JPH0491950A - Thermosetting resin decorative sheet and manufacture thereof - Google Patents
Thermosetting resin decorative sheet and manufacture thereofInfo
- Publication number
- JPH0491950A JPH0491950A JP2208264A JP20826490A JPH0491950A JP H0491950 A JPH0491950 A JP H0491950A JP 2208264 A JP2208264 A JP 2208264A JP 20826490 A JP20826490 A JP 20826490A JP H0491950 A JPH0491950 A JP H0491950A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- thermosetting resin
- sheet
- decorative sheet
- uneven shape
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 22
- 239000011347 resin Substances 0.000 title claims abstract description 22
- 229920001187 thermosetting polymer Polymers 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 7
- 238000000465 moulding Methods 0.000 abstract description 9
- 238000010030 laminating Methods 0.000 abstract description 4
- 239000011888 foil Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 238000007731 hot pressing Methods 0.000 abstract description 2
- 229920000877 Melamine resin Polymers 0.000 description 8
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229920006267 polyester film Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000004640 Melamine resin Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920002397 thermoplastic olefin Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、熱硬化性樹脂被覆化粧板２．特にメラミン化
粧板およびその製造法に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention provides a thermosetting resin-coated decorative board 2. In particular, it relates to melamine decorative boards and their manufacturing methods.
従オ、熱硬化性樹脂化粧板、特にメラミン化粧板におい
ては、一般にチタン紙に普通の印刷インキで印刷するこ
とにより模様か付与される。また、この種の化粧板の装
飾性を高めるために、エンボス模様を有するポリオレフ
ィン系樹脂シート・をメラミン化粧板に積層成形フるこ
とか行オ）れている。Second, in the case of thermosetting resin decorative boards, especially melamine decorative boards, patterns are generally imparted by printing on titanium paper with ordinary printing ink. In addition, in order to enhance the decorative properties of this type of decorative board, a polyolefin resin sheet having an embossed pattern is laminated and molded onto a melamine decorative board.
さらに、チタン紙に真珠光沢顔料または金属粉顔料を含
有する光輝性インキにより模様を印刷し、これをメラミ
ン樹脂で含浸したのち熱圧により硬化させることも行わ
れている。Furthermore, patterns are printed on titanium paper using glitter ink containing pearlescent pigments or metal powder pigments, which is then impregnated with melamine resin and then cured by heat pressure.
しかし１、Ｌ記の普通インキによる印刷ではインキ層が
メラミンと密着せず、化粧板゛としての表面物性も得ら
れない。また、上記のエンボス模様シートを用いる場合
にも、ポリオレフィン系樹脂か耐熱圧性に乏しいため、
製品表面の艶かなくなる傾向にある。さらに上記の最後
の公知技術では、チタン紙に光輝性印刷を施しでも、メ
ラミン含浸オーバーレイ紙の影響で最終製品において光
輝性か発揮されず、光線の角度の違いによっても変化か
生じないなどの欠点かあった。However, in printing with ordinary ink as described in 1.L, the ink layer does not come into close contact with the melamine, and the surface properties as a decorative board cannot be obtained. In addition, even when using the above-mentioned embossed pattern sheet, since the polyolefin resin has poor heat and pressure resistance,
The surface of the product tends to become dull. Furthermore, in the last known technique mentioned above, even if glitter printing is applied to titanium paper, the final product does not exhibit glitter due to the influence of the melamine-impregnated overlay paper, and there are disadvantages such as no change due to differences in the angle of the light beam. There was.
本発明は、これら従来の化粧板における問題点を解消し
、光輝性があり、しかも角度によって表面の表情が変化
するメラミシ化粧板およびその製造方法を提供すること
を目的としている。It is an object of the present invention to solve these problems with conventional decorative boards and to provide a melamic decorative board that is shiny and whose surface expression changes depending on the angle, and a method for manufacturing the same.
本発明は上記の目的を達成するもので、表面に光輝性イ
ンキ層が存在し、このインキ層の最表面に微細な凹凸形
状か設けられていることを特徴とする熱硬化性樹脂化粧
板である。The present invention achieves the above object, and is a thermosetting resin decorative board characterized by having a glittering ink layer on its surface, and having a fine uneven shape provided on the outermost surface of this ink layer. be.
本発明はさらに、離型シート上にポリオレフィン系樹脂
の層を設け、該樹脂層の表面に微細な凹凸形状を付与し
た後、該凹凸面に光輝性インキを用いて印刷層を形成し
、こうして得られた転写シートを熱硬化性樹脂含浸紙と
重ねて熱圧成形し、次いで該離型シートを剥離すること
を特徴とする、表面に微細な凹凸形状を有する熱硬化性
樹脂化粧板の製造法である。The present invention further provides a layer of polyolefin resin on a release sheet, and after giving a fine uneven shape to the surface of the resin layer, a printing layer is formed on the uneven surface using a glitter ink. Production of a thermosetting resin decorative board having fine irregularities on the surface, which is characterized by stacking the obtained transfer sheet on thermosetting resin-impregnated paper, thermo-pressing molding, and then peeling off the release sheet. It is the law.
本発明の化粧板の最も外側の表面（光輝性インキ層の上
）に形成される微細な凹凸形状は、特に次のようなもの
が好ましい。すなわち、平行な直線または曲線を形成す
る凹凸ないし溝の群どそｔｌを囲む閉じた境界線とから
なるパターンの集合体であって、その中でも特に閉領域
で区画されこの領域の境界線を共有して隣り合うパター
ンの平行な直線群または直線群の方向か異なり、溝の深
さおよび間隔か０．１〜１００μで、境界線を介して隣
接する線群の方向差か５°以上のものか特に好ましい。The fine uneven shape formed on the outermost surface (on the glitter ink layer) of the decorative board of the present invention is particularly preferably as follows. In other words, it is a collection of patterns consisting of a group of unevenness or grooves forming parallel straight lines or curves and a closed boundary line surrounding the tl, among which a group is particularly divided into closed areas and shares the boundary line of this area. The direction of parallel straight lines or straight line groups of adjacent patterns is different, the groove depth and interval are 0.1 to 100μ, and the direction difference between adjacent line groups across the boundary line is 5° or more. Especially preferred.
なお、これらの線群の領域は境界線を有しなくてもよい
。この種のパターンは、視差によって各閉鎖域の光沢が
変わることに、その意匠の特色かある。隣接する線群の
方向かすべて異なるようにするには、位相幾何学の１４
色問題の定理」から、方向差の種類が４種類以上あるこ
とか必要１−分である。そのほか、上記のようなパター
ンと砂目、木目、導管等の他のパターンの凹凸形状を：
Ｅｇザイク状に組合せてもよい。Note that the areas of these line groups do not need to have boundary lines. A distinctive feature of this type of pattern's design is that the gloss of each closed area changes depending on the parallax. To make the directions of adjacent lines all different, use 14 of topology.
From the color problem theorem, it is necessary that there are four or more types of direction differences. In addition, the uneven shapes of the above patterns and other patterns such as sand grain, wood grain, conduit, etc.:
They may be combined in an Egsaic pattern.
前述した微細な凹凸形状を付（テするための賦早フィル
ムとしては、熱圧又はデンション（：強い基材シートに
、熱可塑性ポリオレフィン系樹脂の層を積層し、てシー
トを形成し、この樹脂層（二〕−ンポス模様を設けるこ
とにより製造されるものを使用することかできる。この
場合の基材シートは、ポリオレフィン系樹脂層よりも熱
変形温度か高いプラスチックシートであることか好まし
い。このような賦形シートは、例えば特願平１−１１８
７６号明細書に記載されている。そのほか、熱可塑性樹
脂の基材フィルムと、電離放射線硬化樹脂の塗膜にエン
ボスか設けらねているエンボス賦形フィルムも使用でき
る（特願昭６３−２５８０６０ ）号の請求項２参照）
。The preheating film for forming the above-mentioned fine irregularities is prepared by laminating a layer of thermoplastic polyolefin resin on a strong base sheet to form a sheet. Layer (2) - A material manufactured by providing a pattern can be used. In this case, the base sheet is preferably a plastic sheet whose heat deformation temperature is higher than that of the polyolefin resin layer. Such shaped sheets are disclosed in, for example, Japanese Patent Application No. 1-118
It is described in the specification of No. 76. In addition, an embossed film in which embossing is provided on a base film of thermoplastic resin and a coating film of ionizing radiation curing resin can also be used (see claim 2 of Japanese Patent Application No. 63-258060).
.
」−記の光輝性イン４層は、転写法より設けることかで
き、好ましくは、基材フィルノ、表面に、基材フィルム
側に剥離層を有する転写層を積層してなる転写シートて
あって、剥離層が基材フィルｌ、側より、１液型ウレタ
ンインキよりなる第一剥離層と、２液型つ１／タンイン
キよりなる第ニー剥離層とからなる転写フィルムか用い
られる。この剥離層の構成はボリエヂレンテしフタし一
ト・（ＰＥＴ）フィルムの場合に特に好まし、い。しか
し２ポリプロピ１ノンフイルムの場合はこのフィルムか
離型性をイ１ｔ′るので、ｌ波型ウレタンインキよりな
る第一剥離層を省略することかでき、２液型ウレタンイ
ンキ層たけても良好に剥離することができる。The four glittering layers described in "-" can be provided by a transfer method, and preferably, a transfer sheet is formed by laminating a base material Filno and a transfer layer having a release layer on the base film side on the surface thereof. A transfer film is used in which the release layer is a base film, and from the side, the first release layer is made of a one-component urethane ink, and the second release layer is made of a two-part urethane ink. This configuration of the release layer is particularly preferred in the case of polyester film (PET). However, in the case of 2-polypropylene-1 non-film, this film has poor mold releasability, so the first release layer made of 1-wave type urethane ink can be omitted, and even a 2-component urethane ink layer can be used. It can be peeled off.
光輝性インキ層は、成形前は箔落ちしない程度に転写フ
ィルム（賦型フィルノ、）と密着し、熱圧成形後は剥離
性か容易であり、しかも熱硬化性樹脂と密着し、表面物
性を有するものか特に有利である。光輝性顔料としては
、例えば、アルミニウム粉、銅粉、真鍮粉等の金属粉、
金属薄片、金属蒸着合成樹脂フィルムの裁断片等の金属
光沢を有する顔料、二酸化チタン被覆雲母、魚鱗箔、酸
塩化ヒスマス等の真珠光沢や干渉を有する顔料が用いら
れる。光輝性インキとしては、２液型ポリウレタン系イ
ンキが特に適している。Before molding, the glitter ink layer adheres to the transfer film (imprinted FILNO) to the extent that the foil does not fall off, and after hot-press molding, it is easily removable, and it also adheres closely to the thermosetting resin, improving surface properties. It is particularly advantageous to have Examples of bright pigments include metal powders such as aluminum powder, copper powder, and brass powder;
Pigments with metallic luster such as metal flakes and cut pieces of metallized synthetic resin film, pigments with pearlescent luster or interference such as titanium dioxide-coated mica, fish scale foil, and hismuth acid chloride are used. A two-component polyurethane ink is particularly suitable as the glitter ink.
光輝性インキ層を熱硬化性化粧板に転勾したのちのこの
インキ層」ニに微細な凹凸形状が残るように、上記のよ
うにしてエンボス加重する。−とにより転写フィルムの
剥離層重に凹凸形状を付与する。After the glittering ink layer is transferred to the thermosetting decorative board, the ink layer is subjected to embossing as described above so that fine irregularities remain on the ink layer. - imparts an uneven shape to the release layer of the transfer film.
この場合の剥離層どしてはポリオレフィン系のフィルム
、拐゛にポリプロピレンか用いらね、この上に光輝性２
液型インキを直接形成してもよい。イソシアネ−１・と
このフィルムは結合しにくいので、熱１“ト成形後にフ
ィルムか剥離しなくなることはない。In this case, the release layer is a polyolefin film, and polypropylene is used as the release layer.
A liquid ink may also be formed directly. Since the isocyanate-1 and this film are difficult to bond, the film does not peel off after hot molding.
（ｉｉｒ記のようにして製造された転写フィルムの光輝
性インキ層は、熱硬化性樹脂として公知の高圧または低
圧メラミン、ジアリルフタレ−１・、不飽和ポリニスデ
ル等を用いた化粧板に転写される。(The glitter ink layer of the transfer film produced as described in item ii) is transferred to a decorative board using known thermosetting resins such as high-pressure or low-pressure melamine, diallylphthale-1, unsaturated polynisdel, etc.
転写は、熱圧成形により行われ、次いて剥離層を除去す
る。こうして、成形同時転写により、表面に微細凹凸か
賦形さねた光輝ｆｉインキ層が熱硬化性樹脂層トヘ転写
される。Transfer is performed by hot pressing, and then the release layer is removed. In this manner, the bright fi ink layer, which has fine irregularities formed on the surface, is transferred to the thermosetting resin layer by simultaneous molding and transfer.
第１図は本発明方法を説明するだめの概略断面図であり
、微細な凹凸形状３か付与された剥離層１および光輝性
インキ層２から成る転写フィルム（、Ａ）を、化粧板厚
材４の熱硬化性樹脂層５１に積層して熱圧成形しべＢ）
、次いで剥離層ｌを剥離する（Ｃ）。FIG. 1 is a schematic cross-sectional view for explaining the method of the present invention, in which a transfer film (A) consisting of a release layer 1 provided with a fine uneven shape 3 and a glitter ink layer 2 is transferred to a thick decorative board. Laminated on the thermosetting resin layer 51 of No. 4 to form a thermo-press molded stamen B)
Then, the release layer 1 is removed (C).
第２図は本発明の化粧板の特に好ましい構成を示す断面
図であって、バランスシート４、コア紙５、メラミン樹
脂含浸チタン紙６１．メラミン樹脂含浸オーバーレイ７
、および微細な凹凸形状３を有する光輝性インキ層２か
順次積層され−Ｃいる（実施例参照）。FIG. 2 is a cross-sectional view showing a particularly preferred configuration of the decorative board of the present invention, including a balance sheet 4, a core paper 5, a melamine resin-impregnated titanium paper 61. Melamine resin impregnated overlay 7
, and a glittering ink layer 2 having a fine uneven shape 3 are sequentially laminated (see Examples).
以下、本発明を実施例によりさらに説明するか、本発明
はこれによって限定されるものではない。Hereinafter, the present invention will be further explained with reference to Examples, but the present invention is not limited thereto.
ＰＥＴフィルム（Ｅ−５１００５０μｍ、東洋紡績■製
）トＰＰフィルム（ＦＨＫ−２０２０μｍ１１、二相化
学■製）とを、クラ１ノブラスチツクス■のドライラミ
加工機で接着し、次いて１３（じＣ，３０ｋｇｆ、／’
（Ｊ１１２．４Ｏｒｎ／ｒｒ＋ｉｎＯ熱圧条件−Ｃ」−
記フィルムのＰＰ面に微細な凹凸を、［１−）（エンボ
スにより施す。使用するＵ−ルは版深１０μｍ、周期６
０μｍ（凹部３０ＩＩｎ＋、凸部３０ Ｂ ｒｎ）を有
−する。A PET film (E-510050 μm, manufactured by Toyobo ■) and a PP film (FHK-2020 μm11, manufactured by Nipha Kagaku ■) were bonded together using a dry laminating machine manufactured by Kura1 Noblastics ■, and then 13 (JC, 30 kgf, /'
(J112.4Orn/rr+inO heat and pressure conditions-C”-
Fine irregularities are made on the PP surface of the film by [1-) (emboss).
0 μm (concave portion 30IIn+, convex portion 30Brn).
■−７記のエンボスを施したシートのエンボス面に、ウ
レタンタイプシルバーインク〔昨昭和インク製、アルミ
顔料〕を用いて、ヘル社の電子彫刻機ヘリオクリフシ３
グラフよにり４０線／ｃｍ’、角度００の規、格で彫刻
したベタグラビア版により２回ペタ印刷す゛る。■-Using urethane type silver ink [manufactured by Showa Ink, aluminum pigment] on the embossed surface of the sheet that has been embossed in section 7,
It is printed twice using a solid gravure plate engraved with a standard of 40 lines/cm' and an angle of 00 according to the graph.
得られた、ノーＩ−の印刷面Ｉ：にメラミン含浸オーバ
ーしイ紙（２５ｇ／ｒｎ２太［’ｌｌ産業（掬）を積層
し、さらにその十に順次にメラミン樹脂含浸チタン紙（
■興入、 ８０ ｇ／ｍ２ＰＭ２５Ｐ）、フェノール含
浸コア紙（太田産業（掬）およびバランスシートを積層
し、１３０℃、８０ｋｇｆ／ｃｍ’ 、１５分の条件で
熱圧成形したのぢ、エンボス賦形フィルム（ＰＥＴ／Ｐ
Ｐ複合フィルｊ、）を剥離したところ、光輝性かありし
かも表面に微細な凹凸のある化粧板か得られた。The printed surface I of the resulting No.
■ 80 g/m2PM25P), phenol-impregnated core paper (Ota Sangyo (Kikki)) and balance sheet were laminated and hot-press molded at 130℃, 80kgf/cm' for 15 minutes, and embossed. Film (PET/P
When the P composite film j,) was peeled off, a decorative board with glitter and fine irregularities on the surface was obtained.
本発明によれば、微細な凹凸形状を有する光輝性インキ
層を熱硬化性樹脂化粧板の最表面に設（Ｊることによっ
て、光の角度および見る角度によって表情か変化する化
粧板が提供される。また、本発明方法の成形同時転写は
、このよ・うな化粧板を簡単かつ経済的な手段゛で提供
する。According to the present invention, a glitter ink layer having a fine uneven shape is provided on the outermost surface of a thermosetting resin decorative board, thereby providing a decorative board whose expression changes depending on the angle of light and viewing angle. Moreover, the simultaneous molding and transfer of the method of the present invention provides such decorative laminates in a simple and economical manner.
第１図は本発明方法を説明するための概略断面図であり
、第２図は本発明の化粧板の特に好まし。
い構成を示す断面図である。FIG. 1 is a schematic sectional view for explaining the method of the present invention, and FIG. 2 is a particularly preferred decorative laminate of the present invention. FIG.
Claims (1)
面に微細な凹凸形状が設けられていることを特徴とする
熱硬化性樹脂化粧板。 ２、離型シート上にポリオレフィン系樹脂の層を設け、
該樹脂層の表面に微細な凹凸形状を付与した後、該凹凸
面に光輝性インキ層を形成し、こうして得られた転写シ
ートを熱硬化性樹脂含浸紙に重ねて熱圧成形し、次いで
該離型シートを剥離することを特徴とする、表面に微細
な凹凸形状を有する熱硬化性樹脂化粧板の製造法。[Scope of Claims] 1. A thermosetting resin decorative board characterized by having a glittering ink layer on its surface, and having fine irregularities formed on the surface of this ink layer. 2. Provide a layer of polyolefin resin on the release sheet,
After imparting a fine uneven shape to the surface of the resin layer, a glitter ink layer is formed on the uneven surface, and the thus obtained transfer sheet is placed on thermosetting resin impregnated paper and hot-press molded. A method for producing a thermosetting resin decorative board having a finely uneven surface on its surface, the method comprising peeling off a release sheet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2208264A JPH0491950A (en) | 1990-08-08 | 1990-08-08 | Thermosetting resin decorative sheet and manufacture thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2208264A JPH0491950A (en) | 1990-08-08 | 1990-08-08 | Thermosetting resin decorative sheet and manufacture thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0491950A true JPH0491950A (en) | 1992-03-25 |
Family
ID=16553362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2208264A Pending JPH0491950A (en) | 1990-08-08 | 1990-08-08 | Thermosetting resin decorative sheet and manufacture thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0491950A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997038868A3 (en) * | 1996-04-15 | 1997-12-11 | Boris Siegmund Davis | Method for producing decorative articles using transfer foils |
| EP1304236A1 (en) * | 2001-10-19 | 2003-04-23 | MZE Engineering GmbH | Process for producing a structured varnish layer |
-
1990
- 1990-08-08 JP JP2208264A patent/JPH0491950A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997038868A3 (en) * | 1996-04-15 | 1997-12-11 | Boris Siegmund Davis | Method for producing decorative articles using transfer foils |
| EP1304236A1 (en) * | 2001-10-19 | 2003-04-23 | MZE Engineering GmbH | Process for producing a structured varnish layer |
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