JPH062204A - Polyvinyl chloride gloves and its production - Google Patents
Polyvinyl chloride gloves and its productionInfo
- Publication number
- JPH062204A JPH062204A JP4161187A JP16118792A JPH062204A JP H062204 A JPH062204 A JP H062204A JP 4161187 A JP4161187 A JP 4161187A JP 16118792 A JP16118792 A JP 16118792A JP H062204 A JPH062204 A JP H062204A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- glove
- film
- pile
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Gloves (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は非粘着性，吸水性を有す
る塩化ビニル手袋及びその製造方法に関するものであ
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to non-adhesive, water-absorbing vinyl chloride gloves and a method for producing the same.
【０００２】[0002]
【従来の技術】従来、この種の塩化ビニル手袋は、粉末
や塩化ビニルブレンドレジンをコーティングした（特開
昭６１−２４９７１６号公報，特開昭６１−２４９７１
７号公報）りして非粘着性を保持させたものがある。2. Description of the Related Art Conventionally, vinyl chloride gloves of this type have been coated with powder or vinyl chloride blend resin (Japanese Patent Laid-Open Nos. 61-249716 and 61-24971).
No. 7 gazette), the non-adhesiveness is retained.
【０００３】[0003]
【発明が解決しようとする課題】しかし、上記従来技術
にあっては粉末をコーティングしたものではこれが使用
時に剥がれてしまい、塩化ビニルブレンドレジンをコー
ティングしたものでは物性が変化して手を荒してしま
い、長期使用時には手の発汗により内部がむれると言う
不具合を有していたものである。However, in the above-mentioned prior art, the powder-coated one is peeled off at the time of use, and the vinyl chloride-blended resin-coated one has a change in the physical properties, which leads to rough hands. However, when used for a long period of time, there is a problem that the inside of the hand gets peeled due to sweating of the hand.
【０００４】本発明は、従来技術の有するこのような問
題点に鑑みなされたものであり、その目的とするところ
は、非粘着性を損なわず、内部がむれずかつ物性の変化
のない塩化ビニル手袋を提供することである。The present invention has been made in view of the above problems of the prior art. The object of the present invention is to provide vinyl chloride which does not impair the non-adhesiveness, does not lose its inside and does not change its physical properties. It is to provide gloves.
【０００５】[0005]
【課題を解決するための手段】上記目的を達成するため
に本発明がなした技術的手段は、手袋本体の内面にパイ
ルを含有する非粘着性，吸水性の皮膜を設けたことであ
る。To achieve the above object, the technical means of the present invention is to provide a non-adhesive, water-absorbent film containing a pile on the inner surface of the glove body.
【０００６】[0006]
【作用】上記せる技術的手段により、パイルを含有する
非粘着性，吸水性の皮膜が塩化ビニル製手袋本体の内面
に形成されて接着性に優れ、かつ手との接触面に滑性を
与え、長期使用にも内部がむれることがない塩化ビニル
手袋が得られる。By the above technical means, a non-adhesive, water-absorbent film containing a pile is formed on the inner surface of the vinyl chloride glove body to provide excellent adhesiveness, and to give a smooth contact surface with the hand. A vinyl chloride glove that does not get loose inside even after long-term use is obtained.
【０００７】[0007]
【実施例】以下、本発明の一実施例を図面に基づいて説
明すると、本発明の手袋は此種の技術分野において周知
の形態および構造である手袋製造型を所定の温度に調整
した後、該型を塩化ビニル樹脂溶液に１回または２回浸
漬して手袋本体となる塩化ビニルペーストを附着させ、
引き上げてセミキュアー、冷却して型面に一層又は二層
必要によっては数層からなる手袋本体１を成膜し、然る
後、これを表面処理剤に再度浸漬する。DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to the drawings. The glove of the present invention has a well-known form and structure in this technical field. The mold is dipped once or twice in a vinyl chloride resin solution to attach a vinyl chloride paste that will become the glove body,
The glove main body 1 is pulled up and semi-cured, and cooled to form a single layer or two layers on the mold surface, and if necessary, several layers are formed into a film, and then the glove main body 1 is immersed again in the surface treatment agent.
【０００８】塩化ビニル樹脂溶液は塩化ビニルペースト
レジンに可塑剤、安定剤、ゲル化剤、顔料など通常用い
られている各種の添加剤を配合してなる周知の塩化ビニ
ルペーストであり、このような粘度4000〜10000 cps と
した塩化ビニルペーストを手袋製造型に附着させてセミ
キュアー、冷却して薄膜状の手袋本体１とするために一
層もしくは二層或は数層に成膜を形成し、この成膜の表
面に表面処理剤を施し皮膜２を形成する為、パイル３を
含有せしめた表面処理剤溶液にさらに手袋製造型を浸漬
する。The vinyl chloride resin solution is a well-known vinyl chloride paste prepared by blending a vinyl chloride paste resin with various additives that are normally used, such as a plasticizer, a stabilizer, a gelling agent and a pigment. A vinyl chloride paste having a viscosity of 4000 to 10000 cps is attached to a glove manufacturing mold, semi-cured, and cooled to form a thin film-shaped glove body 1, and a film is formed in one or two or several layers. In order to form the film 2 by applying a surface treatment agent to the surface of the film, the glove making mold is further dipped in the surface treatment agent solution containing the pile 3.
【０００９】皮膜２は、可塑剤部数20〜50部の塩化ビニ
ル樹脂やウレタン樹脂、アクリル樹脂等任意の樹脂にパ
イル３を含有せしめた粘度が10〜200 cps のエマルジョ
ンタイプの表面処理剤の成膜であって、この表面処理剤
に前記本体１の成膜層を有する手袋製造型を再度浸漬し
て表面処理を施し、引き上げ、予備乾燥、キュアー、冷
却を順次行って皮膜２を設ける。The coating 2 is an emulsion-type surface treatment agent having a viscosity of 10 to 200 cps which is obtained by adding the pile 3 to any resin such as vinyl chloride resin, urethane resin, acrylic resin having 20 to 50 parts of plasticizer. A glove manufacturing mold having a film-forming layer of the main body 1 is immersed again in the surface treatment agent to perform a surface treatment, and is pulled up, preliminarily dried, cured, and cooled in this order to form a film 2.
【００１０】従って、上記せる如く製造型上に設けられ
た本体１の表面に前記皮膜２を設け反転離型することに
より、手袋本体１の内面にパイル３を含有せしめた非粘
着性，吸水性の皮膜２を設けた手袋が形成される。Therefore, as described above, the film 2 is provided on the surface of the main body 1 provided on the manufacturing mold, and the mold 3 is reversed and released, so that the inner surface of the glove main body 1 contains the pile 3 and is non-adhesive and water-absorbing. A glove provided with the coating 2 is formed.
【００１１】パイル３は綿パイル，レーヨンパイル等吸
湿性を有する任意のパイルであり、0.5 〜2.5 デニール
で長さが0.01〜 0.5mmのものを用い、前記エマルジョン
タイプの表面処理剤に練り込む。The pile 3 is any pile having hygroscopicity, such as cotton pile and rayon pile, and has a denier of 0.5 to 2.5 and a length of 0.01 to 0.5 mm, and is kneaded into the emulsion type surface treating agent.
【００１２】次に具体的な実施態様について説明する
と、下記配合（イ）による液温35℃の塩化ビニルペース
トに、型温50℃に調整された手袋製造型を浸漬し、引き
上げた後 170℃ 4分セミキュアーし、常温まで冷却す
る。Explaining a concrete embodiment, a glove manufacturing mold adjusted to a mold temperature of 50 ° C. is dipped in a vinyl chloride paste having a liquid temperature of 35 ° C. according to the following composition (a), and after pulling up 170 ° C. Semi-cure for 4 minutes and cool to room temperature.
【００１３】 −配合（イ）− 塩化ビニルペーストレジン（1650重合度） １００ＰＨＲ 可塑剤（フタル酸エステル、ポリエステル） １００ＰＨＲ 安定剤（Ca-Ba-Zn） ４ＰＨＲ ゲル化剤（Ca/Si ） ４ＰＨＲ 顔 料 １ＰＨＲ-Blending (a) -Vinyl chloride paste resin (1650 degree of polymerization) 100PHR Plasticizer (phthalate ester, polyester) 100PHR Stabilizer (Ca-Ba-Zn) 4PHR Gelling agent (Ca / Si) 4PHR Face agent 1 PHR
【００１４】次いで、前記塩化ビニルペーストが付着成
膜した手袋製造型を、下記配合（ロ）のエマルジョンタ
イプの表面処理剤（液温25℃）に浸漬60cm／分して引き
上げ30cm／分、然る後60〜 140℃ 2分予備乾燥、 220℃
8分キュアーして型温70℃まで冷却後、反転離型し、塩
化ビニル手袋を得た。この手袋は粘着性がなく、かつ物
性の低下がなく風合が軟らかくしなやか（低モジュラス
高伸張）であり、耐油性もよく、異物感が無く使用感良
好で手のむれもなく、さらに離型及び手の脱着が容易で
あった。Next, the glove manufacturing mold to which the vinyl chloride paste was deposited was immersed in an emulsion type surface treatment agent (liquid temperature 25 ° C.) of the following formulation (b) at 60 cm / min and pulled up at 30 cm / min. 60-140 ℃ 2 minutes after pre-drying, 220 ℃
After curing for 8 minutes and cooling to a mold temperature of 70 ° C, the mold was reversed and released to obtain vinyl chloride gloves. This glove is non-sticky, has no deterioration in physical properties, is soft and supple (low modulus, high extension), has good oil resistance, does not feel foreign matter, has a good feeling of use, and has good grip on the hands. It was easy to attach and detach the hands.
【００１５】 −配合（ロ）− 塩化ビニルラテックス， G-576 ５０００部（固型分55％） 増粘剤 適 量 分散剤 適 量 界面活性剤 適 量 水 ５０００部 綿パイル ２００部-Blending (b) -Vinyl chloride latex, G-576 5000 parts (solid content 55%) Thickener proper amount dispersant proper amount surfactant surfactant proper water 5000 parts cotton pile 200 parts
【００１６】前記エマルジョンタイプの表面処理剤の調
整法の一例は綿パイル200 ｇを1000mlの温水（40℃，分
散剤添加）に混入して良く練り吸水せしめ、これをＰＶ
Ｃラテックス5000mlと水1000mlとの混合液に添加して攪
拌した後、粘度調整のため増粘剤を添加して更に界面活
性剤を添加し攪拌する。An example of the method for preparing the emulsion type surface treatment agent is as follows: 200 g of cotton pile is mixed with 1000 ml of warm water (40 ° C., with a dispersant added) and kneaded well to absorb water.
After being added to a mixed solution of 5000 ml of C latex and 1000 ml of water and stirred, a thickener for adjusting viscosity and a surfactant are further added and stirred.
【００１７】表１に本発明実施品と表面未処理品の物
性、滑性を表す。Table 1 shows the physical properties and lubricity of the product of the present invention and the surface-untreated product.
【表１】 [Table 1]
【００１８】尚、物性はJIS S 2045に基づき、滑性にあ
っては角度を自由に変えられる台にビニルをはり（処理
面を上にする）、 2ｇのふんどうを静かに置き、台の角
度を変えて、ふんどうが滑り始めるときの角度で比較し
た。Based on JIS S 2045, the physical properties are based on JIS S 2045. For lubricity, stick vinyl on a table whose treatment angle can be freely changed (the treated surface is up) and gently place 2 g of the loincloth on the table. I changed the angle and compared the angles when the loin begins to slip.
【００１９】[0019]
【発明の効果】本発明は、手袋製造型を塩化ビニル樹脂
溶液に浸漬して塩化ビニルペーストを附着成膜せしめ、
然る後、パイルを練り込んだ表面処理剤に再度浸漬して
手袋本体の内面に、パイルを含有する皮膜を設けたた
め、該皮膜が手袋本体との接着性が極めて優れ剥れるこ
とがなく、かつ手との接触面においてパイルが吸水性を
発揮して手袋内部がむれることなく手に密着することも
ない。しかもパイルが練り込みであるため剥離脱落する
ことがもなく、滑性を付与し、非粘着性が長期間におい
て維持でき、物性の変化もなく大変有用で使用勝手に優
れるものである。Industrial Applicability According to the present invention, a glove manufacturing mold is dipped in a vinyl chloride resin solution to deposit a vinyl chloride paste to form a film,
After that, since the coating containing the pile was provided on the inner surface of the glove body by immersing it again in the surface treatment agent in which the pile was kneaded, the coating had extremely excellent adhesiveness with the glove body and did not peel off. Moreover, the pile exerts water absorbency on the contact surface with the hand, and the inside of the glove does not come loose and does not adhere to the hand. Moreover, since the pile is kneaded, it does not peel off and fall off, imparts lubricity, can maintain non-adhesiveness for a long period of time, is very useful with no change in physical properties, and is excellent in usability.
【図１】 本発明塩化ビニル手袋の一例を一部切欠いて
示す正面図である。FIG. 1 is a front view showing an example of a vinyl chloride glove of the present invention with a part cut away.
【図２】 拡大断面図。FIG. 2 is an enlarged sectional view.
１：手袋本体 ２：皮膜 ３：パ
イル1: Glove body 2: Film 3: Pile
Claims (2)
を設けた塩化ビニル手袋。1. A vinyl chloride glove in which a film containing a pile is provided on the inner surface of the glove body.
して塩化ビニルペーストを附着成膜せしめ、然る後、パ
イルを練り込んだ表面処理剤に再度浸漬して皮膜を設
け、反転離型することを特徴とする塩化ビニル手袋の製
造方法。2. A glove manufacturing mold is dipped in a vinyl chloride resin solution to attach a vinyl chloride paste to form a film. After that, the film is dipped again in a surface treatment agent in which piles have been kneaded to form a film, and then a reverse mold release is performed. A method for producing a vinyl chloride glove, comprising:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4161187A JPH062204A (en) | 1992-06-19 | 1992-06-19 | Polyvinyl chloride gloves and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4161187A JPH062204A (en) | 1992-06-19 | 1992-06-19 | Polyvinyl chloride gloves and its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH062204A true JPH062204A (en) | 1994-01-11 |
Family
ID=15730247
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4161187A Pending JPH062204A (en) | 1992-06-19 | 1992-06-19 | Polyvinyl chloride gloves and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH062204A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57135042U (en) * | 1981-02-18 | 1982-08-23 | ||
| US6953582B2 (en) | 1999-04-07 | 2005-10-11 | Sheh Wei (Usa), Inc. | Skin-enhancing glove and method of manufacture |
| JP2007063688A (en) * | 2005-08-30 | 2007-03-15 | Showa Glove Kk | Inner-surface-flocked glove and method for producing the same |
| US20150102522A1 (en) * | 2012-05-18 | 2015-04-16 | Sumitomo Rubber Industries, Ltd. | Method of producing elastic glove |
| US9435757B2 (en) | 2011-08-15 | 2016-09-06 | X-Ray Optical Systems, Inc. | Sample viscosity and flow control for heavy samples, and X-ray analysis applications thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS407448Y1 (en) * | 1964-01-22 | 1965-03-08 | ||
| JPS6285002A (en) * | 1985-10-03 | 1987-04-18 | エステ−化学株式会社 | Production of glove made of vinyl chloride |
-
1992
- 1992-06-19 JP JP4161187A patent/JPH062204A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS407448Y1 (en) * | 1964-01-22 | 1965-03-08 | ||
| JPS6285002A (en) * | 1985-10-03 | 1987-04-18 | エステ−化学株式会社 | Production of glove made of vinyl chloride |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57135042U (en) * | 1981-02-18 | 1982-08-23 | ||
| JPH0125387Y2 (en) * | 1981-02-18 | 1989-07-31 | ||
| US6953582B2 (en) | 1999-04-07 | 2005-10-11 | Sheh Wei (Usa), Inc. | Skin-enhancing glove and method of manufacture |
| JP2007063688A (en) * | 2005-08-30 | 2007-03-15 | Showa Glove Kk | Inner-surface-flocked glove and method for producing the same |
| US9435757B2 (en) | 2011-08-15 | 2016-09-06 | X-Ray Optical Systems, Inc. | Sample viscosity and flow control for heavy samples, and X-ray analysis applications thereof |
| US20150102522A1 (en) * | 2012-05-18 | 2015-04-16 | Sumitomo Rubber Industries, Ltd. | Method of producing elastic glove |
| US9578906B2 (en) * | 2012-05-18 | 2017-02-28 | Sumitomo Rubber Industries, Ltd. | Method of producing elastic glove |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |