に有効である。なお、ここでいうヤーンはモノフ
ィラメントが一定本数束ねられたものを指し、束ねられ
方により単糸、双糸等の種類がある。The present invention will be described in more detail below. The plain weave glass cloth conventionally used for this purpose is shown in FIG.
As shown in FIG. 3, each yarn of the warp yarn (1) and the weft yarn (2) is alternately woven up and down. On the other hand, the glass cloth of the satin weave used in the present invention has two warp threads (1) and two weft threads (2) shown in FIG. A plurality of warp threads (1) and weft threads (2), such as those in which three warp threads (1) and weft threads (2) are floated up and down at the same time (when the numbers of warp threads and weft threads do not match) There is also. ] Is a cloth that is woven up and down at the same time. This nanako-woven glass cloth has less thread waviness (bending) than the plain-woven glass cloth, and is therefore effective in improving dimensional stability. The yarn here refers to a bundle of a fixed number of monofilaments, and there are various types such as single yarn and twin yarn depending on how they are bundled.
【0006】本発明では、ななこ織りは、同時に浮沈さ
せるヤーンの本数を2〜5本とするよう限定している。
この理由は、浮沈させるヤーンの本数が多いほど糸のう
ねり(屈曲)が小さくなるので寸法安定性の改善に有利
であるが、しかし、6本以上になるとガラスクロスの取
り扱い性が損なわれたり、樹脂を含浸させる際にヤーン
が重なるトラブルが生じ易くなる等の問題が生じるから
である。In the present invention, the satin weave limits the number of yarns to be floated and sunk at the same time to 2 to 5.
The reason is that the larger the number of yarns to be floated and settled, the smaller the yarn waviness (bending), which is advantageous in improving dimensional stability. However, when the number of yarns is 6 or more, the handling property of the glass cloth is impaired, This is because problems such as a problem that yarns tend to overlap with each other when impregnating a resin are likely to occur.
【0007】本発明ではプリプレグを構成するガラスク
ロスがななこ織りで織られ、かつ、通気度が1〜10c
c/cm2 /secであることが重要である。通気度が
1cc/cm2 /sec未満であるとガラスクロス中へ
の樹脂含浸が困難となり、プリプレグを成形して得られ
る積層板中に、樹脂によって充填されない空隙部分が生
じるという成形性の問題があり、一方10cc/cm2
/secを越えると、ガラスクロス中の空隙を充填する
ためには多量の樹脂を含浸させることが必要となり、樹
脂を多量に含浸させると得られる積層板の寸法安定性を
損なうという問題を生じる。この通気度をコントロール
する手段としては、織りの打ち込み密度(打ち込み本
数)を変える方法や開繊処理等のガラスクロスに対する
加工により行う方法がある。In the present invention, the glass cloth constituting the prepreg is woven with a satin weave and has an air permeability of 1 to 10c.
It is important that it is c / cm 2 / sec. If the air permeability is less than 1 cc / cm 2 / sec, it becomes difficult to impregnate the glass cloth with the resin, and there is a problem of moldability that voids that are not filled with the resin occur in the laminated plate obtained by molding the prepreg. Yes, while 10 cc / cm 2
If it exceeds / sec, it is necessary to impregnate a large amount of resin in order to fill the voids in the glass cloth, and impregnating a large amount of resin causes a problem of impairing the dimensional stability of the obtained laminate. As a means for controlling the air permeability, there are a method of changing the driving density (the number of driving) of the weave, and a method of processing the glass cloth such as opening treatment.
【0008】本発明において、ななこ織りされたガラス
クロス基材と組み合わせる樹脂の種類については特に限
定はなく、例えばエポキシ樹脂、ポリイミド樹脂等の熱
硬化性樹脂や弗素樹脂等の熱可塑性樹脂を使用すること
ができる。そして、本発明ではプリプレグ中の樹脂含有
率が20〜40重量%であることが重要である。何故な
らば、プリプレグ中の樹脂含有率が20重量%未満の場
合は成形した積層板中に樹脂で充填されていない空隙部
分が生じる問題が起こり、また、40重量%を越えると
本発明の目的である寸法安定性の改善が達成し難くなく
なるからである。In the present invention, the kind of resin to be combined with the satin-woven glass cloth base material is not particularly limited, and for example, thermosetting resin such as epoxy resin or polyimide resin or thermoplastic resin such as fluorine resin is used. be able to. In the present invention, it is important that the resin content of the prepreg is 20 to 40% by weight. The reason for this is that when the resin content in the prepreg is less than 20% by weight, voids that are not filled with resin occur in the molded laminate, and when it exceeds 40% by weight, the object of the present invention is This is because it is difficult to achieve the improvement in dimensional stability.
【0009】本発明における、プリプレグ及び積層板の
製造条件については特に限定はなく、使用する樹脂の種
類により決定すればよい。そして、プリプレグを積層一
体化して積層板とする際に、銅箔等の金属箔を同時に一
体化して金属箔張り積層板とすることも可能である。ま
た、この金属箔張り積層板を用いてエッチングにより回
路を有する内層材を作製し、この内層材とプリプレグ及
び銅箔等の金属箔を積層一体化して内層回路を有する積
層板を得ることができる。本発明では積層板又は内層回
路を有する積層板を製造する際に使用するプリプグは全
て請求項1記載のプリプレグのみを使用することは勿
論、従来知られている既存のプリプレグを併用するよう
にしてもよい。In the present invention, the manufacturing conditions of the prepreg and the laminated plate are not particularly limited and may be determined depending on the type of resin used. When the prepregs are laminated and integrated to form a laminated plate, it is possible to simultaneously integrate metal foils such as copper foil to form a metal foil-clad laminated plate. Further, an inner layer material having a circuit can be produced by etching using this metal foil-clad laminate, and the inner layer material and a metal foil such as prepreg and copper foil can be laminated and integrated to obtain a laminate having an inner layer circuit. . In the present invention, all the prepregs used for producing a laminated plate or a laminated plate having an inner layer circuit use only the prepreg according to claim 1, and of course, an existing prepreg known in the related art is used in combination. Good.
【0010】[0010]
【実施例】以下、本発明を実施例及び比較例により説明
する。勿論、この発明は下記の実施例に限らない。EXAMPLES The present invention will be described below with reference to Examples and Comparative Examples. Of course, the present invention is not limited to the following embodiments.
【0011】(実施例1〜6及び比較例1〜6)表1〜
2に示すガラスクロス及び樹脂を使用して含浸、乾燥を
行って、表1〜2に示す樹脂含有率のプリプレグを得
た。次いで各プリプレグを8枚重ね、その両側に厚みが
35μmの銅箔(古河サーキットフォイル社製)を配
し、加圧加熱して積層一体化し、各種の銅張積層板を得
た。このとき、樹脂がエポキシ樹脂のものは170℃,
30kg/cm2 ,60分間の加圧加熱とし、樹脂がポ
リイミド樹脂のものは200℃,40kg/cm2 ,9
0分間の加圧加熱とした。(Examples 1 to 6 and Comparative Examples 1 to 6) Tables 1 to 1
The glass cloth and resin shown in 2 were used for impregnation and drying to obtain prepregs having resin contents shown in Tables 1 and 2. Next, 8 sheets of each prepreg were stacked, and a copper foil (manufactured by Furukawa Circuit Foil Co., Ltd.) having a thickness of 35 μm was arranged on both sides of the prepreg, and they were laminated under pressure and heating to obtain various copper-clad laminates. At this time, if the resin is epoxy resin, 170 ℃,
Pressurization and heating at 30 kg / cm 2 , 60 minutes, and polyimide resin at 200 ° C., 40 kg / cm 2 , 9
It was pressurized and heated for 0 minutes.
【0012】得られた銅張積層板について、成形性及び
寸法安定性を評価しその結果を表1〜2に示す。また、
使用したガラスクロスの取り扱い性についても観察し、
その結果も表1〜2に示す。なお、成形性の評価は銅張
積層板の銅箔をエッチングにより除去した後、目視にて
樹脂の充填性を評価した。また、寸法安定性(平面方向
の寸法安定性)については、銅張積層板にあらかじめ複
数の基準点を設け、この基準点間の寸法の変化率を評価
した。すなわち初期値に対するエッチングによる銅箔の
除去及び170℃60分間の加熱処理の後の値の変化率
を寸法変化率とした。The resulting copper clad laminate was evaluated for formability and dimensional stability, and the results are shown in Tables 1-2. Also,
Observing the handleability of the glass cloth used,
The results are also shown in Tables 1-2. The moldability was evaluated by visually evaluating the resin filling property after removing the copper foil of the copper-clad laminate by etching. Regarding the dimensional stability (dimensional stability in the plane direction), a plurality of reference points were provided in advance on the copper clad laminate, and the rate of dimensional change between the reference points was evaluated. That is, the rate of change of the value after the removal of the copper foil by etching and the heat treatment at 170 ° C. for 60 minutes with respect to the initial value was defined as the rate of dimensional change.
【0013】[0013]
【表1】 [Table 1]
【0014】[0014]
【表2】 [Table 2]
【0015】(実施例7)実施例1で得られた銅張積層
板の両面に、写真法によるパターン形成とエッチングに
よる回路形成を行って、残銅率50%の回路を有する内
層材を得た。この内層材の両側に、実施例1で得られた
プリプレグ2枚を各々配し、更にその両外側に厚みが1
8μmの銅箔(古河サーキットフォイル社製)を配し、
170℃,30kg/cm2 ,60分間の加圧加熱をし
て積層一体化し、内層回路を有する積層板を得た。積層
一体化する前に前記の内層材にあらかじめ複数の基準点
を設け、この基準点間の寸法が170℃,30kg/c
m2 ,60分間の加圧加熱でどう変化するかを測定し
た。得られた二次成形後の寸法変化率は−0.03%で
あった。(Embodiment 7) Pattern formation by a photo method and circuit formation by etching are performed on both surfaces of the copper clad laminate obtained in Example 1 to obtain an inner layer material having a circuit with a residual copper rate of 50%. It was Two pieces of the prepreg obtained in Example 1 are arranged on both sides of the inner layer material, and a thickness of 1 is provided on both outer sides of the prepreg.
8μm copper foil (Furukawa Circuit Foil)
It was pressure-heated at 170 ° C. and 30 kg / cm 2 for 60 minutes to be laminated and integrated to obtain a laminated plate having an inner layer circuit. Before the lamination and integration, a plurality of reference points are provided in advance on the inner layer material, and the dimension between the reference points is 170 ° C, 30 kg / c.
It was determined how changes in m 2, 60 minutes of pressure and heat. The obtained dimensional change rate after secondary molding was -0.03%.
【0016】(比較例7)比較例1で得られた銅張積層
板の両面に、写真法によるパターン形成とエッチングに
よる回路形成を行って、残銅率50%の回路を有する内
層材を得た。この内層材の両側に、比較例1で得られた
プリプレグ2枚を各々配し、更にその両外側に厚みが1
8μmの銅箔(古河サーキットフォイル社製)を配し、
170℃,30kg/cm2 ,60分間の加圧加熱をし
て積層一体化し、内層回路を有する積層板を得た。積層
一体化する前に前記の内層材にあらかじめ複数の基準点
を設け、この基準点間の寸法が170℃,30kg/c
m2 ,60分間の加圧加熱でどう変化するかを測定し
た。得られた二次成形後の寸法変化率は−0.09%で
あった。(Comparative Example 7) Pattern formation by a photo method and circuit formation by etching were performed on both surfaces of the copper clad laminate obtained in Comparative Example 1 to obtain an inner layer material having a circuit with a residual copper rate of 50%. It was Two pieces of the prepreg obtained in Comparative Example 1 were arranged on both sides of this inner layer material, and a thickness of 1 was applied to both outer sides of the prepreg.
8μm copper foil (Furukawa Circuit Foil)
It was pressure-heated at 170 ° C. and 30 kg / cm 2 for 60 minutes to be laminated and integrated to obtain a laminated plate having an inner layer circuit. Before the lamination and integration, a plurality of reference points are provided in advance on the inner layer material, and the dimension between the reference points is 170 ° C, 30 kg / c.
It was determined how changes in m 2, 60 minutes of pressure and heat. The obtained dimensional change rate after secondary molding was -0.09%.
【0017】[0017]
【発明の効果】本発明に係るプリプレグは、同時に浮沈
させるヤーンの本数を2〜5本とするななこ織りで織ら
れ、通気度が1〜10ccであるガラスクロスを基材と
し、樹脂含有率が20〜40重量%であるという構成と
なっているので、本発明のプリプレグによれば成形性を
損なわずに、寸法安定性が良好な積層板が得られる。従
って、本発明のプリプレグ及び積層板を使用することで
寸法安定性が良好なプリント配線板を得ることができ
る。EFFECT OF THE INVENTION The prepreg according to the present invention is woven with a satin weave in which the number of yarns to be floated and sunk at the same time is from 2 to 5, and is based on a glass cloth having an air permeability of 1 to 10 cc, and has a resin content of Since the prepreg of the present invention has a composition of 20 to 40% by weight, a laminate having good dimensional stability can be obtained without impairing moldability. Therefore, a printed wiring board having good dimensional stability can be obtained by using the prepreg and the laminated board of the present invention.
【0018】また、本発明のプリプレグを使用した内層
回路を有する積層板は二時成型後の寸法変化率が良好な
ものとなる。従って、寸法安定性が良好な多層プリント
配線板を得ることができる。Further, the laminate having an inner layer circuit using the prepreg of the present invention has a good dimensional change rate after two-time molding. Therefore, a multilayer printed wiring board having good dimensional stability can be obtained.
【図1】本発明の一実施例のプリプレグ作製に使用した
ななこ織りしたガラスクロスの平面図である。FIG. 1 is a plan view of a satin-woven glass cloth used for producing a prepreg according to an embodiment of the present invention.
【図2】本発明の他の実施例のプリプレグ作製に使用し
たななこ織りしたガラスクロスの平面図である。FIG. 2 is a plan view of a satin-woven glass cloth used for producing a prepreg according to another embodiment of the present invention.
【図3】平織のガラスクロスの例を示す平面図である。FIG. 3 is a plan view showing an example of a plain weave glass cloth.
1 たて糸 2 よこ糸 1 warp thread 2 weft thread
Claims (3)
本とするななこ織りで織られ、通気度が1〜10ccで
あるガラスクロスを基材とし、樹脂含有率が20〜40
重量%であるプリプレグ。1. The number of yarns to be floated and settled simultaneously is 2 to 5.
Woven with a nanako woven fabric, with a glass cloth having an air permeability of 1 to 10 cc as a base material, and a resin content of 20 to 40
Prepreg that is wt%.
一体化された積層板。2. A laminated plate laminated and integrated using the prepreg according to claim 1.
一体化された内層回路を有する積層板。3. A laminate having an inner layer circuit laminated and integrated using the prepreg according to claim 1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5236270A JP2570250B2 (en) | 1993-09-22 | 1993-09-22 | Prepreg and laminate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5236270A JP2570250B2 (en) | 1993-09-22 | 1993-09-22 | Prepreg and laminate |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0790096A true JPH0790096A (en) | 1995-04-04 |
JP2570250B2 JP2570250B2 (en) | 1997-01-08 |
Family
ID=16998298
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5236270A Expired - Lifetime JP2570250B2 (en) | 1993-09-22 | 1993-09-22 | Prepreg and laminate |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2570250B2 (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61194252A (en) * | 1985-02-19 | 1986-08-28 | 日東紡績株式会社 | Inorganic fiber fabric and its production |
JPS63318196A (en) * | 1987-06-22 | 1988-12-27 | Asahi Shiyueebell Kk | Glass fiber fabric reinforced printed wiring board |
JPH038832A (en) * | 1989-06-06 | 1991-01-16 | Asahi Shiyueebell Kk | Inorganic yarn woven fabric for laminate |
JPH05283828A (en) * | 1992-03-31 | 1993-10-29 | Asahi Shiyueebell Kk | Laminate for printed-circuit board |
-
1993
- 1993-09-22 JP JP5236270A patent/JP2570250B2/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61194252A (en) * | 1985-02-19 | 1986-08-28 | 日東紡績株式会社 | Inorganic fiber fabric and its production |
JPS63318196A (en) * | 1987-06-22 | 1988-12-27 | Asahi Shiyueebell Kk | Glass fiber fabric reinforced printed wiring board |
JPH038832A (en) * | 1989-06-06 | 1991-01-16 | Asahi Shiyueebell Kk | Inorganic yarn woven fabric for laminate |
JPH05283828A (en) * | 1992-03-31 | 1993-10-29 | Asahi Shiyueebell Kk | Laminate for printed-circuit board |
Also Published As
Publication number | Publication date |
---|---|
JP2570250B2 (en) | 1997-01-08 |
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