JPH0459897A - Wax composition for candle - Google Patents
Wax composition for candleInfo
- Publication number
- JPH0459897A JPH0459897A JP16976390A JP16976390A JPH0459897A JP H0459897 A JPH0459897 A JP H0459897A JP 16976390 A JP16976390 A JP 16976390A JP 16976390 A JP16976390 A JP 16976390A JP H0459897 A JPH0459897 A JP H0459897A
- Authority
- JP
- Japan
- Prior art keywords
- wax
- candle
- candles
- weight
- sorbitan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 239000001993 wax Substances 0.000 claims abstract description 42
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 13
- 239000000194 fatty acid Substances 0.000 claims abstract description 13
- 229930195729 fatty acid Natural products 0.000 claims abstract description 13
- -1 sorbitan fatty acid ester Chemical class 0.000 claims abstract description 13
- 239000012188 paraffin wax Substances 0.000 claims abstract description 12
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims abstract description 8
- 239000001587 sorbitan monostearate Substances 0.000 claims abstract description 8
- 235000011076 sorbitan monostearate Nutrition 0.000 claims abstract description 8
- 229940035048 sorbitan monostearate Drugs 0.000 claims abstract description 8
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 claims abstract description 3
- 235000011071 sorbitan monopalmitate Nutrition 0.000 claims abstract description 3
- 239000001570 sorbitan monopalmitate Substances 0.000 claims abstract description 3
- 229940031953 sorbitan monopalmitate Drugs 0.000 claims abstract description 3
- 238000005336 cracking Methods 0.000 claims description 10
- 238000002156 mixing Methods 0.000 abstract description 3
- 238000001816 cooling Methods 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000004200 microcrystalline wax Substances 0.000 description 3
- OTGQIQQTPXJQRG-UHFFFAOYSA-N N-(octadecanoyl)ethanolamine Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCO OTGQIQQTPXJQRG-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- SSZBUIDZHHWXNJ-UHFFFAOYSA-N palmityl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC SSZBUIDZHHWXNJ-UHFFFAOYSA-N 0.000 description 2
- 230000035900 sweating Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229940093629 isopropyl isostearate Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔発明の目的］
（産業上の利用分野）
本発明は新規なローソク用ワックス組成物に関する。更
に詳しくは、パラフィンワックス成分と特定の界面活性
剤成分の組合わせからなる、燃焼性及び耐ヒビ割れ性に
優れたローソク用ワックス組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Object of the Invention] (Field of Industrial Application) The present invention relates to a novel wax composition for candles. More specifically, the present invention relates to a wax composition for candles that is composed of a combination of a paraffin wax component and a specific surfactant component and has excellent flammability and cracking resistance.
（従来の技術）
一般に家庭用、業務用の灯火用ローソクはパラフィンワ
ックスに高級脂肪酸を混合したものを加熱、溶融し、型
に注入し、次いで冷却固化して製造されるが、冷却の条
件でローソクの品質が大きく変ることが知られている。(Prior art) Generally, candles for household and commercial use are manufactured by heating and melting a mixture of paraffin wax and higher fatty acids, injecting it into a mold, and then cooling it to solidify it. It is known that the quality of candles can vary greatly.
例えば冷却速度が遅い場合、製造されるローソクの耐ヒ
ビ割れ性、表面光沢あるいは耐ブロッキング性などの特
性（以下、外観特性ということもある。）は良くなる傾
向にあるが、ローソクを燃やしたときに燃焼鉢（ローソ
クの灯火側の上面部位）が平滑にならなかったりその縁
の一部が欠けたりし、あるいはローソクの溶融物が盛上
がったり、更には燃焼針から流れたりして燃焼性が不良
となる。一方、逆に冷却速度が速い場合、ローソクの燃
焼性は良くなる傾向にあるが、ローソクにヒビ割れが生
じたり、表面が粗くなって光沢を失ったり、耐ブロッキ
ング性が悪化する。For example, if the cooling rate is slow, the candles produced tend to have better properties such as crack resistance, surface gloss, or anti-blocking properties (hereinafter also referred to as appearance properties), but when the candle is burned In some cases, the combustion pot (the upper part of the candle on the light side) is not smooth or part of its edge is chipped, or the molten material from the candle bulges up or even flows from the burning needle, resulting in poor combustibility. becomes. On the other hand, if the cooling rate is fast, the flammability of the candle tends to improve, but the candle may crack, the surface may become rough and lose its luster, and the anti-blocking property may deteriorate.
前記したローソクのヒビ割れを防ぐ方法としては、ワッ
クスの組成においてイソパラフィンの含有量を多くする
か、あるいはマイクロワックスなどの高融点ワックスを
該ワックスに添加する方法などがとられているが、製造
条件、特に高速冷却のもとでは前者の方法ではローソク
が軟らか（なって耐ブロッキング性が悪くなり、また後
者の方法もローソクの燃焼性を著しく悪化させることが
知られている。Methods to prevent the above-mentioned cracks in candles include increasing the content of isoparaffin in the wax composition, or adding high melting point wax such as micro wax to the wax, but depending on the manufacturing conditions. It is known that, especially under high-speed cooling, the former method results in soft candles (and poor anti-blocking properties), and the latter method also significantly deteriorates the flammability of the candle.
（発明が解決しようとする課題）
本発明は、ローソク製造時の冷却条件の如何に拘らず、
また通常行なわれているローソクのヒビ割れ防止方法で
みられるローソクの品質を損なうことなく、ローソクの
燃焼性とヒビ割れ性などの外観特性を同時に満足するロ
ーソク用ワックス組成物に関するもので、パラフィンワ
ックスのカーボン数の範囲がＣ２９以上のパラフィンワ
ックスを含有するワックス組成物に対して、特定のソル
ビタン脂肪酸エステル類を配合することにより前記した
問題点を解決しようとするものである。(Problem to be solved by the invention) The present invention solves the problem regardless of the cooling conditions during candle manufacturing.
It also relates to a wax composition for candles that simultaneously satisfies appearance characteristics such as flammability and cracking resistance of candles without impairing the quality of candles that is seen in the conventional method of preventing cracking of candles. The above-mentioned problems are attempted to be solved by blending specific sorbitan fatty acid esters into a wax composition containing paraffin wax having a carbon number range of C29 or higher.
（課題を解決するための手段）
本発明を概説すれば、本発明は、ローソク用に使用され
るワックス組成物において、ワックス成分としてＣ２９
以上のパラフィンワックスを３５〜４５重量％含有する
ワックス成分、及び該ワックス成分１ｏｏ１１部に対し
てソルビタン脂肪酸エステル類を０．０１重量部以上配
合したものであることを特徴とするローソクの燃焼性及
び耐ヒビ割れ性に優れたローソク用ワックス組成物に関
するものである。(Means for Solving the Problems) To summarize the present invention, in the wax composition used for candles, C29 is used as a wax component.
The flammability of the candle is characterized by a wax component containing 35 to 45% by weight of the above paraffin wax, and 0.01 part by weight or more of sorbitan fatty acid esters per 10.1 parts by weight of the wax component. This invention relates to a wax composition for candles that has excellent cracking resistance.
以下、本発明の構成を詳しく説明する。Hereinafter, the configuration of the present invention will be explained in detail.
本発明におけるローソク用ワックス組成物は、ローソク
の良好な燃焼性を得るためにワックス成分として、０２
９以上のパラフィンワックスが全ワックス成分の３５〜
４５重量％の割合で含有するものを使用することを特徴
とするものである。これは通常のワックスの製造方法の
発汗操作における温度条件を変えることにより容易に製
造することができる。このような方法で製造されたワッ
クス組成物はイソパラフィンの含有量が少ないものであ
り、これをローソクの生産性を考慮して急速冷却のもと
てローソクを製造した場合、ローソクにヒビ割れ９表面
光沢。The wax composition for candles in the present invention contains 0.2% as a wax component in order to obtain good flammability of candles.
Paraffin wax of 9 or more accounts for 35 to 35% of the total wax component
It is characterized in that it contains 45% by weight. This can be easily produced by changing the temperature conditions during the sweating operation of a conventional wax production method. The wax composition produced by this method has a low content of isoparaffin, and when it is rapidly cooled to produce candles in consideration of candle productivity, the candle may have cracks 9 on its surface. Shiny.
耐ブロッキング性などに問題が生じることは前述の通り
である。As mentioned above, problems such as blocking resistance arise.
本発明は、パラフィンワックスを主体としながらローソ
クの品質を悪くするイソパラフィンの含有量を多くする
方法や、またはマイクロワックスなどの高融点ワックス
を添加する方法を採用するのではなく、高度に燃焼性を
維持しながら、前記した特定のソルビタン脂肪酸エステ
ル系界面活性剤を用いることにより、ローソクのヒビ割
れ等の外観特性を改良しようとするものである。当然の
ことながら、本発明においては、前記したイソパラフィ
ンあるいはマイクロワックスを添加することを排除する
ものではない。The present invention does not adopt a method that uses paraffin wax as the main ingredient but increases the content of isoparaffin, which deteriorates the quality of the candle, or a method that adds high melting point wax such as micro wax. By using the above-mentioned specific sorbitan fatty acid ester surfactant, the appearance characteristics such as cracking of candles can be improved while maintaining the same. Naturally, the present invention does not exclude the addition of the above-described isoparaffin or microwax.
本発明で使用する界面活性剤はワックスに易溶であって
、添加することによってワックスの色調を変えないこと
、かつ、ローソク製造時にワックスに混合される高級脂
肪酸と反応しないことが必要である。また同時に特にヒ
ビ割れ防止作用としてワックスが固化する際、ワックス
結晶の凝集力を分散、均一化する機能が必要である。The surfactant used in the present invention must be easily soluble in the wax, must not change the color tone of the wax when added, and must not react with higher fatty acids mixed into the wax during candle manufacture. At the same time, it is necessary to have a function of dispersing and uniformizing the cohesive force of the wax crystals when the wax solidifies, especially as a crack prevention function.
本発明は、前記した観点から界面活性剤について鋭意検
討した結果、非イオン界面活性剤が有効であること、な
かでもソルビタン脂肪酸エステル類が諸条件を満足して
ローソクのヒビ割れ防止などの特性改善に効果のあるこ
とが見出された。その他の高級脂肪酸エステル類、たと
えば、イソプロピルイソステアレート、ブチルステアレ
ート、ヘキサデシルステアレートなど；高級脂肪酸のア
ルカノールアミド類、たとえばステアリン酸モノエタノ
ールアミドなど；およびアルキルフェノールエーテル類
、たとえばポリオキシエチレンノニルフェノールエーテ
ルなどは効果をもたなかった。As a result of extensive studies on surfactants from the above-mentioned viewpoints, the present invention found that nonionic surfactants are effective, and that sorbitan fatty acid esters in particular satisfy various conditions and improve properties such as preventing cracking of candles. was found to be effective. Other higher fatty acid esters, such as isopropyl isostearate, butyl stearate, hexadecyl stearate; alkanolamides of higher fatty acids, such as stearic acid monoethanolamide; and alkylphenol ethers, such as polyoxyethylene nonylphenol ether etc. had no effect.
本発明で使用されるソルビタン脂肪酸エステル類として
は、例えばソルビタンモノステアレートおよびソルビタ
ンモノパルミテートなどがあげられ、この中でワックス
の融点に最も近い融点をもつソルビタンモノステアレー
トが特に好ましいものである。Examples of the sorbitan fatty acid esters used in the present invention include sorbitan monostearate and sorbitan monopalmitate, and among these, sorbitan monostearate, which has a melting point closest to that of wax, is particularly preferred. .
ソルビタンモノステアレートのワックスへの添加量はワ
ックス中のイソパラフィン含有量およびローソク製造時
の冷却条件により、その最少必要添加量は異なるが、一
般にワックス組成物全体対して０．０１重量部以上配合
して良く、特に好ましくは０．０３〜０．１５重量部の
範囲がよい。The minimum amount of sorbitan monostearate added to the wax varies depending on the isoparaffin content in the wax and the cooling conditions during candle manufacturing, but it is generally 0.01 part by weight or more based on the entire wax composition. The amount may be particularly preferably from 0.03 to 0.15 parts by weight.
しかしながら、本発明においては前記した添加量を超え
て、たとえば、０．２０Ｍ量部あるいはそれ以上を添加
してもローソクの燃焼性およびその他の品質に影響する
ことがないため、同等差支えないものである。However, in the present invention, even if the amount added exceeds the above-mentioned amount, for example, 0.20 M part or more, it will not affect the flammability and other qualities of the candle, so there is no problem. be.
（実施例）
以下、本発明を実施例により更に詳しく説明するが、本
発明はこれら実施例のものに限定されない。(Examples) Hereinafter, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited to these Examples.
実施例１〜３／比較例１〜４
発汗装置でワックス成分として０２９〜Ｃ３４のパラフ
ィンワックス含有量が表−１の重量％となるように調整
されたワックス（１００重量部）にソルビタンモノステ
アレートを０．１重量部（比較例３は無添加）、ステア
リン酸５重量部を加え、これを工業的に用いられている
６３０大の３号ローソク成型機で、水温、水量をかえて
ローソクの冷却速度が毎分６℃、 １３℃および２０℃
である条件でローソクに成型し１条件ごとに１０本のロ
ーソクを抜取って燃焼させ、点火から９０分間のローソ
クの燃焼鉢に生ずる縁の欠損数および溶融液の盛上り回
数の総数を計測した。この総数が１５以下を良、 １６
〜３０をやや不良、 ３１以上を不良としてローソクの
燃焼性を評価した。また、同時にローソク表面のヒビ割
れ状態についても観察した。これは、電気スタンドなと
のライトにローソクをかざしローソク全体について亀裂
の有無を観察するもので、亀裂がローソク１本につき１
個でもあればヒビ割れ性不合格と評価した。Examples 1 to 3/Comparative Examples 1 to 4 Sorbitan monostearate was added to wax (100 parts by weight) which was adjusted so that the content of 029 to C34 paraffin wax as a wax component was the weight% shown in Table 1 in a sweating device. 0.1 part by weight (no additive in Comparative Example 3) and 5 parts by weight of stearic acid were used to make candles using an industrially used 630 size No. 3 candle molding machine by changing the water temperature and water amount. Cooling rate: 6℃, 13℃ and 20℃ per minute
The candles were molded into candles under certain conditions, and 10 candles were taken out for each condition and burned, and the total number of edges missing and the number of times the molten liquid swelled in the candle burning pot was measured for 90 minutes after ignition. . If this total number is 15 or less, it is considered good; 16
The flammability of the candle was evaluated with a score of ~30 as slightly poor and a score of 31 or higher as poor. At the same time, we also observed cracks on the candle surface. This involves holding a candle over a light such as a desk lamp and observing whether there are any cracks on the entire candle.There are only 1 crack per candle.
If there was even a single particle, it was evaluated as a failure due to cracking property.
この結果、実施例１〜３でわかるようにＣ２９〜Ｃ８４
のパラフィンワックスを３６〜４５重量部含有するワッ
クスにおいて、全ての冷却条件で燃焼性及びヒビ割れ状
態が良好であった。As a result, as shown in Examples 1 to 3, C29 to C84
The wax containing 36 to 45 parts by weight of paraffin wax had good flammability and cracking under all cooling conditions.
実施例４〜５
表−２に示すように実施例１で用いたワックス組成物（
１００重量部）にソルビタンモノステアレートをそれぞ
れ０．０５．０．１５重量部含有させたワックスを、毎
分６℃の冷却条件で前記と同じローソク成型機でローソ
クを成型し、同じ方法でローソクの燃焼性を評価した結
果はすべて良好であった。Examples 4-5 As shown in Table 2, the wax composition used in Example 1 (
100 parts by weight) containing 0.05 and 0.15 parts by weight of sorbitan monostearate, respectively, were molded into candles using the same candle molding machine as described above under cooling conditions of 6°C per minute. The results of evaluating the flammability of the materials were all favorable.
比較例５〜６
表−３に示すように、実施例２で用いたワックスにソル
ビタンモノステアレートにかえてイソブチルイソステア
レート、及びステアリン酸モノエタノールアミドを各々
０．１重量部配合し、毎分６℃の冷却条件で実施例２
と同様の評価を行なった。その結果、ローソクの燃焼性
は良いものの口、−ツクのヒビ割れ状態は不合格であっ
た。Comparative Examples 5 to 6 As shown in Table 3, 0.1 parts by weight each of isobutyl isostearate and stearic acid monoethanolamide were added to the wax used in Example 2 instead of sorbitan monostearate, and each Example 2 under cooling conditions of 6°C
A similar evaluation was conducted. As a result, although the flammability of the candle was good, the cracks in the opening and the opening of the candle did not pass the test.
（以下余白）
〔発明の効果〕
本発明により、耐ブロツキング性０表面の平滑性、光沢
などローソクの一般的品質を損なうことなしに、優れた
燃焼性および耐ヒビ割れ性をもつローソクを製造するた
めのローソク用のワックス組成物が提供される。(The following is a blank space) [Effects of the Invention] According to the present invention, a candle having excellent combustibility and cracking resistance is produced without impairing the general qualities of candles such as anti-blocking, surface smoothness, and gloss. A wax composition for a candle is provided.
また１本発明のローソク用組成物は、ローソク製造時に
おいて、広範囲の製造条件に対応することができ、特に
冷却条件を急速冷却とすることができるため、ローソク
の生産を効率的かつ生産性に行なうことができる。In addition, the candle composition of the present invention can be applied to a wide range of manufacturing conditions during candle manufacturing, and in particular can be used for rapid cooling, making candle production efficient and productive. can be done.
特許出願人 東 燃 株式会社代 理 人Patent applicant Higashi Nen Co., Ltd. Reason Man
Claims (1)
ワックス成分としてＣ＿２＿９以上のパラフィンワック
スを３５〜４５重量％含有するワックス成分、及び該ワ
ックス成分１００重量部に対してソルビタン脂肪酸エス
テル類を０．０１重量部以上配合したものであることを
特徴とするローソクの燃焼性及び耐ヒビ割れ性に優れた
ローソク用ワックス組成物。 ２、Ｃ＿２＿９以上のパラフィンワックスが、Ｃ＿２＿
９〜Ｃ＿３＿４のものである請求項第１項に記載のロー
ソク用ワックス組成物。 ３、ソルビタン脂肪酸エステル類が、ソルビタンモノス
テアレート及びソルビタンモノパルミテートより選ばれ
た少なくとも１種である請求項第１項に記載のローソク
用ワックス組成物。[Claims] 1. In a wax composition used for candles,
A wax component containing 35 to 45% by weight of paraffin wax with C_2_9 or higher as a wax component, and 0.01 part by weight or more of sorbitan fatty acid esters per 100 parts by weight of the wax component. A candle wax composition with excellent candle combustibility and cracking resistance. 2.Paraffin wax with C_2_9 or higher has C_2_
9 to C_3_4. The candle wax composition according to claim 1. 3. The candle wax composition according to claim 1, wherein the sorbitan fatty acid ester is at least one selected from sorbitan monostearate and sorbitan monopalmitate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16976390A JPH0459897A (en) | 1990-06-29 | 1990-06-29 | Wax composition for candle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16976390A JPH0459897A (en) | 1990-06-29 | 1990-06-29 | Wax composition for candle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0459897A true JPH0459897A (en) | 1992-02-26 |
Family
ID=15892404
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16976390A Pending JPH0459897A (en) | 1990-06-29 | 1990-06-29 | Wax composition for candle |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0459897A (en) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6503285B1 (en) | 2001-05-11 | 2003-01-07 | Cargill, Inc. | Triacylglycerol based candle wax |
| US6645261B2 (en) | 2000-03-06 | 2003-11-11 | Cargill, Inc. | Triacylglycerol-based alternative to paraffin wax |
| US6758869B2 (en) | 2000-02-02 | 2004-07-06 | Cleanwax, Llp | Non sooting paraffin containing candle |
| US6773469B2 (en) | 2002-11-12 | 2004-08-10 | Cargill, Incorporated | Triacylglycerol based wax for use in candles |
| US6797020B2 (en) | 2002-11-12 | 2004-09-28 | Cargill, Incorporated | Triacylglycerol based wax for use in container candles |
| US6824572B2 (en) | 2001-03-06 | 2004-11-30 | Cargill, Incorporated | Vegetable oil based wax compositions |
| US6852140B1 (en) | 1999-09-24 | 2005-02-08 | Cleanwax, Llc | Low-soot, low-smoke renewable resource candle |
| US7128766B2 (en) | 2001-09-25 | 2006-10-31 | Cargill, Incorporated | Triacylglycerol based wax compositions |
| US7387649B2 (en) | 1998-08-12 | 2008-06-17 | Tao Bernard Y | Vegetable lipid-based composition and candle |
| US7510584B2 (en) | 2004-10-13 | 2009-03-31 | Daniel S. Cap | Acetylated wax compositions and articles containing them |
| US7588607B1 (en) | 2005-03-16 | 2009-09-15 | Daniel S. Cap | Candlewax compositions with improved scent-throw |
| US8137418B2 (en) | 1998-08-12 | 2012-03-20 | Indiana Soybean Alliance | Vegetable lipid-based composition and candle |
| US8876919B2 (en) | 2010-03-10 | 2014-11-04 | Elevance Renewable Sciences, Inc. | Lipid-based wax compositions substantially free of fat bloom and methods of making |
| US8911515B2 (en) | 2005-01-10 | 2014-12-16 | Elevance Renewable Sciences, Inc. | Candle and candle wax containing metathesis and metathesis-like products |
| US8940090B2 (en) | 2007-02-16 | 2015-01-27 | Elevance Renewable Sciences, Inc. | Wax compositions and methods of preparing wax compositions |
| US9139801B2 (en) | 2011-07-10 | 2015-09-22 | Elevance Renewable Sciences, Inc. | Metallic soap compositions for various applications |
| US9249360B2 (en) | 2010-07-09 | 2016-02-02 | Elevance Renewable Sciences, Inc. | Compositions derived from metathesized natural oils and amines and methods of making |
| US9458411B2 (en) | 2010-11-23 | 2016-10-04 | Cargill, Incorporated | Lipid-based wax compositions substantially free of fat bloom and methods of making |
-
1990
- 1990-06-29 JP JP16976390A patent/JPH0459897A/en active Pending
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8137418B2 (en) | 1998-08-12 | 2012-03-20 | Indiana Soybean Alliance | Vegetable lipid-based composition and candle |
| US7731767B2 (en) | 1998-08-12 | 2010-06-08 | Indiana Soybean Board, Inc. | Vegetable lipid-based composition and candle |
| US8404003B2 (en) | 1998-08-12 | 2013-03-26 | Indiana Soybean Board, Inc. | Vegetable lipid-based composition and candle |
| US7387649B2 (en) | 1998-08-12 | 2008-06-17 | Tao Bernard Y | Vegetable lipid-based composition and candle |
| US6852140B1 (en) | 1999-09-24 | 2005-02-08 | Cleanwax, Llc | Low-soot, low-smoke renewable resource candle |
| US6758869B2 (en) | 2000-02-02 | 2004-07-06 | Cleanwax, Llp | Non sooting paraffin containing candle |
| US6645261B2 (en) | 2000-03-06 | 2003-11-11 | Cargill, Inc. | Triacylglycerol-based alternative to paraffin wax |
| US7217301B2 (en) | 2000-03-06 | 2007-05-15 | Cargill, Incorporated | Triacylglycerol-based alternative to paraffin wax |
| US6824572B2 (en) | 2001-03-06 | 2004-11-30 | Cargill, Incorporated | Vegetable oil based wax compositions |
| EP1390460A4 (en) * | 2001-05-11 | 2004-10-20 | Cargill Inc | Triacylglycerol based candle wax |
| US7462205B2 (en) | 2001-05-11 | 2008-12-09 | Elevance Renewable Sciences, Inc. | Triacylglycerol based candle wax |
| US6503285B1 (en) | 2001-05-11 | 2003-01-07 | Cargill, Inc. | Triacylglycerol based candle wax |
| US6770104B2 (en) | 2001-05-11 | 2004-08-03 | Cargill, Incorporated | Triacylglycerol based candle wax |
| EP1390460A1 (en) * | 2001-05-11 | 2004-02-25 | Cargill Incorporated | Triacylglycerol based candle wax |
| US8070833B2 (en) | 2001-05-11 | 2011-12-06 | Elevance Renewable Sciences, Inc. | Triacyglycerol based candle wax |
| US7128766B2 (en) | 2001-09-25 | 2006-10-31 | Cargill, Incorporated | Triacylglycerol based wax compositions |
| US6797020B2 (en) | 2002-11-12 | 2004-09-28 | Cargill, Incorporated | Triacylglycerol based wax for use in container candles |
| US6773469B2 (en) | 2002-11-12 | 2004-08-10 | Cargill, Incorporated | Triacylglycerol based wax for use in candles |
| US7510584B2 (en) | 2004-10-13 | 2009-03-31 | Daniel S. Cap | Acetylated wax compositions and articles containing them |
| US8911515B2 (en) | 2005-01-10 | 2014-12-16 | Elevance Renewable Sciences, Inc. | Candle and candle wax containing metathesis and metathesis-like products |
| US7588607B1 (en) | 2005-03-16 | 2009-09-15 | Daniel S. Cap | Candlewax compositions with improved scent-throw |
| US8940090B2 (en) | 2007-02-16 | 2015-01-27 | Elevance Renewable Sciences, Inc. | Wax compositions and methods of preparing wax compositions |
| US8876919B2 (en) | 2010-03-10 | 2014-11-04 | Elevance Renewable Sciences, Inc. | Lipid-based wax compositions substantially free of fat bloom and methods of making |
| US9249360B2 (en) | 2010-07-09 | 2016-02-02 | Elevance Renewable Sciences, Inc. | Compositions derived from metathesized natural oils and amines and methods of making |
| US9867771B2 (en) | 2010-07-09 | 2018-01-16 | Elevance Renewable Sciences, Inc. | Waxes derived from metathesized natural oils and amines and methods of making |
| US9458411B2 (en) | 2010-11-23 | 2016-10-04 | Cargill, Incorporated | Lipid-based wax compositions substantially free of fat bloom and methods of making |
| US10179888B2 (en) | 2010-11-23 | 2019-01-15 | Cargill, Incorporated | Lipid-based wax compositions substantially free of fat bloom and methods of making |
| US9139801B2 (en) | 2011-07-10 | 2015-09-22 | Elevance Renewable Sciences, Inc. | Metallic soap compositions for various applications |
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