JPH06322545A - Plated resin product - Google Patents
Plated resin productInfo
- Publication number
- JPH06322545A JPH06322545A JP10660893A JP10660893A JPH06322545A JP H06322545 A JPH06322545 A JP H06322545A JP 10660893 A JP10660893 A JP 10660893A JP 10660893 A JP10660893 A JP 10660893A JP H06322545 A JPH06322545 A JP H06322545A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- rubber
- weight
- plating
- graft copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 16
- 239000011347 resin Substances 0.000 title claims abstract description 16
- 229920001971 elastomer Polymers 0.000 claims abstract description 42
- 239000005060 rubber Substances 0.000 claims abstract description 42
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 33
- 238000007747 plating Methods 0.000 claims abstract description 29
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 25
- 239000004431 polycarbonate resin Substances 0.000 claims abstract description 23
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract description 23
- 239000000178 monomer Substances 0.000 claims abstract description 22
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 10
- 239000011342 resin composition Substances 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 7
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 6
- 229920003244 diene elastomer Polymers 0.000 claims abstract description 5
- 239000002131 composite material Substances 0.000 claims description 26
- 125000003118 aryl group Chemical group 0.000 claims description 21
- 238000000034 method Methods 0.000 abstract description 24
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 abstract description 15
- 238000013329 compounding Methods 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 239000000047 product Substances 0.000 description 21
- 239000000126 substance Substances 0.000 description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- -1 carbonyl halide Chemical class 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000003486 chemical etching Methods 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- 239000004419 Panlite Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920006243 acrylic copolymer Polymers 0.000 description 2
- 150000008360 acrylonitriles Chemical class 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000007788 roughening Methods 0.000 description 2
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- URFNSYWAGGETFK-UHFFFAOYSA-N 1,2-bis(4-hydroxyphenyl)ethane Natural products C1=CC(O)=CC=C1CCC1=CC=C(O)C=C1 URFNSYWAGGETFK-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000006085 branching agent Substances 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- KPVWDKBJLIDKEP-UHFFFAOYSA-L dihydroxy(dioxo)chromium;sulfuric acid Chemical compound OS(O)(=O)=O.O[Cr](O)(=O)=O KPVWDKBJLIDKEP-UHFFFAOYSA-L 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- KCAMXZBMXVIIQN-UHFFFAOYSA-N octan-3-yl 2-methylprop-2-enoate Chemical compound CCCCCC(CC)OC(=O)C(C)=C KCAMXZBMXVIIQN-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920006230 thermoplastic polyester resin Polymers 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は熱可塑性樹脂よりなるメ
ッキ製品に関する。更に詳しくは耐熱性、成形加工性、
機械的性質及びメッキ性に優れた熱可塑性樹脂よりなる
メッキ製品に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a plated product made of a thermoplastic resin. More specifically, heat resistance, molding processability,
The present invention relates to a plated product made of a thermoplastic resin having excellent mechanical properties and plating properties.
【０００２】[0002]
【従来の技術】熱可塑性樹脂成形品にメッキ加工して金
属様外観を賦与することはよく知られている。従来から
広く利用されているメッキ樹脂製品として ABS樹脂メッ
キ製品が知られているが、更に高い耐熱性と機械的性質
を有する樹脂メッキ製品が望まれている。2. Description of the Related Art It is well known that a thermoplastic resin molded product is plated to give a metallic appearance. ABS resin plated products have been known as plated resin products that have been widely used, but resin plated products having higher heat resistance and mechanical properties have been desired.
【０００３】芳香族ポリカーボネート樹脂は優れた耐熱
性と機械的性質を備えたエンジニアリングプラスチック
として種々の分野、例えば機械部品等に使用されてお
り、これにメッキ加工したものは上述の特性を有するの
で ABS樹脂メッキ製品では使用できなかった分野から強
く期待されている。しかしながら、芳香族ポリカーボネ
ート樹脂のメッキ加工やメッキ製品には種々の未解決の
問題があり、充分に満足すべきものは得られていない。Aromatic polycarbonate resins are used as engineering plastics having excellent heat resistance and mechanical properties in various fields, such as machine parts, and the plated products have the above-mentioned characteristics. There are strong expectations from fields that could not be used in resin-plated products. However, there are various unsolved problems in the plating processing of aromatic polycarbonate resin and plated products, and a satisfactory product has not been obtained yet.
【０００４】熱可塑性樹脂成形品のメッキは一般に（a)
前処理、（b)化学エッチング、（c)触媒付与、（d)活性
化、（e)化学メッキ、（f)電気メッキの工程からなり、
これらの工程で特に（a)前処理と（b)化学エッチングの
工程は、成形品の表面を粗化することによってメッキ下
地に適した微細な凹凸を形成し、樹脂とメッキした金属
膜との間に良好な密着性を与える重要な工程であり、こ
れらの工程は樹脂の種類によって異なる。例えば ABS樹
脂では、前処理工程は単に成形品表面に付着した油脂類
を除去する程度でよく、メッキの下地になる成形品の表
面粗化は主にクロム酸−硫酸酸化液による化学エッチン
グ工程で行なわれ、その後電気メッキまでの処理を行な
えば、容易に優れた密着強度を有するメッキ製品が得ら
れる。Plating of thermoplastic resin moldings is generally carried out by (a)
It consists of pretreatment, (b) chemical etching, (c) catalyst application, (d) activation, (e) chemical plating, (f) electroplating,
In these steps, in particular (a) pretreatment and (b) chemical etching, the surface of the molded product is roughened to form fine irregularities suitable for the plating base, and the resin and the plated metal film are combined. It is an important step that gives good adhesion between them, and these steps differ depending on the type of resin. For example, in the case of ABS resin, the pretreatment process may simply remove the oils and fats adhering to the surface of the molded product, and the surface roughening of the molded product, which is the base of plating, is mainly performed by a chemical etching process using a chromic acid-sulfuric acid oxidizing solution. If the treatment is performed and then the processing up to electroplating is performed, a plated product having excellent adhesion strength can be easily obtained.
【０００５】これに対し、芳香族ポリカーボネート樹脂
では、上記の ABS樹脂の処理方法では十分な表面粗化が
行なわれないので、その後の化学メッキ工程で化学ニッ
ケルや化学銅メッキが付着しないか、付着しても簡単に
剥離する。これを解決するために、ジメチルホルムアミ
ド等の有機溶剤で前処理する方法（特公昭４５−１２９
９６号公報）、酸化アルカリ溶液で前処理する方法（特
公昭４４−２９３９９号公報）、芳香族ポリカーボネー
ト樹脂に特定の化合物を配合する方法（特公昭５０−３
９１０２号公報）等が提案されている。しかしながら、
これらの前処理法は作業環境上やコスト的に好ましくな
く、また芳香族ポリカーボネート樹脂に特定の化合物を
配合する方法は化学エッチングの条件が ABS樹脂の場合
よりも難しい等の欠点を有している。これらの欠点を解
決するために芳香族ポリカーボネート樹脂に ABS樹脂を
配合する方法、芳香族ポリカーボネート樹脂に ABS樹脂
とMBS樹脂を配合する方法等が提案されているが、未だ
十分とは言えず改良が望まれている。On the other hand, in the case of the aromatic polycarbonate resin, the surface roughening is not sufficiently performed by the above method of treating the ABS resin, so that the chemical nickel or the chemical copper plating does not adhere or does not adhere in the subsequent chemical plating process. Even if peeled off easily. In order to solve this, a method of pretreatment with an organic solvent such as dimethylformamide (Japanese Patent Publication No. 45-129).
96), a method of pretreatment with an alkali oxide solution (Japanese Patent Publication No. 44-29399), and a method of compounding a specific compound with an aromatic polycarbonate resin (Japanese Patent Publication No. 50-3).
No. 9102) has been proposed. However,
These pretreatment methods are not preferable in terms of work environment and cost, and the method of compounding an aromatic polycarbonate resin with a specific compound has the drawback that the chemical etching conditions are more difficult than in the case of ABS resin. . In order to solve these drawbacks, a method of blending an aromatic polycarbonate resin with an ABS resin, a method of blending an aromatic polycarbonate resin with an ABS resin and an MBS resin, and the like have been proposed, but improvements cannot be said to be sufficient yet. Is desired.
【０００６】[0006]
【発明が解決しようとする課題】本発明の目的は、優れ
た耐熱性、成形加工性、機械的性質を有し、特に ABS樹
脂のメッキと同様の工程で容易にメッキが可能なメッキ
製品を提供することにある。An object of the present invention is to provide a plated product which has excellent heat resistance, moldability and mechanical properties and which can be easily plated by the same process as plating of ABS resin. To provide.
【０００７】本発明者は、上記目的を達成せんとして鋭
意検討した結果、芳香族ポリカーボネート樹脂と ABS樹
脂の樹脂混合物に、ポリオルガノシロキサンゴムとポリ
アルキル（メタ）アクリレートゴムとの特定の複合ゴム
系グラフトポリマーを配合すると、その成形品のメッキ
性が飛躍的に向上することを見出し、本発明に到達し
た。As a result of earnest studies aimed at achieving the above object, the present inventor has found that a resin mixture of an aromatic polycarbonate resin and an ABS resin contains a specific composite rubber system of a polyorganosiloxane rubber and a polyalkyl (meth) acrylate rubber. The present inventors have found that when a graft polymer is blended, the plating property of the molded product is dramatically improved, and the present invention has been achieved.
【０００８】[0008]
【課題を解決するための手段】本発明は、熱可塑性樹脂
の成形品にメッキ加工した樹脂メッキ製品であり熱可塑
性樹脂が、（A)芳香族ポリカーボネート樹脂２０〜８０
重量％及び（B)ジエン系ゴムの存在下で二種以上の共重
合可能なビニル系単量体を重合して得られるグラフト共
重合体８０〜２０重量％からなる樹脂混合物１００重量
部に対して（C)ポリオルガノシロキサンゴム成分とポリ
アルキル（メタ）アクリレートゴム成分とが分離できな
いように相互に絡み合った構造を有している複合ゴムに
一種又は二種以上のビニル系単量体がグラフト重合され
てなる複合ゴム系グラフト共重合体又は該複合ゴム系グ
ラフト共重合体とビニル系重合体との混合物１〜５０重
量部を配合した樹脂組成物であることを特徴とする樹脂
メッキ製品に係るものである。DISCLOSURE OF THE INVENTION The present invention is a resin-plated product obtained by plating a molded product of a thermoplastic resin, wherein the thermoplastic resin is (A) aromatic polycarbonate resin 20-80.
% To 100 parts by weight of a resin mixture consisting of 80 to 20% by weight of a graft copolymer obtained by polymerizing two or more copolymerizable vinyl monomers in the presence of (B) diene rubber. (C) a polyorganosiloxane rubber component and a polyalkyl (meth) acrylate rubber component are grafted with one or more vinyl monomers on a composite rubber having a structure in which they are intertwined with each other so that they cannot be separated. A resin-plated product, which is a resin composition containing 1 to 50 parts by weight of a composite rubber-based graft copolymer obtained by polymerization or a mixture of the composite rubber-based graft copolymer and a vinyl-based polymer. It is related.
【０００９】本発明で使用する（A)芳香族ポリカーボネ
ート樹脂は、二価フェノールとカーボネート前駆体とを
溶液法又は溶融法で反応させて製造される。二価フェノ
ールとしては例えば２，２−ビス（４−ヒドロキシフェ
ニル）プロパン（通称ビスフェノールＡ）、ビス（４−
ヒドロキシフェニル）メタン、ビス（４−ヒドロキシフ
ェニル）エタン、２，２−ビス（４−ヒドロキシ−３，
５−ジメチルフェニル）プロパン、２，２−（４−ヒド
ロキシ−３−メチルフェニル）プロパン、ビス（４−ヒ
ドロキシフェニル）スルフォン等があげられる。好まし
い二価フェノールはビス（４−ヒドロキシフェニル）ア
ルカンであり、なかでもビスフェノールＡが好ましい。
また、カーボネート前駆体としてはカルボニルハライ
ド、ジアリールカーボネート、ハロホルメート等があげ
られ、具体的にはホスゲン、ジフェニルカーボネート、
二価フェノールのジハロホルメート及びそれらの混合物
である。芳香族ポリカーボネート樹脂を製造するに当
り、前記二価フェノールを単独で使用しても又は二種以
上使用してもよい。また、適当な分子量調節剤、分岐
剤、反応を促進するための触媒等も使用できる。芳香族
ポリカーボネート樹脂の分子量は特定されないが、分子
量があまりに低いと耐衝撃性等が低下し、あまりに高い
と成形加工性が低下するようになるので、粘度平均分子
量で表して１０，０００〜５０，０００のものが好まし
く、１５，０００〜３０，０００ののものが特に好まし
い。また、芳香族ポリカーボネート樹脂の二種以上を混
合しても差支えない。The aromatic polycarbonate resin (A) used in the present invention is produced by reacting a dihydric phenol with a carbonate precursor by a solution method or a melting method. Examples of the dihydric phenol include 2,2-bis (4-hydroxyphenyl) propane (commonly called bisphenol A) and bis (4-
Hydroxyphenyl) methane, bis (4-hydroxyphenyl) ethane, 2,2-bis (4-hydroxy-3,
Examples thereof include 5-dimethylphenyl) propane, 2,2- (4-hydroxy-3-methylphenyl) propane and bis (4-hydroxyphenyl) sulfone. A preferred dihydric phenol is bis (4-hydroxyphenyl) alkane, and bisphenol A is particularly preferred.
Further, examples of the carbonate precursor include carbonyl halide, diaryl carbonate, haloformate, and the like. Specifically, phosgene, diphenyl carbonate,
The dihaloformates of dihydric phenols and mixtures thereof. In producing the aromatic polycarbonate resin, the above dihydric phenols may be used alone or in combination of two or more kinds. Further, an appropriate molecular weight regulator, branching agent, catalyst for accelerating the reaction and the like can also be used. Although the molecular weight of the aromatic polycarbonate resin is not specified, impact resistance and the like decrease when the molecular weight is too low, and molding processability decreases when the molecular weight is too high. Therefore, the viscosity average molecular weight is 10,000 to 50, Those of 5,000 are preferable, and those of 15,000 to 30,000 are particularly preferable. Further, it is possible to mix two or more aromatic polycarbonate resins.
【００１０】本発明で使用する（B)グラフト共重合体
は、ジエン系ゴムの存在下で二種以上の共重合可能なビ
ニル系単量体を重合して得られるグラフト共重合体であ
る。ここで用いるジエン系ゴムとしては、例えばポリブ
タジエン、ポリイソプレン、ブタジエン−スチレン共重
合体、ブタジエン−アクリロニトリル共重合体等があげ
られる。かかるゴム成分に共重合可能なビニル系単量体
としては、例えばアクリロニトリル、メタアクリロニト
リル、クロロアクリロニトリル等のシアン化ビニル化合
物、スチレン、α−メチルスチレン、 p−メチルスチレ
ン、アルコキシスチレン、ハロゲン化スチレン等の芳香
族ビニル化合物、アクリル酸メチル、アクリル酸エチ
ル、アクリル酸ブチル、アクリル酸オクチル等のアクリ
ル酸の低級アルキルエステル、メタクリル酸メチル、メ
タクリル酸エチル、メタクリル酸ブチル、メタクリル酸
オクチル等のメタクリル酸の低級アルキルエステル等が
あげられる。グラフト共重合体は塊状重合、溶液重合、
懸濁重合、乳化重合等のいずれの方法で製造したもので
あってもよく、またグラフトの方式としては一段グラフ
トでも、多段グラフトでも差支えない。また、製造の際
に副生するグラフト成分のみの共重合体が混合されてい
てもよく、二種以上のグラフト共重合体の混合物であっ
てもよい。The (B) graft copolymer used in the present invention is a graft copolymer obtained by polymerizing two or more copolymerizable vinyl monomers in the presence of a diene rubber. Examples of the diene rubber used here include polybutadiene, polyisoprene, butadiene-styrene copolymer, butadiene-acrylonitrile copolymer and the like. Examples of vinyl monomers copolymerizable with the rubber component include vinyl cyanide compounds such as acrylonitrile, methacrylonitrile, and chloroacrylonitrile, styrene, α-methylstyrene, p-methylstyrene, alkoxystyrene, halogenated styrene, etc. Aromatic vinyl compounds, lower alkyl esters of acrylic acid such as methyl acrylate, ethyl acrylate, butyl acrylate, octyl acrylate, and methacrylic acid such as methyl methacrylate, ethyl methacrylate, butyl methacrylate, octyl methacrylate, etc. Examples include lower alkyl esters. Graft copolymer is bulk polymerization, solution polymerization,
It may be produced by any method such as suspension polymerization and emulsion polymerization, and the grafting method may be either single-stage grafting or multi-stage grafting. Further, a copolymer of only the graft component produced as a by-product during the production may be mixed, or a mixture of two or more kinds of graft copolymers may be used.
【００１１】（A)芳香族ポリカーボネート樹脂と（B)グ
ラフト共重合体の配合割合は、（A)と（B)の合計重量中
（A)芳香族ポリカーボネート樹脂２０〜８０重量％及び
（B)グラフト共重合体８０〜２０重量％であり、（A)芳
香族ポリカーボネート樹脂３０〜７０重量％及び（B)グ
ラフト共重合体７０〜３０重量％が好ましい。芳香族ポ
リカーボネート樹脂の配合量が２０重量％未満の場合に
は得られる成形品の耐衝撃性や耐熱性等が低下し、８０
重量％を超えると成形加工性やメッキ性等が低下するよ
うになる。また、更にこの中にポリエチレンテレフタレ
ート等の熱可塑性ポリエステル樹脂を少割合で添加して
も良い。The blending ratio of (A) aromatic polycarbonate resin and (B) graft copolymer is 20 to 80% by weight of (A) aromatic polycarbonate resin and (B) in the total weight of (A) and (B). The graft copolymer is 80 to 20% by weight, preferably (A) the aromatic polycarbonate resin 30 to 70% by weight and (B) the graft copolymer 70 to 30% by weight. If the blending amount of the aromatic polycarbonate resin is less than 20% by weight, the impact resistance and heat resistance of the obtained molded article will decrease, and
If it exceeds the weight%, the molding processability and plating property will be deteriorated. Further, a small amount of thermoplastic polyester resin such as polyethylene terephthalate may be added to this.
【００１２】本発明で使用する（C)複合ゴム系グラフト
共重合体は、ポリオルガノシロキサンゴム成分とポリア
ルキル（メタ）アクリレートゴム成分とが分離できない
ように相互に絡み合った構造を有している複合ゴムに一
種又は二種以上のビニル系単量体がグラフト重合されて
なる複合ゴム系グラフト共重合体又はかかる複合ゴム系
グラフト共重合体とビニル系重合体との混合物である。The (C) composite rubber-based graft copolymer used in the present invention has a structure in which the polyorganosiloxane rubber component and the polyalkyl (meth) acrylate rubber component are intertwined with each other so that they cannot be separated. A composite rubber-based graft copolymer obtained by graft-polymerizing one or more vinyl-based monomers to a composite rubber or a mixture of such a composite rubber-based graft copolymer and a vinyl-based polymer.
【００１３】ここで使用する複合ゴムの粒子径があまり
に小さいと得られる樹脂組成物の耐衝撃性が低下するよ
うになり、あまりに大きいと得られる樹脂組成物の成形
品の表面外観が悪化するようになるので、複合ゴムの平
均粒子径は０．０８〜０．６μm であることが好まし
い。複合ゴム系グラフト共重合体を得るには、まず３員
環以上の各種の環状オルガノシロキサン、例えばヘキサ
メチルシクロトリシロキサン、オクタメチルシクロテト
ラシロキサン、デカメチルシクロペンタシロキサン等
と、架橋剤及び／又はグラフト交叉剤を使用して乳化重
合によりポリオルガノシロキサンゴムのラテックスを調
整し、次にアルキル（メタ）アクリレート単量体、架橋
剤及び／又はグラフト交叉剤をポリオルガノシロキサン
ゴムのラテックスに含浸させてから重合することによっ
て得られる。If the particle size of the composite rubber used here is too small, the impact resistance of the resulting resin composition will decrease, and if it is too large, the surface appearance of the molded article of the resulting resin composition will deteriorate. Therefore, the average particle size of the composite rubber is preferably 0.08 to 0.6 μm. To obtain a composite rubber-based graft copolymer, first, various cyclic organosiloxanes having 3 or more membered rings, such as hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, etc., and a crosslinking agent and / or A latex of polyorganosiloxane rubber is prepared by emulsion polymerization using a graft crossing agent, and then the latex of polyorganosiloxane rubber is impregnated with an alkyl (meth) acrylate monomer, a crosslinking agent and / or a graft crossing agent. It is obtained by polymerizing.
【００１４】ここで使用するアルキル（メタ）アクリレ
ート単量体としては、例えばメチルアクリレート、エチ
ルアクリレート、 n−プロピルアクリレート、 n−ブチ
ルアクリレート、２−エチルヘキシルアクリレート等の
アルキルアクリレート、ヘキシルメタクリレート、２−
エチルヘキシルメタクリレート等のアルキルメタクリレ
ート等があげられ、特に n−ブチルアクリレートが好ま
しい。Examples of the alkyl (meth) acrylate monomer used here include alkyl acrylates such as methyl acrylate, ethyl acrylate, n-propyl acrylate, n-butyl acrylate and 2-ethylhexyl acrylate, hexyl methacrylate and 2-
Examples thereof include alkyl methacrylates such as ethylhexyl methacrylate, and n-butyl acrylate is particularly preferable.
【００１５】かかる複合ゴムにグラフト重合させるビニ
ル系単量体としては、例えばスチレン、α−メチルスチ
レン等の芳香族ビニル化合物、アクリロニトリル、メタ
クリロニトリル等のシアン化ビニル化合物、メチルメタ
クリレート、２−エチルヘキシルメタクリレート等のメ
タクリル酸エステル、メチルアクリレート、エチルアク
リレート、ブチルアクリレート等のアクリル酸エステル
等があげられ、これらは単独で又は二種以上組合わせて
使用される。Examples of the vinyl-based monomer to be graft-polymerized on the composite rubber include aromatic vinyl compounds such as styrene and α-methylstyrene, vinyl cyanide compounds such as acrylonitrile and methacrylonitrile, methyl methacrylate and 2-ethylhexyl. Examples thereof include methacrylic acid esters such as methacrylate, acrylic acid esters such as methyl acrylate, ethyl acrylate, and butyl acrylate. These may be used alone or in combination of two or more.
【００１６】複合ゴム系グラフト共重合体における複合
ゴムとビニル系単量体の割合は、グラフト共重合体の重
量を基準にして複合ゴム３０〜９５重量％及びビニル系
単量体７０〜５重量％が好ましく、複合ゴム４０〜９０
重量％及びビニル系単量体６０〜１０重量％が特に好ま
しい。ビニル系単量体が５重量％未満では樹脂組成物中
での本グラフト共重合体の分散不良が生じ易く、また７
０重量％を超えると衝撃強度の改良効果が低下するよう
になるので好ましくない。The ratio of the composite rubber to the vinyl-based monomer in the composite rubber-based graft copolymer is 30 to 95% by weight of the composite rubber and 70 to 5% by weight of the vinyl-based monomer based on the weight of the graft copolymer. %, Composite rubber 40-90
Weight% and 60 to 10 weight% of vinyl monomer are particularly preferable. If the amount of the vinyl-based monomer is less than 5% by weight, poor dispersion of the present graft copolymer in the resin composition is likely to occur.
If it exceeds 0% by weight, the effect of improving the impact strength will decrease, which is not preferable.
【００１７】また、（C)成分として、上記の複合ゴム系
グラフト共重合体とビニル系重合体との混合物を使用し
てもよく、その際ビニル系共重合体としては、上記のグ
ラフト重合させるビニル系単量体と同様の芳香族ビニル
単量体、シアン化ビニル単量体及び（メタ）アクリル酸
エステル単量体からなる群より選ばれた一種以上の単量
体７０〜１００重量％と、これと共重合可能なビニル系
単量体、例えばエチレン、酢酸ビニル等を３０〜０重量
％とを共重合して得られるものが用いられる。これらの
ビニル系共重合体は二種以上を併用してもよい。このよ
うな複合ゴム系グラフト共重合体又は該複合ゴム系グラ
フト共重合体とビニル系重合体との混合物の好ましいも
のとしては特開平１−２３０６６４号公報に記載の複合
ゴム系グラフト共重合体又は該グラフト共重合体とビニ
ル系重合体との混合物があげられる。なかでも好ましい
ものとして三菱レイヨン（株）よりメタブレン S−２０
０１という商品名で市販されているものがあげられる。As the component (C), a mixture of the above composite rubber graft copolymer and a vinyl polymer may be used, in which case the vinyl copolymer is the above graft polymerized. 70 to 100% by weight of one or more monomers selected from the group consisting of aromatic vinyl monomers, vinyl cyanide monomers and (meth) acrylic acid ester monomers similar to vinyl monomers. A vinyl monomer which is copolymerizable therewith, for example, one obtained by copolymerizing 30 to 0% by weight of ethylene, vinyl acetate or the like is used. Two or more kinds of these vinyl-based copolymers may be used in combination. Preferred examples of such a composite rubber-based graft copolymer or a mixture of the composite rubber-based graft copolymer and a vinyl-based polymer are the composite rubber-based graft copolymers described in JP-A 1-230664 or A mixture of the graft copolymer and a vinyl polymer can be used. Among them, Metabrene S-20 from Mitsubishi Rayon Co., Ltd. is preferred.
The commercially available product under the trade name of 01 is available.
【００１８】（C)複合ゴム系グラフト共重合体の配合量
は、前記（A)芳香族ポリカーボネート樹脂と（B)グラフ
ト共重合体の混合樹脂１００重量部に対し１〜５０重量
部、好ましくは２〜３０重量部である。配合量が１重量
部未満ではメッキ性向上に対する充分な効果が得られ難
く、５０重量％を超えると得られる成形品の耐熱性やメ
ッキの密着強さ等が低下するようになる。The compounding amount of the (C) composite rubber-based graft copolymer is 1 to 50 parts by weight, preferably 100 parts by weight of the mixed resin of the (A) aromatic polycarbonate resin and the (B) graft copolymer. It is 2 to 30 parts by weight. If the blending amount is less than 1 part by weight, it is difficult to obtain a sufficient effect for improving the plating property, and if it exceeds 50% by weight, the heat resistance and the adhesion strength of the plating of the obtained molded article are deteriorated.
【００１９】本発明における樹脂組成物には、本発明の
目的を損なわない範囲で必要に応じて例えば酸化防止
剤、難燃剤、難燃助剤、可塑剤、滑剤、離型剤等を配合
してもよく、また例えばタルク、マイカ、ガラス繊維、
カーボン繊維、ウイスカー等の強化剤を配合することも
可能である。The resin composition according to the present invention may optionally contain, for example, an antioxidant, a flame retardant, a flame retardant aid, a plasticizer, a lubricant, a release agent, etc., within a range that does not impair the object of the present invention. May also be used, such as talc, mica, fiberglass,
It is also possible to add a reinforcing agent such as carbon fiber or whiskers.
【００２０】本発明における組成物の製造は、任意の方
法で行なうことができる。例えばタンブラー、Ｖ型ブレ
ンダー、ナウターミキサー、バンバリーミキサー、混練
ロール、押出機等の混合機で混合して製造することがで
きる。また、このようにして得られた樹脂組成物は既知
の種々の方法、例えば射出成形法、押出成形法等により
成形される。The composition of the present invention can be produced by any method. For example, it can be produced by mixing with a mixer such as a tumbler, a V-type blender, a Nauter mixer, a Banbury mixer, a kneading roll and an extruder. The resin composition thus obtained is molded by various known methods such as injection molding and extrusion molding.
【００２１】[0021]
【実施例】以下に実施例をあげて本発明を更に説明す
る。なお、実施例中の部は重量部である。メッキ方法及
び各物性の測定方法は下記の通りである。なお、このメ
ッキ方法はＡＢＳ樹脂の通常のメッキ条件に準じてい
る。 (A）メッキ方法： a.脱脂：奥野製薬工業（株）製のエースクリーン A−２
２０（５０ g／リットル）、５０℃×５分 b.エッチング：ＣｒＯ3 （４００ g／リットル）、Ｈ2
ＳＯ4 （４００ g／リットル）、６５℃×１０分 c.中和：ＨＣｌ（５０ml／リットル）、室温×２分 d.キャタリスト：奥野製薬工業（株）製キャタリスト C
（５０ml／リットル）ＨＣｌ（１５０ml／リットル）、
室温×３分 e.アクセレータ：Ｈ2 ＳＯ4 （１００ml／リットル）、
４０℃×３分 f.無電解ニッケルメッキ：奥野製薬工業（株）製 TMP化
学ニッケルメッキ A、 TMP化学ニッケルメッキ B、４０
℃×８分 g.脱脂：奥野製薬工業（株）製トップサン（５０ g／リ
ットル）、室温×１分h.電気銅メッキ：３ A／dm2 ×２
時間 注：各工程間には水洗工程が入る。 (B）無電解メッキ沈着速度：メッキテスト片全面に無電
解ニッケルが沈着する時間を＋−で表わす。（＋＋＋速
い←→−遅い、＋＋＋で約２分、−で約１０分以上であ
る） (C）密着強度：銅メッキを施した角板にカッターにて１
cm幅のケガキをいれ、テンシロンにて５０mm／分の速度
で引き剥したときの強度を測定した。 (D）アイゾット衝撃値：ASTM D−２５６に準拠（厚み
３．２mmノッチ付）した。 (E）荷重たわみ温度：ASTM D−６４８に準拠（荷重１
８．６ kgf／cm2 ）した。EXAMPLES The present invention will be further described with reference to the following examples. The parts in the examples are parts by weight. The plating method and the measuring method of each physical property are as follows. It should be noted that this plating method complies with normal plating conditions for ABS resin. (A) Plating method: a. Degreasing: A-screen A-2 manufactured by Okuno Chemical Industries Co., Ltd.
20 (50 g / liter), 50 ° C. × 5 minutes b. Etching: CrO 3 (400 g / liter), H 2
SO 4 (400 g / liter), 65 ° C. × 10 minutes c. Neutralization: HCl (50 ml / liter), room temperature × 2 minutes d. Catalyst: Okano Pharmaceutical Co., Ltd. Catalyst C
(50 ml / liter) HCl (150 ml / liter),
Room temperature x 3 minutes e. Accelerator: H 2 SO 4 (100 ml / liter),
40 ℃ x 3 minutes f. Electroless nickel plating: Okuno Chemical Industries Co., Ltd. TMP chemical nickel plating A, TMP chemical nickel plating B, 40
℃ × 8 minutes g. Degreasing: Top Sun (50 g / l) manufactured by Okuno Chemical Industries Co., Ltd., room temperature × 1 minute h. Electrolytic copper plating: 3 A / dm 2 × 2
Time Note: There is a washing process between each process. (B) Electroless plating deposition rate: The time during which electroless nickel is deposited on the entire surface of the plating test piece is represented by +-. (+++ Fast ← → -Slow, +++ is about 2 minutes, -is about 10 minutes or more) (C) Adhesive strength: 1 with a cutter on a copper-plated square plate
A scribe with a width of cm was put in, and the strength when peeled off with a tensilon at a speed of 50 mm / min was measured. (D) Izod impact value: conformed to ASTM D-256 (thickness 3.2 mm with notch). (E) Deflection temperature under load: According to ASTM D-648 (load 1
8.6 kgf / cm 2 ).
【００２２】[0022]
【実施例１〜３及び比較例１〜４】粘度平均分子量２
５，０００の芳香族ポリカ−ボネ−ト樹脂［帝人化成
（株）製パンライト L−１２５０］、 ABS樹脂［宇部サ
イコン（株）製サイコラック Y−５４０ A］、複合ゴム
系グラフト共重合体［三菱レイヨン（株）製メタブレン
S−２００１］、 MBS樹脂［鐘淵化学工業（株）製カネ
エ−ス B−５６］及びアクリル系共重合体［呉羽化学工
業（株）製 HIA−１５］を表１記載の量混合し、径３０
mmのベント式押出機［ナカタニ（株）製 VSK−３０］に
よりシリンダー温度２５０℃でペレット化した。このペ
レットを１１０℃で５時間乾燥した後、射出成形機[FAN
UC（株）製 MODEL T−１５０ D］によりシリンダー温度
２６０℃、金型温度７５℃で角板（１５０mm×１５０mm
×３mm）を成形し、加工により５０mm×１００mm×３mm
のメッキ試験片とし、常法により電気銅メッキを施して
密着強度試験を測定した。また、同成形機によりシリン
ダー温度２６０℃、金型温度７０℃で物性試験片を成形
して各物性を測定した。結果を表１に示した。Examples 1 to 3 and Comparative Examples 1 to 4 Viscosity average molecular weight 2
5,000 aromatic polycarbonate resin [Panlite L-1250 manufactured by Teijin Kasei Co., Ltd.], ABS resin [Cycolac Y-540 A manufactured by Ube Saikon Co., Ltd.], composite rubber-based graft copolymer [Metablene manufactured by Mitsubishi Rayon Co., Ltd.
S-2001], MBS resin [Kanefuchi Chemical Industry Co., Ltd. Kaneace B-56] and acrylic copolymer [Kureha Chemical Industry Co., Ltd. HIA-15] were mixed in the amounts shown in Table 1, Diameter 30
Pelletization was carried out at a cylinder temperature of 250 ° C. using a vent type extruder of mm [VSK-30 manufactured by Nakatani Co., Ltd.]. After drying these pellets at 110 ° C for 5 hours, injection molding machine [FAN
UC model MODEL T-150 D] with a cylinder temperature of 260 ° C and a mold temperature of 75 ° C.
X 3 mm) and processed to 50 mm x 100 mm x 3 mm
As a plating test piece of No. 3, electrolytic copper plating was applied by a conventional method, and the adhesion strength test was measured. Further, each physical property was measured by molding a physical property test piece with the same molding machine at a cylinder temperature of 260 ° C. and a mold temperature of 70 ° C. The results are shown in Table 1.
【００２３】なお、表１中の樹脂及び添加剤の記号は下
記のものを示す。 PC：芳香族ポリカーボネート樹脂［帝人化成（株）製パ
ンライト L−１２５０］ ABS ： ABS樹脂［宇部サイコン（株）製サイコラック Y
−５４０ A］ A ：複合ゴム系グラフト共重合体［三菱レイヨン（株）
製メタブレン S−２００１］ B ： MBS樹脂［鐘淵化学工業（株）製カネエ−ス B−５
６］ C ：アクリル系共重合体［呉羽化学工業（株）製 HIA−
１５］The symbols for resins and additives in Table 1 are as follows. PC: Aromatic polycarbonate resin [Panlite L-1250 manufactured by Teijin Kasei Co., Ltd.] ABS: ABS resin [Psycholac Y manufactured by Ube Saikon Co., Ltd.]
-540 A] A: Composite rubber-based graft copolymer [Mitsubishi Rayon Co., Ltd.
Metablen S-2001] B: MBS resin [Kanebuchi B-5 manufactured by Kanegafuchi Chemical Industry Co., Ltd.]
6] C: Acrylic copolymer [HIA- manufactured by Kureha Chemical Industry Co., Ltd.]
15]
【００２４】[0024]
【表１】 [Table 1]
【００２５】[0025]
【発明の効果】本発明によれば、優れた耐熱性、成形加
工性、機械的性質を有し、特に ABS樹脂のメッキと同様
の工程で容易にメッキが可能なメッキ製品を提供するこ
とを可能にし、その奏する工業的効果は格別なものであ
る。According to the present invention, it is possible to provide a plated product which has excellent heat resistance, moldability and mechanical properties, and in particular can be plated easily in the same process as plating of ABS resin. The industrial effects that enable and produce are exceptional.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ０８Ｌ 57/00 ＬＭＨ 69/00 ＬＰＮ // Ｃ０８Ｆ 291/02 ＭＲＢ (Ｃ０８Ｌ 69/00 55:02 83:04 33:04） ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Internal reference number FI Technical display location C08L 57/00 LMH 69/00 LPN // C08F 291/02 MRB (C08L 69/00 55:02 83 : 04 33:04)
Claims (1)
樹脂メッキ製品であり、熱可塑性樹脂が（A)芳香族ポリ
カーボネート樹脂２０〜８０重量％及び（B)ジエン系ゴ
ムの存在下で二種以上の共重合可能なビニル系単量体を
重合して得られるグラフト共重合体８０〜２０重量％か
らなる樹脂混合物１００重量部に対して（C)ポリオルガ
ノシロキサンゴム成分とポリアルキル（メタ）アクリレ
ートゴム成分とが分離できないように相互に絡み合った
構造を有している複合ゴムに一種又は二種以上のビニル
系単量体がグラフト重合されてなる複合ゴム系グラフト
共重合体又は該複合ゴム系グラフト共重合体とビニル系
重合体との混合物１〜５０重量部を配合した樹脂組成物
であることを特徴とする樹脂メッキ製品。1. A resin-plated product obtained by plating a molded product of a thermoplastic resin, wherein the thermoplastic resin is two kinds in the presence of (A) 20 to 80% by weight of an aromatic polycarbonate resin and (B) a diene rubber. (C) Polyorganosiloxane rubber component and polyalkyl (meth) based on 100 parts by weight of a resin mixture consisting of 80 to 20% by weight of a graft copolymer obtained by polymerizing the above copolymerizable vinyl monomer. A composite rubber-based graft copolymer obtained by graft-polymerizing one or more vinyl-based monomers to a composite rubber having a structure in which they are intertwined with each other so that they cannot be separated from an acrylate rubber component, or the composite rubber A resin-plated product, which is a resin composition containing 1 to 50 parts by weight of a mixture of a graft graft copolymer and a vinyl polymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10660893A JP2865970B2 (en) | 1993-05-07 | 1993-05-07 | Resin plated products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10660893A JP2865970B2 (en) | 1993-05-07 | 1993-05-07 | Resin plated products |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06322545A true JPH06322545A (en) | 1994-11-22 |
| JP2865970B2 JP2865970B2 (en) | 1999-03-08 |
Family
ID=14437836
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10660893A Expired - Lifetime JP2865970B2 (en) | 1993-05-07 | 1993-05-07 | Resin plated products |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2865970B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8552096B2 (en) | 2009-07-31 | 2013-10-08 | Sabic Innovative Plastics Ip B.V. | Flame-retardant reinforced polycarbonate compositions |
| US9085687B2 (en) | 2012-02-03 | 2015-07-21 | Sabic Global Technologies B.V. | Polycarbonate blends having improved electroplate adhesion |
| CN114316554A (en) * | 2021-12-01 | 2022-04-12 | 金发科技股份有限公司 | High-spherical-pressure flame-retardant PC/ABS material and preparation method and application thereof |
-
1993
- 1993-05-07 JP JP10660893A patent/JP2865970B2/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8552096B2 (en) | 2009-07-31 | 2013-10-08 | Sabic Innovative Plastics Ip B.V. | Flame-retardant reinforced polycarbonate compositions |
| US9085687B2 (en) | 2012-02-03 | 2015-07-21 | Sabic Global Technologies B.V. | Polycarbonate blends having improved electroplate adhesion |
| CN114316554A (en) * | 2021-12-01 | 2022-04-12 | 金发科技股份有限公司 | High-spherical-pressure flame-retardant PC/ABS material and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2865970B2 (en) | 1999-03-08 |
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