JPH05263189A - High strength cold rolled steel sheet and galvanized high strength cold rolled steel sheet good in formability, and their manufacture - Google Patents

High strength cold rolled steel sheet and galvanized high strength cold rolled steel sheet good in formability, and their manufacture

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Publication number
JPH05263189A
JPH05263189A JP6045292A JP6045292A JPH05263189A JP H05263189 A JPH05263189 A JP H05263189A JP 6045292 A JP6045292 A JP 6045292A JP 6045292 A JP6045292 A JP 6045292A JP H05263189 A JPH05263189 A JP H05263189A
Authority
JP
Japan
Prior art keywords
steel sheet
rolled steel
cold
strength
cold rolled
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP6045292A
Other languages
Japanese (ja)
Inventor
Naoki Yoshinaga
直樹 吉永
Kosaku Shioda
浩作 潮田
Osamu Akisue
治 秋末
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP6045292A priority Critical patent/JPH05263189A/en
Publication of JPH05263189A publication Critical patent/JPH05263189A/en
Withdrawn legal-status Critical Current

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  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Abstract

PURPOSE:To manufacture a high strength cold rolled steel sheet excellent in press formability by preparing a cold rolled steel sheet having a specified componental compsn. in which the content of Mn, Si and P is prescribed under specified conditions. CONSTITUTION:A slab contg., by weight, 0.0003 to 0.01% C, >0.03 to <=0.8% Si, >1.5 to 3.5% Mn, 0.04 to 0.12% P, 0.0005 to 0.015% S, 0.005 to 0.1% Al, 0.0003 to 0.0060% N, 0.003 to 0.1% Ti and >0.0005 to 0.0025% B, and the balance Fe with inevitable impurities is prepd. In this slab, the finish of hot rolling is executed at >=(Ar3-100) deg.C, and it is coiled from a room temp. to 750 deg.C, is cold-rolled at >=60% draft and is subjected to continuous annealing at 700 to 900 deg.C. In this way, the objective Ti-contg. dead soft high strength cold rolled steel sheet having high hardenability in working (WH properties) and high hardenability in coating/baking (BH properties) in a low strain area can be obtd.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、成形性に優れた高強度
冷延鋼板およびその製造方法に関するものであり、特に
低歪域での高加工硬化性(WH性)と高塗装焼付硬化性
(BH性)を有するTi含有極低炭素高強度冷延鋼板に
係るものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a high-strength cold-rolled steel sheet excellent in formability and a method for producing the same, and particularly to high work hardenability (WH property) in a low strain range and high paint bake hardenability. The present invention relates to a Ti-containing ultra low carbon high strength cold rolled steel sheet having (BH property).

【0002】[0002]

【従来の技術】本発明に関する高強度冷延鋼板とは、自
動車、家庭電気製品、建物などにプレス成形をして使用
されるものである。そして、表面処理をしない狭義の冷
延鋼板と、防錆のために例えばZnメッキや合金化Zn
メッキなどの表面処理を施した冷延鋼板の両方を含む。
本発明による鋼板は、成形後の面形状性が良好でかつ優
れた耐デント性を有する深絞り用高強度冷延鋼板である
ので、使用にあたっては板厚を減少すること、すなわち
軽量化が可能となり、地球環境保全に寄与しうるもので
ある。
2. Description of the Related Art The high-strength cold-rolled steel sheet according to the present invention is used by press forming for automobiles, household electric appliances, buildings and the like. And cold-rolled steel sheet in a narrow sense without surface treatment and, for example, Zn plating or alloyed Zn for rust prevention.
Includes both cold-rolled steel sheets that have undergone surface treatment such as plating.
Since the steel sheet according to the present invention is a high-strength cold-rolled steel sheet for deep drawing that has good surface shape after forming and has excellent dent resistance, it is possible to reduce the sheet thickness in use, that is, to reduce the weight. And can contribute to global environment conservation.

【0003】上記本発明に係わる冷延鋼板は、自動車な
どのパネルなどに使用されるので、まず優れた加工性が
要求される。加工性には種々あるが、a)成形品の面形
状が良好であること、特に面歪がなく形状がよく金型に
凍結されること、b)割れずに成形可能なこと、c)表
面にストレッチャーストレインが現れないこと、が必須
である。
Since the cold-rolled steel sheet according to the present invention is used for a panel of an automobile or the like, first of all, excellent workability is required. There are various workability, but a) the surface shape of the molded product is good, especially the surface is free from surface distortion and the shape is well frozen, b) it can be molded without cracking, and c) the surface. It is essential that the stretcher strain does not appear in the.

【0004】そのためには、プレス成形時にYP−El
が0.2%以下で低YPが好ましい。例えば、面歪の観
点からは、降伏強度(YP)が28kgf/mm2 以下である
必要がある。今、引張強度(TS)が35〜50kgf/mm
2 級の鋼板を前提とすると、降伏比(YR=YP/T
S)が0.55以下の低YRの材料が好ましい。成形の
可否は、引張特性値で言えば主に平均塑性歪値(以下平
均r値という)と全伸び(T.El)で決定され、平均
r値が1.5以上でT.Elが35%以上であれば、狙
いとする部品は成形可能である。
For this purpose, YP-El is used for press molding.
Is 0.2% or less, and low YP is preferable. For example, from the viewpoint of surface strain, the yield strength (YP) needs to be 28 kgf / mm 2 or less. Now, the tensile strength (TS) is 35-50kgf / mm
Assuming a grade 2 steel plate, the yield ratio (YR = YP / T
A low YR material having an S) of 0.55 or less is preferable. In terms of tensile property value, the propriety of forming is mainly determined by the average plastic strain value (hereinafter referred to as the average r value) and the total elongation (T.El), and when the average r value is 1.5 or more, the T.E. If El is 35% or more, the target component can be molded.

【0005】一方、強度の観点から考えてみると、プレ
ス成形して塗装焼付後の強度が高いほど好ましい。なぜ
ならば、製品の耐デント性が優れるからである。ここ
で、耐デント性とは完成した自動車に石などが当たる場
合、鋼板に生じる永久的な窪み変形に対する抵抗性を意
味する。そのためには、まずプレス時によく加工硬化し
(高WH)、かつ塗装焼付時に高いBH性が付与され、
塗装焼付後の強度(YP+WH+BH)が高くなること
が必要である。
On the other hand, from the viewpoint of strength, it is preferable that the strength after press molding and baking is high. This is because the product has excellent dent resistance. Here, the dent resistance means resistance to permanent dent deformation that occurs in a steel plate when a completed automobile is hit with stones or the like. For that purpose, first of all, it is well work-hardened at the time of pressing (high WH) and has a high BH property at the time of coating baking,
It is necessary that the strength (YP + WH + BH) after baking is increased.

【0006】すなわち、最終的な目的である高強度鋼板
の利用による板厚減少を可能とするためには、WHが4
kgf/mm2 以上でかつBHも2kgf/mm2 以上、従ってWH
+BHが6kgf/mm2 以上必要となる。しかし、一般的に
はBH量が5kgf/mm2 超となるとストレッチャーストレ
インが発生するので、注意を要する。ここで、WH量と
は2%引張変形時の変形応力からYPを差し引いた量で
あり、一方BH量とは、2%予歪後170℃×20分の
塗装焼付相当の熱処理をして再引張をした際の応力の増
加量である。以上の状況から明らかなように、パネル用
鋼板の板厚の減少が可能になるには、強度と加工性に優
れ、かつ多くの条件を同時に満足する必要がある。
That is, in order to make it possible to reduce the plate thickness by using a high-strength steel plate, which is the final purpose, WH is 4
kgf / mm 2 or more and BH is also 2 kgf / mm 2 or more, therefore WH
+ BH is required to be 6 kgf / mm 2 or more. However, in general, when the BH amount exceeds 5 kgf / mm 2, stretcher strain will occur, so caution is required. Here, the WH amount is an amount obtained by subtracting YP from the deformation stress at the time of 2% tensile deformation, while the BH amount is reheated by heat treatment equivalent to coating baking of 170 ° C × 20 minutes after 2% prestrain. This is the amount of increase in stress when tension is applied. As is clear from the above situation, in order to be able to reduce the plate thickness of the panel steel sheet, it is necessary to have excellent strength and workability and satisfy many conditions at the same time.

【0007】最近の技術進歩により、極低炭素鋼の溶製
が容易になった現在、良好な加工性を有する極低炭素冷
延鋼板の需要は、益々増加しつつある。特に、TiやN
bを単独または複合添加した極低炭素冷延鋼板に関する
加工性向上の技術が多数発表されている。例えば特開昭
58−185752号公報には表面性状を改良したTi
添加深絞用冷延鋼板が開示され、また特開昭59−31
827号公報および特開昭59−38337号公報など
には、TiとNbを複合添加した極低炭素冷延鋼板であ
るが、きわめて良好な加工性を有し、塗装焼付硬化(B
H)性を兼備し、溶融亜鉛メッキ特性にも優れているこ
とを提示している。
Due to recent technological advances, it has become easier to melt ultra-low carbon steel, and the demand for ultra-low carbon cold-rolled steel sheet having good workability is increasing more and more. Especially Ti and N
Many technologies for improving the workability of ultra-low carbon cold-rolled steel sheets in which b is added alone or in combination have been announced. For example, in JP-A-58-185752, Ti having improved surface properties is used.
A cold-rolled steel sheet for added deep drawing is disclosed, and JP-A-59-31
No. 827 and Japanese Patent Laid-Open No. 59-38337 disclose ultra-low carbon cold-rolled steel sheets in which Ti and Nb are added in combination, but they have extremely good workability and have a coating bake hardening (B
H) and also have excellent hot-dip galvanizing properties.

【0008】一方、加工性を確保しつつ強度を上昇させ
るために、従来から多くの試みがなされてきた。特に、
35〜50kgf/mm2 の引張強度を有する鋼板にする場合
には、鋼中にP,Siなどを添加し、これらの固溶体強
化機構を利用して強度を増加してきた。例えば、特公昭
57−57945号公報はTi含有極低炭素鋼にPを添
加して50kgf/mm2 の引張強度を有する鋼板の製造例を
示し、また前記特開昭59−31827号公報において
もTiとNbを添加した極低炭素鋼に主にSiとPを添
加し、引張強度で45kgf/mm2 級までの高強度冷延鋼板
の製造方法を開示している。
On the other hand, many attempts have heretofore been made to increase the strength while ensuring the workability. In particular,
In the case of forming a steel sheet having a tensile strength of 35 to 50 kgf / mm 2 , P, Si, etc. are added to the steel and the strength is increased by utilizing these solid solution strengthening mechanism. For example, Japanese Examined Patent Publication No. 57-57945 shows an example of manufacturing a steel sheet having a tensile strength of 50 kgf / mm 2 by adding P to a Ti-containing ultra-low carbon steel, and also in the above-mentioned Japanese Laid-Open Patent Publication No. 59-31827. Disclosed is a method for producing a high-strength cold-rolled steel sheet having a tensile strength of up to 45 kgf / mm 2 by mainly adding Si and P to an ultra-low carbon steel containing Ti and Nb.

【0009】以上のように従来から強化元素としてP、
次いでSiが多用されている。これは、PやSiは固溶
体強化能が非常に高く少量の添加で強度を上昇でき、か
つ延性や深絞り性がそれほど低下せず、添加コストもそ
れほど上昇しないと考えられてきたからである。しか
し、実際にはこれらの元素だけで強度の上昇を達成しよ
うとすると強度のみならず降伏強度も同時に著しく上昇
するため、面形状不良が発生し、自動車のパネルには使
用が制約される場合がある。また、溶融亜鉛メッキをす
る場合にはメッキ不良をSiが惹起したり、P,Siが
合金化速度を著しく低下させたりするので、生産性が低
下したりする問題がある。
As described above, P is conventionally used as a strengthening element,
Next, Si is frequently used. This is because it has been considered that P and Si have a very high solid solution strengthening ability and can be added with a small amount to increase the strength, the ductility and the deep drawability do not decrease so much, and the addition cost does not increase so much. However, in reality, if an attempt is made to increase the strength only with these elements, not only the strength but also the yield strength will increase significantly at the same time. is there. Further, in the case of hot dip galvanizing, Si causes a plating failure, and P and Si significantly reduce the alloying rate, so that there is a problem that productivity is lowered.

【0010】一方、固溶体強化元素としてMnやCrを
利用することも知られている。特開昭63−19014
1号公報および特開昭64−62440号公報にはMn
をTi含有極低炭素鋼へ添加し、また、特公昭59−4
2742号公報や前記した特公昭57−57945号公
報においては、MnとCrをTi添加極低炭素鋼へ添加
する技術が開示されているが、(i)MnやCrの添加
は、主な添加元素であるPやSiの補助的な役割しかな
く、従って、得られた冷延鋼板も強度のわりには降伏強
度が高く、かつ(ii)上記(i)以外の目的で、例えば
(a)加工硬化率を向上させる、(b)BH性を付与す
る、(c)2次加工性を向上させる、(d)溶融亜鉛メ
ッキのメッキ性を改善する、などの目的で積極的に添加
しているわけでもない。
On the other hand, it is also known to use Mn or Cr as a solid solution strengthening element. JP-A-63-19014
No. 1 and JP-A-64-62440 disclose Mn.
Is added to Ti-containing ultra-low carbon steel, and
Japanese Patent No. 2742 and Japanese Patent Publication No. 57-57945 described above disclose a technique of adding Mn and Cr to a Ti-added ultra-low carbon steel, but (i) Mn and Cr are mainly added. The elements P and Si have only a supplementary role, and therefore the obtained cold-rolled steel sheet also has high yield strength for strength, and (ii) for the purpose other than (i) above, for example, (a) processing Actively added for the purpose of improving the curing rate, (b) imparting BH property, (c) improving secondary workability, (d) improving the plating property of hot dip galvanizing, etc. Not really.

【0011】さらに、特開平2−111841号公報
は、Tiを添加した極低炭素鋼に1.5%以上3.5%
未満のMnを添加した焼付硬化性を有する良加工性冷延
鋼板および溶融亜鉛メッキ鋼板を開示している。多量の
Mnの添加により、Ar3 変態点の低下による熱間圧延
の操業安定性と金属組織の均一性を目的としている。ま
た、一層の延性の向上を目的にCrやVの0.2〜1.
0%までの添加も開示している。しかし、多量のMnや
Crの添加が機械的性質、特に強度と延性のバランスを
改善するという観点からの記述はない。さらに、2次加
工性、化成処理性、メッキ付着性の観点から、Siの添
加量を、0.03%以下としている。しかし、Siは有
効な固溶体強化元素であり、実際にはこれらの特性を大
きく阻害することなく0.03%超添加することも可能
である。
Further, Japanese Patent Laid-Open No. 2-111841 discloses that ultra-low carbon steel containing Ti has a content of 1.5% or more and 3.5% or more.
Disclosed are a good workability cold-rolled steel sheet and a hot-dip galvanized steel sheet having bake hardenability, in which Mn of less than 1 is added. By adding a large amount of Mn, the purpose is to improve the operation stability of hot rolling and the homogeneity of the metal structure due to the reduction of the Ar 3 transformation point. Further, for the purpose of further improving the ductility, 0.2 to 1.
Additions up to 0% are also disclosed. However, there is no description from the viewpoint that the addition of a large amount of Mn or Cr improves the mechanical properties, particularly the balance between strength and ductility. Furthermore, the amount of Si added is 0.03% or less from the viewpoint of secondary workability, chemical conversion treatment property, and plating adhesion. However, Si is an effective solid solution strengthening element, and in practice it is possible to add more than 0.03% without significantly impairing these characteristics.

【0012】[0012]

【発明が解決しようとする課題】自動車のパネルなどに
使用される鋼板には、プレスののちにスプリングバック
や面歪などが生じない良好な面形状性が厳しく要求され
る。ところで、面形状性は、降伏強度が低いほど好まし
いことはよく知られている。しかし、鋼板の高強度化
は、従来技術で述べたように一般に降伏強度の著しい上
昇を伴う。従って、降伏強度の上昇を極力抑制して、強
度の上昇を達成する必要がある。
Steel sheets used for automobile panels and the like are strictly required to have good surface formability such that spring back and surface distortion do not occur after pressing. By the way, it is well known that the lower the yield strength is, the more preferable the surface shape property is. However, increasing the strength of a steel sheet generally involves a marked increase in the yield strength as described in the prior art. Therefore, it is necessary to suppress the increase in yield strength as much as possible and achieve the increase in strength.

【0013】さらに、プレス成形をしたあとの鋼板には
耐デント特性が要求される。耐デント特性は、板厚が一
定の場合、プレス加工して塗装焼付したのちの変形応力
が高いほど良好となる。従って、同じ降伏強度の鋼板を
考えた場合、低歪域での加工硬化能か高く、かつ塗装焼
付硬化能が高いほど、耐デント特性は向上することにな
る。
Further, the steel sheet after press forming is required to have dent resistance. When the plate thickness is constant, the dent resistance property becomes better as the deformation stress after press working and paint baking is higher. Therefore, considering steel sheets having the same yield strength, the higher the work hardening ability in the low strain region and the higher the paint bake hardening ability, the higher the dent resistance property.

【0014】以上から、自動車のパネルなどに使用され
る望ましい高強度鋼板は、降伏強度はそれほど高くな
く、著しく加工硬化し、できれば塗装焼付硬化能を合わ
せ持つ鋼板である。勿論、平均r値(深絞り特性)や伸
び(張出特性)などの加工性にも優れる必要があり、さ
らに常温で実質的に非時効である必要がある。
From the above, desirable high-strength steel sheets used for automobile panels and the like are steel sheets which have not so high yield strength, undergo remarkable work hardening, and, if possible, have paint bake hardening ability. Needless to say, it is also necessary to have excellent workability such as average r value (deep drawing property) and elongation (protrusion property), and it is also necessary to be substantially non-aging at room temperature.

【0015】本発明は、このような要望を満足するもの
であって、鋼中の成分を特定すること、すなわちTi含
有極低炭素鋼板にMnとCrを積極的に添加して、Si
やPを強度の許容する範囲で低下せしめ、これによって
引張強度が40〜50kgf/mm2 、降伏強度が19〜28
kgf/mm2 、低歪域での加工硬化能の指標であるWH量
(2%変形応力−降伏強度)が4kgf/mm2 以上であると
共に塗装焼付硬化能を有し、かつ平均r値と伸びが良好
で、2次加工脆性の生じにくく、さらに必要に応じて溶
融亜鉛メッキ特性も良好な高強度冷延鋼板およびその製
造方法を提供することを目的とするものである。
The present invention satisfies these needs, and specifies the components in the steel, that is, Mn and Cr are positively added to a Ti-containing ultra-low carbon steel sheet to obtain Si.
And P are reduced within the range of allowable strength, whereby the tensile strength is 40 to 50 kgf / mm 2 , and the yield strength is 19 to 28.
kgf / mm 2 , WH amount (2% deformation stress-yield strength), which is an index of work hardening ability in a low strain region, is 4 kgf / mm 2 or more, and has a coating bake hardening ability and an average r value. It is an object of the present invention to provide a high-strength cold-rolled steel sheet having good elongation, less likely to cause secondary work embrittlement, and, if necessary, good hot-dip galvanizing properties, and a method for producing the same.

【0016】[0016]

【課題を解決するための手段】本発明者らは、上記の目
的を達成するために、鋭意研究を遂行し、以下に述べる
ような新知見を得た。すなわち、Tiを添加した極低炭
素鋼をベースに、代表的な固溶体強化元素であるP,S
i,Mn,Crを添加し、冷間圧延、焼鈍、調質圧延後
の引張特性、特に降伏強度と加工硬化現象を詳細に調査
した。その結果、従来から固溶体強化元素として多用さ
れているSi,Pは、(a)まず微量の添加で著しく降
伏強度を上昇させること、(b)その結果低歪域での加
工硬化率が著しく減少することが判明した。一方、従来
固溶体強化元素としてあまり用いられないMn,Crを
添加すると、(a)降伏強度は殆ど上昇せず、引張強度
が上昇する、(c)その結果、低歪域での加工硬化率が
むしろこれらの添加により増加するという、極めて重要
な新知見を得た。
[Means for Solving the Problems] In order to achieve the above-mentioned object, the inventors of the present invention have conducted earnest research and obtained new findings as described below. That is, P and S, which are typical solid solution strengthening elements, are based on ultra low carbon steel containing Ti.
The tensile properties after cold rolling, annealing, and temper rolling, in particular i, Mn, and Cr were added, and the yield strength and work hardening phenomena were investigated in detail. As a result, Si and P, which have been frequently used as solid solution strengthening elements, (a) first increase the yield strength remarkably by adding a small amount, and (b) as a result, the work hardening rate in the low strain region is remarkably reduced. It turned out to do. On the other hand, when Mn and Cr, which have not been used so far as solid solution strengthening elements, are added, (a) the yield strength is hardly increased and the tensile strength is increased. (C) As a result, the work hardening rate in the low strain region is increased. Rather, we have gained a very important new finding that it increases with the addition of these.

【0017】これらの機構についても検討を加えた結
果、(a)降伏強度はFe元素と添加したX元素との原
子半径の差で決定され、原子半径の差が大きいほど増加
する、(b)加工硬化率は転位のすべり挙動と深く関係
し、X元素の添加により積層欠陥エネルギーが低下する
と、転位の交差すべりが困難となる結果転位密度が上昇
し加工硬化率が増加する、という基本原理を構築した。
これによれば、Si,PはFeより著しく原子半径が小
さく、従って原子半径差が大きくなるので降伏強度が著
しく上昇し、Mn,Crは原子半径がFeのそれと極め
て近いので殆ど降伏強度を変化させなかったものと理解
できる。
As a result of investigating these mechanisms, (a) the yield strength is determined by the difference in atomic radius between the Fe element and the added X element, and increases as the difference in atomic radius increases, (b) The work-hardening rate is closely related to the slip behavior of dislocations, and if the stacking fault energy is lowered by the addition of the X element, it becomes difficult to cross-slip dislocations, and as a result, the dislocation density increases and the work-hardening rate increases. It was constructed.
According to this, Si and P have a remarkably smaller atomic radius than Fe, and therefore the difference in atomic radius becomes large, so that the yield strength is remarkably increased, and Mn and Cr have an atomic radius very close to that of Fe, so that the yield strength is almost changed. You can understand that you did not let me.

【0018】一方、加工硬化率と関係する積層欠陥エネ
ルギーへの影響に関しては必ずしも明瞭でないが、初期
加工硬化後の転位構造の電子顕微鏡による詳しい観察結
果から、Si,Pは調査した添加量の範囲内で殆ど積層
欠陥エネルギーに影響を与えないが、Mn,Crはこれ
を低下させる傾向のあることが、初めて明らかとなっ
た。
On the other hand, although the influence on the stacking fault energy related to the work hardening rate is not always clear, from the detailed observation result of the dislocation structure after the initial work hardening by an electron microscope, Si and P are in the range of the added amount investigated. For the first time, it was revealed that Mn and Cr tend to lower the stacking fault energy, although they have almost no effect on the stacking fault energy.

【0019】以上の機構により、Mn,Crを添加する
と降伏強度は殆ど変化せず、加工硬化率が増加して引張
強度が上昇したものと考える。このような特徴的な挙動
は、上述した本発明の目的を達成するためには、従来の
Si,Pの添加より、Mn,Crの添加のほうが好まし
いことを意味する。従って、本発明ではMn,Crの積
極的な活用を従来技術の基本的な解決手段とする。ただ
し、Mn,Crの添加だけでは、所望の強度が得られな
い場合が発生したり、製造コストが上昇したりするの
で、PおよびSiとの併用添加する。
According to the above mechanism, it is considered that when Mn and Cr are added, the yield strength hardly changes, the work hardening rate increases, and the tensile strength increases. Such characteristic behavior means that the addition of Mn and Cr is preferable to the conventional addition of Si and P in order to achieve the above-mentioned object of the present invention. Therefore, in the present invention, the positive use of Mn and Cr is the basic solution to the prior art. However, if only Mn and Cr are added, the desired strength may not be obtained and the manufacturing cost may increase, so P and Si are used in combination.

【0020】さらに本発明者らは、Mn,Crの積極的
な添加によりBH性も向上するという新知見も得た。こ
れは、これらの元素がCと引力の相互作用を有するた
め、TiCやNbCと平衡するマトリックス中の固溶C
をより安定化するので、これらの溶解度積が大きくな
り、焼鈍中に再固溶して残存する固溶C量が増加したも
のと考える。従って、Mn,Crの添加はBH性を付与
するための新しい手段としても活用できる。また、BH
性に寄与する固溶Cは、極低炭素鋼の欠点として知られ
ている2次加工脆化の防止手段として有効である。
Further, the present inventors have obtained new knowledge that the BH property is also improved by positively adding Mn and Cr. This is because these elements have an attractive interaction with C, so solid solution C in the matrix that equilibrates with TiC or NbC.
It is considered that since these are more stabilized, the solubility products of these become larger and the amount of solid solution C remaining after re-solid solution during annealing increases. Therefore, addition of Mn and Cr can be utilized as a new means for imparting BH property. Also, BH
Soluble C, which contributes to the property, is effective as a means for preventing secondary work embrittlement, which is known as a drawback of ultra-low carbon steel.

【0021】さらに本発明者らは、従来鋼において強化
元素として多用されているSi,Pの添加量を抑制し、
Mn,Crを活用する本発明鋼が、特にゼンジマー方式
の連続溶融亜鉛メッキプロセスによる合金化溶融亜鉛メ
ッキ鋼板の製造において、次のような長所を有する新知
見も得た。すなわち、Si,PはZnとFeの合金化反
応を抑制するため、これらの元素を多量に含む鋼板を製
造するときには、ラインスピードを減少させ生産性を低
下せざるを得なかった。また、Siの添加はメッキ密着
性を劣化し、プレス成形時に種々の問題を生じた。一
方、Mn,Crの添加は、本発明の範囲内において、こ
のような悪影響をもたらさず、むしろMnは改善するこ
とが判明した。
Furthermore, the present inventors suppress the addition amount of Si and P, which are often used as strengthening elements in conventional steel,
The present invention steel utilizing Mn and Cr has the following new advantages, especially in the production of galvannealed steel sheet by the continuous hot dip galvanizing process of the Zenzimer system. That is, since Si and P suppress the alloying reaction between Zn and Fe, when producing a steel sheet containing a large amount of these elements, the line speed had to be reduced and the productivity had to be reduced. Further, the addition of Si deteriorates the adhesion of plating and causes various problems during press molding. On the other hand, it has been found that the addition of Mn and Cr does not cause such an adverse effect within the scope of the present invention, but rather improves Mn.

【0022】本発明は、このような思想と新知見に基づ
いて構築されたものであり、その要旨とするところは、
重量%で、C:0.0003〜0.01%、Si:0.
03超〜0.8%以下、Mn:1.5超〜3.5%、
P:0.04〜0.12%、S:0.0005〜0.0
15%、Al:0.005〜0.1%、N:0.000
3〜0.0060%、Ti:0.003〜0.1%、
B:0.0005超〜0.0025%を含有し、残部F
eおよび不可避的不純物からなる成形性に優れた冷延鋼
板および溶融亜鉛メッキ冷延鋼板で必要によりCr:
0.01〜3.0%を含有することができる。
The present invention is constructed on the basis of such an idea and new knowledge, and the gist thereof is as follows.
% By weight, C: 0.0003 to 0.01%, Si: 0.
More than 03 to 0.8%, Mn: more than 1.5 to 3.5%,
P: 0.04-0.12%, S: 0.0005-0.0
15%, Al: 0.005-0.1%, N: 0.000
3 to 0.0060%, Ti: 0.003 to 0.1%,
B: more than 0.0005 to 0.0025%, balance F
e and unavoidable impurities in a cold-rolled steel sheet and a hot-dip galvanized cold-rolled steel sheet, which have excellent formability, and if necessary Cr:
It may contain 0.01 to 3.0%.

【0023】さらに本発明は上記の化学成分よりなるス
ラブを(Ar3 −100)℃以上の温度で熱間圧延の仕
上げを行い、室温から750℃の温度で巻取り、60%
以上の圧延率で冷間圧延を行い、連続焼鈍における焼鈍
温度を700〜900℃とする冷延鋼板の製造方法であ
り、さらに上記の化学成分よりなるスラブを(Ar3
100)℃以上の温度で熱間圧延の仕上げを行い、室温
から750℃の温度で巻取り、60%以上の圧延率で冷
間圧延を行い、焼鈍温度を700〜900℃のインライ
ン焼鈍型溶融亜鉛メッキを施す溶融亜鉛メッキ冷延鋼板
の製造方法である。
Further, according to the present invention, the slab having the above chemical composition is hot-rolled at a temperature of (Ar 3 -100) ° C. or higher, and wound at a temperature of room temperature to 750 ° C. to 60%.
This is a method for producing a cold-rolled steel sheet in which cold rolling is performed at the above rolling rate and the annealing temperature in continuous annealing is 700 to 900 ° C., and a slab composed of the above chemical components is (Ar 3
Finishing hot rolling at a temperature of 100) ° C or higher, winding at a temperature of room temperature to 750 ° C, cold rolling at a rolling rate of 60% or higher, and in-line annealing type melting at an annealing temperature of 700 to 900 ° C. It is a method of manufacturing a galvanized cold-rolled steel sheet that is galvanized.

【0024】[0024]

【作用】ここに本発明において鋼組成および製造条件を
上述のように限定する理由についてさらに説明する。C
は成品の材質特性を決定する極めて重要な元素であり、
0.0003%未満になると粒界強度が低下し、2次加
工脆性が発生する。またBH性の改善もなく、かつ製造
コストが著しく増加するので、その下限を0.0003
%とする。一方、0.01%超になると強度は上昇する
が、成形性が著しく低下する。従って、その上限を0.
01%とする。
The reason why the steel composition and manufacturing conditions are limited as described above in the present invention will be further described. C
Is an extremely important element that determines the material properties of the product,
If it is less than 0.0003%, the grain boundary strength decreases and secondary work embrittlement occurs. Moreover, since the BH property is not improved and the manufacturing cost is significantly increased, the lower limit is set to 0.0003.
%. On the other hand, if it exceeds 0.01%, the strength is increased, but the formability is significantly lowered. Therefore, the upper limit is set to 0.
It is set to 01%.

【0025】Siは、安価に強度を上昇する元素として
知られており、その添加量は狙いとする強度レベルに応
じて変化するが、下限を0.03%超とする。一方、添
加量が0.8%超となると、降伏強度が上昇しすぎてプ
レス時に面歪が発生する。さらに化成処理性の低下、溶
融亜鉛メッキの密着性の低下、合金化反応の遅延による
生産性の低下などの問題が発生するので、その上限を
0.8%とする。
Si is known as an element that increases the strength at a low cost, and the addition amount thereof changes depending on the target strength level, but the lower limit is made 0.03% or more. On the other hand, if the addition amount exceeds 0.8%, the yield strength increases excessively and surface strain occurs during pressing. Further, problems such as deterioration of chemical conversion treatment, deterioration of adhesion of hot dip galvanizing, and deterioration of productivity due to delay of alloying reaction occur, so the upper limit is made 0.8%.

【0026】Mnは、降伏強度をあまり上昇させず強度
を増加させる有効な固溶体強化元素であり、かつ焼付硬
化能を付与したり、化成処理性や溶融亜鉛メッキ性を改
善する効果も有するので、本発明においては積極的に添
加する。このような効果を表わすには1.5%超の添加
を必要とする。一方、3.5%を超えると焼鈍後低温変
態生成物が増加し、降伏強度が著しく増加したり延性が
低下したりする。さらに、平均r値も低下するのでその
上限を3.5%とする。
Mn is an effective solid solution strengthening element that does not significantly increase the yield strength and increases the strength, and also has the effect of imparting bake hardenability and improving the chemical conversion treatment property and hot dip galvanizing property. In the present invention, it is positively added. Addition of more than 1.5% is required to exhibit such effects. On the other hand, if it exceeds 3.5%, the low temperature transformation product after annealing increases, the yield strength remarkably increases, and the ductility decreases. Furthermore, the average r value also decreases, so the upper limit is made 3.5%.

【0027】CrもMn同様、降伏強度を殆ど上昇させ
ず強度を増加させる有効な元素であり、かつ焼付硬化能
を付与するので、本発明では積極的に利用する。しか
し、その含有量が0.01%未満では効果が現れず、上
記効果を顕著に発揮させるためには0.3%超であるこ
とが好ましい。また、3%を超えると熱延板の酸洗性が
低下したり、製品板の化成処理性が劣化したりするの
で、その範囲を0.01〜3%とする。
Like Mn, Cr is an effective element that does not substantially increase the yield strength and increases the strength, and imparts the bake hardenability, so that it is positively used in the present invention. However, if the content is less than 0.01%, the effect does not appear, and in order to exert the above effects remarkably, it is preferably more than 0.3%. Further, if it exceeds 3%, the pickling property of the hot-rolled sheet deteriorates or the chemical conversion treatment property of the product sheet deteriorates, so the range is made 0.01 to 3%.

【0028】PはSi同様、安価に強度を上昇する元素
として知られており、狙いとする強度レベルに応じてそ
の添加量を変化させることができる。すなわち、引張強
度を上昇させるためには、その添加量を適宜調整する
が、極低炭素鋼をベースに引張強度が35kgf/mm2 以上
の鋼板を製造するには通常0.04%以上は必要であ
る。しかし、添加量が0.12%超となると、降伏強度
が上昇しすぎてプレス時に面形状不良を引き起こす。さ
らに、連続溶融亜鉛メッキ時に合金化反応が極めて遅く
なり、生産性が低下する。また、2次加工脆化も発生す
る。従って、上限値を、0.12%とする。
Like Si, P is known as an element that increases strength at a low cost, and the amount of P added can be changed according to the target strength level. That is, in order to increase the tensile strength, the addition amount is appropriately adjusted, but 0.04% or more is usually required to manufacture a steel sheet having a tensile strength of 35 kgf / mm 2 or more based on ultra-low carbon steel. Is. However, if the addition amount exceeds 0.12%, the yield strength increases excessively and causes a surface shape defect during pressing. Furthermore, the alloying reaction becomes extremely slow during continuous hot dip galvanizing, which lowers productivity. In addition, secondary processing embrittlement also occurs. Therefore, the upper limit value is 0.12%.

【0029】S量は低い方が好ましいが、0.0005
%未満になると製造コストが上昇するので、これを下限
値とする。一方、0.015%超になるとMnSやTi
Sなどの硫化物が数多く析出し、加工性が劣化するの
で、これを上限値とする。Alは脱酸調整に使用する
が、0.005%未満ではTiの添加歩留りが低下す
る。一方、0.1%超になるとコスト上昇を招く。
The lower the S content, the better, but 0.0005
If it is less than%, the manufacturing cost increases, so this is made the lower limit. On the other hand, if it exceeds 0.015%, MnS and Ti
A large amount of sulfides such as S precipitate and the workability deteriorates, so this is made the upper limit. Al is used for adjusting the deoxidation, but if it is less than 0.005%, the yield of addition of Ti decreases. On the other hand, if it exceeds 0.1%, the cost increases.

【0030】Tiは、NあるいはCやSの一部あるいは
全部を固定することにより、極低炭素鋼の加工性と非時
効性を確保する役割を有する。Tiは、全量のNをTi
Nとして固定するので、Ti=Ti−3.4Nとした
時2≦Ti/C≦20とすることが好ましく、かつ
0.003〜0.10%とする。Tiが0.003%未
満ではその添加効果が現れず、一方、0.10%超とな
ると著しい合金コストの上昇を招くからである。
By fixing a part or all of N, C or S, Ti has a role of ensuring the workability and non-aging property of the ultra low carbon steel. Ti is the total amount of N
Since it is fixed as N, when Ti * = Ti-3.4N, it is preferable that 2 ≦ Ti * / C ≦ 20, and 0.003 to 0.10%. This is because if Ti is less than 0.003%, the effect of addition is not exhibited, while if it exceeds 0.10%, the alloy cost is significantly increased.

【0031】Nは低い方が好ましい。しかし、0.00
03%未満にするには著しいコスト上昇を招く。一方、
余り多いと多量のTiやAlの添加が必要になったり、
加工性が劣化したりするので、0.0060%を上限値
とする。
Lower N is preferable. But 0.00
If it is less than 03%, a significant cost increase will occur. on the other hand,
If it is too much, it becomes necessary to add a large amount of Ti or Al.
Since the workability is deteriorated, 0.0060% is made the upper limit value.

【0032】Bは、Nが事前に固定されている場合には
結晶粒界に偏析し、2次加工脆化の防止に有効であり、
0.0005%以下では、その効果が不充分であるが、
0.0025%超になると添加コストの上昇や加工性の
劣化の原因となるので、この範囲とした。
B is segregated at the grain boundaries when N is fixed in advance, and is effective in preventing secondary work embrittlement.
If less than 0.0005%, the effect is insufficient,
If it exceeds 0.0025%, it causes the increase of the addition cost and the deterioration of the workability.

【0033】本発明は以上のように構成されるが、この
ような成分で所望の特性を持つ高強度冷延鋼板とするに
は、以下の方法で製造することが好ましい。すなわち、
通常の方法で製造したスラブを熱延するに際し、その仕
上げ温度を、成品板の加工性を確保するという観点から
Ar3 −100℃以上とし、また、巻取り温度を室温か
ら750℃とするのがよい。
The present invention is constructed as described above, but in order to obtain a high strength cold rolled steel sheet having the desired characteristics with such components, it is preferable to manufacture it by the following method. That is,
When hot-rolling the slab manufactured by the usual method, the finishing temperature is set to Ar 3 −100 ° C. or higher from the viewpoint of ensuring the workability of the product sheet, and the winding temperature is set to room temperature to 750 ° C. Is good.

【0034】本発明はその成品材質が熱延巻取り温度の
影響をあまり受けないという特徴を有する。これは、N
がTiNとして固定された極低炭素鋼であるということ
に加え、MnやCrなどをかなり添加しており熱延板の
組織が著しく微細で均一化していることも一因と考えら
れる。巻取り温度で750℃を上限目標としたのは、コ
イル両端部での材質劣化に起因する歩留り減少を防止す
る観点からである。
The present invention is characterized in that the product material thereof is not so much affected by the hot rolling coiling temperature. This is N
In addition to being an ultra-low carbon steel fixed as TiN, Mn, Cr, etc. are considerably added, and the structure of the hot-rolled sheet is remarkably fine and uniform. The upper limit of the coiling temperature of 750 ° C. is set from the viewpoint of preventing a decrease in yield due to material deterioration at both ends of the coil.

【0035】冷間圧延は通常の条件でよく、焼鈍後の深
絞り性を確保する目的から、その圧下率は60%以上と
する。連続焼鈍あるいはライン内焼鈍方式の連続溶融Z
nメッキ設備の焼鈍温度は、700℃〜900℃とする
のがよく、焼鈍温度が700℃未満では、再結晶が不充
分であること、また、加工性やBH性は焼鈍温度の上昇
とともに向上するが、900℃超では高温すぎて板破断
や板の平坦度が悪化するからである。
Cold rolling may be performed under normal conditions, and the rolling reduction is set to 60% or more for the purpose of ensuring deep drawability after annealing. Continuous melting Z with continuous annealing or in-line annealing
The annealing temperature of the n-plating equipment is preferably 700 ° C. to 900 ° C. When the annealing temperature is less than 700 ° C., recrystallization is insufficient, and the workability and BH property are improved as the annealing temperature rises. However, if the temperature exceeds 900 ° C., the temperature will be too high and the plate breakage or the flatness of the plate will be deteriorated.

【0036】かくして、本発明によれば、引張強度が4
0〜50kgf/mm2 、降伏強度が19〜28kgf/mm2 、低
歪域での加工硬化能の指標であるWH量(2%変形応力
−降伏強度)が4kgf/mm2 以上で2kgf/mm2 以上のBH
性を有し、かつ平均r値と伸びも良好な高強度冷延鋼板
が製造される。
Thus, according to the present invention, the tensile strength is 4
0 to 50 kgf / mm 2 , yield strength 19 to 28 kgf / mm 2 , WH amount (2% deformation stress-yield strength), which is an index of work hardening ability in low strain region, is 2 kgf / mm 2 or more 4 kgf / mm 2. 2 or more BH
A high-strength cold-rolled steel sheet having good properties and good average r value and elongation is manufactured.

【0037】[0037]

【実施例】【Example】

〔実施例1〕表1に示す組成を有する鋼を溶製し、スラ
ブ加熱温度1150℃、仕上げ温度900℃、巻取り温
度680℃で熱間圧延し、4.0mm厚の鋼板とした。酸
洗後、80%の圧下率の冷間圧延を施し0.8mmの冷延
板とし、次いで均熱840℃で連続焼鈍をした。さら
に、0.5%の圧下率の調質圧延をし、JIS5号引張
試験片を採取し引張試験に供した。引張試験結果をまと
めて表2に示す。
Example 1 Steels having the compositions shown in Table 1 were melted and hot-rolled at a slab heating temperature of 1150 ° C., a finishing temperature of 900 ° C. and a winding temperature of 680 ° C. to obtain 4.0 mm thick steel plates. After pickling, cold rolling with a reduction rate of 80% was performed to obtain a 0.8 mm cold-rolled sheet, and then continuous annealing was performed at a soaking temperature of 840 ° C. Further, temper rolling was carried out at a rolling reduction of 0.5%, and JIS No. 5 tensile test pieces were sampled and subjected to a tensile test. The results of the tensile test are summarized in Table 2.

【0038】[0038]

【表1】 [Table 1]

【0039】[0039]

【表2】 [Table 2]

【0040】ここで、本発明において重要となるWH量
は、圧延方向に2%の引張歪を付加した時の加工硬化量
であり、2%変形応力から降伏応力(YP)を差し引い
た量である。また、BH量は2%予歪材に170℃×2
0分の塗装焼付相当の熱処理を施してから再度引張試験
を行った場合の応力の上昇量(再引張試験時の下降伏応
力から2%変形応力を差し引いた値)である。また、2
次加工脆化遷移温度は、調質圧延した鋼板から直径50
mmのブランクを打ち抜き、次いで直径33mmのポンチで
カップ成形し、これに種々の温度で落重試験を施した場
合の延性−脆性遷移温度である。
Here, the WH amount which is important in the present invention is the work hardening amount when a tensile strain of 2% is applied in the rolling direction, which is the amount obtained by subtracting the yield stress (YP) from the 2% deformation stress. is there. The BH content is 2% prestrained material at 170 ° C x 2
It is the amount of increase in stress (value obtained by subtracting 2% deformation stress from the falling yield stress at the time of re-pulling test) when the tensile test is carried out again after the heat treatment equivalent to coating baking for 0 minutes. Also, 2
Subsequent embrittlement transition temperature is 50 mm from the temper-rolled steel plate.
The ductile-brittle transition temperature when a blank of mm is punched out, then cup-formed with a punch having a diameter of 33 mm, and subjected to a drop weight test at various temperatures.

【0041】表2から明らかなように、本発明鋼は、従
来鋼の同レベルの引張試験を有する高強度鋼板と比較し
て降伏強度が低く面形状性が良好であり、WHとBH量
が高いので、例えば自動車の外・内板パネルには好適の
材料である。すなわち、本発明鋼は従来鋼と比較して、
同一強度でも降伏強度が低くプレス後の面形状が良好と
なることが期待できる。
As is clear from Table 2, the steel of the present invention has a lower yield strength, a better surface shape, and a higher WH and BH content than the high strength steel sheet having the same level of tensile test as the conventional steel. Because of its high price, it is a suitable material for outer and inner panel of automobiles, for example. That is, the steel of the present invention, compared with the conventional steel,
It can be expected that the yield strength is low and the surface shape after pressing is good even with the same strength.

【0042】一方、図1に示すように、本発明鋼は、従
来鋼と比較して降伏強度が同一でも(WH+BH)量が
高いので耐デント特性(σd =YP+WH+BH)も同
時に改善される。さらに、表2に示すように本発明鋼は
従来鋼よりP,Siの添加量が少なく、MnやCrを多
量に添加しているのでBH量も高く、耐2次加工脆性に
も優れている。ここで、鋼1−4は、Ti<3.4Nと
なるため製品板を100℃で1時間人工時効すると降伏
点伸び(YP−El)が1.0%も生じた。これでは、
プレス時にストレッチャーストレインが発生する。
On the other hand, as shown in FIG. 1, the steel of the present invention has a higher (WH + BH) amount than the conventional steel even if the yield strength is the same, so that the dent resistance (σ d = YP + WH + BH) is simultaneously improved. Further, as shown in Table 2, the steel of the present invention has a smaller amount of P and Si added than the conventional steel and a large amount of Mn and Cr, so that the BH content is high and the secondary work embrittlement resistance is also excellent. .. Here, Steel 1-4 had Ti <3.4N, so when the product plate was artificially aged at 100 ° C. for 1 hour, yield point elongation (YP-El) of 1.0% occurred. With this,
Stretcher strain occurs during pressing.

【0043】〔実施例2〕表1の1−1,1−2,1−
3,2−1,2−2,2−3に示す組成を有する鋼を溶
製し、スラブ加熱温度1150℃、仕上げ温度900
℃、巻取り温度680℃の条件で熱間圧延し、4.0mm
厚の鋼板とした。酸洗後、80%の圧下率の冷間圧延を
施し0.8mmの冷延板とし、次いで最高加熱温度840
℃まで加熱してから冷却し、460℃で慣用の溶融亜鉛
メッキを行い(浴中Al濃度は0.11%)、さらに加
熱して520℃で20秒間合金化処理後約10℃/秒で
室温まで冷却した。得られた合金化亜鉛メッキ鋼板につ
いて機械的性質、メッキ密着性、およびメッキ皮膜中の
Fe濃度を測定した。これらの結果も表3にまとめて示
す。
Example 2 1-1, 1-2, 1-of Table 1
Steel having the composition shown in 3,2-1,2-2,2-3 is melted, and the slab heating temperature is 1150 ° C and the finishing temperature is 900.
Hot rolled at ℃, winding temperature 680 ℃, 4.0mm
It was a thick steel plate. After pickling, cold rolling with a reduction rate of 80% is applied to make a cold-rolled sheet of 0.8 mm, and then the maximum heating temperature is 840.
After heating to ℃, cooling, and conventional hot dip galvanizing at 460 ℃ (Al concentration in the bath is 0.11%), further heating at 520 ℃ for 20 seconds after alloying treatment at about 10 ℃ / second Cooled to room temperature. The obtained galvannealed steel sheet was measured for mechanical properties, plating adhesion, and Fe concentration in the plating film. These results are also summarized in Table 3.

【0044】[0044]

【表3】 [Table 3]

【0045】ここで、メッキ密着性は180°密着曲げ
を行い、亜鉛皮膜の剥離状況を、曲げ加工部にセロテー
プを接着したのち、これをはがしてテープに付着した剥
離メッキ量から判定した。評価は、下記の5段階とし
た。 1…剥離大、2…剥離中、3…剥離小、4…剥離少量、
5…剥離全く無 また、メッキ層中のFe濃度は、X線回折によって求め
た。
Here, the plating adhesion was determined by determining the peeling condition of the zinc coating after the cellophane tape was bonded to the bent portion after peeling the zinc coating by 180 ° contact bending, and then peeling and peeling the tape. The evaluation was made into the following 5 grades. 1 ... Large peeling, 2 ... During peeling, 3 ... Small peeling, 4 ... Small peeling,
5 ... No peeling at all The Fe concentration in the plating layer was determined by X-ray diffraction.

【0046】表3から明らかなように、本発明鋼は従来
鋼と比較して低YPで、かつWHとBH量が高く、耐デ
ント性と対応するσd も向上する。これは、実施例1で
も確認された点である。さらに、従来鋼と比較し本発明
鋼はメッキ密着性が良好であり、合金層中のFe濃度も
望ましい相と考えられているδ1 相のそれに相当する量
となっている。これは、本発明においてはメッキ密着性
を劣化させるSiや合金化反応を抑制するPやSiを極
力低減し、MnやCrを添加して強度を上昇させている
ためと考えられる。
As is clear from Table 3, the steel of the present invention has a low YP, a high WH and BH content, and a high dent resistance and corresponding σ d as compared with the conventional steel. This is the point confirmed also in Example 1. Further, the steel of the present invention has better plating adhesion than the conventional steel, and the Fe concentration in the alloy layer is also an amount corresponding to that of the δ 1 phase considered to be a desirable phase. This is considered to be because in the present invention, Si that deteriorates the plating adhesion and P and Si that suppress the alloying reaction are reduced as much as possible, and Mn and Cr are added to increase the strength.

【0047】[0047]

【発明の効果】本発明により従来にないプレス成形性に
優れた高強度冷延鋼板が得られる。また、本発明鋼は溶
融亜鉛メッキ特性も良好であり、防錆機能も発揮でき
る。その結果、本発明鋼を自動車のボディやフレームな
どに使用すると、板厚の軽減すなわち車体の軽量化が可
能となるので、最近話題となっている地球環境の保全に
も本発明は大きく寄与できる。
EFFECTS OF THE INVENTION According to the present invention, a high-strength cold-rolled steel sheet excellent in press formability that has never been obtained can be obtained. Further, the steel of the present invention has good hot-dip galvanizing properties and can also exhibit a rust preventive function. As a result, when the steel of the present invention is used for the body and frame of automobiles, the thickness of the plate can be reduced, that is, the weight of the vehicle body can be reduced. Therefore, the present invention can greatly contribute to the conservation of the global environment, which has been a hot topic recently. ..

【図面の簡単な説明】[Brief description of drawings]

【図1】降伏強度とσd (デント特性の指標)との関係
を示す図表である。
FIG. 1 is a chart showing the relationship between yield strength and σ d (index of dent characteristics).

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 C22C 38/14 C23C 2/40 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Internal reference number FI Technical indication C22C 38/14 C23C 2/40

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 重量%で、 C :0.0003〜0.01%、 Si:0.03超〜0.8%以下、 Mn:1.5超〜3.5%、 P :0.04〜0.12%、 S :0.0005〜0.015%、 Al:0.005〜0.1%、 N :0.0003〜0.0060%、 Ti:0.003〜0.1%、 B :0.0005超〜0.0025% 残部Feおよび不可避的不純物からなる成形性に優れた
冷延鋼板および溶融亜鉛メッキ冷延鋼板。
1. By weight%, C: 0.0003 to 0.01%, Si: more than 0.03 to 0.8%, Mn: more than 1.5 to 3.5%, P: 0.04. -0.12%, S: 0.0005-0.015%, Al: 0.005-0.1%, N: 0.0003-0.0060%, Ti: 0.003-0.1%, B: more than 0.0005 to 0.0025% A cold-rolled steel sheet and a hot-dip galvanized cold-rolled steel sheet that are excellent in formability and consist of the balance Fe and unavoidable impurities.
【請求項2】 Cr:0.01〜3.0%を含有する請
求項1に記載の冷延鋼板および溶融亜鉛メッキ冷延鋼
板。
2. The cold-rolled steel sheet and hot-dip galvanized cold-rolled steel sheet according to claim 1, containing Cr: 0.01 to 3.0%.
【請求項3】 請求項1,2に記載の化学成分よりなる
スラブを(Ar3 −100)℃以上の温度で熱間圧延の
仕上げを行い、室温から750℃の温度で巻取り、60
%以上の圧延率で冷間圧延を行い、連続焼鈍における焼
鈍温度を700〜900℃とする冷延鋼板の製造方法。
3. A slab made of the chemical composition according to claim 1 or 2 is hot-rolled at a temperature of (Ar 3 -100) ° C. or higher and wound at a temperature of room temperature to 750 ° C.
A method for manufacturing a cold-rolled steel sheet, wherein cold rolling is performed at a rolling ratio of at least%, and the annealing temperature in continuous annealing is 700 to 900 ° C.
【請求項4】 請求項1,2に記載の化学成分よりなる
スラブを(Ar3 −100)℃以上の温度で熱間圧延の
仕上げを行い、室温から750℃の温度で巻取り、60
%以上の圧延率で冷間圧延を行い、焼鈍温度を700〜
900℃のインライン焼鈍型溶融亜鉛メッキを施す溶融
亜鉛メッキ冷延鋼板の製造方法。
4. A slab made of the chemical composition according to claim 1 or 2 is hot-rolled at a temperature of (Ar 3 -100) ° C. or higher, and wound at room temperature to 750 ° C.
Cold rolling at a rolling ratio of at least 100% and an annealing temperature of 700 to
A method for producing a hot-dip galvanized cold-rolled steel sheet which is subjected to in-line annealing type hot-dip galvanizing at 900 ° C.
JP6045292A 1992-03-17 1992-03-17 High strength cold rolled steel sheet and galvanized high strength cold rolled steel sheet good in formability, and their manufacture Withdrawn JPH05263189A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6045292A JPH05263189A (en) 1992-03-17 1992-03-17 High strength cold rolled steel sheet and galvanized high strength cold rolled steel sheet good in formability, and their manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6045292A JPH05263189A (en) 1992-03-17 1992-03-17 High strength cold rolled steel sheet and galvanized high strength cold rolled steel sheet good in formability, and their manufacture

Publications (1)

Publication Number Publication Date
JPH05263189A true JPH05263189A (en) 1993-10-12

Family

ID=13142680

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JPH05263189A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0823490A1 (en) * 1996-02-22 1998-02-11 Sumitomo Metal Industries, Ltd. Galvannealed sheet steel and process for producing the same
JP2015212405A (en) * 2014-05-01 2015-11-26 新日鐵住金株式会社 440 MPa CLASS HIGH STRENGTH ALLOYED GALVANIZED STEEL SHEET EXCELLENT IN SECONDARY PROCESSING BRITTLENESS RESISTANCE AND MANUFACTURING METHOD THEREFOR
JPWO2020145293A1 (en) * 2019-01-08 2021-10-07 日本製鉄株式会社 Vehicles with exterior panels and exterior panels

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0823490A1 (en) * 1996-02-22 1998-02-11 Sumitomo Metal Industries, Ltd. Galvannealed sheet steel and process for producing the same
EP0823490A4 (en) * 1996-02-22 1999-10-13 Sumitomo Metal Ind Galvannealed sheet steel and process for producing the same
JP2015212405A (en) * 2014-05-01 2015-11-26 新日鐵住金株式会社 440 MPa CLASS HIGH STRENGTH ALLOYED GALVANIZED STEEL SHEET EXCELLENT IN SECONDARY PROCESSING BRITTLENESS RESISTANCE AND MANUFACTURING METHOD THEREFOR
JPWO2020145293A1 (en) * 2019-01-08 2021-10-07 日本製鉄株式会社 Vehicles with exterior panels and exterior panels

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