JPH0780494A - Controlling method for operation of activated sludge circulation modification method - Google Patents
Controlling method for operation of activated sludge circulation modification methodInfo
- Publication number
- JPH0780494A JPH0780494A JP3513594A JP3513594A JPH0780494A JP H0780494 A JPH0780494 A JP H0780494A JP 3513594 A JP3513594 A JP 3513594A JP 3513594 A JP3513594 A JP 3513594A JP H0780494 A JPH0780494 A JP H0780494A
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- JP
- Japan
- Prior art keywords
- aerobic
- tank
- activated sludge
- air
- tanks
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は嫌気−好気活性汚泥循環
変法を用いて廃水中の有機物及び窒素を高効率に除去す
る運転制御方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an operation control method for highly efficiently removing organic matter and nitrogen in wastewater by using a modified anaerobic-aerobic activated sludge circulation method.
【0002】[0002]
【従来の技術】従来から下水等の廃水中の有機物を効率
的に除去するとともに、閉鎖性水域の富栄養化の原因物
質と考えられている窒素及びリンを除去する方法が種々
提案されている。この富栄養化とは、水域中のN,P等
の栄養塩類の濃度が増大し、これらを栄養素とする生物
活動が活発となって生態系が変化することを指してい
る。特に湖沼等に生活排水とか工場廃水が大量に流入す
ると、上記の富栄養化が急速に進行することが知られて
いる。2. Description of the Related Art Various methods have conventionally been proposed for efficiently removing organic matter in wastewater such as sewage and removing nitrogen and phosphorus which are considered to be the causative agents of eutrophication in closed water areas. . This eutrophication refers to an increase in the concentration of nutrient salts such as N, P in the water area, which activates biological activities using these nutrients as nutrients and changes the ecosystem. In particular, it is known that the above-mentioned eutrophication rapidly progresses when a large amount of domestic wastewater or industrial wastewater flows into lakes and the like.
【0003】近時、窒素の除去率を高めることが要求さ
れており、窒素に関する規制も厳しくなることが予想さ
れるので、これを除去することができる高度処理プロセ
スを採用する施設が増加するものと考えられる。Recently, it has been required to increase the removal rate of nitrogen, and it is expected that the regulations on nitrogen will be stricter. Therefore, the number of facilities adopting an advanced treatment process capable of removing this will increase. it is conceivable that.
【0004】廃水中の窒素とかリンを除去する手段とし
て、物理化学的な方法及び生物学的方法が提案されてい
るが、物理化学的方法はコストが嵩む関係から普及して
いない現状にある。例えば物理化学的方法として実用化
されているリン除去方法に凝集沈澱及び晶析手段がある
が、この手段はコストや維持管理面で難点がある。Although physicochemical methods and biological methods have been proposed as means for removing nitrogen and phosphorus in wastewater, physicochemical methods are not widely used because of the high cost. For example, a phosphorus removal method which has been put into practical use as a physicochemical method includes a coagulation precipitation method and a crystallization method, but this method has a drawback in terms of cost and maintenance.
【0005】一方、生物学的に窒素とリンを同時に除去
する方法として、従来の活性汚泥法の変法として嫌気−
好気活性汚泥法が注目されている。(例えば水質汚濁研
究、第12巻,第7号 441−448,1989を参
照。) この嫌気−好気活性汚泥法とは、例えば図4に示したよ
うに、生物反応槽を溶存酸素(以下DOと略称)の存在
しない嫌気槽1a,1bとDOの存在する複数段の好気
槽2a,2b,2cとに仕切り、この嫌気槽1a,1b
により、流入する原水3を無酸素状態下で撹拌機構10
による撹拌を行って活性汚泥中の脱窒菌による脱窒を行
い、次に好気槽2a,2b,2cの内方に配置した散気
管4にブロワ5から空気を供給することにより、エアレ
ーションによる酸素の存在下で活性汚泥による有機物の
酸化分解と硝化菌によるアンモニアの硝化を行う。そし
て最下流側の好気槽2cの硝化液を硝化液循環ポンプ6
を用いて嫌気槽1aに送り込むことにより、嫌気槽1
a,1bの脱窒効果が促進される。On the other hand, as a biological biological method for simultaneously removing nitrogen and phosphorus, an anaerobic method is a modification of the conventional activated sludge method.
The aerobic activated sludge method is drawing attention. (See, for example, Water Pollution Research, Volume 12, No. 7, 441-448, 1989.) This anaerobic-aerobic activated sludge method is, for example, as shown in FIG. The anaerobic tanks 1a and 1b in which DO is abbreviated) are divided into a plurality of aerobic tanks 2a, 2b and 2c in which DO is present.
The raw water 3 flowing in is agitated by the stirring mechanism 10 under anoxic condition.
Oxygen by aeration by supplying air from the blower 5 to the diffuser pipe 4 arranged inside the aerobic tanks 2a, 2b, 2c by performing denitrification by denitrifying bacteria in the activated sludge. In the presence of, oxidative decomposition of organic matter by activated sludge and nitrification of ammonia by nitrifying bacteria are performed. Then, the nitrification solution in the aerobic tank 2c on the most downstream side is transferred to the nitrification solution circulation pump 6
By feeding into the anaerobic tank 1a using
The denitrification effect of a and 1b is promoted.
【0006】上記硝化菌はDO濃度が低くなると活性が
低下するので、最下流側の好気槽2cのDOを測定して
DO制御装置12によりブロワ5の駆動を制御している
のが通例である。Since the activity of the above nitrifying bacteria decreases as the DO concentration decreases, it is customary to measure the DO of the aerobic tank 2c on the most downstream side and control the drive of the blower 5 by the DO control device 12. is there.
【0007】前記脱窒菌とは、嫌気条件下で硝酸呼吸に
よりN02−N及びN03−NをN2やNO2に還元する細
菌を指している。又、原水中のリンは嫌気槽1a,1b
内で放出され、好気槽2a,2b,2c内で活性汚泥に
取り込まれて除去される。7は最終沈澱池であり、この
最終沈澱池7の上澄液は、処理水11として図外の消毒
槽等を経由してから放流され、該最終沈澱池7内に沈降
した汚泥の一部は汚泥返送ポンプ8により嫌気槽1aに
返送され、他の汚泥は余剰汚泥引抜ポンプ9から図外の
余剰汚泥処理装置に送り込まれて処理される。The denitrifying bacterium is a bacterium that reduces N0 2 -N and N0 3 -N to N 2 and NO 2 by respiration of nitric acid under anaerobic conditions. Also, phosphorus in raw water is anaerobic tanks 1a and 1b.
It is released inside and is taken in and removed by the activated sludge in the aerobic tanks 2a, 2b and 2c. Reference numeral 7 denotes a final settling basin, and the supernatant of the final settling basin 7 is discharged as treated water 11 after passing through a disinfection tank or the like not shown in the figure, and a part of sludge settled in the final settling basin 7. Is returned to the anaerobic tank 1a by the sludge return pump 8, and other sludge is sent from the excess sludge drawing pump 9 to an excess sludge treatment device (not shown) for treatment.
【0008】かかる嫌気−好気活性汚泥処理方法を用い
ることにより、通常の標準活性汚泥法で達成される有機
物除去効果と同程度の効果が得られる上、窒素とリンに
関しては活性汚泥法よりも高い除去率が達成される。By using such an anaerobic-aerobic activated sludge treatment method, the same effect as the organic substance removal effect achieved by the normal standard activated sludge method can be obtained, and nitrogen and phosphorus are more effective than the activated sludge method. A high removal rate is achieved.
【0009】[0009]
【発明が解決しようとする課題】しかしながらこのよう
な従来の嫌気−好気活性汚泥処理法の場合、効率的な運
転制御方法の確立が困難であり、特に好気槽における硝
化効率と、それに伴う嫌気槽における脱窒効果をともに
充分に高めることが困難であるという課題があった。However, in the case of such a conventional anaerobic-aerobic activated sludge treatment method, it is difficult to establish an efficient operation control method, and in particular, the nitrification efficiency in the aerobic tank and the accompanying There is a problem that it is difficult to sufficiently enhance the denitrification effect in the anaerobic tank.
【0010】即ち、前記嫌気−好気活性汚泥法における
動作態様は、嫌気槽1a,1bにおける脱窒反応と、好
気槽2a,2b,2cにおける硝化反応とに大別するこ
とが出来るが、反応の律速となっているのは後者,即ち
硝化反応である。特に嫌気−好気活性汚泥処理法によっ
て効率的に窒素を除去するためには、嫌気槽における脱
窒と好気槽における硝化を最適な運転条件に保持するこ
とが要求される上、窒素除去工程は硝化工程に影響され
る度合が高いため、良好な窒素除去を行うためには硝化
工程が良好に行われていることが必要である。That is, the operation mode in the anaerobic-aerobic activated sludge method can be roughly classified into a denitrification reaction in the anaerobic tanks 1a and 1b and a nitrification reaction in the aerobic tanks 2a, 2b and 2c. The latter, that is, the nitrification reaction, is the rate-determining reaction. In particular, in order to remove nitrogen efficiently by the anaerobic-aerobic activated sludge treatment method, it is required to maintain denitrification in the anaerobic tank and nitrification in the aerobic tank under the optimum operating conditions, and the nitrogen removing step. Is highly affected by the nitrification process, so that the nitrification process must be performed well in order to perform good nitrogen removal.
【0011】この硝化反応は、前記したように硝化菌に
よって引き起こされるが、この硝化菌の活性は、pH,
水温等の微妙な変化により容易に影響を受けることが知
られている。又、エアレーションの時間を十分にとるた
めに、標準活性汚泥法の場合よりも生物反応槽の容積を
2〜3倍にすることが必要であり、都市部等の用地確保
が困難な条件下での採用が難しいという問題がある。This nitrification reaction is caused by the nitrifying bacteria as described above. The activity of the nitrifying bacteria is
It is known that it is easily affected by subtle changes such as water temperature. In addition, in order to obtain sufficient aeration time, it is necessary to increase the volume of the biological reaction tank by a factor of 2 to 3 compared with the standard activated sludge method, and under conditions where it is difficult to secure land for urban areas. There is a problem that it is difficult to adopt.
【0012】生物反応槽の容積を小さくするためには硝
化反応速度を高める手段を施すことが肝要である。その
ための簡易な方法として、余剰汚泥の引抜量を小さくし
て反応槽内の汚泥濃度を高めるSRT制御が考えられ
る。しかしこの方法は最終沈澱池での固液分離効率を低
下させて流出水中の汚泥浮遊物濃度を高めてしまう危険
性がある。In order to reduce the volume of the biological reaction tank, it is essential to provide a means for increasing the nitrification reaction rate. As a simple method for that purpose, SRT control that increases the sludge concentration in the reaction tank by reducing the amount of excess sludge drawn out can be considered. However, this method has a risk of reducing the solid-liquid separation efficiency in the final settling tank and increasing the concentration of sludge suspended matter in the effluent.
【0013】硝化が良好に進行している場合には、脱窒
反応の良否が窒素除去率を左右するので、高い窒素除去
率を維持するには硝化反応と脱窒反応のバランスを良好
に保持することが要求される。When the nitrification progresses satisfactorily, the quality of the denitrification reaction influences the nitrogen removal rate. Therefore, in order to maintain a high nitrogen removal rate, a good balance between the nitrification reaction and the denitrification reaction is maintained. Required to do so.
【0014】前記したように硝化菌はDO濃度が低くな
ると活性が低下することが知られているが、好気槽2
a,2b,2c内でのDO濃度は、流入負荷変動とか水
量に起因して常に変化しており、且つエアレーションの
条件によってDOの低濃度領域が生じる場合がある。更
に原水3の流れ方向によってもDOの濃度分布が異なっ
ており、上流側、即ち嫌気槽1bに近い好気槽2aでは
DO濃度が低く、逆に下流側の好気槽2cではDO濃度
が高くなる傾向がある。従って複数段の好気槽2a,2
b,2cの前段部分では硝化菌の活性が低くなってしま
い、好気槽全体として硝化反応が不安定になってしまう
ことになり易い。As described above, it is known that the activity of nitrifying bacteria decreases as the DO concentration decreases.
The DO concentration in a, 2b, and 2c is constantly changing due to inflow load fluctuations and the amount of water, and a low concentration region of DO may occur depending on aeration conditions. Furthermore, the DO concentration distribution also differs depending on the flow direction of the raw water 3, and the DO concentration is low in the upstream side, that is, the aerobic tank 2a close to the anaerobic tank 1b, and conversely, the DO concentration is high in the downstream aerobic tank 2c. Tends to become. Therefore, a plurality of aerobic tanks 2a, 2
The activity of nitrifying bacteria becomes low in the front part of b and 2c, and the nitrification reaction is likely to become unstable in the aerobic tank as a whole.
【0015】前記図4で説明したように、従来は最下流
側の好気槽2cのDO濃度を測定してDO制御装置12
によりブロワ5の駆動を制御していたのを改良して、D
O濃度の測定位置を上流側に移行してブロワ5の駆動を
制御する手段も考慮されるが、このような制御を行った
場合には好気槽の下流側でのエアレーションが逆に過剰
になってしまい、しかもブロワ5を稼働するための電気
消費量が増加してしまうという問題点が生じる。As described above with reference to FIG. 4, the DO controller 12 is conventionally used to measure the DO concentration in the aerobic tank 2c on the most downstream side.
By improving the control of the drive of the blower 5 by
A means for controlling the drive of the blower 5 by moving the O concentration measuring position to the upstream side is also considered, but when such control is performed, aeration on the downstream side of the aerobic tank is excessive. However, there is a problem in that the electric power consumption for operating the blower 5 increases.
【0016】そこで本発明はこのような嫌気−好気活性
汚泥処理が有している課題を解消して、複数段の好気槽
におけるDO濃度に起因する硝化反応の低下を防止し、
ひいては嫌気槽における脱窒反応を高めることができる
運転活性汚泥循環変法の運転制御方法を提供することを
目的とするものである。Therefore, the present invention solves the problems of such anaerobic-aerobic activated sludge treatment and prevents the reduction of nitrification reaction due to the DO concentration in a plurality of aerobic tanks.
Furthermore, it aims at providing the operation control method of the operation activated sludge circulation modification which can raise the denitrification reaction in an anaerobic tank.
【0017】[0017]
【課題を解決するための手段】本発明は上記の目的を達
成するために、原水を嫌気槽で脱窒細菌により脱窒を行
う工程と、複数段の好気槽で硝化細菌により硝化を行う
工程と、沈澱槽で固液分離して上澄液を処理水として放
流する工程とを含む活性汚泥循環変法処理において、先
ず請求項1により、上記複数段の好気槽内に配置された
各散気管に対する空気の送風量を、上流側から下流側に
向けて順次減少させたテーパードエアレーションを実施
する運転制御方法にしてある。In order to achieve the above object, the present invention performs a step of denitrifying raw water with denitrifying bacteria in an anaerobic tank, and nitrifying with nitrifying bacteria in a plurality of aerobic tanks. In a modified activated sludge circulation process comprising a step and a step of solid-liquid separation in a settling tank and discharging a supernatant as treated water, first, according to claim 1, the sludge is placed in the aerobic tanks of a plurality of stages. The operation control method is to perform tapered aeration in which the amount of air blown to each air diffuser is sequentially reduced from the upstream side to the downstream side.
【0018】又、請求項2により、上記複数段の好気槽
の中で、最上流側の好気槽の溶存酸素濃度を測定して、
この測定値が所定値以上であるように各散気管に対する
空気の送風量をコントロールする運転制御方法にしてあ
る。更に請求項3により、上流側の好気槽内に配置され
た散気管に対する空気の送風機構と、下流側の好気槽内
に配置された散気管に対する空気の送風機構とを別々に
構成する一方、最上流側の好気槽に第1の溶存酸素濃度
計を設置するとともに最下流側の好気槽に第2の溶存酸
素濃度計を設置して、第1の溶存酸素濃度計の計測値に
基づいて前記上流側の送風機構に対する送風量を制御
し、且つ第2の溶存酸素濃度計の計測値に基づいて前記
下流側の送風機構に対する送風量を制御する運転制御方
法を提供する。Further, according to claim 2, among the aerobic tanks of the plurality of stages, the dissolved oxygen concentration of the aerobic tank on the most upstream side is measured,
The operation control method is to control the amount of air blown to each air diffuser so that the measured value is equal to or greater than a predetermined value. Further, according to claim 3, an air blowing mechanism for the air diffuser arranged in the upstream aerobic tank and an air blowing mechanism for the air diffuser arranged in the downstream aerobic tank are separately configured. On the other hand, the first dissolved oxygen concentration meter is installed in the aerobic tank on the most upstream side, and the second dissolved oxygen concentration meter is installed in the aerobic tank on the most downstream side to measure the first dissolved oxygen concentration meter. There is provided an operation control method for controlling an air flow rate to the upstream air flow mechanism based on a value and controlling an air flow rate to the downstream air flow mechanism based on a measurement value of a second dissolved oxygen concentration meter.
【0019】又、上記各好気槽の溶存酸素濃度が、2.
0(mg/l)以下にならないように空気の送風量を制
御する。The dissolved oxygen concentration of each aerobic tank is 2.
The air flow rate is controlled so that it does not become 0 (mg / l) or less.
【0020】[0020]
【作用】かかる活性汚泥循環変法の運転制御方法によれ
ば、原水が嫌気槽もしくは嫌気条件下で脱窒され、好気
槽もしくは好気条件下での曝気と硝化細菌の作用に基づ
く硝化が行われる一方、複数段の好気槽に対する送風量
を上流側から下流側に向けて順次減少させたテーパード
エアレーションを実施したことにより、上流側好気槽の
DO濃度不足に起因する硝化菌の活性低下を防止して硝
化反応を良好に維持することができる。[Operation] According to the operation control method of the modified activated sludge circulation method, the raw water is denitrified in the anaerobic tank or the anaerobic condition, and the aeration in the aerobic tank or the aerobic condition and the nitrification based on the action of the nitrifying bacteria are performed. On the other hand, the activity of nitrifying bacteria due to lack of DO concentration in the upstream aerobic tank was achieved by performing tapered aeration in which the air flow rate to the multiple aerobic tanks was gradually decreased from the upstream side to the downstream side. The decrease can be prevented and the nitrification reaction can be favorably maintained.
【0021】又、複数段の好気槽の中で、最上流側の好
気槽のDO濃度を測定して、この測定値が所定値以上で
あるように各散気管に対する空気の送風量をコントロー
ルすることにより、流入負荷変動とか水量に起因して流
れ方向に生じるDO濃度の分布変化に対処することが可
能となり、更に好気槽の上流側と下流側の送風機構を別
々に構成して最上流側と最下流側に設置したDO計の計
測値に基づいて両送風機構に対する送風量を制御したこ
とにより、上流側好気槽でのDO低下に基づく硝化反応
の阻害現象が防止されるとともに下流側好気槽に対して
送風量が過剰になることがなくなり、好気槽全域に亙っ
て安定した硝化反応が行われ、硝化菌の活性の低下に基
づく硝化反応の不安定化が防止され、ひいては嫌気槽に
おける窒素除去率が向上するという作用が得られる。Further, in a plurality of aerobic tanks, the DO concentration in the aerobic tank on the most upstream side is measured, and the amount of air blown to each air diffuser is adjusted so that the measured value is a predetermined value or more. By controlling it, it becomes possible to cope with the fluctuation of the inflow load and the change in the distribution of the DO concentration caused in the flow direction due to the amount of water, and further, the ventilation mechanism on the upstream side and the downstream side of the aerobic tank are separately configured. By controlling the amount of air blown to both air blowing mechanisms based on the measured values of the DO meters installed on the most upstream side and the most downstream side, the inhibition phenomenon of the nitrification reaction due to the DO decrease in the upstream aerobic tank is prevented. At the same time, the amount of air blown to the downstream aerobic tank does not become excessive, a stable nitrification reaction is performed throughout the aerobic tank, and the nitrification reaction becomes unstable due to the decrease in the activity of nitrifying bacteria. Prevented, and eventually nitrogen removal rate in anaerobic tank Effect of improving is obtained.
【0022】[0022]
【実施例】以下、図面に基づいて本発明にかかる活性汚
泥循環変法の運転制御方法の一実施例を、前記従来の構
成部分と同一の構成部分に同一の符号を付して詳述す
る。図1は本発明の第1実施例を示す概要図であり、図
中の1a,1bは廃水の脱窒を行うための嫌気槽、2
a,2b,2c,2dは硝化を行うための複数段の好気
槽であり、この嫌気槽1a,1bと好気槽2a,2b,
2c,2dとは同一の生物反応槽を仕切板13,13で
区切って分割構成されている。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the operation control method of the modified activated sludge circulation method according to the present invention will be described in detail below with reference to the drawings, in which the same components as those of the conventional components are designated by the same reference numerals. . FIG. 1 is a schematic view showing a first embodiment of the present invention, in which 1a and 1b are anaerobic tanks for denitrifying waste water, and 2
a, 2b, 2c and 2d are aerobic tanks of a plurality of stages for performing nitrification. The anaerobic tanks 1a and 1b and the aerobic tanks 2a and 2b,
The same biological reaction tanks as 2c and 2d are divided by partition plates 13 and 13 to be divided.
【0023】14は最初沈澱池、15は原水貯留槽であ
り、両槽には水位計16が配置されている。最初沈澱池
14には原水汲上げポンプP1が配備され、原水貯留槽
15には原水撹拌ポンプP2と原水供給ポンプP3とが配
備されている。Reference numeral 14 is a first sedimentation basin, 15 is a raw water storage tank, and water level gauges 16 are arranged in both tanks. Initially, the settling tank 14 is provided with a raw water pumping pump P 1 , and the raw water storage tank 15 is provided with a raw water stirring pump P 2 and a raw water supply pump P 3 .
【0024】上記嫌気槽1a,1bには、各々汚泥撹拌
ポンプP4,P4が配備されている。又、好気槽2a,2
b,2c,2d内にはエア吹出機構としての散気管4,
4,4,4が配置され、外部に上記散気管4,4,4,
4にエアを供給するためのブロワ5とバルブV1,V2,
V3,V4が配備されている。P5は硝化液循環ポンプで
ある。Sludge agitation pumps P 4 and P 4 are provided in the anaerobic tanks 1a and 1b, respectively. Also, the aerobic tanks 2a, 2
b, 2c, and 2d have air diffusers 4 as an air blowing mechanism.
4, 4, 4 are arranged, and the air diffusers 4, 4, 4, are provided outside.
Blower 5 and the valve V 1, V 2 for supplying air to 4,
V 3 and V 4 are deployed. P 5 is a nitrification solution circulation pump.
【0025】7は最終沈澱池、17は処理水貯留槽、1
8は余剰汚泥貯留槽であり、最終沈澱池7には撹拌機構
19が配備され、処理水貯留槽17には水位計20が配
置されている。P6は余剰汚泥引抜ポンプ、P7は汚泥返
送ポンプ、P8は処理水排出ポンプであり、余剰汚泥引
抜ポンプP6にはタイマー21が付設されていて、所定
時間毎に余剰汚泥の引抜動作を行うように設定されてい
る。Reference numeral 7 is a final settling tank, 17 is a treated water storage tank, 1
Reference numeral 8 denotes a surplus sludge storage tank, a stirring mechanism 19 is provided in the final settling tank 7, and a water level gauge 20 is arranged in the treated water storage tank 17. P 6 is a surplus sludge drawing pump, P 7 is a sludge returning pump, P 8 is a treated water discharge pump, and a timer 21 is attached to the surplus sludge drawing pump P 6 to draw out excess sludge at every predetermined time. Is set to do.
【0026】更に嫌気槽1bには酸化還元電位計22が
配置されており、好気槽2dには同様な酸化還元電位計
23とpH計25、DO計26及びアルカリ貯留槽24
とが配置されている。P9はアルカリ貯留槽24内のア
ルカリを好気槽2dに注入するための薬注ポンプであ
る。Further, a redox potential meter 22 is arranged in the anaerobic tank 1b, and a similar redox potential meter 23, a pH meter 25, a DO meter 26 and an alkaline storage tank 24 are arranged in the aerobic tank 2d.
And are arranged. P 9 is a chemical injection pump for injecting the alkali in the alkali storage tank 24 into the aerobic tank 2d.
【0027】かかる装置の基本的作用は以下の通りであ
る。先ず最初沈澱池14の原水が原水汲上げポンプP1
によって汲み上げられて原水貯留槽15に貯留される。
原水貯留槽15内の水位は水位計16によって監視され
て、原水汲上げポンプP1の駆動が制御されている。The basic operation of such a device is as follows. First of all, the raw water in the settling basin 14 is the raw water pump P 1
Is pumped up and stored in the raw water storage tank 15.
The water level in the raw water storage tank 15 is monitored by a water level gauge 16 to control the drive of the raw water pumping pump P 1 .
【0028】原水撹拌ポンプP2によって撹拌された原
水は、原水供給ポンプP3の駆動に伴って嫌気槽1aか
ら嫌気槽1bへ流入し、汚泥撹拌ポンプP4,P4の撹拌
作用と脱窒細菌の作用に基づいて、NO3−N、NO2−
NイオンのN2への還元、即ち脱窒が行われる。The raw water stirred by the raw water stirring pump P 2 flows from the anaerobic tank 1a into the anaerobic tank 1b as the raw water supply pump P 3 is driven, and the sludge stirring pumps P 4 and P 4 are stirred and denitrified. based on the action of bacteria, NO 3 -N, NO 2 -
Reduction of N ions to N 2 , that is, denitrification, is performed.
【0029】次に原水は好気槽2a,2b,2c,2d
に順次流入して、ブロワ5の駆動に伴ってバルブV1,
V2,V3,V4を介して散気管4,4,4,4に供給さ
れる空気のエアレーションによる曝気が行われ、硝化細
菌の作用に基づいてアンモニア性窒素NH4−NのNO2
−N又はNO3−Nへの酸化、即ち硝化が行われる。Next, the raw water is aerobic tanks 2a, 2b, 2c, 2d.
To the valve V 1 as the blower 5 is driven.
Aeration is performed by aeration of the air supplied to the air diffusers 4 , 4 , 4 , 4 via V 2 , V 3 , and V 4, and NO 2 of ammoniacal nitrogen NH 4 —N is generated based on the action of nitrifying bacteria.
Oxidation to —N or NO 3 —N, ie nitrification, takes place.
【0030】上記の作用時に、嫌気槽1bと好気槽2d
内の酸化還元電位が酸化還元電位計22,23によって
測定され、好気槽2d内のpHとDO濃度がpH計25
及びDO計26によって測定される。酸化還元電位は、
液の酸化力或は還元力の強さを知るための指標となるも
のであり、測定された酸化還元電位とpH値とから必要
に応じてアルカリ貯留槽に貯留されたアルカリが薬注ポ
ンプP9を介して好気槽2d内に注入される。During the above operation, the anaerobic tank 1b and the aerobic tank 2d
The redox potential inside is measured by the redox potential meters 22 and 23, and the pH and DO concentration inside the aerobic tank 2d are measured by the pH meter 25.
And the DO meter 26. The redox potential is
It serves as an index for knowing the strength of the oxidizing power or reducing power of the liquid, and the alkali stored in the alkali storage tank is used as the chemical injection pump P if necessary from the measured redox potential and pH value. It is injected via 9 into the aerobic tank 2d.
【0031】更に好気槽2dの硝化液が硝化液循環ポン
プP5を用いて嫌気槽1aに送り込まれることにより、
該嫌気槽1a,1bの脱窒効果が促進される。特に廃水
中のリンは嫌気槽1a,1b内で放出され、好気槽2
a,2b,2c,2d内で活性汚泥に取り込まれて除去
される。Further, the nitrifying solution in the aerobic tank 2d is sent to the anaerobic tank 1a by using the nitrifying solution circulating pump P 5 .
The denitrification effect of the anaerobic tanks 1a and 1b is promoted. Particularly, phosphorus in the wastewater is released in the anaerobic tanks 1a and 1b, and
It is taken into and removed by the activated sludge in a, 2b, 2c and 2d.
【0032】好気槽2d内の余剰汚泥は、余剰汚泥引抜
ポンプP6により引き抜かれて余剰汚泥貯留槽18に一
旦貯留され、最終沈澱池7内に沈降した汚泥の一部は汚
泥返送ポンプP7により嫌気槽1aに返送される。更に
最終沈澱池7の上澄液は、処理水貯留槽17に貯留され
てから水位計20に監視された処理水排出ポンプP8の
駆動に伴って処理水11として図外の消毒槽等を経由し
てから放流される。The surplus sludge in the aerobic tank 2d is drawn by the surplus sludge drawing pump P 6 and temporarily stored in the surplus sludge storage tank 18, and a part of the sludge settled in the final settling tank 7 is a sludge return pump P. It is returned to the anaerobic tank 1a by 7 . Further, the supernatant of the final settling basin 7 is stored in the treated water storage tank 17 and then the treated water discharge pump P 8 monitored by the water level gauge 20 is driven as treated water 11 into a disinfecting tank (not shown) or the like. It is released after passing through.
【0033】本第1実施例では、上記の装置を用いて以
下に記すような2系統の運転制御実験を行った。In the first embodiment, the two-system operation control experiment as described below was conducted using the above apparatus.
【0034】(1)4槽の好気槽2a,2b,2c,2
d内に配置された各散気管4に対するブロワ5からの送
風量を全て0.5(l/min)としてエアレーション
を実施した。(1) Four aerobic tanks 2a, 2b, 2c, 2
Aeration was performed by setting the air flow rate from the blower 5 to each air diffusing tube 4 arranged in d to 0.5 (l / min).
【0035】(2)バルブV1,V2,V3,V4の開度を
調整して、上記各散気管4に対するブロワ5からの送風
量を、上流側から下流側に向けて「0.7」「0.6」
「0.4」「0.3」(l/min)と順次減少させた
テーパードエアレーションを実施した。(2) By adjusting the openings of the valves V 1 , V 2 , V 3 , and V 4 , the blown air amount from the blower 5 to each of the diffuser pipes 4 is set to "0" from the upstream side to the downstream side. .7 "and" 0.6 "
Tapered aeration was carried out in order of "0.4" and "0.3" (l / min).
【0036】尚、上記(1)系統(2)系統とも全送風
量は2(l/min)で同一とした。そして各好気槽2
a,2b,2c,2dのDO濃度を別々に測定した。The total air flow rate was 2 (l / min) in both the systems (1) and (2). And each aerobic tank 2
The DO concentrations of a, 2b, 2c and 2d were measured separately.
【0037】その結果、(1)系統の場合には、DO濃
度は上流側から「0.5」「3.0」「3.9」「4.
8」(mg/l)であり、(2)系統の場合には、DO
濃度は「3.2」「4.9」「4.7」「4.4」(m
g/l)であった。As a result, in the case of the system (1), the DO concentration is “0.5”, “3.0”, “3.9”, “4.
8 "(mg / l), and in the case of (2) system, DO
The density is "3.2""4.9""4.7""4.4" (m
g / l).
【0038】一般に好気槽における硝化反応を良好に維
持するためには、上記DO濃度を2(mg/l)を下限
として送風量を決定するのが良いとされている(例えば
参考文献として活性汚泥循環変法の技術資料P35〜P
36を参照)。Generally, in order to maintain a good nitrification reaction in an aerobic tank, it is said that it is better to determine the air flow rate with the DO concentration being 2 (mg / l) as a lower limit (for example, as a reference, the activity is Technical data of modified sludge circulation method P35-P
36).
【0039】そして上記の実験結果から(1)系統の運
転制御方法では、好気槽2aのDO濃度が0.5(mg
/l)であって、2(mg/l)以下であるため、硝化
反応が良好に維持できなくなる可能性がある。これに対
して(2)系統の運転制御方法ではDO濃度がすべて2
(mg/l)以上であり、硝化反応が良好に進行してい
る。From the above experimental results, in the (1) system operation control method, the DO concentration in the aerobic tank 2a is 0.5 (mg
/ L) and 2 (mg / l) or less, the nitrification reaction may not be maintained well. On the other hand, in the operation control method of (2) system, the DO concentration is all 2
(Mg / l) or more, and the nitrification reaction is proceeding well.
【0040】上記の結果から、全送風量が同一である場
合には、(2)系統の運転制御方法、即ち、好気槽2
a,2b,2c,2dの上流側の送風量を多くして下流
側の送風量を少なくする運転制御方法が有効であること
が判明した。このようなテーパードエアレーションを実
施することにより、上流側好気槽2aのDO濃度不足に
起因する硝化菌の活性低下が防止され、且つ好気槽全体
の硝化反応を良好に維持することができる。From the above results, when the total air flow rate is the same, (2) the operation control method of the system, that is, the aerobic tank 2
It has been found that the operation control method of increasing the air flow rate on the upstream side of a, 2b, 2c, 2d and decreasing the air flow rate on the downstream side is effective. By performing such tapered aeration, it is possible to prevent the activity of nitrifying bacteria from being lowered due to insufficient DO concentration in the upstream aerobic tank 2a, and to maintain the nitrification reaction of the entire aerobic tank in a good condition.
【0041】図2は本発明の第2実施例を示す概要図で
あり、前記図4に示す従来例と同一の構成部分に同一の
符号を付して表示してある。この第2実施例の場合に
は、図4の例とは異なって最上流側の好気槽2aのDO
を測定し、DO制御装置12によりブロワ5の駆動を制
御しており、好気槽2aのDO濃度が2.0(mg/
l)以下にならないようにブロワ5を駆動することを特
徴としている。FIG. 2 is a schematic diagram showing a second embodiment of the present invention, in which the same components as those of the conventional example shown in FIG. 4 are indicated by the same reference numerals. In the case of the second embodiment, the DO of the aerobic tank 2a on the most upstream side is different from the example of FIG.
The DO controller 12 controls the drive of the blower 5, and the DO concentration of the aerobic tank 2a is 2.0 (mg / mg).
l) It is characterized in that the blower 5 is driven so as not to fall below.
【0042】このような方法によってもDO濃度の減少
に起因する硝化菌の活性低下を防止して、各好気槽2
a,2b,2cにおける硝化反応を良好に維持すること
ができる。即ち、流入負荷変動とか水量に起因して流れ
方向に生じるDO濃度の分布変化に対処することが可能
となり、特に好気槽2a,2b,2cの前段部分での硝
化菌の活性の低下に基づく硝化反応の不安定化を防止す
ることができる。Even with such a method, it is possible to prevent the activity of nitrifying bacteria from decreasing due to the decrease in the DO concentration, and to prevent each aerobic tank 2
The nitrification reaction in a, 2b, and 2c can be favorably maintained. That is, it becomes possible to deal with the change in the distribution of the DO concentration that occurs in the flow direction due to the fluctuation of the inflow load or the amount of water, and especially based on the decrease in the activity of the nitrifying bacteria in the front part of the aerobic tanks 2a, 2b, 2c. Instability of the nitrification reaction can be prevented.
【0043】図3は本発明の第3実施例を示す概要図で
あり、この例では4槽に分割形成された好気槽2a,2
b,2c,2d中の上流側の好気槽2a,2b内に配置
された散気管4,4とブロワ5との間に開閉制御弁28
を装備する一方、下流側の好気槽2c,2d内に配置さ
れた散気管4,4とブロワ5との間に開閉制御弁29を
装備してある。FIG. 3 is a schematic view showing a third embodiment of the present invention. In this example, aerobic tanks 2a, 2 divided into four tanks are formed.
An open / close control valve 28 is provided between the blower 5 and the air diffusers 4 and 4 arranged in the aerobic tanks 2a and 2b on the upstream side in b, 2c and 2d.
On the other hand, an open / close control valve 29 is provided between the blower 5 and the air diffusers 4 and 4 arranged in the downstream aerobic tanks 2c and 2d.
【0044】更に最上流側の好気槽2aに第1の溶存酸
素濃度計(DO計)30を設置して、このDO計30の
計測値に基づいて上記開閉制御弁28の開度を決定する
DO制御を実施するとともに、最下流側の好気槽2d
に第2の溶存酸素濃度計(DO計)31を設置し、この
DO計31の計測値に基づいて開閉制御弁29の開度を
決定するDO制御を実施することが特徴となってい
る。Further, a first dissolved oxygen concentration meter (DO meter) 30 is installed in the aerobic tank 2a on the most upstream side, and the opening degree of the opening / closing control valve 28 is determined based on the measured value of the DO meter 30. DO control is performed and the aerobic tank 2d on the most downstream side
A second dissolved oxygen concentration meter (DO meter) 31 is installed in the above, and the DO control for determining the opening degree of the opening / closing control valve 29 based on the measurement value of the DO meter 31 is featured.
【0045】上記の構成を要約すると、上流側の好気槽
2a,2b内に配置された散気管4,4に対する空気の
送風機構と、下流側の好気槽2c,2d内に配置された
散気管4,4に対する空気の送風機構とを別々に構成
し、上記第1のDO計30の計測値に基づいて上流側好
気槽2a,2bに対する送風量を制御し、且つ第2のD
O計31の計測値に基づいて下流側好気槽2c,2dに
対する送風量を制御することが特徴となっている。To summarize the above configuration, an air blowing mechanism for the air diffusers 4 and 4 arranged in the aerobic tanks 2a and 2b on the upstream side and the aerobic tanks 2c and 2d on the downstream side are arranged. An air blowing mechanism for the air diffusers 4 and 4 is separately configured, the air blowing amount to the upstream aerobic tanks 2a and 2b is controlled based on the measurement value of the first DO meter 30, and the second D
The feature is that the amount of air blown to the downstream aerobic tanks 2c and 2d is controlled based on the measured value of the O meter 31.
【0046】かかる第3実施例によれば、上流側の好気
槽2a,2b内に配置された散気管4,4に対するブロ
ワ5からの送風量はDO制御によって制御される一
方、下流側の好気槽2c,2d内に配置された散気管
4,4に対するブロワ5からの送風量はDO制御によ
って制御される。従って原水3の負荷変動とか水温変化
に対して上流側好気槽2a,2b内でのDO低下に基づ
く硝化反応の阻害現象を防止することができるととも
に、下流側好気槽2c,2dに対して送風量が過剰にな
ることを未然に防止することができる。従って好気槽2
a,2b,2c,2dの全域に亙って安定した硝化反応
が行われ、硝化効率を高めることができる。According to the third embodiment, the amount of air blown from the blower 5 to the air diffusers 4 and 4 arranged in the aerobic tanks 2a and 2b on the upstream side is controlled by the DO control, while that on the downstream side is controlled. The amount of air blown from the blower 5 to the air diffusers 4 and 4 arranged in the aerobic tanks 2c and 2d is controlled by DO control. Therefore, it is possible to prevent the inhibition phenomenon of the nitrification reaction due to the DO decrease in the upstream side aerobic tanks 2a and 2b against the load fluctuation of the raw water 3 and the water temperature change, and to the downstream side aerobic tanks 2c and 2d. As a result, it is possible to prevent the amount of air blown from becoming excessive. Therefore aerobic tank 2
A stable nitrification reaction is performed over the entire area of a, 2b, 2c, and 2d, and the nitrification efficiency can be increased.
【0047】[0047]
【発明の効果】以上詳細に説明したように、本発明にか
かる活性汚泥循環変法の運転制御方法によれば、原水が
嫌気槽で脱窒され、好気槽での曝気と硝化細菌の作用に
基づく硝化が行われる一方、複数段の好気槽に対する送
風量を上流側から下流側に向けて順次減少させたテーパ
ードエアレーションを実施したことにより、好気槽の上
流側におけるDO濃度不足に起因する硝化菌の活性低下
を防止して硝化反応を良好に維持することができる。As described above in detail, according to the operation control method of the modified activated sludge circulation method according to the present invention, the raw water is denitrified in the anaerobic tank, and the aeration and the action of nitrifying bacteria in the aerobic tank are performed. While nitrification based on the above is performed, tapered air aeration is performed to reduce the air flow rate to multiple aerobic tanks from the upstream side to the downstream side. It is possible to prevent the activity of nitrifying bacteria from decreasing and to maintain the nitrification reaction favorably.
【0048】更に複数段の好気槽の中で、最上流側の好
気槽の溶存酸素濃度を測定して、この測定値が所定値以
上であるように各散気管に対する空気の送風量をコント
ロールすることにより、流入負荷変動とか水量に起因し
て流れ方向に生じるDO濃度の分布変化に対処すること
が可能となり、好気槽全体として硝化反応の不安定化を
防止して該好気槽での硝化反応が促進されるという効果
が得られる。Further, the dissolved oxygen concentration in the aerobic tank on the most upstream side is measured in the aerobic tanks of a plurality of stages, and the amount of air blown to each diffuser pipe is adjusted so that the measured value is equal to or more than a predetermined value. By controlling it, it becomes possible to cope with the fluctuation of the inflow load or the distribution change of the DO concentration caused in the flow direction due to the amount of water, thereby preventing the nitrification reaction from becoming unstable in the aerobic tank as a whole. The effect of accelerating the nitrification reaction is obtained.
【0049】更に好気槽の上流側と下流側の送風機構を
別々に構成して最上流側と最下流側に設置したDO計の
計測値に基づいて両送風機構に対する送風量を制御した
ことにより、DO低下に基づく上流側好気槽での硝化反
応の阻害現象がなく、しかも下流側好気槽への送風量が
過剰になることが防止されて好気槽全域に亙って硝化反
応を安定化することができる。Further, the blower mechanisms on the upstream side and the downstream side of the aerobic tank are separately configured, and the blower amounts for both blower mechanisms are controlled based on the measured values of the DO meters installed on the uppermost stream side and the lowermost stream side. As a result, there is no obstruction phenomenon of the nitrification reaction in the upstream aerobic tank due to the decrease in DO, and moreover, the amount of air blown to the downstream aerobic tank is prevented, and the nitrification reaction is prevented throughout the aerobic tank. Can be stabilized.
【0050】特に嫌気−好気活性汚泥処理法によって効
率的に窒素を除去するためには、嫌気槽における脱窒と
好気槽における硝化を最適な運転条件に保持することが
要求される上、窒素除去工程は硝化工程に影響される度
合が高いため、高い窒素除去率を維持するには硝化反応
と脱窒反応のバランスを良好に保持することが要求され
るものであるが、本発明では好気槽のDO制御を実施し
たことにより、律速となっている硝化反応が安定にして
且つ促進され、これに伴って嫌気槽における窒素除去率
を向上させることができる活性汚泥循環変法の運転制御
方法を提供するものである。Particularly, in order to remove nitrogen efficiently by the anaerobic-aerobic activated sludge treatment method, it is required to maintain denitrification in the anaerobic tank and nitrification in the aerobic tank under optimum operating conditions. Since the nitrogen removal step is highly influenced by the nitrification step, it is required to maintain a good balance between the nitrification reaction and the denitrification reaction in order to maintain a high nitrogen removal rate. The DO control of the aerobic tank stabilizes and accelerates the rate-limiting nitrification reaction, and the nitrogen removal rate in the anaerobic tank can be improved accordingly. A control method is provided.
【図1】本発明にかかる活性汚泥循環変法の運転制御方
法の第1実施例を示す概要図。FIG. 1 is a schematic diagram showing a first embodiment of an operation control method of an activated sludge circulation modification according to the present invention.
【図2】本発明の第2実施例を示す概要図。FIG. 2 is a schematic diagram showing a second embodiment of the present invention.
【図3】本発明の第3実施例を示す概要図。FIG. 3 is a schematic diagram showing a third embodiment of the present invention.
【図4】従来の嫌気−好気活性汚泥処理の一例を示す概
要図。FIG. 4 is a schematic diagram showing an example of conventional anaerobic-aerobic activated sludge treatment.
1a,1b…嫌気槽 2a,2b,2c,2d…好気槽 4…散気管 5…ブロワ 13…仕切板 14…最初沈澱池 15…原水貯留槽 16,20…水位計 17…処理水貯留槽 18…余剰汚泥貯留槽 22,23…酸化還元電位計 24…アリカリ貯留槽 25…pH計 26…DO計 28,29…開閉制御弁 30…第1の溶存酸素濃度計 31…第2の溶存酸素濃度計 1a, 1b ... Anaerobic tank 2a, 2b, 2c, 2d ... Aerobic tank 4 ... Diffuser pipe 5 ... Blower 13 ... Partition plate 14 ... First settling tank 15 ... Raw water storage tank 16, 20 ... Water level gauge 17 ... Treated water storage tank 18 ... Excess sludge storage tank 22, 23 ... Redox potential meter 24 ... Alikari storage tank 25 ... pH meter 26 ... DO meter 28, 29 ... Open / close control valve 30 ... First dissolved oxygen concentration meter 31 ... Second dissolved oxygen Densitometer
Claims (4)
う工程と、複数段の好気槽で硝化細菌により硝化を行う
工程と、沈澱槽で固液分離して上澄液を処理水として放
流する工程とを含む活性汚泥循環変法処理において、 上記複数段の好気槽内に配置された各散気管に対する空
気の送風量を、上流側から下流側に向けて順次減少させ
たテーパードエアレーションを実施することを特徴とす
る活性汚泥循環変法の運転制御方法。1. A step of denitrifying raw water with denitrifying bacteria in an anaerobic tank, a step of nitrifying with nitrifying bacteria in a plurality of aerobic tanks, and solid-liquid separation in a precipitation tank to treat a supernatant. In the activated sludge circulation modification method including the step of discharging as water, the air blowing amount to each diffuser pipe arranged in the aerobic tank of the above-mentioned multiple stages was gradually reduced from the upstream side to the downstream side. A method for controlling operation of a modified activated sludge circulation method, characterized by performing tapered aeration.
う工程と、複数段の好気槽で硝化細菌により硝化を行う
工程と、沈澱槽で固液分離して上澄液を処理水として放
流する工程とを含む活性汚泥循環変法処理において、 上記複数段の好気槽の中で、最上流側の好気槽の溶存酸
素濃度を測定して、この測定値が所定値以上であるよう
に各散気管に対する空気の送風量をコントロールするこ
とを特徴とする活性汚泥循環変法の運転制御方法。2. A step of denitrifying raw water with denitrifying bacteria in an anaerobic tank, a step of nitrifying with nitrifying bacteria in a plurality of aerobic tanks, and solid-liquid separation in a precipitation tank to treat a supernatant. In the activated sludge circulation modified process including the step of discharging as water, in the aerobic tanks of the above-mentioned multiple stages, the dissolved oxygen concentration of the aerobic tank on the most upstream side is measured, and the measured value is a predetermined value or more. The method for controlling the operation of the modified activated sludge circulation method is characterized by controlling the amount of air blown to each air diffuser.
う工程と、複数段の好気槽で硝化細菌により硝化を行う
工程と、沈澱槽で固液分離して上澄液を処理水として放
流する工程とを含む活性汚泥循環変法処理において、 上流側の好気槽内に配置された散気管に対する空気の送
風機構と、下流側の好気槽内に配置された散気管に対す
る空気の送風機構とを別々に構成する一方、最上流側の
好気槽に第1の溶存酸素濃度計を設置するとともに最下
流側の好気槽に第2の溶存酸素濃度計を設置して、第1
の溶存酸素濃度計の計測値に基づいて前記上流側の送風
機構に対する送風量を制御し、且つ第2の溶存酸素濃度
計の計測値に基づいて前記下流側の送風機構に対する送
風量を制御することを特徴とする活性汚泥循環変法の運
転制御方法。3. A step of denitrifying raw water with denitrifying bacteria in an anaerobic tank, a step of nitrifying with nitrifying bacteria in a plurality of aerobic tanks, and solid-liquid separation in a precipitation tank to treat a supernatant. In the modified activated sludge circulation process including the step of discharging as water, the air blowing mechanism for the air diffuser pipe arranged in the upstream aerobic tank and the air diffuser pipe arranged in the downstream aerobic tank While the air blowing mechanism is configured separately, the first dissolved oxygen concentration meter is installed in the aerobic tank on the most upstream side and the second dissolved oxygen concentration meter is installed in the aerobic tank on the most downstream side. , First
Controlling the air flow rate to the upstream air blowing mechanism based on the measured value of the dissolved oxygen concentration meter, and controlling the air flow rate to the downstream air blowing mechanism based on the measurement value of the second dissolved oxygen concentration meter. A method for controlling operation of a modified activated sludge circulation method characterized by the above.
(mg/l)以下にならないように空気の送風量を制御
することを特徴とする請求項1,2,3記載の活性汚泥
循環変法の運転制御方法。4. The dissolved oxygen concentration of each aerobic tank is 2.0.
The operation control method according to the modified activated sludge circulation method according to claim 1, 2, or 3, wherein the amount of air blown is controlled so as not to be less than (mg / l).
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JP03513594A JP3379199B2 (en) | 1993-07-22 | 1994-03-07 | Operation control method of activated sludge circulation method |
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JP5-180988 | 1993-07-22 | ||
JP18098893 | 1993-07-22 | ||
JP03513594A JP3379199B2 (en) | 1993-07-22 | 1994-03-07 | Operation control method of activated sludge circulation method |
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JPH0780494A true JPH0780494A (en) | 1995-03-28 |
JP3379199B2 JP3379199B2 (en) | 2003-02-17 |
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---|---|---|---|---|
KR20000066472A (en) * | 1999-04-16 | 2000-11-15 | 유호원 | Denitrification Processing System and the Method for the Wastewater |
KR100293244B1 (en) * | 1998-05-12 | 2001-10-25 | 김동우 | Device for separation of solids, liquid and gases from sewage and wastewater |
JP2007229599A (en) * | 2006-02-28 | 2007-09-13 | Kansai Pgs Kk | Sewage treating apparatus |
JP2008012425A (en) * | 2006-07-05 | 2008-01-24 | Nippon Steel Corp | Method and apparatus for removing phosphorus and nitrogen from sewage |
JP2010253428A (en) * | 2009-04-28 | 2010-11-11 | Asahi Kasei Chemicals Corp | Wastewater treatment apparatus and wastewater treatment method |
JP2011104585A (en) * | 2009-10-20 | 2011-06-02 | Metawater Co Ltd | Wastewater treatment method and wastewater treatment apparatus |
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-
1994
- 1994-03-07 JP JP03513594A patent/JP3379199B2/en not_active Ceased
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100293244B1 (en) * | 1998-05-12 | 2001-10-25 | 김동우 | Device for separation of solids, liquid and gases from sewage and wastewater |
KR20000066472A (en) * | 1999-04-16 | 2000-11-15 | 유호원 | Denitrification Processing System and the Method for the Wastewater |
JP2007229599A (en) * | 2006-02-28 | 2007-09-13 | Kansai Pgs Kk | Sewage treating apparatus |
JP4671888B2 (en) * | 2006-02-28 | 2011-04-20 | 関西ピー・ジー・エス株式会社 | Sewage treatment equipment |
JP2008012425A (en) * | 2006-07-05 | 2008-01-24 | Nippon Steel Corp | Method and apparatus for removing phosphorus and nitrogen from sewage |
JP2010253428A (en) * | 2009-04-28 | 2010-11-11 | Asahi Kasei Chemicals Corp | Wastewater treatment apparatus and wastewater treatment method |
JP2011104585A (en) * | 2009-10-20 | 2011-06-02 | Metawater Co Ltd | Wastewater treatment method and wastewater treatment apparatus |
JP2015027659A (en) * | 2013-03-08 | 2015-02-12 | メタウォーター株式会社 | Device and method for processing drain water |
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