JPH0580259B2 - - Google Patents

Info

Publication number: JPH0580259B2
Authority: JP; Japan
Prior art keywords: catalyst; alumina; pore volume; pores; angstroms
Prior art date: 1985-10-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP87237070A

Other languages

English (en)

Japanese (ja)

Other versions

JPS6490038A (en

Inventor

Jei Gyatooso Maaku

Eru Erigu Danieru

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Honeywell UOP LLC

Original Assignee

UOP LLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-10-01

Filing date

1987-09-21

Publication date

1993-11-08

1987-09-21 Application filed by UOP LLC filed Critical UOP LLC

1989-04-05 Publication of JPS6490038A publication Critical patent/JPS6490038A/ja

1993-11-08 Publication of JPH0580259B2 publication Critical patent/JPH0580259B2/ja

Status Granted legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 claims description 103
239000011148 porous material Substances 0.000 claims description 73
229930195733 hydrocarbon Natural products 0.000 claims description 60
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 57
150000002430 hydrocarbons Chemical class 0.000 claims description 53
238000000034 method Methods 0.000 claims description 44
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 34
239000000463 material Substances 0.000 claims description 30
238000005984 hydrogenation reaction Methods 0.000 claims description 26
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 21
229910052717 sulfur Inorganic materials 0.000 claims description 21
239000011593 sulfur Substances 0.000 claims description 21
239000001257 hydrogen Substances 0.000 claims description 17
229910052739 hydrogen Inorganic materials 0.000 claims description 17
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 16
229910052759 nickel Inorganic materials 0.000 claims description 16
239000004215 Carbon black (E152) Substances 0.000 claims description 11
239000007788 liquid Substances 0.000 claims description 7
238000001879 gelation Methods 0.000 claims description 5
229910052799 carbon Inorganic materials 0.000 claims description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
239000000203 mixture Substances 0.000 description 22
239000003921 oil Substances 0.000 description 12
-1 Diolefin hydrocarbons Chemical class 0.000 description 10
230000015572 biosynthetic process Effects 0.000 description 10
230000032683 aging Effects 0.000 description 9
239000002245 particle Substances 0.000 description 8
239000000047 product Substances 0.000 description 8
238000004519 manufacturing process Methods 0.000 description 7
239000000376 reactant Substances 0.000 description 7
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
239000002131 composite material Substances 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
238000005804 alkylation reaction Methods 0.000 description 5
239000002585 base Substances 0.000 description 5
150000001993 dienes Chemical class 0.000 description 5
239000007789 gas Substances 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
150000001336 alkenes Chemical class 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
238000006356 dehydrogenation reaction Methods 0.000 description 4
238000009826 distribution Methods 0.000 description 4
239000000017 hydrogel Substances 0.000 description 4
229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
239000007791 liquid phase Substances 0.000 description 4
150000005673 monoalkenes Chemical class 0.000 description 4
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
230000005070 ripening Effects 0.000 description 4
238000012360 testing method Methods 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
150000004996 alkyl benzenes Chemical class 0.000 description 3
230000029936 alkylation Effects 0.000 description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
239000003349 gelling agent Substances 0.000 description 3
229910052736 halogen Inorganic materials 0.000 description 3
150000002367 halogens Chemical class 0.000 description 3
235000010299 hexamethylene tetramine Nutrition 0.000 description 3
239000004312 hexamethylene tetramine Substances 0.000 description 3
239000012535 impurity Substances 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
239000012071 phase Substances 0.000 description 3
239000000243 solution Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
238000009835 boiling Methods 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
238000004581 coalescence Methods 0.000 description 2
238000011109 contamination Methods 0.000 description 2
150000002816 nickel compounds Chemical class 0.000 description 2
229910052763 palladium Inorganic materials 0.000 description 2
229910052697 platinum Inorganic materials 0.000 description 2
239000010970 precious metal Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000011949 solid catalyst Substances 0.000 description 2
WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 2
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 1
150000000475 acetylene derivatives Chemical class 0.000 description 1
239000002253 acid Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
230000003139 buffering effect Effects 0.000 description 1
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
238000001354 calcination Methods 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000004927 clay Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
238000005056 compaction Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical class C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
150000002019 disulfides Chemical class 0.000 description 1
238000005868 electrolysis reaction Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000010304 firing Methods 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000000499 gel Substances 0.000 description 1
239000007863 gel particle Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
239000003317 industrial substance Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
238000006317 isomerization reaction Methods 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229940078494 nickel acetate Drugs 0.000 description 1
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
229910000480 nickel oxide Inorganic materials 0.000 description 1
LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000008188 pellet Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
238000002459 porosimetry Methods 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000011027 product recovery Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000007670 refining Methods 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
238000005987 sulfurization reaction Methods 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

JP62237070A 1985-10-01 1987-09-21 High macro perforated catalyst for selective hydrogenation of olefin hydrocarbon Granted JPS6490038A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US78279085A	1985-10-01	1985-10-01

Publications (2)

Publication Number	Publication Date
JPS6490038A JPS6490038A (en)	1989-04-05
JPH0580259B2 true JPH0580259B2 (ko)	1993-11-08

Family

ID=25127190

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP62237070A Granted JPS6490038A (en)	1985-10-01	1987-09-21	High macro perforated catalyst for selective hydrogenation of olefin hydrocarbon

Country Status (3)

Country	Link
JP (1)	JPS6490038A (ko)
BR (1)	BR8704841A (ko)
ZA (1)	ZA876600B (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102005035816A1 (de) *	2005-07-30	2007-02-01	Oxeno Olefinchemie Gmbh	Verfahren zur Hydrierung von Oxo-Aldehyden mit hohen Estergehalten
FR2909571B1 (fr) *	2006-12-11	2009-10-02	Inst Francais Du Petrole	Catalyseur prepare par impregnation d'une solution aqueuse contenant des particules oxy(hydroxy)de d'un cation en interaction avec une espece moleculaire d'un metal du groupe viii
JP2011083701A (ja) *	2009-10-15	2011-04-28	Jx Nippon Oil & Energy Corp	水素源不純物に対する抗被毒特性に優れた水添触媒及びその製造方法
FR3025728B1 (fr) *	2014-09-11	2018-04-20	IFP Energies Nouvelles	Catalyseur mesoporeux a base de nickel et son utilisation en hydrogenation.

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3793388A (en) *	1972-05-30	1974-02-19	Phillips Petroleum Co	Selective hydrogenation of acetylene from olefins with a nickel on alumina catalyst
US3959400A (en) *	1973-10-01	1976-05-25	Mobil Oil Corporation	Olefin dimerization

1987
- 1987-09-03 ZA ZA876600A patent/ZA876600B/xx unknown
- 1987-09-21 BR BR8704841A patent/BR8704841A/pt not_active IP Right Cessation
- 1987-09-21 JP JP62237070A patent/JPS6490038A/ja active Granted

Also Published As

Publication number	Publication date
BR8704841A (pt)	1989-04-18
ZA876600B (en)	1988-04-27
JPS6490038A (en)	1989-04-05

Legal Events

Date	Code	Title	Description
2004-11-24	R250	Receipt of annual fees	Free format text: JAPANESE INTERMEDIATE CODE: R250
2005-11-22	R250	Receipt of annual fees	Free format text: JAPANESE INTERMEDIATE CODE: R250
2006-11-21	R250	Receipt of annual fees	Free format text: JAPANESE INTERMEDIATE CODE: R250
2007-09-21	EXPY	Cancellation because of completion of term

Publication	Publication Date	Title
US4695560A (en)	1987-09-22	Catalyst for the selective hydrogenation of diolefinic hydrocarbons
CN106604978B (zh)	2020-03-03	具有大于300纳米中值大孔直径的中孔和大孔共混镍活性相的催化剂及其在氢化中的用途
US4347392A (en)	1982-08-31	Process for the selective hydrogenation of a hydrocarbon fraction with 2 or 3 carbon atoms per molecule
JP3831821B2 (ja)	2006-10-11	接触水素化方法およびこの方法において使用可能な触媒
EP1385626B1 (en)	2010-06-02	Process for selective hydrogenation of alkynes and catalyst therefor
US7582805B2 (en)	2009-09-01	Supported catalyst for the selective hydrogenation of alkynes and dienes
CN107454860B (zh)	2020-08-11	具有50至300纳米中值大孔直径的中孔和大孔共混镍活性相催化剂及其在氢化中的用途
US4762956A (en)	1988-08-09	Novel catalyst and process for hydrogenation of unsaturated hydrocarbons
US3821123A (en)	1974-06-28	Olefin isomerization catalyst
JP2000153154A (ja)	2000-06-06	炭化水素流中における不飽和化合物の選択的水素添加のための触媒及び方法
KR20020040789A (ko)	2002-05-30	탈수소화 촉매 반응의 개선
US4734540A (en)	1988-03-29	Catalyst for the selective hydrogenation of polyunsaturated organics
EP0183293B1 (en)	1989-05-24	Catalysts and process for the selective hydrogenation of acetylenes
JPH09173843A (ja)	1997-07-08	選択的水素化触媒及びこの触媒を用いた方法
US4940687A (en)	1990-07-10	Catalyst and process for hydrogenation of unsaturated hydrocarbons
KR20020052170A (ko)	2002-07-02	수소화 촉매
JPH0580259B2 (ko)	1993-11-08
KR101109814B1 (ko)	2012-02-16	올레핀의 선택적 수소화 방법
US6812369B2 (en)	2004-11-02	Hydrotreating catalyst composition and processes therefor and therewith
EP0307520B1 (en)	1991-06-12	High macropore selective hydrogenation catalyst
CN1016165B (zh)	1992-04-08	用于烯烃选择性加氢的富含大孔的催化剂
CA1298269C (en)	1992-03-31	High macropore catalyst for the selective hydrogenation of diolefinic hydrocarbons
KR900004522B1 (ko)	1990-06-29	디올레핀 탄화수소의 선택적 수소화를 위한 마크로포어촉매
AU592456B2 (en)	1990-01-11	High macrapore catalyst for the selective hydrogenation of olefinic hydrocarbons
KR100305482B1 (ko)	2001-12-01	거대기공을가진탈수소반응용촉매