JPH06123086A - Cloth for ink-jet printing and printing method - Google Patents
Cloth for ink-jet printing and printing methodInfo
- Publication number
- JPH06123086A JPH06123086A JP4293817A JP29381792A JPH06123086A JP H06123086 A JPH06123086 A JP H06123086A JP 4293817 A JP4293817 A JP 4293817A JP 29381792 A JP29381792 A JP 29381792A JP H06123086 A JPH06123086 A JP H06123086A
- Authority
- JP
- Japan
- Prior art keywords
- water
- cloth
- repellents
- ink
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、インクジェット捺染に
用いる布帛及びそれを用いた捺染法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cloth used for ink-jet printing and a printing method using the same.
【０００２】[0002]
【従来の技術】従来、布帛に図柄を印捺する方法として
は、スクリーン捺染法，ローラ捺染法，ロータリースク
リーン捺染法，転写捺染法等が用いられてきたが、図柄
の変更毎にスクリーン枠，彫刻ローラ，転写紙等を用意
する必要があり、これらスクリーン枠，彫刻ローラ，転
写紙の作成はかなり高価であるため、かなりのロットを
生産しないと経済的な面で合わない点のみならず、ファ
ッションの多様化に迅速に対応出来ないという欠点を有
する。2. Description of the Related Art Conventionally, as a method for printing a pattern on a cloth, a screen printing method, a roller printing method, a rotary screen printing method, a transfer printing method, etc. have been used. It is necessary to prepare engraving rollers, transfer paper, etc., and since the production of these screen frames, engraving rollers, transfer paper is quite expensive, not only is it economically incompatible unless a large lot is produced, It has the drawback of not being able to quickly respond to the diversification of fashion.
【０００３】これ等の欠点を解決するために、スキャナ
ーで見本を読み取り、コンピュータで画像処理を行い、
その結果をインクジェット方式で印捺する技術が開発さ
れてきたが、これ等は被捺染物を紙に限定していたた
め、布帛に適用した場合に滲みが著しく鮮明性に劣ると
いう問題があり、問題の解決が望まれていた。In order to solve these drawbacks, a sample is read by a scanner and image processing is performed by a computer.
A technique for printing the results by an inkjet method has been developed, but since these are limited to paper to be printed, there is a problem that bleeding is markedly inferior in sharpness when applied to a fabric, which is a problem. Was desired.
【０００４】この滲みを防止する目的で、染料インクの
粘度を増大せしめる方法が知られているが、染料インク
の粘度を増大せしめると、インクジェットのノズル詰り
が発生する。There is known a method of increasing the viscosity of the dye ink for the purpose of preventing the bleeding, but if the viscosity of the dye ink is increased, the nozzle clogging of the ink jet will occur.
【０００５】これらの問題を解決するために特開昭６３
−８５１８８号公報には予めデンプン，カルボキシメチ
ルセルロース等水溶性高分子で前処理することにより滲
みを防止する方法が提案されているが、未だ十分な滲み
防止効果が得られていないという欠点を有す。In order to solve these problems, Japanese Patent Laid-Open No. 63-63
Although a method of preventing bleeding by pretreatment with a water-soluble polymer such as starch or carboxymethylcellulose is proposed in Japanese Patent Publication No. -85188, it has a drawback that a sufficient bleeding preventing effect has not been obtained yet. .
【０００６】更に、特願平２−２９８３９９号には撥水
剤及び柔軟撥水剤から選ばれた１種とヒドロトロープ剤
で前処理することにより滲みを防止する方法が、また特
願平３−３３７７２０号には柔軟撥水剤と高吸水性樹脂
で前処理することにより滲みを防止する方法が、また特
公昭６３−３１５９３号公報には撥水度５０点以上の布
帛を用いることにより滲みを防止する方法が提案されて
おり、これらの方法によれば滲みは防止できるものの、
得られた製品はインクのドットが見えて印刷調になり、
またその撥水性により捺染後の仕上加工時に仕上剤が多
量に必要となるなどの問題があった。Further, Japanese Patent Application No. 2-298399 discloses a method for preventing bleeding by pretreatment with one kind selected from a water repellent and a soft water repellent and a hydrotrope, and Japanese Patent Application No. No. 337720 discloses a method of preventing bleeding by pretreatment with a soft water repellent and a super absorbent polymer, and Japanese Patent Publication No. 63-31593 discloses a method of using a cloth having a water repellency of 50 or more. Methods have been proposed to prevent this, and although bleeding can be prevented by these methods,
In the obtained product, ink dots are visible and it looks like a print,
Further, due to its water repellency, there is a problem that a large amount of finishing agent is required at the time of finishing processing after printing.
【０００７】[0007]
【発明が解決しようとする課題】本発明者等は、布帛の
インクジェット方式による捺染方法について鋭意研究を
続けた結果既存法の有する諸問題点の悉くが解決された
新規捺染用布帛及びそれを用いた捺染法を見出し本発明
を完成したものである。DISCLOSURE OF INVENTION Problems to be Solved by the Invention The inventors of the present invention, as a result of continuing diligent research on a textile printing method using an ink jet method, have solved a problem of existing methods, and a new textile printing cloth has been used. The present invention has completed the present invention by finding a printing method that was used.
【０００８】本発明の目的は、卓越した鮮明さと捺染品
位を有するインクジェット方式による捺染品を得うる布
帛及びそれを用いた捺染法を提供するにある。An object of the present invention is to provide a cloth capable of obtaining a printed article by an ink jet system having excellent sharpness and printing quality, and a printing method using the same.
【０００９】[0009]
【課題を解決するための手段】上述の目的を達成するた
め、本発明は次の構成を取る。即ち、第１番目の発明
は、撥水剤及び柔軟撥水剤から選ばれる少なくとも１種
が布帛の少なくとも一方の表層部に偏在して付着してい
ると共に、吸水剤が布帛の撥水剤及び柔軟撥水剤から選
ばれる少なくとも１種が付着していない部分に付着して
いることを特徴とするインクジェット捺染用布帛を要旨
とし、また第２番目の発明は、撥水剤及び柔軟撥水剤か
ら選ばれる少なくとも１種を布帛の少なくとも一方の表
層部に偏在して付着せしめた後、吸水剤を布帛の撥水剤
及び柔軟撥水剤から選ばれる少なくとも１種が付着して
いない部分に付着せしめ、しかる後布帛の撥水剤及び柔
軟撥水剤から選ばれる少なくとも１種の偏在付着面側に
インクジェット方式で染料インクを染着させることを特
徴とするインクジェット捺染法を要旨とする。To achieve the above object, the present invention has the following constitution. That is, the first invention is that at least one selected from a water repellent and a soft water repellent is unevenly distributed and attached to at least one surface layer portion of the fabric, and the water absorbing agent is a water repellent of the fabric. A second aspect of the present invention is a water-repellent agent and a soft water-repellent agent, which is characterized in that at least one kind selected from a soft water-repellent agent is attached to a portion to which no water-repellent agent is attached. After at least one kind selected from the above is unevenly distributed on at least one surface layer portion of the cloth, the water absorbing agent is adhered to a part of the cloth where at least one kind selected from a water repellent and a soft water repellent is not adhered. The main point is an inkjet printing method, which comprises dyeing a dye ink by an inkjet method onto at least one unevenly attached surface side of a water repellent agent and a soft water repellent agent of a cloth.
【００１０】以下、本発明を詳細に説明する。The present invention will be described in detail below.
【００１１】本発明において使用される布帛は綿，レー
ヨン，麻，絹，羊毛等の天然繊維、アセテート，トリア
セテート等の半合成繊維、ポリエステル，ナイロン，ア
クリル等の合成繊維及び各種繊維の混紡，交織等よりな
るものである。布帛としては、織物，編物，不織布など
の形態のものが挙げられる。The cloth used in the present invention is a natural fiber such as cotton, rayon, hemp, silk or wool, a semi-synthetic fiber such as acetate or triacetate, a synthetic fiber such as polyester, nylon or acrylic, and a mixed or mixed fabric of various fibers. And so on. Examples of the cloth include woven, knitted, and non-woven fabrics.
【００１２】本発明において、撥水剤は特に限定され
ず、フッ素系化合物，シリコン系化合物，ジルコニウム
系化合物等一般的な撥水剤がいずれも使用できる。ま
た、柔軟撥水剤としてはオクタデシルエチレン尿素，酢
酸ジルコニウム，ポリオレフィン系化合物，ワックス系
化合物，シリコーン系化合物等が挙げられる。かかる撥
水剤及び柔軟撥水剤の量は、乾燥重量で布帛に対して
０．１〜１０％程度の割合で付着するように使用される
のが好ましい。即ち多量に用いると、撥水性が強すぎて
得られた製品が印刷調となり、またその後の仕上加工時
に仕上剤が多量に必要となる等の問題があるので、上記
の割合で用いる。In the present invention, the water repellent is not particularly limited, and any general water repellent such as a fluorine compound, a silicon compound and a zirconium compound can be used. Examples of the soft water repellent include octadecyl ethylene urea, zirconium acetate, polyolefin compounds, wax compounds, silicone compounds and the like. The amounts of the water repellent and the soft water repellent are preferably used so as to be attached to the cloth in a dry weight ratio of about 0.1 to 10%. That is, when used in a large amount, the product obtained becomes too water-repellent to give a print-like product, and a large amount of finishing agent is required during the subsequent finishing processing.
【００１３】本発明において、吸水剤は特に限定され
ず、糊剤，吸水性シリコン塩類等が挙げられる。糊材と
してはデンプン類（デンプン，可溶性デンプン，水溶性
デンプン誘導体等）、水溶性のセルロース誘導体（カル
ボキシメチルセルロース，ヒドロキシエチルセルロー
ス，メチルセルロース等）、アルギン酸ナトリウム、ア
ラビアゴム、ガム類（ローカストビーンガム，グアーガ
ム等）、水溶性タンパク（ゼラチン，にかわ等）、水溶
性の合成高分子化合物（ポリアクリル酸ナトリウム，ポ
リビニルアルコール，ポリエチレンオキシド，ポリビニ
ルピロリドン，ポリアクリルアミド，ポリエチレンイミ
ン，４級化水溶性カチオンポリマー等）等が挙げられ
る。かかる吸水剤の量は、乾燥重量で布帛に対して０．
１〜３％程度の割合で付着するように使用されるのが好
ましい。即ち多量に用いると、風合の変化が大きくなり
過ぎるので、上記の割合で用いる。In the present invention, the water absorbing agent is not particularly limited, and examples thereof include a sizing agent and a water absorbing silicon salt. As the sizing material, starches (starch, soluble starch, water-soluble starch derivative, etc.), water-soluble cellulose derivative (carboxymethylcellulose, hydroxyethylcellulose, methylcellulose, etc.), sodium alginate, gum arabic, gums (locust bean gum, guar gum, etc.) ), Water-soluble proteins (gelatin, glue, etc.), water-soluble synthetic polymer compounds (sodium polyacrylate, polyvinyl alcohol, polyethylene oxide, polyvinylpyrrolidone, polyacrylamide, polyethyleneimine, quaternized water-soluble cationic polymers, etc.) Is mentioned. The amount of such a water absorbing agent is 0.
It is preferably used so as to be attached at a rate of about 1 to 3%. That is, if a large amount is used, the change in the texture becomes too large, so the above ratio is used.
【００１４】そして、上記撥水剤及び柔軟撥水剤から選
ばれる１種には固着反応剤、例えば炭酸ナトリウム，炭
酸水素ナトリウム等のアルカリ性物質やヒドロトロープ
剤例えば尿素，モノメチル尿素，ジメチル尿素，チオ尿
素，モノメチルチオ尿素，ジメチルチオ尿素，ホルムア
ミド，ジメチルホルムアミド，ジメチルアセトアミド等
を加えても良い。One kind selected from the water repellent and the soft water repellent is a sticking reaction agent, for example, an alkaline substance such as sodium carbonate and sodium hydrogen carbonate, and a hydrotrope agent such as urea, monomethylurea, dimethylurea and thiol. Urea, monomethylthiourea, dimethylthiourea, formamide, dimethylformamide, dimethylacetamide, etc. may be added.
【００１５】本発明で肝要なことは、かかる撥水剤及び
柔軟撥水剤から選ばれる１種が布帛の少なくとも一方の
表層部に偏在して付着していると共に、吸水剤が布帛の
撥水剤及び柔軟撥水剤から選ばれる少なくとも１種が付
着していない部分に付着していることである。What is essential in the present invention is that one kind selected from the water repellent and the soft water repellent is unevenly distributed on at least one surface layer portion of the cloth, and the water absorbent is water repellent of the cloth. That is, at least one selected from the agents and the soft water-repellent agent is attached to a portion where it is not attached.
【００１６】布帛の一方の表層部に撥水剤及び柔軟撥水
剤から選ばれる少なくとも 偏在して付着せしめるに
は、例えば撥水剤及び柔軟撥水剤から選ばれる少なくと
も１種を含有する処理液をパッディング法，スプレー法
等により付与した後、片面より例えば１２０℃以上で急
速に乾燥し、処理液を乾燥面側にマイグレーションを起
こさしめる方法や、処理液をコーティング法により付与
せしめる方法等を用いることができる。また両方の表層
部に偏在して付着せしめるには、例えば処理液をパッデ
ィング法，スプレー法等により付与した後、両面より例
えば１３０℃以上で急速に乾燥し、処理液を表層部にマ
イグレーションを起こさしめる方法等を用いることがで
きる。In order to make the water-repellent agent and the soft water-repellent agent at least unevenly distributed on one surface layer of the cloth, for example, a treatment liquid containing at least one kind selected from the water-repellent agent and the soft water-repellent agent. Is applied by a padding method, a spray method, etc., and then rapidly dried at, for example, 120 ° C. or more from one side to cause the treatment liquid to migrate to the dried surface side, or a method for applying the treatment liquid by a coating method. Can be used. Further, in order to make the uneven distribution on both surface layers, for example, after applying the treatment liquid by a padding method, a spray method or the like, the treatment liquid is rapidly dried at, for example, 130 ° C. or more from both surfaces to migrate the treatment liquid to the surface portion. A method of raising it can be used.
【００１７】吸水剤を布帛の撥水剤及び柔軟撥水剤から
選ばれる少なくとも１種が付着していない部分に付着せ
しめるには、吸水剤を含有する処理液をパッディング
法，スプレー法等により付与せしめる方法等を用いるこ
とができる。In order to make the water absorbing agent adhere to a portion of the cloth where at least one selected from the water repellent and the soft water repellent is not adhered, the treatment liquid containing the water absorbing agent is applied by a padding method, a spray method or the like. It is possible to use a method of giving it.
【００１８】その後、布帛の撥水剤及び柔軟撥水剤から
選ばれる少なくとも１種の偏在付着面側にインクジェッ
ト方式により染料インクを付与する。Then, a dye ink is applied by an ink jet method to the side of at least one kind of unevenly distributed surface selected from the water repellent and the soft water repellent of the cloth.
【００１９】本発明に使用するインクジェット方式とし
てはノズル内に発熱抵抗素子を埋め込み、その発熱によ
りインクを沸騰させ、その泡の圧力によりインクを吐出
させるバブルジェット方式、圧電素子に電気信号を加え
て変形させインク室の体積変化を励起してインク粒子を
飛ばすパルスジェット方式、超音波振動しているノズル
からインクを加圧連続噴射させて粒子化し、粒子を荷電
量に制御一定電界中を通過偏向させ、記録，非記録粒子
に分けて記録する荷電制御方式等が挙げられる。As the ink jet method used in the present invention, a heating resistance element is embedded in the nozzle, the ink is boiled by the heat generation, and the ink is ejected by the pressure of the bubble, and an electric signal is applied to the piezoelectric element. Pulse jet method that deforms and excites volume change of ink chamber to fly ink particles, ink is continuously jetted under pressure from nozzles that are vibrating ultrasonically to make particles, and the particles are controlled to charge amount Deflection through a constant electric field A charge control method in which recording is performed separately for recording and non-recording particles can be used.
【００２０】本発明に使用する染料としては、布帛を構
成する繊維構造物の素材に応じて直接染料，反応染料，
酸性染料，カチオン染料，分散染料等を用いることがで
きる。例えば絹繊維に対しては直接染料，酸性染料，反
応染料、綿繊維に対しては直接染料，反応染料、ポリエ
ステル繊維に対しては分散染料、ナイロン繊維には酸性
染料，反応染料などがある。The dyes used in the present invention include direct dyes, reactive dyes, and reactive dyes depending on the material of the fiber structure constituting the cloth.
Acid dyes, cationic dyes, disperse dyes and the like can be used. For example, there are direct dyes, acid dyes and reactive dyes for silk fibers, direct dyes and reactive dyes for cotton fibers, disperse dyes for polyester fibers, and acid dyes and reactive dyes for nylon fibers.
【００２１】本発明において上記の如き染料を溶解もし
くは分散せしめる媒体としては、従来の一般的捺染にお
ける媒体，従来のインクジェット方式に用いられる媒体
が使用出来、水又は水と有機溶剤との混合物が挙げられ
るが、水を用いるのが一般的である。また、染料インク
には各種の分散剤，界面活性剤，粘度調整剤，表面張力
調整剤，ｐＨ調整剤，電導度調整剤等を必要に応じて添
加する。In the present invention, as a medium in which the above dye is dissolved or dispersed, a medium used in conventional general printing or a medium used in a conventional ink jet system can be used, and water or a mixture of water and an organic solvent can be used. However, it is common to use water. Further, various kinds of dispersants, surfactants, viscosity modifiers, surface tension modifiers, pH modifiers, conductivity modifiers, etc. are added to the dye ink as needed.
【００２２】かかる印捺を施した布帛は次に８０〜１２
０℃で乾燥し、次いで染料に応じた方法で染料を固着
し、洗浄，乾燥する。The fabric subjected to such printing is then
It is dried at 0 ° C., then the dye is fixed by a method depending on the dye, washed and dried.
【００２３】布帛の表層部に撥水剤及び柔軟撥水剤より
選ばれた少なくとも１種を付着させることにより、捺染
時にドット状に付着するインクの滲みを防止することが
できるようになり、滲みや混色がなく、染料インクは微
小ドット状に確実に染着されるようになる。更に布帛の
中層部には吸水剤が付着しているので、染料インクは布
帛の中層部にまで浸透しやすくなり、印刷調とならな
い。By adhering at least one selected from a water repellent agent and a soft water repellent agent to the surface layer of the cloth, it becomes possible to prevent the ink from adhering in a dot shape at the time of printing and to prevent the ink from bleeding. There is no color mixture, and the dye ink is surely dyed in the form of fine dots. Further, since the water absorbing agent is attached to the middle layer of the cloth, the dye ink easily penetrates into the middle layer of the cloth, and the print tone is not obtained.
【００２４】[0024]
【実施例】次に実施例に基づき本発明を具体的に説明す
る。EXAMPLES The present invention will be described in detail with reference to Examples.
【００２５】この実施例においては、布帛として経糸５
０番手単糸，緯糸５０番手単糸からなる経密度１３６本
／吋，緯密度７２本／吋の綿平織物を常法にて毛焼，糊
抜，精練，漂白，シルケットの処理を行ったものを用い
た。In this embodiment, the warp yarn 5 is used as the cloth.
Cotton plain fabric with warp density of 136 yarns / inch and weft density of 72 yarns / inch consisting of 0 count single yarn and 50 count single yarn was subjected to quilting, desizing, scouring, bleaching and mercerizing in the usual manner. I used one.
【００２６】該平織物に、アサヒガードＡＧ４８０（旭
硝子社製のフッ素系撥水剤，固型分３０％）３０ｇ／
ｌ、尿素（ヒドロトロープ剤）３０ｇ／ｌ、重炭酸ナト
リウム（固着反応剤）３０ｇ／ｌ及び残部を水で調整し
た処理液をナイフオーバーコータにより片面に付与し、
１２０℃にて２０分間乾燥し、１５０℃にて３分間ベー
キング処理した。尚、撥水剤の付着量は３０ｇ／ｍ2 で
あった。30 g / Asahi Guard AG480 (fluorine-based water repellent manufactured by Asahi Glass Co., Ltd., solid content 30%) on the plain woven fabric
1, urea (hydrotrope agent) 30 g / l, sodium bicarbonate (fixing reaction agent) 30 g / l, and the balance adjusted with water were applied to one side with a knife overcoater,
It was dried at 120 ° C. for 20 minutes and baked at 150 ° C. for 3 minutes. The amount of the water repellent attached was 30 g / m 2 .
【００２７】かかる処理を行った平織物にサンシリコン
Ｍ−８４（三洋化成社製のシリコン系吸水剤，固型分３
０％）５０ｇ／ｌ、ダックアルギンＮＳＰＭ（紀文社製
の中粘度タイプアルギン酸ソーダ）２５ｇ／ｌ及び残部
を水で調整した処理液をパッディング処理し、マングル
で絞り率６５％に絞った後、１２０℃にて２分間乾燥し
た。On the plain woven fabric which has been subjected to such treatment, San Silicon M-84 (a silicon water absorbing agent manufactured by Sanyo Kasei Co., Ltd., a solid component 3
0%) 50 g / l, duck algin NSPM (Kibunsha medium viscosity type sodium alginate) 25 g / l and the rest treated with water, padded, and squeezed to 65% with a mangle. It was dried at 120 ° C. for 2 minutes.
【００２８】このようにして前処理した織物に、Ｃ．
Ｉ．Ｒｅａｃｔｉｖｅ Ｂｌｕｅ １５ １００ｇ／
ｌ、尿素（ヒドロトロープ剤）５０ｇ／ｌ及び残部を水
で調整したインク、及びＣ．Ｉ．Ｒｅａｃｔｉｖｅ Ｒ
ｅｄ ２２ ８０ｇ／ｌ、尿素（ヒドロトロープ剤）５
０ｇ／ｌ及び残部を水で調整したインクを別々にパルス
ジェット方式のインクジェットプリンターに搭載し、８
ドット／ｍｍの連続プリントを行い、次いで１２０℃に
て２分間乾燥し、飽和蒸気１０２℃にて１０分間熱処理
した後、洗浄，乾燥し実施例１の製品を得た。The woven fabric pretreated in this manner was treated with C.I.
I. Reactive Blue 15 100g /
1, urea (hydrotrope agent) 50 g / l and the balance water-adjusted ink, and C.I. I. Reactive R
ed 22 80 g / l, urea (hydrotrope agent) 5
8 g / l and ink with the balance adjusted with water were separately mounted on a pulse jet type inkjet printer, and 8
Dots / mm were continuously printed, then dried at 120 ° C. for 2 minutes, heat-treated at 102 ° C. for 10 minutes in saturated steam, washed and dried to obtain the product of Example 1.
【００２９】比較例１ 実施例１において、撥水剤をコーティングしなかった他
は実施例１と同様の処理を行い、比較例１の製品を得
た。Comparative Example 1 The product of Comparative Example 1 was obtained by performing the same treatment as in Example 1 except that the water repellent was not coated.
【００３０】比較例２ 実施例１と同様の平織物に、アサヒガードＡＧ４８０
３０ｇ／ｌ、尿素３０ｇ／ｌ、重炭酸ナトリウム３０ｇ
／ｌ及び残部を水で調整した処理液をパッディング処理
し、マングルで絞り率６５％に絞った後、１２０℃にて
２分間乾燥し、１５０℃にて３分間ベーキング処理し
た。Comparative Example 2 Asahi Guard AG480 was applied to the same plain weave as in Example 1.
30 g / l, urea 30 g / l, sodium bicarbonate 30 g
/ L and the treatment solution with the balance adjusted to water were padded, squeezed with a mangle to a squeezing ratio of 65%, dried at 120 ° C for 2 minutes, and baked at 150 ° C for 3 minutes.
【００３１】このようにして前処理した平織物に、実施
例１と同様のインクジェットプリントを行い、比較例２
の製品を得た。Inkjet printing similar to that in Example 1 was carried out on the plain fabric pretreated in this way, and Comparative Example 2
Got the product.
【００３２】実施例１，比較例１〜２で得られた製品の
滲み，浸透性，発色性を表１に示す。Table 1 shows the bleeding, penetrability and color developability of the products obtained in Example 1 and Comparative Examples 1 and 2.
【００３３】滲みは１０人の専門検査員の肉眼観察によ
り判断した。その判断基準は次の通りである。 ◎：滲みなし ○：滲み若干有り △：滲みやや有り ×：滲み大The bleeding was judged by visual observation of 10 professional inspectors. The judgment criteria are as follows. ◎: No bleeding ○: Some bleeding △: Some bleeding ×: Large bleeding
【００３４】また、浸透性は１０人の専門検査員の肉眼
観察により判断した。その判断基準は次の通りである。 ◎：浸透性非常に良好 ○：浸透性良好 △：浸透性やや不良 ×：浸透性不良Further, the permeability was judged by visual observation by 10 professional inspectors. The judgment criteria are as follows. ◎: Penetration is very good ○: Penetration is good △: Penetration is slightly poor ×: Penetration is poor
【００３５】また、発色性は１０人の専門検査員の肉眼
観察により判断した。その判断基準は次の通りである。 ◎：発色性非常に良好 ○：発色性良好 △：発色性やや不良 ×：発色性不良The color developability was judged by visual observation by 10 professional inspectors. The judgment criteria are as follows. ⊚: Very good color developability ○: Good color developability Δ: Slightly poor color developability ×: Poor color developability
【００３６】[0036]
【表１】 [Table 1]
【００３７】表１から明らかな様に実施例で得られた製
品は滲みがなく型際が鮮明であり、染料の浸透性が良好
で印刷調のものではなく、発色性に優れ非常に品質のよ
い捺染布帛であった。As is clear from Table 1, the products obtained in the examples had no bleeding, were sharp on the edge of the mold, had good dye permeability, were not in print quality, and had excellent color development and were of very high quality. It was a good printing fabric.
【００３８】[0038]
【発明の効果】本発明のインクジェット捺染用布帛は滲
みがなく、布帛の中層部まで捺染されるので、型際が鮮
明で、印刷調でない高品位な捺染布帛を得ることができ
る。また、本発明は極細線の均一な捺染をも可能とする
ものであり、非常に効率よく、あらゆる分野で品質のよ
い捺染を可能とするものであり、ファッションの多様化
に即応できる実用的なものである。EFFECT OF THE INVENTION Since the ink-jet printing cloth of the present invention has no bleeding and the middle layer of the cloth is printed, it is possible to obtain a high-quality printing cloth having a clear pattern on the edge of the mold. Further, the present invention is capable of uniform printing of ultrafine wires, is very efficient, enables high-quality printing in all fields, and is a practical product that can immediately respond to diversification of fashion. It is a thing.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｂ４１Ｍ 5/00 Ｂ 9221−2Ｈ // Ｄ０６Ｍ 15/00 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Internal reference number FI technical display location B41M 5/00 B 9221-2H // D06M 15/00
Claims (2)
くとも１種が布帛の少なくとも一方の表層部に偏在して
付着していると共に、吸水剤が布帛の撥水剤及び柔軟撥
水剤から選ばれる少なくとも１種が付着していない部分
に付着していることを特徴とするインクジェット捺染用
布帛。1. A water-repellent agent and a soft water-repellent agent, wherein at least one selected from a water-repellent agent and a soft water-repellent agent is unevenly distributed and attached to at least one surface layer portion of the cloth. A fabric for inkjet printing, wherein at least one selected from the above is attached to a portion to which it is not attached.
くとも１種を布帛の少なくとも一方の表層部に偏在して
付着せしめた後、吸水剤を布帛の撥水剤及び柔軟撥水剤
から選ばれる少なくとも１種が付着していない部分に付
着せしめ、しかる後布帛の撥水剤及び柔軟撥水剤から選
ばれる少なくとも１種の偏在付着面側にインクジェット
方式で染料インクを染着させることを特徴とするインク
ジェット捺染法。2. A water repellent is selected from a water repellent and a soft water repellent, after at least one selected from a water repellent and a soft water repellent is unevenly distributed and attached to at least one surface layer of the cloth. At least one selected from the above is adhered to a part where it is not adhered, and then the dye ink is dyed by an inkjet method to the unevenly distributed surface of at least one selected from the water repellent and the soft water repellent of the cloth. Characteristic inkjet printing method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4293817A JP2607451B2 (en) | 1992-10-06 | 1992-10-06 | Fabric for ink-jet printing and printing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4293817A JP2607451B2 (en) | 1992-10-06 | 1992-10-06 | Fabric for ink-jet printing and printing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06123086A true JPH06123086A (en) | 1994-05-06 |
| JP2607451B2 JP2607451B2 (en) | 1997-05-07 |
Family
ID=17799540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4293817A Expired - Fee Related JP2607451B2 (en) | 1992-10-06 | 1992-10-06 | Fabric for ink-jet printing and printing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2607451B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07292573A (en) * | 1994-04-19 | 1995-11-07 | Higashi Kagaku:Kk | Cloth and its finishing method |
| EP0693587A3 (en) * | 1994-07-21 | 1998-04-15 | Canon Kabushiki Kaisha | Ink-jet printing cloth, ink-jet printing process and production process of print |
| WO2006013906A1 (en) | 2004-08-02 | 2006-02-09 | Fujifilm Corporation | Optical film, producing method therefor, polarizing plate and image display apparatus |
| JP2010007192A (en) * | 2008-06-25 | 2010-01-14 | Konica Minolta Ij Technologies Inc | Inkjet printing method |
| US7867571B2 (en) | 2001-02-02 | 2011-01-11 | Schoeller Textil Ag | Textile surface |
-
1992
- 1992-10-06 JP JP4293817A patent/JP2607451B2/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07292573A (en) * | 1994-04-19 | 1995-11-07 | Higashi Kagaku:Kk | Cloth and its finishing method |
| EP0693587A3 (en) * | 1994-07-21 | 1998-04-15 | Canon Kabushiki Kaisha | Ink-jet printing cloth, ink-jet printing process and production process of print |
| US7867571B2 (en) | 2001-02-02 | 2011-01-11 | Schoeller Textil Ag | Textile surface |
| WO2006013906A1 (en) | 2004-08-02 | 2006-02-09 | Fujifilm Corporation | Optical film, producing method therefor, polarizing plate and image display apparatus |
| JP2010007192A (en) * | 2008-06-25 | 2010-01-14 | Konica Minolta Ij Technologies Inc | Inkjet printing method |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2607451B2 (en) | 1997-05-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2952128B2 (en) | Fabric for inkjet printing, inkjet printing method and printed matter | |
| US6352563B1 (en) | Printed cloth and method of manufacturing the same | |
| JP2895697B2 (en) | Textile for printing, ink jet printing method using the same, and printed matter | |
| JP2895695B2 (en) | Fabric for inkjet printing, inkjet printing method and printed matter | |
| JP3474814B2 (en) | Treatment agent for ink-jet printing of cellulosic fiber and / or protein fiber, printing cloth and printing method | |
| JP2607446B2 (en) | Fabric printing method | |
| JPH06123086A (en) | Cloth for ink-jet printing and printing method | |
| JP2732999B2 (en) | Coloring and anti-dyeing method by inkjet method | |
| JP3187562B2 (en) | Fabric printing method | |
| JPH06270596A (en) | Transfer sheet and dyeing method using the same | |
| JPH0657656A (en) | Method for printing fabric | |
| JP2593830B2 (en) | Fabric printing method | |
| JP2607450B2 (en) | Fabric for ink-jet printing and printing method thereof | |
| JPH10183481A (en) | Fabric for ink jet printing and printing method | |
| WO2003054288A1 (en) | Method for textile printing, pre-treating fluid for textile printing and fiber sheet for textile printing | |
| JP2774042B2 (en) | Inkjet printing method | |
| JPH05148775A (en) | Printing of cloth by ink-jet process | |
| JPH0253976A (en) | Dyeing of cloth | |
| JP2607447B2 (en) | Fabric printing method | |
| JP2758788B2 (en) | Inkjet fabric | |
| JPH05148777A (en) | Method for printing cloth | |
| JP2700981B2 (en) | Blur printing by inkjet method | |
| JPH06207383A (en) | Multicolor printed fabric and its production | |
| JP2883714B2 (en) | Fabric printing method | |
| JP3162967B2 (en) | Fabric printing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080213 Year of fee payment: 11 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090213 Year of fee payment: 12 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100213 Year of fee payment: 13 |
|
| LAPS | Cancellation because of no payment of annual fees |