JPH06292745A - Golf club shaft - Google Patents

Golf club shaft

Info

Publication number
JPH06292745A
JPH06292745A JP5084654A JP8465493A JPH06292745A JP H06292745 A JPH06292745 A JP H06292745A JP 5084654 A JP5084654 A JP 5084654A JP 8465493 A JP8465493 A JP 8465493A JP H06292745 A JPH06292745 A JP H06292745A
Authority
JP
Japan
Prior art keywords
shaft
golf club
carbon
club shaft
base material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP5084654A
Other languages
Japanese (ja)
Inventor
Takenori Nakayama
武典 中山
Yasunori Wada
恭典 和田
Hidekazu Ido
秀和 井戸
Hiroshi Sato
廣士 佐藤
Hidetoshi Nishimoto
英敏 西本
Yoshinori Terada
好則 寺田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to JP5084654A priority Critical patent/JPH06292745A/en
Publication of JPH06292745A publication Critical patent/JPH06292745A/en
Withdrawn legal-status Critical Current

Links

Abstract

PURPOSE:To provide a golf club shaft which is superior to a golf club shaft consisting of a conventional carbon material in the qualities of antiwear, antidamage and design (a fine sight such as a color tone) and is excellent in a flying distance and directional stability like those of the conventional shafts. CONSTITUTION:This is a golf club shaft whose feature is that the surface of its shaft base material consisting of a carbon material is covered with an Ni-P plating layer whose P content is more than 0.1wt.%.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、ゴルフクラブ用シャフ
トに関し、詳細には、耐摩耗性、耐傷付き性や意匠性に
優れたゴルフクラブ用シャフトに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a golf club shaft, and more particularly to a golf club shaft excellent in wear resistance, scratch resistance and design.

【0002】[0002]

【従来の技術】ゴルフクラブの性能としては、より大き
な飛距離が出ること及び方向安定性に優れることが望ま
れている。従来、ゴルフクラブヘッド(以降、ヘッドと
いう)の構成材料を高強度化することにより飛距離を拡
大するが、その反面、方向安定性に欠けてくるといわれ
ている。一方、より軟らかい材料によりヘッドを構成す
れば、飛距離が出なく、又、傷が付き易いという欠点が
ある。そのため、ヘッドの構成材料(材質)として、鉄
からアルミ、カーボン、チタン等に至るまで種々の材料
が提案され、実施されているが、このようなヘッド材質
による改善だけでは飛距離及び方向安定性の向上に限界
がある。
2. Description of the Related Art As a performance of a golf club, it is desired to have a greater flight distance and excellent directional stability. Conventionally, the flight distance is increased by increasing the strength of the constituent material of a golf club head (hereinafter referred to as a head), but on the other hand, it is said that directional stability is lacking. On the other hand, if the head is made of a softer material, there are drawbacks that the flight distance is not long and the head is easily scratched. Therefore, various materials such as iron, aluminum, carbon, titanium, etc. have been proposed and implemented as constituent materials (materials) of the head, but improvement in flight distance and directional stability can be achieved only by improving the head material. There is a limit to the improvement of.

【0003】そこで、ゴルフクラブ用シャフト(以降、
シャフトという)の材質も併せて種々検討されている。
その中で、最近、飛距離及び方向安定性を向上し得るシ
ャフト材質としてカーボンを主原料とする材料(即ち、
カーボン系材料)が注目されており、かかるカーボン系
材料よりなるゴルフクラブ用シャフト(以降、カーボン
シャフトという)も汎用されつつある。
Therefore, a golf club shaft (hereinafter,
Various materials are also being studied.
Among them, recently, as a shaft material capable of improving flight distance and directional stability, a material containing carbon as a main raw material (that is,
A carbon-based material) has been attracting attention, and a golf club shaft (hereinafter referred to as a carbon shaft) made of such a carbon-based material is being widely used.

【0004】[0004]

【発明が解決しようとする課題】ところが、前記従来の
カーボンシャフトにおいては、キャディバッグ等のケー
スとの接触時や他のゴルフクラブとの接触時に摩耗や疵
が発生し易いという問題点があり、その改善が要望され
ている。又、ゴルファーによってはカーボンシャフトの
色調が暗くて美観の面(意匠性)に不満足感を有してお
り、その改善の要望が潜在している。
However, the above-mentioned conventional carbon shaft has a problem that abrasion and flaws are likely to occur at the time of contact with a case such as a caddy bag or at the time of contact with other golf clubs. Improvement is required. Further, some golfers have a dark color tone of the carbon shaft and are unsatisfactory in terms of aesthetics (design), and there is a latent demand for improvement.

【0005】本発明は、このような事情に着目してなさ
れたものであって、その目的は前記従来のカーボンシャ
フトの有する問題点を解消し、該カーボンシャフトに比
べて耐摩耗性、耐傷付き性及び意匠性に優れると共に、
該カーボンシャフトと同様に飛距離及び方向安定性に優
れたゴルフクラブ用シャフトを提供しようとするもので
ある。
The present invention has been made in view of the above circumstances, and its purpose is to solve the problems of the conventional carbon shaft, and to improve wear resistance, scratch resistance, and abrasion resistance as compared with the carbon shaft. While being excellent in design,
The present invention aims to provide a golf club shaft having excellent flight distance and directional stability as with the carbon shaft.

【0006】[0006]

【課題を解決するための手段】上記目的を達成するため
に、本発明に係るゴルフクラブ用シャフトは次のような
構成としている。即ち、請求項1記載のゴルフクラブ用
シャフトは、ゴルフクラブ用シャフト基材がカーボン系
材料よりなるゴルフクラブ用シャフトであって、該基材
の表面にP含有量:0.1wt%以上のNi−P系めっき被覆層
を有することを特徴とするゴルフクラブ用シャフトであ
る。又、請求項2記載のゴルフクラブ用シャフトは、前
記Ni−P系めっき被覆層が電気めっきにより形成されて
いる請求項1記載のゴルフクラブ用シャフトである。
In order to achieve the above object, a golf club shaft according to the present invention has the following structure. That is, the golf club shaft according to claim 1 is a golf club shaft in which the golf club shaft base material is made of a carbon-based material, and the P content on the surface of the base material is 0.1% by weight or more of Ni-. A golf club shaft having a P-based plating coating layer. The shaft for a golf club according to claim 2 is the shaft for a golf club according to claim 1, wherein the Ni-P-based plating coating layer is formed by electroplating.

【0007】[0007]

【作用】本発明に係るゴルフクラブ用シャフトは、前記
の如く、ゴルフクラブ用シャフト基材がカーボン系材料
よりなるゴルフクラブ用シャフトであって、該基材の表
面にP含有量:0.1wt%以上のNi−P系めっき被覆層を有
するので、この基材に起因して、従来のカーボンシャフ
トと同様に飛距離及び方向安定性に優れ、又、この基材
表面のNi−P系めっき被覆層に起因して、従来のカーボ
ンシャフトに比べて優れた耐摩耗性、耐傷付き性及び意
匠性を有し得る。
As described above, the golf club shaft according to the present invention is a golf club shaft in which the golf club shaft base material is made of a carbon material, and the P content on the surface of the base material is 0.1 wt%. Since it has the above Ni-P type plating coating layer, it has excellent flight distance and directional stability due to this base material like the conventional carbon shaft, and the Ni-P type plating coating layer on the surface of this base material. Due to the above, it can have excellent wear resistance, scratch resistance and designability as compared with the conventional carbon shaft.

【0008】即ち、シャフト基材がカーボン系材料より
なるので、従来のカーボンシャフトを構成するカーボン
系材料と同様の機械的・物理的性質(シャフトして必要
な強度、靱性、剛性、振動特性等)を有し、従って、本
発明に係るシャフトは、従来のカーボンシャフトと同様
に飛距離及び方向安定性に優れている。
That is, since the shaft base material is made of a carbon-based material, mechanical and physical properties similar to those of the carbon-based material constituting the conventional carbon shaft (strength, toughness, rigidity, vibration characteristics, etc. required for the shaft). Therefore, the shaft according to the present invention is as excellent in flight distance and directional stability as the conventional carbon shaft.

【0009】一方、この基材表面のNi−P系めっき被覆
層は、基材のカーボン系材料よりも著しく硬くて耐摩耗
性及び耐傷付き性に優れており、その素地(基材)であ
るカーボン系材料との密着性もよいので、本発明に係る
シャフトは、従来のカーボンシャフトに比べて優れた耐
摩耗性及び耐傷付き性を有し得る。又、Ni−P系めっき
層は元来優れた表面品質を有し、シャンペンゴールド色
を呈するなど光沢があって美観があるので、シャフトの
色調が明るくて意匠性(美観)が向上する。更に、メタ
リック系の光沢付与もでき、カーボンシャフトの暗い色
調をユニークな色調に改善することもできる。
On the other hand, the Ni-P-based plating coating layer on the surface of the base material is significantly harder than the carbon-based material of the base material and is excellent in wear resistance and scratch resistance, and is the base material (base material). Since the adhesion to the carbon-based material is also good, the shaft according to the present invention can have excellent wear resistance and scratch resistance as compared with the conventional carbon shaft. In addition, the Ni-P-based plating layer originally has excellent surface quality, and has a gloss and an aesthetic appearance such as a champagne gold color, so the color tone of the shaft is bright and the designability (aesthetic appearance) is improved. Further, metallic luster can be imparted, and the dark color tone of the carbon shaft can be improved to a unique color tone.

【0010】ここで、Ni−P系めっき被覆層中のP含有
量は、前記の如く0.1wt%以上とする必要がある。それ
は、P含有量:0.1wt%未満では、めっき層の硬度が低く
て耐摩耗性及び耐傷付き性が低下すると共に光沢も劣
り、それらの必要性能が不充分となるからである。尚、
P含有量は0.1wt%以上であればよく、P含有量の上限値
は規定されるものではないが、30wt% 超ではNi−P系め
っき被覆層の靱性低下による耐摩耗性の低下が少し起こ
り、又、基材との密着性も少し低下するので、30wt% 以
下にすることが望ましく、更には、めっき効率の面を考
慮すると25wt% 以下にすることが好ましい。
Here, the P content in the Ni-P system plating coating layer must be 0.1 wt% or more as described above. This is because if the P content is less than 0.1 wt%, the hardness of the plating layer is low, the wear resistance and scratch resistance are reduced, and the gloss is also poor, resulting in insufficient required performance. still,
The P content may be 0.1 wt% or more, and the upper limit of the P content is not specified. However, if it exceeds 30 wt%, the wear resistance is slightly decreased due to the decrease in the toughness of the Ni-P-based plating coating layer. Since it occurs and the adhesiveness to the base material is slightly lowered, it is desirable to set it to 30 wt% or less, and more preferably 25 wt% or less in consideration of the plating efficiency.

【0011】前記基材表面のNi−P系めっき被覆層は、
電気めっきにより形成されていることが望ましい。即
ち、Ni−P系めっき被覆層は無電解めっき又は電気めっ
きにより得られるが、後者の電気めっきを適用する方が
望ましい。それは、電気めっきの方が、安価且つ容易に
めっき膜厚やめっき成分を制御し得るからである。この
場合、P含有量:0.1wt%以上の範囲内において、Ni−P
系めっき被覆層中のP含有量を調整することにより、該
めっき被覆層の硬度を制御でき、それにより個々のシャ
フトに応じた最適のめっき品質を与え得る。
The Ni-P-based plating coating layer on the surface of the substrate is
It is preferably formed by electroplating. That is, the Ni-P-based plating coating layer can be obtained by electroless plating or electroplating, but the latter electroplating is preferably applied. This is because electroplating can control the plating film thickness and plating components more easily and cheaply. In this case, P content: within the range of 0.1 wt% or more, Ni-P
By adjusting the P content in the system coating layer, it is possible to control the hardness of the coating layer, thereby providing optimum plating quality according to each shaft.

【0012】尚、本発明において、シャフト基材として
用いるカーボン系材料は、カーボンを主原料とする材料
であり、その一例としてカーボンがあるが、主原料のカ
ーボン以外にボロン、カプラー、サイファー、チタン、
セラミック等を副原料として含有させたものも適用でき
る。
In the present invention, the carbon-based material used as the shaft base material is a material whose main raw material is carbon, and one example thereof is carbon. In addition to the main raw material carbon, boron, coupler, cypher, titanium ,
A material containing ceramics or the like as an auxiliary material is also applicable.

【0013】シャフト基材表面のNi−P系めっき被覆層
は、成分としてNi及びP(0.1wt%以上)を含むことを必
須とするものであり、その一例としてNi−Pめっき層
(0.1wt%以上)があるが、これに限定されるものではな
く、FeやCo、W等の如き他の成分を必要に応じて添加す
ることができる。又、Ni−P系めっき層の厚みも限定さ
れるものではなく、必要に応じて適宜な厚みに調整する
ことができる。更に、基材表面に対するNi−P系めっき
層の被覆面積も限定されるものではなく、必要に応じて
適宜調整すればよく、例えば意匠面等の点から基材表面
の適宜な部分に一個所又は複数個所被覆してもよく、或
いは全面に被覆してもよい。
The Ni-P plating coating layer on the surface of the shaft base material essentially contains Ni and P (0.1 wt% or more) as components, and one example thereof is a Ni-P plating layer (0.1 wt%). % Or more), but is not limited thereto, and other components such as Fe, Co, and W can be added as necessary. Further, the thickness of the Ni-P based plating layer is not limited, and can be adjusted to an appropriate thickness as necessary. Further, the coating area of the Ni-P-based plating layer on the surface of the base material is not limited, and may be appropriately adjusted as necessary. For example, one portion is provided on an appropriate portion of the base material surface from the viewpoint of design surface. Alternatively, it may be coated at a plurality of locations, or may be coated on the entire surface.

【0014】又、Ni−P系めっき被覆層の形成後のもの
を、必要に応じて適当な加熱処理を施してもよい。例え
ば、 250〜500 ℃の加熱処理を施すことができ、この場
合にはNi−P系の金属間化合物の生成あるいはその他の
構造変化を生じるために硬度が上昇し、より一層の耐摩
耗性向上が図れる。
If necessary, the Ni-P-based plating coating layer may be subjected to an appropriate heat treatment. For example, heat treatment at 250 to 500 ° C. can be applied. In this case, Ni—P-based intermetallic compound is generated or other structural changes occur, so that the hardness is increased and the wear resistance is further improved. Can be achieved.

【0015】[0015]

【実施例】本発明の実施例を以下説明するが、本発明は
この実施例に制限されるものではない。
EXAMPLES Examples of the present invention will be described below, but the present invention is not limited to these examples.

【0016】表1に本発明の実施例に係るゴルフクラブ
シャフト及び比較例に係るゴルフクラブシャフトの材質
を試験結果とともに示す。この表1に示す如く、比較例
に係るシャフト(No.1)は市販のカーボンシャフトであ
る。実施例に係るシャフトは、市販のカーボンシャフト
を基材として用い、該基材の表面に厚み:30μm の無電
解Ni−Pめっき層を被覆したもの(No.2)、及び、厚
み:30μm の電気Ni−Pめっき層を被覆したもの(No.
3)である。ここで、無電解Ni−Pめっき層の被覆は、
次亜燐酸ナトリウムを還元剤として適宜添加した硫酸ニ
ッケル及び塩化ニッケル系浴をベース浴として用い、無
電解めっき方法により行った。電気Ni−Pめっき層の被
覆は、硫酸ニッケル及び塩化ニッケル系浴をベース浴と
して用い、電流密度:5〜40A/dm2 の条件で電気めっ
き方法により行った。尚、Ni−Pめっき層中のP量を3
wt% とした。
Table 1 shows the materials of the golf club shaft according to the example of the present invention and the golf club shaft according to the comparative example together with the test results. As shown in Table 1, the shaft (No. 1) according to the comparative example is a commercially available carbon shaft. The shaft according to the example uses a commercially available carbon shaft as a base material, and the surface of the base material is coated with an electroless Ni-P plating layer having a thickness of 30 μm (No. 2), and an electric power having a thickness of 30 μm. Ni-P plating layer coated (No.
3). Here, the coating of the electroless Ni-P plating layer is
This was carried out by an electroless plating method using a nickel sulfate and nickel chloride-based bath to which sodium hypophosphite was appropriately added as a reducing agent as a base bath. The coating of the electric Ni-P plating layer was performed by an electroplating method using nickel sulfate and nickel chloride-based bath as a base bath under the condition of current density: 5 to 40 A / dm 2 . In addition, the amount of P in the Ni-P plating layer is 3
It was set to wt%.

【0017】上記実施例に係るシャフト及び比較例に係
るシャフトについて、砂落とし摩耗試験法(JIS H8503)
に準じ、耐摩耗性試験を行った。ここで、この試験での
研削材(砂)としてはSiC #80(JIS H8503)を用い、砂
落とし速度は320 ±10g/minとし、砂落とし時間は5min
とした。表1に示す如く、比較例に係るシャフト即ち
カーボンシャフト(No.1)の摩耗量を1としたとき、実
施例に係るシャフトの中、No.2(無電解Ni−Pめっき層
を被覆したもの)についての磨耗量は0.001 であり、N
o.3(電気Ni−Pめっき層を被覆したもの)についての
磨耗量は0.001 以下である。従って、比較例に係るカー
ボンシャフトに比し、本発明の実施例に係るシャフトは
耐摩耗性に極めて優れ、又、その中でも電気Ni−Pめっ
き層を被覆したもの(No.3)が最も優れているといえ
る。
With respect to the shafts according to the above-mentioned examples and the shafts according to the comparative examples, a sand removal wear test method (JIS H8503)
A wear resistance test was conducted in accordance with. Here, SiC # 80 (JIS H8503) was used as the abrasive (sand) in this test, the sand removal rate was 320 ± 10 g / min, and the sand removal time was 5 min.
And As shown in Table 1, when the wear amount of the shaft according to the comparative example, that is, the carbon shaft (No. 1) is 1, the shaft according to the example is No. 2 (coated with an electroless Ni-P plating layer). ) Is 0.001 and N
The wear amount of o.3 (coated with an electric Ni-P plating layer) is 0.001 or less. Therefore, as compared with the carbon shaft according to the comparative example, the shaft according to the example of the present invention has extremely excellent wear resistance, and among them, the one coated with the electric Ni-P plating layer (No. 3) is the best. Can be said to be.

【0018】更に、上記実施例に係るシャフト及び比較
例に係るシャフト(耐摩耗性試験に供していないもの)
をシャフトとして用いたゴルフクラブを作製し、これら
のクラブをゴルフ場にて1ラウンドプレーを15回繰り返
して使用した。その結果、比較例に係るシャフト(カー
ボンシャフト)を用いたゴルフクラブでは、キャディバ
ッグその他のケース等との接触によりシャフト表面に摩
耗や疵の発生が認められたが、実施例に係るシャフトを
用いたゴルフクラブでは、こうした接触による摩耗や疵
の発生は全く認められなかった。
Further, the shaft according to the above-mentioned example and the shaft according to the comparative example (those not subjected to the abrasion resistance test)
Golf clubs were produced using the above as a shaft, and these clubs were used by repeating one round play 15 times at a golf course. As a result, in the golf club using the shaft (carbon shaft) according to the comparative example, abrasion and scratches were found on the surface of the shaft due to contact with the caddy bag and other cases, but the shaft according to the example was used. In the golf club, no wear or flaws due to such contact were observed.

【0019】[0019]

【表1】 [Table 1]

【0020】[0020]

【発明の効果】本発明に係るゴルフクラブ用シャフトは
前述の如き構成を有し作用をなすものであるので、従来
のカーボンシャフトと同様に優れた飛距離及び方向安定
性を確保し得ると共に、従来のカーボンシャフトに比べ
て耐摩耗性及び耐傷付き性及び意匠性(色調等)の向上
を図ることができるようになるという効果を奏する。
Since the golf club shaft according to the present invention has the above-described structure and functions, it can ensure excellent flight distance and directional stability as well as the conventional carbon shaft, and at the same time, it has a conventional structure. It is possible to improve wear resistance, scratch resistance, and designability (color tone, etc.) as compared with the carbon shaft of (1).

───────────────────────────────────────────────────── フロントページの続き (72)発明者 佐藤 廣士 兵庫県神戸市西区高塚台1丁目5番5号 株式会社神戸製鋼所神戸総合技術研究所内 (72)発明者 西本 英敏 兵庫県神戸市中央区脇浜町1丁目3番18号 株式会社神戸製鋼所神戸本社内 (72)発明者 寺田 好則 大阪府大阪市中央区備後町4丁目1−3 株式会社神戸製鋼所大阪支社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Hiroshi Sato 1-5-5 Takatsukadai, Nishi-ku, Kobe-shi, Hyogo Prefecture Kobe Steel Co., Ltd. Kobe Research Institute (72) Inventor Hidetoshi Nishimoto Central, Kobe City, Hyogo Prefecture 1-3-18 Wakihama-cho, Ward Ward Kobe Steel, Ltd. Kobe Head Office (72) Inventor Yoshinori Terada 4- 1-3, Bingocho, Chuo-ku, Osaka-shi, Osaka Kobe Steel Works, Osaka Branch

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 ゴルフクラブ用シャフト基材がカーボン
系材料よりなるゴルフクラブ用シャフトであって、該基
材の表面にP含有量:0.1wt%以上のNi−P系めっき被覆
層を有することを特徴とするゴルフクラブ用シャフト。
1. A golf club shaft in which a golf club shaft base material is made of a carbon-based material, and a Ni-P plating coating layer having a P content of 0.1 wt% or more is provided on the surface of the base material. Shafts for golf clubs characterized by.
【請求項2】 前記Ni−P系めっき被覆層が電気めっき
により形成されている請求項1記載のゴルフクラブ用シ
ャフト。
2. The golf club shaft according to claim 1, wherein the Ni—P-based plating coating layer is formed by electroplating.
JP5084654A 1993-04-12 1993-04-12 Golf club shaft Withdrawn JPH06292745A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5084654A JPH06292745A (en) 1993-04-12 1993-04-12 Golf club shaft

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5084654A JPH06292745A (en) 1993-04-12 1993-04-12 Golf club shaft

Publications (1)

Publication Number Publication Date
JPH06292745A true JPH06292745A (en) 1994-10-21

Family

ID=13836709

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5084654A Withdrawn JPH06292745A (en) 1993-04-12 1993-04-12 Golf club shaft

Country Status (1)

Country Link
JP (1) JPH06292745A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7320832B2 (en) 2004-12-17 2008-01-22 Integran Technologies Inc. Fine-grained metallic coatings having the coefficient of thermal expansion matched to the one of the substrate
US7387578B2 (en) 2004-12-17 2008-06-17 Integran Technologies Inc. Strong, lightweight article containing a fine-grained metallic layer

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7320832B2 (en) 2004-12-17 2008-01-22 Integran Technologies Inc. Fine-grained metallic coatings having the coefficient of thermal expansion matched to the one of the substrate
US7387578B2 (en) 2004-12-17 2008-06-17 Integran Technologies Inc. Strong, lightweight article containing a fine-grained metallic layer
US7591745B2 (en) 2004-12-17 2009-09-22 Integran Technologies, Inc. Strong, lightweight article containing a fine-grained metallic layer
US7771289B2 (en) * 2004-12-17 2010-08-10 Integran Technologies, Inc. Sports articles formed using nanostructured materials
US7803072B2 (en) 2004-12-17 2010-09-28 Integran Technologies Inc. Strong, lightweight article, containing a fine-grained metallic layer
US7824774B2 (en) 2004-12-17 2010-11-02 Integran Technologies, Inc. Fine-grained metallic coatings having the coefficient of thermal expansion matched to the one of the substrate
US7910224B2 (en) 2004-12-17 2011-03-22 Integran Technologies, Inc. Fine-grained metallic coatings having the coefficient of thermal expansion matched to the one of the substrate
US8025979B2 (en) 2004-12-17 2011-09-27 Integran Technologies Inc. Strong, lightweight article containing a fine-grained metallic layer
US8129034B2 (en) 2004-12-17 2012-03-06 Integran Technologies, Inc. Fine-grained metallic coatings having the coeficient of thermal expansion matched to one of the substrate

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