JPH07118689A - Cleaning agent composition for hard surface - Google Patents
Cleaning agent composition for hard surfaceInfo
- Publication number
- JPH07118689A JPH07118689A JP29376793A JP29376793A JPH07118689A JP H07118689 A JPH07118689 A JP H07118689A JP 29376793 A JP29376793 A JP 29376793A JP 29376793 A JP29376793 A JP 29376793A JP H07118689 A JPH07118689 A JP H07118689A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- group
- hard surface
- cleaning
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、金属、ガラス、陶磁
器、プラスチック等の硬表面に付着しているあらゆる汚
れも容易に除去することが出来る洗浄剤、特に洗浄機を
利用した洗浄に好適な洗浄剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is suitable for cleaning agents capable of easily removing any dirt adhering to hard surfaces such as metal, glass, ceramics, plastics, etc., and particularly suitable for cleaning using a cleaning machine. Detergent composition.
【０００２】[0002]
【従来の技術】近年、人手不足、労働環境の整備、衛生
管理の充実等の観点からホテル、レストラン、給食セン
ター等での食器洗浄が洗浄機により自動化されている。
また食肉、水産物及び農産物等の加工工場、乳製品、飲
料品等の製造工場の部品、設備の洗浄および、食品流通
分野で用いられるコンテナの洗浄等においても機械化、
自動化が急速に普及している。特に、食器洗浄分野にお
いては、生活様式の変化、食生活の欧米化に伴い、メニ
ューも多様化しており、油汚れ、蛋白汚れの付着が増加
傾向にある。さらに、食器類も金彩模様を配したもの、
クリスタルグラスなどの高級品の使用頻度が高まってい
る。2. Description of the Related Art In recent years, dishwashers in hotels, restaurants, lunch centers and the like have been automated by washing machines from the viewpoints of labor shortage, maintenance of working environment, enhancement of hygiene management and the like.
In addition, mechanization in the processing of meat, marine products and agricultural products, the parts and facilities of manufacturing plants for dairy products and beverages, and the cleaning of containers used in the food distribution field, etc.
Automation is spreading rapidly. Especially in the field of dishwashing, the menu is diversifying with the change of lifestyle and the westernization of eating habits, and the adhesion of oil stains and protein stains tends to increase. Furthermore, the tableware also has a golden pattern,
The frequency of using high-end products such as crystal glasses is increasing.
【０００３】従来、これらの物を手で洗浄する場合は、
陰イオン界面活性剤、陽イオン界面活性剤、両性界面活
性剤、非イオン界面活性剤またはその混合物を主成分と
した洗浄剤が用いられていた。これらの洗浄剤は、洗浄
能及び起泡性に優れているが、洗浄機で用いた場合、洗
浄液を供給するポンプ中に多量の泡が発生して、ポンプ
の運転に支障を与えたり、被洗物に対する噴霧力が弱
く、十分な洗浄能を発揮しない。併せて、濯ぎに多量の
水と時間を要して経済性に欠けるという問題がある。Conventionally, when cleaning these items by hand,
Detergents based on anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants or mixtures thereof have been used. Although these cleaning agents have excellent cleaning ability and foaming ability, when used in a cleaning machine, a large amount of foam is generated in the pump that supplies the cleaning liquid, which may hinder the operation of the pump or cause damage to the pump. The spray force on the wash is weak, and the washing performance is not sufficient. At the same time, there is a problem that rinsing requires a large amount of water and a lot of time, which is not economical.
【０００４】このような問題点を考慮して、洗浄機を利
用した、硬表面洗浄剤で油汚れの洗浄除去を主点として
いるものとしては、苛性アルカリと水溶性グリコールエ
ーテルからなる洗浄剤（特開昭６１−２９６０９７号公
報）、苛性アルカリと水溶性アルカノールアミンからな
る洗浄剤（特開昭６１−２９６０９８号公報）がある。
界面活性剤の洗浄能を主点としたものとしては、非イオ
ン界面活性剤から成る洗浄剤（特開昭６２−５０３９
７、特公平２−３３７６０）等がある。In view of these problems, the main purpose of cleaning and removing oil stains with a hard surface cleaning agent using a cleaning machine is a cleaning agent composed of caustic alkali and water-soluble glycol ether ( JP-A-61-296097) and a detergent comprising a caustic alkali and a water-soluble alkanolamine (JP-A-61-296098).
The main point of the cleaning ability of the surfactant is a cleaning agent composed of a nonionic surfactant (JP-A-62-5039).
7 and Japanese Patent Publication No. 2-33760).
【０００５】多価金属イオンのキレート能と洗浄能を主
点としたものとして、トリポリ燐酸塩、珪酸塩、苛性カ
リ、次亜塩素酸塩、水から成る液体洗浄剤（特開昭６２
−５０３９９号公報）、苛性アルカリ、トリポリ燐酸ナ
トリウム、珪酸塩、高分子物質を含有する洗浄剤（特開
昭６３−３７８３８号公報）、苛性アルカリと２−ヒド
ロキシエチルイミノジ酢酸塩等から成る洗浄剤組成物
（特公平２−２７３９７号公報）、苛性アルカリとニト
リロトリ酢酸のアルカリ金属塩等から成る洗浄剤組成物
（特公平３−６０３５８号公報）、苛性アルカリ、ポリ
アクリル酸塩と特定の水から成る自動食器洗浄機用洗浄
剤（特開平４−１５２９９号公報）がある。カルシウム
補足キレート能と洗浄能を主点としてものとして、非イ
オン界面活性剤、キレート剤及び酵素から成る自動食器
洗浄機用洗浄剤組成物（特開平４−７２３９８号公報、
特開平４−７２３９７号公報、特開平４−７２３９８号
公報）等の技術が報告されている。しかしながらこれ等
の方法では、食器に付着する食物由来の汚染物を洗浄機
だけで簡単に除去できない上に、グラス類の侵食及び白
化、陶磁器を彩る模様の剥落、さらには洗浄機へのスケ
ールの付着などの問題がある。A liquid detergent comprising tripolyphosphate, silicate, caustic potash, hypochlorite, and water, which mainly has chelating ability and washing ability for polyvalent metal ions (Japanese Patent Laid-Open No. Sho 62-62).
No. -50399), a caustic alkali, sodium tripolyphosphate, a silicate, a detergent containing a polymer substance (Japanese Patent Laid-Open No. 63-37838), and a cleaning comprising caustic alkali and 2-hydroxyethyliminodiacetic acid salt. Agent composition (Japanese Patent Publication No. 2-27397), a detergent composition comprising caustic alkali and an alkali metal salt of nitrilotriacetic acid, etc. (Japanese Patent Publication No. 3-60358), caustic alkali, polyacrylic acid salt and specific water There is a cleaning agent for an automatic dishwashing machine (JP-A-4-15299). A detergent composition for an automatic dishwasher, which is mainly composed of calcium-supplementing chelating ability and washing ability and comprises a nonionic surfactant, a chelating agent and an enzyme (Japanese Patent Laid-Open No. 4-72398,
Techniques such as JP-A-4-72397 and JP-A-4-72398) have been reported. However, these methods cannot easily remove food-derived contaminants adhering to tableware with a washing machine alone, in addition to eroding and whitening of glasses, peeling of patterns that decorate ceramics, and even the scale of washing machines. There is a problem such as adhesion.
【０００６】[0006]
【発明が解決しようとする課題】本発明は、金属、ガラ
ス、陶磁器、プラスチック等の硬表面に付着している種
々の汚れも容易に除去することが出来る洗浄剤を提供す
るものである。特に油汚れに対する洗浄力及び再汚染防
止効果に優れ、食器類に対する侵食、劣化を防止し、ス
ケール付着抑制能を有する、洗浄機を利用した洗浄に好
適な硬表面洗浄剤組成物を提供するものである。DISCLOSURE OF THE INVENTION The present invention provides a cleaning agent which can easily remove various stains adhering to a hard surface such as metal, glass, ceramics and plastics. In particular, it provides a hard surface cleaner composition suitable for cleaning using a cleaning machine, which has excellent cleaning power against oil stains and recontamination prevention effect, prevents erosion and deterioration of tableware, and has a scale adhesion suppressing ability. Is.
【０００７】[0007]
【課題を解決するための手段】本発明の硬表面洗浄剤組
成物は、以下の（ａ），（ｂ）および（ｃ）成分、ある
いはは、更に（ｄ）成分を含有することを特徴とする。 （ａ） アルカリ剤。 （ｂ） 下記一般式（３）で表わされる界面活性剤。 Ｒ１Ｏ（ＥＯ）ｎ（ＰＯ）ｍＲ２ （３） （Ｒ１：炭素数６〜２４の直鎖或いは分岐のアルキル
基、アルケニル基もしくはアルキルフェニル基 Ｒ２：炭素数１〜８の直鎖或いは分岐のアルキル基もし
くはアルキルフェニル基 ＥＯ：エチエレンオキサイド ＰＯ：プロピレンオキサイド ｎ，ｍ：０〜１０ ＥＯ，ＰＯを付加する場合は、ランダム付加でもブロッ
ク付加でもよい。） （Ｃ） 下記一般式（４）で表わされるマレイン酸もし
くは無水マレイン酸のホモポリマー又はこれらと共重合
可能な単量体から得られるコーポリマー或いはこれらの
ポリマーの水溶性塩。 （Ｒ１，Ｒ２，Ｒ３，Ｒ４：水素又は炭素数１〜５のア
ルキル基、フェニル基、アルコキシル基またはカルボキ
シル基 Ｍ：水素、アルカリ金属または有機アミン ｘ／ｙ（共重合モル比）＝１／１０〜１０／１ 重量平均分子量：１，０００〜１００，０００） （ｄ） 賦形剤The hard surface cleaning composition of the present invention is characterized by containing the following components (a), (b) and (c), or further a component (d). To do. (A) Alkaline agent. (B) A surfactant represented by the following general formula (3). R 1 O (EO) n (PO) mR 2 (3) (R 1 : a straight-chain or branched alkyl group having 6 to 24 carbon atoms, an alkenyl group or an alkylphenyl group R 2 : a straight chain having 1 to 8 carbon atoms Alternatively, branched alkyl group or alkylphenyl group EO: Ethylene oxide PO: Propylene oxide n, m: 0 to 10 When adding EO, PO, random addition or block addition may be performed.) (C) The following general formula ( A homopolymer of maleic acid or maleic anhydride represented by 4), a copolymer obtained from a monomer copolymerizable therewith, or a water-soluble salt of these polymers. (R 1, R 2, R 3, R 4: a hydrogen or an alkyl group having 1 to 5 carbon atoms, a phenyl group, an alkoxyl group or a carboxyl group M: hydrogen, an alkali metal or an organic amine x / y (copolymerization molar ratio) = 1/10 to 10/1 weight average molecular weight: 1,000 to 100,000) (d) Excipient
【０００８】[0008]
【発明の実施態様】（ａ）成分のアルカリ剤としては、
苛性ソーダ、苛性カリ等の苛性アルカリ金属塩が好適に
用いられ、炭酸ソーダ、炭酸カリ、珪酸ソーダ、珪酸カ
リ等も使用できる。（ａ）成分のアルカリ剤は、洗浄剤
組成物中に０．５〜５０重量％配合することが好適で、
より好ましくは０．５重量％以上〜３０重量％未満であ
る。BEST MODE FOR CARRYING OUT THE INVENTION As the alkaline agent as the component (a),
Caustic alkali metal salts such as caustic soda and caustic potassium are preferably used, and sodium carbonate, potassium carbonate, sodium silicate, potassium silicate and the like can also be used. The alkaline agent as the component (a) is preferably added to the detergent composition in an amount of 0.5 to 50% by weight,
More preferably, it is 0.5% by weight or more and less than 30% by weight.
【０００９】（ｂ）成分の界面活性剤としては、下記一
般式（５）で表わされる界面活性剤を洗浄剤組成物中に
０．１〜２０重量％配合する。 Ｒ１Ｏ（ＥＯ）ｎ（ＰＯ）ｍＲ２ （５） （Ｒ１：炭素数６〜２４の直鎖或いは分岐のアルキル
基、アルケニル基もしくはアルキルフェニル基 Ｒ２：炭素数１〜８の直鎖或いは分岐のアルキル基もし
くはアルキルフェニル基 ＥＯ：エチエレンオキサイド ＰＯ：プロピレンオキサイド ｎ，ｍ：０〜１０ ＥＯ，ＰＯを付加する場合は、ランダム付加でもブロッ
ク付加でもよい。）As the component (b) surfactant, 0.1 to 20% by weight of a surfactant represented by the following general formula (5) is added to the detergent composition. R 1 O (EO) n (PO) mR 2 (5) (R 1 : linear or branched alkyl group having 6 to 24 carbon atoms, alkenyl group or alkylphenyl group R 2 : linear chain having 1 to 8 carbon atoms Alternatively, a branched alkyl group or an alkylphenyl group EO: ethylene oxide PO: propylene oxide n, m: 0 to 10 When EO, PO is added, it may be random addition or block addition.)
【００１０】（Ｃ）成分としては 下記一般式（６）で
表わされるマレイン酸もしくは無水マレイン酸のホモポ
リマー又はこれらと共重合可能な単量体から得られるコ
ーポリマー或いはこれらのポリマーの水溶性塩；０．５
〜３０重量％を洗浄剤組成物中に配合する。 （Ｒ１，Ｒ２，Ｒ３，Ｒ４：水素又は炭素数１〜５のア
ルキル基、フェニル基、アルコキシル基またはカルボキ
シル基 Ｍ：水素、アルカリ金属または有機アミン ｘ／ｙ（共重合モル比）＝１／１０〜１０／１ 重量平均分子量：１，０００〜１００，０００）As the component (C), a homopolymer of maleic acid or maleic anhydride represented by the following general formula (6), a copolymer obtained from a monomer copolymerizable therewith, or a water-soluble salt of these polymers is used. ; 0.5
-30% by weight is incorporated into the detergent composition. (R 1, R 2, R 3, R 4: a hydrogen or an alkyl group having 1 to 5 carbon atoms, a phenyl group, an alkoxyl group or a carboxyl group M: hydrogen, an alkali metal or an organic amine x / y (copolymerization molar ratio) = 1/10 to 10/1 weight average molecular weight: 1,000 to 100,000)
【００１１】本発明の硬表面洗浄剤組成物は、液体、ス
ラリー状、粉粒体、固体等で、特に剤形は限定されない
が、使用者の取扱い易さ及び安全性の点より、スラリー
状或いは固体タイプが好適である。スラリー状及び固体
にする為、（ｄ）成分の賦形剤としては、賦形化できる
ものであれば特に限定されるものでないが、リン酸塩、
珪酸塩、硫酸塩、炭酸塩、塩酸塩等の無機塩類及び又は
エチレングリコール、プロピレングリコール、ポリエチ
レングリコール、ジエチレングリコールモノエチルエー
テル、プロピレングリコールモノプロピルエーテル等の
グリコール類が好適に用いられ、洗浄剤組成物中１〜８
０重量％配合することが好適で、より好ましくは５〜７
０重量％であり、生産性の点から無機塩とグリコール類
を併用することがより好ましい。The hard surface cleaning composition of the present invention is a liquid, a slurry, a powder or a solid, and the like, and the dosage form is not particularly limited, but from the viewpoint of ease of handling by the user and safety, it is a slurry. Alternatively, the solid type is suitable. In order to form a slurry and a solid, the excipient of the component (d) is not particularly limited as long as it can be shaped, but phosphate,
Inorganic salts such as silicates, sulfates, carbonates and hydrochlorides and / or glycols such as ethylene glycol, propylene glycol, polyethylene glycol, diethylene glycol monoethyl ether and propylene glycol monopropyl ether are preferably used, and a detergent composition Medium 1-8
It is preferable to add 0% by weight, more preferably 5 to 7
It is 0% by weight, and it is more preferable to use an inorganic salt and a glycol in combination from the viewpoint of productivity.
【００１２】本発明の硬表面洗浄剤組成物中において、
前記必須成分の他に任意成分として、例えばエチレンジ
アミンテトラ酢酸ナトリウム、ニトリロ酢酸カリウム、
クエン酸、リンゴ酸等のキレート剤、界面活性剤、色
素、香料、酵素、酸化剤等も配合することが可能であ
る。In the hard surface cleaning composition of the present invention,
As an optional component in addition to the above essential components, for example, sodium ethylenediaminetetraacetate, potassium nitriloacetate,
A chelating agent such as citric acid and malic acid, a surfactant, a dye, a fragrance, an enzyme, an oxidant, etc. can be added.
【００１３】[0013]
【発明の効果】本発明によれば、（ａ）アルカリ剤と
（ｂ）特定の界面活性剤と（ｃ）特定の高分子物質を配
合して硬表面洗浄剤組成物とすることで、油汚れに対す
る洗浄力及び再汚染防止効果の優れた性能を有し、かつ
食器類の白化、侵食等の劣化防止、及びスケール付着を
抑制することが出来る。According to the present invention, (a) an alkaline agent, (b) a specific surfactant, and (c) a specific polymer substance are blended to form a hard surface cleaning composition, whereby an oil is prepared. It has excellent performance of cleaning power against dirt and anti-redeposition effect, and can prevent whitening of tableware, deterioration such as erosion, and suppress scale adhesion.
【００１４】また、本発明によれば、更に、（ｄ）賦形
剤を併用することでスラリー状及び固体となり、使用者
の取扱い易さ、安全性を確保することが出来る。Further, according to the present invention, by further using (d) an excipient, it becomes a slurry or a solid, and the easiness of handling and safety by the user can be secured.
【００１５】[0015]
【実施例】表１に（ｂ）成分である特定界面活性剤と表
２に（ｃ）成分である特定高分子物質を示す。これらを
配合した各組成の硬表面洗浄剤組成物を調整し、実施例
で採用した洗浄性能、機械の作動性、金彩磁器及びクリ
スタルグラスへの影響、スケール付着抑制能の評価方法
を示す。EXAMPLES Table 1 shows the specific surfactant as the component (b) and Table 2 shows the specific polymer substance as the component (c). The hard surface cleaning composition of each composition containing these is prepared, and the evaluation method of the cleaning performance, machine operability, influence on gold porcelain and crystal glass, and scale adhesion suppressing ability adopted in the examples is shown.
【００１６】[0016]
【表１】 [Table 1]
【００１７】[0017]
【表２】 [Table 2]
【００１８】（１）．洗浄性能 洗浄機として１ドア式の業務用食器洗浄機（ＩＨＩ製，
Ｄ−６型）を用いて、油汚れ（バターを塗った
皿）、蛋白汚れ（卵黄を塗った皿）で、通常の洗浄条
件（洗浄温度；６０℃，洗浄濃度；０．２％，洗浄時
間；４０ｓｅｃ．濯ぎ温度；８０℃，濯ぎ時間；１５ｓ
ｅｃ．）で洗浄し、乾燥後、目視判定する。 判定基準 ◎；汚れが完全に除去された。 ；汚れが殆ど除去された。 Δ；汚れの除去が不十分である。 ×；汚れが殆ど除去されない。(1). Washing performance As a washing machine, a one-door type dishwasher for professional use (made by IHI,
D-6 type) with oil stains (buttered dish) and protein stains (yolk coated dish) under normal washing conditions (washing temperature: 60 ° C, washing concentration: 0.2%, washing) Time: 40 sec. Rinse temperature: 80 ° C, rinse time: 15 s
ec. ), And then visually judge after drying. Criteria ⊚: Soil was completely removed. Most of the dirt was removed. Δ: Insufficient removal of dirt. X: Soil is hardly removed.
【００１９】（２）．機械の作動性 前記の洗浄性能を評価する際、機械の作動性を同時に評
価する。 判定基準 ◎；泡立ちが殆ど無く洗浄機の運転に支
障がない。 ；泡立ちが若干有るが洗浄機の運転に支障がない。 Δ；泡立ちが有り洗浄機の運転に若干支障あり。 ×；泡立ちが多く洗浄機の運転に支障あり。(2). Machine operability When evaluating the cleaning performance, the machine operability is evaluated at the same time. Judgment criteria ◎: There is almost no foaming and there is no hindrance to the operation of the washing machine. There is some foaming, but it does not hinder the operation of the washing machine. Δ: Foaming occurred and operation of the washing machine was slightly hindered. X: A lot of foaming occurred and hindered the operation of the washing machine.
【００２０】（３）．クリスタルグラスへの影響 水道水（ＣａＯ；５０ｐｐｍ）を用い、食器洗浄条件と
同じ（洗浄剤濃度；０．２％，洗浄温度；６０℃）洗浄
液を調製し、この中に金彩磁器及びクリスタルグラスを
１週間浸漬し、表面状態の変化を目視判定する。 判定基準 ◎；全然変化なし。 ；殆ど変化なし。 Δ；若干白濁が認められる。 ×；白濁が激しい。(3). Effect on crystal glass Using tap water (CaO; 50ppm), prepare the same cleaning solution as the dish washing conditions (cleaner concentration; 0.2%, cleaning temperature; 60 ° C), and add gold porcelain and crystal glass to it. After soaking for 1 week, the change in surface condition is visually judged. Judgment criteria ◎: No change at all. There is almost no change. Δ: Some cloudiness is observed. X: White turbidity is severe.
【００２１】（４）．金彩磁器への影響 水道水（ＣａＯ；５０ｐｐｍ）を用い、食器洗浄条件と
同じ（洗浄剤濃度；０．２％，洗浄温度；６０℃）洗浄
液を調製し、この中に金彩磁器及びクリスタルグラスを
１週間浸漬し、表面状態の変化を目視判定する。 判定基準 ◎；全然変化なし。 ；殆ど変化なし。 Δ；若干彩色変化が認められる。 ×；彩色低下が激しい。(4). Effect on gold porcelain Using tap water (CaO; 50 ppm), the same washing solution as the dishwashing conditions (cleaner concentration; 0.2%, washing temperature; 60 ° C) was prepared, and gold porcelain and crystal glass were placed in this washing liquid. After soaking for 1 week, the change in surface condition is visually judged. Judgment criteria ◎: No change at all. There is almost no change. Δ: A slight color change is recognized. ×: The coloring is severely deteriorated.
【００２２】（５）．スケール付着抑制能 水道水（ＣａＯ；５０ｐｐｍ）を用い、食器洗浄機の濯
ぎ工程と同様の濃度（０．０１〜０．００１％）の洗浄
液を調製し、１００ｍｌのＳＵＳ３０４製のステンレス
ビーカーに入れ、８０℃温浴で蒸発乾固させ、水道水で
洗浄後、スケール付着量を測定した 判定基準 ◎；スケール付着なし。 ；スケール付着が殆どなし。 Δ；スケール付着があり。 ×；スケール付着が著しい。(5). Scale Adhesion Inhibition Ability Using tap water (CaO; 50 ppm), prepare a cleaning solution having the same concentration (0.01 to 0.001%) as in the dishwasher rinsing step, and put it in a 100 ml SUS304 stainless beaker, After evaporating to dryness in a 80 ° C warm bath and washing with tap water, the amount of scale adherence was measured. Judgment standard ◎; No scale adherence. There is almost no scale adhesion. Δ: There is scale adhesion. X: Scale adhesion is remarkable.
【００２３】実施例１〜６ 表３に示した組成の各洗浄剤組成物を調製し、洗浄性能
の内、油汚れ、蛋白汚れ、および機械の作動性を評価
し、比較例１〜３と併せて結果を表３に示した。Examples 1 to 6 Each cleaning composition having the composition shown in Table 3 was prepared and the cleaning performance was evaluated for oil stains, protein stains, and machine operability. The results are also shown in Table 3.
【００２４】[0024]
【表３】 [Table 3]
【００２５】[0025]
【表４−１】 [Table 4-1]
【００２６】表３に示す通り、界面活性剤を含まない比
較例１、２は当然ながら油汚れ除去が劣り、界面活性剤
を含む比較例３は泡立ちが多く機械の作動性が劣る。高
分子物質を含まない比較例１〜３はクリスタルグラスの
白濁、金彩の低下を招く。それに比較して各実施例は各
評価項目において良い結果を得ている。As shown in Table 3, Comparative Examples 1 and 2 containing no surfactant are inferior in the removal of oil stains, and Comparative Example 3 containing a surfactant is liable to foam and inferior in machine operability. Comparative Examples 1 to 3, which do not contain a polymer substance, cause cloudiness of crystal glass and deterioration of gold color. In comparison, each of the examples has a good result in each evaluation item.
【００２７】実施例７〜１６ 表４−２に示した組成の各洗浄剤組成物を調製し、洗浄
性能の内、油汚れ、蛋白汚れ、金彩磁器、クリスタルグ
ラスへの影響、スケール付着抑制能、および機械の作動
性を評価し、その結果を表４−２に示した。また併せて
（ｂ）、（ｃ）成分を含まない比較例４〜８の評価結果
を表４−１に示した。Examples 7 to 16 Each cleaning composition having the composition shown in Table 4-2 was prepared, and among cleaning performances, oil stains, protein stains, gold porcelain, influence on crystal glass, and scale adhesion inhibiting ability. , And the operability of the machine were evaluated, and the results are shown in Table 4-2. In addition, the evaluation results of Comparative Examples 4 to 8 not containing the components (b) and (c) are shown in Table 4-1.
【００２８】表４−１に示す通り、界面活性剤を含まな
い比較例４、５、６、８は当然ながら油汚れ除去に劣
り、界面活性剤を含む比較例７は泡立ちが多く機械の作
動性に劣る。高分子物質を含まない比較例４〜７はクリ
スタルグラスの白濁、金彩の低下を招く。それに比較し
て表４−２に示す通各実施例は各評価項目において良い
結果を得ている。As shown in Table 4-1, Comparative Examples 4, 5, 6 and 8 not containing a surfactant are naturally inferior in removing oil stains, and Comparative Example 7 containing a surfactant has a lot of foaming and operates the machine. Inferior in sex. Comparative Examples 4 to 7, which do not contain a polymer substance, cause cloudiness of crystal glass and deterioration of gold color. In comparison, in each of the examples shown in Table 4-2, good results are obtained in each evaluation item.
【００２９】実施例１７〜２２ 表５に示した組成の各洗浄剤組成物を調製し、洗浄性能
の内、油汚れ、蛋白汚れ金彩磁器、クリスタルグラスへ
の影響、スケール付着抑制能、および機械の作動性を評
価し、その結果を表５に示した。Examples 17 to 22 Each cleaning composition having the composition shown in Table 5 was prepared, and among the cleaning performances, oil stains, protein stains, gold porcelain, influence on crystal glass, scale adhesion inhibiting ability, and mechanical properties. Was evaluated, and the results are shown in Table 5.
【００３０】[0030]
【表４−２】 [Table 4-2]
【００３１】スラリー状及び固体タイプ硬表面洗浄剤組
成物の製造方法は、イオン交換水を攪拌しながら、
（ａ）成分のアルカリ剤を添加し、８０℃に保温しなが
ら（ｂ）成分の特定界面活性剤、（ｃ）成分の特定高分
子物質、（ｄ）成分の賦形剤の順に投入し、均一になっ
たら容器に注いで室温で放冷し、スラリー状及び固体タ
イプの硬表面洗浄剤組成物を得た。The method for producing a slurry type or solid type hard surface cleaner composition is as follows:
While adding the alkaline agent of the component (a) and keeping the temperature at 80 ° C., the specific surfactant of the component (b), the specific polymer substance of the component (c), and the excipient of the component (d) are added in this order. When it became uniform, it was poured into a container and allowed to cool at room temperature to obtain a slurry type and solid type hard surface cleaning composition.
【００３２】[0032]
【表５】 [Table 5]
Claims (2)
％、 （ｂ） 下記一般式（１）で表わされる界面活性剤を
０．１〜２０重量％および Ｒ１Ｏ（ＥＯ）ｎ（ＰＯ）ｍＲ２ （１） （Ｒ１：炭素数６〜２４の直鎖或いは分岐のアルキル
基、アルケニル基もしくはアルキルフェニル基 Ｒ２：炭素数１〜８の直鎖或いは分岐のアルキル基もし
くはアルキルフェニル基 ＥＯ：エチエレンオキサイド ＰＯ：プロピレンオキサイド ｎ，ｍ：０〜１０ ＥＯ，ＰＯを付加する場合は、ランダム付加でもブロッ
ク付加でもよい。） （Ｃ） 下記一般式（２）で表わされるマレイン酸もし
くは無水マレイン酸のホモポリマー又はこれらと共重合
可能な単量体から得られるコーポリマー或いはこれらの
ポリマーの水溶性塩を０．５〜３０重量％含有すること
を特徴とする硬表面洗浄剤組成物。 （Ｒ１，Ｒ２，Ｒ３，Ｒ４：水素又は炭素数１〜５のア
ルキル基、フェニル基、アルコキシル基またはカルボキ
シル基 Ｍ：水素、アルカリ金属または有機アミン ｘ／ｙ（共重合モル比）＝１／１０〜１０／１ 重量平均分子量：１，０００〜１００，０００）(A) 0.5 to 50% by weight of an alkaline agent, (b) 0.1 to 20% by weight of a surfactant represented by the following general formula (1) and R 1 O (EO) n. (PO) mR 2 (1) (R 1 : a linear or branched alkyl group, alkenyl group or alkylphenyl group having 6 to 24 carbon atoms R 2 : a linear or branched alkyl group or alkyl group having 1 to 8 carbon atoms Phenyl group EO: Ethylene oxide PO: Propylene oxide n, m: 0-10 When adding EO, PO, it may be random addition or block addition.) (C) Maleic acid represented by the following general formula (2) Or a homopolymer of maleic anhydride, a copolymer obtained from a monomer copolymerizable therewith, or a water-soluble salt of these polymers in an amount of 0.5 to 30% by weight. Hard surface cleaner composition characterized. (R 1, R 2, R 3, R 4: a hydrogen or an alkyl group having 1 to 5 carbon atoms, a phenyl group, an alkoxyl group or a carboxyl group M: hydrogen, an alkali metal or an organic amine x / y (copolymerization molar ratio) = 1/10 to 10/1 weight average molecular weight: 1,000 to 100,000)
０．５重量％以上、３０重量％未満、 上記（ｂ）成分
を０．１〜２０重量％、と（Ｃ）成分０．１〜２０重量
％および（ｄ） 賦形剤を１〜８０重量％含有すること
を特徴とするスラリー状または固体タイプ硬表面洗浄剤
組成物。2. (a) 0.5% by weight or more and less than 30% by weight of caustic soda and / or caustic potash, 0.1-20% by weight of the component (b), and 0.1-20% of the component (C). %, And (d) 1 to 80% by weight of an excipient, a slurry-like or solid type hard surface cleaner composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29376793A JPH07118689A (en) | 1993-10-20 | 1993-10-20 | Cleaning agent composition for hard surface |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29376793A JPH07118689A (en) | 1993-10-20 | 1993-10-20 | Cleaning agent composition for hard surface |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07118689A true JPH07118689A (en) | 1995-05-09 |
Family
ID=17798953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29376793A Pending JPH07118689A (en) | 1993-10-20 | 1993-10-20 | Cleaning agent composition for hard surface |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07118689A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997006232A1 (en) * | 1995-08-07 | 1997-02-20 | Unilever Plc | Improvements relating to hard surface cleaning composition |
| US5738127A (en) * | 1995-04-25 | 1998-04-14 | Hoechst Aktiengesellschaft | Process for removing contaminating coatings from metal surfaces |
| JPH10226800A (en) * | 1997-02-17 | 1998-08-25 | Kao Corp | Detergent composition for use in tableware washer |
| JPH11349983A (en) * | 1998-06-10 | 1999-12-21 | Asahi Denka Kogyo Kk | Detergent |
| WO2000034171A1 (en) * | 1998-12-04 | 2000-06-15 | Katsutoshi Ichikawa | Simplified crane |
| WO2000046327A1 (en) * | 1999-02-02 | 2000-08-10 | Henkel-Ecolab Gmbh & Co. Ohg | Agent for cleaning hard surfaces |
| WO2001059049A1 (en) * | 2000-02-09 | 2001-08-16 | Amechem Inc. | Multipurpose, multifunctional complex cleaning and washing agent |
| US6362149B1 (en) | 2000-08-03 | 2002-03-26 | Ecolab Inc. | Plastics compatible detergent composition and method of cleaning plastics comprising reverse polyoxyalkylene block co-polymer |
| US6530383B1 (en) | 1997-11-22 | 2003-03-11 | Ecolab Gmbh & Co. Ohg | Agent for cleaning hard surfaces |
| US6680286B1 (en) | 2000-11-14 | 2004-01-20 | Sanyo Chemical Industries, Ltd. | Detergent composition comprising a quaternary ammonium salt of a carboxyl containing polymer |
| JP2006070204A (en) * | 2004-09-03 | 2006-03-16 | Asahi Denka Kogyo Kk | Detergent composition containing phosphorus for automatic dish washer |
| JP2007238951A (en) * | 1997-01-13 | 2007-09-20 | Ecolab Inc | Alkaline detergent containing mixed organic and inorganic sequestrant improved in soil removal capability |
| JP2009543896A (en) * | 2006-07-14 | 2009-12-10 | イーコラブ インコーポレイティド | Alkaline floor cleaning composition and floor cleaning method |
| JP2011149001A (en) * | 2009-12-25 | 2011-08-04 | Kao Corp | Powdery washing agent composition for use in automatic washing machine |
| JP2012007131A (en) * | 2010-06-28 | 2012-01-12 | Adeka Corp | Detergent composition for dishwashers and cleaning method using the composition |
-
1993
- 1993-10-20 JP JP29376793A patent/JPH07118689A/en active Pending
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5738127A (en) * | 1995-04-25 | 1998-04-14 | Hoechst Aktiengesellschaft | Process for removing contaminating coatings from metal surfaces |
| AU720987B2 (en) * | 1995-08-07 | 2000-06-22 | Unilever Plc | Improvements relating to hard surface cleaning composition |
| WO1997006232A1 (en) * | 1995-08-07 | 1997-02-20 | Unilever Plc | Improvements relating to hard surface cleaning composition |
| JP2007238951A (en) * | 1997-01-13 | 2007-09-20 | Ecolab Inc | Alkaline detergent containing mixed organic and inorganic sequestrant improved in soil removal capability |
| JPH10226800A (en) * | 1997-02-17 | 1998-08-25 | Kao Corp | Detergent composition for use in tableware washer |
| US6530383B1 (en) | 1997-11-22 | 2003-03-11 | Ecolab Gmbh & Co. Ohg | Agent for cleaning hard surfaces |
| JPH11349983A (en) * | 1998-06-10 | 1999-12-21 | Asahi Denka Kogyo Kk | Detergent |
| WO2000034171A1 (en) * | 1998-12-04 | 2000-06-15 | Katsutoshi Ichikawa | Simplified crane |
| WO2000046327A1 (en) * | 1999-02-02 | 2000-08-10 | Henkel-Ecolab Gmbh & Co. Ohg | Agent for cleaning hard surfaces |
| WO2001059049A1 (en) * | 2000-02-09 | 2001-08-16 | Amechem Inc. | Multipurpose, multifunctional complex cleaning and washing agent |
| US6362149B1 (en) | 2000-08-03 | 2002-03-26 | Ecolab Inc. | Plastics compatible detergent composition and method of cleaning plastics comprising reverse polyoxyalkylene block co-polymer |
| US6838422B2 (en) | 2000-08-03 | 2005-01-04 | Ecolab Inc. | Plastics compatible detergent composition and method of cleaning plastics |
| US6680286B1 (en) | 2000-11-14 | 2004-01-20 | Sanyo Chemical Industries, Ltd. | Detergent composition comprising a quaternary ammonium salt of a carboxyl containing polymer |
| JP2006070204A (en) * | 2004-09-03 | 2006-03-16 | Asahi Denka Kogyo Kk | Detergent composition containing phosphorus for automatic dish washer |
| JP2009543896A (en) * | 2006-07-14 | 2009-12-10 | イーコラブ インコーポレイティド | Alkaline floor cleaning composition and floor cleaning method |
| JP2011149001A (en) * | 2009-12-25 | 2011-08-04 | Kao Corp | Powdery washing agent composition for use in automatic washing machine |
| JP2012007131A (en) * | 2010-06-28 | 2012-01-12 | Adeka Corp | Detergent composition for dishwashers and cleaning method using the composition |
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