JPH05254853A - Mold for press-forming - Google Patents
Mold for press-formingInfo
- Publication number
- JPH05254853A JPH05254853A JP4057845A JP5784592A JPH05254853A JP H05254853 A JPH05254853 A JP H05254853A JP 4057845 A JP4057845 A JP 4057845A JP 5784592 A JP5784592 A JP 5784592A JP H05254853 A JPH05254853 A JP H05254853A
- Authority
- JP
- Japan
- Prior art keywords
- substrate
- press mold
- dense
- sintered body
- molding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
- C03B11/06—Construction of plunger or mould
- C03B11/08—Construction of plunger or mould for making solid articles, e.g. lenses
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
- C03B11/06—Construction of plunger or mould
- C03B11/08—Construction of plunger or mould for making solid articles, e.g. lenses
- C03B11/084—Construction of plunger or mould for making solid articles, e.g. lenses material composition or material properties of press dies therefor
- C03B11/086—Construction of plunger or mould for making solid articles, e.g. lenses material composition or material properties of press dies therefor of coated dies
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B2215/00—Press-moulding glass
- C03B2215/02—Press-mould materials
- C03B2215/03—Press-mould materials defined by material properties or parameters, e.g. relative CTE of mould parts
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B2215/00—Press-moulding glass
- C03B2215/02—Press-mould materials
- C03B2215/08—Coated press-mould dies
- C03B2215/10—Die base materials
- C03B2215/12—Ceramics or cermets, e.g. cemented WC, Al2O3 or TiC
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B2215/00—Press-moulding glass
- C03B2215/02—Press-mould materials
- C03B2215/08—Coated press-mould dies
- C03B2215/14—Die top coat materials, e.g. materials for the glass-contacting layers
- C03B2215/22—Non-oxide ceramics
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明はプレス成形型に関し、特
には、ガラスレンズ等をプレス成形するための、成形面
が鏡面加工されるプレス成形型に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a press mold, and more particularly to a press mold for molding glass lenses and the like, the molding surface of which is mirror-finished.
【０００２】[0002]
【従来の技術】プレス成形品の表面形状はプレス作業に
おける重要な品質項目である。特に、仕上研摩工程抜き
で、ガラスレンズ、プラスチックレンズ等の完成品をプ
レス成形しようとする場合は、製品表面に転写されるこ
ととなるプレス成形型の成形面の鏡面加工性が良好であ
ることが求められる。また、被加工物との反応性が少な
いこと、耐摩耗性の良いこと、十分な機械的強度を持つ
ことも求められる。2. Description of the Related Art The surface shape of a press-formed product is an important quality item in press work. In particular, when press-molding finished products such as glass lenses and plastic lenses without the finishing polishing step, the mirror surface workability of the molding surface of the press mold that will be transferred to the product surface is good. Is required. Further, it is required to have low reactivity with the work piece, good wear resistance, and sufficient mechanical strength.
【０００３】従来、このようなプレス成形型として、セ
ラミックスや金属の表面に炭化ケイ素膜が被着されたも
のが知られている（特公平３−５５４２１）。このなか
でも、緻密質ＳｉＣ焼結体（密度９５％〜９８％）を基
体とし、成形面にはＣＶＤ（化学蒸着法）ＳｉＣ膜を被
着させたものがガラス成形用として、実用化されてい
る。この緻密質ＳｉＣプレス成形型は、鏡面加工性が良
く、またガラス成形品との離型性も良い。Conventionally, as such a press-molding die, one in which a silicon carbide film is adhered to the surface of ceramics or metal is known (Japanese Patent Publication No. 3-55421). Among these, a compact SiC sintered body (density 95% to 98%) is used as a substrate, and a CVD (Chemical Vapor Deposition) SiC film is applied to the molding surface, which has been put to practical use for glass molding. There is. This dense SiC press mold has good mirror surface workability and good mold releasability from a glass molded product.
【０００４】しかし、この緻密質ＳｉＣプレス成形型に
は、加工が困難である。耐衝撃性が弱い、という問
題点がある。特に、非球面レンズ用の型等の加工に手間
がかかる型では、この問題は、コスト面や納期面から重
大である。However, this dense SiC press mold is difficult to process. There is a problem that impact resistance is weak. This problem is particularly serious in terms of cost and delivery in the case of a mold for an aspherical lens, which requires a lot of work to process.
【０００５】[0005]
【発明が解決しようとする課題】本発明の目的は、鏡面
加工性と成形品との無反応性とに優れ、かつ、加工し易
すく、耐衝撃性の良いプレス成形型を提供することにあ
る。SUMMARY OF THE INVENTION An object of the present invention is to provide a press mold which is excellent in mirror surface workability and non-reactivity with molded products, is easy to process, and has good impact resistance. is there.
【０００６】[0006]
【課題を解決するための手段】上記目的を達成するた
め、本発明のプレス成形型は、基体（１）、該基体の一
部表面に設けられた成形面（２）及び該基体の他の一部
表面に設けられた摺動面（３）を含むプレス成形型にお
いて； （ａ）基体（１）が、多孔質セラミック焼結体よりな
り； （ｂ）成形面（２）が、緻密質のＳｉＣ膜（１１）で覆
われており； （ｃ）摺動面（３）が、緻密質の無機材料膜、又は、該
基体を構成するセラミック多孔質体に無機材料が含浸さ
れた含浸層、からなる摺動面保護層（１３）を含む； ことを特徴とする。In order to achieve the above object, the press mold of the present invention comprises a substrate (1), a molding surface (2) provided on a part of the surface of the substrate, and other substrates. In a press molding die including a sliding surface (3) provided on a part of the surface; (a) the substrate (1) is made of a porous ceramic sintered body; (b) the molding surface (2) is dense (C) the sliding surface (3) is a dense inorganic material film, or an impregnated layer in which a ceramic porous body constituting the substrate is impregnated with the inorganic material. A sliding surface protective layer (13) made of;
【０００７】また、本発明のプレス成形型の他の一態様
は、基体（１）と、該基体の一部表面に設けられた成形
面（２）とを含むプレス成形型において； （ａ）基体（１）が、気孔体積率が３０〜５０％の多孔
質ＳｉＣ焼結体よりなり； （ｂ）成形面（２）が、緻密質のＳｉＣ膜（１１）で覆
われている； ことを特徴とする。Another embodiment of the press mold of the present invention is a press mold including a substrate (1) and a molding surface (2) provided on a part of the surface of the substrate; (a) The substrate (1) is made of a porous SiC sintered body having a porosity volume ratio of 30 to 50%; (b) the molding surface (2) is covered with a dense SiC film (11); Characterize.
【０００８】本発明のプレス成形型は、被成形品の材料
・品種において、特定のものに限定されない。ただし、
その特性から、特にガラス・プラスチック製のレンズの
成形用の型に好適である。また、本発明のプレス成形型
は、型としての完成品（全ての仕上加工や付属品組立が
終了した状態、すなわちすぐ打てる状態）のみならず、
鏡面加工などの仕上加工前の状態をも含む概念である。The press-molding die of the present invention is not limited to a particular material or type of the article to be molded. However,
Due to its characteristics, it is particularly suitable for a mold for molding a glass / plastic lens. Further, the press-molding die of the present invention is not only a finished product as a die (a state in which all finishing processing and accessory assembly are completed, that is, a state in which it can be immediately punched),
It is a concept that also includes a state before finishing such as mirror finishing.
【０００９】基体の形状・寸法も特に限定されない。成
形面とは、被加工物が成形作業中に接触する型の表面部
分をいう。しかし、作業の内容によっては、この接触部
の外周部を含むこともありうる。摺動面とは、成形作業
に伴う型の運動（上下・左右等）の際に、型が案内面と
摺動する部分をいう。The shape and size of the substrate are not particularly limited. The molding surface refers to the surface portion of the mold with which the workpiece contacts during the molding operation. However, depending on the content of the work, the outer peripheral portion of the contact portion may be included. The sliding surface means a portion where the mold slides on the guide surface during the movement of the mold (up and down, left and right, etc.) accompanying the molding work.
【００１０】基体に必要とされる物理特性は、特に一律
に数値化されるものではない。本発明のプレス成形型の
応用される作業の具体的な内容により、プレス成形型が
十分な耐久性を有するよう個々に設定されるものであ
る。一つの目安としては、曲げ強度（ＪＩＳ Ｒ１６０
１）４kg/mm2以上でかつ弾性率が２，０００〜１５，０
００kg/mm2の範囲にあることである。The physical properties required for the substrate are not particularly uniformly quantified. Depending on the specific contents of the work to which the press mold of the present invention is applied, the press mold is individually set to have sufficient durability. One guideline is bending strength (JIS R160
1) 4kg / mm 2 or more and an elastic modulus of 2,000 to 15.0
It is in the range of 00 kg / mm 2 .
【００１１】基体を構成するセラミック焼結体の多孔性
は特に数値的に限定されない。使用する材質と求められ
る強度に応じて適宜選択する。気孔率が高いほど、一般
に加工しやすくなるが、強度と剛性が下がる。一つの目
安としては、気孔率は２０〜６０％である。特にＳｉＣ
焼結体では、気孔率３０〜５０％が性質のバランスの上
から好ましい。The porosity of the ceramic sintered body constituting the substrate is not limited numerically. It is appropriately selected according to the material used and the required strength. Higher porosity generally facilitates processing, but reduces strength and rigidity. As one guide, the porosity is 20 to 60%. Especially SiC
In the sintered body, a porosity of 30 to 50% is preferable from the viewpoint of property balance.
【００１２】使用するセラミック材料の種類も特に限定
されない。ここで、セラミックとしたのは、硬度・耐熱
性・耐食性が優れているので、本発明の目的を達成する
のに好適だからである。The type of ceramic material used is also not particularly limited. Here, ceramic is used because it has excellent hardness, heat resistance, and corrosion resistance, and is suitable for achieving the object of the present invention.
【００１３】セラミック材質の例としては、ＳｉＣ、Ｓ
ｉ3 Ｎ4 、アルミナ、ムライト、ジルコニアよりなる群
より選ばれた１又は２以上の物質からなるものがあげら
れる。プレス成形型の使用条件（温度、被加工材質、必
要強度）から適宜選択することができる。成形面のＳｉ
Ｃ膜をＣＶＤ法で付ける場合には、成膜温度が高い（一
例１３００℃）ので、成膜後の冷却時に発生する熱応力
を一定値以下におさえる必要があることから、使用する
基体セラミック材質はＳｉＣと熱膨張率が似かよったも
のであることが好ましい。そのため、基体材質として特
に好ましいのは、ＳｉＣである。Examples of ceramic materials include SiC and S
Examples of the material include one or more substances selected from the group consisting of i 3 N 4 , alumina, mullite, and zirconia. It can be appropriately selected depending on the use conditions (temperature, material to be processed, required strength) of the press mold. Si of molding surface
When the C film is applied by the CVD method, since the film forming temperature is high (1300 ° C. in one example), it is necessary to keep the thermal stress generated at the time of cooling after the film formation below a certain value. Is preferably one having a coefficient of thermal expansion similar to that of SiC. Therefore, SiC is particularly preferable as the base material.
【００１４】気孔の形状・寸法は特に限定されるもので
はないが、平均気孔径が０．１〜１０μm の範囲にある
のが好ましい。平均気孔径が０．１μm より小さくなる
と成形面と基体との密着性を向上させることが難しく、
１０μm を越えて平均気孔径が大きくなると基体の強度
が低下し、成形面の平滑性が悪化し易い。The shape and size of the pores are not particularly limited, but the average pore diameter is preferably in the range of 0.1 to 10 μm. If the average pore diameter is smaller than 0.1 μm, it is difficult to improve the adhesion between the molding surface and the substrate,
When the average pore diameter exceeds 10 μm, the strength of the substrate is lowered and the smoothness of the molding surface is apt to be deteriorated.
【００１５】焼結体の製造方法も特に限定されない。一
般的には、あらかじめ造粒されたセラミック粉末を加圧
成形する方法や、鋳込、押出、射出等の成形方法が採用
され、適切な密度を得るために必要な温度（ＳｉＣの場
合１，７００〜２，２００℃）で焼結される。The method for producing the sintered body is also not particularly limited. Generally, a method of press-molding a ceramic powder that has been granulated in advance or a molding method such as pouring, extrusion, or injection is adopted, and the temperature required for obtaining an appropriate density (for SiC, 1, It is sintered at 700-2,200 ° C.
【００１６】成形面緻密質ＳｉＣ膜で覆う目的は、同面
の鏡面加工性と耐摩性の改善である。ＳｉＣ膜は成形面
全面を覆うことが好ましい。ただし、被加工物との接触
条件がゆるやかな部分や、鏡面加工の要求されない部分
は、膜着けしなくともよい場合があり、その場合をも、
本発明は包含するものである。The purpose of covering the compacted surface with the dense SiC film is to improve the mirror surface workability and abrasion resistance of the same surface. The SiC film preferably covers the entire molding surface. However, there are cases where it is not necessary to attach a film to the part where the contact condition with the work piece is gentle or where mirror finishing is not required.
The present invention is intended to be included.
【００１７】成形面のＳｉＣ膜の厚さは０．１〜０．７
mmであることが好ましい。さらに好ましくは０．２〜
０．５mmである。理由は、０．１mm未満では耐摩性の改
善が不充分になり易く、型寿命を延ばすことが困難であ
る。また、０．７mmを越える厚みになると基体との密度
差、熱膨張差とにより膜の剥離が生じ易くなり型寿命を
延ばすことが困難である。The thickness of the SiC film on the molding surface is 0.1 to 0.7.
mm is preferred. More preferably 0.2-
It is 0.5 mm. The reason is that if it is less than 0.1 mm, the abrasion resistance tends to be insufficiently improved, and it is difficult to extend the mold life. Further, if the thickness exceeds 0.7 mm, peeling of the film is likely to occur due to the difference in density with the substrate and the difference in thermal expansion, and it is difficult to extend the mold life.
【００１８】本発明のＳｉＣ膜の結晶構造はβ−ＳｉＣ
が望ましい。理由は、成膜が低温度で可能であり、容易
に、しかも高速で成膜できるからである。The crystal structure of the SiC film of the present invention is β-SiC.
Is desirable. The reason is that the film can be formed at a low temperature and can be formed easily and at high speed.
【００１９】本発明のＳｉＣ膜の成膜方法は、特に限定
されないが、減圧ＣＶＤによることが望ましい。理由
は、純度の高い膜を形成できるからである。他の方法と
しては、イオンプレーティング法、イオンビーム蒸着
法、プラズマＣＶＤ法、スパッタリング法等があげられ
る。The method of forming the SiC film of the present invention is not particularly limited, but low pressure CVD is preferable. The reason is that a highly pure film can be formed. Other methods include an ion plating method, an ion beam vapor deposition method, a plasma CVD method, a sputtering method and the like.
【００２０】摺動面に摺動保護層を設ける目的は、多孔
質基体の気孔からのゴミの浸出の防止である。このゴミ
が成形面に出てくると、製品の傷の原因となる。摺動保
護層は、摺動するプレス成形型には、極力設けたほうが
よい。しかし、成形面から遠い部分の摺動面には、上記
の目的からして、設ける必要のない場合もある。また、
摺動しない方のプレス成形型には、摺動保護層を設けな
くてもよい場合が多い。The purpose of providing the sliding protection layer on the sliding surface is to prevent dust from leaching from the pores of the porous substrate. If this dust appears on the molding surface, it may cause damage to the product. The sliding protection layer should be provided as much as possible on the sliding press molding die. However, in some cases, it is not necessary to provide the sliding surface far from the molding surface for the above purpose. Also,
In many cases, the slide mold that does not slide does not need to be provided with a slide protection layer.
【００２１】摺動保護層は、成形面の緻密質のＳｉＣ膜
と同一の膜であってよい。両膜の成膜が同一工程で同時
にできるので製造上便利である。The sliding protection layer may be the same film as the dense SiC film on the molding surface. Both films can be formed simultaneously in the same process, which is convenient in manufacturing.
【００２２】摺動保護層は、また、基体を構成するセラ
ミック多孔質体に無機材料が含浸された層であってよ
い。無機材料中でも、金属シリコン、金属亜鉛、金属ア
ルミニウム等が好適である。その理由は、含浸が容易な
ためである。含浸層の形成時は、成形面のＳｉＣ膜成膜
の前でも、後でもよい。また、基体の荒加工の前でも後
でもよい。含浸層の厚さも特に限定されない。基体の芯
部まで含浸されていてもよい。その場合は、基体のじん
性、剛性の向上にも有効である。The sliding protection layer may also be a layer in which an inorganic material is impregnated in the ceramic porous body constituting the substrate. Among the inorganic materials, metallic silicon, metallic zinc, metallic aluminum and the like are preferable. The reason is that impregnation is easy. The impregnated layer may be formed before or after the SiC film is formed on the molding surface. Further, it may be before or after the rough processing of the substrate. The thickness of the impregnated layer is also not particularly limited. The core of the substrate may be impregnated. In that case, it is also effective for improving the toughness and rigidity of the substrate.
【００２３】本発明のプレス成形型の製造・機械加工の
手順・方法は特に限定されない。一般的には、基体のプ
レス成形→仮焼結→粗加工→本焼結（含浸）→一次仕上
加工→ＳｉＣ膜付け→仕上加工、の手順である。The procedure and method for manufacturing and machining the press mold of the present invention are not particularly limited. In general, the procedure is as follows: press molding of substrate → temporary sintering → roughing → main sintering (impregnation) → primary finishing → SiC film application → finishing.
【００２４】[0024]
【発明の効果】本発明は以下の効果を有する。 製造しやすいプレス成形型を提供する。基体が、焼結
・加工ともに容易な多孔質セラミック焼結体製だからで
ある。 耐衝撃性の良いプレス成形型を提供する。基体が、シ
ョックの吸収性に優れた多孔質体だからである。 成形面のＳｉＣ膜の耐剥離性が良いプレス成形型を提
供する。ＳｉＣ膜が基体の孔に入り込む効果（アンカリ
ング効果）があるからである。 成形面の鏡面加工性・摺動面の耐ゴミ性は従来技術の
プレス成形型と同様に良好なプレス成形型を提供する。The present invention has the following effects. Provide a press mold that is easy to manufacture. This is because the base body is made of a porous ceramic sintered body that is easy to sinter and process. Provide a press mold having good impact resistance. This is because the substrate is a porous body having excellent shock absorption. (EN) Provided is a press molding die having a SiC film on a molding surface with good peeling resistance. This is because the SiC film has an effect (anchoring effect) of entering the holes of the substrate. The mirror surface machinability of the molding surface and the dust resistance of the sliding surface are as good as those of the conventional press molding dies.
【００２５】[0025]
【実施例】以下、本発明を実施例及び比較例によって説
明する。ただし本発明はこれらの実施例によって限定さ
れるものではない。EXAMPLES The present invention will be described below with reference to examples and comparative examples. However, the present invention is not limited to these examples.
【００２６】本発明の実施例を以下のように作成し
た。β−ＳｉＣ粉末（イビデン（株）ベータランダムＵ
Ｆグレード平均粒径０．３μm ）を成形型に充填後、２
TON/cm2 の等方圧を加えてφ２０×Ｌ１００mmの棒状の
成形体を得た。ついで上記成形体を１気圧アルゴンガス
雰囲気下で１，９４５℃まで５℃／min の速度で昇温
し、４時間保持後室温まで冷却してＳｉＣの多孔体を得
た。An example of the present invention was prepared as follows. β-SiC powder (beta random U of Ibiden Co., Ltd.)
Filling the mold with F grade average particle size 0.3 μm), 2
Isotropic pressure of TON / cm 2 was applied to obtain a rod-shaped molded body of φ20 × L100 mm. Then, the molded body was heated to 1,945 ° C. at a rate of 5 ° C./min under an atmosphere of 1 atmosphere of argon gas, held for 4 hours and cooled to room temperature to obtain a SiC porous body.
【００２７】上記多孔体から試験片を切り出し、曲げ強
度（ＪＩＳ Ｒ１６０１）を測定すると８kg/mm2であ
り、弾性率は５，０００kg/mm2であった。また、水銀圧
入法（マイクロメリテックス社ポアサイザ９３２０）に
より上記多孔体の気孔径分布を測定したところ、平均気
孔径が２．２μm であった。また、密度が１．８０g/cm
2 であり気孔率は４４％と測定された。A test piece was cut out from the above-mentioned porous body and the bending strength (JIS R1601) was measured to be 8 kg / mm 2 , and the elastic modulus was 5,000 kg / mm 2 . Further, the pore size distribution of the above porous body was measured by a mercury porosimetry (Poresizer 9320, manufactured by Micromeritex Co., Ltd.), and it was found that the average pore size was 2.2 μm. Also, the density is 1.80 g / cm
2 and the porosity was measured as 44%.
【００２８】上記多孔体を所定の形状に研削加工して基
体（１）を得た。続いて、この基体の成形面および摺動
面に、減圧ＣＶＤ法によりＳｉＣの膜を形成した。膜厚
は、成膜時に同時に使用したカーボン板（ダミー）に付
着した膜厚を測定した。基体の外形寸法は径２０mm、長
さ２５mmであった。The above porous body was ground into a predetermined shape to obtain a substrate (1). Subsequently, a SiC film was formed on the molding surface and the sliding surface of this substrate by the low pressure CVD method. As the film thickness, the film thickness attached to the carbon plate (dummy) used at the same time as the film formation was measured. The outer dimensions of the substrate were 20 mm in diameter and 25 mm in length.
【００２９】この減圧ＣＶＤによる成膜条件は以下のと
おりであった。 使用装置：形式 減圧ＣＶＤ メーカー エステック 使用ガス：トリクロルシラン、プロパン、水素 基体温度：１３００℃〜１３２０℃ 炉内全圧力：３Torr〜１Torr 成膜時間：１２０分The film forming conditions by this low pressure CVD were as follows. Equipment used: Type Low-pressure CVD maker STEC Gas used: trichlorosilane, propane, hydrogen Substrate temperature: 1300 ° C to 1320 ° C Total furnace pressure: 3 Torr to 1 Torr Film formation time: 120 minutes
【００３０】成膜後の型材をダイヤモンド研摩加工し
て、鏡面の成形面を持ったプレス成形型を得た。この型
で、ガラスレンズ（材質 ホウケイ酸、成形温度 ４０
０℃）を５，０００回成形して、成形後の成形面の変化
を観察した。その結果、カケ、ハガレ、鏡面劣化は見ら
れず、良好であった。The die material after the film formation was diamond-polished to obtain a press die having a mirror surface. With this mold, glass lens (material borosilicate, molding temperature 40
(0 ° C.) was molded 5,000 times, and changes in the molding surface after molding were observed. As a result, chipping, peeling, and mirror surface deterioration were not observed, which was good.
【００３１】本発明の実施例〜を同様なプロセスで
作成した。それらの諸元を表１に示す。Examples of the invention were made by a similar process. The specifications are shown in Table 1.
【００３２】[0032]
【表１】 [Table 1]
【００３３】ここで、実施例の基体（多孔質体）は、
市販のアルミナ粉末（昭和電工（株）ＡＬ−１６０Ｓ
Ｇ、平均粒径０．４μm ）を実施例１と同様の成形型に
充填後２TON/cm2 の等方圧を加えて成形し、続いて大気
中１，５００℃まで２．５℃/minの速度で昇温し２時間
保持後、室温まで冷却させてアルミナの多孔体を得た。Here, the substrate (porous body) of the embodiment is
Commercially available alumina powder (Showa Denko KK AL-160S)
G, average particle size 0.4 μm) in a molding die similar to that of Example 1 and then isotropically pressurized at 2 TON / cm 2 to be molded, and subsequently in air at 1,500 ° C. to 2.5 ° C./min. The temperature was raised at a rate of 2, the temperature was maintained for 2 hours, and then cooled to room temperature to obtain a porous body of alumina.
【００３４】これらを用いて、実施例と同一条件でプ
レス成形試験を行った。その結果を表２に示す。いずれ
の実施例も良好な試験結果であった。Using these, a press molding test was conducted under the same conditions as in the examples. The results are shown in Table 2. All the examples had good test results.
【００３５】また、比較例として、β−ＳｉＣ粉末（イ
ビデン（株）ベータランダムＵＦグレード、平均粒径
０．３μm ）に焼結助剤としてＢ、Ｃとをそれぞれ、
０．３wt％、３wt％添加後実施例１と同様の操作で成
形、焼結させた。As a comparative example, β-SiC powder (Ibiden Co., Ltd. beta random UF grade, average particle size 0.3 μm) was added with B and C as sintering aids, respectively.
After addition of 0.3 wt% and 3 wt%, molding and sintering were performed in the same manner as in Example 1.
【００３６】[0036]
【表２】 [Table 2]
【００３７】基体が緻密質ＳｉＣ（気孔率５％）の比較
例と、本発明の実施例（多孔質ＳｉＣ、気孔率２２
％）とでは、基体の研削加工時間が２４時間：３時間
と、本発明の実施例のほうが約８分の１の加工時間であ
った。A comparative example in which the substrate is dense SiC (porosity 5%) and an example of the present invention (porous SiC, porosity 22)
%), The grinding time of the substrate was 24 hours: 3 hours, and the working time of the embodiment of the present invention was about ⅛.
【図１】本発明の一実施例のプレス成形型の概念図であ
る。FIG. 1 is a conceptual diagram of a press mold according to an embodiment of the present invention.
１ 基体 ２ 成形面 ３ 摺動面 １１ ＳｉＣ膜 １３ 摺動保護層 1 Base 2 Molding Surface 3 Sliding Surface 11 SiC Film 13 Sliding Protective Layer
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ０４Ｂ 41/87 Ｍ ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI technical display location C04B 41/87 M
Claims (10)
れた成形面（２）及び該基体の他の一部表面に設けられ
た摺動面（３）を含むプレス成形型において； （ａ）基体（１）が、多孔質セラミック焼結体よりな
り； （ｂ）成形面（２）が、緻密質のＳｉＣ膜（１１）で覆
われており； （ｃ）摺動面（３）が、緻密質の無機材料膜、又は、該
基体を構成するセラミック多孔質体に無機材料が含浸さ
れた含浸層、からなる摺動保護層（１３）を含む； ことを特徴とするプレス成形型。1. A press mold comprising a substrate (1), a molding surface (2) provided on a partial surface of the substrate, and a sliding surface (3) provided on another partial surface of the substrate. (A) the substrate (1) is made of a porous ceramic sintered body; (b) the molding surface (2) is covered with a dense SiC film (11); (c) a sliding surface ( 3) A slide protective layer (13) comprising a dense inorganic material film or an impregnated layer in which a ceramic porous body constituting the substrate is impregnated with an inorganic material; Mold.
率が２０〜６０％である請求項１記載のプレス成形型。2. The press mold according to claim 1, wherein the porous ceramic sintered body has a pore volume ratio of 20 to 60%.
Ｃ、Ｓｉ3 Ｎ4 、アルミナ、ムライト、ジルコニアより
なる群より選ばれた１又は２種以上の物質からなる請求
項１記載のプレス成形型。3. The porous ceramic sintered body is made of Si
The press mold according to claim 1, which is made of one or more substances selected from the group consisting of C, Si 3 N 4 , alumina, mullite, and zirconia.
度（ＪＩＳ Ｒ１６０１）４kg/mm2以上でありかつ弾性
率が２，０００〜１５，０００kg/mm2以上である請求項
１記載のプレス成形型。Wherein said porous ceramic sintered body, the bending strength (JIS R1601) is at 4 kg / mm 2 or more and an elastic modulus of claim 1, wherein at 2,000~15,000kg / mm 2 or more press Mold.
均粒径が０．１〜１０μm である請求項１記載のプレス
成形型。5. The press mold according to claim 1, wherein the average particle diameter of the pores of the porous ceramic sintered body is 0.1 to 10 μm.
０．１〜０．７mmである請求項１記載のプレス成形型。6. The press mold according to claim 1, wherein the dense SiC film (11) has a thickness of 0.1 to 0.7 mm.
密質の無機材料膜がＳｉＣ膜である請求項１記載のプレ
ス成形型。7. The press mold according to claim 1, wherein the dense inorganic material film forming the sliding surface protection layer (13) is a SiC film.
が、金属シリコンが含浸された層である請求項１記載の
プレス成形型。8. The press mold according to claim 1, wherein the impregnation layer constituting the sliding protection layer (13) is a layer impregnated with metallic silicon.
られた成形面（２）とを含むプレス成形型において； （ａ）基体（１）が、気孔体積率が３０〜５０％の多孔
質ＳｉＣ焼結体よりなり； （ｂ）成形面（２）が、緻密質のＳｉＣ膜（１１）で覆
われている； ことを特徴とするプレス成形型。9. A press mold comprising a substrate (1) and a molding surface (2) provided on a partial surface of the substrate; (a) the substrate (1) has a pore volume ratio of 30 to 50. % Of a porous SiC sintered body; (b) the molding surface (2) is covered with a dense SiC film (11);
られた成形面（２）及び該基体の他の一部表面に設けら
れた摺動面（３）を含むプレス成形型において； （ａ）基体（１）が、気孔体積率が３０〜５０％の多孔
質ＳｉＣ焼結体よりなり； （ｂ）成形面（２）が、緻密質のＳｉＣ膜（１１）で覆
われており； （ｃ）摺動面（３）が、緻密質のＳｉＣ膜からなる摺動
保護層（１３）を含む； ことを特徴とするプレス成形型。10. A press mold comprising a substrate (1), a molding surface (2) provided on a partial surface of the substrate, and a sliding surface (3) provided on another partial surface of the substrate. (A) The substrate (1) is made of a porous SiC sintered body having a porosity volume ratio of 30 to 50%; (b) The molding surface (2) is covered with a dense SiC film (11). (C) The sliding surface (3) includes a sliding protection layer (13) made of a dense SiC film;
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05784592A JP3219449B2 (en) | 1992-03-16 | 1992-03-16 | Press mold |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05784592A JP3219449B2 (en) | 1992-03-16 | 1992-03-16 | Press mold |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05254853A true JPH05254853A (en) | 1993-10-05 |
| JP3219449B2 JP3219449B2 (en) | 2001-10-15 |
Family
ID=13067318
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP05784592A Expired - Lifetime JP3219449B2 (en) | 1992-03-16 | 1992-03-16 | Press mold |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3219449B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002255570A (en) * | 2001-02-28 | 2002-09-11 | Ibiden Co Ltd | Die for forming glass lens and method for manufacturing the same |
| JP2002293552A (en) * | 2001-03-28 | 2002-10-09 | Ibiden Co Ltd | Mold and method for manufacturing the same |
| JP2008239476A (en) * | 1997-09-05 | 2008-10-09 | Element Six Ltd | Diamond-silicon carbide-silicon composite |
| JP2016044093A (en) * | 2014-08-21 | 2016-04-04 | 株式会社フジコー | Method for producing sic molded body and sic molded body |
-
1992
- 1992-03-16 JP JP05784592A patent/JP3219449B2/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008239476A (en) * | 1997-09-05 | 2008-10-09 | Element Six Ltd | Diamond-silicon carbide-silicon composite |
| JP2002255570A (en) * | 2001-02-28 | 2002-09-11 | Ibiden Co Ltd | Die for forming glass lens and method for manufacturing the same |
| JP2002293552A (en) * | 2001-03-28 | 2002-10-09 | Ibiden Co Ltd | Mold and method for manufacturing the same |
| JP2016044093A (en) * | 2014-08-21 | 2016-04-04 | 株式会社フジコー | Method for producing sic molded body and sic molded body |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3219449B2 (en) | 2001-10-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH07299708A (en) | Manufacture of silicon nitride system ceramics part | |
| US20060141093A1 (en) | Composite mold and method for making the same | |
| US4526875A (en) | Ceramic material for cutting tools and process for the production thereof | |
| JP3219449B2 (en) | Press mold | |
| US5352643A (en) | High strength alumina and process for producing same | |
| JPH0379299B2 (en) | ||
| JPS63103836A (en) | Mold for molding optical glass element | |
| KR870001737B1 (en) | The mould for making lenses by press | |
| JP2000072453A (en) | Forming mold for glass mold and its production | |
| JPH0214881A (en) | Surface deposited carbonaceous material | |
| JPH11255523A (en) | Mold for forming glass mold and its production | |
| JP2002274867A (en) | Optical glass element press forming die and optical glass element | |
| JPH0572336B2 (en) | ||
| JP2007230825A (en) | Member for glass conveyance, and its production method | |
| JPS60176928A (en) | Mold for press molding glass lens | |
| JP3851383B2 (en) | Optical glass element press mold and method of manufacturing the same | |
| KR960012315B1 (en) | Method for manufacturing a cutting tool of si3n4 with improved resistant-wear property | |
| JPH05270844A (en) | Molding die for optical glass | |
| JPH0735262B2 (en) | Molding material for glass molding | |
| JP2004345899A (en) | Press molding die | |
| JP2002255570A (en) | Die for forming glass lens and method for manufacturing the same | |
| JP2964367B2 (en) | Mold for optical element molding | |
| JPH07257933A (en) | Glass press-forming die | |
| JPH04265234A (en) | Forming die for optical glass element | |
| JPH01313337A (en) | Mold material and mold for molding glass |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20070810 Year of fee payment: 6 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080810 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080810 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090810 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090810 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100810 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100810 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110810 Year of fee payment: 10 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120810 Year of fee payment: 11 |
|
| EXPY | Cancellation because of completion of term | ||
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120810 Year of fee payment: 11 |