JPH06100350A - Production of faking material - Google Patents

Production of faking material

Info

Publication number
JPH06100350A
JPH06100350A JP25169892A JP25169892A JPH06100350A JP H06100350 A JPH06100350 A JP H06100350A JP 25169892 A JP25169892 A JP 25169892A JP 25169892 A JP25169892 A JP 25169892A JP H06100350 A JPH06100350 A JP H06100350A
Authority
JP
Japan
Prior art keywords
powder
artificial
resultant
hollow capsule
hollow
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP25169892A
Other languages
Japanese (ja)
Inventor
Osamu Sakamoto
修 坂本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Isuzu Motors Ltd
Original Assignee
Isuzu Motors Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Isuzu Motors Ltd filed Critical Isuzu Motors Ltd
Priority to JP25169892A priority Critical patent/JPH06100350A/en
Publication of JPH06100350A publication Critical patent/JPH06100350A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06Acrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10Coating or impregnating
    • C04B20/1055Coating or impregnating with inorganic materials
    • C04B20/1066Oxides, Hydroxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00439Physico-chemical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00456Odorless cements

Abstract

PURPOSE:To improve the heat insulating properties by making white powdery child particles of Al(OH)3 adhere to the surface of a parent particle composed of a fine hollow powder, dispersing the resultant hollow capsule powder as a filler in a resin matrix, molding and hardening it. CONSTITUTION:A fine hollow powder such as an organic microballoon having several score to several hundred mum average particle diameter is used as a parent particle and child particles composed of a white Al(OH)3 powder having several mum average particle diameter are made to adhere to the surface of the parent particle according to the microcapsulation method such as the electrostatic adhesion method so as to prepare a hollow capsule powder. The resultant hollow capsule powder is then used as a filler and mixed in a matrix composed of a liquid methacrylate resin, etc., in a prescribed ratio. The resultant mixture is stirred and uniformly dispersed so as to prepare a raw material of a faking material. The resultant raw material is subsequently molded according to the press molding method or the injection molding method, then cooled and hardened, thus producing the objective prescribed-shape faking material excellent in heat insulating properties, e.g. an artificial marble, an artificial ivory or an artificial wood.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は人工大理石、人工象牙、
人工木材等のフェイク材の製造方法に関するものであ
る。
The present invention relates to an artificial marble, artificial ivory,
The present invention relates to a method for manufacturing a faux material such as artificial wood.

【0002】[0002]

【従来の技術】従来、建材や装飾品等に多くも用いられ
ている人工大理石、人工象牙、人工木材等のフェイク材
は、美観的にも本物に劣らず、かつ安価に製造できるこ
とから、最近では建材等の分野において、その需要が益
々高まっている。
Fake materials such as artificial marble, artificial ivory, and artificial wood, which have been often used for building materials and ornaments, have been recently developed because they are aesthetically inferior and can be manufactured at low cost. In the field of building materials, etc., the demand is increasing more and more.

【0003】このフェイク材のうち、人工大理石に係る
製造方法の一つとして代表的なものに水酸化アルミニウ
ムなどの白色粉末等からなるフィラーを、メタクリル樹
脂等のマトリックス中に均一に分散させ、これを所定の
形状に成形硬化させて製造する方法が知られている。
Of these faux materials, a typical one of the manufacturing methods for artificial marble is to uniformly disperse a filler made of white powder such as aluminum hydroxide in a matrix such as methacrylic resin. There is known a method of manufacturing by molding and hardening the above into a predetermined shape.

【0004】[0004]

【発明が解決しようとする課題】ところで、従来の方法
によって製造されたフェイク材は重量が重い上に、高価
な白色粉末を多量に使用する必要があるため、材料費が
高いといった欠点を有していた。また、これを建材等に
使用する場合には、さらに断熱性、吸音性、吸振性を具
備したものが要求されている。
By the way, the faux material manufactured by the conventional method has a drawback that the weight is heavy and the material cost is high because a large amount of expensive white powder must be used. Was there. Further, when it is used as a building material or the like, it is required to further have heat insulating properties, sound absorbing properties, and vibration absorbing properties.

【0005】そこで、本発明はこの問題点を有効に解決
するために案出されたものであり、その目的は軽量かつ
安価で、しかも断熱性、吸音性、吸振性に優れた新規な
フェイク材の製造方法を提供するものである。
Therefore, the present invention was devised to effectively solve this problem, and its purpose is a novel faux material which is lightweight and inexpensive, and which is excellent in heat insulation, sound absorption and vibration absorption. The present invention provides a method for manufacturing the same.

【0006】[0006]

【課題を解決するための手段】上記課題を解決するため
に本発明は、人工大理石、人工象牙、人工木材等のフェ
イク材の製造方法において、微小中空粉体からなる母粒
子表面に、水酸化アルミニウム等の白色粉体からなる子
粒子を付着させてカプセル化した中空カプセル粉体を形
成した後、該中空カプセル粉体をフィラーとしてメタク
リル樹脂等からなるマトリックス中に均一に分散させ、
その後、これを所定の形状に成形硬化してなるものであ
る。
In order to solve the above-mentioned problems, the present invention provides a method for producing a fake material such as artificial marble, artificial ivory, artificial wood, etc. After forming a hollow capsule powder in which child particles made of white powder such as aluminum are adhered and encapsulated, the hollow capsule powder is uniformly dispersed as a filler in a matrix made of methacrylic resin,
After that, this is molded and cured into a predetermined shape.

【0007】本発明に用いる微小中空粉体としては、い
わゆるマイクロバルーンが最も適している。このマイク
ロバルーンは有機系と無機系の材料からなり、代表的な
ものとしてはガラスバルーン、シリカバルーン、シラス
バルーン、カーボンバルーン、フェノールバルーン、塩
化ビニリデンバルーン、アルミナバルーン、ジルコニア
バルーン等があるが、本発明に用いるものとしては、こ
のうち有機系のマイクロバルーンであるフェノールバル
ーン、塩化ビニリデンバルーンが適している。すなわ
ち、ガラスバルーン、シリカバルーン等の無機系マイク
ロバルーンでは弾力性に乏しいため、カプセル化におけ
る衝撃等によって割れが生ずる虞があるからである。ま
た、使用するマイクロバルーンの大きさはカプセル化等
の都合により、数十〜数百μmの範囲ものが望ましい。
数十μm以下では所望の軽量化や断熱性等を得るために
多量のマイクロバルーンを使用する必要があり、また、
数百μm以上では強度や品質が劣ってしまう虞があるか
らである。
So-called microballoons are most suitable as the micro hollow powder used in the present invention. This microballoon is made of organic and inorganic materials, and typical ones include glass balloons, silica balloons, silas balloons, carbon balloons, phenol balloons, vinylidene chloride balloons, alumina balloons, zirconia balloons, etc. Among these, phenolic balloons and vinylidene chloride balloons, which are organic microballoons, are suitable for use in the invention. That is, since inorganic microballoons such as glass balloons and silica balloons have poor elasticity, they may be cracked by impact or the like during encapsulation. Further, the size of the microballoons used is preferably in the range of several tens to several hundreds of μm due to reasons such as encapsulation.
If the thickness is several tens of μm or less, it is necessary to use a large amount of microballoons in order to obtain desired weight reduction and heat insulation properties.
This is because if the thickness is several hundreds μm or more, the strength and quality may be deteriorated.

【0008】[0008]

【作用】本発明は上述したような製造方法であるため、
母材中に中空部が均一に点在したいわゆる多孔質状のフ
ェイク材が得られる。従って、本発明のフェイク材を従
来のフェイク材と比較した場合、材料密度が低くなって
単位体積辺りの重量が大巾に軽量化され、また、高価な
白色粉体の使用量も減少させることができる。さらに、
このフェイク材中に点在している中空部内のガスが、断
熱、吸音、吸振効果を発揮することになる。尚、このフ
ェイク材を人工大理石等の美観を重視したものに適用し
た場合においても、中空カプセル粉体の母粒子となる微
小中空粉体表面が無機化合物粉体等の白色粉体からなる
子粒子で覆われた状態となっているため、母粒子表面が
露出することがなく、製品の美観を損ねることもない。
Since the present invention is the manufacturing method as described above,
A so-called porous fake material in which hollow portions are uniformly scattered in the base material is obtained. Therefore, when the fake material of the present invention is compared with a conventional fake material, the material density is low, the weight per unit volume is significantly reduced, and the amount of expensive white powder used is also reduced. You can further,
The gas in the hollow portions scattered in the fake material exhibits heat insulating, sound absorbing, and vibration absorbing effects. Even when this faux material is applied to artificial marble or the like that places importance on aesthetics, fine hollow powder particles that are the mother particles of the hollow capsule powder, the surface of which is a white powder such as an inorganic compound powder Since the surface of the mother particle is not exposed, the appearance of the product is not spoiled.

【0009】[0009]

【実施例】以下、本発明の一実施例を添付図面を参照し
ながら詳述する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described in detail below with reference to the accompanying drawings.

【0010】図1は本発明に係る人工大理石の製造方法
の一実施例を示したものである。図示するように、ま
ず、平均粒径が100μm程度の有機系マイクロバルー
ン(エクスパンセル社製、商品名:EXPANCEL)
を母粒子とし、静電付着法等のマイクロカプセル化手段
を用いてその周囲にこれを覆うように、白色度の高い高
品位水酸化アルミニウムからなる平均粒径が数μm程度
の子粒子を連続的に付着させて中空カプセル粉体を製造
する。すなわち、マイクロバルーンの表面が露出して製
品の色合い等に悪影響を与えないようにするためであ
る。
FIG. 1 shows an embodiment of a method for producing an artificial marble according to the present invention. As shown in the figure, first, an organic microballoon having an average particle size of about 100 μm (manufactured by Expancel, trade name: EXPANCEL)
Is used as a mother particle, and a microencapsulation means such as an electrostatic adhesion method is used to cover the periphery of the microencapsulating means. To produce a hollow capsule powder. That is, this is to prevent the surface of the microballoon from being exposed and adversely affecting the color tone of the product.

【0011】次に、この中空カプセル粉体をフィラーと
して、液状のメタクリル樹脂からなるマトリックス中に
所定量混入した後、攪拌機等を用いてこのフィラーをマ
トリックス中に均一に分散させてフェイク原料を形成す
る。そして、この中空カプセル粉体が拡散されたフェイ
ク原材料をホットプレス成形、射出成形等の成形法を用
いて成形した後、冷却硬化させて所望形状のフェイク材
を得ることとなる。
Next, the hollow capsule powder is mixed as a filler into a matrix made of a liquid methacrylic resin in a predetermined amount, and then the filler is uniformly dispersed in the matrix by using a stirrer or the like to form a fake raw material. To do. Then, the fake raw material in which the hollow capsule powder is diffused is molded by a molding method such as hot press molding or injection molding, and then cooled and cured to obtain a fake material having a desired shape.

【0012】図2は本発明の製造方法によって得られた
人工大理石の部分拡大断面図である。図示するように、
この人工大理石は、メタクリル樹脂等のマトリックス1
中に中空カプセル粉体2がフィラーとして均一に分散固
定された状態となっている。また、子粒子4は被覆状態
を損なわずに母粒子3に密着している状態となってお
り、母粒子3の表面が露出して、製品の美観を損ねるよ
うなことはない。
FIG. 2 is a partially enlarged sectional view of the artificial marble obtained by the manufacturing method of the present invention. As shown,
This artificial marble has a matrix 1 such as methacrylic resin.
The hollow capsule powder 2 is uniformly dispersed and fixed therein as a filler. Further, the child particles 4 are in a state of being in close contact with the mother particles 3 without impairing the covering state, and the surface of the mother particles 3 is not exposed and the appearance of the product is not spoiled.

【0013】このようにして得られた本発明に係るフェ
イク材にあっては、単位体積辺りの密度が低いため、フ
ェイク材全体が軽くなり、また、高価な白色粉体の使用
量も減少することになる。また、マトリックス中にフィ
ラーとして中空カプセル粉体が均一に分散されているた
め、中空カプセル粉体内のガスが、断熱、吸音、吸振効
果を発揮することになる。
In the fake material according to the present invention thus obtained, since the density per unit volume is low, the entire fake material becomes lighter and the amount of expensive white powder used also decreases. It will be. Moreover, since the hollow capsule powder is uniformly dispersed as a filler in the matrix, the gas in the hollow capsule powder exhibits heat insulating, sound absorbing, and vibration absorbing effects.

【0014】従って、本発明に係るフェイク材1を人工
大理石として例えば、浴槽やシステムキッチンに用いた
場合では断熱効果による保温性や調理熱の断熱性が向上
し、また、人工木材として壁材に用いた場合は保温性と
共に、吸音効果が向上し、さらには地震等の吸振効果も
向上することになる。
Therefore, when the faux material 1 according to the present invention is used as an artificial marble, for example, in a bathtub or a system kitchen, the heat insulation effect and the heat insulation of cooking heat are improved, and the artificial wood is used as a wall material. When it is used, not only the heat retaining property but also the sound absorbing effect is improved, and further the vibration absorbing effect such as an earthquake is also improved.

【0015】[0015]

【発明の効果】以上要するに本発明によれば、従来のフ
ェイク材に比較して、美観を損なうことなく、軽量化が
達成されるため、運搬や取扱が容易になると共に、コス
トの低減が達成される。さらには優れた断熱性、吸音
性、吸振性を発揮することができるため、エネルギ節約
や快適性及び安全性等が大巾に向上する等といった優れ
た効果を有する。
In summary, according to the present invention, as compared with the conventional fake material, the weight reduction is achieved without spoiling the aesthetic appearance, so that the transportation and handling are facilitated and the cost reduction is achieved. To be done. Furthermore, since excellent heat insulating properties, sound absorbing properties, and vibration absorbing properties can be exhibited, there are excellent effects such as energy saving and a great improvement in comfort and safety.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例を示す工程図である。FIG. 1 is a process chart showing an embodiment of the present invention.

【図2】本発明に係るフェイク材を示す部分拡大断面図
である。
FIG. 2 is a partially enlarged cross-sectional view showing a fake material according to the present invention.

【符号の説明】[Explanation of symbols]

1 マトリックス 2 フィラー(中空カプセル粉体) 3 母粒子 4 子粒子 1 Matrix 2 Filler (hollow capsule powder) 3 Mother particle 4 Child particle

フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 C04B 38/08 B C08K 9/10 KCR 7242−4J // B29B 11/16 9350−4F 15/08 9350−4F B29K 33:00 105:16 Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI Technical display location C04B 38/08 B C08K 9/10 KCR 7242-4J // B29B 11/16 9350-4F 15/08 9350-4F B29K 33:00 105: 16

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 人工大理石、人工象牙、人工木材等のフ
ェイク材の製造方法において、微小中空粉体からなる母
粒子表面に、水酸化アルミニウム等の白色粉体からなる
子粒子を付着させてカプセル化した中空カプセル粉体を
形成した後、該中空カプセル粉体をフィラーとしてメタ
クリル樹脂等からなるマトリックス中に均一に分散さ
せ、その後、これを所定の形状に成形硬化してなること
を特徴とするフェイク材の製造方法。
1. A method for producing a faux material such as artificial marble, artificial ivory, artificial wood, etc., wherein capsules are prepared by adhering child particles made of white powder such as aluminum hydroxide to the surface of mother particles made of fine hollow powder. The method is characterized in that after forming a hollow capsule powder that has been made into a solid form, the hollow capsule powder is uniformly dispersed as a filler in a matrix made of methacrylic resin or the like, and then molded and cured into a predetermined shape. Fake material manufacturing method.
JP25169892A 1992-09-21 1992-09-21 Production of faking material Pending JPH06100350A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP25169892A JPH06100350A (en) 1992-09-21 1992-09-21 Production of faking material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP25169892A JPH06100350A (en) 1992-09-21 1992-09-21 Production of faking material

Publications (1)

Publication Number Publication Date
JPH06100350A true JPH06100350A (en) 1994-04-12

Family

ID=17226679

Family Applications (1)

Application Number Title Priority Date Filing Date
JP25169892A Pending JPH06100350A (en) 1992-09-21 1992-09-21 Production of faking material

Country Status (1)

Country Link
JP (1) JPH06100350A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997005201A1 (en) * 1995-08-01 1997-02-13 The Yokohama Rubber Co., Ltd. Adhesive composition and process for the production thereof
JPH11189721A (en) * 1997-12-26 1999-07-13 Toshiba Silicone Co Ltd Polyorganosiloxane composition having decreased specific gravity
EP1433819A1 (en) * 2001-03-16 2004-06-30 Toshiyuki Yamamuro Light clay and process for producing the same
JP2010144027A (en) * 2008-12-18 2010-07-01 Takenaka Komuten Co Ltd Premix composition for insulation production and insulation
JP2012017382A (en) * 2010-07-07 2012-01-26 Yokohama Rubber Co Ltd:The Material for forming syntactic foam, and method for producing syntactic foam

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997005201A1 (en) * 1995-08-01 1997-02-13 The Yokohama Rubber Co., Ltd. Adhesive composition and process for the production thereof
JPH11189721A (en) * 1997-12-26 1999-07-13 Toshiba Silicone Co Ltd Polyorganosiloxane composition having decreased specific gravity
EP1433819A1 (en) * 2001-03-16 2004-06-30 Toshiyuki Yamamuro Light clay and process for producing the same
EP1433819A4 (en) * 2001-03-16 2005-12-07 Infua Co Ltd Light clay and process for producing the same
JP2010144027A (en) * 2008-12-18 2010-07-01 Takenaka Komuten Co Ltd Premix composition for insulation production and insulation
JP2012017382A (en) * 2010-07-07 2012-01-26 Yokohama Rubber Co Ltd:The Material for forming syntactic foam, and method for producing syntactic foam

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