JPH07328831A - Surface-covered carbonized tungsten group cemented carbide made and mill whose hard vapor deposition layer has excellent separation resistance - Google Patents
Surface-covered carbonized tungsten group cemented carbide made and mill whose hard vapor deposition layer has excellent separation resistanceInfo
- Publication number
- JPH07328831A JPH07328831A JP6154231A JP15423194A JPH07328831A JP H07328831 A JPH07328831 A JP H07328831A JP 6154231 A JP6154231 A JP 6154231A JP 15423194 A JP15423194 A JP 15423194A JP H07328831 A JPH07328831 A JP H07328831A
- Authority
- JP
- Japan
- Prior art keywords
- vapor deposition
- hard vapor
- deposition layer
- unit hard
- cutting edge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23C—MILLING
- B23C5/00—Milling-cutters
- B23C5/02—Milling-cutters characterised by the shape of the cutter
- B23C5/10—Shank-type cutters, i.e. with an integral shaft
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5053—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials non-oxide ceramics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23C—MILLING
- B23C2224/00—Materials of tools or workpieces composed of a compound including a metal
- B23C2224/04—Aluminium oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23C—MILLING
- B23C2224/00—Materials of tools or workpieces composed of a compound including a metal
- B23C2224/28—Titanium carbide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23C—MILLING
- B23C2224/00—Materials of tools or workpieces composed of a compound including a metal
- B23C2224/32—Titanium carbide nitride (TiCN)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23C—MILLING
- B23C2224/00—Materials of tools or workpieces composed of a compound including a metal
- B23C2224/36—Titanium nitride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23C—MILLING
- B23C2228/00—Properties of materials of tools or workpieces, materials of tools or workpieces applied in a specific manner
- B23C2228/10—Coating
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Milling Processes (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Ceramic Products (AREA)
- Chemical Vapour Deposition (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】この発明は、通常の切削は勿論の
こと、特に高い発熱を伴なう高送りや高切込みなどの重
切削に用いた場合にも硬質蒸着層に剥離の発生なく、長
期に亘ってすぐれた切削性能を発揮する表面被覆炭化タ
ングステン基超硬合金製エンドミル(以下、被覆超硬エ
ンドミルという)に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention does not cause peeling in a hard vapor-deposited layer when used for heavy cutting such as high feed and high depth of cut with high heat generation as well as normal cutting. The present invention relates to a surface-coated tungsten carbide based cemented carbide end mill (hereinafter referred to as a coated cemented carbide end mill) that exhibits excellent cutting performance for a long period of time.
【0002】[0002]
【従来の技術】従来、一般に被覆超硬エンドミルとし
て、図2に、平面図、A矢視図、およびB−B断面図で
例示される通り、炭化タングステン(以下、WCで示
す)基超硬合金で構成されたシャンク部1と切刃部2か
らなり、かつ切刃部2には複数本の外周刃3が等間隔で
全長に亘ってねじれながら存在し、前記外周刃3が逃げ
面3aとすくい面3bで構成された基体Sの少なくとも
切刃部2の底刃4を含む先端部の表面を、図3に切刃部
の外周刃部分が概略部分横断面図で示されるように、化
学蒸着法および/または物理蒸着法により形成された
0.5〜15μmの範囲内の所定の平均層厚を有する硬
質蒸着層Tで被覆してなるものが知られている。また、
上記硬質蒸着層Tが、Ti、炭化チタン、窒化チタン、
炭窒化チタン、TiとAlの複合窒化物、TiとAlの
複合炭窒化物、および酸化アルミニウム(以下、それぞ
れTiC,TiN,TiCN,(Ti,Al)N,(T
i,Al)CN、およびAl2 O3 で示す)のうちの1
種の単層または2種以上の複層からなることも知られて
いる。2. Description of the Related Art Conventionally, a tungsten carbide (hereinafter referred to as WC) base cemented carbide is generally used as a coated cemented carbide end mill, as illustrated in FIG. 2 with a plan view, a view taken along arrow A and a sectional view taken along line BB. The shank portion 1 and the cutting edge portion 2 are made of an alloy, and the cutting edge portion 2 has a plurality of outer peripheral blades 3 twisted at equal intervals over the entire length, and the outer peripheral blade 3 has a flank 3a. The surface of the tip portion including at least the bottom blade 4 of the cutting edge portion 2 of the base body S constituted by the rake face 3b, as shown in FIG. 3 in which the outer peripheral blade portion of the cutting edge portion is shown in a schematic partial cross-sectional view, It is known to coat with a hard vapor deposition layer T having a predetermined average layer thickness within the range of 0.5 to 15 μm formed by a chemical vapor deposition method and / or a physical vapor deposition method. Also,
The hard vapor deposition layer T is made of Ti, titanium carbide, titanium nitride,
Titanium carbonitride, composite nitride of Ti and Al, composite carbonitride of Ti and Al, and aluminum oxide (hereinafter, TiC, TiN, TiCN, (Ti, Al) N, (T, respectively).
i, Al) CN, and Al 2 O 3 ) 1)
It is also known to consist of a single layer of two or more than two layers.
【0003】[0003]
【発明が解決しようとする課題】一方、近年の切削機械
の高性能化はめざましく、切削加工の省力化とも相まっ
て、送りや切込みを大きくした切削条件での切削加工が
行なわれる傾向にあるが、上記の従来被覆超硬エンドミ
ルにおいては、これを上記の高い発熱を伴なう高送り切
削や高切込み切削などに用いると、硬質蒸着層に剥離が
発生し易く、比較的短時間で使用寿命に至るのが現状で
ある。On the other hand, in recent years, cutting machines have been remarkably improved in performance, and coupled with labor saving in cutting, there is a tendency that cutting is performed under cutting conditions with a large feed and depth of cut. In the above-mentioned conventional coated carbide end mill, if this is used for high feed cutting or high depth cutting accompanied by the above-mentioned high heat generation, peeling easily occurs in the hard vapor deposition layer and the service life is relatively short. It is the current situation.
【0004】[0004]
【課題を解決するための手段】そこで、本発明者等は、
上記のような観点から、硬質蒸着層に剥離の発生がない
被覆超硬エンドミルを開発すべく研究を行なった結果、
上記の従来被覆超硬エンドミルに適用されている単層ま
たは複層の硬質蒸着層を1単位とし(以下、これをユニ
ット硬質蒸着層という)、切刃部の先端面の底刃、並び
に図1に概略部分横断面図で示されるように、同じく切
刃部を構成する外周刃3の逃げ面3aを単数のユニット
硬質蒸着層T1 で被覆し、前記切刃部における前記単数
のユニット硬質蒸着層形成以外の部分を複数のユニット
硬質蒸着層T1 ,T2 ,T3 ,T4 で被覆すると共に、
前記複数のユニット硬質蒸着法のうちの最外側のユニッ
ト硬質蒸着層T1 を上記底刃および逃げ面3aと同じ構
成とした被覆超硬エンドミルは、通常の切削加工は勿論
のこと、高送り切削や高切込み切削などの高い発熱を伴
なう切削に用いた場合にも上記超硬蒸着層がすぐれた耐
剥離性を示し、長期に亘ってすぐれた切削性能を発揮す
るという研究結果を得たのである。Therefore, the present inventors have
From the above viewpoint, as a result of conducting research to develop a coated carbide end mill that does not cause peeling in the hard vapor deposition layer,
A single-layer or multiple-layer hard vapor deposition layer applied to the above-mentioned conventional coated carbide end mill is defined as one unit (hereinafter, this is referred to as a unit hard vapor deposition layer), and the bottom blade of the tip surface of the cutting edge portion, and FIG. As shown in the schematic partial cross-sectional view in Fig. 1 , the flank 3a of the outer peripheral blade 3 which also constitutes the cutting edge portion is covered with a single unit hard vapor deposition layer T1, and the single unit hard vapor deposition in the cutting edge portion is performed. The portions other than the layer formation are covered with a plurality of unit hard vapor deposition layers T 1 , T 2 , T 3 and T 4 , and
The coated cemented carbide end mill in which the outermost unit hard vapor deposition layer T 1 of the plurality of unit hard vapor deposition methods has the same configuration as the bottom blade and the flank 3a can be used for high-feed cutting as well as ordinary cutting. We have obtained the research results that the above-mentioned carbide deposition layer exhibits excellent delamination resistance even when used for cutting with high heat generation such as high cutting depth and high cutting depth, and exhibits excellent cutting performance for a long period of time. Of.
【0005】この発明は、上記の研究結果にもとづいて
なされたものであって、切刃部とシャンク部からなる基
体がWC基超硬合金で構成され、かつ少なくとも前記切
刃部の先端部が化学蒸着法および/または物理蒸着法に
よる硬質蒸着層で被覆された被覆超硬エンドミルにおい
て、(a) 上記切刃部の先端面の底刃、並びに同じく
上記切刃部を構成する外周刃の逃げ面が単数のユニット
硬質蒸着層で被覆され、(b) 上記切刃部における上
記単数のユニット硬質蒸着層形成以外の部分が複数のユ
ニット硬質蒸着層で被覆されると共に、前記複数のユニ
ット硬質蒸着層のうちの最外側のユニット硬質蒸着層を
上記単数のユニット硬質蒸着層と同じ構成とし、(c)
上記ユニット硬質蒸着層を、Ti,TiC,TiN,
TiCN,(Ti,Al)N,(Ti,Al)CN、お
よびAl2 O3 のうちの1種の単層または2種以上の複
層で構成する、以上(a)〜(c)の要件を満足するこ
とを特徴とする硬質蒸着層がすぐれた耐剥離性を有する
被覆超硬エンドミルに特徴を有するものである。The present invention has been made based on the above research results, in which a base body composed of a cutting blade portion and a shank portion is made of WC-based cemented carbide, and at least the tip portion of the cutting blade portion is formed. In a coated carbide end mill coated with a hard vapor deposition layer by a chemical vapor deposition method and / or a physical vapor deposition method, (a) a relief of a bottom blade of a tip end surface of the cutting blade portion and an outer peripheral blade which also constitutes the cutting blade portion. The surface is coated with a single unit hard vapor deposition layer, and (b) portions other than the formation of the single unit hard vapor deposition layer in the cutting edge portion are coated with a plurality of unit hard vapor deposition layers, and the plurality of unit hard vapor deposition layers are covered. The outermost unit hard vapor deposition layer of the layers has the same structure as the single unit hard vapor deposition layer, and (c)
The unit hard vapor deposition layer is formed of Ti, TiC, TiN,
Requirements of the above (a) to (c), which is composed of a single layer of TiCN, (Ti, Al) N, (Ti, Al) CN, and Al 2 O 3 or a multilayer of two or more thereof. The hard vapor-deposited layer is characterized by satisfying the above conditions and is characterized by a coated carbide end mill having excellent peeling resistance.
【0006】なお、この発明の被覆超硬エンドミルは、
(a) 基体の切刃部における底刃、並びに少なくとも
切刃部の先端部における外周刃の逃げ面をマスキングし
た状態で、これに化学蒸着法および/または物理蒸着法
を施して、単数または複数のユニット硬質蒸着層で被覆
し、ついで前記マスキングを除去して、少なくとも切刃
部の先端部全体を単数のユニット硬質蒸着層で被覆する
方法、(b) 上記の従来被覆超硬エンドミルおよび本
発明被覆超硬エンドミルの使用済のものを用意し、これ
ら使用済被覆超硬エンドミルの切刃部における底刃、並
びに外周刃の逃げ面に残留する硬質蒸着層を除去すると
共に、寸法出しを行なった状態で、少なくとも切刃部の
先端部全体を単数のユニット硬質蒸着層で被覆する方
法、以上(a)または(b)の方法によって製造するの
が望ましい。The coated carbide end mill of the present invention is
(A) A single or a plurality of pieces are obtained by performing chemical vapor deposition and / or physical vapor deposition on the bottom edge of the base blade and at least the flank of the outer peripheral edge at the tip of the cutting edge, which are masked. Of the unit hard vapor-deposited layer, then removing the masking, and coating at least the entire tip of the cutting edge portion with a single unit hard vapor-deposited layer, (b) the conventional coated carbide end mill and the present invention. Prepared used coated carbide end mills, removed the bottom blade in the cutting edge part of these used coated carbide end mills, and the hard vapor deposition layer remaining on the flank of the outer peripheral blade, and performed dimensioning. In this state, at least the entire tip portion of the cutting edge portion is preferably coated with a single unit hard vapor deposition layer, or by the above method (a) or (b).
【0007】[0007]
【実施例】つぎに、この発明の被覆超硬エンドミルを実
施例により具体的に説明する。WC基超硬合金基体とし
て、JIS規格M20に相当する組成を有する直径:1
0mmの汎用2枚刃エンドミル(SED2100SG)を
用意し、一方表1に示される組成と厚さの単層または複
層で構成されたユニット硬質蒸着層A〜Lを設計し、ま
ず、上記基体の切刃部における底刃、並びに外周刃の逃
げ面をマスキングし、この状態で表1に示される設計に
もとづいて前記基体の表面に、表2〜5に示される組合
せで物理蒸着法に分類されるイオンプレーティング法お
よび通常の化学蒸着法にて単数または複数のユニット硬
質蒸着層T2 〜T4 (図1参照)を形成し、ついで前記
マスキングを除いた状態で切刃部全体を同じく表2〜5
に示される組合せでユニット硬質蒸着層T1 で被覆する
ことにより本発明被覆超硬エンドミル1〜43をそれぞ
れ製造した。また、比較の目的で、表6に示される通り
基体の切刃部をユニット硬質蒸着層A〜Lのいずれかで
被覆する以外は同一の条件で従来被覆超硬エンドミル1
〜12をそれぞれ製造した。EXAMPLES Next, the coated carbide end mill of the present invention will be described in detail with reference to Examples. As a WC-based cemented carbide substrate, it has a composition equivalent to JIS standard M20. Diameter: 1
A 0 mm general-purpose 2-flute end mill (SED2100SG) was prepared, while unit hard vapor deposition layers A to L composed of single layers or multiple layers having the composition and thickness shown in Table 1 were designed. The bottom face of the cutting edge and the flanks of the outer peripheral face are masked, and in this state, based on the design shown in Table 1, the surface of the substrate is classified into the physical vapor deposition methods in the combinations shown in Tables 2 to 5. A single or a plurality of unit hard vapor deposition layers T 2 to T 4 (see FIG. 1) are formed by an ion plating method and an ordinary chemical vapor deposition method, and then the entire cutting edge portion is also exposed in the state where the masking is removed. 2-5
Each of the coated carbide end mills 1 to 43 of the present invention was manufactured by coating with the unit hard deposition layer T 1 in the combination shown in. For the purpose of comparison, a conventional coated carbide end mill 1 under the same conditions except that the cutting edge portion of the substrate is coated with any of the unit hard deposition layers A to L as shown in Table 6.
~ 12 were produced respectively.
【0008】つぎに、この結果得られた各種の被覆超硬
エンドミルについて、 被削材:S50C(ブリネル硬さ:236を有する炭素
鋼)、 切削速度:120m/min 、 送り:0.04mm/刃、 軸方向切込み:15mm、 径方向切込み:1mm、 切削時間:60分、 の条件で鋼のダウンカット方式による湿式高送り高切込
み切削試験を行ない、外周刃の刃先部の逃げ面摩耗幅を
測定した。これらの測定結果を表2〜6に示した。Next, regarding various coated carbide end mills obtained as a result, the work material: S50C (carbon steel having Brinell hardness: 236), cutting speed: 120 m / min, feed: 0.04 mm / blade , Axial depth of cut: 15 mm, Radial depth of cut: 1 mm, Cutting time: 60 minutes, Wet high feed high depth of cut cutting test of steel is performed under the following conditions, and the flank wear width of the edge of the outer peripheral blade is measured. did. The results of these measurements are shown in Tables 2-6.
【0009】[0009]
【表1】 [Table 1]
【0010】[0010]
【表2】 [Table 2]
【0011】[0011]
【表3】 [Table 3]
【0012】[0012]
【表4】 [Table 4]
【0013】[0013]
【表5】 [Table 5]
【0014】[0014]
【表6】 [Table 6]
【0015】[0015]
【発明の効果】表2〜6に示される結果から、本発明被
覆超硬エンドミル1〜43は、いずれも高い発熱を伴な
う高送り高切込み切削にもかかわらず、硬質蒸着層に剥
離の発生がなく、すぐれた耐摩耗性を示すのに対して、
従来被覆超硬エンドミル1〜12は、いずれも硬質蒸着
層に剥離が発生し、比較的短時間で使用寿命に至ること
が明らかである。上述のように、この発明の被覆超硬エ
ンドミルは、通常の切削は勿論のこと、特に高切込み切
削や高送り切削などの高い発熱を伴なう切削に用いた場
合にも硬質蒸着層に剥離の発生なく、長期に亘ってすぐ
れた切削性能を発揮するので、切削機械の高性能化およ
び切削加工の省力化にも十分満足に対応することができ
るなど工業上有用な特性をもつものである。From the results shown in Tables 2 to 6, in the coated carbide end mills 1 to 43 of the present invention, despite the high feed and high depth of cut cutting accompanied by high heat generation, the hard vapor deposition layer was exfoliated. While it does not occur and shows excellent wear resistance,
It is apparent that in the conventional coated carbide end mills 1 to 12, peeling occurs in the hard vapor deposition layer and the service life is reached in a relatively short time. As described above, the coated carbide end mill of the present invention peels off to a hard vapor deposition layer not only in ordinary cutting but also when used for cutting with high heat generation such as high-cutting cutting and high-feed cutting. Since it exhibits excellent cutting performance over a long period of time with no occurrence of cutting edge, it has industrially useful characteristics such as high performance of cutting machines and labor saving of cutting processing. .
【図1】本発明被覆超硬エンドミルの外周刃を示す概略
部分横断面図である。FIG. 1 is a schematic partial cross-sectional view showing an outer peripheral blade of a coated carbide end mill of the present invention.
【図2】被覆超硬エンドミルを構成する基体の正面図、
A矢視図、およびB−B断面図である。FIG. 2 is a front view of a substrate constituting a coated carbide end mill,
It is an arrow A view and a BB sectional view.
【図3】従来被覆超硬エンドミルの外周刃を示す概略部
分横断面図である。FIG. 3 is a schematic partial cross-sectional view showing an outer peripheral blade of a conventional coated carbide end mill.
S 基体 T 硬質蒸着層 T1 〜T4 ユニット硬質蒸着層 1 シャンク部 2 切刃部 3 外周刃 3a 逃げ面 3b すくい面 4 底刃S substrate T hard vapor deposition layer T 1 to T 4 unit hard vapor deposition layer 1 shank part 2 cutting edge part 3 outer peripheral blade 3a flank surface 3b rake surface 4 bottom blade
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C23C 16/30 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI technical display location C23C 16/30
Claims (1)
タングステン基超硬合金で構成され、かつ少なくとも前
記切刃部の先端部が化学蒸着法および/または物理蒸着
法による硬質蒸着層で被覆された表面被覆炭化タングス
テン基超硬合金製エンドミルにおいて、 上記切刃部の先端面の底刃、並びに同じく上記切刃部を
構成する外周刃の逃げ面が単数のユニット硬質蒸着層で
被覆され、 上記切刃部における上記単数のユニット硬質蒸着層形成
以外の部分が複数のユニット硬質蒸着層で被覆されると
共に、前記複数のユニット硬質蒸着層のうちの最外側の
ユニット硬質蒸着層を上記単数のユニット硬質蒸着層と
同じ構成とし、 上記ユニット硬質蒸着層を、Ti、炭化チタン、窒化チ
タン、炭窒化チタン、TiとAlの複合窒化物、Tiと
Alの複合炭窒化物、および酸化アルミニウムのうちの
1種の単層または2種以上の複層で構成したこと、を特
徴とする硬質蒸着層がすぐれた耐剥離性を有する表面被
覆炭化タングステン基超硬合金製エンドミル。1. A substrate comprising a cutting edge portion and a shank portion is made of a tungsten carbide based cemented carbide, and at least a tip portion of the cutting edge portion is covered with a hard vapor deposition layer formed by a chemical vapor deposition method and / or a physical vapor deposition method. In the surface-coated tungsten carbide-based cemented carbide end mill, the bottom blade of the tip surface of the cutting edge portion, and the flank of the outer peripheral blade that also constitutes the cutting edge portion are coated with a single unit hard vapor deposition layer, While the portion other than the unit hard vapor deposition layer formation of the singular unit in the cutting edge portion is covered with a plurality of unit hard vapor deposition layers, the outermost unit hard vapor deposition layer of the plurality of unit hard vapor deposition layers is the singular. The unit hard vapor deposition layer has the same structure, and the unit hard vapor deposition layer is formed of Ti, titanium carbide, titanium nitride, titanium carbonitride, a composite nitride of Ti and Al, and Ti and Al. A surface-coated tungsten carbide-based cemented carbide having a hard vapor-deposited layer having excellent delamination resistance, characterized by comprising a composite carbonitride and a single layer of aluminum oxide or a multilayer of two or more types. Alloy end mill.
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JP15423194A JP3196510B2 (en) | 1994-06-13 | 1994-06-13 | Surface-coated tungsten carbide based cemented carbide end mill with excellent peel resistance with hard deposited layer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15423194A JP3196510B2 (en) | 1994-06-13 | 1994-06-13 | Surface-coated tungsten carbide based cemented carbide end mill with excellent peel resistance with hard deposited layer |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH07328831A true JPH07328831A (en) | 1995-12-19 |
JP3196510B2 JP3196510B2 (en) | 2001-08-06 |
Family
ID=15579719
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JP15423194A Expired - Fee Related JP3196510B2 (en) | 1994-06-13 | 1994-06-13 | Surface-coated tungsten carbide based cemented carbide end mill with excellent peel resistance with hard deposited layer |
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JP (1) | JP3196510B2 (en) |
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CN100344788C (en) * | 2002-09-12 | 2007-10-24 | 上海星航五金制品有限公司 | Heat treatment method for knife-edge tungsten carbide |
WO2018117556A1 (en) * | 2016-12-20 | 2018-06-28 | 주식회사 티씨케이 | Semiconductor manufacturing component comprising deposition layer covering interlayer boundary and manufacturing method thereof |
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WO2010064359A1 (en) * | 2008-12-01 | 2010-06-10 | パナソニック株式会社 | Electrode foil for capacitor and electrolytic capacitor using the electrode foil |
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Cited By (7)
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---|---|---|---|---|
CN100344788C (en) * | 2002-09-12 | 2007-10-24 | 上海星航五金制品有限公司 | Heat treatment method for knife-edge tungsten carbide |
JP2021119026A (en) * | 2016-09-26 | 2021-08-12 | 株式会社Moldino | Hard coating film-coated tool and manufacturing method thereof |
WO2018117556A1 (en) * | 2016-12-20 | 2018-06-28 | 주식회사 티씨케이 | Semiconductor manufacturing component comprising deposition layer covering interlayer boundary and manufacturing method thereof |
US11180855B2 (en) | 2016-12-20 | 2021-11-23 | Tokai Carbon Korea Co., Ltd. | Semiconductor manufacturing component comprising deposition layer covering interlayer boundary and manufacturing method thereof |
CN110899803A (en) * | 2020-01-02 | 2020-03-24 | 山东大学 | Integral ceramic milling cutter for high-speed milling of nickel-based alloy and manufacturing method thereof |
CN110899803B (en) * | 2020-01-02 | 2021-01-29 | 山东大学 | Integral ceramic milling cutter for high-speed milling of nickel-based alloy and manufacturing method thereof |
WO2021260775A1 (en) * | 2020-06-22 | 2021-12-30 | 住友電工ハードメタル株式会社 | Cutting tool |
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---|---|
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