JPH0769705A - Production of building material - Google Patents

Production of building material

Info

Publication number
JPH0769705A
JPH0769705A JP21969193A JP21969193A JPH0769705A JP H0769705 A JPH0769705 A JP H0769705A JP 21969193 A JP21969193 A JP 21969193A JP 21969193 A JP21969193 A JP 21969193A JP H0769705 A JPH0769705 A JP H0769705A
Authority
JP
Japan
Prior art keywords
straw
sewage sludge
building material
inorganic mineral
mineral fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP21969193A
Other languages
Japanese (ja)
Inventor
Yukito Muraguchi
幸人 村口
Hideji Kawai
秀治 川合
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Inax Corp
Original Assignee
Inax Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inax Corp filed Critical Inax Corp
Priority to JP21969193A priority Critical patent/JPH0769705A/en
Publication of JPH0769705A publication Critical patent/JPH0769705A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PURPOSE:To inexpensively produce a building material having high strength by using sewage sludge burned ash. CONSTITUTION:Sewage sludge burned ash, lime, straw and/or inorganic mineral fibers are mixed, formed and treated in an autoclave. By this treatment, SiO2, CaO and lime (CaO, Ca(OH)2) react to form calcium silicate hydrate and are hardened. The hardening reaction is accelerated by the autoclave treatment and the reaction is smoothly carried out. A part of SiO2 component adhered to the straw or a part of SiO2 component in the inorganic mineral fibers react with Ca(OH)2 to accelerate hardening. As the burning is not carried out, less energy consumption is required compared with materials usually obtained by carrying out burning. Owing to strength increasing effect by fibers of straw and inorganic mineral fibers, the obtained building material has very high strength. Effective use of straw together with sewage sludge burned ash can be attained.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は建材の製造方法に係り、
特に、下水汚泥焼却灰を原料として建材を製造する方法
に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a building material manufacturing method,
In particular, it relates to a method for producing a building material using sewage sludge incineration ash as a raw material.

【0002】[0002]

【従来の技術】近年、下水処理場から発生する下水汚泥
は増加傾向にあり、今後の下水道普及率の向上や下水処
理技術の高度化を考慮すると、下水汚泥発生量は増々増
加するものと予測される。
2. Description of the Related Art In recent years, the amount of sewage sludge generated from sewage treatment plants has been increasing, and it is predicted that the amount of sewage sludge will increase more and more considering the improvement of the sewerage diffusion rate and the advancement of sewage treatment technology. To be done.

【0003】従来、下水汚泥の処分方法としては、埋立
が最も多いが、今後の下水汚泥発生量の増加の面から、
有効利用を図ることが強く望まれており、その利用方法
の開発が様々な分野で進められている。
Conventionally, landfilling has been the most popular disposal method of sewage sludge, but from the viewpoint of increasing the amount of sewage sludge generated in the future,
There is a strong demand for effective utilization, and the development of the utilization method is being advanced in various fields.

【0004】この下水汚泥の有効利用の実用化の面で
は、建設資材としての利用が注目を集めており、例えば
下水汚泥焼却灰を含む成形原料を成形、焼成して建材を
製造する方法がある。
In terms of practical use of the effective use of the sewage sludge, its use as a construction material has been attracting attention. For example, there is a method of forming a building material containing sewage sludge incineration ash and firing the building material. .

【0005】[0005]

【発明が解決しようとする課題】しかしながら、従来の
下水汚泥焼却灰を用いた建材の製造方法では、焼成によ
るエネルギー消費が大きいという欠点がある。
However, the conventional method for manufacturing a building material using sewage sludge incineration ash has a drawback that energy consumption due to firing is large.

【0006】本発明は上記従来の問題点を解決し、下水
汚泥焼却灰を使用して高強度建材を低消費エネルギーに
て製造する方法を提供することを目的とする。
It is an object of the present invention to solve the above conventional problems and to provide a method for producing a high-strength building material with low energy consumption by using sewage sludge incineration ash.

【0007】[0007]

【課題を解決するための手段】本発明の建材の製造方法
は、下水汚泥焼却灰と、石灰と、藁及び/又は無機鉱物
繊維とを混合した後、成形し、次いでオートクレーブ処
理することを特徴とする。
The method for producing a building material according to the present invention is characterized in that sewage sludge incineration ash, lime, straw and / or inorganic mineral fiber are mixed, molded, and then autoclaved. And

【0008】以下に本発明を詳細に説明する。The present invention will be described in detail below.

【0009】本発明の方法においては、まず、下水汚泥
焼却灰と、石灰と、藁及び/又は無機鉱物繊維とを混合
して成形原料を製造する。
In the method of the present invention, first, sewage sludge incineration ash, lime, and straw and / or inorganic mineral fibers are mixed to produce a forming raw material.

【0010】この場合、各材料の混合割合は、次のよう
な範囲とするのが好ましい。
In this case, the mixing ratio of each material is preferably in the following range.

【0011】下水汚泥焼却灰:100重量部 石灰:20〜100重量部 藁及び/又は無機鉱物繊維:5〜20重量部 なお、石灰としては生石灰,消石灰等を用いることがで
きる。また、無機鉱物繊維としては、ワラストナイト,
蛇紋岩等を用いることができる。なお、藁は長さ10〜
40mm程度に切断して混合するのが好ましい。また、
無機鉱物繊維についても必要に応じて適宜切断する。
Sewage sludge incineration ash: 100 parts by weight Lime: 20 to 100 parts by weight Straw and / or inorganic mineral fibers: 5 to 20 parts by weight As lime, quick lime, slaked lime and the like can be used. As the inorganic mineral fiber, wollastonite,
Serpentine and the like can be used. The length of straw is 10
It is preferable to cut into about 40 mm and mix. Also,
Inorganic mineral fibers are also cut as needed.

【0012】下水汚泥焼却灰と、石灰と、藁及び/又は
無機鉱物繊維とを混合して得られた成形原料は、成形
し、次いでオートクレーブ処理する。
A molding raw material obtained by mixing sewage sludge incinerated ash, lime, and straw and / or inorganic mineral fibers is molded and then autoclaved.

【0013】ここで成形は、一軸加圧成形,振動プレス
成形により行なうことができ、例えば一軸加圧成形法の
場合、成形条件は面圧100〜300kgf/cm2
度で行なうのが好ましい。
The molding can be carried out by uniaxial pressure molding or vibration press molding. For example, in the case of the uniaxial pressure molding method, the molding condition is preferably a surface pressure of 100 to 300 kgf / cm 2 .

【0014】また、成形後のオートクレーブ処理条件と
しては、次のような条件を採用するのが好ましい。
The following conditions are preferably adopted as the autoclave treatment conditions after molding.

【0015】オートクレーブ処理条件 温度:100〜200℃ 処理時間:3〜7hr これにより、床材、壁材等として有用な高強度建材を製
造することができる。
Autoclave treatment conditions Temperature: 100 to 200 ° C. Treatment time: 3 to 7 hours As a result, a high-strength building material useful as a floor material, a wall material or the like can be manufactured.

【0016】[0016]

【作用】下水汚泥焼却灰と石灰とを成形してオートクレ
ーブ処理することにより、下水汚泥焼却灰中のSiO
2 ,CaOと石灰(CaO,Ca(OH)2 )が下記の
如く反応してケイ酸カルシウム水和物を生成して硬化す
る。
[Function] SiO in sewage sludge incineration ash is obtained by molding sewage sludge incineration ash and lime and subjecting to autoclave treatment.
2 , CaO and lime (CaO, Ca (OH) 2 ) react as described below to form calcium silicate hydrate and harden.

【0017】 Ca(OH)2 +SiO2 →ケイ酸カルシウム水和物 この硬化反応はオートクレーブ処理により促進され、反
応は円滑に進行する。
Ca (OH) 2 + SiO 2 → calcium silicate hydrate This hardening reaction is promoted by the autoclave treatment, and the reaction proceeds smoothly.

【0018】本発明においては、成形原料として藁及び
/又は無機鉱物繊維を配合するため、藁に付着している
SiO2 分の一部、或いは、無機鉱物繊維中のSiO2
分の一部もCa(OH)2 と反応して硬化を促進させ
る。しかも、これら藁,無機鉱物繊維の繊維による強度
向上効果により、得られる建材は著しく高強度なものと
なる。また、本発明においては、焼成を行なわないた
め、従来の焼成を行なうものに比べて、消費エネルギー
が小さくてすむ。
[0018] In the present invention, to formulate a straw and / or inorganic mineral fibers as a molding material, a portion of the SiO 2 minutes attached to straw, or, SiO 2 inorganic mineral fibers
Some of the minutes also react with Ca (OH) 2 to accelerate curing. Moreover, the resulting building material becomes remarkably high in strength due to the strength-improving effect of the straw and the inorganic mineral fibers. Further, in the present invention, since the firing is not performed, the energy consumption is smaller than that of the conventional firing.

【0019】本発明において、特に藁を使用する場合に
は、下水汚泥焼却灰のみならず藁の有効利用を図ること
もでき、省資源の面で有利である。
In the present invention, particularly when straw is used, not only sewage sludge incineration ash but also straw can be effectively utilized, which is advantageous in terms of resource saving.

【0020】[0020]

【実施例】以下に実施例及び比較例を挙げて本発明をよ
り具体的に説明する。
EXAMPLES The present invention will be described more specifically with reference to Examples and Comparative Examples below.

【0021】実施例1〜3 表1に示す配合にて成形原料を製造し、下記条件にて一
軸加圧成形し、次いで、下記条件にてオートクレーブ処
理して20cm×20cm×40cmの建材を製造し
た。
Examples 1 to 3 A molding raw material was produced according to the composition shown in Table 1, uniaxially pressure-formed under the following conditions, and then autoclaved under the following conditions to produce a building material of 20 cm × 20 cm × 40 cm. did.

【0022】成形条件 面圧:250kgf/cm2 オートクレーブ処理条件 温度:180℃ 処理時間:5hr 得られた建材について曲げ強度を測定し、結果を表1に
示した。
Molding condition Surface pressure: 250 kgf / cm 2 Autoclave treatment condition Temperature: 180 ° C. Treatment time: 5 hr The bending strength of the obtained building material was measured, and the results are shown in Table 1.

【0023】比較例1 藁を用いなかったこと以外は実施例1と同様に行なっ
て、得られた建材の曲げ強度を測定して結果を表1に示
した。
Comparative Example 1 Bending strength of the obtained building material was measured in the same manner as in Example 1 except that straw was not used, and the results are shown in Table 1.

【0024】表1より明らかなように、本発明の建材の
製造方法によれば下水汚泥焼却灰を有効利用して高強度
建材を安価に得ることができる。
As is clear from Table 1, according to the method for manufacturing a building material of the present invention, a high-strength building material can be obtained at a low cost by effectively utilizing sewage sludge incineration ash.

【0025】[0025]

【表1】 [Table 1]

【0026】[0026]

【発明の効果】以上詳述した通り、本発明の建材の製造
方法によれば、下水汚泥焼却灰を有効利用して、壁材、
床材等として有用な高強度建材を低消費エネルギーにて
製造することができる。特に、藁を配合する場合には、
下水汚泥焼却灰と共に藁の有効利用を図ることもでき、
工業的に極めて有利である。
As described in detail above, according to the method for manufacturing a building material of the present invention, the sewage sludge incineration ash is effectively used to make a wall material,
A high-strength building material useful as a floor material or the like can be manufactured with low energy consumption. Especially when blending straw,
It is also possible to make effective use of straw with sewage sludge incineration ash,
It is extremely advantageous industrially.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C04B 14:38) ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display location C04B 14:38)

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 下水汚泥焼却灰と、石灰と、藁及び/又
は無機鉱物繊維とを混合した後、成形し、次いでオート
クレーブ処理することを特徴とする建材の製造方法。
1. A method for producing a building material, which comprises mixing sewage sludge incineration ash, lime, straw and / or inorganic mineral fibers, molding, and then autoclaving.
JP21969193A 1993-09-03 1993-09-03 Production of building material Pending JPH0769705A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21969193A JPH0769705A (en) 1993-09-03 1993-09-03 Production of building material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21969193A JPH0769705A (en) 1993-09-03 1993-09-03 Production of building material

Publications (1)

Publication Number Publication Date
JPH0769705A true JPH0769705A (en) 1995-03-14

Family

ID=16739455

Family Applications (1)

Application Number Title Priority Date Filing Date
JP21969193A Pending JPH0769705A (en) 1993-09-03 1993-09-03 Production of building material

Country Status (1)

Country Link
JP (1) JPH0769705A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109867450A (en) * 2019-03-30 2019-06-11 肇庆市珈旺环境技术研究院 Sludge incineration ash cement and preparation and application thereof
CN112094101A (en) * 2020-08-31 2020-12-18 安徽康健新型建材有限公司 Formula and production method of urban sludge and coal gangue hollow brick

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109867450A (en) * 2019-03-30 2019-06-11 肇庆市珈旺环境技术研究院 Sludge incineration ash cement and preparation and application thereof
CN109867450B (en) * 2019-03-30 2022-04-22 肇庆市珈旺环境技术研究院 Sludge incineration ash cement and preparation and application thereof
CN112094101A (en) * 2020-08-31 2020-12-18 安徽康健新型建材有限公司 Formula and production method of urban sludge and coal gangue hollow brick

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