JPH07304651A - Liquid detergent for scrubbing - Google Patents
Liquid detergent for scrubbingInfo
- Publication number
- JPH07304651A JPH07304651A JP10047494A JP10047494A JPH07304651A JP H07304651 A JPH07304651 A JP H07304651A JP 10047494 A JP10047494 A JP 10047494A JP 10047494 A JP10047494 A JP 10047494A JP H07304651 A JPH07304651 A JP H07304651A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- powder
- scrubbing
- liquid detergent
- scrubbing material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、液状スクラブ洗浄剤に
関し、特に、洗顔料，シャンプ−，角質化皮膚除去剤等
の人の肌や、その他傷つき易い被洗浄体の表面を洗浄す
るのに好適な洗浄剤に好適に用いられる液状のスクラブ
洗浄剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a liquid scrub cleaning agent, and more particularly to cleaning human skin such as facial cleansers, shampoos, keratinized skin removers and the like, and the surface of other easily-washed objects. The present invention relates to a liquid scrub cleaner that is preferably used as a suitable cleaner.
【０００２】[0002]
【従来の技術】近年、人の皮膚の汚れや老化した角質細
胞を物理的にこすり落し、更に適当な刺激を皮膚に与え
て新陳代謝を促進させるために、例えば、洗顔料，ボデ
−シャンプ−あるいは角質化皮膚除去剤等の洗浄剤にス
クラブ材を添加することが広く行われるようになった。
現在、そのようなスクラブ洗浄剤に使用されているスク
ラブ材としては、天然素材では、例えば、くるみ，ピ−
チ，あんず等の植物種子核を粉砕したものや、合成物で
は、ポリエチレン等の合成樹脂類の粉末が多く用いられ
ている。しかし、上記の天然素材は、硬度が高すぎるた
め粉砕して得られる粉末にシャ−プな角部が形成され、
皮膚を傷つけるという実用上の問題があった。他方、ポ
リエチレンは、適度の硬さを有し、粉砕された粉末が柔
らかい角を持つ不定形粒子で肌を傷つける恐れがないの
で、一般に広く実用されている。2. Description of the Related Art In recent years, in order to physically scrape away dirt and aging keratinocytes of human skin and further give a suitable stimulus to the skin to promote metabolism, for example, a face wash, body shampoo or It has become common practice to add scrubbing agents to cleaning agents such as keratinized skin removers.
As a scrubbing material currently used for such a scrubbing agent, natural materials such as walnuts and peels are used.
For crushed plant seed nuclei such as Ji and apricot, and for synthetic products, powders of synthetic resins such as polyethylene are often used. However, since the above natural material has too high hardness, sharp corners are formed in the powder obtained by crushing,
There was a practical problem of damaging the skin. On the other hand, polyethylene is generally widely used because it has an appropriate hardness, and the pulverized powder does not have a risk of damaging the skin due to amorphous particles having soft corners.
【０００３】しかし、従来使用されている前記素材のス
クラブ材は、例えば、ポリエチレンは、その製造法や分
子量によって多少異なるが、0.92〜0.98の範囲内の固有
の真比重を有するため、その粉末を水性液体洗浄剤に添
加するときは容易に浮上し、また、くるみ，ピ−チ，あ
んず等の植物種子核は、1.22〜1.26の範囲の固有の真比
重を有するため水性液剤中では経時的に沈降分離し、均
一に分散した安定な液状洗浄剤を提供することが困難で
あった。更に、他の樹脂粉体類やカオリン，クレ−のよ
うな無機鉱物質粉末類は、植物種子核より比重が更に大
きいため、水性液剤中で一層容易に分離するので不都合
である。However, the scrubbing material of the above-mentioned material which has been conventionally used, for example, polyethylene has a specific true specific gravity within the range of 0.92 to 0.98, although the polyethylene is slightly different depending on the manufacturing method and the molecular weight thereof. It easily floats when added to an aqueous liquid detergent, and since plant seed nuclei such as walnuts, peach, and apricots have an intrinsic true specific gravity in the range of 1.22 to 1.26, they gradually change over time in an aqueous liquid agent. It has been difficult to provide a stable liquid detergent which is separated by sedimentation and uniformly dispersed. Furthermore, other resin powders and inorganic mineral powders such as kaolin and clay have a larger specific gravity than plant seed nuclei, and are therefore disadvantageous because they are more easily separated in an aqueous liquid formulation.
【０００４】これらの比重の大きいスクラブ材を液体洗
浄剤に分散させるには、例えば、10μｍ以下の微細な粉
末であることが要求され、そのような微粉末を所望量加
えると容易に分離するので、極く微量しか添加できず、
従って、スクラブ洗浄剤としてのマッサ−ジ効果は実質
的に期待できない。また、スクラブ効果を重視して、所
望量のスクラブ材を含有する洗浄剤を、例えば、カ−ボ
ポ−ル，メチルセルロ−スやベントナイト等の増粘剤に
よって高粘度のペ−スト状にし、均一に分散するスクラ
ブ材を洗浄剤中に安定に保持させさることが行われてい
る。そのような高粘性物は組成分離を抑制するが、通
常、チュ−ブ容器に入れられ、使用に望ましいポンプ式
やボトム式にはできないという不利がある。In order to disperse the scrubbing material having a large specific gravity in the liquid detergent, for example, a fine powder having a particle size of 10 μm or less is required, and if such a fine powder is added in a desired amount, it is easily separated. , Only a very small amount can be added,
Therefore, the massaging effect as a scrub cleaning agent cannot be substantially expected. Further, with emphasis on the scrubbing effect, a cleaning agent containing a desired amount of scrubbing material is made into a highly viscous paste with a thickener such as carbopol, methylcellulose or bentonite, A scrubbing material that is uniformly dispersed is held stably in a cleaning agent. Although such a highly viscous substance suppresses composition separation, it has the disadvantage that it is usually placed in a tube container and cannot be a pump type or a bottom type, which is desirable for use.
【０００５】[0005]
【発明が解決しようとする課題】上記のように皮膚マサ
−ジ性に優れた非分離性の液状スクラブ洗浄剤は今のと
ころ知られていない。従って、本発明の課題は、所望量
のスクラブ材を含有する皮膚マサ−ジ効果の優れた非分
離性液状スクラブ洗浄剤を提供することにある。また、
本発明の他の技術的課題は、経時的に極めて安定で使用
に好適な液状スクラブ洗浄剤を提供することにある。本
発明のその他の課題ないし技術的特徴は、以下の記載か
ら一層明らかになるであろう。As described above, a non-separable liquid scrub cleansing agent having excellent skin mastability has not been known so far. Therefore, an object of the present invention is to provide a non-separable liquid scrub cleaner containing a desired amount of scrub material and having an excellent skin massage effect. Also,
Another technical object of the present invention is to provide a liquid scrub cleaner which is extremely stable over time and suitable for use. Other problems and technical features of the present invention will become more apparent from the following description.
【０００６】本発明者らは、上記のような課題を解決す
べく、各種スクラブ材について試作研究を重ねた結果、
充填材と合成樹脂との複合樹脂粉末が、所望の比重に容
易にコントロ−ルすることができ、且つ皮膚マッサ−ジ
効果の優れた実用的に極めて望ましい液状スクラブ洗浄
剤を開発した。The inventors of the present invention have conducted trial research on various scrubbing materials in order to solve the above problems, and as a result,
We have developed a practically highly desirable liquid scrub cleaner that is a composite resin powder of a filler and a synthetic resin that can be easily controlled to a desired specific gravity and has an excellent skin massage effect.
【０００７】[0007]
【課題を解決するための手段】すなわち、本発明は、合
成樹脂に無機質粉末及び／又は有機質粉末を含有せしめ
て成る複合樹脂粉末であって、その平均真比重が0.95〜
1.10の範囲に調整された複合樹脂粉末をスクラブ材とし
て水性液状洗浄剤中に含有せしめて成る液状スクラブ洗
浄剤を要旨とするものである。[Means for Solving the Problems] That is, the present invention is a composite resin powder comprising a synthetic resin containing an inorganic powder and / or an organic powder, the average true specific gravity of which is 0.95 to
The gist of the present invention is a liquid scrubbing detergent obtained by incorporating a composite resin powder adjusted to the range of 1.10 into an aqueous liquid detergent as a scrubbing material.
【０００８】本発明の液状スクラブ洗浄材に用いられる
複合樹脂スクラブ粉末の調製に用いられる合成樹脂は、
比較的比重が小さいもの、特に、真比重が１以下の熱可
塑性合成樹脂であって、その代表的なものとしては、例
えば、ポリエチレン，ポリプロピレン等のポリオレフィ
ン又はポリアミド系樹脂が挙げられる。また、本発明の
複合樹脂スクラブ粉末の調製に用いられる充填材として
は、例えば、炭酸カルシウム，シリカ，ゼオライト，水
酸化アルミニウム，ベントナイト，木粉，セルロ−ス，
キトサン，シリコン樹脂，エポキシ樹脂，ポリエステル
樹脂又はアクリル樹脂等の無機質あるいは有機質の粉末
が例示される。これらの充填材は、単独でも二種以上を
組み合わせて使用することもできる。The synthetic resin used for preparing the composite resin scrub powder used in the liquid scrub cleaning material of the present invention is
A thermoplastic synthetic resin having a relatively small specific gravity, particularly a true specific gravity of 1 or less, and a typical example thereof is a polyolefin such as polyethylene or polypropylene, or a polyamide resin. Examples of the filler used for preparing the composite resin scrub powder of the present invention include calcium carbonate, silica, zeolite, aluminum hydroxide, bentonite, wood powder, cellulose,
Examples thereof include inorganic or organic powders such as chitosan, silicone resin, epoxy resin, polyester resin or acrylic resin. These fillers may be used alone or in combination of two or more.
【０００９】本発明に係る複合樹脂粉末スクラブ材は、
上記の合成樹脂と充填材を含有一体化させた複合体の粉
末であって、その複合体の比重は、0.95〜1.10の範囲内
に調整される。そのスクラブ材の調製は、代表的には、
溶解沈殿法又は機械粉砕法によって好都合に行うことが
でき、また、粉状体は、好ましくは 1.0〜1000μｍの範
囲の粒径に調製される。The composite resin powder scrubbing material according to the present invention is
It is a powder of a composite in which the synthetic resin and the filler are contained and integrated, and the specific gravity of the composite is adjusted within the range of 0.95 to 1.10. The preparation of the scrub material is typically
It can be conveniently carried out by the solution-precipitation method or the mechanical grinding method, and the powder is preferably prepared to a particle size in the range of 1.0 to 1000 μm.
【００１０】上記溶解沈殿法は、合成樹脂に所定量の粉
末充填材を配合し、これを溶剤に加えて加温し合成樹脂
を溶解させた後、冷却して複合樹脂粉末を析出沈殿させ
る方法であって、溶剤の組合せと樹脂濃度及び冷却速度
等を選択することにより粒度を調節することができる。The above-mentioned dissolution-precipitation method is a method in which a predetermined amount of powder filler is blended with a synthetic resin, and this is added to a solvent to heat the synthetic resin, and then the synthetic resin is cooled to precipitate and precipitate the composite resin powder. The particle size can be adjusted by selecting the combination of solvents, the resin concentration, the cooling rate, and the like.
【００１１】また機械粉砕法は、合成樹脂に所定量のス
クラブ用粉末充填材を配合し、その均一混合物を押出
機、例えば、二軸押出機で混練押出してカットし、得ら
れたペレットを粉砕して篩でふるうことにより所望の粒
度条件の充填材含有複合樹脂粉末スクラブ材を製造する
ことができる。このスクラブ材の製造においては、使用
対象や使用目的等によって充填材及び樹脂の種類，それ
らの混合割合及びスクラブ材の粒度が選択され、且つ洗
浄剤中へのスクラブ材の含有量が選択される。In the mechanical pulverization method, a predetermined amount of powder filler for scrub is mixed with a synthetic resin, and a uniform mixture thereof is kneaded and extruded by an extruder, for example, a twin-screw extruder and cut, and the obtained pellets are pulverized. Then, a filler-containing composite resin powder scrubbing material having a desired particle size condition can be produced by sieving with a sieve. In the production of this scrubbing material, the types of filler and resin, their mixing ratio and the particle size of the scrubbing material are selected according to the intended use and the purpose of use, and the content of the scrubbing material in the cleaning agent is selected. .
【００１２】本発明の洗浄剤に用いられる複合樹脂粉末
スクラブ材は、その真の平均比重が0.95〜1.10の範囲に
調製することが重要であって、実用上特に好ましい範囲
は、1.02〜1.05である。また、粉末スクラブ材の粒度
は、例えば、1.0 〜1000μｍ、好ましくは 600μｍ以下
のものが好都合に採用される。更に、樹脂粉末スクラブ
材の複合一体化においては、洗顔用，ハンドソ−プ用，
ボデ−シャンプ−用あるいは角質化皮膚除去用、その他
の使用対象あるいは使用目的等によって充填材及びその
含有量が選択され、また、その充填材の粒度も選択使用
される。更に、複合樹脂粉末スクラブ材は、通常、液状
洗浄剤中に１〜20重量％の範囲量が添加使用されるが、
実用的に好ましい範囲は、３〜10重量％である。It is important that the composite resin powder scrubbing material used in the cleaning agent of the present invention has a true average specific gravity in the range of 0.95 to 1.10, and a practically particularly preferable range is 1.02 to 1.05. is there. The particle size of the powder scrubbing material is conveniently 1.0 to 1000 .mu.m, preferably 600 .mu.m or less. Furthermore, in the composite integration of resin powder scrubbing material, for face washing, hand soap,
The filler and its content are selected depending on the intended use or purpose of use for body shampoo or keratinized skin removal, and the particle size of the filler is also selected and used. Further, the composite resin powder scrubbing material is usually used in an amount of 1 to 20% by weight in the liquid detergent,
A practically preferable range is 3 to 10% by weight.
【００１３】本発明の液状スクラブ洗浄剤は、前述のよ
うに、例えば、洗顔用，ボディ洗浄用あるいは角質化皮
膚除去用の洗浄剤及び皮膚マッサ−ジ効果を高める洗浄
剤として極めて有用であるばかりでなく、自動車ボデ−
洗浄剤のような金属塗装物表面や硝子表面の洗浄剤，家
庭用洗浄剤や工業用洗浄剤としても望ましい優れた実用
性を有する。それらの個々の洗浄対象に対応して、スク
ラブ材及び洗浄主剤としての界面活性剤の種類と含有量
とがそれぞれ適宜選択され、特に、傷が付き易い洗浄表
面に対しては、軟質研摩剤入り洗浄剤が好適に使用され
る。As described above, the liquid scrub cleansing agent of the present invention is extremely useful, for example, as a cleansing agent for cleansing the face, washing the body or removing keratinized skin, and as a cleansing agent for enhancing the effect of skin massaging. Not a car body
It has excellent practicability, which is also desirable as a cleaning agent for the surface of metal coatings and glass surfaces such as cleaning agents, household cleaning agents, and industrial cleaning agents. The type and content of the scrubbing agent and the surfactant as the main cleaning agent are appropriately selected in accordance with the respective objects to be cleaned, and in particular, for a cleaning surface that is easily scratched, a soft abrasive is used. A cleaning agent is preferably used.
【００１４】[0014]
【作用】本発明の液状スクラブ洗浄剤は、比重をその水
性洗浄剤に自由に適合させることができ、低粘性液状体
にもかかわらず経時的に浮上したり沈降分離する等の不
都合現象がなく、極めて優れた分散安定性が得られる。
また、合成樹脂と充填材それぞれの種類と混合割合及び
スクラブ材の粒度を選択して使用対象、あるいは使用目
的に応じた所望のスクラブ洗浄剤を容易に製造すること
ができる。The liquid scrubbing detergent of the present invention can freely adapt its specific gravity to the aqueous detergent, and does not cause inconvenience such as floating or sedimentation over time despite the low viscosity liquid. , Extremely excellent dispersion stability is obtained.
Further, it is possible to easily produce a desired scrub cleaning agent according to the object of use or the purpose of use by selecting the types and mixing ratios of the synthetic resin and the filler and the particle size of the scrub material.
【００１５】[0015]
【実施例】次に、具体例により、本発明の液状スクラブ
洗浄剤を更に詳細に説明する。 実施例 １ 比重が0.92のポリエチレンと充填材として真比重が2.70
の炭酸カルシウム粉末（調整された粒径約２μｍ品）と
を 100：19.5の重量割合で均一に混合し、二軸押出機で
混練押出して、比重が1.03の複合樹脂ペレットを製造し
た。これを粉砕し、80メッシュの篩をパスした平均粒径
が約 110μｍ以下の粒子から成るスクラブ材（Ａ）を作
製した。これを用いて下記組成のスクラブ洗浄剤を調製
した。EXAMPLES Next, the liquid scrub cleaner of the present invention will be described in more detail by way of specific examples. Example 1 Polyethylene having a specific gravity of 0.92 and a true specific gravity of 2.70 as a filler.
Calcium carbonate powder (adjusted particle size of about 2 μm) was uniformly mixed at a weight ratio of 100: 19.5, and the mixture was kneaded and extruded by a twin-screw extruder to produce composite resin pellets having a specific gravity of 1.03. This was crushed, and a scrubbing material (A) composed of particles having an average particle size of about 110 μm or less that was passed through a 80-mesh screen was prepared. Using this, a scrub cleaning agent having the following composition was prepared.
【００１６】 配 合 成 分 配合量（ｇ） ラウリン硫酸エステルトリエタノ−ルアミン ４００ ラウリルポリオキシエチレン（３モル） ２００ ラウリルジエタノ−ルアミド ５０ グリセリンモノパルミチン酸エステル １０ マカデミアナッツオイル １０ プロピレングリコ−ル ５０ 上記スクラブ材（Ａ） ５０（約５重量％) 防腐剤，キレ−ト剤，着色剤等 各少量 精 製 水 ２３０[0016] Constitutive Ingredients amount (g) of lauric acid ester triethanolamine Tano - triethanolamine 400 lauryl polyoxyethylene (3 mol) 200 Raurirujietano - Ruamido 50 glycerol mono palmitate 10 Macadamia nut oil 10 propylene glycol - le 50 above Scrubbing material (A) 50 (about 5% by weight) Preservatives, chelating agents, coloring agents, etc. Small amount of each purified water 230
【００１７】上記組成物を均一に撹拌混合し、得られた
液状スクラブ洗浄剤を容量200mｌのガラス瓶に入れ、30
日間静置して分散状態の変化を肉眼で観察した。30日後
の肉眼による調査では、浮上物や沈降物等による分散状
態の変化は全くなく極めて安定な分散状態の保持が観察
された。また、それを使用した皮膚スクラブ洗浄感も作
製時と変わりなく望ましいものであった。The above composition was uniformly mixed by stirring, and the obtained liquid scrub cleaning agent was put in a glass bottle having a volume of 200 ml,
It was allowed to stand for a day and the change in the dispersed state was visually observed. In the visual inspection after 30 days, there was no change in the dispersion state due to floating substances or sediments, and it was observed that the dispersion state was kept extremely stable. Further, the feeling of cleaning the skin scrub using the same was as desirable as that at the time of preparation.
【００１８】実施例 ２ スクラブ材（Ｂ）として、比重が0.92のポリエチレン
と、比重が約1.33で平均粒径が約６μｍのシリコン粉末
との66：34の割合の混合物を約10倍量のキシレンに溶解
し、溶解沈殿法によってシリコン含有ポリエチレン複合
樹脂粉末を沈殿させた。これを分離して粒子径が約18μ
ｍで平均比重が約 1.028の複合樹脂微粉末スクラブ材
（Ｂ）を調製した。これを用いて、下記組成のスクラブ
洗浄剤を調製した。Example 2 As a scrubbing material (B), a mixture of polyethylene having a specific gravity of 0.92 and silicon powder having a specific gravity of about 1.33 and an average particle size of about 6 μm in a ratio of 66:34 was used in about 10 times the amount of xylene. And the silicon-containing polyethylene composite resin powder was precipitated by the dissolution precipitation method. This is separated and the particle size is about 18μ
A composite resin fine powder scrubbing material (B) having an average specific gravity of about 1.028 in m was prepared. Using this, a scrub cleaning agent having the following composition was prepared.
【００１９】 配 合 成 分 配合量（ｇ） Ｎラウリルグルタミン酸トリエタノ−ルアミン ２００ Ｎラウリルメチルタウリンナトリウム １００ ラウリン酸トリエタノ−ルアミン １００ ミリスチン酸トリエタノ−ルアミン １００ ラウリルイミダゾリウムベタイン ５０ プロピレングリコ−ル ６０ 上記スクラブ材（Ｂ） ５０（約５重量％) 防腐剤，キレ−ト剤，着色剤等 各少量 精 製 水 ３４０[0019] Constitutive Ingredients amount (g) N-lauryl glutamate triethanolamine - triethanolamine 200 N lauryl methyl taurate, sodium 100 laurate triethanolamine - triethanolamine 100 myristic acid triethanolamine - triethanolamine 100 lauryl imidazolium betaine 50 propylene glycol - le 60 above scrubbing material (B) 50 (about 5% by weight) Preservatives, chelating agents, coloring agents, etc. Small amounts Purified water 340
【００２０】比較例 １及び２ 実施例１において、複合樹脂微粉末スクラブ材に換え
て、約60μｍの大きさのくるみの粉末スクラブ材（Ｃ）
又は平均粒径が約20μｍのポリエチレン粉末スクラブ材
（Ｄ）をそれぞれ５重量％用いたほかは全く同様にし
て、液状スクラブ洗浄剤を調製し、それらの分散安定性
及びスクラブ材感と調べた。調査結果を前記実施例１及
び２のそれらと共に、下掲表１にまとめて示す。Comparative Examples 1 and 2 In Example 1, instead of the composite resin fine powder scrub material, a walnut powder scrub material (C) having a size of about 60 μm was used.
Alternatively, liquid scrub cleaners were prepared in exactly the same manner except that polyethylene powder scrubbing material (D) having an average particle diameter of about 20 μm was used in an amount of 5% by weight, and their dispersion stability and scrubbing material feel were examined. The results of the investigation are shown together with those of Examples 1 and 2 in Table 1 below.
【００２１】[0021]
【表１】 具 体 例 スクラブ材 分散安定性 スクラブ感 実施例１ （Ａ） 良 好 良 好 〃 ２ （Ｂ） 良 好 良 好 比較例１ （Ｃ） 不 可 可 〃 ２ （Ｄ） 不 可 良 好 表中の比較例１の分散安定性の不可は、くるみの粉末が
沈降し、また比較例２の分散安定性の不可は、ポリエチ
レン粉末が洗浄剤の上部に浮上した。[Table 1] Sample body Scrub Dispersion stability Scrub feeling Example 1 (A) Good Good Good Good 〃 2 (B) Good Good Good Good Good Comparative Example 1 (C) No Yes 〃 2 (D) No Good Good In the table of Comparative Example 1 where the dispersion stability was not good, the walnut powder was precipitated, and in the case of Comparative Example 2 where the dispersion stability was not good, the polyethylene powder floated above the detergent.
【００２２】[0022]
【発明の効果】上表からも明らかなように、本発明の液
状スクラブ洗浄剤は、優れた分散安定性を有するので長
期にわたって高い品質及び洗浄効果が確保され、高い商
品価値が保持されるばかりでなく、使用対象に応じて所
望素材のスクラブ材が選択使用でき、また、その所望素
材のスクラブ材の粒度を自由に選択することができるの
で優れた実用性と産業上の利用性を有する。As is clear from the above table, the liquid scrubbing agent of the present invention has excellent dispersion stability, so that high quality and cleaning effect are secured for a long period of time, and high commercial value is maintained. Not only that, the scrubbing material of the desired material can be selectively used according to the intended use, and the particle size of the scrubbing material of the desired material can be freely selected, so that it has excellent practicality and industrial applicability.
Claims (3)
粉末を含有せしめて成る複合樹脂粉末であって、その平
均真比重が0.95〜1.10の範囲に調整された複合樹脂粉末
をスクラブ材として水性液状洗浄剤中に含有せしめて成
る液状スクラブ洗浄剤。1. A composite resin powder comprising a synthetic resin containing an inorganic powder and / or an organic powder, the composite resin powder having an average true specific gravity adjusted to a range of 0.95 to 1.10. A liquid scrub cleaner that is contained in a cleaner.
ロピレン等のポリオレフィン又はポリアミド系樹脂を主
剤とし、無機質及び有機質の粉末が、炭酸カルシウム，
シリカ，ゼオライト，水酸化アルミニウム，ベントナイ
ト，木粉，セルロ−ス，キトサン，シリコン樹脂，エポ
キシ樹脂，ポリエステル樹脂及びアクリル樹脂より成る
群から選択される請求項１に記載の液状スクラブ洗浄
剤。2. The synthetic resin is a polyolefin or polyamide resin such as polyethylene or polypropylene as a main component, and the inorganic and organic powders are calcium carbonate,
The liquid scrub cleaner according to claim 1, which is selected from the group consisting of silica, zeolite, aluminum hydroxide, bentonite, wood powder, cellulose, chitosan, silicone resin, epoxy resin, polyester resin and acrylic resin.
又は機械粉砕法によって粒径 1.0〜1000μｍの範囲に調
製された請求項１又は２に記載の液状スクラブ洗浄剤。3. The liquid scrub cleaning agent according to claim 1, wherein the composite resin powder scrubbing material is prepared in a particle size range of 1.0 to 1000 μm by a dissolution precipitation method or a mechanical grinding method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10047494A JPH07304651A (en) | 1994-05-16 | 1994-05-16 | Liquid detergent for scrubbing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10047494A JPH07304651A (en) | 1994-05-16 | 1994-05-16 | Liquid detergent for scrubbing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07304651A true JPH07304651A (en) | 1995-11-21 |
Family
ID=14274917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10047494A Ceased JPH07304651A (en) | 1994-05-16 | 1994-05-16 | Liquid detergent for scrubbing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07304651A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0894850A1 (en) * | 1997-08-01 | 1999-02-03 | Martini S.p.A. | Detergent composition and means which comprises it |
| KR20010047891A (en) * | 1999-11-23 | 2001-06-15 | 임범수 | Mud |
| US8017046B2 (en) | 2000-06-30 | 2011-09-13 | Kao Corporation | Skin cosmetic composition |
| JP2013515150A (en) * | 2009-12-22 | 2013-05-02 | ザ プロクター アンド ギャンブル カンパニー | Liquid cleaning and / or cleansing composition |
| JP6074492B1 (en) * | 2015-12-24 | 2017-02-01 | 資生堂ホネケーキ工業株式会社 | Granulated powder |
| JP2018199787A (en) * | 2017-05-29 | 2018-12-20 | 株式会社ニイタカ | Detergent composition for circulation type automatic washing machine |
-
1994
- 1994-05-16 JP JP10047494A patent/JPH07304651A/en not_active Ceased
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0894850A1 (en) * | 1997-08-01 | 1999-02-03 | Martini S.p.A. | Detergent composition and means which comprises it |
| KR20010047891A (en) * | 1999-11-23 | 2001-06-15 | 임범수 | Mud |
| US8017046B2 (en) | 2000-06-30 | 2011-09-13 | Kao Corporation | Skin cosmetic composition |
| JP2013515150A (en) * | 2009-12-22 | 2013-05-02 | ザ プロクター アンド ギャンブル カンパニー | Liquid cleaning and / or cleansing composition |
| JP6074492B1 (en) * | 2015-12-24 | 2017-02-01 | 資生堂ホネケーキ工業株式会社 | Granulated powder |
| JP2018199787A (en) * | 2017-05-29 | 2018-12-20 | 株式会社ニイタカ | Detergent composition for circulation type automatic washing machine |
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