JPH0499202A - Manufacture of colored zinc powder - Google Patents
Manufacture of colored zinc powderInfo
- Publication number
- JPH0499202A JPH0499202A JP2210282A JP21028290A JPH0499202A JP H0499202 A JPH0499202 A JP H0499202A JP 2210282 A JP2210282 A JP 2210282A JP 21028290 A JP21028290 A JP 21028290A JP H0499202 A JPH0499202 A JP H0499202A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- zinc powder
- zinc
- coloring
- blue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000004040 coloring Methods 0.000 claims abstract description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 230000001590 oxidative effect Effects 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 abstract description 15
- 239000010936 titanium Substances 0.000 abstract description 4
- 229910052719 titanium Inorganic materials 0.000 abstract description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052748 manganese Inorganic materials 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 229910052720 vanadium Inorganic materials 0.000 abstract description 2
- 238000010298 pulverizing process Methods 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 description 11
- 239000011701 zinc Substances 0.000 description 11
- 239000007789 gas Substances 0.000 description 7
- 238000005507 spraying Methods 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 3
- 229910001297 Zn alloy Inorganic materials 0.000 description 3
- 238000007751 thermal spraying Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- -1 nitrogen gas Chemical compound 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
Landscapes
- Coating By Spraying Or Casting (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Powder Metallurgy (AREA)
Abstract
Description
【発明の詳細な説明】 １班り五亘史互 本発明は、着色亜鉛粉の製造方法に関する。[Detailed description of the invention] 1 group of five students The present invention relates to a method for producing colored zinc powder.
且里辺亘速韮亘
従来、亜鉛粉を着色したものは知られておらず、亜鉛合
金粉についても、それ自体発色した製品は知られていな
い。Hitherto, colored zinc powder has not been known, nor has any zinc alloy powder itself been known to be colored.
本発明者等は、４５０〜７００℃で加熱し、発色粉が得
られることを特願平１−１０５８１９号として出願して
いる。しかし、より低温で発色することを見い出してい
なかった。The present inventors have filed a patent application in Japanese Patent Application No. 1-105819 stating that colored powder can be obtained by heating at 450 to 700°C. However, it has not been found that color develops at lower temperatures.
そこで本発明者等は、鋭意検討した結果、意外にも容易
に着色亜鉛粉を得ることを見い出したのである。As a result of intensive research, the inventors of the present invention discovered that it is surprisingly easy to obtain colored zinc powder.
これにより、以下の発明を提供する。This provides the following invention.
ｋ」■λ槽滅。k” ■λ tank extinguished.
即ち、本発明は、
発色元素を含む亜鉛粉を３５０〜４５０℃未満に加熱酸
化することを特徴とする着色亜鉛粉の製造方法に関する
。That is, the present invention relates to a method for producing colored zinc powder, which comprises heating and oxidizing zinc powder containing a coloring element at a temperature of 350 to less than 450°C.
の
本発明で用いる亜鉛は、蒸留亜鉛地金１種（純度９８．
５％以上）、最純亜鉛地金（純度９９．９９５％以上）
並びに電気亜鉛地金（純度９９．９９％以上）が使用さ
れ、例えば、上記蒸留亜鉛地金１種では、Ｐｂ１．５重
量％以下、Ｃｄ０．１重量％以下、モしてＦｅｄ、０２
重量％以下である。The zinc used in the present invention is distilled zinc ingot (purity 98.
5% or more), the purest zinc metal (purity 99.995% or more)
In addition, an electrolytic zinc ingot (purity of 99.99% or more) is used. For example, in the above distilled zinc ingot, Pb is 1.5% by weight or less, Cd is 0.1% by weight or less, and Fed, 02
% by weight or less.
ｐｂ及び／またはＣｃｌを意図的に含めない場合には、
こうした不純物の合計が １．５重量％以下の亜鉛地金
を用いることが好ましい。If pb and/or Ccl are not intentionally included,
It is preferable to use a zinc base metal containing 1.5% by weight or less of such impurities in total.
不純物を極力排除したい場合には、Ｐｂ含有量が０．０
０５重量％以下の最純亜鉛地金及び電気亜鉛地金の使用
が好ましい。If you want to eliminate impurities as much as possible, Pb content is 0.0.
It is preferable to use purest zinc ingots and electrolytic zinc ingots with a content of 0.05% by weight or less.
本発明で対象となるものは上記の亜鉛に、一定の添加元
素を添加し、酸化することにより発色するものである。The object of the present invention is one that develops color by adding certain additional elements to the above-mentioned zinc and oxidizing it.
即ち、酸化膜の光の干渉による発色効果を示すものであ
る。That is, it shows the coloring effect due to light interference of the oxide film.
添加元素としては、Ｔ１、Ｍｎ、Ｖ等である。Examples of additive elements include T1, Mn, and V.
これらの元素は、必要に応じて０．０１〜１０゜０重量
％添加される。These elements are added in an amount of 0.01 to 10.0% by weight, if necessary.
特に、上記添加元素を加え、粉砕して粉を得る場合は、
０．５〜１０％と多く添加し、脆化することが好ましい
。In particular, when adding the above additive elements and grinding to obtain powder,
It is preferable to add as much as 0.5 to 10% to cause embrittlement.
この粉砕した粉を、３５０〜４５０℃未満に加熱酸化す
ることにより着色亜鉛粉を得る。この温度では、本来亜
鉛合金の溶融点以下の温度であるが、意外に鮮明な発色
の粉である点が、驚かされるのである。Colored zinc powder is obtained by heating and oxidizing this pulverized powder at a temperature below 350 to 450°C. Although this temperature is originally below the melting point of the zinc alloy, it is surprising that the powder has a surprisingly vivid color.
この場合、酸化時間は３秒から１００分行われる。この
時間の長短により、種々の一定の色が発色するのである
。例えば、チタン添加の場合であれば、青色、濃青色、
青紫色、赤紫色、黄金色等に変化しそれぞれ発色する。In this case, the oxidation time is from 3 seconds to 100 minutes. Depending on the length of this time, various fixed colors develop. For example, in the case of titanium addition, blue, dark blue,
The color changes to blue-purple, red-purple, golden yellow, etc., respectively.
また、粉の大きさは任意に選べ、５μｍ〜１０ｍｍと広
い範囲のものも可能である。Further, the size of the powder can be arbitrarily selected, and a wide range of 5 μm to 10 mm is also possible.
さらに、より鮮明な発色を得るためには、目的酸化温度
になるまで、不活性ガス（例えば、Ａｒガス等）又は中
性ガス（Ｎ、等）を侵入させ、その後空気等酸素を含む
ガスにより酸化することが望ましい。昇温までに粒表面
が酸化されてしまい発色の妨害することを防ぐためであ
る。Furthermore, in order to obtain more vivid coloring, inert gas (e.g. Ar gas, etc.) or neutral gas (N, etc.) is introduced until the desired oxidation temperature is reached, and then an oxygen-containing gas such as air is introduced. Oxidation is desirable. This is to prevent the grain surface from being oxidized before the temperature rises, which would interfere with color development.
また別の方法としては、発色元素を含む亜鉛を溶解し、
噴霧法により亜鉛合金粉を製造し、該粉を流動層等で一
定時間酸化する方法で行う。Another method is to dissolve zinc containing a coloring element,
Zinc alloy powder is produced by a spraying method, and the powder is oxidized in a fluidized bed or the like for a certain period of time.
この噴霧法の場合、酸素含有ガスで噴霧する場合は、流
動層と連結された装置により、連続酸化することが望ま
しい。In this atomization method, when atomizing with an oxygen-containing gas, continuous oxidation is preferably performed using a device connected to a fluidized bed.
さらに酸素含有ガス中で噴霧する場合、粒形状が球状と
なり難いため、窒素ガス等酸素が最低５％以下のガスで
噴霧し、酸化を別の装置で行う方法も考えられる。Furthermore, when spraying in an oxygen-containing gas, it is difficult for the particles to become spherical, so a method of spraying with a gas containing at least 5% oxygen, such as nitrogen gas, and performing oxidation in a separate device is also considered.
この場合、粉の形状が球状であり、発色する色が種々の
色に制御し易くなる。In this case, the shape of the powder is spherical, and the color developed can be easily controlled to various colors.
また、前記着色亜鉛粉を溶射法により、被めっき物に溶
射することにより、種々の形状の製品の着色を可能とし
、被めっき物の耐食性を上昇させることができる。Further, by thermally spraying the colored zinc powder onto an object to be plated by a thermal spraying method, it is possible to color products of various shapes and improve the corrosion resistance of the object to be plated.
さらに溶射法でなくとも、接着面を有する材料の接着面
に上記着色亜鉛粉を付着させ、化粧板等に用いることも
好ましい。Furthermore, even if the thermal spraying method is not used, it is also preferable to apply the colored zinc powder to the adhesive surface of a material having an adhesive surface and use it for decorative boards and the like.
この場合、着色亜鉛面にざらつきを生じることもあるが
、このためには透明な有機剤を表面に塗布することが好
ましい。In this case, the colored zinc surface may become rough, but for this purpose it is preferable to apply a transparent organic agent to the surface.
さらに着色亜鉛粉を顔料の１つとして用いることもでき
る。Furthermore, colored zinc powder can also be used as one of the pigments.
１墓上上
蒸留亜鉛（９８，５ｗｔ％Ｚｎ）に５ｗｔ％Ｔｉ（ｍ、
ｐ。1. 5 wt% Ti (m,
p.
６２０℃）を含ませた合金を粉砕し、篩別し５０μのも
のを得た。この合金粉を用いて３５０℃〜４５０℃未満
の温度範囲で行った場合は、上記の変化する発色スピー
ドが更に遅くなり、酸化膜厚のコントロールが非常にし
易くなった。即ち第１図に示すごとく３５０℃であれば
黄金色、４００℃では赤紫色、４２５℃では青色と、特
定の温度で、所望の色調を有する着色亜鉛粉を得ること
ができた。620° C.) was crushed and sieved to obtain a 50 μm alloy. When this alloy powder was used in a temperature range of 350° C. to less than 450° C., the speed at which the color changed as described above became even slower, making it much easier to control the oxide film thickness. That is, as shown in FIG. 1, colored zinc powder having a desired color tone could be obtained at specific temperatures: golden yellow at 350°C, reddish-purple at 400°C, and blue at 425°C.
１應１
蒸留亜鉛（９８，５ｗｔ％Ｚｎ）に０，２５ｗｔ％Ｔ１
を含ませた合金（ｍ、ｐ、 ４５０°Ｃ）を３５０℃に
溶解し、Ｎ、ガス噴霧により合金粉を得た。 この場合
、噴霧後のチャンバー内の雰囲気も酸素を微量とするこ
とを（３％）により、球状の亜鉛粉を得た。この原料を
用いて３５０℃〜４５０℃未満の温度範囲で、合金粉を
加熱した。第２図に示すごとく３５０℃であれば黄金色
、４００℃では赤紫色、４２５℃では青色と、特定の温
度で、所望の色調を有する着色亜鉛粉を得ることができ
た。実施例１に比べ、黄金色になるまでの所要時間が、
短いことが、把握された。10.1 distilled zinc (98.5wt%Zn) with 0.25wt%T1
An alloy containing (m, p, 450°C) was melted at 350°C, and an alloy powder was obtained by spraying with N and gas. In this case, spherical zinc powder was obtained by controlling the atmosphere in the chamber after spraying to have a trace amount of oxygen (3%). Using this raw material, alloy powder was heated in a temperature range of 350°C to less than 450°C. As shown in FIG. 2, colored zinc powder having a desired color tone could be obtained at specific temperatures: golden yellow at 350°C, reddish-purple at 400°C, and blue at 425°C. Compared to Example 1, the time required to turn golden was
I realized that it was short.
１里辺激１
（１）従来、得られたことのない着色亜鉛粉を提供でき
た。1. Ritobe Geki 1 (1) We were able to provide colored zinc powder that had never been obtained before.
（２）曲面を有する鉄製品等に容易に着色し、かつ防食
をすることが可能である。(2) It is possible to easily color iron products with curved surfaces and provide corrosion protection.
（３）鉄製品以外にも溶射により、着色亜鉛を付着する
ことができる。(3) Colored zinc can be applied to other than iron products by thermal spraying.
（４）好ましい化粧板を容易に得ることができる。(4) A desirable decorative board can be easily obtained.
（５）顔料の１つとして好ましく用いるこができる。(5) It can be preferably used as one of the pigments.
第１図は本発明の実施例１の熱処理温度と発色順位を示
す。
第２図は本発明の実施例２の熱処理温度と発色順位を示
す。FIG. 1 shows the heat treatment temperature and coloring order of Example 1 of the present invention. FIG. 2 shows the heat treatment temperature and color development order of Example 2 of the present invention.
Claims (1)
化することを特徴とする着色亜鉛粉の製造方法。A method for producing colored zinc powder, which comprises heating and oxidizing zinc powder containing a coloring element at a temperature of 350 to less than 450°C.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2210282A JP2563658B2 (en) | 1990-08-10 | 1990-08-10 | Method for producing colored zinc powder |
| US07/765,410 US5198026A (en) | 1989-04-27 | 1991-09-25 | Colored zinc powder, its method of production and method for producing colored article |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2210282A JP2563658B2 (en) | 1990-08-10 | 1990-08-10 | Method for producing colored zinc powder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0499202A true JPH0499202A (en) | 1992-03-31 |
| JP2563658B2 JP2563658B2 (en) | 1996-12-11 |
Family
ID=16586818
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2210282A Expired - Fee Related JP2563658B2 (en) | 1989-04-27 | 1990-08-10 | Method for producing colored zinc powder |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2563658B2 (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61288040A (en) * | 1985-06-17 | 1986-12-18 | Nikko Aen Kk | Zinc alloy for hot dipping and its use |
| JPH07110962A (en) * | 1993-10-15 | 1995-04-25 | Sanyo Electric Co Ltd | Recording and reproducing apparatus of optical recording medium |
-
1990
- 1990-08-10 JP JP2210282A patent/JP2563658B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61288040A (en) * | 1985-06-17 | 1986-12-18 | Nikko Aen Kk | Zinc alloy for hot dipping and its use |
| JPH07110962A (en) * | 1993-10-15 | 1995-04-25 | Sanyo Electric Co Ltd | Recording and reproducing apparatus of optical recording medium |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2563658B2 (en) | 1996-12-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |